Professional Documents
Culture Documents
PA1NT FORMULATIONS
Volume 4
by
Ernest W. Flick
I np I NOYES PUBLICATIONS
WesWood, New Jersey, U.S.A.
Copyright 8 1997 by Ernest W. Flick
No patt of this book may be reproduced or utilized in
any fonn or by any means, electronic or mechanical
including photocopying, recording 01 by any informa-
tion stonge and retrieval system, without permission
in Writing from the Publisher.
Library of Congress Catalog Card Number: 75-2939
ISBN 0-8155-1415-8
Printed in the United States
10 9 8 7 6 5 4 3 2 1
Flick, Ernest W.
Water-based paint formulations.
Each formula has been placed in the chapter which is most applicable. The
reader, if seeking a formula for a specific end use, should check each chapter
which could possibly apply.
vii
...
viii Preface
In addition to the above, there are two other sections which will be helpful to
the reader:
Ernest W. Flick
Notice
Water-based paint raw materials could be toxic, and therefore, due caution
should always be exercised in the use of these hazardous materials. Final
determination of the suitability of any information or product for use
contemplated by any user, and the manner of that use, is the sole
responsibility of the user. We strongly recommend that users seek and
adhere to a manufacturer's or supplier's current instructions for handling
each material they use.
The Author and Publisher have used their best efforts to include only the
most recent data available. The reader is cautioned to consult the supplier
in case of questions regarding current availability.
SECTION I: COATINGS AND TOPCOATS . . . . . . . . . . . . . . . . . . . . 1
Acrylic EmulsiodUrea-Formaldehyde Wood
Clearcoat Modification . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2
Aliphatic Wood Coating Formulation (Sancure
825/Rhoplex CL-104) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3
Ancamine 2410 High Solids Coating . . . . . . . . . . . . . . . . . . . . . . . . 4
Exhibit 4 .Starting Formulation Ancamine
2410/Ancamide 500 High Solids Coating . . . . . . . . . . . . . . . . . . 5
Black Single Coat K-Flex XM-4316 PU Dispersion
Cured with HMMM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6
Clear Bake Coating . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7
Phenolic Clear Bake Coating . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8
Clear Bake Coating . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9
Phenolic Clear Bake Coating . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9
Clear Wood Coating-A & B & C K-Flex UD-320W Modified . . . . 10
Direct to Metal Acrylic Latex Coating Starting Point
Formulation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11
Low Gloss VinyVABS Topcoat . . . . . . . . . . . . . . . . . . . . . . . . . . . 12
Clear Topcoat for Flexible Substrates . . . . . . . . . . . . . . . . . . . . . . . 12
Strippable Coating Sample Formulation A Unmodified . . . . . . . . . . 13
Strippable Coating Sample Formulation B
Lower Adhesion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13
Strippable Coating Formulations Thickened with Ucar
Polyphobe Rheology Modifiers Formula C Good Leveling . . . . . 14
Formula D High Build . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14
Strippable Coating for Plastic Substrates . . . . . . . . . . . . . . . . . . . . . 15
Strippable Coating Formulations . . . . . . . . . . . . . . . . . . . . . . . . . . 16
Topcoat for Prefinished Hardboard Siding . . . . . . . . . . . . . . . . . . . . 17
Water-Borne Alkyd/Melamine Wood Clearcoat Modification . . . . . . 18
Waterborne Clear High Gloss Topcoat . . . . . . . . . . . . . . . . . . . . . . 20
White Gloss Maintenance Topcoat . . . . . . . . . . . . . . . . . . . . . . . . . 21
White Gloss Topcoat . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22
Wood Topcoat Model Formulations . . . . . . . . . . . . . . . . . . . . . . . . 23
ix
x Contents and Subject Index
Acrylic Eaulsion/Urea-Formaldehyde
Wood C l e a r c o a t M o d i f i c a t i o n
K-Flex UD-320W i s an a l i p h a t i c , s a t u r a t e d , w a t e r s o l u b l e r e s i n
m o d i f i e r . T h i s urethane d i o l m o d i f y i n g r e s i n i m p a r t s improved
s t a i n r e s i s t a n c e t o t h e f o r c e d d r y ( t h e r m o s e t ) wood c l e a r c o a t
f o r m u l a t ion b e l ow.
F o r m u l a t i on Procedure:
1 . The components were added i n t h e o r d e r as p r e s e n t e d , f o r
e a s i e r in c o r p o r a t i o n .
2 . The Nacure 155 c a t a l y s t was p r e - d i l u t e d w i t h t h e methanol
below i t i n t h e f o r m u l a t i o n b e f o r e i n c o r p o r a t i o n , w i t h a
Nacure 155/Methanol r a t i o o f 4 5 . 5 / 5 4 . 5 .
S u b s t r a t e : B i r c h Faced Plywood
S e a l e r : S e l f S e a l e d ( 2 Coats, 2 bakes)
S e a l e r / T o p c o a t , WFT: 20-25u ( 0 . 8 - 1 . 0 m i l ) / C o a t
S e a l e r / T o p c o a t Bake: 10 min./71C (160F)
4 Hour Spot T e s t
Stain Test: 0% UD-320W 10% UD-320W
Acrylic/UD-320W/B-65 50/0/50 40/10/50
Coffee Severe Haze Light Stain
Milk Severe Haze No E f f e c t
Mustard No E f f e c t Light Stain
Water Severe Haze No E f f e c t
Lemon J u i c e S l i g h t Haze No E f f e c t
SOURCE: K i n g I n d u s t r i e s : F o r m u l a t i o n WR-26
Coatings and Topcoats 3
A l i p h a t i c Wood C o a t i n n F o r m u l a t i o n
JSancure 8 2 5 / R h o ~ l e x CL-104)
61 end : Pounds
Rhoplex CL-104 (38% S o l i d s ) 134.2
Water 33.8
Add f o l l o w i n g w i t h good a g i t a t i o n :
M i x 10-15 m i n u t e s
Add and m i x 30 m i n u t e s
W i t h no d e t r i m e n t a l e f f e c t upon:
*Topcoat r e c o a t a b i l i t y and i n t e r c o a t adhesion
*Gloss r e t e n t i o n upon a g i n g
*Tannin b l e e d r e s i stance
*Water s e n s i t i v i t y
*Chemical r e s i s t a n c e
Ancamine 2410 H i g h S o l i d s C o a t i n g
Disperse, t h e n r e d u c e speed
B Side:
Ancami ne 241 0 150.5 15.5
Ethyl Alcohol 37.7 5.8
Dissolve, t h e n add:
Disperse t o 6 n . s . u .
Typical Properties:
Non V o l a t i l e b y W e i g h t : 0 . 7 5 Wei g h t / G a l l o n Comp A: 12.06
Non V o l a t i l e b y Volume: 0 . 6 0 W e i g h t / G a l l o n Comp 0: 9.65
PVC: 0 . 1 6 Mixinq Ratio: 1:l
CPVC: 0 . 3 4 Weight p e r G a l l o n : 10.85
PVC/CPVC: 0 . 4 8 I n i t i a l Viscosity: 580 cP
P i gment C o n t e n t : 0 . 3 0 Pot L i f e : 4 . 5 h r
N V V on V e h i c l e : 0 . 6 4 D r y t o Touch: 0 . 7 5 hr
VOC g / 1 : 3 2 7 . 9 Dry Hard: 4 h r
VOC l b s / g a l : 2 . 7 4
SOURCE: A i r P r o d u c t s a n d C h e m i c a l s , I n c . : Ancamine 2 4 1 0 C u r i n g
Agent: E x h i b i t 3 Formulation
Coatings and Topcoats 5
E x h i b i t 4 - S t a r t i n g Formul-ation
Ancarni ne 2 4 1 O/Ancami d e 500 High. Sol i d s C o a t i n g
D i s p e r s e a t H i g h Speed
Reduce Speed, t h e n add:
B Side:
Ancami ne 241 0 77.67 8.00
B e e t l e 216-8 22.7 2.60
Ancamide 500 81.8 10.34
Ethyl Alcohol 29.1 4.44
M e t h y l E t h y l Ketone 73.9 11.01
nButyl Alcohol 81.7 12.10
Ethyl Alcohol 9.8 1.49
Typical Properties:
Non V o l a t i l e b y W e i g h t : 0.72 W e i g h t / G a l l o n Comp A : 9.68
Non V o l a t i l e by Volume: 0.64 W e i g h t / G a l l o n Comp 0: 7.53
PVC: 0.056 M i x i n g R a t i o : 1:l
CPVC: 0.31 Weight p e r G a l l o n : 8.61
P V C / C P V C : 0.17 I n i t i a l V i s c o s i t y : 270 C P
Pigment C o n t e n t : 0.09 Pot L i f e : 3 h r
NVV on V e h i c l e : 0.7 D r y t o Touch: 1.5 h r
VOC g / l : 290.53 Dry Hard: 4 h r
VOC l b s / g a l : 2.43
C o r r o s i o n Resi s t a n c e :
E x h i b i t 4 i s a p r e l i m i n a r y s t a r t i n g f o r m u l a t i o n combi n i ng
Ancamine 2410 c u r i n g a g e n t w i t h Ancamide 500 c u r i n g a g e n t as t h e
B s i d e . C o r r o s i o n r e s i s t a n c e i s v e r y good. C l e v e l a n d h u m i d i t y
t e s t i n g showed no a t t a c k a f t e r 700 h o u r s . S a l t s p r a y r e s u l t s
on g r i t b l a s t e d s t e e l showed no a t t a c k i n t h e f i e l d and m i n o r
a t t a c k a t t h e s c r i b e (8 r a t i n g ) a f t e r 7 0 0 h o u r s .
B l a c k S i n g l e C o a t K-Flex-XM-4316 P U - D ~ s p e r s l o nC u r e d w i t h HMMM
F o r m u l a t i o n WR-40 i s a h i g h p e r f o r m a n c e h i g h g l o s s b l a c k
f o r m u l a t i o n based on K - F l e x XM-4316 p o l y e s t e r - u r e t h a n e d i s p e r s i o n
c r o s s l i n k e d w i t h an amino r e s i n . The f o r m u l a t i o n o f f e r s a h i g h
g l o s s c o a t i ng
Component: %Wt
Pigment G r i n d P a s t e , P a r t 1 :
K-F1 ex XM-2311 2.40
Water, d e i o n i z e d 2.95
Dimethylethanolamine ( 1 ) 0.15
Monarch 1300 1 .oo
K-Sperse 152 MS 0.07
Dimethylethanolamine ( 2 ) 0.10
Pigment Paste, P a r t 2 :
K - F l e x XM-2311 1.20
K-F1 ex XM-4316 1.20
Water, d e i o n i z e d 1.10
Pigment P a s t e 10.17
K-F1 ex XM-4316 63.95
Water d e i o n i zed 6.20
Resimene 747 9.55
N a c u r e 2547 0.13
S i l w e t L7604/L7605 ( 1 : l ) 25% i n H20 0.40
Water as r e q u i r e d f o r v i s c o s i t y a d j u s t m e n t 9.60
Formulation Characteristics:
R e s i n/HMMM, r a t 1 0 : 75/25
N o n v o l a t i l e , c a l c u l a t e d , 'YO: 3 9 . 0
T h e o r e t i c a l VOC, g / L , ( l b / g a l l o n ) : 145, ( 1 . 2 3 )
pH: 7 . 8 - 8 . 3
B r o o k f i e l d V i s c o s i t y , 25C, s p i n d l e #16, 60 rpm, c p . : 300-500
F i l m P r o p e r t i e s : S u b s t r a t e , aluminum
Cure S c h e d u l e , t e m p e r a t u r e , t i m e : 150C, 1 5 m i n u t e s
Dry F i l m Thickness, m i l , (micron): 1.0 (25)
G l o s s , 60, 20, 90: 91, 8 1
Formulation Notes:
P i g m e n t G r i n d P a s t e P a r t 1 : B l e n d t h e K - F l e x XM-2311 p o l y u r e t h a n e
d i s p e r s a n t r e s i n w i t h w a t e r and d i m e t h y l e t h a n o l a m i n e ( 1 ) a n d add
t h e c a r b o n b l a c k , p r e m i x and add t h e b l e n d o f K-Sperse w i t h
d i m e t h y l e t h a n o l a m i n e ( 2 ) , c h e c k t h e pH and add more d i m e t h y l e t h a -
n o l a m i n e i f pH i s b e l o w 9 . 2 , d i s p e r s e i n a s t e e l b a l l m i l l t o
Hegman NS 8 r a t i n g .
P i g m e n t P a s t e P a r t 2 : A f t e r g r i n d i n g i n t h e s t e e l b a l l m i l l add
t h e a d d i t i o n a l K - F l e x XM-2311, XM-4316 and w a t e r t o t h e b a l l
m i l l , r u n f o r an a d d i t i o n a l 30 m i n u t e s . The p i g m e n t c o n c e n t r a t e
i s s t a b l e . A f t e r l o n g e r a g i n g a d d i t i o n o f s m a l l amounts o f amine
f o r pH a d j u s t m e n t m i g h t b e r e q u i r e d .
L e t d o w n F o r m u l a : L e t t h e p i g m e n t p a s t e down u n d e r a g i t a t i o n
w i t h r e m a i n d e r o f K - F l e x XM-4316, w a t e r , m e l a m i n e c r o s s l i n k e r
and c a t a l y s t . Add t h e s i l i c o n e s u r f a c t a n t a n d u s e t h e r e m a i n d e r
o f t h e w a t e r f o r v i s c o s i t y a d j u s t m e n t s . F i n a l pH o f t h e f o r m u l a -
t i o n s h o u l d be between 7 . 8 t o 8 . 3 .
SOURCE: K i n g I n d u s t r i e s : P r e l i m i n a r y F o r m u l a t i o n WR-40
Coatings and Topcoats 7
C l e a r Bake C o a t i n g
M a t e r i a1 : ~
Pounds _Gal 1ons
_ _
E p i -Re2 3522-W-60 Resin 637.50 69.29
T y p i c a l C o a t i ng P r o p e r t ies :
% N o n - v o l a t i l e - w e i g h t : 48.5
- volume: 43.2
V i s c o s i t y : 57 K . U .
pH: 7 . 0
Pounds/Gallon: 9 . 0 5
V o l a t i l e Composition:
_ _ _ _G _
Pounds a l l o_
ns
Water 388.0 46.50
Organics 62.7 8.00
V o l a t i l e O r g a n i c Compounds (VOC):
Pounds/Gallon: 1.46
Grams/Li t e r : 175
F i l m Properties:*
Bake Schedule: P e n c i l Hardness Reverse Impact, in.-lbs.
5 min. a t 450F 4H 160
30 min. a t 400F 5H 160
15 min. a t 400F 5H 160
30 min. a t 350F 4H 160
C l e a r Bake C o a t i n q
M a t e r i a1 : Pounds Gal l o n s
Epi -Rez 3551 -WY-43 Resi n 756.0 84.00
Add under a g i t a t i o n :
E k t a p r o EEP 21.2 2.68
B e e t l e 80 86.8 9.54
Water 31.5 3.78
Typical Coating Properties:
T o t a l Weight S o l i d s , %: 47.5
T o t a l Volume S o l i d s , %: 41.8
Pounds/Gallon: 8 . 9 6
Epoxy/Urea, based on s o l i d s %: 80/20
V o l a t i l e O r g a n i c Compounds VOC) :
Pounds/Gal l o n : 1 . 8 5
Grams/Li t e r : 222
V i s c o s i t y , B r o o k f i e l d #5 Sp n d l e , 20 rpm, c p s : 1,400
Typical Film Properties:
Dry F i l m T h i c k n e s s : 1 . 0 m i l
S u b s t r a t e : B o n d e r i t e 1000
Bake Schedule a t 350F, m i n u t e s : 20
P e n c i l Hardness: 3H
Reverse Impact, i n . l b s . : 80
S t a r t i n g F o r m u l a t i o n No. 2501: Epi-Rez 3551-WY-43 R e s i n
P h e n o l i c C l e a r Bake C o a t i n g
M a t e r i a1 : ~~
Pounds Gallons
Epi-Rez 3540-WY-55 Resin 442.9 48.48
Water 115.5 13.87
Premix and add s l o w l y under a g i t a t i o n :
M e t h y l o n 75108 162.5 16.75
B u t y l O x i t o l Glycol Ether 48.8 6.50
n-Butyl Alcohol 43.9 6.50
Syntex 3981 A c c e l e r a t o r 58.1 7.90
Typical Coating Properties:
T o t a l Weight S o l i d s , %: 4 6 . 6
T o t a l Volume S o l i d s , %: 3 1 . 0
Pounds/Gallon: 8 . 7 2
E p o x y / P h e n o l i c : 60:40
C a t a l y s t , a c t i v e on r e s i n s o l i d s , %: 3 . 3
V o l a t i l e O r g a n i c Compounds (VOC):
Pounds/Gallon: 2 . 6 8
Grams/Li t e r : 322
V i s c o s i t y , #4 F o r d Cup, seconds: 40-60
pH: 6 . 4
R e d u c t i o n f o r C o n v e n t i o n a l Spray A p p l i c a t i o n : None
Typical Film Properties:
Dry F i l m Thickness: 0 . 4 m i l s
S u b s t r a t e : B o n d e r i t e 1000
Bake Schedule: 15 min. a t 450F
P e n c i l Hardness: 9H
Reverse I m p a c t , i n . l b s . : > I 6 0
MEK R e s i s t a n c e , d o u b l e r u b s : 100
S t a r t i n g F o r m u l a t i o n No. 2502: Epi-Rez 3540-WY-55 R e s i n
C l e a r Bake C o a t i n g
M a t e r i a1 : Pounds Gal l o n s
Epi -Rez 3540-WY-55 R e s i n 579.6 63.42
Water 113.7 13.65
Premix and add:
B e e t l e Urea Formaldehyde R e s i n 80.7 8.92
n-Butyl Alcohol 43.2 6.40
Syntex 3981 A c c e l e r a t o r 55.9 7.61
P h e n o l i c C l e a r Bake C o a t i n g
M a t e r i a1 : _ _ _ _Gal
Pounds _1ons
_
P a r t A:
Epi -Rez 3551 -WY-43 R e s i n 662.1 73.56
Premix and add under a g i t a t i o n :
S a n t o l ink EP560 93.1 10.18
E k t a p r o EEP 80.6 10.16
Add under a g i t a t i o n :
Water 50.8 6.10
T y p i c a l C o a t i ng P r o p e r t i es :
T o t a l Weight S o l i d s , %: 42.0
T o t a l Volume S o l i d s , %: 3 6 . 6
Pounds/Gallon: 8.87
Epoxy/Phenolic, based on s o l i d s , p e r c e n t : 80/20
V o l a t i l e O r g a n i c Compounds (VOC):
Pounds/Gal 1on: 2.90
G r a m s / L i t e r : 348
V i s c o s i t y , #4 F o r d Cup, seconds: 70-80
T y p i c a l F i 1m P r o p e r t ies :
Dry F i l m T h i c k n e s s : 0 . 5 m i l
S u b s t r a t e : B o n d e r i t e 1000
Bake Schedule a t 350F. m i n u t e s : 20
P e n c i l Hardness: 5H
Reverse Impact, i n . l b s . : s160
MEK R e s i s t a n c e , Double Rubs: 100
S t a r t i n g F o r m u l a t i o n No. 2505: €pi-Rez 3551-WY-43 R e s i n
SOURCE: S h e l l Chemical C o . : S t a r t i n g F o r m u l a t i o n s
10 Water-Based Paint Formulations
C l e a r Wood C o a t i n Q - A & B 8 C
_-
K-F1 e x UD-320W Modi f ie d
The f o l l o w i n g wood c o a t i n g f o r m u l a t i o n e v a l u a t e s K - F l e x
UD-320W a t 5 and 10% m o d i f i c a t i o n on s o l i d s . The s y s t e m was
c a t a l y z e d w i t h K-Cure 129W. Cure r e s p o n s e was examined on
c l e a n b a r e and 840 t r e a t e d Aluminum a t a r a p i d s c h e d u l e o f 60
sec./82C. Hardness improvements were f o u n d a t a l l l e v e l s o f
m o d i f i c a t i o n (See f i l m p r o p e r t i e s ) . The t r e a t e d s u b s t r a t e gave
s o f t e r f i l m s i n i t i a l l y compared t o b a r e m e t a l , b u t i m p r o v e d
p r o p e r t i e s were o b s e r v e d a f t e r 2 4 h o u r s a g i n g . K - F l e x UD-320W
m o d i f i c a t i o n increased f i l m hardness b u t d i d n o t improve water
resistance properties
Formul a t i on : *W -W Wt%C
Rhoplex AC-1024 66.7 61 .8 51.4
B e e t l e 65 33.3 34.3 40.4
K - F l e x UD-320W 0.0 3.9 8.2
FC-430 0.13 0.13 0.13
K - C u r e 129W 1.7 1.7 1.8
F i l m Properties:
S u b s t r a t e : Aluminum ( C l e a n B a r e )
C u r e : 60 sec./82C
F i l m T h i c k n e s s : 0 . 7 + - 0 . 1 m i l DFT
Crosshatch
Adhesion
Penci 1 KHN25 MEK Rubs (%Loss)
A: 50,’-/50
Initial HB-F 4.19 200 0
24 H o u r s F-H 11.20 200 0
0 : 45/5/50
Initial HB-F 6.25 200 0
24 H o u r s H-2H 14.20 200 0
C: 35/10/55
Initial HB-F 5.41 180 0
24 H o u r s H-2H 15.50 200 0
Set a s i d e f o r l a t e r a d d i t i o n , i n t o a s e p a r a t e v e s s e l add:
Water Phase:
Water 150 18.00720
Bentone AD 1.4 0.064641
Tamol 165 11.2 1.222707
Drewpl us L-493 1 0.133155
B u t y l Cel l o s o l v e 36.6 4 .a73501
Dibutyl Phthalate 7.3 0.8371 55
n
Ammonia (28) 0.4
Premix:
Anal y s i s:
P e r c e n t Sol i d s , Weight : 31 .8
P e r c e n t S o l i d s , Volume: 28.4
V i s c o s i t y @ 25C, #2 Zahn, Secs.: 20-25
G l o s s ( 6 0 / 2 0 ) : 7/4
pH: 8.0-8.5
VOC ( e x c l u d i n g w a t e r ) :
Grams/Li t e r : 288
Pounds/Gal 1on : 2 . 4
F o r m u l a t i o n 2124-54C
C l e a r Topcoat for F l e x i b l e S u b s t r a t e s
M a t e r i a1 : Lbs. Gals.
Spensol L53 826.5 95.00
S u r f y n o l 104H 4.0 0.50
C o l l o i d 679 1.9 0.25
Ucar SCT 100 2.3 0.25
M i cheml ube 737 16.4 2.00
Water 16.7 2.00
Analysis:
P e r c e n t Sol i d s , Wei g h t : 29.8
P e r c e n t S o l i d s , Volume: 2 8 . 6
V i s c o s i t y @ 25C, # 4 Ford, Secs.: 65+-5
Pounds/Gallon: 8 . 7
PH: 8 . 5 t - 0 . 3
VOC ( e x c l u d i n g w a t e r ) :
G r a m s / L i t e r : 374
Pounds/Gallon: 3 . 1
F o r m u l a t i o n 2307-248
S t r i p p a b l e C o a t i n g Sample F o r m u l a t i o n A
_____
Unmodi f ied
Coating Properties:
V i s c o s i t y , cP: 1060
S t o r m e r V i s c o s i t y , KU: 70
pH V a l u e : 6 . 6
T o t a l S o l i d s , % by weight: 59.3
S t r i p p a b l e C o a t i n q Sample F o r m u l a t i o n B
Lower
- - Adhesion
Inqredients: _ _
Pounds ~a l l o n s
G
Ucar L a t e x 447 777.0 86.33
AMP-95 2.1 0.27
Ucar F i l m e r IBT 46.7 5.91
Foamaster VF 2.1 0.27
Soya L e c i t h i n 20.0 2.29
Water 41.1 4.93
Coating Properties:
V i s c o s i t y , cP: 1820
Stormer V i s c o s i t y , K U : 83
pH V a l u e : 6 . 7
T o t a l S o l i d s , % by w e i g h t : 60.3
S u b s t r a t e S t r i p p a b i 1i t y :
Substrate: Formula A Formula B
Galvanized Steel X X
A1 -Bonderi t e X X
A1 -A1 o d i ne X X
Cold R o l l e d Steel X X
My1 a r X X
G1 ass X X
Polystyrene X X
G l o s s A1 k y d X X
Polyester X X
X=peeled c l e a n and e a s i l y
Coating P r o p e r t i e s :
V i s c o s i t y , cP: 2500
Stormer V i s c o s i t y , KU: 104
pH V a l u e : 8 . 1
T o t a l S o l i d s , % by w e i g h t : 6 0 . 1
Formula D
High B u i l d
Ingredients: ~~Pounds Gal 1ons
Ucar L a t e x 447 702.7 06.97
AMP-95 4.8 0.62
Ucar F i l m e r IBT 46.9 5.94
Foamaster VF 2.1 0.27
Water 40.6 4.07
Ucar Polyphobe 102 11.6 1.33
Coating P r o p e r t i e s :
V i s c o s i t y , cP: 3200
Stormer V i s c o s i t y , KU: 84
pH V a l u e : 8 . 9
T o t a l S o l i d s , % by w e i g h t : 58.8
S u b s t r a t e S t r i p p a b i 1 it y :
Substrate: Formula C Formula D
Galvanized S t e e l X X
A1 -Bonderi t e X X
A1 - A l o d i ne NT NT
Cold R o l l e d Steel X X
Mylar X X
G1 ass X X
Polystyrene NT NT
Gloss A l k y d X X
Polyester NT NT
X=peeled c l e a n and e a s i l y NT=not t e s t e d
Premix #2:
T r i o c t y l Phosphate 40.2 5.22 4.74
S t r i p p i n g A i d (3) 13.9 1.47 1.64
Water 39.2 4.71 4.62
P r e m i x #3:
T h i c k e n e r (4) 27.1 3.10 3.19
Water 27.2 3.26 3.20
P r e m i x #4:
Triethylamine 7.2 1.18 0.85
I s o p r o p a n o l , 91% 8.6 1.27 1.01
Water 14.3 1.72 1 .68
Water 48.3 5.80 5.69
iers:
) Defoamer - P a t c o t e 513 ( P a t t e r s o n C h e m i c a l ) o r e q u i v a l e n t .
) Soya L e c i t h i n - K e l e c i n 1081 (Spencer K e l l o g g ) o r e q u i v -
a1 e n t .
(3) S t r i p p i n g A i d - S t r o d e x PK-90 ( D e x t e r C h e m i c a l s ) o r
equivalent.
(4) T h i c k e n e r - A c r y s o l ASE-60 (Rohm and Haas) o r e q u i v a l e n t .
Procedure:
B l e n d Premix #1 f i r s t , i n t h e o r d e r shown, and t h e n add t h e
r e m a i n i n g Premixes i n n u m e r i c a l o r d e r . A l l o w f i v e t o 10 m i n u t e s
o f a g i t a t i o n between a d d i t i o n s o f P r e m i x e s . The l a s t i n c r e m e n t
o f w a t e r , shown b e l o w Premix #4, can b e added i n s t a g e s t o a l l o w
proper a g i t a t i o n .
Coating Properties:
T o t a l S o l i d s , % b y w t : 40.1
p H : 8.6
V i s c o s i t y , B r o o k f i e l d , cP: 2410
V i s c o s i t y , S t o r m e r , KU: 84
Heat-Age S t a b i l i t y , 2 wk a t 12OF: Pass
Freeze-Thaw S t a b i l i t y , 3 c y c l e s : Pass
S t r i p p a b l e C o a t i nq F o r m u l a t i o n s
S u p p l ie r s :
( 1 ) Thickener - A c r y s o l G-110 (Rohm and Haas) o r e q u i v a l e n t .
( 2 ) W e t t i n g A g e n t - I n t e r w e t #33 ( I n t e r s t a b ) o r e q u i v a l e n t .
N o t e : I n c l u d e a s u i t a b l e p r e s e r v a t i v e i n each f o r m u l a s u g g e s t i o n .
Letdown :
Ucar V e h i c l e 462 535.4 60.8
Cyme1 325 45.2 4.4
A r c o s o l ve PP Sol v e n t 36.1 4.9
Cycat 4040 2.8 0.3
Foamaster VF 1.1 0.1
CAO-1 A n t i - O x i d a n t 3.0 0.3
T i n u v i n 328 UV Absorber 6.5 0.7
Paint Properties:
Pigment Volume C o n c e n t r a t i o n , %: 28
C r o s s l i n k e r , phr: 15
C o s o l v e n t , p h r : 15
Volume S o l i d s , %: 41
Weight p e r G a l l o n , l b : 10.6
K - F l e x XM-2304 i s an e x p e r i m e n t a l p r i m a r y h y d r o x y l c o n t a i n i n g
a l i p h a t i c , saturated urethane r e s i n m o d i f i e r . T h i s water-borne
a l k y d / m e l a m i n e wood c l e a r c o a t f o r m u l a t i o n d e m o n s t r a t e s i m p r o v e d
s t a i n r e s i s t a n c e and f l o w / l e v e l i n g u s i n g t h i s p r o d u c t .
%K-Flex XM-2304
Component: 0% 5% 10%
C a r g i l l 7412 31 . 5 28.3 25.1
Resimene 747 31 . 5 31.5 31.5
Isopropanol 14.8 14.8 14.8
Water 15.7 15.6 15.6
K - F l e x XM-2304 0.0 3.5 6.5
Nacure 155 6.5 6.5 6.5
4 Hour S p o t T e s t
SOURCE: K i n g I n d u s t r i e s : F o r m u l a t i o n WR-24
Coatings and Topcoats 19
Water-Borne Alkyd/Melamine
Wood C l e a r c o a t M o d i f i c a t i o n
K - F l e x UD-320W i s an a l i p h a t i c , s a t u r a t e d , w a t e r s o l u b l e
r e s i n m o d i f i e r . This urethane d i o l modifying r e s i n imparts
s t a i n r e s i s t a n c e t o t h e f o r c e d d r y (thermoset) alkyd/melamine
wood c l e a r c o a t f o r m u l a t i o n b e l o w .
