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LEARNING PLAN FORM

SUBJECT : CHEMSTRY
Main Topic : Acid and Base
Class / Program / Semester : XI Level / Natural Science / 2
Meeting to :2
Allocation of Time : 2 Hours of Lesson
Competency Standards : 4. Understanding the properties of acid and base
solution, methods of measurements, and its
application.
Basic Competency : 4.2. Describing acid and base by determining
properties of solution, calculating pH of one
solution, and calculating the concentration of
reactant and product in electrolyte solution from
acid base titration.
Indicators : 1. Calculating concentration of H+ and OH- in a
solution
2. Calculating the acidity (pH) of a solution.
3. Explaining and formulating acid base titration.
4. Calculating the unknown concentration of certain
solution trough titration method.

I. Learning Objectives
1. Students can calculate concentration of H+ and OH- in a solution.
2. Students can calculate the acidity (pH) of a solution.
3. Students can explain and formulate acid base titration.
4. Students can calculate the unknown concentration of certain solution trough
titration method.

II. Learning Matters


1. The Acidity of Acids and Bases
2. Reaction of Acids and Bases

III. Learning Method


Method: 1. Expository
2. Discussion
3. Student Active Learning
4. Ask and Answer

IV. Steps of Learning


a. Initial activity:
1. The opening greeting and check the attendances of students.
2. Students are divided into some groups randomly
2. Giving students some motivations and brain storming about acid base theories.
3. Organizing learning matters will be taught.

b. Main Activities:
1. Students listen to the teacher who teach the matter of the acidity of acids and
based and reaction of acids and bases.
2. Students discuss about some questions given by teacher after teach the matter of
the acidity of acids and base and reaction of acids and bases
3. Students do some exercises given by teacher after teach the matter of the acidity
of acids and base and reaction of acids and bases in front of class one by one in
each group.
c. Last Activity:
1. Feed back from students to teacher by ask and answer method.
2. Evaluation (Home work).
3. Closing greeting.

V. Equipment / Materials / Resources


- Book of Chemistry.
Justiana, Sandri, dkk, 2006. Chemistry for Senior High School Year XI. Jakarta:
Yudhistira.
Sunardi, 2006. Kimia Bilingual untuk SMA Kelas XI. Bandung: Yrama Widya.
- Laptop and infocus.
- White board.
- Marker.

VI. Assessments
- Written test : Answer the Question in Objective Test (Homework) and Essay.
- Performance : Ability in answering from one question.

VII. Appendix
Summary of Topic
A. The Acidity (pH) of Acids and Bases
Acidity is the measure of concentration of an acid in a substance, often measured in
term of pH. In this case, pH of a solution can be determine based on calculation or
measurement. In this subchapter how to calculate pH of a solution and how to measure pH
will be explained.

1. Calculating pH of Acid and Base Solutions


At room temperature, the pure water is dissociated into H+ and OH- ions. The
concentration of H+ and OH- ions is considered to be the same, that is 10 -7-mole. Thus, in
every one liter of the pure water there are H+ and OH- ions each of 10-7 mole. The
dissolving of an acid in water will add the concentration of H+ ion in the solution.
Meanwhile, the dissolving of a base in water will add the concentration of OH- ion in the
solution which can reduce the concentration of H+ ion. Soren Pieter L Sorrensen proposed
the pH concept to replace the concentration as a measure of acidity or basicity of a solution,
in which the relation of pH and concentration of H+ ion and OH- was represented by the
following equation.
pH = - log [H+] and pOH = - log [OH-]

a. pH of Strong Acids and Strong Base


pH = - log [H+] and pOH = - log [OH-]

b. pH of Weak Acids and Weak Base


[ ]
pH = −log H + = −log [
Ka × H + ]
[
pH = −log OH −
] = −log Kb × OH[ −
]
B. Reaction of Acids and Bases
1. Acid Base Neutralization
If an acid solution and base are mixed, the H+ ion from the acid will react with OH-
ions from base to form water according to the following reaction equation.
H+ (aq) + OH-(aq) → H2O(l)
In a certain composition, the mixture of those two substances can be neutral,
therefore the reaction of an acid and a base is called the neutralization reaction. Besides
H2O is formed, in the neutralization reaction other compound are also formed which are the
combination of remaining ions in the acid base mixture, that is salts.
NaOH + H2O → NaC + H2O
2. Acid Base Titration
The concept of neutralization reaction can be applied in titration. Titration is a
method of determining the concentration of a dissolved substance by adding quantities of a
standard solution is referred to as the titrant. Generally, a titration is based on the volume of
solution, so it’s called volumetric titration. In the relation to acids and base, then titration
involving reactions of those two substances is called acid base titration.

Calculation in acid base titration.


Short cut:
Macid x Vacid x e = Mbase x Vbase x e

…………..P_)(*&^%$#@!................

Objective Test
(as Homework)

1. Concentrations of hydroxide and hydrogen ion in NaOH 0.01M solution are…


a. [OH-] = 1M and [H+] = 10-12 M
b. [OH-] = 10-1M and [H+] = 10-12 M
c. [OH-] = 10-2M and [H+] = 10-12 M
d. [OH-] = 1M and [H+] = 10-2 M
e. [OH-] = 10-1M and [H+] = 10-1 M

2. Concentration of hydrogen ion found in 250 mL of HCN 0.15M solution


(Ka = 5 x 10-10) is …..
a. 8.7 x 10-6M c. 6.5 x 10-6M e. 4.0 x 10-7M
b. 8.0 x 10-6M d. 8.7 x 10-7M

3. pH of a weak base which has one valence is equal to 11. The concentration of OH- ion
in the base solution is …..
a. 1 x 10-11 c. 1 x 10-4 e. 1 x 10-2
-14 -3
b. 1 x 10 d. 1 x 10

4. A sulfuric acid 0.01M solution gives a same color with a weak acid 0.1M solution
when they are dropped by any similar indicator. Ka of the weak acid is ……..
a. 1 x 10-3 c. 4 x 10-2 e. 4 x 10-5
-3 -4
b. 4 x 10 d. 4 x 10

5. To neutralize 10 mL of sulfuric acid 0.1M solution the solution hydroxide 0.1M is


required as much as ………..
a. 5 mL c. 15 mL e. 40 mL
b. 10 mL d. 20 mL

Answer Key
Objective Test
1. C
2. A
3. D
4. B
5. D

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