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1: Arenes
Benzene C6H6
Methylbenzene
c. Use your data booklet to compare the melting points and boiling points
of benzene and methylbenzene. Suggest reasons for the differences.
2. Would you expect the C=C bond in benzene to be more or less susceptible to
addition reaction than the C=C bond in alkenes? Explain your answer.<42>
3. Some of reactions of benzene and its result are shown in table below:<43>
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b. Why does benzene produce a sootier flame than either cyclohexane or
cyclohexene?
5. Write an equation for the addition reaction of benzene with chlorine. Name
the products and state the conditions.<44bi>
8. Write an equation for the reaction of benzene with fuming sulfuric acid. Name
the product and state the conditions.<45a>
9. Write an equation for the reaction of benzene with concentrated nitric acid
and concentrated sulfuric acid. Name the products and state the
conditions.<45b>
10.Suggest a reason for the fact that benzene, an unsaturated compound, does
not ready undergo addition reaqctions.<46>
a. Name the attacking species present in the mixture of acids and write a
balanced equation to represent its formation.<48a>
b. What is the mechanism for the nitration of benzene? State the type of
reaction taking place.<48b>
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b. What names are given to each of the reactions shown above?<50b>
13.Dry chlorine was passed slowly into about 20 cm3 of benzene contained in a
flask irradiated with an ultraviolet lamp. The entire apparatus was set up in a
fume cupboard and was covered completely with black paper.<51>
e. Give two reasons for carrying out the experiment in a fume cupboard.