K - F l e x UD-320W: 0% 5% 10%
% Sol i d s ( C a l c u l a t e d ) 66.6 66.5 66.4
A1 kyd/K-F1 ex UD-32OW/HMMM 50/0/50 45/5/50 40/10/50
4 Hour Spot T e s t
Stain Test 0% UD-320W 5% UD-320W 10% UD-320W
Mustard Mild Attack M i l d Attack No E f f e c t
Ketchup Stain No E f f e c t No E f f e c t
Coffee Severe S t a i n Severe S t a i n Mild Stain
Homog. M i l k Severe A t t a c k No E f f e c t No E f f e c t
Lemon J u i c e Mild Attack Severe A t t a c k Severe A t t a c k
Pepsi Cola Mild Attack M i l d Attack No E f f e c t
N a i l P o l i s h Remover Severe A t t a c k No E f f e c t No E f f e c t
W h i l e a l l 3 f o r m u l a s were u n a f f e c t e d i n t h e 4 h o u r s p o t t e s t
b y b l e a c h and m i n e r a l o i l , t h e y a l l e x h i b i t e d s t a i n i n g f r o m w a t e r
and a s e v e r e a t t a c k f r o m i s o p r o p a n o l and l i q u i d c l e a n e r
SOURCE: K i n g I n d u s t r i e s : F o r m u l a t i o n WR-25
20 Water-Based Paint Formulations
A d j u s t pH t o 8 . 5 - 9 . 0
Add f o l l o w i n g w h i l e m i x i n g :
A d j u s t v i scosi t y
Properties:
% N o n v o l a t i l e ( b y w e i g h t ) : 31.2
% N o n v o l a t i l e ( b y volume): 29.4
Weight p e r G a l l o n (pounds): 8 . 4 8
T h e o r e t i c a l VOC ( g r a m s / l i t e r ) : 106
V i s c o s i t y ( c P s ) : 150+-10%
Letdown :
M e t h y l C a r b i t o l S o l v e n t )Premix 8.5 1 .oo
A c r y s o l SCT-275 1 8.6 1 .oo
Ucar V e h i c l e 435 626.9 72.06
Ucar F i l m e r IBT 15.8 2.00
Troysan Polyphase AF-1 4.9 0.50
DeeFo HG-12 1.9 0.25
Sodium N i t r i t e , 15% Aqueous S o l u t i o n 9.0 1.08
Ammonium Hydroxide, 28% Aqueous S o l u t i o n 1.8 0.25
A d j u s t t o minimum pH 8.7
Pai n t P r o p e r t i es :
Pigment Volume C o n c e n t r a t i o n (PVC), %: 18.3
T o t a l S o l i d s , %:
by volume: 36.1
pH Value, i n i t i a l : 8 . 7
Viscosity:
Stormer, KU: 78
I C I , p o i s e : 1.1
Weight p e r G a l l o n , l b : 10.3
Freeze-Thaw S t a b i l i t y , 3 c y c l e s : Pass
Heat S t a b i l i t y , 2 weeks a t 140F: Pass
Film Properties:
Contrast Ratio, 6-mil wet drawdown: 0.958
Gloss, 60: 70
Gloss, 20: 25
M i x a t l o w speed:
Analysis:
Pigment Volume C o n c e n t r a t i o n , Percent: 20.0
P i g m e n t / B i n d e r R a t i o : 0.94/1
P e r c e n t S o l i d s , Weight: 5 7 . 4
P e r c e n t S o l i d s , Volume: 44.0
V i s c o s i t y @ 25C, KU: 72-76
Pounds/Gallon: 11.08
pH: 8 . 8 - 9 . 0
VOC ( e x c l u d i n g w a t e r ) :
Grams/Li t e r : 144
Pounds/Gallon: 1.2
Chromate Coi 1- C o a t i na P r i m e r
Ingredients: ~
Pounds _G a l l o_
ns _
Wei sht%
Pigment G r i n d :
Dei o n i zed Water 46.0 5.54 4.33
E t h y l e n e G1y c o l 3.8 0.41 0.35
N,N-Dimethylethanolamine 0.6 0.09 0.06
Foamaster VF 0.3 0.03 0.03
T e r g i t o l N o n i o n i c S u r f a c t a n t NP-10 3.8 0.45 0.35
Polywet ND-2 15.3 1.63 1.44
L-203-D S t r o n t i u m Chromate 25.6 0.83 2.41
233 B a s i c Z i n c Chromate 25.6 0.81 2.41
T i -Pure R-900 204.5 5.96 19.25
Letdown :
N, N - D i m e t h y l e t h a n o l ami ne 5.9 0.79 0.56
Ucar V e h i c l e 462 629.5 71.85 59.26
Carbi t o 1 Solvent 16.1 1.88 1.52
A r c o s o l v e PP S o l v e n t 16.1 2.15 1.52
Cyme1 303 35.5 3.55 3.42
Foamaster VF 1.8 0.22 0.17
D e i o n i z e d Water 31.7 3.81 2.92
Procedure:
Charge t h e f i r s t s i x g r i n d components t o a Cowles m i x e r i n
o r d e r l i s t e d . Thoroughly m i x l i q u i d components b e f o r e a d d i n g
pigments. Add pigments s l o w l y and s t i r u n t i l u n i f o r m . G r i n d a t
h i g h speed f o r 10 m i n u t e s o r u n t i l g r i n d reaches about 50C.
For t h e letdown, add t h e i n g r e d i e n t s i n t h e o r d e r shown,
making s u r e t h e mix i s u n i f o r m a f t e r each a d d i t i o n . For a l e s s
c r i t i c a l procedure, p r e m i x f i l m i n g a i d s w i t h c r o s s l i n k e r and
w a t e r . M i x p a i n t a t l e a s t 10 m i n u t e s a f t e r t h e f i n a l a d d i t i o n .
P a i n t P r o p e r t i 8s:
Pigment:Binder Ratio: 0 . 8 : l . O
T o t a l N o n v o l a t i l e s , % by w e i g h t : 54.3
R e s i n :Me1ami ne: 89; 1 1
O r g a n i c i n E f f l u e n t , % by volume: 10 9
V i s c o s i t y , B r o o k f i e l d , cP: 300
pH Value: 9
Low-Sheen C o i l - C o a t i n q Topcoat
I n q r e d ie n t s : _
Pounds _ G a l l o _
ns ~
Weight%
Pigment G r i nd:
Ethylene Glycol 2.42 0.26 0.23
P o l y w e t ND-2 9.69 1.03 0.93
T e r g i t o l N o n i o n i c S u r f a c t a n t NP-10 2.39 0.27 0.23
Foamaster VF 1.17 0.15 0.11
N, N - D i m e t h y l e t h a n o l ami ne 0.30 0.04 0.03
D e i o n i zed Water 95.87 11.53 9.25
S i l c r o n G-601 48.46 2.77 4.68
T i -Pure R-960 o r Zopaque RCL-6 193.80 5.82 18.70
Letdown :
Foamaster VF 2.11 0.27 0.20
D e i o n i z e d Water 22.10 2.65 2.13
N,N-Dimethylethanolamine 3.26 0.44 0.32
Ucar V e h i c l e 462 585.18 66.80 56.47
Pigment G r i nd 354.10 21.87 34.16
A r c o s o l v e PP S o l v e n t 30.20 4.02 2.91
Cyme1 303 39.50 3.95 3.81
Procedure:
Charge t h e f i r s t s i x g r i n d components t o a Cowles m i x e r t a n k
i n t h e o r d e r l i s t e d . M i x a t l o w speed f o r 5 m i n u t e s . S l o w l y add
t h e p i g m e n t s and s t i r u n t i l u n i f o r m . G r i n d a t h i g h speed f o r
10 m i n u t e s o r u n t i l g r i n d reaches 5 0 C .
For t h e l e t d o w n , combine t h e a n t i f o a m , w a t e r , and t h e amine;
b l e n d i n t o Ucar V e h i c l e 462 w i t h s l o w a g i t a t i o n . Reduce t h e
pigment g r i n d w i t h t h e n e u t r a l i z e d l a t e x and s t i r a t l o w speed
f o r 10 m i n u t e s . Add t h e melamine r e s i n and s o l v e n t . S t i r a t
moderate speed f o r 10 m i n u t e s .
Paint Properties:
P i g m e n t : B i n d e r R a t i o : 0 . 8 : l .O
Pigment Volume C o n c e n t r a t i o n , %: 1 9 . 7
T o t a l N o n v o l a t i l e s , % by w e i g h t : 53.6
O r g a n i c i n E f f l u e n t , % by volume: 1 0 . 5
Resi n:Mel ami ne: 87: 13
Medium-Gloss C o i l - C o a t i n g Topcoat
Letdown :
Foamaster VF 4.29 0.55 0.41
D e i o n i z e d Water 4.61 0.55 0.44
N,N-Dimethylethanol ami ne 2.97 0.40 0.28
Ucar V e h i c l e 462 630.31 71.96 59.64
Pigment G r i nd 322.06 15.69 30.45
A r c o s o l v e PP S o l v e n t 31.57 4.20 2.99
Cyme1 303 35.22 3.52 3.33
D e i o n i z e d Water 26.02 3.13 2.46
Procedure:
Charge t h e f i r s t s i x g r i n d components t o a Cowles m i x e r t a n k
i n t h e o r d e r l i s t e d . M i x a t low speed f o r 5 m i n u t e s . S l o w l y add
t h e t i t a n i u m d i o x i d e and s t i r u n t i l u n i f o r m . G r i n d a t h i g h speed
f o r 10 m i n u t e s o r u n t i l g r i n d reaches 50C.
For t h e letdown, combine t h e f i r s t i n c r e m e n t o f w a t e r , t h e
a n t i f o a m , and t h e amine; b l e n d i n t o t h e Ucar V e h i c l e 462 w i t h
slow a g i t a t i o n . Reduce t h e pigment g r i n d w i t h t h e n e u t r a l i z e d
l a t e x and s t i r a t low speed f o r 10 m i n u t e s . Add t h e r e m a i n i n g
w a t e r , melamine r e s i n , and s o l v e n t . S t i r a t moderate speed f o r
10 m i n u t e s .
Paint Properties:
Pigment:Binder R a t i o : 0 . 8 : l .O
Pigment Volume C o n c e n t r a t i o n (PVC): 18.9
T o t a l N o n v o l a t i l e s , % by w e i g h t : 53.1
O r g a n i c i n E f f l u e n t , % by volume: 10.5
Resin:Melami ne: 89: 11
pH Value: 9
L e t Down:
Ucar V e h i c l e 441 630.2 72.86 60.38
Dispersant (1 ) 3.1 0.31 0.30
Soya L e c i t h i n 4.9 0.53 0.47
Defoamer ( 3 ) 1.6 0.20 0.15
Melamine ( 6 ) 5.6 0.56 0.54
Butyl Cellosolve Solvent 14.4 1.92 1.38
Thickener (7) 6.3 0.73 0.60
B l u e T i n t Paste ( 8 ) 2.6 0.29 0.25
S u o ~ile r s :
D i s p e r s a n t - S t r o d e x PK-90 ( D e x t e r Chemical) o r e q u i v a l e n t
D i s p e r s a n t - Ross and Rowe 551 (Ross and Rowe Chemicals)
or equivalent.
Defoamer - Foamaster VF (Diamond Shamrock) o r e q u i v a l e n t .
C a l c i u m Carbonate - A t o m i t e (Thompson, Weinman) o r e q u i v -
alent.
T i t a n i u m D i o x i d e - T i - P u r e R-900 ( d u P o n t ) o r e q u i v a l e n t .
Me1ami ne - Cyme1 350 (American Cyanamid) o r e q u i v a l e n t .
T h i c k e n e r - A c r y s o l G-110, 22% (Rohm and Haas) o r e q u i v -
a1 e n t .
Aqueous D i s p e r s i o n - T h a l o B l u e (Tenneco) o r e q u i v a l e n t .
Procedure:
Charge t h e f i r s t f i v e components t o a Cowles m i x e r t a n k i n t h e
o r d e r l i s t e d . M i x a t l o w speed f o r one m i n u t e . S l o w l y add p i g -
ments and s t i r u n t i l u n i f o r m . G r i n d a t h i g h speed u n t i l d e s i r e d
g r i n d f ineness has been accompl ished.
For t h e letdown, p r e - b l e n d Ucar V e h i c l e 441, S t r o d e x PK-90,
soya l e c i t h i n , and defoamer. W i t h s l o w a g i t a t i o n , add t o t h e
pigment g r i n d . S t i r a t l o w speed f o r 5 t o 10 m i n u t e s . P r e - b l e n d
B u t y l C e l l o s o l v e S o l v e n t and melamine and add t o l e t down. S t i r
f o r f i v e m i n u t e s . Add b l u e t i n t p a s t e and t h i c k e n e r and s t i r
f o r 5 t o 10 m i n u t e s . If done s l o w l y and c a r e f u l l l y , l e t down
components may be added s e q u e n t i a l l y .
Coating Properties:
N o n v o l a t i l e s , %: 54 t o 55
pH: 8 . 0
Pigment/Binder R a t i o : 1 . O
V i s c o s i t y a t 25C ( B r o o k f i e l d LVT, 60 r p m ) , cP: 200 o 300
Grind Composition: Q
J o n c r y l 540 41.8
AMP-95 1. o
S u r f y n o l 104 1.o
T i - P u r e R-960 48.6
Water 7.6
( G r i n d t o 6 + Hegman on t h e B a l l M i l l )
Enamel C h a r a c t e r i s t i c s :
V i s c o s i t y , c p s ( 2 5 C ) : 200-205
pH: 8 . 7 0 - 8 . 7 5
Pigment/Binder R a t i o : 0 . 7 6 : l .O
A p p l i c a t i o n and Cure:
S u b s t r a t e : B o n d e r i t e 1000 ( i r o n p h o s p h a t e d CRS)
Cure S c h e d u l e : 1 5 ' / 3 0 0 F (150C)
DFT ( m i l s ) : 0 . 9 + - 0 . 0 1 ( 2 2 . 5 ~ )
Film Properties: 0 C
A c r y l ic/K-Flex/HMMM: 65/5/30 57/16/33
Penci 1 Hardness 4H-5H 4H-5H
Knoop Hardness ( 2 5 9 ) 17.0 18.4
MEK R e s i s t a n c e (2X) 100 100
C r o s s h a t c h Adhesion 100% 100%
Impact Resistance:
Direct ( i n lbs): 100-110 100-110
Reverse ( i n l b s ) : 20- 30 20 -30
C1 eve1 and H u m i d i t y (55C) 9/M 9/MD
S y n e r g i s t i c E f f e c t s o f Combinina N a c o r r w i t h
A n t i - C o r r o s i v e Pinment i n an A i r D r y Water R e d u c i b l e
A1 kyd M o d i f i e d A c r y l i c Enamel
Improvements i n t h e c o r r o s i o n r e s i s t a n c e o f a w a t e r r e d u c i b l e
a i r d r y a c r y l i c enamel a r e p o s s i b l e u s i n g N a c o r r r u s t and c o r r -
o s i o n i n h i b i t o r s , When used i n c o m b i n a t i o n w i t h a c a l c i u m s t r o n t -
ium p h o s p h o s i l i c a t e c o r r o s i o n i n h i b i t i n g p i g m e n t ( H a l o x SW-1111,
a d e f in i t e improvement in c o r r o s i o n r e s i s t a n c e was o b t a i ned.
S a l t s p r a y t e s t i n g was c a r r i e d o u t o v e r i r o n p h o s p h a t e d p a n e l s
( B o n d e r i t e 1000).
Hal ox Haloxt
Grind: Control SW-111 Nacorr
Aquamac 1090 3.79 3.79 3.76
Nacorr ____ ---- 0.78
2-Butoxyethanol 2.79 2.79 2.77
N y t a l 400 11.61 9.29 9.21
H a l o x SW-111 ____ 2.38 2.36
Raven B l a c k 16 0.71 0.71 0.70
Letdown: (Add g r a d u a l l y w h i l e on m i l l a t l o w r p m ) :
C o b a l t Hydrocure 0.06 0.06 0.06
Manganese H y d r o c u r e 0.08 0.08 0.08
Water 15.85 15.85 15.72
Ammonium H y d r o x i d e , 30% 0.28 0.27 0.27
H a l ox Haloxt
Characteristics: Control SW-111 Nacorr
P i gment/Bi n d e r R a t i o 0.4 0.4 0.4
Non-Volatile, % by weight 44.3 44.4 44.0
T o t a l Resin S o l i d s , % by weight 32.0 32.0 31.8
N a c o r r , % based on t o t a l p a i n t w e i g h t -- __ 0.8
H a l o x , % based on t o t a l p a i n t w e i g h t -- 2.4 2.4
Film Properties:
S u b s t r a t e : B o n d e r i t e 1000 I r o n Phosphated CRS
C u r e : 7 days a t room t e m p e r a t u r e (22-23C)
A p p l i c a t i o n : Spray
F i l m T h i c k n e s s : 20-25 m i c r o n s
H a l ox H a l ox+
F o r m u l a t i o n Test Procedure: Control SW-111 N a c o r r 1151
Penci 1 Hardness 2B-B 28-8 28-8
Tukon Hardness, KHN25 1.2 2.2 2.2
C r o s s h a t c h Adhesion, % removed 0 0 0
S a l t Spray, 100 h o u r s Light-med Very l i g h t No r u s t
rust rust
S a l t Spray, 310 h o u r s Very Very Medi u m
dense r u s t dense r u s t rust
The use o f N a c o r r s w i t h t h e a n t i - c o r r o s i v e p i g m e n t o f f e r e d t h e
b e s t c o r r o s i o n r e s u l t s i n t h i s s t u d y . They had l i t t l e o r no
d e l e t e r i o u s e f f e c t on o t h e r p a i n t p r o p e r t i e s .
SOURCE: K i n g I n d u s t r i e s : N a c o r r W R - 1 4
32 Water-Based Paint Formulations
-
Lb Gal
P a r t A:
G r i n d Base:
DER 660x80 (Dow) 472.55 51.47
Nuosperse 657 ( H u l s America) 3.54 0.42
B e e t l e 216-8 (American Cyanamid) 2.84 0.34
Dowanol PM (Dow) 47.26 6.20
T i P u r e R-960 (DuPont) 307.16 9.44
L e t Down:
H i g h F l a s h Naphtha ( A s h l a n d ) 73.72 10.03
M e t h y l P r o p y l Ketone (Eastman) 14.18 2.10
P a r t 8:
Ancamide 2353 ( A i r P r o d u c t s ) 131.44 14.86
n-Butanol (Ashland) 34.78 5.14
P r o p e r t ies :
P a r t A V i s c o s i t y : 86KU VOC, @ 80KU: 2.8 l b / g a l
P a r t B V i s c o s i t y : 64KU Mix R a t i o : 4:l by Volume
M i xed V i s c o s i t y : 80KU I n d u c t i o n Time: 0
PVC: 15.2% Pot L i f e , h r : 3
Vo 1 ume S o l i d s : 62.2% Dry Times:
Set t o Touch, min: 50
Dust Free, min: 75
Hard D r y : O v e r n i g h t
60 G l o s s : 104
P a r t A:
G r i n d Base:
L i q u i d DGEBA Epoxy 352.76 36.43
Nuosperse 657 ( H u l s America) 3.88 0.46
S u r f y n o l 740 ( A i r P r o d u c t s ) 1.76 0.25
Dowanol PM (Dow) 48.68 6.32
T i P u r e R-960 (DuPont) 388.04 11.92
L e t Down:
Part 8 :
Ancamide 2353 ( A i r P r o d u c t s ) 212.03 23.46
n-Butanol (Ashland) 63.14 9.34
P r o p e r t ies :
P a r t A V i s c o s i t y : 73 KU VOC, @ 70 KU: 2.2 l b / g a l
P a r t B V i s c o s i t y : 64 KU M i x R a t i o : 2:l by Volume
Mixed V i s c o s i t y : 70 KU I n d u c t i o n Time: 0
PVC: 17% Pot L i f e , h r : 2
Volume S o l i d s : 70% Dry Times:
Set t o Touch, h r : 5
Dust Free, h r : 7
Hard D r y : O v e r n i g h t
60 G l o s s : 102
C a r v Gloss W h i t e Enamel
Letdown :
Ucar L a t e x 481 620.0 71.84
Water 19.6 2.35
B u t y l C a r b i t o 1 Sol v e n t 12.8 1.60
S o l v e n t 142HT 32.8 5.00
LE-410 Emulsion 15.0 1.82
S u r f y n o l 104E 2.0 0.24
Paint Properties:
Pigment Volume C o n c e n t r a t i o n , %: 1 7 . 8
Volume S o l i d s , %: 4 0 . 6
Weight S o l i d s , %: 5 1 . 9
Stormer, KU: 85
I C I , Poise: 2.0
pH Value: 9 - 9 . 6
Freeze-Thaw S t a b i l i t y , c y c l e s passed: 0 . 1
Heat-Age S t a b i l i t y , 120F, weeks passed: 4
VOC, grams p e r l i t e r : 196
T y p i c a l T i t a n i u m D i o x i d e Pigment Performance
T i o x i d e TR 90 83 1.7 88 54
T i o x i d e TR 93 86 1.8 86 57
T i o x i d e TR 80 85 2.0 90 68
C a w Gloss W h i t e Enamel
Letdown :
Ucar L a t e x 481 620.0 71.84
Butyl C a r b i t o l Solvent 12.8 1.60
Sol v e n t 142HT 32.8 5.00
LE-410 Emulsion 15.0 1.82
Ucar Polyphobe 102 Rheo. Mod. 5.0 0.57
Ucar Polyphobe 106HE Rheo. Mod. 2.7 0.31
Water 10.0 1.20
S u r f y n o l 104E 2.0 0.24
Paint Properties:
Pigment Volume C o n c e n t r a t i o n , %: 17.8
Volume S o l i d s , %: 40.7
Weight S o l i d s , %: 5 2 . 1
S t o r m e r , KU: 86
ICI, P o i s e : 2 . 5
pH Value: 9 - 9 . 6
Freeze-Thaw S t a b i l i t y , c y c l e s passed: 0-1
Heat-Age S t a b i l i t y , 120F, weeks passed: 4
VOC, grams p e r l i t e r : 196
F i 1m P r o p e r t i e s :
G l o s s , 60: 88
Gloss, 2 0 : 47
Flow and L e v e l i n g : E x c e l l e n t
Dry-to-Touch, h o u r : 1
Recoat, h o u r s : 2-4
W a t e r / B l is t e r R e s i s t a n c e : Excel l e n t
M a t e r i a1.L _ _ _ _
Pounds _l o_
Gal ns
P a r t A:
Epi-Rez 5522-WY-55 R e s i n 490.6 54.82
Michem Lube 743 Mar and S l i p Agent 41 . O 5.00
C y c l o S o l 63 32.3 4.37
E k t a s o l v e EP, 2 - P r o p o x y e t h a n o l 33.2 4.37
Water 53.6 6.44
Part 0 :
E p i - C u r e 8290-Y-60 C u r i n g Agent 145.8 16.51
DeeFo P I - 4 C o n c e n t r a t e Defoamer 4.0 0.49
Water 66.6 8.00
Composite B l e n d : V i scosi t y
Part A 58 K.U. 650.7 75.00
Part B 68 K.U. 216.4 25.00
P a r t s A and 0 85 K.U.
Resi n Composi t i on :
Epoxy R e s i n , %: 75.0
C u r i n g Agent, %: 25.0
T o t a l , %: 100.0
G l o s s S a f e t y R e d Enamel
Letdown :
Ucar L a t e x 481 416.9 48.31
B u t y l C e l l o s o l v e Solvent 38.3 5.10
B u t y l C a r b i t o l Solvent 12.4 1.55
S o l v e n t 140 32.8 5.00
LE-410 Emulsion 15.0 1.82
Aquatrend I 1 Red I r o n Oxide D i s p . 878-1046 5.0 0.31
C o l a n y l Carmine D i s p . 13-3148 (Azo Red) 3.0 0.29
S u r f y n o l 104E 2.0 0.24
Paint Properties:
Pigment Volume C o n c e n t r a t i o n , %: 11 .O
Volume S o l i d s , %: 39.5
Weight S o l i d s , %: 43.4
Stormer, KU: 88
ICI, P o i s e : 1 . 5
pH Value: 8.5-9.5
Freeze-Thaw S t a b i l i t y , c y c l e s passed: 5
Heat-Age S t a b i l i t y , 12OF, weeks passed: 4
VOC, grams p e r l i t e r : 210
Film Properties:
Gloss, 60: 81
Gloss, 20: 40
Flow and L e v e l i n g : E x c e l l e n t
Dry-to-Touch, hour: I
Recoat, h o u r s : 2-4
Water/Bl is t e r R e s i s t a n c e : Excel l e n t
G l o s s S a f e t y Y e l l o w Enamel
Letdown :
Ucar L a t e x 481 572.9 66.39
Water 24.0 2.88
Byk 026 2.0 0.25
Butyl C a r b i t o l Solvent 12.8 1.60
Sol v e n t 142HT 32.8 5.00
LE-410 Emulsion 15.0 1.82
A q u i s Dalamar Y e l l o w D i s p . YW-811D 76.2 8.28
Aquatrend I 1 Y e l l o w I r o n O x i d e D i s p . 878-0012 12.1 0.73
Aquatrend I 1 Lamp B l a c k D i s p . 878-9908 0.1 0.01
S u r f y n o l 104E 2.0 0.24
Paint Properties:
Pigment Volume C o n c e n t r a t i o n , %: 1 1 . 4
Volume S o l i d s , %: 3 7 . 4
Weight S o l i d s , %: 43.9
Stormer, KU: 89
ICI, P o i s e : 1 . 7
pH V a l u e : 8 . 5 - 9 . 5
Freeze-Thaw S t a b i l i t y , c y c l e s passed: 5
Heat-Age S t a b i l i t y , 120F, weeks passed: 4
VOC, grams p e r l i t e r : 218
F i 1m P r o p e r t i es :
G l o s s , 60: 86
G l o s s , 20: 46
F1ow and L e v e l ing : E x c e l 1e n t
Dry-to-Touch, h o u r : 1
Recoat, h o u r s : 2-4
W a t e r / B l i s t e r Resistance: E x c e l l e n t
P a r t 0:
Epi-Cure 8537-WY-60 C u r i n g Agent 160.0 17.70
E k t a s o l v e DB A c e t a t e 8.2 1 .oo
Triethylamine 3.7 0.61
P a t c o t e 519 Defoamer 4.0 0.57
Kronos 2020 o r Tronox CR-800 250.0 7.33
H i g h Speed d i s p e r s e t o a t e x t u r e o f 10 P . C . S . , t h e n add:
R e s i n C o m p o s i t i o n (based on s o l i d s ) :
Epoxy Resin, %: 65.0
C u r i n g Agent, %: 35.0
T o t a l , %: 100.0
R e d u c t i o n f o r C o n v e n t i o n a l Spray ( b y volume):
P a r t s A and B: 17 P a r t s
Water: 1 Part
Gloss W
~ h i.t e. Enamel
~
Part B:
E p i - C u r e 8536-MY-60 C u r i n g Agent 160.0 19.28
Deefo P I - 4 C o n c e n t r a t e Defoamer 4.0 0.49
R u t i l e T i t a n i u m D i o x i d e , Kronos 2020 o r
Tronox CR-800 250.0 7.33
H i g h speed d i s p e r s e t o a t e x t u r e o f 10 P . C . S t h e n add:
R e s i n C o m p o s i t i o n ( b a s e d on s o l i d s ) :
Epoxy R e s i n , % : 62.2
C u r i n g A g e n t , %: 37.8
R e d u c t i o n f o r C o n v e n t i o n a l Spray ( b y v o l u m e ) :
None r e q u i r e d
M a t e r i a1 : ~
Pounds _Gal 1ons
_ _
P a r t A:
€ p i -Rez 5522-WY-55 R e s i n 442.2 49.41
C y c l o S o l 63 22.2 3.00
E k t a s o l v e EP, 2 - P r o p o x y e t h a n o l 22.7 3.00
Water 93.8 11 . 2 6
P a r t 8:
Epi -Cure 8290-Y-60 C u r i n g Agent 135.1 15.30
Deefo P I - 4 C o n c e n t r a t e Defoamer 4.0 0.49
T i - P u r e R-960 o r Kronos 2160 250.0 7.74
Water 12.5 1 .so
H i g h speed d i s p e r s e t o a t e x t u r e o f 10 P . S . C
Composite B l e n d : V i scosi t y
Part A 61 K . U . 580.9 66.67
Part B 103 K . U . 470.9 33.33
P a r t s A and B 83 K . U .
R e s i n C o m p o s i t i o n (based on s o l i d s ) :
Epoxy R e s i n , % : 74.5
C u r i n g Agent, %: 25.5
R e d u c t i o n f o r C o n v e n t i o n a l Spray ( b y v o l u m e ) :
P a r t s A and B : 25 p a r t s
Water: 1 part
M a t e r i a1 : Lbs. Gals.
Spensol L53 261.6 30.00
Amrnoni um Hydroxi de 1.9 0.25
D i sperse-Ayd W28 4.4 0.50
C o l l o i d 679 1.9 0.25
Ucar SCT 100 2.3 0.25
S u n b r i t e Yellow 272-0558 50.0 4.69
Sunbri t e Green 264-8142 25.0 1.43
T i t a n o x 2101 25.0 0.75
Mapico 1075 50.0 1.48
Letdown :
Spensol L53 526.7 60.40
Analysis:
Pigment Volume Concentration, Percent: 24.7
Pigrnent/Binder R a t i o : 0 . 6 / l . O
Percent S o l i d s , Weight: 41.2
Percent Sol i d s , Vol ume: 33.8
V i s c o s i t y @ 25C, #2 Zahn, Secs.: 50-60
Pounds/Gallon: 9 . 5
pH: 8.5+-0.3
VOC ( e x c l u d i n g w a t e r ) :
Grams/Liter: 289
Pounds/Gallon: 2.4
Letdown :
Ucar F i l m e r I B T 11.9 1.50
B u t y l Carbi to1 Solvent 11.9 1.50
A c r y s o l SCT-275 17.2 2.00
Ucar L a t e x 379G 418.2 46.21
Col l o i d 643 2.8 0.37
Pai n t P r o p e r t i e s
PVC, %: 3 5 . 6
Volume S o l ids %: 3 7 . 6
Weight Sol i d s %: 5 3 . 4
Weight p e r Ga l o n , l b : 1.09
S t o r m e r . KU: 04
I C I . noise: 1. 4
I .
pH, i n i t i a l : 8 . 2
Freeze-thaw S t a b i l i t y , 3 c y c l e s : Pass
Heat-Aged S t a b i l i t y , 2 weeks a t 120F: Pass
F i 1m P r o p e r t i e s :
Ref 1e c t a n c e , %: 91.9
G l o s s , 60: 8
Sheen, 85: 22
C o n t r a s t R a t i o , 3 - m i l f i l m * : 0.968
Flow and l e v e l i n g , brushed: Good
Letdown :
Ucar L a t e x 481 556.0 64.43
Dee Fo 102OF 5.0 0.68
B u t y l C e l l o s o l v e Sol v e n t 39.0 5.21
B u t y l C a r b i t o l Solvent 12.4 1.57
Sol v e n t 142HT 32.8 5.00
LE-410 Emu1s i on 15.0 1.80
Water 15.0 1.80
Ucar Polyphobe 102 Rheo. Mod. 8.3 0.95
Ucar Polyphobe 106HE Rheo. Mod. 4.5 0.52
S u r f y n o l 104E 2.0 0.24
Paint Properties:
Pigment Volume C o n c e n t r a t i o n , %: 2 . 3
Volume S o l i d s , %: 37.9
Weight S o l i d s , %: 4 0 . 6
Stormer, KU: 90
I C I , Poise: 2 . 6
pH V a l u e : 8.5-9
Freeze-Thaw S t a b i l i t y , c y c l e s passed: 5
Heat-Age S t a b i l i t y , 120F, weeks passed: 4
VOC, grams p e r l i t e r : 204
F i l m Properties:
G l o s s , 60: 91
G l o s s , 20: 65
Flow and L e v e l i n g : E x c e l l e n t
Dry-to-Touch, h o u r : 1
Recoat, h o u r s : 2
W a t e r / B l is t e r R e s i s t a n c e : Excel l e n t
P i n e h u r s t G l o s s Green Enamel
Letdown :
Ucar L a t e x 481 640.0 74.16
Water 8.3 1 .oo
B u t y l C a r b i t o l Solvent 12.4 1.55
S o l v e n t 142HT 32.8 5.00
B u t y l C e l l o s o l v e Solvent 31 . 5 4.20
Water 8.8 1.06
LE-410 Emulsion 15.0 1.82
S u r f y n o l 104E 2.0 0.24
Paint Properties:
Pigment Volume C o n c e n t r a t i o n , %: 4 . 6
Volume S o l i d s , %: 37.1
Weight S o l i d s , %: 4 2 . 0
Stormer, KU: 88
I C I , Poise: 2.3
pH Value: 8 . 5 - 9 . 5
Freeze-Thaw S t a b i l i t y , c y c l e s passed: 5
Heat-Age S t a b i l i t y , 120F, weeks passed: 4
VOC, grams p e r l i t e r : 221
Film Properties:
G l o s s , 60: 88
G l o s s , 20: 64
Flow and L e v e l ing: Excel 1e n t
Dry-to-Touch, h o u r : 1
Recoat. h o u r s : 2-4
W a t e r / B l i s t e r Resistance: E x c e l l e n t
D i s p e r s e 10-15 m i n u t e s on a h i g h - s p e e d m i l l
Add t h e f o l l o w i n g w i t h s l o w a g i t a t i o n .
L e t Down:
Rhopl ex R-AC-507 550.0 51.55
Ethylene glycol 40.0 3.75
Texanol 25.0 2.34
Water 32.0 3.01
*These i n g r e d i e n t s a r e p r e m i x e d .
E x t e r i o r Maintenance-Type C o a t i n g
D i s p e r s e 10-15 m i n u t e s on a h i g h - s p e e d m i 11.
Add t h e f o l l o w i n g w i t h s l o w a g i t a t i o n .
L e t Down:
Rhopl ex MV-23 527.0 46.64
Texanol 5.0 0.44
Ethylene glycol 30.0 2.65
Water 30.0 2.66
Letdown :
Thickener; premix* 29.9 3.48
Ucar L a t e x 3796 428.4 47.28
Ucar F i l m e r IBT 20.0 2.52
Byk 035 1.9 0.25
T r i t o n A n i o n i c S u r f a c t a n t GR-7M 0.5 0.06
Pa n t P r o p e r t i e s :
PVC, %: 23.0
Volume S o l i d s , %: 31.8
Weight S o l i d s , %: 46.0
Weight p e r G a l l o n , l b : 10.60
Stormer, KU: 82
I C I , poise: 0.4
pH, i n i t i a l : 8 . 5
Freeze-thaw S t a b i l i t y , 3 c y c l e s : Pass
Heat-Aged S t a b i l i t y , 2 weeks a t 120F: Pass
F i 1m P r o p e r t i es :
R e f l e c t a n c e , %: 89.5
Gloss, 60: 59
Contrast Ratio, 3-mil f i l m : 0.967
Flow and L e v e l i n g :
brushed: Very Good
drawdown, NYPC Blade: 8
Letdown :
Water 39.9 4.79
C o l l o i d 640 1.o 0.13
NeoCar L a t e x 6040 425.0 47.39
Water 100.0 12.00
Ucar F i l m e r IBT 30.0 3.79
Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n 4.0 0.52
Ucar Polyphobe 102 Rheology M o d i f i e r 20.0 2.30
Water 50.0 6.00
Paint Properties:
PVC, %: 2 4 . 9
Volume S o l i d s , %: 3 0 . 5
Weight S o l i d s , %: 44.5
Weight p e r G a l l o n , l b : 10.47
Stormer, KU: 88-93
I C I , poise: 1.1
pH V a l u e : 8.75-9.25
Heat-Aged S t a b i l i t y , 4 weeks a t 140F: Pass
Film Properties:
Gloss, 20: 20
G l o s s , 60: 65
C o n t r a s t R a t i o , 3 - m i l f i l m : 0.980
ASTM Scrub C y c l e s , w i t h shim: 1600
B l o c k R e s i s t a n c e , 1 day: Exc
Wet Adhesion, 4 h o u r s : Exc
Flow and L e v e l i n g : Exc
S t a i n Removal : Exc
S o u t h e r n P i n e s G l o s s W h i t e Enamel
Ingredients: ___
Pounds Gallons
Pigment G r i n d :
Propylene G l y c o l 40.0 4.62
Water 20.0 2.40
Tamol 731 9.6 1.05
T r i t o n N o n i o n i c S u r f a c t a n t CF-10 2.4 0.27
B y k 023 2.5 0.35
T i - P u r e R-900 240.0 7.02
Nuosept 145 1.4 0.16
Water 11.1 1.33
Ammoni um H y d r o x i d e , 28% Aqueous S o l u t i on 2.0 0.24
Letdown :
U c a r L a t e x 481 620.0 71.84
Butyl Carbitol Solvent 12.8 1.62
S o l v e n t 142HT 20.0 3.05
T r i t o n A n i o n i c S u r f a c t a n t GR-5M 1.o 0.12
Byk 0 2 6 1.o 0.14
LE-410 Emu1 s i on 15.0 1.82
U c a r P o l y p h o b e 102 Rheo. Mod. 20.0 2.30
Water 11.9 1.43
S u r f y n o l 104E 2.0 0.24
Pai n t P r o p e r t i e s :
P i g m e n t Volume C o n c e n t r a t i o n , %: 1 7 . 6
Volume S o l i d s , %: 4 1 . 1
W e i g h t S o l i d s , %: 5 3 . 1
S t o r m e r , KU: 90
I C I , Poise: 1.9
pH V a l u e : 8 . 5 - 9 . 5
Freeze-Thaw S t a b i l i t y , c y c l e s p a s s e d : 5
H e a t - A g e S t a b i l i t y , 12OF, weeks p a s s e d : 4
VOC, grams p e r l i t e r : 1 7 4
Film Properties:
G l o s s , 6 0 : 88
G l o s s , 2 0 : 52
F1 ow a n d L e v e l in g : E x c e l 1e n t
Dry-to-Touch, hour: 2
Recoat, hours: 4
W a t e r / B l is t e r R e s i s t a n c e : E x c e l 1e n t
Waterborne B l a c k Enamel
Based o n E o o t u f 37-143/37-680
X F o r r u l a No. 3019-28A1
Add f o l l o w i n g i n o r d e r under a g i t a t i o n :
W o l l a s t o k u p 10 ES 48.40 2.00
Raven 410 20.02 1.38
H i g h speed d i s p e r s e t o 5 N.S.
Add f o l l o w i n g under a g i t a t i o n :
Component 0:
M i x f o l l o w i n g under high-speed a g i t a t i o n u n t i l uniform:
E p o t u f 37-1 43 91.85 10.32
E p o t u f 37-058 7.95 1.07
2-Butoxy Ethanol 73.09 9.84
Tap Water 98.04 11.77
Wei g h t / G a l l o n ( L b s . ) : 8.96
Percent S o l i d s (Wt.): 57.50
Percent S o l i d s ( V o l . ) : 37.30
PVC ( % ) : 46.30
VOC ( Lbs. /Gal 1on) : 2.80
Waterborne D a r k B l u e Enamel
Based on E p o t u f 37-143/37-600
(Formula No. 3019-31Dl
Add f o l l o w i n g i n o r d e r under a g i t a t i o n :
W o l l a s t o k u p 10 ES 64.97 2.68
S u n f a s t B l u e 248-3750 34.60 2.31
H i g h speed d i s p e r s e t o 5 N . S .
Add f o l l o w i n g under a g i t a t i o n :
Component 0 :
M i x f o l l o w i n g under high-speed a g i t a t i o n u n t i l u n i f o r m :
Weight/Gallon ( L b s . ) : 9.12
Percent S o l i d s (Wt.): 57.50
Percent S o l i d s ( V o l . ) : 37.30
PVC ( % ) : 46.30
VOC ( L b s / G a l l o n ) : 2.83
Component A : Lbs
~
Add f o l l o w i n g i n o r d e r under a g i t a t i o n :
W o l l a s t o k u p 10 ES 78.51 3.24
S u n b r i t e Y e l l o w 75 23.71 2.22
S u n f a s t B l u e 248-3750 9.68 0.65
T i o x i d e TR92 9.21 0.28
H i g h speed d i s p e r s e t o 5 N.S.
Add f o l l o w i n g under a g i t a t i o n :
Component B:
Mix f o l l o w i n g under high-speed a g i t a t i o n u n t i l u n i f o r m :
E p o t u f 37-143 82.10 9.22
E p o t u f 37-058 6.97 0.94
2-Butoxy E t h a n o l 59.85 7.97
Tap Water 123.78 14.86
.
Wei g h t / G a l 1on (Lbs ) : 9.20
.
P e r c e n t Sol i d s (Wt ) : 57.50
Percent S o l i d s ( V o l . ) : 37.30
PVC ( % ) : 46.30
VOC ( L b s . / G a l l o n ) : 2.80
Component A : Lbs
EpOtuf 37-680 179.20 20.23
A r c o s o l v PTB 22.73 3.11
2-Butoxy E t h a n o l 3.41 0.45
Dowanol PPH 8.36 0.95
Add f o l l o w i n g i n o r d e r under a g i t a t i o n :
W o l l a s t o k u p 10 ES 78 * 45 3.24
S u n b r i t e Ye1 l o w 74 26.52 2.49
Novoperm Red F3RK-70 8.20 0.76
H i g h speed d i s p e r s e t o 5 N . S .
Add f o l l o w i n g u n d e r a g i t a t i o n :
Component B:
M i x f o l l o w i n g under h i g h - s p e e d a g i t a t i o n u n t i l u n i f o r m :
EpOtuf 37-143 82.02 9.22
E p o t u f 37-058 7.80 1.oo
2-Butoxy E t h a n o l 60.60 8.07
Tap Water 122.11 14.66
Component A : !&
E p o t u f 37-680 97.48 11 . o o
A r c o s o l v PTB 25.04 3.43
2-Butoxy E t h a n o l 3.73 0.50
Dowanol PPH 9.29 1 .06
Add f o l l o w i n g i n o r d e r under a g i t a t i o n :
W o l l a s t o k u p 1 0 ES 60.09 2.48
Novoperm Red F3RK-70 20.69 1.92
H i g h speed d i s p e r s e t o 5 N . S .
Add f o l l o w i n g under a g i t a t i o n :
Component 8 :
Mix f o l l o w i n g under high-speed a g i t a t i o n u n t i l u n i f o r m :
E p o t u f 37-1 43 80.34 9.03
E p o t u f 37-058 7.88 1.06
2-Butoxy E t h a n o l 65.27 14.22
Tap Water 118.45 8.69
.
Wei g h t / G a l 1 on ( Lbs ) : 8.97
.
P e r c e n t Sol i d s (Wt ) : 57.50
Percent S o l i d s ( V o l . ) : 37.30
PVC ( % ) : 46.30
VOC ( L b s . / G a l l o n ) : 2.84
Add f o l l o w i n g i n o r d e r under a g i t a t i o n :
H i g h speed d i s p e r s e t o 5 N.S.
Add f o l l o w i n g under a g i t a t i o n :
Component 8:
M i x f o l l o w i n g under h i g h - s p e e d a g i t a t i o n u n t i l uniform:
E p o t u f 37-143 84.28 9.47
E p o t u f 37-058 7.36 1.00
2-Butoxy E t h a n o l 57.28 7.63
Tap Water 124.03 14.89
Weight/Gallon ( L b s . ) : 9.12
Percent S o l i d s (Wt.): 57.50
Percent S o l i d s ( V o l . ) : 37.30
PVC ( % I : 46.30
VOC ( L b s . / G a l l o n ) : 2.80
Add f o l l o w i n g i n o r d e r under a g i t a t i o n :
W o l l a s t o k u p 10 ES 83.03 3.43
S u n b r i t e Y e l l o w 74 32.49 3.05
T i o x i d e TR-92 12.63 0.38
H i g h speed d i s p e r s e t o 5 N . S .
Add f o l l o w i n g under a g i t a t i o n :
Component 8 :
M i x f o l l o w i n g under h i g h - s p e e d a g i t a t i o n u n t i l u n i f o r m :
E p o t u f 37-143 80.25 9.02
E p o t u f 37-058 6.91 0.93
2-Butoxy E t h a n o l 65.03 8.66
Tap Water 119.86 14.39
Wei g h t / G a l l on ( L b s . ) : 9.23
Percent S o l i d s (Wt.): 57.50
Percent S o l i d s ( V o l . ) : 37.30
PVC ( % ) : 46.30
VOC ( L b s . / G a l l o n ) : 2.40
W h i s o e r i n g P i n e s Semigloss W h i t e Enamel
Letdown :
Ucar L a t e x 461 556.0 64.66
Ucar F i l m e r I 6 T 12.4 1.57
Sol v e n t 142HT 31.5 4.80
LE-410 Emulsion 15.0 1 .BO
Ucar Polyphobe 102 Rheo. Mod 16.9 1.94
Water 19.7 2.37
S u r f y n o l 104E 2.0 0.24
Paint Properties:
Pigment Volume C o n c e n t r a t i o n , %: 23.3
Volume S o l i d s , %: 39.2
Weight S o l i d s , %: 51.5
Stormer, KU: 93
I C I , Poise: 2.1
pH V a l u e : 8.5-9.5
Freeze-Thaw S t a b i l i t y , c y c l e s passed: 5
Heat-Age S t a b i l i t y , 120F. weeks passed: 4
VOC, grams p e r l i t e r : 181
Film Properties:
G l o s s , 60: 5 4
Gloss, 20: 14
Flow and L e v e l i n g : E x c e l l e n t
Dry-to-Touch, h o u r : 2
Recoat, h o u r s : 4
Water/61 is t e r R e s i s t a n c e : Excel l e n t
P a r t A: &j Gals
Epi -Rez 3520-WY-55 Epoxy R e s i n (She1 1 ) 363.24 39.20
DER 331 Epoxy R e s i n (Dow) 40.36 4.17
Water 52.32 6.27
S u r f y n o l DF-11OD ( A i r P r o d u c t s ) 3.00 0.36
P a r t B:
Anquami ne 401 C u r i n g Agent ( A i r P r o d u c t s ) 90.46 9.90
Dowanol PM S o l v e n t (Dow) 40.87 5.37
Benzyl Alcohol 29.97 3.44
S u r f y n o l DF-l10D ( A i r P r o d u c t s ) 3.00 0.36
T i P u r e 960 (DuPont) 272.48 8.16
G l a c i a l Acetic Acid ( A i r Products) 5.31 0.61
Water 185.01 22.16
Typical Properties:
W t S o l i d s ( % ) : 65.84 Resin Stoichiometry: 1.3:1
Volume S o l i d s ( 3 6 ) : 4 0 . 9 5 VOC ( l b / g a l ) : 1 . 5 3
PVC ( % ) : 1 9 . 9 4 VOC ( g / l ) : 184
W h i t e G1 o s s Enamel P r o p e r t i es :
Pot L i f e , h r : > 4
G l o s s , 60 spec, 1 d a y : >90
G l o s s , 60 spec, 4 week: >90
Mix Ratio: 1 : l
M i x e d V i s c o s i t y , cP: 290
Tack F r e e Time, h r : 1
H a r d D r y Time, h r : 6-8
P e n c i l Hardness, o v e r n i g h t : HB
P e n c i l Hardness, 7 d a y s : H
Cross Hatch Adhesion: 5
1 / 8 " Mandrel Bend: Pass
D i r e c t I m p a c t R e s i s t a n c e , i n - l b s : 60
Reverse I m p a c t R e s i s t a n c e , i n - l b s : 20
VOC, l b / g a l : 1 . 6
Volume S o l i d s , % : 4 1
PVC, Yo: 1 9 . 9
Anquamixe-401/Sol i d R e s i n D i s p e r s i o n
2 : 1 W h i t e -Gloss Enamel
P a r t A: Lbs G-a 1s
Epi -Rez 3520-WY-55 Epoxy Res1 n (She1 1 ) 557.4 61.26
Water 45.1 5.41
P a r t B:
Anquamine 401 C u r i n g Agent ( A i r P r o d u c t s ) 72.5 7.93
Dowanol PM S o l v e n t (00,) 26.0 3.42
Dowanol EPh S o l v e n t (Dow) 17.0 1.85
Defoamer 4.0 0.50
T i P u r e R960 (DuPont) 227.7 6.82
G1 a c i a1 A c e t i c A c i d ( A i r P r o d u c t s ) 2.0 0.23
Water 105.0 12.58
Typical Properties:
W t Solids (%): 74.26 Resin Stoichiometry: 1.58:l
Volume S o l i d s ( % ) : 4 3 . 0 3 VOC ( l b / g a l ) : 1 . 2 6
PVC ( % I : 1 5 . 8 5 VOC ( g / l ) : 1 5 1
W h i t e G l o s s Enamel P r o p e r t i e s :
Pot L i f e , h r : >6
G l o s s , 60 spec, 1 d a y : > 9 0
G l o s s , 60 spec, 4 w k : > 9 0
Mix Ratio: 2 : l
M i x e d V i s c o s i t y , cP: 3 6 0
Tack F r e e Time, h r : 1
H a r d D r y Time, h r : 6 - 8
P e n c i l Hardness, o v e r n i g h t : HB
P e n c i l Hardness, 7 d a y s : H
Cross Hatch Adhesion: 5
1/8" Mandrel Bend: Pass
D i r e c t I m p a c t R e s i s t a n c e , in-1 b s . : 60
Reverse I m p a c t R e s i s t a n c e , i n - l b s . : 20
Taber A b r a s i o n , mg loss/lOOO c y c l e s : 9 0
VOC, l b / g a l : 1 . 8
Volume Sol i d s , ' % : 4 3
PVC, % : 1 6 . 5
C l e a r Bake C o a t i n s
M a t e r i a1 : Pounds _ Gal l o n
_ _ s ~
Epi -Rez 3551 -WY-43 Resi n 617.04 68.56
Add under a g i t a t i o n :
E k t a p r o EEP 16.14 2.04
B e e t l e 80 188.87 20.87
Water 71 .OS 8.53
T y p i c a l C o a t i n g P r o p e r t i es :
T o t a l Weight S o l i d s , %: 51.8
T o t a l Volume S o l i d s , %: 47.4
Pounds/Gallon: 8.93
Epoxy/Urea, based on s o l i d s , %: 60/40
V o l a t i l e O r g a n i c Compounds (VOC):
Pounds/Gallon: 1.47
Grams/Li t e r : 176
V i s c o s i t y , #4 F o r d Cup, seconds: 60-70
Typical F i l m Properties:
Dry F i l m Thickness: 0.7 m i l
S u b s t r a t e : B o n d e r i t e 1000
Bake Schedule a t 350F, m i n u t e s : 20
P e n c i l Hardness: 6H
Reverse Impact, i n . l b s . : 160
M€K Double Rubs: 100
S t a r t i n g F o r m u l a t i o n No. 2503: Epi-Rez 3551-WY-43 R e s i n
Phenol ic C l e a r Bake C o a t i n g
M a t e r i a1 : Pounds _ Gal l o n
_ _ s ~
Epi -Rez 3540-WY-55 R e s i n 439.6 48.07
M e t h y l I s o b u t y l Ketone 98.8 14.81
Dei o n i zed Water 98.8 11.85
S i l w e t L-7604 S u r f a c t a n t 2.4 0.28
S a n t o l i n k EP-560 193.3 21.15
Dimethylethanolamine 19.1 2.54
Syntex 3981 A c c e l e r a t o r 9.1 1.30
T y p i c a l Coating P r o p e r t i e s :
T o t a l Weight S o l i d s , %: 46.8
T o t a l Volume S o l i d s , %: 42.7
Pounds p e r G a l l o n : 8.61
Epoxy/Phenol ic, sol i d s : 60/40
P e r c e n t C a t a l y s t , A c t i v e , on Resins S o l i d s : 0 . 5
V o l a t i l e O r g a n i c Compounds (VOC):
Pounds/Gallon: 2.90
Grams/Li t e r : 348
V i s c o s i t y , B r o o k f i e l d , #5 S p i n d l e a t 50 RPM, cps: 1,200
Typical Film Properties:
Dry F i l m T h i c k n e s s : 0.5 m i l s
S u b s t r a t e : B o n d e r i t e 1000
Bake Schedule: 10 m i n u t e s a t 400F
P e n c i l Hardness: 6H
Reverse Impact, i n . l b s . : 160
MEK R e s i s t a n c e , d o u b l e r u b s : 100
S t a r t i n g F o r m u l a t i o n No. 2504: Epi-Rez 3540-WY-55 Resin
C l e a r H i q h Gloss, Bakina F i n i s h
M a t e r i a1 : Lbs. Gals.
Cymel 303 premi x--combi ne in t h e f o l l o w i n g o r d e r :
Cymel 303 57.6 5.76
Isopropanol 4.5 0.68
Nacure 2500-X 4.5 0.55
Triethylamine 0.6 0.10
Water 28.8 3.46
Add i n f o l l o w i n g o r d e r w i t h a g i t a t i o n :
Spensol L51 768.1 87.88
Cymel 303 Premix 96.0 10.55
A e r o s o l OTS 5.4 0.63
Lodyne S107B 5.4 0.56
Byk 301 3.1 0.38
Cure f o r 2 h o u r s a t 250F o r 30 m i n u t e s a t 300F.
Analysis:
R a t i o o f Spensol L51 t o Cymel 303: 80:20
P e r c e n t S o l i d s , Weight: 33.8
P e r c e n t S o l i d s , Volume: 30.1
VOC ( e x c l u d i n g w a t e r ) :
Grams/Li t e r : 189
Pounds/Gallon: 1 . 6
F o r m u l a t i o n 2061-40D
B l u e M e t a l 1ic U r e t h a n e Enamel
Analysis:
P e r c e n t Sol i d s , Weight : 31 .8
P e r c e n t S o l i d s , Volume: 28.4
V i s c o s i t y @ 25C, #2 Zahn, Secs.: 25-30
pH: 8.0-8.5
VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 408
Pounds/Gallon: 3 . 4
F o r m u l a t i o n 2099-19
E x p e r i r e n t a l Water-Reducible P o l y e s t e r Gloss W h i t e
B a k i n g Enamel U s i n a H a l o x SZP-391
Grind: Lbs./lOO G a l s . G m s / L i t e r
W/R P o l y e s t e r 72-7203 170.0 204.0
DMEA 10.0 12.0
Cyme1 303 50.0 60.0
H i g h Speed D i s p e r s e t o 7 Hegman g r i n d .
Letdown :
Mix u n t i l uniform - Do n o t a e r a t e !
Hold f o l l o w i n g f o r v i s c o s i t y adjustment.
Formula C o n s t a n t s : Formula P r o p e r t i e s :
.
% P i gment/Wt : 23.16 .
D e n s i t y 1bs. / g a l : 10.36
% Pigment/Vol : 7.25 . D e n s i t y g/L: 1,249
% S o l i d s / W t . : 48.24 V i s c . #2 Zahn ( s e c . : 50-60
% S o l i d s / V o l . : 33.12 pH @ R . T . : 8.5-9.0
% PVC: 21.85
VOC, l b s . / g a l . : 2.03
VOC, g/L: 304.5
G r i nd C o m p o s i t i o n : Wt%
T i t a n o x 2020 15.07
A c r y s o l WS-68 3.97
2-Butoxyethanol 0.67
n-Butanol 0.63
DMEA 0.90
0.1. Water 4.69
( P e b b l e M i l l G r i n d t o 7 t on Hegman)
Letdown Composi t i on :
A c r y s o l WS-68 43.63
n-Butanol 0.54
Hexamethoxymethylmelamine 4.51
2-Butoxyethanol 3.90
*DMEA (10% i n w a t e r ) 2.20
* O . I . Water 20.10
*Used t o a d j u s t pH and v i s c o s i t y
Characteristics:
P i gment/Bi nder : 40/60
A c r y l ic/Mel ami ne: 80/20
T o t a l S o l i d s , %: 3 7 . 7
T o t a l Resin S o l i d s , %: 22.6
W t . / g a l . C 25C ( l b / g a l ) : 9.65
V.O.C. (Measured) l b . / g a l . : 1.84
A p p l i c a t i o n and Cure:
S u b s t r a t e : B o n d e r i t e 1000 ( i r o n phosphated CRS)
Cure Schedule: 1 5 ' a t 149C (300F)
F i 1m T h i c k n e s s : 0 . 7 - 0 . 8 m i 1
SOURCE: K i n g I n d u s t r i e s : F o r m u l a t i o n WR-17
Enamels-Baking 67
Water R e d u c i b l e P o l v e s t e r B a k i n g Enamel
I n t h i s s t u d y N a c o r r c o r r o s i o n i n h i b i t o r s were i n c o r p o r a t e d
i n t o a p i g m e n t e d w a t e r b o r n e p o l y e s t e r system c r o s s l i n k e d w i t h a
h i g h -NH t y p e melamine r e s i n . The N a c o r r s were added a t a l e v e l
o f 3%, based o n t h e t o t a l f o r m u l a w e i g h t . S i n c e t h e N a c o r r s a l s o
f u n c t i o n a s d i s p e r s i n g a g e n t s , t h e r e i s a d e f i n i t e advantage i n
in c o r p o r a t i ng them in t o t h e d i s p e r s i n g s t a g e .
SOURCE: K i n g I n d u s t r i e s : N a c o r r WR-18
68 Water-Based Paint Formulations
Pebble o r s a n d m i l l g r i n d t h e above m a t e r i a l s t o 7+ N . S .
Letdown :
Spensol L54 536.9 61.50
Analysis:
Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 18
Pigment/Binder R a t i o : 0 . 8 / 1 .O
P e r c e n t S o l i d s , Weight: 44.7
P e r c e n t S o l i d s , Volume: 3 2 . 6
V i s c o s i t y @ 25C, #4 Ford, Secs. : 30
Gloss ( 6 0 ) : 60-70
Pounds/Gal l o n : 10.3
pH: 8 . 3 + - 0 . 3
VOC ( e x c l u d i ng w a t e r ) :
G r a m s / L i t e r : 240
Pounds/Gal 1on : 2
?-Component W a t e r b o r n e S y s t e E
F o r m u l a t i o n WR-41 d e m o n s t r a t e s t h e i m p r o v e d p e r f o r m a n c e o f a
2-component w a t e r b o r n e system when m o d i f i e d w i t h K - F l e x XM-4316,
a p o l y e s t e r - u r e t h a n e d i s p e r s i o n . A t b o t h NCO/OH r a t i o s , i m p r o v e -
ments were made i n g l o s s , M E K r e s i s t a n c e , and f l e x i b i l i t y .
NCO/OH R a t i o : 1 . 1
Acrylic/PU-Dispersion: 80/20
Component A : Wt%
E m u l s i o n E-3275 71 .38
K-F1 ex XM-4316 17.40
Sodium N i t r i t e (5% aq) 0.00
P r o g l y d e DMM 0.89
Edaplan LA 402 0.07
S i l w e t 7001 (5% a q ) 0.00
S i l w e t 7605 (25% a q ) 0.25
S i l w e t 7604 (25% a q ) 0.25
Dimethylethanolamine 0.73
Component 0:
Bayhydur XP-7063 9.03
Formulation Characteristics:
N o n v o l a t i l e , t h e o r e t i c a l , % : 46.3
T h e o r e t i c a l VOC, g / L , ( l b / g a l l o n ) : 60, (0.5)
F o r m u l a t i o n P r o p e r t e s , A i r - D r y 20-25C, 2 weeks:
G l o s s 60, %: 95
20, %: 69
K o e n i g Hardness s e c ) : 69
P e n c i l H a r d n e s s : H-2H
Knoop Hardness: 2 . 4
MEK Double Rubs: 80
I m p a c t , D i r e c t , i n c h . l b . : >160
I m p a c t , Reverse, i n c h . l b . : >160
Formulation Preparation:
Add component B t o component A under l o w shear m e c h a n i c a l
a g i t a t i o n f o r approx. 5 m i n u t e s .
SOURCE: K i n g I n d u s t r i e s : P r e l i m i n a r y F o r m u l a t i o n WR-41
Exterior Paints and Related Products 71
E x t e r i o r F l a t House P a i n t w i t h ZnO
Inqredients: Pounds
___. Gal l o n s
P i gment G r in d :
Water 236.2 28.30
U c a r P o l yphobe 9831 R h e o l o g y Modi f ie r 9.5 1.10
Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n 1.8 0.20
P r o x e l GXL 2.0 0.20
C o l l o i d 226/35 8.5 0.80
C o l l o i d 640 1.9 0.30
T r i t o n N o n i o n i c S u r f a c t a n t X-100 3.3 0.40
P r o p y l e n e G1 y c o l 25.9 3.00
P o t a s s i u m T r i p o l y p h o s p h a t e (KTPP) 1.5 0.10
T i - P u r e R-706 225.0 6.60
417-W Z i n c O x i d e 25.0 0.60
Minex 4 125.9 5.80
N y t a l 300 50.0 2.10
Letdown :
U c a r L a t e x 625 426.4 48.40
Butyl Carbitol Solvent 10.7 1.40
C o l l o i d 640 1.9 0.30
Skane M - 8 2.2 0.30
Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n 0.9 0.10
Paint Properties:
P i g m e n t Volume C o n c e n t r a t i o n , %: 4 0 . 0
Volume S o l i d s , %: 3 8 . 0
Weight S o l i d s , %: 5 5 . 6
Weight p e r G a l l o n , l b : 11.59
Stormer, KU: 95
I C I , Poise: 1.1
pH V a l u e : 8 . 9
Freeze-Thaw S t a b i l i t y , c y c l e s p a s s e d : 3
Heat-Age S t a b i l i t y , 120F, weeks p a s s e d : 2
F i 1m P r o p e r t i e s :
C o n t r a s t R a t i o , 6 - m i l w e t drawdown: 0 . 9 6 9
R e f l e c t a n c e , %: 9 1 . 9
Sheen, 8 5 : 8
Wet A d h e s i o n , g l o s s a l k y d : E x c e l l e n t
F l o w and L e v e l i n g : Good
Sag R e s i s t a n c e , m i l s : >12
E x t e r i o r F l a t House P a i n t w i t h ZnO
Letdown :
Ucar L a t e x 625 426.4 48.40
Ucar F i l m e r I B T 10.7 1.40
C o l l o i d 640 1.9 0.30
Skane ME 2.2 0.30
Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n 0.9 0.10
Pai n t P r o p e r t ies :
P i gment Vol ume C o n c e n t r a t i o n , %: 40.0
Volume S o l i d s , %: 38.0
Weight S o l i d s , %: 5 5 . 6
V i s c o s i t y , e q u i 1ib r a t e d :
S t o r m e r , KU: 98
I C I , Poise: 1.5
Freeze-Thaw S t a b i l i t y , c y c l e s passed: 3
Heat-Aged S t a b i l i t y , 120F, weeks passed: 2
F i l m Properties:
C o n t r a s t R a t i 0 , 6 - m i 1 wet drawdown : 0.968
R e f l e c t a n c e , %: 9 1 . 9
Sheen, 85: 7
Heat-Aged S t a b i l i t y , 2 weeks a t 120F: Pass
Wet Adhesion, g l o s s a l k y d : E x c e l l e n t
Exterior Gloss W h i t e
Inqredients: Pounds Gallons
Pigment G r i n d :
Water 112.0 13.40
Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n 1. o 0.10
S o l v e n t 142HT 10.0 1.50
Tamol 165 13.7 1.50
P o t a s s i u m T r i p o l y p h o s p h a t e (KTPP) 0.5 0.03
T r i t o n N o n i o n i c S u r f a c t a n t CF-10 3.0 0.40
P r o x e l GXL 2.0 0.20
Byk 023 2.5 0.30
T i -Pure R-706 225.0 6.80
Letdown :
Ucar L a t e x 481 519.0 58.60
Sol v e n t 142HT 10.0 1.50
Byk 025 2.0 0.30
Butyl C a r b i t o l Solvent 26.0 3.30
Water 85.6 10.10
Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n 1. o 0.10
Ucar P o l yphobe 9831 Rheology Modi f ie r 14.8 1.70
Paint Properties:
Pigment Volume C o n c e n t r a t i o n , %: 1 9 . 8
Volume S o l i d s , %: 3 3 . 9
Weight S o l i d s , %: 4 5 . 8
Weight p e r G a l l o n , l b : 10.28
S t o r m e r , KU: 9 5
I C I , Poise: 1.8
pH Value: 9-9.5
Freeze-Thaw S t a b i l i t y , c y c l e s passed: 0-1
Heat Age S t a b i l i t y , 120F, weeks passed: 4
V o l a t i l e O r g a n i c C o n t e n t , g / L : 120
Film Properties:
G l o s s , 60: 7 7
G l o s s , 20: 3 4
F1ow and L e v e l ing : E x c e l 1e n t
Dry-to-Touch, h o u r s : 2
Recoat, h o u r s : 4-6
W a t e r / B l is t e r Resi s t a n c e : Good
E x t e r i o r House P a i n t
M a t e r i a1 : -
Lbs
Grind:
Water 101.6 12.20
Nuosept 95 (Nuodex) 1.5 0.16
Tamol 731 (Rohm and Haas) 7.5 0.82
I g e p a l CO-630 (GAF) 3.4 0.38
T i - P u r e R-902 (DuPont) 213.3 6.23
B e a v e r w h i t e 325 T a l c (Cyprus) 111.7 1.07
325 W.G. M i c a ( U n i m i n ) 25.4 4.99
FCA (Foam C o n t r o l Agent) 4.5 0.20
Premix and add:
Ethylene Glycol 23.6 2.54
Texanol (Eastman) 5.9 0.74
N a t r o s o l P l u s 330 PA ( A q u a l o n ) 4.0 0.36
Letdown :
Water 125.0 15.01
248-5809 (McWhorter) 437.8 48.03
FCA (Foam C o n t r o l Agent) 3.0 0.39
Water 50.0 6.10
Properties:
Pigment Volume C o n t e n t , %: 31.2
% N o n v o l a t i l e ( b y w e i g h t ) : 54.6
% N o n v o l a t i l e ( b y volume): 39.3
VOC. g / l : 126
Stormer V i s c o s i t y . K . U . : 90+-5
I C 1 V i s c o s i t y , P o i s e : 1+-0.1
G l o s s a t 60, %: 0-5
Recommended P r o d u c t s :
A g i t a n 260, 315 o r 731
E x t e r i o r House P a i n t - T i n t Base
Letdown :
Ucar L a t e x 625 455.9 51.80
Ucar F i l m e r I B T 11.4 1.40
C o l l o i d 640 1.9 0.30
Troysan Polyphase AF-1 7.3 0.80
Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n 0.9 0.10
Paint Properties:
Pigment Volume C o n c e n t r a t i o n , %: 3 5 . 8
Volume S o l i d s , %: 38.0
Weight S o l i d s , %: 53.2
Viscosity, equilibrated:
Stormer, KU: 91
I C I , poise: 1.4
Freeze-Thaw S t a b i l i t y , c y c l e s passed: 3
Heat-Aged S t a b i l i t y , 120F, weeks passed: 2
Fi l m Properties:
C o n t r a s t R a t i o , 6 - m i l wet drawdown: 0.956
R e f l e c t a n c e , %: 9 0 . 1
Sheen, 85: 7
C o l o r Acceptance: E x c e l l e n t
C o l o r F l o a t : Good
Wet Adhesion, 4 - h r : E x c e l l e n t
Flow and L e v e l i n g , ASTM D-4062: 8
Film Build, sq.ft./gal.: 411
L o w Temperature Coalescence:
s e a l e d : 10
u n s e a l e d : 10
E x t e r i o r Senialoss
I n q r e d ie n t s : ~
Pounds _Gal 1ons
_ _
Pigment G r i n d :
Water 150.0 18.96
Nuosept 95 2.3 0.25
P r o p y l e n e G1 y c o l 60.5 7.00
Tamol 1124 7.4 0.75
Ammonium H y d r o x i d e (28% Aqueous S o l u t i o n ) 2.0 0.25
T r i t o n N o n i o n i c S u r f a c t a n t N-57 2.1 0.25
C o l l o i d 653 1.9 0.25
T i -Pure R-700 250.0 7.16
Letdown :
Water 91.5 10.99
Ucar Pol yphobe 102 Rheology Modi f ie r 13.1 1 .so
Ucar L a t e x 2300 447.7 50.88
Ucar F i l m e r IBT 11.2 1.41
Col l o i d 653 2.8 0.37
Troysan Polyphase AF-1 7.3 0.75
T r i t o n A n i o n i c S u r f a c t a n t GR-7M 1.1 0.13
Paint Properties:
Pigment Volume C o n c e n t r a t i o n , %: 22.0
Volume S o l i d s , %: 32.6
Weight S o l i d s , %: 47.2
Weight p e r G a l l o n , l b : 10.43
Stormer, KU: 99
I C I , P o i s e : 1 .26
pH V a l u e : 8.0
Freeze-Thaw S t a b i l i t y , c y c l e s passed: 7
Film Properties:
G l o s s , 60: 78.3
G l o s s , 20: 39.6
C o n t r a s t R a t i o , 6 - m i l wet drawdown: 0.964
R e f l e c t a n c e , %: 91.8
Scrub R e s i s t a n c e , c y c l e s passed: 161
E x t e r i o r Semisloss F o r m u l a t i o n
Letdown :
Water 1 5.5 0.66
Ucar Polyphobe 102 Rheology M o d i f i e r ) Premix 4.4 0.51
NeoCar Latex 2300 474.4 53.61
C o l l o i d 643 1.8 0.23
Ucar F i l m e r I B T 15.8 1.99
Troysan Polyphase A F - 1 7.4 0.74
T r i t o n A n i o n i c S u r f a c t a n t GR-7M 1.1 0.13
Ammonium Hydroxide, 28% Aqueous S o l u t i o n 1.8 0.23
Pai n t P r o p e r t i es :
PVC, %: 23.6
Volume S o l i d s , %: 38.7
Weight S o l i d s , %: 52.6
Weight per Gallon, l b : 10.68
Stormer, KU: 99
I C I , poise: 1.5
pH Value: 8.7
Freeze-Thaw S t a b i l i t y , 3 c y c l e s : Pass
Heat-Aged S t a b i l i t y , 4 weeks a t 140F: pass
F i 1m P r o p e r t ies :
R e f l e c t a n c e , %: 92.3
Gloss, 20: 19
Gloss, 60: 59.5
Flow and L e v e l i n g : Exc
C o l o r Acceptance: Exc
E x t e r i o r T i n t Base F o r m u l a t i o n
Letdown :
Water 3.8 0.5
Ucar L a t e x 625 319.2 36.3
Ucar L a t e x 461 145.5 16.9
Ucar F i l m e r IBT 11.4 1.4
C o l l o i d 640 1.9 0.3
Troysan Polyphase AF-1 7.3 0.8
Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n 0.9 0.1
Pai n t P r o p e r t ies :
P i gment Vol ume C o n c e n t r a t ion, %: 3 5 . 8
Volume S o l i d s , %: 3 8 . 0
Weight p e r G a l l o n , l b : 1 0 . 9
Stormer, KU: 83
I C I , P o i s e : 0.95
pH V a l u e : 9 . 6
Freeze-Thaw S t a b i l i t y , c y c l e s passed: 3
Heat-Age S t a b i l i t y , 12OF, weeks passed: 2
R a t i o o f Ucar L a t e x e s 625:461: 70:30
F i lrn P r o p e r t i e s :
Sheen. 8 5 : 9 . 2
C o n t r a s t R a t i o , 6 - m i l wet drawdown: 0.952
Dry Adhesion ( u n t r e a t e d aluminum, g a l v a n i z e d s t e e l , a1 kyd
and l a t e x c h a l k ) : Exc
Wet Adhesion ( u n t r e a t e d aluminum, g a l v a n i z e d s t e e l , a l k y d
and l a t e x c h a l k , g l o s s a l k y d ) : Exc
B1 is t e r i ng ( u n t r e a t e d a1 umi num, g a l v a n i zed s t e e l , a1 kyd
and l a t e x c h a l k ) : Exc
E x t e r i o r Trim Formulation
Modi f ie d V i n v l A c r v l ic P a i n t
Letdown :
Water 78.0 9.4
Ucar P o l yphobe 1 14 Rheology Modi f ie r 6.5 0.7
Butyl Carbitol Solvent 20.5 2.6
Ucar F i l m e r I 8 T 10.2 1.3
Ucar L a t e x 3796 316.1 34.9
Ucar L a t e x 633G 162.0 18.4
C o l l o i d 643 2.8 0.4
T r o y s a n P o l y p h a s e AF-1 7.2 0.7
Byk 346 1.1 0.1
Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n 1.8 0.3
P a i n t P r o p e r t ia s :
Pigment Volume C o n c e n t r a t i o n , %: 24.2
Volume S o l i d s , %: 35.0
Weight p e r G a l l o n , l b : 1 0 . 7
S t o r m e r , KU: 96
I C I , Poise: 1.2
p H Value: 7 . 6
Freeze-Thaw S t a b i l i t y , c y c l e s passed: 3
Heat-Age S t a b i l i t y , 120F, weeks passed: 2
R a t i o o f Ucar L a t e x e s 379G:6336: 7 0 : 3 0
F i l m Properties:
G l o s s , 60: 46
G l o s s , 20: 10
C o n t r a s t R a t i o , 6 - m i l wet drawdown: 0.967
R e f l e c t a n c e , %: 91.8
Block Resistance: 8
D r y Adhesion ( u n t r e a t e d aluminum, g a l v a n i z e d s t e e l , a1 k y d
and l a t e x c h a l k ) : Exc
Wet Adhesion ( u n t r e a t e d aluminum, g a l v a n i z e d s t e e l , a l k y d
and l a t e x c h a l k , g l o s s a l k y d ) ; Exc
B l i s t e r i n g ( u n t r e a t e d aluminum, g a l v a n i z e d s t e e l , a l k y d
and l a t e x c h a l k ) : Exc
E x t e r i o r Trim Formulation
Letdown :
Water 7.2 0.9
NeoCar L a t e x 2300 365.4 41.3
Ucar L a t e x 6336 107.8 12.3
C o l l o i d 643 1.8 0.3
Ucar F i l m e r IBT 15.8 2.0
Troysan Polyphase A F - 1 7.4 0.8
T r i t o n A n i o n i c S u r f a c t a n t GR-7M 1.1 0.1
Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n 1.8 0.3
Paint Properties:
Pigment Volume C o n c e n t r a t i o n , %: 24.0
Volume S o l i d s , %: 3 5 . 5
Weight p e r G a l l o n , l b : 1 0 . 7
Stormer, KU: 93
I C I , Poise: 1 . 4
pH Value: 8 . 9
Freeze-Thaw S t a b i l i t y , c y c l e s passed: 3
Heat-Age S t a b i l i t y , 12OF, weeks passed: 2
F i l m Properties:
G l o s s , 60: 77
G l o s s , 20: 28
C o n t r a s t R a t i o , 6 - m i l wet drawdown: 0.977
R e f l e c t a n c e , %: 9 2 . 2
B l o c k R e s i s t a n c e , 1-week d r y , RT: 8
Dry Adhesion ( u n t r e a t e d aluminum, g a l v a n i z e d s t e e l ,
a l k y d c h a l k ) : Exc
Wet Adhesion ( u n t r e a t e d aluminum, g a l v a n i z e d s t e e l ,
a l k y d c h a l k , g l o s s a l k y d ) : Good
61 is t e r i ng ( u n t r e a t e d a1 umi num, g a l v a n i z e d s t e e l , a1 kyd
c h a l k ) : Good
Letdown :
Water 47.2 5.7
Butyl Carbitol Solvent 20.5 2.6
Ucar F i l m e r I 8 T 10.2 1.3
Ucar L a t e x 626 372.5 42.8
Ucar L a t e x 471 129.4 14.9
C o l l o i d 643 2.8 0.4
T r o y s a n P o l y p h a s e AF-1 7.2 0.8
Byk 346 1.1 0.1
Ammonium H y d r o x i d e , 28% Aqueous Sol u t i on 1.8 0.3
Paint Properties:
Pigment Volume C o n c e n t r a t i o n , %: 2 4 . 2
Volume S o l i d s , %: 35.0
Weight p e r G a l l o n , l b : 10.5
S t o r m e r , KU: 89
I C I , Poise: 1.5
p H Value: 8 . 8
Freeze-Thaw S t a b i l i t y , c y c l e s passed: 3
Heat-Age S t a b i l i t y , 120F, weeks p a s s e d : 2
R a t i o o f Ucar L a t e x e s 626:Ucar 471: 7 0 : 3 0
F i 1m P r o p e r t ies :
G l o s s , 6 0 : 53
G l o s s , 20: 15
C o n t r a s t R a t i o , 6 - m i l wet drawdown: 0 . 9 7
Reflectance, %: 92.2
Block Resistance: 9
D r y Adhesion ( u n t r e a t e d aluminum, g a l v a n i z e d s t e e l , a l k y d
and l a t e x c h a l k ) : Exc
B l i s t e r i n g ( u n t r e a t e d aluminum, g a l v a n i z e d s t e e l , a l k y d and
l a t e x c h a l k ) : Exc
Wet A d h e s i o n ( u n t r e a t e d aluminum, g a l v a n i z e d s t e e , a l k y d and
l a t e x c h a l k , g l o s s a l k y d ) : Exc
E x t e r i o r W h i t e F l a t House P a i n t
Letdown :
Ucar L a t e x 625 408.6 46.40
Ucar F i l m e r IBT 10.2 1.30
C o l l o i d 640 1.9 0.30
Troysan Polyphase AF-1 7.3 0.80
Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n 1.8 0.20
Paint Properties:
Pigment Volume C o n c e n t r a t i o n , %: 42.5
Volume S o l i d s , %: 38.0
Weight S o l i d s , %: 5 5 . 7
V i s c o s i t y , e q u i 1 ib r a t e d :
Stormer, KU: 90
I C I , Poise: 1 . 3
Freeze-Thaw S t a b i l i t y , c y c l e s passed: 3
Heat-Aged S t a b i l i t y , 120F, weeks passed: 2
Film Properties:
C o n t r a s t R a t i o , 6 - m i l wet drawdown: 0.965
R e f l e c t a n c e , %: 91.9
Wet Adhesion, g l o s s a l k y d : E x c e l l e n t
C h a l k Adhesion, ASTM # 5 : G o o d
E x t e r i o r White T r i m House P a i n t
Letdown :
Ucar L a t e x 625 459.3 52.20
Ucar F i l m e r I B T 11.5 1 .50
C o l l o i d 640 2.8 0.40
T r o y s a n P o l y p h a s e AF-1 7.3 0.80
Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n 0.9 0.10
Byk 346 1.1 0.10
Paint Properties:
Pigment Volume C o n c e n t r a t i o n , %: 27.0
Volume S o l i d s , %: 3 4 . 0
Weight S o l i d s , %: 48.6
Viscosity, equilibrated:
S t o r m e r , KU: 91
I C I , Poise: 1 . 3
Freeze-Thaw S t a b i l i t y , c y c l e s passed: 3
Heat-Aged S t a b i l i t y , 120F, weeks passed: 2
Film Properties:
C o n t r a s t R a t i o , 6 - m i l wet drawdown: 0.968
R e f l e c t a n c e , %: 9 3 . 4
G l o s s , 60: 40
Wet Adhesion, g l o s s a l k y d , 4 - h r : E x c e l l e n t
Adhesion, 1 week, ASTM D3359 ( w e t ) :
a l k y d : 4A
aluminum: 5A
C h a l k Adhesion, ASTM # 5 : Good
B l i s t e r i n g , 24 h r s . :
aluminum: 10
a l k y d c h a l k (ASTM # 5 ) : 8 F
Flow and L e v e l i n g , b r u s h e d : 7
Good Q u a l i t y W h i t e E x t e r i o r F l a t P a i n t f o r Masonry
Letdown :
Water 1 127.1 15.26
P r o p y l e n e G1 y c o l ) Premi x 40.0 4.62
C e l l o s i z e Hydroxyethyl C e l l u l o s e )
QP-15,000 ) 2.3 0.20
C o l l o i d 643 2.0 0.26
NeoCar L a t e x 2300 305.0 34.47
Ucar F i l m e r I B T 13.0 1.64
Paint Properties:
PVC, %: 5 0 . 0
Volume S o l i d s , %: 3 5 . 3
Weight S o l i d s , %: 5 4 . 6
Weight p e r G a l l o n , l b : 11.98
S t o r m e r , KU: 88-93
I C I , p o i s e : 0.8-1.0
pH V a l u e : 8 . 0 - 8 . 5
Heat-Aged S t a b i l i t y , 4 weeks a t 140F: Pass
Film Properties:
R e f l e c t a n c e , %: 8 9 . 4
Gloss, 60: 2
Sheen, 85: 3
C o n t r a s t R a t i o , 3 - m i l f i l m : 0.970
ASTM S c r u b C y c l e s , w i t h s h i m F a i l u r e : >3000
Good Q u a l i t y W h i t e E x t e r i o r F l a t P a i n t f o r Wood
Ingredients: Pounds Gallons
Pigment G r i nd:
Water 195.8 23.50
C e l l o s i z e H y d r o x y e t h y l C e l l u l o s e QP- 15,000 2.5 0.22
Potassium T r i p o l y p h o s p h a t e (KTPP) 2.0 0.09
Nuosept 95 1.5 0.16
C o l l o i d 643 2.0 0.26
T r i t o n N o n i o n i c S u r f a c t a n t N-101 3.0 0.34
AMP-95 1.o 0.13
Tamol 850 7.0 0.71
T i -Pure R-902 245.0 7.35
E a g l e 417W 50.0 1.07
Snowf 1ake 70.0 3.11
Minex 4 85.0 3.92
Letdown :
Water ) 51 .5 6.17
P r o p y l e n e G1y c o l 1 40.0 4.62
C e l l o s i z e Hydroxethyl C e l l u l o s e ) Premix
QP-15,OOO 1 2.0 0.17
C o l l o i d 643 2.0 0.26
NeoCar L a t e x 2300 405.0 45.77
Ucar F i l m e r I B T 17.0 2.15
Note: I f wet a d h e s i o n i s d e s i r e d , b l e n d i n g w i t h an a c r y l i c
r e s i n , such as Ucar L a t e x 625, i s recommended.
Paint Properties:
PVC, %: 39.8
Volume S o l i d s , %: 38.8
Weight S o l i d s , %: 5 6 . 6
Weight p e r G a l l o n , l b : 11.82
Stormer, KU: 88-93
I C I , p o i s e : 0.8-1 . O
pH v a l u e : 8 . 0 - 8 . 5
Heat-Aged S t a b i l i t y , 4 weeks a t 140F: Pass
F i 1m P r o p e r t ies :
R e f l e c t a n c e , %: 9 0 . 8
Gloss, 60: 3
Sheen, 85: 6
C o n t r a s t R a t i o , 3 - m i l f i l m : 0.976
ASTM Scrub C y c l e s , w i t h shim F a i l u r e : >3000
Greqson D r i v e Gloss W h i t e
Letdown :
Ucar L a t e x 481 519.0 58.60
S o l v e n t 142HT 10.0 1.50
Byk 025 2.0 0.30
Butyl Carbitol Solvent 26.0 3.30
Water 76.4 9.17
Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n 1.o 0.10
Ucar P o l y p h o b e 106HE Rheo. Mod. 14.0 1 .60
Paint Properties:
Pigment Volume C o n c e n r t a t i o n , % : 1 9 . 8
Volume S o l i d s , %: 3 3 . 9
Weight S o l i d s , %: 45.8
S t o r m e r , KU: 87
I C I , Poise: 1.0
pH V a l u e : 9 - 9 . 5
Freeze-Thaw S t a b l i t y , c y c l e s passed: 0-1
Heat-Age S t a b i l i y. 12OF, weeks p a s s e d : 4
V O C , grams p e r 1 t e r : 120
Film Properties:
G l o s s , 6 0 : 90
G l o s s . 2 0 : 70
F1 ow and L e v e l ing : E x c e l 1e n t
Dry-to-Touch, hours: 2
Recoat, h o u r s : 4-6
W a t e r / B l i s t e r R e s i s t a n c e : Good
H i g h Q u a l i t y E x t e r i o r Semi G l o s s P a i n t
M a t e r i a1 :
Grind:
Water 62.50 5.99
N a t r o s o l P l u s (Aqualon) 0.52 0.05
A c r y s o l RM 1020 (Rohm and Haas) 31.32 3.00
A c r y s o l RM 825 (Rohm and Haas) 7.31 0.70
Pigment D i s p e r s e r NL (BASF) 1.04 0.10
TKPP (10% i n w a t e r ) 3.13 0.30
P r o x e l GXL ( I C 1 B i o c i d e s ) 2.09 0.20
FCA (Foam C o n t r o l Agent) 3.13 0.30
Kronos 2310 (Kronos) 261 .02 25.02
Letdown :
Propylene g l y c o l 41.76 4.00
Dowanol DPnB (Dow) 10.44 1 .oo
Mineral S p i r it s 10.44 1 .oo
A c r o n a l DS 6183 (BASF) 417.63 40.00
FCA (Foam C o n t r o l Agent) 3.13 0.30
Water 188.46 18.04
P r o p e r t i es :
Pigment Volume C o n t e n t , %: 2 5 . 5
% N o n v o l a t i l e ( b y w e i g h t ) : 45.2
% N o n v o l a t i l e ( b y volume): 32.1
VOC, g / l : 107.0
Stormer V i s c o s i t y , K . U . : 1 0 5 t - 5
I C 1 V i s c o s i t y , P o i s e : 1.5+-2
G l o s s a t 60, %: 6 7 . 0
A g i t a n 731
Weight p e r G a l l o n , l b s / g a l l o n : 10.6
% foam on m a n u f a c t u r i n g : 0.66
Recommended P r o d u c t :
A g i t a n 731: H i g h p e r f o r m a n c e w t h e x c e l l e n t p e r s i s t e n c y
A l t e r n a t i v e Products:
A g i t a n 260 o r A g i t a n 315
SOURCE: K i n g I n d u s t r i e s : F o r m u l a t on WR-39-2
88 Water-Based Paint Formulations
H i g h Sheen W h i t e House P a i n t
Letdown :
Ucar L a t e x 625 461.9 52.19
Ucar F i l m e r IBT 11.5 1.45
Col l o i d 643 1.9 0.25
Troysan Polyphase A F - 1 7.3 0.75
Byk 346 1.1 0.13
Ammmonium H y d r o x i d e , 28% Aqueous S o l u t on 0.9 0.13
Paint Properties:
Pigment Volume C o n c e n t r a t i o n , %: 35 2
Volume S o l i d s , %: 38.1
Weight S o l i d s , %: 5 4 . 0
V i s c o s i t y , e q u i 1ib r a t e d :
Stormer, KU: 88
I C I , Poise: 1.O
Freeze-Thaw S t a b i l i t y , c y c l e s passed: 3
Heat-Aged S t a b i l i t y , 120F, weeks passed: 2
F i l m Properties:
C o n t r a s t R a t i o , 6 - m i l wet drwadown: 0.984
R e f l e c t a n c e , %: 9 2 . 2
Sheen, 8 5 : 6 4 . 0
Wet Adhesion, g l o s s a l k y d : E x c e l l e n t
Chalk Adhesion, ASTM #5: Good
L o w VOC E x t e r i o r House P a i n t
M a t e r i a1 : Lbs %Wt
Grind:
N a t r o s o l 250 MHR 2.5% ( A q u a l o n ) 127.0 15.2
Water 85.0 10.2
Tamol 731 (Rohm and Haas) 16.0 1.8
KTPP 1.o 0.1
T r i t o n CF-10 (Rohm and Haas) 1. o 0.1
Kathon LX 1.5% (Rohm and Haas) 1.7 0.2
FCA (Foam C o n t r o l Agent) 2.0 0.3
T i -Pure R-902 ( DuPont ) 250.0 7.5
E a g l e Z i n c 417W ( E a g l e ) 25.0 0.5
Minex 4 ( I n d u s m i n ) 144.0 6.6
A t t a g e l 50 ( E n g l e h a r d ) 5.0 0.2
Letdown :
E m u l s i o n E-3122 (Rohm and Haas) 301 . O 34.0
FCA (Foam C o n t r o l A g e n t ) 2.0 0.3
A c r y s o l RM-2020 (Rohm and Haas) 15.0 0.2
N a t r o s o l 250 MHR 2.5% ( A q u a l o n ) 29.0 1.7
Skane M-8 (Rohm and Haas) 2.0 3.5
Water 149.0 17.9
Properties:
Pigment Volume C o n t e n t , %: 4 3 . 5
% N o n v o l a t i l e (by w e i g h t ) : 52.4
% N o n v o l a t i l e (by volume): 34.3
Stormer V i s c o s i t y , K.U.: 9 2 t - 5
I C 1 V i s c o s i t y , Poise: 1.3+-2
Recommended P r o d u c t :
A g i t a n 731: S u p e r i o r p e r f o r m a n c e i n b o t h a p p l i c a t i o n and
production o f p a i n t . Fine tuning w i l l optimize
p e r f o r m a n c e and may p r o v i d e a c o s t advantage.
A g i t a n 315: E x c e l l e n t foam c o n t r o l i n a l l a s p e c t s o f p a i n t
m a n u f a c t u r e and a p p l i c a t i o n . Lower c o s t a l t e r -
n a t i v e t o 731.
A l t e r n a t i v e P r o d u c t : A g i t a n 260
SOURCE: K i n g I n d u s t r i e s : F o r m u l a t i o n WR-39-4
90 Water-Based Paint Formulations
Q u a l i t y E x t e r i o r F l a t Formulation
Letdown :
Water 1 188.2 22.6
N a t r o s o l P l u s 330 ) premix 4.0 0.4
Propylene G l y c o l 30.0 3.5
Drewpl u s L-475 2.0 0.3
Ucar L a t e x 6390 65.0 7.4
NeoCar L a t e x 2300 208.0 23.5
Ucar F i l m e r I 8 T 14.0 1.7
Paint Properties:
Pigment Volume C o n c e n t r a t i o n , %: 48.7
Volume S o l i d s , %: 3 0 . 0
Weight p e r G a l l o n , l b : 11.5
Stormer, KU: 83-88
I C I , Poise: 0.9
pH V a l u e : 8 . 9
Low Temperature Coalescence: Pass
Film Properties:
G l o s s , 60: 2
Sheen, 85: 2
C o n t r a s t R a t i o , 6 - m i l wet drawdown: 0.990
R e f l e c t a n c e , %: 8 8 . 4
Scrub R e s i s t a n c e , c y c l e s passed: >1500
D r y Adhesion, c r o s s h a t c h t a p e p u l l : Pass
Wet Adhesion, c y c l e s passed: >2000
5 0 - m i l M u d c r a c k i n g : Pass
Letdown :
Ucar Latex 379G 408.3 45.12
Ucar Filmer IBT 17.8 2.25
Skane M-8 2.2 0.25
Colloid 640 1.9 0.25
Q u a l i t y White E x t e r i o r Trim P a i n t
Letdown :
Water 16.7 1.99
Ucar Polyphobe 9831 Rheology M o d i f i e r ) 5.8 0.69
Water ) Premix 44.7 5.38
B u t y l C a r b i t o l Solvent 30.7 3.04
Ucar L a t e x 626 496.7 57.08
Col l o i d 643 2.8 0.39
Troysan Polyphase AF-1 7.2 0.79
T r i t o n A n i o n i c S u r f a c t a n t GR-7M 1.1 0.10
Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n 0.9 0.10
Paint Properties:
Pigment Volume C o n c e n t r a t i o n , %: 24.2
Volume S o l i d s , %: 3 5 . 0
Weight S o l i d s , %: 49.7
Weight p e r G a l l o n , l b : 1 0 . 5 6
Stormer, KU: 95
I C I , Poise: 1.4
pH V a l u e : 8 . 9
Freeze-Thaw S t a b i l i t y , c y c l e s passed: 3
Heat-Age S t a b i l i t y , 12OF. weeks passed: 2
Film Properties:
G l o s s , 60: 71
Gloss, 2 0 : 26
C o l o r Acceptance: E x c e l l e n t
Flow and L e v e l i n g : E x c e l l e n t
Wet Adhesion, 2 4 - h r d r y : E x c e l l e n t
Q u a l i t y White E x t e r i o r T r i m P a i n t
Letdown :
Water 8.2 0.98
Ucar Pol yphobe 102 Rheology Modi f ie r ) Premi x 8.6 1.02
Water 1 44.7 5.38
B u t y l C a r b i t o 1 Sol v e n t 20.5 2.56
Ucar F i l m e r IBT 10.2 1.28
Ucar L a t e x 626 496.7 57.08
C o l l o i d 643 2.8 0.39
Troysan Polyphase AF-1 7.2 0.79
T r i t o n A n i o n i c S u r f a c t a n t GR-7M 1.1 0.10
Ammonium Hydroxide, 28% Aqueous S o l u t i o n 0.9 0.10
Paint Properties:
Pigment Volume C o n c e n t r a t i o n , %: 24.2
Volume S o l i d s , %: 35.0
Weight S o l i d s , %: 49.7
Weight p e r G a l l o n , l b : 10.56
Stormer, KU: 90-95
I C I , Poise: 1.4
pH Value: 8 . 9
Freeze-Thaw S t a b i l i t y , c y c l e s passed: 3
Heat-Age S t a b i l i t y , 12OF, weeks passed: 2
Film Properties:
Gloss, 60: 62
Gloss, 20: 15
C o l o r Acceptance: E x c e l l e n t
Flow and L e v e l i n g : Excel l e n t
Wet Adhesion, 24-hr d r y : E x c e l l e n t
Q u a l i t y W h i t e House P a i n t w i t h ZnO
Letdown :
Paint Properties:
Pigment Volume C o n c e n t r a t i o n , %: 45.0
Volume S o l i d s , %: 35.4
V i s c o s i t y , e q u i 1ib r a t e d :
Stormer, KU: 82
I C I , p o i s e : 0.85
Weight p e r G a l l o n , l b : 11.70
Freeze-thaw S t a b i l i t y , 3 c y c l e s : Pass
Heat-Aged S t a b i l i t y , 2 weeks a t 120F: Pass
F i 1m P r o p e r t ies :
C o n t r a s t R a t i o , 6 - m i l wet drawdown: 0.951
R e f l e c t a n c e , %: 91 . 1
Sheen, 85: 4.0
Flow and L e v e l i n g , b r u s h e d : Good
Wet Adhesion: E x c e l l e n t
M a t e r i a1 : Lbs. Gals .
A r o l o n 840-W-39 130.5 15.00
Water 50.0 6.00
C o l l o i d 679 1.9 0.25
C e l l o s i ze QP4400 1.o 0.09
Ammonium H y d r o x i d e 1.9 0.25
D i sperse-Ayd W28 4.4 0.50
Kroma Red RO 7097 50.0 1.23
T i t a n o x 2101 5.0 0.15
Durami t e 150.0 6.61
Letdown : u sI Gals_
A r o l o n 840-W-39 304.5 35.00
Spensol L51 304.1 34.75
Ucar S C T I 00 2.3 0.25
Analysis:
Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 2 2 . 0
Pigment/Binder R a t i o : 0.8/1 .O
Percent S o l i d s , Weight: 46.9
P e r c e n t S o l i d s , Volume: 3 6 . 4
V i s c o s i t y (a 25C, K U : 85-95
Pounds/Gal l o n : I O . 1
pH: 8 . 5 + - 0 . 3
VOC ( e x c l u d i n g w a t e r ) :
Grams/Li t e r : 150
Pounds/Gallon: 1 . 3
Weather B a r r i e r Formulat-
Letdown :
Ucar L a t e x 123 496.6 55.9
Ucar F i l m e r IBT 6.0 0.8
Antifoam (3) 2.0 0.3
Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n 2.5 0.3
S, u p p l ie r s :
( 1 ) D i s p e r s a n t - C o l l o i d 226/35 (Rhone-Poulenc) o r e q u i v a l e n t .
W e t t i n g Agent - S u r f y n o l 104 ( A i r P r o d u c t s ) o r e q u i v a l e n t .
A n t i f o a m - C o l l o i d 643 (Rhone-Poulenc) o r e q u i v a l e n t .
T i t a n i u m D i o x i d e - T i - P u r e R-960 (DuPont) or e q u i v a l e n t .
C a l c i u m Carbonate - A t o m i t e (ECC) o r e q u i v a l e n t .
( 6 ) Z i n c O x i d e - Kadox 915 (Cookson) o r e q u i v a l e n t .
( 7 ) M i l d e w c i d e - N o p c o c i d e N-96 ( H e n k e l ) o r e q u i v a l e n t .
Paint Properties:
Pigment Volume C o n c e n t r a t i o n (PVC), %: 40
T o t a l S o l i d s , %:
b y Volume: 5 3 . 8
by Weight: 68.5
S t o r m e r V i s c o s i t y , KU: 110
F i 1m P r o p e r t i e s * :
Tensile:
S t r a i n Rate, i n / m i n : 2 . 0
S t r e s s , p s i : 108
E l o n g a t i o n , % : 1070
T e n s i l e a f t e r 24-hour Water i m m e r s i o n :
S t r a i n Rate, i n / m i n : 2 . 0
S t r e s s , p s i : 52
E l o n g a t i o n , % : 1650
Water Pondi ng:
Water T r a n s m i s s i o n a t 2 4 Hours, mg: 9 0
Low T e m p e r a t u r e F l e x i b i l i t y :
180 Bend a t -2OC: No C r a c k i n g
* D r i e d and C o n d i t i o n e d 7 Days a t 72F (22C) and 50% RH
W h i t e E x t e r i o r F l a t House P a i n t w i t h Z i n c O x i d e
I n q r e d ients: Pounds _ G a l l o n
_ _s ~
Pigment G r i n d :
Water 249.1 29.90
C e l l o s i z e H y d r o x y e t h y l C e l l u l o s e ER-30,000 4.0 0.40
Nuosept 95 2.3 0.25
P r o p y l e n e G1 y c o l 25.9 2.98
Potassium T r i p o l y p h o s p h a t e (KTPP) 2.0 0.20
Tamol 850 4.0 0.40
T r i t o n N o n i o n i c S u r f a c t a n t N-101 2.1 0.24
C o l l o i d 640 1.9 0.25
T i -Pure R-706 200.0 5.90
E a g l e 417W 50.0 1.11
Minspar 4 100.0 4.63
N y t a l 300 75.0 3.16
Letdown :
Water 75.0 9.00
Ucar L a t e x 353 251 .O 27.50
Ucar L a t e x 6390 88.7 10.08
Ucar F i l m e r IBT 23.8 3.01
Col l o i d 640 3.8 0.51
Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n 3.0 0.40
Paint Properties:
PVC, %: 41 . 1
Volume S o l i d s , %: 36.0
Weight S o l i d s , %: 5 9 . 6
Weight p e r G a l l o n , l b : 11.61
S t o r m e r , KU: 93
I C I , poise: 0.9
pH, i n i t i a l : 9 . 4
Freeze-thaw S t a b i l i t y , 5 c y c l e s : Pass
Heat-Aged S t a b i l i t y :
1 week a t 140F: Pass
2 weeks a t 120F: Pass
R o l l e r S t a b i l i t y , 1 week*: Pass
F i 1m P r o p e r t i es :
R e f l e c t a n c e , %: 88.2
C o n t r a s t R a t i o , 3 - m i l f i l m : 0.951
Wet Adhesion, 2 4 - h r . , c y c l e s : >2000
C h a l k Adhesion:
D r y : Exc
Wet: Exc
Color*:
Acceptance: Exc
Development : Exc
F l o a t : Exc
* T i n t e d w i t h 2% by w e i g h t p h t h a l o b l u e ( H u l s 888-7124)
W h i t e E x t e r i o r F l a t House P a i n t w i t h Z i n c O x i d e
Letdown :
NeoCar L a t e x 6035 378.0 41.77
Ucar F i l m e r IBT 20.0 2.53
Skane M-8 1.o 0.12
C o l l o i d 643 1.5 0.21
Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n 2.0 0.24
Cel l o s i z e H y d r o x y e t h y l C e l l u l o s e QP-4400 43.0 5.16
Pai n t P r o p e r t ies :
PVC, %: 45.0
Volume S o l i d s , %: 3 7 . 0
Weight S o l i d s , %: 54.7
Weight p e r G a l l o n , l b : 1 1 . 7
Stormer, KU: 97
ICI, p o i s e : 0 . 8 - 1 . 0
pH V a l u e : 8 . 5 - 9 . 0
Heat-Aged S t a b i l i t y , 4 weeks a t 1 4 0 F : Pass
Film Properties:
R e f l e c t a n c e , %: 89.7
G l o s s , 60: 3
Sheen, 85: 4
C o n t r a s t R a t i o , 3 - m i l f i l m : 0.969
ASTM Scrub C y c l e s , w i t h shim F a i l u r e : > l o 0 0
C h a l k Adhesion: Exc
White R o o f Coating
M a t e r i a1 : Lbs. Gals.
Water 172.60 20.72
PMA-100 1 .80 0.09
Ammonia (28%) 0.90 0.12
Potassium Tripolyphosphate 1.92 0.09
AZO-33 Z i n c O x i d e 22.83 0.49
Durami t e 466.65 20.74
T i t a n o x 2160 24.31 0.73
B u b b l e B r e a k e r 3295 3.30 0.44
B u b b l e B r e a k e r 776-P 3.30 0.44
M e t h o c e l 31 2MS 4.14 0.36
Texanol 17.93 2.27
D i s p e r s e under h i g h s h e a r f o r 10-15 m i n u t e s .
Add l e t d o w n :
Analysis:
Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 47.5
P i g m e n t / B i n d e r R a t i o : 2.26/1
P e r c e n t S o l i d s , W e i g h t : 63.18
P e r c e n t S o l i d s , Volume: 47.33
V i s c o s i t y @ 25C, KU: 80-90
Gloss: F l a t
Pounds/Gallon: 11.91
pH: 8 . 8 - 9 . 2
VOC ( e x c l u d i n g w a t e r ) :
Grams/Liter: 64.0
Pounds/Gallon: 0 . 5 3
C l e a r H i g h Gloss V a r n i s h
Analysis:
Percent Sol i d s , Weight : 30.9
Percent S o l i d s , Volume: 28.0
V i s c o s i t y @ 25C #2 Zahn, Secs.: 20
Gloss ( 6 0 ) : 100+
Pounds/Gallon: 8 . 7
pH: 8.5+-0.3
VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 290
Pounds/Gallon: 2 . 4
F o r m u l a t i o n 2307-22A
Fast-Dry S e a l e r
M a t e r i a1 : Lbs. Gal s .
Spensol L51 687.2 78.63
Add i n f o l l o w i n g o r d e r w i t h a g i t a t i o n :
A r o l o n 840-W-39 176.2 20.25
S u r f y n o l 104H 5.2 0.66
Lodyne S I 0 7 2.2 0.23
Analysis:
R a t i o o f Spensol L51 t o A r o l o n 840: 75:25
Percent S o l i d s , Weight: 32.1
Percent S o l i d s , Volume: 29.5
V i s c o s i t y @ 25C, #2 Zahn, Secs.: 2 3 t - 4
Pounds/Gallon: 8.73
pH: B t - 0 . 5
VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 286
Pounds/Gallon: 2 . 4
Forrnul a t i o n 2061 - 9 1 A
S0URCE:Reichhold Chemicals, I n c . : Spensol L51: F o r m u l a t i o n s
102 Water-Based Paint Formulations
Economv F l a t W a l l P a i n t
Letdown :
Water 30.2 3.63
Ucar L a t e x 353 125.4 13.78
Ucar F i l m e r I B T 8.1 1.03
Drewpl u s L-475 1.9 0.25
Paint Properties:
PVC, %: 70.0
Volume S o l i d s , %: 2 9 . 8
Weight S o l i d s , %: 5 0 . 2
Weight p e r G a l l o n , l b : 11.32
S t o r m e r , KU: 9 4
I C I , p o i s e : 0.9
pH, i n i t i a l : 8 . 3
Freeze-thaw S t a b i l i t y , 5 c y c l e s : Pass
Heat-Aged S t a b i l i t y , 2 weeks a t 120F: Pass
Film Properties:
R e f l e c t a n c e , %: 9 1 . 2
Sheen, 85: 1 . 1
C o n t r a s t R a t i o , 3 - m i l f i l m : 0.959
ASTM S c r u b C y c l e s , w i t h s h i m f a i l u r e , 10%: 102
Color*:
Acceptance: Exc
Development: Exc
* T i n t e d w i t h 2% b y w e i g h t p h t h a l o b l u e ( H u l s 888-7214) or
r e d i r o n o x i d e ( H u l s 888-1045).
Economy F l a t W a l l P a i n t
Letdown :
Water 30.2 3.63
Ucar L a t e x 353 125.4 13.78
Ucar F i l m e r IBT 8.1 1.03
Orewplus L-475 1.9 0.25
Paint Properties:
PVC, %: 70.0
Volume S o l i d s , %: 29.8
Weight S o l i d s , %: 5 0 . 2
Weight p e r G a l l o n , l b : 11.32
S t o r m e r , KU: 94
I C I .. .o o i s e : 0 . 9
pH, i n i t i a l : 8 . 3
Freeze-thaw S t a b i l i t y , 5 c y c l e s : Pass
Heat-Aged S t a b i l i t y , 2 weeks a t 120F: Pass
F i 1m P r o p e r t ies :
R e f l e c t a n c e , %: 9 1 . 2
Sheen, 85: 1 . 1
C o n t r a s t R a t i o , 3 - m i l f i l m : 0.959
ASTM S c r u b C y c l e s , w i t h s h i m f a i l u r e , 10%: 102
Color*:
Acceptance: Exc
Development : Exc
* T i n t e d w i t h 2% b y w e i g h t p h t h a l o b l u e ( H u l s 888-7214) or
r e d i r o n o x i d e ( H u l s 888-1045).
Letdown :
Ucar L a t e x 3796 200.0 22.10
Ucar F i l m e r IBT 3.0 0.38
Drewplus L-475 4.0 0.52
Ucar Polyphobe 102 Rheology M o d i f i e r 17.3 1.98
Water 50.0 6.01
Paint Properties :
PVC, %: 63.1
Volume S o l i d s , %: 3 4 . 5
Weight S o l i d s , %: 5 5 . 1
Weight p e r G a l l o n , l b : 12.18
Stormer, KU: 87
I C I , poise: 2.1
pH, i n i t i a l : 9 . 2
Freeze-Thaw S t a b i 1 it y , 1 c y c l e : Pass
Heat-Aged S t a b i l i t y , 4 weeks a t 140F: Pass
V o l a t i l e O r g a n i c Content, g / L : 4 5 . 6
F i 1m P r o p e r t ies :
Ref 1 e c t a n c e , %: 9 0 . 0
Sheen, 85: 2
C o n t r a s t R a t i o , 3 - m i l f i l m : * 0.961
ASTM Scrub C y c l e s , w i t h shim F a i l u r e : 330
Color:*
Acceptance: Excel l e n t
Development: E x c e l l e n t
Low Temperature Coalescence I O - m i l drawdown a t 40F: Pass
Mudcracki ng, 3 0 - m i 1 on s h e e t r o c k : Pass
* T i n t e d w i t h 2% by w e i g h t p h t h a l o b l u e ( H u l s 888-7214)
o r r e d i r o n o x i d e ( H u l s 888-1045).
H i a h - Q u a l i t y Super F l a t I n t e r i o r P a i n t
Letdown :
Ucar L a t e x 3796 419.8 46.64
Ucar F i l m e r IBT 16.8 2.11
C o l l o i d 640 3.5 0.50
Ucar Pol yphobe 102 Rheology Modi f ie r 7.5 0.86
Water 51.3 6.16
Pai n t P r o p e r t i es :
PVC, %: 43.3
Volume S o l i d s , %: 43.4
Weight S o l i d s , %: 61.0
Weight p e r G a l l o n , l b : 12.09
Stormer. KU: 90
I C I , p o i s e : 2.0
pH, i n i t i a l : 9 . 2
Freeze-Thaw S t a b i l i t y , 3 c y c l e s : Pass
Heat-Aged S t a b i l i t y , 4 weeks a t 140F: Pass
F i 1m P r o p e r t ies :
R e f l e c t a n c e , %: 92.5
Sheen, 85: 7
C o n t r a s t R a t i o , 3 - m i l f i l m * : 0.962
ASTM Scrub Cycles, w i t h shim F a i l u r e : >2000
Color*:
Acceptance: Excel 1e n t
Development : Excel 1e n t
* T i n t e d w i t h 2% by w e i g h t p h t h a l o b l u e ( H u l s 888-7214) or
r e d i r o n o x i d e ( H u l s 888-1045).
I n t e r i o r C l e a r Wood F i n i s h
(RhoDlex CL-l04/Sancure 8151
B1 end : Pounds
Rhopl ex CL-104 (38.5%) 540.0
Sancure 815 (35.0%) 148.5
S u r f y n o l DF-62 1.4
S u r f y n o l 104PG-50 3.0
M i x above f o r 10 m i n u t e s b e f o r e a d d i n g t h e f o l l o w i n g :
Hexyl C a r b i t o 1 20.8
Propylene G l y c o l 30.0
A c r y s o l RM-1020 18.0
Water 66.0
Michem 39235 22.3
Aqueous Ammonia ( 14%) 2.5
I n t e r i o r Sandina S e a l e r
(RhoDlex CL-1051
E l end : Pounds
Rhopl ex CL-105 ( 3 7 . 0 % ) 709.3
S u r f y n o l DF-62 1.3
Water 32.9
Aqueous Ammonia (14%) 8.0
M i x above f o r 10 m i n u t e s b e f o r e a d d i n g t h e f o l l o w i n g :
Propasol B 45.2
Hexyl C a r b i t o 1 22.3
A c r y s o l RM-2020 4.1
Water 30.8
Aqueous Ammonia (7%) 2.6
S u r f y n o l 104DPM 3.0
F o r m u l a t i o n C (Rohm & Haas)
I n t e r i o r Contractor F l a t
Letdown :
Ucar Latex 379G 148.0 16.35
Ucar F i l m e r I B T 8.0 1.01
C o l l o i d 643 2.5 0.34
Water 50.0 6.00
Ucar Polyphobe 10 Rheology
-. Modi f ie r 21 .o 2.41
Water 217.5 26.11
Paint Properties:
PVC, %: 7 1 . 4
Volume Sol i d s , %: 40.3
Wei g h t Sol i d s , %: 29.4
Weight p e r Gal on, l b : 11.3
pti, i n i t i a l : 8 5-9.0
I n t e r i o r Good Q u a l i t y F l a t
f o r R o l l e r and Brush A p p l i c a t i o n
I C I , P: 1.4
Scrub C y c l e s : 1200
F l o w / L e v e l i n g : Good
50-mi 1 Mudcrack: Pass
R o l l e r / S p a t t e r : M i n i mal
I n t e r i o r Good Q u a l i t y F l a t
f o r R o l l e r and B r u s h A p p l i c a t i o n
Letdown :
Ucar L a t e x 379 254.0 20.07
Ucar F i l m e r I B T 16.0 2.03
C o l l o i d 643 2.5 0.34
Water 60.3 7.20
Ucar Polyphobe 9831 Rheology M o d i f i e r 12.5 1.40
Water 119.2 14.31
Paint Properties:
Pigment Volume C o n c e n t r a t i o n , %: 5 8 . 0
Volume S o l i d s , %: 34.4
Weight S o l i d s , %: 5 1 . 9
Weight p e r G a l l o n , l b : 1 1 . 3
S t o r m e r , KU: 95
I C I , Poise: 1.6
pH V a l u e : 8 . 5 - 9 . 0
V o l a t i l e O r g a n i c C o n t e n t , g / L : 139
Film Properties:
Sheen, 85: 1.8
Flow and L e v e l i n g : Good
Sag R e s i s t a n c e , m i l s : 7
I n t e r i o r Good Q u a l i t y F l a t
Letdown :
Ucar L a t e x 3796 254.0 28.07
Ucar F i l m e r IBT 16.0 2.03
Col l o i d 643 2.5 0.34
Water 50.0 6.00
Ucar P o l yphobe 103 Rheology Modi f ie r 22.8 2.62
Water 119.2 14.31
Paint Properties:
PVC, %: 5 8 . 0
Volume S o l i d s , %: 3 4 . 4
Weight S o l i d s , %: 5 1 . 9
Weight p e r G a l l o n , l b : 11.3
pH, i n i t i a l : 8 . 5 - 9 . 0
T h i c k e n e r Comparison:
Ucar Polyphobe Ucar Pol yphobe
02 03
NVM, l b / 1 0 0 g a l 7.0 5.7
Stormer, KU 86/96 91 /98
I C I , poise 1.8 1.5
Scrub C y c l e s 1200 1102
F l o w / L e v e l ing Exc Exc
50-mi 1 Mudcracki ng Pass Pass
I n t e r i o r Semi g l o s s F o r m u l a t i o n
Letdown :
Water 24.8 3.0
Ucar Polyphobe 102 Rheology M o d i f i e r 2.2 0.3
B u t y l C a r b i t o l Solvent 23.8 3.0
Ucar F i l m e r I B T 11.9 1.5
Ucar L a t e x 379G 346.8 38.3
Ucar L a t e x 6030 184.0 20.9
C o l l o i d 643 2.8 0.4
Byk 346 1.1 0.1
Ammoni um H y d r o x i de, 28% Aqueous Sol u t i on 1.8 0.3
Paint Properties:
Pigment Volume C o n c e n t r a t i o n , %: 2 2 . 5
Volume S o l i d s , 96: 3 6 . 4
Weight p e r G a l l o n , l b : 10.7
Stormer, KU: 83
I C I , Poise: 1.9
pH Value: 8 . 7
Freeze-Thaw S t a b i l i t y , c y c l e s passed: 3
Heat-Age S t a b i l i t y , 120F. weeks passed: 2
R a t i o o f Ucar L a t e x e s 379:6030: 70:30
Film Properties:
G l o s s , 60: 64
G l o s s , 20: 18
C o n t r a s t R a t i o , 6 - m i l wet drawdown: 0.972
R e f l e c t a n c e , %: 9 1 . 9
Block Resistance: 9
Flow and L e v e l i n g : Good
Low Temperature Coalescence: 10
W a s h a b i l i t y , s t a i n removal*: 10
( c r a y o n , f e l t pen, l i p s t i c k , p e n c i l )
% g l o s s r e t a i n e d : 92
Wet Adhesion, g l o s s a l k y d : Exc
*Washed w i t h F a n t a s t i k ; lO=complete s t a i n removal
_I n t e
_ r i o_ r V~ i n y l A c r y l i c E g g s h e l l
f o r R o l l e r and Brush A p p l i c a t i o n
I n q r e d ie n t s : Pounds Gallons
Pigment G r i n d :
Water 100.0 12.00
P r o p y l e n e G1 y c o l 26.0 3.02
Tamol 1124 8.0 0.81
T r i t o n N o n i o n i c S u r f a c t a n t X-100 2.0 0.23
C o l l o i d 643 1.5 0.21
P r o x e l GXL 1.5 0.15
AMP-95 2.0 0.25
T i -Pure R-900 230.0 6.91
Omyacarb UF 100.0 4.42
ASP-1 70 50.0 2.33
Letdown :
Ucar L a t e x 379 420.0 46.41
Ucar F i l m e r IBT 12.0 1.52
Col l o i d 643 2.5 0.34
AMP-95 2.0 0.25
Ucar Polyphobe 9831 Rheology M o d i f i e r 11 .o 1.27
Water 168.0 20.07
Paint Properties:
Pigment Volume C o n c e n t r a t i o n , %: 36.4
Volume S o l i d s , %: 3 7 . 4
Weight S o l i d s , %: 5 4 . 4
Weight p e r G a l l o n , l b : 1 1 . 3
Stormer, KU: 95
I C I , Poise: 1 . 2
pH V a l u e : 8.5-9.0
V o l a t i l e O r g a n i c Content, g / L : 121
Film Properties:
Gloss, 60: 35
Flow and L e v e l i n g : Good
Sag R e s i s t a n c e , m i l s : 12
I n t e r i o r V i n y l A c r y l ic Eqashel 1
f o r R o l l e r and Brush A p p l i c a t i o n
Letdown :
Ucar L a t e x 379 420.0 46.41
Ucar F i l m e r IBT 12.0 1.52
C o l l o i d 643 2.5 0.34
AMP-95 2.0 0.25
Ucar Pol yphobe 102 Rheology Modi f ie r 30.0 3.45
Water 149.0 17.89
Paint Properties:
Pigment Volume C o n c e n t r a t i o n , %: 36.4
Volume S o l i d s , %: 37.4
Weight S o l i d s , %: 54.4
Weight p e r G a l l o n , l b : 11.3
pH, i n i t i a l : 8 . 5 - 9 . 0
T h i c k e n e r Comparison:
Ucar Polyphobe 114:
NVM l b / 1 0 0 g a l : 5 . 0
Stormer, KU: 93
I C I , P: 0.5
F l o w / L e v e l i n g : Poor
Sag R e s i s t a n c e : 24+
I n t e r i o r V i n y l A c r y l i c Semigloss
Letdown :
Ucar L a t e x 367 423.0 47.00
Water 33.3 4.00
Ucar F i l m e r I B T 23.8 3.01
Nuosept 95 2.0 0.21
T r i t o n N o n i o n i c S u r f a c t a n t GR-5M 1.o 0.12
AMP-95 5.0 0.64
Drewpl us L-475 4.0 0.56
Water ( a d j u s t a c c o r d i n g t o Polyphobe l e v e l ) 214.5 25.75
Ucar Polyphobe 114 Rheology M o d i f i e r 26.5 3.05
Paint Properties:
Pigment Volume C o n c e n t r a t i o n , %: 20.4
Volume S o l i d s , 96: 40.3
Weight S o l i d s , %: 54.2
Weight p e r G a l l o n , l b : 1 0 . 5
T h i c k e n e r Compari son :
Ucar Polyphobe 114:
NVM l b / 1 0 0 g a l : 6.6
B r o o k f i e l d , 0.3, P: 680
I C I , P: 0 . 5
60 G l o s s : 79
Ucar Polyphobe 102:
NVM l b / 1 0 0 g a l : 10.7
Brookfield,-0.3, P : 186
ICI, P: 2.2
60 G l o s s : 74
Ucar Polyphobe 103:
NVM l b / 1 0 0 g a l : 8 . 2
B r o o k f i e l d , 0.3, P: 336
I C I , P: 1 . 5
60 Gloss: 69
Ucar Polyphobe 107;
NVM l b / 1 0 0 g a l : 5 . 1
B r o o k f i e l d , 0.3, P: 226
I C I , P: 0 . 7
60 G l o s s : 67
Ucar Polyphobe 1 0 6 H E :
NVM l b / 1 0 0 g a l : 5.6
B r o o k f i e l d , 0 . 3 , P: 2,086
I C I , P: 0.7
60 Gloss: 70
Letdown :
C e l l o s i z e H y d r o x y e t h y l C e l l u l o s e QP-15,OOOH
( 1 . 5 % aqueous s o l u t i o n ) 45.0 5.2
Ucar L a t e x 367 145.0 16.0
C o l l o i d 677 1 .o 0.1
Procedure:
Under a g i t a t i o n , add a l l i n g r e d i e n t s o f t h e pigment g r i n d i n
t h e o r d e r l i s t e d . Completely d i s p e r s e each i n g r e d i e n t b e f o r e
a d d i n g t h e n e x t . When t h e pigment g r i n d s l u r r y i s complete,
a g i t a t e f o r an a d d i t i o n a l f i v e minutes; t r a n s f e r t o a p e b b l e
m i l l and g r i n d t o Hegman 3. Under a g i t a t i o n , p r e p a r e t h e f i n a l
l e t d o w n i n t h e o r d e r l i s t e d . Under a g i t a t i o n , add t h e pigment
g r i n d s l o w l y t o t h e l e t d o w n . Note: P r o t e c t t h i c k e n e r s o l u t i o n s
w i t h p r e s e r v a t i v e d u r i n g p r o c e s s i n g and s t o r a g e .
Paint Properties:
Pigment Volume C o n c e n t r a t i o n , %: 74
T o t a l S o l i d s , % by w e i g h t : 60
Weight p e r G a l l o n , l b : 10.8
Stormer. KU: 75-80
C o n t r a s t R a t i o : 0.87
Low VOC I n t e r i o r F l a t
I n q r e d ie n t s : _ _ _ _G
Pounds _a _
l l o_
ns
Pigment G r i n d :
Water 333.3 40.00
Kathon LX 1.7 0.20
Tamol 1124 5.1 0.52
T r i t o n N o n i o n i c S u r f a c t a n t N-101 2.0 0.23
Drewpl us L-475 2.0 0.26
Ucar Polyphobe 102 Rheology M o d i f i e r 15.0 1.73
Sodi um H y d r o x i d e 3.0 0.15
T i - P u r e R-902 190.0 5.70
Durami t e 185.0 8.21
Iceberg 155.0 7.07
Water 50.0 6.00
Letdown :
Ucar L a t e x 379 200.7 22.18
Water 39.4 4.73
Drewpl us L-475 2.5 0.33
Ucar F i l m e r I B T 7.7 0.96
Ucar Polyphobe 102 Rheology M o d i f i e r 15.0 1.73
Paint Properties:
Pigment Volume C o n c e n t r a t i o n , %: 64.9
Volume S o l i d s , %: 3 2 . 3
Weight S o l i d s , %: 53.1
Weight p e r G a l l o n , l b : 1 2 . 1
Stormer, KU: 92
VOC, grams p e r l i t e r : 26.09
Film Properties:
G l o s s , 60: 2
Sheen, 8 5 : 3
C o n t r a s t R a t i o , 6 - m i l wet drawdown: 0.977
R e f l e c t a n c e , %: 91 .8
Scrub R e s i s t a n c e , c y c l e s passed: 161
-
Solvent Free I n t e r i o r S a t i n P a i n t
Letdown :
Rovace SF-091 (Rohm and Haas) 372.2 41.50
Rovaque OP-62 L O (Rohm and Haas) 45.0 5.22
FCA (Foam C o n t r o l A g e n t ) 2.0 0.26
A c r y s o l RM-2020 (Rohm and Haas) 15.0 1.65
A c r y s o l TT-935 (Rohm and Haas) 12.5 1.42
Sodium C a r b o n a t e 24.0 2.52
Water 57.5 6.90
Properties:
Pigment Volume C o n t e n t , %: 37.0
% N o n v o l a t i l e ( b y volume): 34.0
Stormer V i s c o s i t y , K . U . : 95+-5
I C 1 V i s c o s i t y . P o i s e : 1.1+-2
G l o s s a t 6 0 , - % : 13.0
Recommended P r o d u c t :
A g i t a n 315: E f f i c i e n t . F i n e t u n i ng w i 11 p r o v i d e c o s t b e n e f i t s .
A l t e r n a t i v e Products:
A g i t a n 260: E f f i c i e n t , c o s t e f f e c t i v e .
A g i t a n 731: E f f i c i e n t , z e r o voc .
SOURCE: King Industries: Formu a t i o n WR-39-3
118 Water-Based Paint Formulations
White I n t e r i o r Eqsshell
Inqredients: Pounds
~~ Gal l o n s
Pigment G r i n d :
Water 226.7 27.21
Ucar Polyphobe 9831 Rheology M o d i f i e r 8.5 0.97
Nuosept 145 2.3 0.25
Tamol 731A 11.5 1.25
T r i t o n N o n i o n i c S u r f a c t a n t N-57 2.3 0.25
AMP-95 2.0 0.26
Propylene G l y c o l 51.8 6.00
Col l o i d 640 1.9 0.25
Tronox CR-800 225.0 6.54
Opt iwh it e 100.0 5.46
Burgess No. 98 25.0 1.15
Letdown :
AMP-95 2.0 0.27
Ucar F i l m e r IBT 22.5 2.85
Water 78.7 9.45
Ucar L a t e x 353 341 .O 37.47
Col l o i d 640 2.8 0.37
Paint Properties:
PVC, %: 35.8
Volume S o l i d s , %: 38.2
Weight S o l i d s , %: 5 2 . 4
Weight p e r G a l l o n , l b : 11.04
Stormer, KU: 95
I C I , poise: 1.4
pH, i n i t i a l : 9.0
Freeze-thaw S t a b i l i t y , 5 c y c es: Pass
Heat-Aged S t a b i l i t y , 2 weeks a t 120F: Pass
F l m Properties:
R e f l e c t a n c e , %: 9 1 . 4
Gloss, 60: 6.3
Sheen, 85: 22.6
Contrast R a t i o , 3-mil film: .969
Color*:
Acceptance : Exc
Development: Exc
* T i n t e d w i t h 2% b y w e i g h t p h t h a l o b l u e ( H u l s 888-7124) o r red
i r o n o x i d e ( H u l s 888-1045).
Green Lacquer
L e t Down:
Ucar V e h i c l e 443 666.11 75.19
Butyl C a r b i t o l Solvent 13.26 1.67
T r i b u t o x y e t h y l Phosphate 13.26 1.58
P h t h a l o Green (3) 51.50 5.10
D e i o n i z e d Water 26.55 3.19
Suppl i e r s :
( 1 ) D i s p e r s a n t - C o l l o i d 107 ( C o l l o i d s ) o r e q u i v a l e n t .
( 2 ) A n t i f o a m - C o l l o i d 675 ( C o l l o i d s ) o r e q u i v a l e n t .
(3) P h t h a l o Green - T i n t - A y d WD-2744 D i s p e r s i on ( D a n i e l
Products) o r equivalent.
( 4 ) Medium Chrome Y e l l o w - X-3356 C . P . Medium Y (Ciba-Geigy)
o r equivalent .
Lacquer P r o p e r t i as :
P i gment/Bi nder Rat io : 0.25/ 1
S o l i d s , %:
by Weight: 37
by Volume: 31
pH: 8 . 5
V i s c o s i t y , No. 4 F o r d Cup, sec: 25
Foam C o n t r o l w i t h A g i t a n A d d i t i v e s i n a
H i a h G l o s s D I Y Waterborne Lacquer
The c h o i c e o f c o a l e s c i n g a g e n t s can s i g n i f i c a n t l y i n f l u e n c e
t h e g e n e r a t i o n o f foam i n a w a t e r b o r n e f o r m u l a t i o n as w e l l as
a f f e c t t h e performance o f t h e foam c o n t r o l agent (FCA).
A d j u s t pH t o 7-8
Adjust t o v i s c o s i t y
P r o p e r t ies :
% N o n v o l a t i l e (by w e i g h t ) : 30.7
% N o n v o l a t i l e ( b y volume): 29.1
pH, 25C: 7 . 5 - 8 . 0
V i s c o s i t y #2 Zahn, 25C ( s e c o n d s ) : 20-26
T h e o r e t i c a l VOC ( p o u n d s / g a l l o n ) : 2 . 0 7
T h e o r e t i c a l VOC ( g r a m s / l it e r ) : 249
W h i t e Lacauer
Pebble M i l l o v e r n i g h t .
L e t Down:
Ucar V e h i c l e 443 421.3 48.2
Antifoam ( 3 ) 0.9 0.1
Proposol S o l v e n t B 40.9 5.6
T r i b u t o x y e t h y l Phosphate 20.4 2.4
Mar-Resi s t a n t A i d ( 5 ) 0.9 0.1
Ammonium Benzoate, 10% Aqueous S o l u t i o n 10.0 1.1
Dei o n i zed Water 150.8 18.1
Suppliers:
( 1 ) Dispersant - Disperbyk ( B y k - M a l l i n c k r o d t ) o r e q u i v a l e n t .
( 2 ) S u r f a c t a n t - S u r f y n o l 104 ( A i r P r o d u c t s ) o r e q u i v a l e n t .
( 3 ) A n t i f o a m - Hodag PX-218 (Hodag) o r e q u i v a l e n t .
( 4 ) T i t a n i u m D i o x i d e - Zopaque RCL-9 (SCM) o r e q u i v a l e n t .
(5) M a r - R e s i s t a n t A i d - Byk 301 ( B y k - M a l l l i n c k r o d t ) o r
equivalent.
Lacquer P r o p e r t i e s :
Pigment/Binder R a t i o : 0.8/1
T o t a l S o l i d s , %: 42.4
pH: 8 . 6
V i s c o s i t y , No. 4 F o r d Cup, sec:
I n i t i a l : 20
A f t e r 10 days a t 140F: 20
W h i t e Lacquer
G r i n d f o r 15 m i n u t e s a t h i g h speed i n a h i g h - s h e a r m i x e r .
L e t Down:
Ucar V e h i c l e 443 546.84 62.00
T r i b u t o x y e t h y l Phosphate 4.60 0.55
Filmer (4) 11.19 1.42
B u t y l C a r b i t o l Solvent 11.20 1.41
Ammonium Benzoate 0.74 0.07
D e i o n i z e d Water 210.25 25.29
Suppl ie r s :
(1) Dispersant - Disperbyk ( B y k - M g l l i n c k r o d t ) o r e q u i v a l e n t
( 2 ) A n t i f o a m - C o l l o i d 675 ( C o l l o i d s ) o r e q u i v a l e n t .
( 3 ) T i t a n i u m D i o x i d e - T i t a n o x 2060 (NL I n d u s t r i e s ) o r
equivalent.
( 4 ) F i l m e r - Texanol (Eastman) o r e q u i v a l e n t .
Lacquer P r o p e r t i e s :
Pigment/Binder R a t i o : 0.67/1
S o l i d s , %:
by Weight: 38.5
b y Volume: 2 8 . 1
pH: 8 . 5
V i s c o s i t y . No. 4 F o r d Cup, s e c : 35
fi
H a l o x BW-100
Letdown :
CL 27NA 340.0 408.0
Drewpl us L-475 2.0 2.4
Mix u n t i l uniform.
Ingredient: -
Lb Gal Wt%
Pigment G r i n d :
Water 100.10 12.02 8.35
Busperse 3 9 / D i s p e r s a n t 8.01 0.74 0.67
Bubreak 448/Defoamer 3.00 0.44 0.25
(Premix n e x t 2 items)
L e t Down:
Rhoplex M V - 2 3 / A c r y l i c E m u l s i o n 483.46 54.94 40.32
Texanol/Ester Alcohol 5.00 0.63 0.42
Ethylene Glycol 30.03 3.23 2.50
Water 20.02 2.40 1.67
P a i n t P r o p e r t ies :
Total Vehicle 60.27
w
83.10
Pigment 39.73 16.90
Volatile 42.67 61.07
Organic Solvent 7.59 10.58
Non-Volati l e 57.33 38.93
N o n - V o l a t i 1e V e h i c l e 17.60 22.02
D e n s i t y ( l b / U . S . gal): 11.99
S p e c i f i c G r a v i t y : 1.44
P.V.C.: 43.42%
P/B R a t i o : 2.258
Spread @ 1 M i l : 624 F2
C o a t i n g VOC: 220 G/L
M a t e r i a l VOC: 109 G/L
&
J! Gal
P a r t A:
L i q u i d DGEBA Epoxy 233.7 24.093
MPA-1078 (Rheox) 4.0 0.541
Part B:
Ancamide 2353 ( A i r P r o d u c t s ) 125.54 15.212
M P A - 1 0 7 8 (Rheox) 4.0 0.541
B e e t l e 216-8 (Cyanamid) 15.0 1.724
P r o p e r t ies :
Volume Sol i d s : 71.8% VOC: <2.1 l b / g a l
PVC: 39.7% M i x i n g R a t i o : 1:l b y Volume
CPVC: 54.6% Pot L i f e , h r : 3
PVC/CVPC : 0.725 Dry t o Touch, h r : 1
W e i g h t / g a l l o n . P a r t A: 14.45 Dry Through, h r : 6
W e i g h t / g a l l o n , P a r t B: 12.45
W e i g h t / g a l l o n : 13.45
P a r t A* & @&
Dow XUS19000.01 Epoxy R e s i n 223.79 23.11
Benzyl Alcohol 11.17 1.28
Water 213.66 25.60
P a r t B:
Anquamine 401 C u r i n g Agent ( A i r P r o d u c t s ) 111.95 12.25
Water 80.05 9.59
G l a c i a l A c e t i c Acid ( A i r P roducts) 2.10 0.24
Red I r o n O x i d e * * 62.98 I .57
LVT 400 T a l c ( B a r r e t t ) 125.94 5.29
W a l l a s t o k u p I O E S (Nyco) 139.95 5.78
Z e o s p h e r e s 400 ( 3 M ) 62.98 3.43
H a l o x SZP 391 76.96 3.07
Dowanol PM S o l v e n t (Dow) 32.18 4.23
Dowanol PnP S o l v e n t (Dow) 33.59 4.55
Typical Properties:
W t S o l i d s (%): 65.96
Volume S o l i d s ( % ) : 5 1 . 1 7
PVC ( % ) : 3 7 . 4
Resin S t o i c h i o m e t r y : 1 .6:1
VOC ( l b / g a l ) : 1 . 2 1
VOC ( g / l ) : 1 4 5
A n t i c o r r o s i v e Primer P r o p e r t i e s :
Pot L i f e , h r : 4
Mix Ratio: 1 : l
Tack F r e e Time, h r : 1 . 0
H a r d D r y Time, h r : 6
VOC, l b / g a l : 1 . 2
Volume S o l i d s , %: 5 1
P V C , % : 37
Cross H a t c h Adhesion: 5
1 / 4 " M a n d r e l Bend: F a i 1
D i r e c t I m p a c t R e s i s t a n c e , in-1 b s : 20
D i r e c t I m p a c t R e s i s t a n c e , i n-1 b s : ( 5
Part A: !=&
Epi-Rez 3520-WY-55 Epoxy R e s i n ( S h e l l ) 342.6 37.65
Benzyl A l c o h o l 8.9 1.03
S u r f y n o l DF-58 Defoamer ( A i r P r o d u c t s ) 4.0 0.48
Water 61.6 7.39
Red I r o n Oxide 73.0 1.79
Barium S u l f a t e 72.8 1.99
l O E S W o l l a s t o k u p (Nyco) 109.4 4.52
Halox SW-1116 100.0 4.20
Zeosphere 4007 (3M) 73.0 3.65
Water Ground M i c a 10.3 0.44
H i g h speed d i s p e r s e t o a t e x t u r e of N . S . , t h e n add:
Part 8 :
Anquamine 401 C u r i n g Agent ( A i r Products) 60.7 6.58
Water 111.8 13.42
Typical Properties:
W t S o l i d s ( % I : 63.1
Volume S o l i d s ( % ) : 4 7 . 3
PVC ( % ) : 3 5 . 1
Resin S t o i c h i o m e t r y (on e q u i v a l e n t s ) : 1.6:1
VOC ( l b / g a l ) : 1.02
voc ( g / l ) : 122.5
A n t i c o r r o s i v e Primer P r o p e r t i e s :
Pot L i f e , h r : 4
Mix R a t i o : 4 : l
Tack F r e e Time, h r : 0 . 5
Hard D r y Time, h r : 6
VOC, l b / g a l : 1 . 0
Volume S o l i d s , %: 47
PVC, %: 35
Cross Hatch Adhesion: 4
P e n c i l Hardness, o v e r n i g h t : HB
P e n c i l Hardness, 7 days: H
1 / 4 ” Mandrel Bend: F a i l
D i r e c t Impact R e s i s t a n c e , i n - l b s : 35
Reverse Impact R e s i s t a n c e , i n - l b s : t5
C o s t E f f e c t i v e 2K Water-Base Epoxv P r i m e r
Usina H a l o x SW-111
M i x f o r 5 m i n u t e s and add t h e f o l l o w i n g w h i l e m i x i n g a t h i g h
speed :
A d d t h e f o l l o w i n g raw m a t e r i a l s i n o r d e r l i s t e d w h i l e m i x i n g a t
h i g h speed:
D i p p i na Primer
L e t Down:
Ucar V e h i c l e 443 500.0 57.52
Antifoam ( 2 ) 0.8 0.11
B u t y l C e l l o s o l v e Solvent 51.5 6.86
B u t y l C a r b i t o l Solvent 20.6 2.60
Hexamethoxymethylmelami ne ( 6 ) 54.7 5.47
Ammonium Benzoate, 10% Aqueous S o l u t i o n 8.5 0.93
Ammonium Hydroxide, 28% Aqueous S o l u t i o n 6.5 0.74
Oeioni zed Water 127.1 15.26
Suppliers:
( 1 ) Dispersant - Bykumen WS ( B y k - M a l l i n c k r o d t ) o r e q u i v a l e n t .
( 2 ) A n t i f o a m - Hodag PX-218 (Hodag) o r e q u i v a l e n t .
( 3 ) T i t a n i u m D i o x i d e - T i - P u r e R-960 (Du Pont) o r e q u i v a l e n t .
( 4 ) B a r y t e s - Sparmite ( P f i z e r ) o r equi v a l e n t .
( 5 ) S t r o n t i u m Chromate - 5-1365 (Oavis/MPC) o r e q u i v a l e n t .
( 6 ) Hexamethoxymethylmelamine - Cyme1 303 (American Cyanamid)
or equivalent.
Primer P r o p e r t i e s :
S o l i d s , % by w t : 37.4
pH: 9.5
V i s c o s i t y , B r o o k f i e l d , cP: 800
Primer Performance:*
Bake Cycle, min: S a l t Spray:
F l a s h Time: 10 Hours Exposed: 565
Bake a t 200F: 2.5 Rusting Rating: 9
F i n a l Bake a t 300F: 10 B l i s t e r R a t i n g : 9M
P e n c i l Hardness: 2H Creepage, i n : 1/8
Gloss, 60: 30
Impact Resistance, i n - l b :
D i r e c t : 45
Reverse: 5
* S u b s t r a t e - B o n d e r i t e 1000
E x p e r i m e n t a l General Purpose T a n n i n - S t a i n R e s i s t a n t
Water-Base P r i m e r U s i n a H a l o x X t a i n A
H i g h speed d i s p e r s e t o 4+ NS g r i n d .
Letdown :
Mor-Lok 1035 467.00 560.40
Skane M-8 2.00 2.40
Aqua Ammonia (28%) 1 .oo 1.20
Texanol 5.00 6.00
Foamaster VL 1 .oo 1.20
Formula C o n s t a n t s : Formula P r o p e r t i e s :
..
% P i gment/Wt : 34.36
% Pigment/Vol : 15.03
D e n s i t y l b s . / g a l . : 1 .23
Density gms./i.: 1,346.7
% Solids/Wt.: 55.81 PH @ R. . : 9.0-9.5
% S o l i d s / V o l . : 40.73 KU V i s c @ R . T . : 95-100
% PVC: 36.89
VOC, l b s . / g a l . : 1.10
VOC, g m s . / l . : 132.04
E x D e r i r e n t a 1 H i ph Performance Tanni n - S t a i n R e s i s t a n t
Water-Base P r i m e r U s i n a H a l o x X t a i n A
H i g h speed d i s p e r s e t o 4+ NS g r i n d
Water 25.00 30.00
Letdown :
Mor-Lok 1043 434.00 520.80
Skane M-8 2.00 2.40
Aqua Ammonia (28%) 1 .oo 1.20
Texanol 4.75 5.70
Foamaster VL 1 .oo 1.20
Add t h e f o l l o w i n g w h i l e m i x i n g and m i x u n t i l u n i f o r m .
Formula C o n s t a n t s : Formula P r o p e r t i e s :
.
% P i gment/Wt : 37.60 D e n s i t y 1b s . / g a l . : 11.51
% P i gment/Vol : 17.11. D e n s i t y gms. /l. : 1,381.2
% S o l i d s / W t . : 57.21 pH @ R . T . : 9 . 0 - 9 . 5
% S o l i d s / V o l . : 41.18 KU V i s c . @ R.T.: 90-95
% PVC: 41.55
VOC, l b s . / g a l . : 1.13
VOC, g m s . / l . : 134.92
E x p e r i m e n t a l Waterbase A c r y l i c Red I r o n O x i d e P r i m e r
H i g h speed d i s p e r s e t o 4+ NS g r i n d .
Letdown :
Mai n c o t e HG-54 510. 0 612.0
Texanol 4. 0 4.8
Dibutyl Phthalate 12 9 15.5
Drew L-493 3 5 4.2
Aqua Ammonia (28%) 1 5 1.8
Raybo 60 5 0 6.0
M i x u n t i l uniform.
Formula C o n s t a n t s : Formula P r o p e r t i e s :
% Pigment/Wt.: 31.58 Density lbs./gal.: 10.63
% Pigment/Vol.: 13.81 D e n s i t y g / L : 1,275.9
% S o l i d s / W t . : 52.35 KU V i s c . B R . T . : 90-95
% S o l i d s / V o l . : 38.97 pH @ R.T.: 8.0-9.0
?6 PVC: 35.41
VOC, l b s . / g a l . : 1.72
VOC. g/L: 206.40
E x p e r i m e n t a l W a t e r b a s e A c r y l i c Red Iron O x i d e P r i m e r
Grind: ~ _ ______
Pounds Gallons
Water 63.00 7.56
Methyl Carbi t o 1 52.00 6.11
Tamol 165 12.30 1 .26
T r i t o n CF-10 3.00 0.34
Drew L-493 1 .oo 0.14
Red I r o n O x i d e 57.40 1.34
S n o w f 1a k e 192.60 8.56
H a l o x BW-191 100.00 4.21
L e t Down:
Mai n c o t e HG54 510.00 60.00
Texanol 4.00 0.50
O i butyl Phthalate 12.90 1.48
Drew L-493 3.60 0.50
Ammoni um H y d r o x i d e 2 8% 1.70 0.24
Sodium N i t r i t e 8.40 1.01
Water 49.00 5.90
U c a r T h i c k e n e r SCT 2 0 0 7.50 0.85
D e n s i t y l b s / g a l : 10.78
% W t . Solids: 53.5
% V o l . S o l i d s : 40.0
% PVC: 3 5 . 0
V i s c o s i t y : 9 0 - 9 5 KU @ 7 7 F
E x D e r i m e n t a l W a t e r b a s e A c r y l i c Red I r o n O x i d e P r i m e r
H i g h speed d i s p e r s e t o 4 + NS g r i n d
Water 25.0 30 0t
Letdown :
Mai n c o t e HG-54 .310.0 612.0
Texanol 4.0 4.0
Dibutyl Phthalate 12 9 15.5
Drew L - 4 9 3 3.5 4.2
A q u a Ammonia ( 2 8 % ) 1.5 1.8
Raybo 6 0 5.0 6.0
Add g r i n d p o r t i o n u n d e r a g i t a t i o n and m i x u n t i l u n 7 f o r m .
Mix a n t i i u n i f o r m
SOURCE: H a l o x P i g m e n t s : S u g g e s t e d F o r m u l a t i o n HG54-491
138 Water-Based Paint Formulations
E x t e r i o r House P a i n t P r i m e r
Letdown :
Water ) 8.3 1 .oo
Ucar Polyphobe 102 )Premix 8.7 1 .oo
Ucar L a t e x 625 508.6 57.80
C o l l o i d 640 1.9 0.25
B u t y l C a r b i t o 1 Sol v e n t 12.7 1.60
NuoCi de 404-D 10.3 1 .oo
T r i t o n N o n i o n i c S u r f a c t a n t CA 2.1 0.25
Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n 1.9 0.25
Paint Properties:
Pigment Volume C o n c e n t r a t i o n , %: 3 2 . 0
Volume S o l i d s , % : 4 0 . 0
Weight S o l i d s , %: 54.5
Viscosity, equilibrated:
Stormer, KU: 90
I C I , Poise: 1.45
Freeze-Thaw S t a b i l i t y , c y c l e s passed: 3
Heat-Aged S t a b i l i t y , 120F, weeks passed: 2
F i l m Properties:
C o n t r a s t R a t i o , 6 - m i l wet drawdown: 0.96
Ref 1e c t a n c e , %: 8 8 . 3
Sheen, 85: 1 9 . 9
Tannin S t a i n Resistance:
Cedar and Redwood: Very Good
I n q r e d ie n t s : Pounds
~~ Gal l o n s
Pigment G r i n d :
Water 244.7 29.37
C e l l o s i z e H y d r o x y e t h y l C e l l u l o s e ER-30,000 3.5 0.32
Nuosept 95 2.3 0.25
Col 1o i d 226/35 10.5 I .oo
C o l l o i d 640 1.9 0.25
T r i t o n N o n i o n i c S u r f a c t a n t N-101 2.1 0.25
Propylene G l y c o l 25.9 3.00
Tronox CR-828 125.0 3.65
N i c r o n 400 T a l c 113.5 4.76
Halox EW-100 100.0 4.37
Letdown :
Ucar L a t e x 163 437.5 49.16
Ucar F i l m e r IET 12.7 1.60
C o l l o i d 640 1.9 0.25
NuoCi de 404-D 10.3 1 .oo
T r i t o n N o n i o n i c S u r f a c t a n t CA 2.1 0.25
Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n 3.8 0.50
Paint Properties:
Pigment Volume C o n c e n t r a t i o n , %: 3 2 . 0
Volume S o l i d s , %: 40.0
Weight S o l i d s , %: 54.0
Weight p e r G a l l o n , l b : 1 1 . 0
Stormer, K U : 86
I C I . p o i s e : 1 .O
pH, i n i t i a l : 8 . 5
Freeze-Thaw S t a b i l i t y , 3 c y c l e s : Pass
Heat S t a b i l i t y , 2 weeks a t 120F: Pass
Film Properties:
R e f l e c t a n c e , %: 8 8 . 3
Sheen, 85: 1 1 . 6
C o n t r a s t R a t i o , 6-mil b a r : 0.96
T a n n i n S t a i n R e s i s t a n c e c e d a r and redwood: Very Good
Ingredients:
- !& Gal Wt%
Pigment Grind:
Water 105.91 12.71 9.28
Busperse 39/Dispersant 8.47 0.79 0.74
Bubreak 448/Defoamer 3.18 0.47 0.28
(Premix next 2 items)
Water 26.48 3.18 2.32
QP-15000 Cellosize/Hydroxyethyl
Cell ul ose 1.06 0.09 0.09
Igepal CTA 639/Surfactant 6.35 0.72 0.56
Aropl az 1271 /Long Oi 1 A1 kyd 40.47 4.82 3.55
Butrol 23/Modified Barium MetaboratelO5.91 3.44 9.28
Ti -Pure R-SOO/Ti tani um Dioxide-
Rutile 211.83 6.36 18.56
Mi ca-325/Potassi um A1 umi num Si 1 i cate 26.48 1.13 2.32
Atomite/Calcium Carbonate 17.71 0.78 1.55
Nytal 3OO/Talc-Magnesium Silicate 17.71 0.75 1.55
Let Down:
Rhoplex MV23/Acrylic Emulsion 511.57 58.13 44.82
Texanol/Ester Alcohol 5.30 0.67 0.46
Ethylene Glycol 31 .77 3.41 2.78
Water 21 .18 2.54 1 .86
Letdown :
Water 93.0 111 . 6
Mai n c o t e PR-71 380.0 456.0
Dibutyl Phthalate 5.7 6.8
Aqua Ammonia ( 2 8 % ) 3.0 3.6
Add s l o w l y w h i l e m i x i n g a t h i g h s p e e d . Do n o t a e r a t e !
Mix u n t i l uniform.
SOURCE: H a l o x P i g m e n t s : S u g g e s t e d F o r m u l a t i o n PR-71/491A
142 Water-Based Paint Formulations
Letdown :
Water 112.0 134.5
Mai n c o t e PR-7 470.0 564.0
D i b u t y l Phtha a t e 7.0 8.4
Aqua Ammonia 28%) 3.0 3.6
Add s l o w l y w h i l e m i x i n g a t h i g h speed. Do n o t a e r a t e !
Mix u n t i l uniform.
Formula C o n s t a n t s : Formula P r o p e r t i e s :
% P i gment/Wt. : 22.51 .
D e n s i t y Lbs / g a l . : 1 0 . 0 0
.
% P i gment/Vol : 8 . 7 6 D e n s i t y g / L : 1,199.7
% S o l i d s / W t . : 47.26 KU V i S c . @ R.T.: 90-95
% S o l id s / V o l . : 35.78 PH @ R.T.: 9 . 0 - 9 . 5
% PVC: 24.48
VOC, l b s . / g a l . : 1.85
VOC, g / L : 222.13
Letdown :
Water 106.5 128.0
Mai ncote PR-71 470.0 564.0
Dibutyl Phthalate 7.0 8.4
Aqua Ammonia (28%) 3.0 3.6
Add grind portion under agitation and mix until uniform. Then add
the following in order listed:
Ethanol 95% 18.0 21 . 6
Raybo 60 5.0 6.0
M i x f o r 5 m i n u t e s a n d add t h e f o l o w i n g w h i l e m i x i n g a t h i g h
speed.
H i g h s p e e d d i s p e r s e t o 5 + Hegman g r i n d . Then a d d t h e f o l l o w i n g
s l o w l y w h i l e m i x i n g . DO NOT AERATE'
Add t h e f o l l o w i n g r a w m a t e r i a l s i n o r d e r l i s t e d w h i l e m i x i n g a t
h i g h speed:
SOURCE: H a l o x P i g m e n t s : S u g g e s t e d F o r m u l a t i o n E p i - R e z / B B l
Primers 145
M i x f o r 5 m i n u t e s and add t h e f o l l o w i n g w h i l e m i x i n g a t h i g h
speed.
Formula C o n s t a n t s : Formula P r o p e r t i e s :
% P i gment/Wt : . 36.75 .
D e n s i t y 1b s . / g a l : 11 .56
% Pigment/Vol. : 15.80 Density g/L: 1,387.2
% Solids/Wt.: 60.10 Set-to-touch: 30 m i n u t e s
.
% S o l id s / V o l : 43.96 D r y Hard: Overnight
% PVC: 35.93
P/B R a t i o : 1.57
VOC, l b s . / g a l . : 1.57
voc, g/L: 188.40
SOURCE: H a l o x P i g m e n t s : Suggested F o r m u l a t i o n
146 Water-Based Paint Formulations
H i g h P e r f o r m a n c e 2 K Water-Base Epoxy P r i m e r
U s i n q H a l o x SZP-391
M i x f o r 5 m i n u t e s and add t h e f o l l o w i n g w h i l e m i x i n g a t h i g h
speed :
Add t h e f o l l o w i n g raw m a t e r i a l s i n o r d e r l i s t e d w h i l e m i x n g a t
h i g h speed:
M a t e r i a1 : Pounds Gal l o n s
P a r t A:
Epon R e s i n 874-CX-90 263.0 28.85
B e e t l e 216-8 12.0 1.41
S h e l l Xylene 75.5 10.49
S h e l l MIBK 60.4 9.10
PGME A c e t a t e 15.1 1.86
Z i n c Phosphate 5-0852 176.5 6.74
10 ES W o l l a s t o k u p 176.5 7.29
Sparmi t e 233.5 6.35
M i c r o M i c a C-3000 38.8 1.36
Copperas R-5098 38.7 0.90
H i g h Speed D i s p e r s e t o a T e x t u r e o f 5-6 N . S
Bentone SD-2 9.3 0.65
P a r t B:
E p i - C u r e C u r i n g Agent 3140 132.0 16.32
S h e l l Xylene 42.9 5.95
She1 1 n - B u t a n o l 18.4 2.73
Composite B l e n d :
Part A 1099.3 75.00
Part B 193.3 25.00
P a r t s A and B: V i s c o s i t y : 85 K . U .
F i 1m P r o D e r t i es :
(Drawdown on CRS. Cured f o r 7 days a t 77F, 55% R.H.)
Pigment: b i n d e r r a t i o : 1.72
C u r i n g agent p h r , on s o l i d s : 56
P o t l i f e ( h r s ; f r o m 85-130 K U ) : 6
Pounds/gallon: 12.92
Dry f i l m t h i c k n e s s : 1.5 m i l s
Set-to-touch dry, h r s . : 1.0
Cotton-free dry, h r s . : 7.5
Through-dry, h r s . : 18.0
P e n c i l hardness: H
I m p a c t r e s i s t a n c e , ( D i r . /Rev. ) : 52/4
F l e x i b i l i t y : Pass 1 / 4 "
A d h e s i o n : SA
S a l t s p r a y t e s t i n g (500 h r s ) : 2F-2M
Water r e s i s t a n c e (500 h r s a t 160F): 4M
House P a i n t P r i m e r
Letdown :
Pai n t P r o p e r t ies :
Pigment Volume C o n c e n t r a t i o n , %: 3 0 . 0
Volume S o l i d s , %: 32.6
V i s c o s i t y , e q u i 1 ib r a t e d :
Stormer, KU: 80
I C I , poise: 0.7
Weight p e r G a l l o n , l b : 1 0 . 5 4
Freeze-Thaw S t a b i l i t y , 3 c y c l e s : Pass
Heat-Aged S t a b i l i t y , 2 weeks a t 120F: Pass
F i l m Properties:
C o n t r a s t R a t i o , 6 - m i l wet drawdown: 0.948
R e f 1ectance, %: 88.7
Sheen, 85: 7 . 0
Flow and L e v e l i n g , brushed: Good
Wet Adhesion: E x c e l l e n t
C h a l k Adhesion: E x c e l l e n t
H i g h speed d i s p e r s e t o a t e x t u r e o f 6-7 N . S .
P a r t B:
E p i - C u r e 8290-Y-60 C u r i n g Agent 60.0 6.80
Water 11.0 1 .32
Zeeosphere 400 100.0 5.00
Water Ground M i c a , 325 mesh 10.0 0.43
Composite B l e n d : Viscosity
Part A 114 K . U . 957.3 80.00
Part B 101 K.U. 234.7 20.00
P a r t s A and B 106 K . U .
Material : =!&
, Gals
Part A:
Epi -Rez 5522-WY-55 R e s i n 330.0 37.21
Oiacetone A l c o h o l 7.0 0.89
Col 1 o i d 640 Defoamer 3.5 0.41
Water 80.0 9.60
R0-4097 Kroma Red 100.0 2.45
Sparmi t e 100.0 2.73
1OES Wol 1a s t o k u p 150.0 6.19
Halox SW-111 50.0 2.10
H i g h speed d i s p e r s e t o a t e x t u r e o f 5-6 P . C . S
Part 8 :
Epi-Cure 8290-Y-60 C u r i n g Agent 60.0 6.80
Water 11.0 1.32
Zeeosphere Type 400 100.0 5.00
Water Ground Mica, 325 mesh 10.0 0.43
Water 53 6.45
H i g h speed d i s p e r s e t o t e x t u r e o f 5-6 N . S .
P a r t 9:
Epi-Cure 8292-Y-60 C u r i n g Agent 60.0 6.80
Water 11c.o 13.20
Lead Based . P r i m e r
B l e n d w e l l and a d d :
Red I r o n O x i d e 100.0 2.34
B a s i c Lead S i l i c o Chromate 100.0 2.93
C e l l t e 499 D i a t o m a c e o u s E a r t h 25.0 1.30
-
Maonesi um S i 1 1 c a t e
I n c r e a s e d i s p e r s e r speed t o 3 , 0 0 0 RPM. A c h i e v e
25.0 1 .05
grind fineness
o f 6 - 7 PCS. Add u n d e r r e d u c e d a g i t a t i o n :
E p i -Rez 3520-WY-55 R e s i n 260.0 30.00
Tap Water 297.0 35.68
P a r t B:
E p i - C u r e 8536-MY-60 C u r i n g Agent 124.5 15.00
C o m p o s i t e B1 end :
Part A 904.6 85.00
Part 8 124.5 15.00
P e b b l e m i l l a p p r o x i m a t e l y 18 h o u r s
P a r t 8:
Epi -Cure 8290-Y-60 C u r i n g Agent 45.3 5.13
Water 35.0 4.20
Zeeospheres Type 400 150.0 7.50
H i g h speed d i s p e r s e t o a t e x t u r e o f 6 PC
R e s i n C o m p o s i t i o n (based on s o l i d s ) :
Epoxy R e s i n , %: 9 0 . 0
C u r i n g Agent, %: 1 0 . 0
T o t a l , %: 1 0 0 . 0
R e d u c t i o n f o r C o n v e n t i o n a l Spray ( b y v o l u m e ) :
P a r t s A and B: 20 p a r t s
Water: 1 part
P a r t 8:
Epi -Cure 8290-Y-60 C u r i n g Agent 82.1 9.30
Kronos 2020 191 . o 5.58
SP B l a c k 4 Powder 0.3 0.02
P a t c o t e 847 Def amer 2.0 0.28
Water 25.0 3.00
T y p i c a l C o a t i nQ P r o o e r t ies :
T o t a Weigh: Sol;ds, %: 51.1
T o t a Weight S o l i d s , %: 39.5
PVC , %: 14.2
V o l a i l e O r g a n i c Compounds (VOC):
Pounds/Gallon: 1 .51
G r a m s / L i t e r : 181
I n d u c t i o n Time, m i n u t e s : 30
R e d u c t i o n f o r C o n v e n t i o n a l Spray ( b y volume):
( V i s c o s i t y = 55 K.U.)
P a r t s A and B : 11 p a r t s
Water: 1 part
#on-Lead/Non-Chromate Primer
Material : Lbs. Gals.
Water 83.89 10.06
I g e p a l CO-630 2.54 0.29
QP-4400 0.87 0.07
Tamol 731 10.70 1.23
Foamaster VL 1.10 0.14
S u r f y n o l 104H 1.66 0.21
D i e t h y l e n e G l y c o l Monomethyl E t h e r 35.32 4.14
T i t a n o x 2101 58.50 1.75
Raven 1020 0.65 0.03
H a l o x BW-191 148.69 6.27
Premix:
Dalpad A 13.24 1.43
Water 58.26 6.99
Premix:
A r o p l a z 1271 37.99 4.54
Cobalt Hydrocure I 1 3.79 0.49
C a l c i um Hydrocem 3.79 0.46
Z i r c o n i um Hydrocem 1.88 0.22
Then add:
S u r f y n o l 104H 3.31 0.17
Skane M-8 2.20 0.15
Premi x :
OR-708 0.17 0.02
Water 2.26 0.26
Analysis:
Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 18.85
P i g m e n t / B i n d e r R a t i o : 0.69/1
P e r c e n t S o l i d s , Weight : 50.54
P e r c e n t S o l i d s , Volume: 3 4 . 5 2
V i s c o s i t y C 25C, KU: 85-89
Gloss (60): F l a t
Pounds/Gallon: 10.08
pH: 8 . 7 - 9 . 2
VOC ( e x c l u d i n g w a t e r ) :
G r a m s / L i t e r : 70.8
Pounds/Gallon: 0 . 6
P r i m e r f o r F a c t o r y - P r i med Hardboard S i d i ng
Letdown :
Ucar V e h i c l e 462 325.0 37.0
Ucar A c r y l i c 515 118.2 13.0
Cyme1 325 31.3 3.0
Foamaster VF 0.9 0.1
Nuocide 960 5.1 0.6
A r c o s o l v e PP S o l v e n t 31 . 3 3.0
Propylene Glycol 35.3 4.3
Paint Properties:
Pigment Volume C o n c e n t r a t i o n , %: 42
C r o s s l i n k e r , p h r : 12
C o s o l v e n t , p h r : 15
Volume S o l i d s , %: 40
Weight p e r G a l l o n , l b : 11.2
Component 8 :
Waterpoxy 701 100.00 11.17
E k t a s o l v e EP 10.40 1.37
Formulation Constants:
Component B:
Waterpoxy 701 100.00 11.17
E k t a s o l v e EP 10.40 1.37
Formulation Constants
_Henkel's
_ ~ _ -Waterpoxy 1 4 0 1 : 7 0 1 System
Component 0 :
Waterpoxy 7 0 1 100.00 11.17
Ektasolve EP 10.40 1.37
Formulati on Constants
Non Volatile by Weight: 0.70 VOC grms/litre: 236.82
Non Volatile by Volume: 0.53 VOC 1bs. /gal . : 1.98
PVC : 0.36 Weight/Gallon Comp A : 13.01
cpvc: 0.55 Weight/Gallon Comp 6 : 8.80
PVC/CPVC : 0.67 Mixing Ratio: 6.97
Pigment Content: 0.44 Weight per Gallon: 12.48
NVV by Wt. o f Vehicle: 0.47
Component B:
Waterpoxy 701 100.00 11.17
E k t a s o l v e EP 10.40 1.37
F o r m u l a t i o n Constants
Component 9 :
Waterpoxy 701 100.00 11.17
E k t a s o l v e EP 10.40 1.37
Formulation Constants
Non V o l a t i l e b y Weight: 0.70 VOC g r m s / l i t r e : 236.82
Non V o l a t i l e bv Volume: 0 . 5 3 VOC l b s . / a a l . 3 : 1.98
PVC : 0 . 3 6 W e i g h t / G a i l o n Comp A : 1 2 . 7 6
CPVC : 0 . 5 5 W e i g h t / G a l l o n Comp 8: 8.80
PVC/CPVC : 0.66 M i x i n g R a t i o : 6.97
Pigment C o n t e n t : 0 . 4 3 Weight p e r G a l l o n : 12.26
NVV b y W t . of V e h i c l e : 0.47
Component 0:
Waterpoxy 702 45.28 5.27
E k t a s o l v e EP 23.41 3.08
Formulation Constants
Non V o l a t i l e by W e i g h t : 0.69 VOC g r m s / l i t r e : 237.36
Non V o l a t i l e b y Volume: 0.51 VOC l b s . / g a l . : 1.98
PVC : 0.39 W e i g h t / G a l l o n Comp A : 12.86
CPVC : 0.50 W e i g h t / G a l l o n Comp B: 8.23
PVC/CPVC : 0.79 Mixing Ratio: 10.47
Pigment C o n t e n t : 0.45 Weight p e r G a l l o n : 12.45
NVV by W t . o f V e h i c l e : 0.44
P r i m e r 211051 Based O n N a l z i n 2
and 10 ES W o l l a s t o c o a t
Henkel 's Waterpoxy 1401 :702 System
Component 8 :
Waterpoxy 702 45.28 5.27
E k t a s o l v e EP 23.41 3.08
F o r m u l a t i o n Constants
Component A: *L
Waterpoxy 1401 453.17 50.07
E k t a s o l v e EP 10.47 1.38
10 ES W o l l a s t o c o a t 256.20 10.59
Red I r o n O x i d e 5-3106 137.75 3.31
S t r o n t i u m Chromate 166.40 5.27
Component B :
Waterpoxy 702 68.04 7.91
E k t a s o l v e EP 35.18 4.64
Formulation Constants
H i g h Speed D i s p e r s e t o a T e x t u r e o f 5-6 N . S
P a r t B:
Epi-Cure 8290-Y-60 C u r i n g Agent 46.7 5.29
Water 8.6 1.03
Zeeosphere 400 t y p e 77.0 3.89
Water Ground Mica, 325 Mesh 7.7 0.33
H i g h Speed D i s p e r s e t o a t e x t u r e o f 4-5 N . S
Res4 n ComDosi t i on :
Epoxy R e s i n , %: 8 9 . 6
C u r i n g Agent, %: 1 0 . 4
R e d u c t i o n t o Spray V i s c o s i t y : None r e q u i r e d
H i g h Speed M i x f o r 15 m i n u t e s
H i g h Speed D i s p e r s e t o a t e x t u r e of 5-6 N . S .
M a t e r i a l P a r t 8:
Epi -Cure 8292-Y-60 C u r i n g Agent 27.0 3.08
E k t a s o l v e EP 37.9 5.00
Water 99.3 11.92
Composite B l e n d : Viscosity
Part A 102 K . U . 921.4 80.00
Part 8 1 0 . 5 secs ( F o r d #4) 164.2 20.00
P a r t s A and 8 68 K . U .
Red I n h i b i t i v e M a i n t e n a n c e P r i m e r
Letdown :
Methyl C a r b i t o l Solvent 8.5 1 .oo
A c r y s o l SCT-275 8.6 1 .oo
Ucar V e h i c l e 435 505.1 58.06
Ucar F i l m e r I B T 11.4 1.44
T r o y s a n Polyphase AF-1 4.9 0.50
Foamex 825 2.1 0.25
Sodium N i t r i t e , 15% Aqueous S o l u t i o n 9.0 1.08
Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n 1.8 0.25
A d j u s t t o minimum pH 8 . 7
Paint Properties:
Pigment Volume C o n c e n t r a t i o n (PVC), %: 30.0
T o t a l S o l i d s , %:
b y volume: 34.0
pH Value, i n i t i a l : 8 . 7
Viscosity:
Stormer. KU: 80
I C I , poise: 0.7
Weight p e r G a l l o n , l b : 1 0 . 4
Freeze-Thaw S t a b i l i t y , 3 c y c l e s : Pass
Heat S t a b i l i t y , 2 weeks a t 140F: Pass
Red I r o n O x i d e C o r r o s i o n R e s i s t a n t EPOXY P r i m e r
(Two Component System)
Ingredients: -
Lb
( P r e p a r e P a r t # l & P a r t #2 s e p a r a t e l y )
P a r t #l
E p o t u f 37-618/Epoxy R e s i n Hardener 147.91 18.96 13.41
Xylol/Xylene 95.36 13.19 8.65
Ye1 k i ns-TS/Soya L e c i t h i n 3.89 0.46 0.35
B u t r o l 2 3 / M o d i f i e d B a r i u m Meta-
borate 194.62 6.32 17.65
Red I r o n O x i d e 194.62 4.98 17.65
N y t a l 300/Talc-Magnesium S i l i c a t e 18.49 0.78 1.68
P a r t #2:
E p o t u f 38-501/Epoxy R e s i n 272.91 30.29 24.74
M e t h y l I s o b u t y l Ketone 70.06 10.49 6.35
X y l o l /Xylene 105.10 14.54 9.53
M i x t w o components i n 1 : l r a t i o and w a i t f o r 30 m i n u t e s b e f o r e
paint application.
P a i n t P r o p e r t i es : %Wt %vel
Total Vehicle 63.03 87.92
Pigment 36.97 12.08
Vol a t i 1e 35.09 74.41
Organi c S o l v e n t 35.09 74.41
Non-Vol a t i1e 64.91 25.59
N o n - V o l a t i l e Veh c l e 27.94 13.52
D e n s i t y ( l b / U . S . g a l ) : 11.03
Specific Gravity 1.32
P.V.C.: 47.19%
P / B R a t i o : 1.323
Spread @ 1 M i l : 411 F2
C o a t i n g VOC: 464 G/L
M a t e r i a l VOC: 464 G/L
Red I r o n O x i d e P r i m e r
Material : Pounds _G a l l o_
~ ns _
P a r t A:
2-Propoxyethanol 11.6 1.50
T r i t o n X-100 S u r f a c t a n t 3.5 0.39
Tamol 731 S u r f a c t a n t 3.5 0.38
91 48 Defoamer 4.0 0.48
Bentone LT, 3% i n w a t e r 75.0 8.95
B l e n d w e l l and add:
P a r t B:
Epi -Cure 8536-MY-60 C u r i ng Agent 124.5 15.00
Composite 81 end :
Part A 893.6 85.00
Part 8 124.5 15.00
Red I r o n Oxide P r i m e r
Ingredients: -
Lb __
Ga 1 Wt%
P i Oment O r in d :
Water 117.69 14.13 11.77
Busperse 3 9 / D i s p e r s a n t 5.65 0.53 0.56
Bubreak 448/Defoamer 2.82 0.42 0.28
Zinc S u l fate-Heptahydrate 1.88 0.11 0.19
I g e p a l CTA 6 3 9 / S u r f a c t a n t 2.82 0.32 0.28
( M i x 10 m i n u t e s and add)
B u t r o l 23/Modi f ie d B a r i um Meta-
borate 47.08 1.53 4.71
Red I r o n O x i d e 94.15 2.41 9.42
N y t a l 300/Talc-Magnesi um S i 1 ic a t e 94.15 3.97 9.42
L e t Down:
( P r e m i x a l l t h e f o l l o w i n g i n g r e d i e n t s and t h en add t o t h e g r i n d )
Beckosol 13-402/Water R e d u c i b l e
A1 k y d 282.46 32.84 28.25
Butyl Cellosolve 84.74 11.28 0.47
Ammonium Hydroxide-28% 22.60 3.01 2.26
Water 233.50 28.03 23.35
A c t iv - 8 / D r i e r 0.94 0.12 0.09
C o b a l t Naphthenate-G%/Drier 1.88 0.26 0.19
Z i r c o n i urn 6%/Dri e r 5.65 0.79 0.56
A n t i s k i n n i n g Agent 1.88 0.25 0.19
D e n s i t y ( l b / U . S . g a l ) : 10.00
Speci f ic G r a v i t y : 1 .20
P.V.C.: 25.50%
P/B R a t i o : 1.093
Spread @ 1 M i l : 505 F2
C o a t i n g VOC: 403 G/L
M a t e r i a l VOC: 233 G/L
Red I r o n O x i d e Water R e d u c i b l e A l k v d P r i m e r
Inqredients: -
Lb Gal Wt%
Pigment G r i n d :
Water 154.98 118.60 14.64
Busperse 3 9 / D i s p e r s a n t 5.81 0.54 0.55
Bubreak 448/Oefoamer 2.91 0.43 0.27
I g e p a l CTA 6 3 9 / S u r f a c t a n t 2.91 0.33 0.27
Zinc S u l f a t e - H e p t a h y d r a t e 1.94 0.12 0.18
B u t r o l 2 3 / M o d i f i e d B a r i u m Meta-
borate 48.43 1.57 4.57
Red I r o n O x i d e 98.86 2.48 9.15
N y t a l 300/Talc-Magnesium S i l i c a t e 193.72 8.17 18.30
L e t Down:
( P r e m i x a l l t h e f o l l o w i n g i n g r e d i e n t s and t h e n add t o t h e g r i n d . )
C a r g i l l 7464/Water R e d u c i b l e A l k y d 248.93 28.78 23.51
Secondary B u t y l A l c o h o l 86.21 12.81 8.14
Ammonium Hydroxide-28% 9.69 1.29 0.91
Water 200.50 24.07 18.94
Cobalt Naphthenate-6%/Orier 1.94 0.26 0.18
Z i r c o n i um 6%/Dri e r 3.87 0.54 0.37
P a i n t P r o p e r t i as:
Total Vehicle 67. ao 87.66
Pigment 32.20 12.34
V o l a t i 1e 49.71 67.42
Organic Solvent 16.14 24.74
Non-Vol a t i 1e 50.29 32.58
Non-Volatile Vehicle 18.08 20.24
D e n s i t y ( l b / U . S . g a l ) : 10.59
S p e c i f i c G r a v i t y : 1.27
P.V.C.: 37.88%
P/B R a t i o : 1.781
Spread I3 1 M i l : 523 F2
C o a t i n g VOC: 357 G/L
M a t e r i a l VOC: 205 G/L
Analysis:
Pigment/Binder Ratio: 1.37/1
Pounds/Gallon: 11.33
Percent Nonvolatile, Weight: 58.5
Percent Nonvolatile, Volume: 43.4
Pigment Volume Concentration, Percent: 31 .O
pH: 8.8
Viscosity @ 25C, KU: 75-78
60/20 Gloss: Flat
Grind Hegman: 4-5
VOC (excluding water):
Grams/Li ter : 1 1 3.0
Pounds/Gallon: 0.94
SOURCE: Reichhold Chemicals, Inc.: Arolon 820: Formula 5-3
Primers 173
P e b b l e m i l l a p p r o x i m a t e l y 18 h o u r s
P a r t 6:
E p i - C u r e 8290-Y-60 C u r i n g Agent 118.3 13.40
Water 55.0 6.60
Composite B l e n d : Viscosity
Part A 64 K.U. 938.1 80.00
Part 0 58 K . U . 173.3 20.00
Parts A t B 85 K . U .
R e s i n C o m p o s i t i o n (based on s o l i d s ) :
Epoxy R e s i n , %: 75.0
C u r i n g Agent, %: 25.0
T o t a l , %: 100.0
R e d u c t i o n f o r C o n v e n t i o n a l Spray ( b y volume):
P a r t s A and 6 : 36 p a r t s
Water: 1 part
L e t Down:
B u t y l C a r b i t o l Solvent--Premix w i t h : 7.2 0.9
Ucar T h i c k e n e r SCT-275 8.2 1 .o
Ucar L a t e x 163 423.6 47.6
A n t i f o a m (4) 4.8 0.6
Mildewcide (IO) 5.8 0.6
Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n 9.0 1.2
Suppl ie r s :
(1) Dispersant - C o l l o i d l l l M ( C o l l o i d s ) o r e q u i v a l e n t .
(2) N o n i o n i c S u r f a c t a n t - T r i t o n CF-10 (Rohm and Haas) o r
equivalent.
(3) B u f f e r - AMP 95 (Angus) o r e q u i v a l e n t .
(4) A n t i f o a m - C o l l o i d 770 ( C o l l o i d s ) o r e q u i v a l e n t .
(5) P r e s e r v a t i v e - Nuosept 95 ( H u l s ) o r e q u i v a l e n t .
(6) T i t a n i u m D i o x i d e - T i - P u r e R-900 (DuPont) o r e q u i v a l e n t .
(7) I n h i b i t i v e Pigment - N a l z i n 2 (NL Chemicals) o r e q u i v a l e n t
(8) M i c a - 325 WG M i c a (KMG M i n e r a l s ) o r e q u i v a l e n t .
(9) C a l c i u m Carbonate - Snowflake (Thompson, Weinman) o r
e q u i Val e n t .
(IO) M i l d e w c i d e - Polyphase AF-1 ( T r o y ) o r e q u i v a l e n t
Paint Properties:
Pigment Volume C o n c e n t r a t i o n (PVC), %: 27.9
T o t a l S o l i d s , % b y Volume: 36.5
U n i v e r s a l Primer
Letdown :
Butyl C a r b i t o l Solvent 21.2 2.66
Ucar L a t e x 461 521.2 59.91
A r c o s o l v PNB 1 10.1 1.37
Ucar F i l m e r I B T ) Premix 10.1 1.27
S a n t i c i z e r 160 ) 2.3 0.24
Sodium N i t r i t e ) Premix 2.4 0.14
Water 1 20.2 2.42
Water 10.7 1.28
Ammoni um H y d r o x i d e , 28% Aqueous Sol u t i on 1.5 0.20
Ucar Polyphobe 102 Rheology M o d i f i e r 5.5 0.59
P a i n t P r o p e r t i es :
Pigment Volume C o n c e n t r a t i o n , %: 2 2 . 4
Volume S o l i d s , %: 38.0
Weight S o l i d s , %: 4 9 . 5
Weight p e r G a l l o n , l b : 10.2
Stormer, KU: 85
I C I , Poise: 0.9
pH v a l u e : 8.5-9.5
Freeze-Thaw S t a b i l i t y , c y c l e s passed: 5
Heat-Age S t a b i l i t y , 120F, weeks passed: 4
VOC, grams p e r l i t e r : 225
Film Properties:
Sheen, 85: 5 max
P r o h e s i o n C o r r o s i o n W e a t h e r i n g C y c l e , h o u r s passed: 800
C l e v e l a n d H u m i d i t y , h o u r s passed: 800
T a n n i n g / S t a i n i n g R e s i s t a n c e : Good
Tape Adhesion (ASTM 0-33): E x c e l l e n t
S a l t Fog, h o u r s : 48 max
Universal Primer
Non-Li f t i ng and H i g h S a l t Spray R e s i s t a n c e
Premix:
D i s p e r s e t o 135F and 5 n . s . u .
F o r m u l a t i o n Constants
1 . Can be r e - c o a t e d w i t h p o w e r f u l s o l v e n t - c o n t a i n i n g t o p c o a t s .
N o n - l i f t i n g e p o x i e s , u r e t h a n e s , and a l k y d s .
2 . Very h i g h s a l t s p r a y r e s i s t a n c e - 3000 h o u r s a t 3 m i l s .
3. F a s t d r y i n g i n t h i n f i l m s .
4. Must be f u l l y c u r e d b e f o r e t o p c o a t e d .
5. Ready t o s p r a y w i t h o u t d i l u t i o n .
6 . Touch d r y i n a p p r o x i m a t e l y 8 m i n u t e s .
Water-Base Acrylic U n i v e r s a l P r i m e r U s i n g
H a l o x SZP-391 & EJW-100
M i x f o r 5 m i n u t e s t h e n add t h e f o l l o w i n g raw m a t e r i a l i n o r d e r
listed:
Letdown :
Rhopl ex MV-23 490.0 588.0
Texanol 8.0 9.6
Skane M-8 2.0 2.4
Nopco NDW 1 .o 1.2
Add g r i n d p o r t i o n under a g i t a t i o n and mix u n t i l u n i f o r m . Then
s l o w l y add t h e f o l l o w i n g raw m a t e r i a l w h i l e m i x i n g a t h i g h
speed. Do n o t a e r a t e !
Mix u n t i l uniform.
Formula C o n s t a n t s : Formula P r o p e r t i e s :
% Pigment/Wt. : 34.55 D e n s i t y 1bs. / g a l . : 1 1 .35
% Pigment/Vol.: 14.76 D e n s i t y g/L: 1 ,367.4
% S o l i d s / W t . : 54.55 KU V i s c . @ R.T.: 90-95
.
96 Sol ids/Vol : 38.71 pH @ R . T . : 9.0-9.5
46 PVC: 38.14
VOC. l b s . / g a l . : 1.14
VOC, g/L: 136.82
Water-Base A c r y l i c U n i v e r s a l P r i m e r U s i n g
H a l o x SZP-391 (L X t a i n A
M i x f o r 5 m i n u t e s t h e n add t h e f o l l o w i n g raw m a t e r i a l i n o r d e r
listed:
E t h y l e n e G1 y c o l 30.0 36.0
Tamol 681 18.5 27.8
T r i t o n CF-10 3.0 3.6
T i -Pure R-902 150.0 180.0
Z i n c Oxide 10.0 12.0
Halox SZP-391 50.0 60.0
Halox X t a i n A 5.0 6.0
Snowf 1 ake 175.0 210.0
H i g h speed d i s p e r s e t o 5+ Hegman g r i n d
Letdown :
Rhopl ex MV-23 490.0 588.0
Texanol 8.0 9.6
Skane M-8 2.0 2.4
Nopco NDW 1. o 1.2
M i x u n t i l u n i f o r m and add t h e f o l l o w i n g :
Mix u n t i l u n i f o r m .
Formula C o n s t a n t s : Formula P r o p e r t i e s :
.
% P i gment/Wt : 34.56 Density lbs./gal.: 11.35
% Pigment/Vol : 14.81 . D e n s i t y g / L : 1,367.4
% S o l i d s / W t . : 54.57 KU V i s c . @ R.T.: 90-95
.
% Soli d s / V o l : 38.76 pH @ R.T.: 9 . 0 - 9 . 5
% PVC: 38.20
VOC, l b s . / g a l . : 1.14
VOC, g / L : 136.69
Add f o l l o w i n g i n o r d e r under a g i t a t i o n :
H i g h speed d i s p e r s e t o 5 N.S.
Add f o l l o w i n g under a g i t a t i o n :
Component 8 :
Mix f o l l o w i n g under high-speed a g i t a t i o n u n t i 1 uniform:
E p o t u f 37-143 77.43 8.80
Mineral S p i r i t s 24.71 3.85
A r o m a t i c 150 24.71 3.35
Tap Water 33.32 4.00
Add f o l l o w i n g i n o r d e r under a g i t a t i o n :
H i g h speed d i s p e r s e t o 5 N.S.
Add f o l l o w i n g under a g i t a t i o n :
Component 0 :
Mix f o l l o w i n g under high-speed a g i t a t i o n u n t i l uniform:
E p o t u f 37-143 72.91 8.28
Mineral S p i r i t s 24.13 3.76
A r o m a t i c 150 24.13 3.28
Tap Water 39.07 4.69
Weight/Gallon ( L b s . ) : 11.02
P e r c e n t Sol i d s (Wt. ) : 54.89
Percent S o l i d s ( V o l . ) : 37.68
PVC ( % I : 37.25
VOC ( L b s . / G a l l o n ) : 2.46
W a t e r b o r n e Red O x i d e Epoxy P r i m e r
M a t e r i a1 : Pounds Gal l o n s
P a r t A:
E p i -Rez 5522-WY-55 R e s i n 330.0 37.21
D i a c e t o n e A1 coho1 7.0 0.89
Col 1o i d 640 Defoamer 3.5 0.41
Water 60.0 7.20
R0-4097 Kroma Red, Red I r o n O x i d e 71.1 1.74
Sparmite Barium S u l f a t e 71 . I 1.94
1OES W o l l a s t o k u p 106.7 4.40
H a l o x SW-111 100.0 4.20
Zeeosphere 400 71 . 1 3.55
Water Ground M i c a , 325 Mesh 7.5 0.32
H i g h Speed D i s p e r s e t o a T e x t u r e o f 5-6 N . S
Part 8 :
€ p i - C u r e 8290-Y-60 C u r i n g Agent 60.0 6.80
Water 110.0 13.20
R e s i n Composi t i on :
Epoxy R e s i n , %: 8 7 . 6
C u r i n g Agent, %: 1 2 . 4
T o t a l , %: 100.0
Waterborne Y e l l o w I r o n Oxide P r i m e r
Based on EDotuf 37-143/37-680
( F o r m u l a No. 3019-396)
Add f o l l o w i n g i n o r d e r under a g i t a t i o n :
H i g h speed d i s p e r s e t o 5 N . S .
Add f o l l o w i n g under a g i t a t i o n :
Component 8 :
Mix f o l l o w i n g under high-speed a g i t a t i o n u n t i l uniform:
E p o t u f 37-143 77.25 8.78
Mineral S p i r it s 24.55 3.82
A r o m a t i c 150 24.55 3.33
Tap Water 33.90 4.07
Weight/Gallon ( L b s . ) : 10.81
P e r c e n t S o l i d s (Wt. ) : 54.80
Percent S o l i d s ( V o l . ) : 38.50
PVC ( % ) : 35.89
.
VOC ( Lbs /Gal 1on) : 2.50
Disperse a t h i g h speed t o 4+ NS g r i n d .
Letdown :
Chempol 10-0091 50.0 60.0
DMEA 4.0 4.8
Aqua Ammonia (28%) 4.0 4.8
Cobalt Hydro-Cure 5% 2.0 2.4
Cal c i um Hydro-Cure 5% 3.5 4.2
Zirconium Hydro-Cure 12% 2.0 2.4
Active 8 1. o 1.2
Byk 301 1.o 1.2
n-Butanol 25.0 30.0
Add s l o w l y w h i l e mixing.
Water R e d u c i b l e A l k y d Y e l l o w I r o n Oxide P r i m e r
U s i n s H a l o x CW-491
D i s p e r s e a t h i g h speed t o 4+ NS g r i n d .
Letdown :
Chempol 10-0091 50.0 60.0
DMEA 4.0 4.8
Aqua Ammonia (28%) 4.0 4.8
C o b a l t H y d r o - c u r e 5% 2.0 2.4
C a l c i u m H y d r o - c u r e 5% 3.5 4.2
Z i r c o n i u m H y d r o - c u r e 12% 2.0 2.4
Active 8 1.o 1.2
Byk 301 1.o 1.2
n-Butanol 25.0 30.0
Add s l o w l y w h i l e m i x i n g .
Water 400.0 480.0
Mix u n t i l uniform.
Formula C o n s t a n t s : Formula P r o p e r t i e s :
% Pigment/Wt.: 25.67 Density lbs./gal.: 10.15
% P i gment/Vol : 10.24 . D e n s i t y g / L : 1,217.8
% S o l i d s / W t . : 44.75 KU V i s c . @ R . T . : 80-85
.
% Sol i d s / V o l : 31 .35 pH C R . T . : 9 . 0 - 9 . 5
% PVC: 32.65
VOC, l b s . / g a l . : 2.93
VOC, g / L : 351.68
Grind: Lbs/100 G a l s . G m s / L i t e r
W/R Epoxy E s t e r R e s i n 340.0 408.0
B u t y l C e l l os01 ve 25.0 30.0
Aqua Ammonia (28%) 3.0 3.6
AMP-95 3.0 3.6
Red I r o n O x i d e 100.0 120.0
H a l o x SZP-391 42.0 50.4
Talc 791 .O 229.2
H i g h speed d i s p e r s e t o 4+ NS G r i n d
Letdown :
W/R Epoxy E s t e r R e s i n 125.0 150.0
B u t y l Cel l o s o l ve 25.0 30.0
Aqua Ammonia (28%) 3.0 3.6
C o b a l t H y d r o c u r e (13%) 2.5 3.0
Manganese H y d r o c u r e (12%) 2.5 3.0
Activ 8 1 .o 1.2
N-Butanol 25.0 30.0
Byk 301 2.0 2.4
A d d s l o w l y w h i l e m i x i n g and m i x u n t i l u n i f o r m .
Formula C o n s t a n t s : Formula P r o p e r t i e s :
% P i gment/Wt. : 31 . 2 4 Density lbs./gal.: 10.65
% P i g m e n t / V o l . : 12.15 O e n s i t y g / l . : 1,278.4
% S o l i d s / W t . : 52.28 KU V i s c . @ R . T . : 80-85
% S o l i d s / V o l . : 34.70 pH @ R . T . : 9 . 0 - 9 . 5
% PVC: 34.70
VOC, l b s . / g a l . : 4.13
voc, g/L: 494.87
SOURCE: H a l o x Pigments: Suggested F o r m u l a t i o n WREE39lH
186 Water-Based Paint Formulations
High speed d i s p e r s e t o 4+ NS g r i n d .
Letdown :
W/R Epoxy E s t e r R e s i n 125.0 150.0
Butyl Cellosolve 25.0 30.0
Aqua Ammonia (28%) 3.0 3.6
C o b a l t Hydrocure (12%) 2.5 3.0
Manganese Hydrocure (12%) 2.5 3.0
Active 8 1.o 1.2
N-Butanol 25.0 30.0
BYK 301 2.0 2.4
Formula C o n s t a n t s : Formul a P r o p e r t i 8s :
.
% P i gment/Wt : 31 ,55 Density l b s . / g a l . : 10.64
% P i gment/Vol : 12.35. D e n s i t y g/L: 1,276.4
% Sol i d s / W t . : 52.54 KU V i s c . @ R.T.: 80-85
% S o l i d s / V o l . : 34.90 p H @ R . T . : 9.0-9.5
% PVC: 35.39
VOC, l b s . / g a l . : 4.12
VOC, g / L : 493.60
Water R e d u c i b l e Epoxy-Ester
Red Iron Oxide Primer
U s i n g H a l o x CW-491
H i g h speed d i s p e r s e t o 4+ NS g r i n d .
Letdown :
W/R Epoxy E s t e r Resin 125.0 150.0
Butyl Cellosolve 25.0 30.0
Aqua Ammonia (28%) 3.0 3.6
C o b a l t Hydrocure (12%) 2.5 3.0
Manganese Hydrocure (12%) 2.5 3.0
Active 8 1 .o 1.2
N- B u t ano 1 25.0 30.0
Byk 301 2.0 2.4
Formula C o n s t a n t s : Formula P r o p e r t i e s :
.
% P i gment/Wt : 31 . 5 5 D e n s i t y l b s . / g a l . : 10.64
% P i gment/Vol : 12.35. D e n s i t y g / L : 1,276.4
% S o l i d s / W t . : 52.54 KU V i s c . @ R . T . : 80-85
% S o l i d s / V o l . : 34.90 pH @ R . T . : 9.0-9.5
% PVC: 35.39
VOC, l b s . / g a l . : 4.12
VOC, g/L: 493.60
L e t Down:
Rhopl ex MV-23/Acryl i c Emu1si on 500.62 56.89 43.10
Texanol/Ester Alcohol 7.01 0.89 0.60
Ethylene Glycol 30.04 3.23 2.59
Water 55.07 6.61 4.74
D e n s i t y ( l b / U . S g a l ) : 11.61
S p e c i f i c G r a v i t y : 1.39
P.V.C.: 40.65%
P/B R a t i o : 1.951
Spread @ 1 M i l : 617 F2
C o a t i n g VOC: 134 G / L
M a t e r i a l VOC: 59 G/L
Letdown :
Methyl C a r b i t o l Solvent 8.5 1.oo
A c r y s o l SCT-275 8.6 1.oo
Ucar V e h i c l e 435 505.1 58.06
Ucar F i l m e r I E T 11.4 1.44
T r o y s a n Polyphase AF-1 4.9 0.50
Foamex 825 2.1 0.25
Sodium N i t r i t e , 15% Aqueous S o l u t i o n 9.0 1.08
Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n 1.8 0.25
A d j u s t t o minimum p H 8 . 7
P a i n t P r o p e r t i es :
Pigment Volume C o n c e n t r a t i o n (PVC) , %: 30.0
T o t a l S o l i d s , %:
b y volume: 34.0
pH Value, i n i t i a l : 8 . 7
Viscosity:
S t o r m e r , KU: 80
I C I , poise: 0.8
Weight p e r G a l l o n , l b : 1 0 . 5
Freeze-Thaw S t a b i l i t y , 3 c y c l e s : Pass
Heat S t a b i l i t y , 2 weeks a t 140F: Pass
-
Lb Gal
P a r t A:
L i q u i d DGEBA Epoxy 307 31.7
MPA-1078 (Rheox) 8 1.0
10 W o l l a s t e k u p AS (Nyco) 250 10.3
Part 8 :
Ancamide 2553 ( A i r P r o d u c t s ) 169 20
Properties:
Volume S o l i d s : 71 .9% VOC: t2.5 l b g a l
PVC: 20.0% M i x i n g R a t i o 4:l b y Volume
CPVC: 47.1% Pot L i f e , h r 5
PVC/CPVC: 0.426 Dry t o Touch, h r : 3
Weight/gallon, P a r t A: 11.29 Dry Through, h r : 7
W e i g h t / g a l l o n , P a r t B: 8.45
Wei g h t / g a l l o n : 10.73
Clear Sealant
Inaredients : Weight%
Ucar L a t e x 100 95.15
T e r g i t o l N o n i o n i c S u r f a c t a n t NP-4 0.16
Nopco NXZ 0.36
P r o x e l GXL 0.24
Ucar F i l m e r I B T 0.85
Cosan 158 0.42
Propylene G l y c o l 0.85
Ucar T h i c k e n e r 146 0.48
Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n 0.64
A c r y s o l SCT-275 0.85
M i x i ng Procedure:
A h i g h - s h e a r , low-speed vacuum m i x e r o f t h e d o u b l e - b l a d e d
p l a n e t a r y t y p e o r t h e d o u b l e - b l a d e d sigma t y p e i s recommended.
Charge t h e l a t e x t o t h e m i x e r . Add t h e r e m a i n i n g i n g r e d i e n t s
s l o w l y i n t h e o r d e r l i s t e d t o t h e m i x e r w i t h a g i t a t i o n . The
mix w i l l t h i c k e n when t h e NH40H i s added. S t i r f o r f i v e m i n u t e s
and t h e n add a s s o c i a t i v e t h i c k e n e r . M i x i n g t i m e s h o u l d be >30
m i nutes.
Sealant P r o p e r t i e s :
N o n v o l a t i l e s , % by w e i g h t : 61.9
pH Value: 8 . 8
V i s c o s i t y , B r o o k f i e l d , P : 24,000
Semco G u n n a b i l i t y , g/sec: 28
ASTM C731: Pass
T o o l i n g Time, min: > 5
Boeing Slump, i n : 0 . 0
E l o n g a t i o n a t Break, %: 1000
T e n s i l e S t r e n g t h , max, p s i : 230
Time f o r 180-mil Bead t o D r y C l e a r , days: 7
Shore "A" Hardness, 7 days a t 50% R.H.: 48
High-Qual it y E x t e r i o r L a t e x Caulk
Caulk P r o p e r t i e s :
T o t a l S o l i d s , %:
-
bv w e i a h t : 84.7
by volume: 74.4
Weight per G a l l o n , t h e o r e t i c a l , l b : 13.5
V i s c o s i t y , B r o o k f i e l d , P:
I n i t i a1 : 2800
A f t e r 5 freeze-thaw c y c l e s : 2150
Pigment Volume C o n c e n t r a t i o n , %: 45
Boeing Slump: None
O F Bend: Pass
Shore "A" Hardness, 72F a t 50% R . H . :
1-day: 10
3-day: 33
7-day: 50
Semco G u n n a b i l i t y , g/sec:
i n i t i a l : 9.5
a f t e r 5 freeze-thaw c y c l e s : 9 . 0
Stress-Strain Properties: 32F -
OF
t e n s i l e s t r e n g t h , max, p s i 54 67 330
e l o n g a t i o n a t break, % 230 155 87
Adhesion P r o p e r t i es : 180 Peel Adhesion*, p l i
Substrate Drv 24-hr. Water Soak
G1ass 20.7 (COH) 15.1 (COH)
A1 umi num 21.9 (COH) 13.2 (COH)
Concrete 20.5 (COH) 12.7 (AO/COH)
Hypal on Sheet 13.8 (COH) 12.9 (COH)
* COH=cohesi ve f a i 1u r e
A 0 =adhesive f a i 1u r e
P a t c h i n a C o l w u n d (Brushina Grader
L e t Down:
Coarse S i l i c a ( 1 0 ) 286.7* 12.2
M i n e r a l Spi r i t s 3.4 0.6
Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n 3.4 0.5
Ethylene Glycol 17.6 1.9
*Post Added
Suppl ie r s :
W e t t i n g Agent - S u r f y n o l 104 ( A i r P r o d u c t s ) o r e q u i v a l e n t .
A n t i f o a m - C o l l o i d 770 ( C o l l o i d s ) o r e q u i v a l e n t .
D i s p e r s a n t - C o l l o i d 226/35 ( C o l l o i d s ) o r e q u i v a l e n t .
P r e s e r v a t i v e - Cosan 101 (Cosan) o r e q u i v a l e n t .
C a l c i u m Carbonate - D u r a m i t e (Thompson, Weinman) o r
equivalent.
M i c a - 325 WG M i c a (KMG M i n e r a l s ) o r e q u i v a l e n t .
T i t a n i u m D i o x i d e - T i - P u r e R-901 (DuPont) o r e q u i v a l e n t .
S i l i c a - C e l i t e 281 ( J o h n s - M a n v i l l e ) o r e q u i v a l e n t .
M i l d e w c i d e - Nopcocide N-96 (Diamond Shamrock) o r
equivalent.
Coarse S i l i c a - R u f f B u f f (Tammsco) o r e q u i v a l e n t .
P a t c h i n g Compound P r o p e r t i 8 s :
Pigment Volume C o n c e n t r a t i o n (PVC) , %: 31 . 7
T o t a l S o l i d s , %:
by Volume: 6 0 . 4
b y Weight: 71.6
P a t c h i n s Compound ( T r o w e l G r a d e l
L e t Down:
Coarse S i 1 i c a 34.5 1.6
Mineral S p i r i
m m-o.n. i.t-i m
.A.......
Ethylene Glycol
~
.,-. -.. . - - , -
... .Hvdrnxida. -
- .- A. .a t-i -e -n -u -
3R% - -n .l -u -t i.n-.n.
s S
3.4
3
-.. 4.
17.2
0.5
0.5
1.9
Suppliers:
( 1 ) W e t t i n g Agent - S u r f y n o l 104 ( A i r P r o d u c t s ) o r e q u i v a l e n t
(2) A n t i f o a m - C o l l o i d 770 ( C o l l o i d s ) o r e q u i v a l e n t .
(3) D i s p e r s a n t - C o l l o i d 226/35 ( C o l l o i d s ) o r e q u i v a l e n t .
( 4 ) P r e s e r v a t i v e - Cosan 101 (Cosan) o r e q u i v a l e n t .
( 5 ) C a l c i u m Carbonate - D u r a m i t e (Thompson, Weinman) o r
equivalent.
(6) M i c a - 325 WG M i c a (KMG M i n e r a l s ) o r e q u i v a l e n t .
(7) T i t a n i u m D i o x i d e - T i - P u r e R-901 (DuPont) o r e q u i v a l e n t .
(8) S i l i c a - C e l i t e 281 ( J o h n s - M a n v i l l e ) o r e q u i v a l e n t .
(9) M i l d e w c i d e - Nopcocide N-96 (Diamond Shamrock) o r
equivalent.
(10) Coarse S i l i c a - R u f f B u f f (Tammsco) o r e q u i v a l e n t .
P a t c h i n g Compound P r o p e r t i e s :
Pigment Volume C o n c e n t r a t i o n ( P V C ) , %: 29.7
T o t a l S o l i d s , %:
b y Volume: 59.9
b y Weight: 70.7
Seal a n t P r o p e r t ies :
T o t a l S o l i d s , % by w t : 79.0
Weight p e r G a l l o n ( t h e o r e t i c a l ) , l b : 12.5
F i l l e r / L a t e x S o l i d s R a t i o : 2.1/1.0
P l a s t i c i z e r (on t o t a l b i n d e r s o l i d s ) , % by w t : 26.0
Shore "A" Hardness ( 4 wks a t 73F, 50% R H ) : 27
T e n s i l e S t r e n g t h ( 2 w k s a t 73F, 50% RH), p s i : 1 3
E l o n g a t i o n ( 2 wks a t 73F, 50% RH), %: 460
180 Peel Adhesion ( p e r i n ) :
Pinewood: 9 ( a d h e s i v e )
Aluminum: 11 ( c o h e s i v e )
G l a s s : 12 ( c o h e s i v e )
E x t r u s i o n : Good g u n n a b i l i t y
ASTM S h r i n k a g e (28 days a t 73F, 50% RH) %: <25
Slump a t Room Temperature: None
Recovery (25% E x t e n s i o n RT f o r 1 / 2 h r ) , %: >80
Sealant A ~ p l i c a t i o n
Inqredients: Weiqht%
Ucar L a t e x 163 33.00
S u r f a c t a n t (1) 0.70
P l a s t i c i z e r (2 9.00
Tool ing Agent 3) 2.00
Water 1.50
Ethvlene Glvco 1 .oo
Calcium c a r b o n a t e ( 4 ) 48.00
Extender (5) 3.00
Surfactant (6) 1 .oo
Titanium Dioxide (7) 0.80
Suppl ie r s :
( 1 ) S u r f a c t a n t - T r i t o n X-405 (Rohm and Haas) o r e q u i v a l e n t .
( 2 ) P l a s t i c i z e r - B e n z o f l e x 9-88 ( V e l s i c o l ) o r e q u i v a l e n t .
(3) T o o l i n g Agent - V a r s o l No. 1 (Exxon) o r e q u i v a l e n t .
( 4 ) Calcium Carbonate - A t o m i t e (Thompson, Weinman) o r
equivalent.
(5) Extender - B a r y t e s No. 1 ( W i l l i a m s ) o r e q u i v a l e n t .
( 6 ) S u r f a c t a n t - Composition T (Merck) o r e q u i v a l e n t .
( 7 ) T i t a n i u m D i o x i d e - T i - P u r e R-901 (OuPont) o r e q u i v a l e n t .
Sealant P r o p e r t i e s :
N o n v o l a t i l e s , %: 8 3 . 3
F i l l e r / L a t e x S o l i d s R a t i o : 2.6/1.0
P l a s t i c i z e r t o L a t e x S o l i d s , %: 31.2
Weight p e r G a l l o n , l b : 12.5
24-hr E x t r u s i o n Rate, g/sec: 3
Shore " A " Hardness, 1 month: 22
T e n s i l e Strength, p s i : 8
E l o n g a t i o n , %: 158
A c c e l e r a t e d Weathering, XW, Wooden Channel, 1000 h r :
Very good
T r a n s l u c e n t Caulk F o r m u l a t i o n
Suppl ie r s :
( 1 ) Antifoam-Nopco NXZ ( H e n k e l ) o r e q u i v a l e n t .
( 2 ) N o n i o n i c S u r f a c t a n t - S u r f y n o l 104E ( A i r P r o d u c t s ) o r
e q u i Val e n t .
( 3 ) D i s p e r s a n t - Disperse-Ayd W-22 ( D a n i e l ) o r e q u i v a l e n t .
( 4 ) S i l i c a - Cab-0-Si1 L-90 (Cabot) o r e q u i v a l e n t .
( 5 ) P l a s t i c i z e r - S a n t i c i z e r 160 (Monsanto) o r e q u i v a l e n t .
( 6 ) P r e s e r v a t i v e - Nuosept 95 ( H u l s ) o r e q u i v a l e n t .
Typical P r o p e r t i 8s:
pH V a l u e : 7 . 2
T o t a l S o l i d s , %:
b y Weight: 6 0 . 2
b y Volume: 55.1
Brookfield Viscosity, P : 31,000
T y p i c a l Performance P r o p e r t i e s :
Boei ng S1 ump: Passed
Semco G u n n a b i l i t y , g/sec: 32
A f t e r 5 Freeze-Thaw C y c l e s : 11
A f t e r 14-day Heat A g i n g : 34
Shore A:
7-day d r y : 30
14-day d r y : 30
ASTM C679 Tack: Passed
ASTM C794 180 Peel Adhesion, p l i :
D r y G l a s s : 33.8
Dry Aluminum: 31.3
Wet G l a s s (7-day i m m e r s i o n ) : 1 5 . 0
Wet Aluminum: 14.0
ASTM C793: Passed
Formulation CT-2012
Trans1 u c e n t Seal a n t
Caulk P r o p e r t i e s :
T o t a l S o l i d s , % by w e i g h t : 61.2
pH Value: 9 . 4
Weight p e r G a l l o n , t h e o r e t i c a l , l b : 3.5
V i s c o s i t y , B r o o k f i e l d , P: 27,800
Boeing Slump: None
Semco G u n n a b i l i t y , g / s e c :
i n i t i a l : 24
a f t e r 5 freeze-thaw c y c l e s : 24
180 Peel Adhesion, Dry, p l i :
g l a s s : >50
a1 umi num: >50
Hunter Lab C o l o r :
L: +93.24
a: -0.59
b : -0.78
Y I E : -0.93
ASTM C732 Weathering-500 Hours: no c r a c k i n g
no d i s c o l o r a t i o n
no adhesion l o s s
V i n y l A c r v l ic Seal a n t
I ng r ed ien t s .: Pounds Gal 1ons
Ucar L a t e x 161 450.0 50.34
Kathon LX (1.5%) ( 1 ) 1.3 0.15
Tamol 850 1.3 0.14
Ethylene Glycol 12.4 1.34
S a n t i c i z e r 160 99.0 10.69
Mineral S p i r i t s 20.0 3.07
N a t r o s o l 250 MXR 3.0 0.28
P o t a s s i um T r i p o l y p h o s p h a t e (KTPP) 1 .o 0.05
Camel F i l 729.4 32.42
T i -Pure R-902 15.0 0.45
T r i t o n N o n i o n i c S u r f a c t a n t X-405 9.1 1 .oo
Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n 0.5 0.07
Typical Properties:
T o t a l S o l i d s , %:
by w e i g h t : 82.2
by volume: 78.2
Pigment Volume C o n c e n t r a t i o n (PVC): 46.9
P i g m e n t : B i n d e r R a t i o : 3:l
P l a s t i c i z e r on L a t e x S o l i d s , %: 40.0
E l o n g a t i o n a t Break, %: 722.0
Boeing Slump: Pass
ASTM C-731: Pass
ASTM C-732 Weathering: No bond l o s s
ASTM C-734 OF Bend: Pass
ASTM C-736 E x t e n s i o n - R e c o v e r y : Pass
Water A b s o r p t i o n , 7 days, %: 41.9
Weather-Barrier Mastic
L e t Down:
Ucar L a t e x 163 502.0 56.4
Ucar F i l m e r I B T 6.0 0.8
Antifoam (2) 2.0 0.3
Suppl ie r s :
(1) Dispersant -
C o l l o i d 226/35 ( C o l l o i d s ) o r e q u i v a l e n t .
(2) Antifoam - Nopco NXZ (Diamond Shamrock) o r e q u i v a l e n t .
( 3 ) T i t a n i u m D i o x i d e - "Ti-Pure" R-960 (DuPont) o r e q u i v a l e n t
( 4 ) Calcium Carbonate - " A t o m i t e " (Thompson, Weinman) o r
equi Val e n t .
(5) Z i n c Oxide - AZO-55 (ASARCO) o r e q u i v a l e n t .
( 6 ) M i l d e w c i d e - Nopcocide N-96 (Diamond Shamrock) o r e q u i v -
a1e n t .
Mastic Properties:
Pigment Volume C o n c e n t r a t i o n (PVC), %: 40.0
T o t a l S o l i d s , %:
by Volume: 53.0
by Weight: 67.3
F i l m Properties*:
Tensi 1e P r o p e r t ies :
S t r a i n Rate, %: 20 100 200
Stress, p s i : 120 120 200
E l o n g a t i o n , %: 420 300 260
T e n s i l e P r o p e r t i e s a f t e r 7 days water immersion:
S t r a i n Rate, i n / m i n : --- --- 200
Stress, p s i : --- ---
70
E l o n g a t i o n , %: --- --- 800
Water Ponding: Water T r a n s m i s s i o n a t 24 h r : 210 mg water
Low-Temperature F l e x i b i l i t y : 180 Bend a t -4F: No c r a c k i n g
Water Vapor T r a n s m i s s i o n Rate f o r 336 h r , perms: 5 . 7
Adhesion t o Urethane Foam, 180 Peel, l b / i n :
D r y : 7.8 (Foam Cohesion F a i l u r e )
Wet-7 days immersion i n w a t e r : 2.2 (Foam Cohesion F a i l u r e )
* D r i e d and c o n d i t i o n e d 7 days a t 72F and 50% RH
Weather-Barrier M a s t i c
L e t Down:
Ucar L a t e x 163 496.9 55.8
Ucar F i l m e r I 8 1 5.8 0.8
Antifoam (3) 1.9 0.3
Water 2.5 0.3
Suppl ie r s :
( 1 ) D i s p e r s a n t - C o l l o i d 226/35 ( C o l l o d s ) o r e q u i v a l e n t .
( 2 ) W e t t i n g Agent - S u r f y n o l 104 ( A i r P r o d u c t s ) o r e q u i v a l e n t .
( 3 ) A n t i f o a m - C o l l o i d 643 ( C o l l o i d s ) o r e q u i v a l e n t .
( 4 ) T i t a n i u m D i o x i d e - T i - P u r e R-960 (DuPont) o r e q u i v a l e n t .
( 5 ) Calcium Carbonate - A t o m i t e (Thompson, Weinman) o r e q u i v -
alent.
( 6 ) Z i n c Oxide - XX-503 ( N J Z i n c ) o r e q u i v a l e n t .
( 7 ) M i l d e w c i d e - Skane M-8 (Rohm and Haas) o r e q u i v a l e n t .
M a s t i c P r o p e r t i8 s :
Pigment Volume C o n c e n t r a t i o n (PVC) %: 43.0
T o t a l S o l i d s , % by Volume: 5 5 . 0
Analysis:
Figment Volume Concentration, Percent: 2.17
Pigment/Binder Concentration, Percent: 0.164
Percent Sol ids, Weight : 42.55
Percent Solids, Volume: 39.29
Pounds/Gallon: 8.59
pH: 8.2-8.6
VOC (excludi n g water) :
Grams/Liter: 229
Pounds/Gallon: 1.91
I n t e r i o r Wiping S t a i n
I E n u l s i o n E-2977)
Blend: Pounds
Water 150.0
Aurasperse W-1021 Y I O 22.5
Aurasperse W-3041 R I O 7.6
Aurasperse W-7012 LB 3.3
Emu1s i on E-2977 372.0
S u r f y n o l DF-37* 1.3
Propylene G l y c o l 39.0
Ammoni um H y d r o x i de (28%) 6.3
A c r y s o l ASE-60\1:1 64.0
Water/premi x 64.0
Water 133.8
S u r f y n o l 104DPM 4.4
* S u r f y n o l DF-58, 70 and 75 defoamers a r e v i a b l e a l t e r n a t i v e s .
Stain
81 end : Pounds
J o n c r y l 95 293.19
E k t a s o l v e DB 9.00
S u r f y n o l DF-37 1.32
Super Seatone B u r n t Umber 100.00
Nuosept 95 1.50
F o r m u l a t i o n F (S.C.Johnson)
L i a h t Redwood Wipina S t a i n
M a t e r i a1 : Lbs. Gals.
Spensol L54 51.9 5.94
Water 51.8 6.22
D i sperse-Ayd W22 0.5 0.06
Foamki 11 639AA 0.8 0.10
Mapico 297 24.5 0.60
BK 5000 1.7 0.04
Pebble m i l l g r i n d 16-24 h r s .
Then add i n f o l l o w i n g o r d e r w i t h a g i t a t i o n :
Letdown :
3% Bentone LT P r e g e l * 288.0 34.12
Spensol L54 254.2 29.12
A r o l o n 820-W-49 187.4 21.29
Lodyne S107 1.7 0.18
QR708B 17.5 2.10
Ammoni um Hydroxi de 1.7 0.23
*3% Bentone LT P r e g e l :
Water ( d e i o n i z e d p r e f e r r e d ) 818.9 98.31
Bentone L T 25.4 1.69
High speed d i s p e r s e r 15-20 m i n u t e s .
Analysis:
R a t i o o f Spensol L54 t o A r o l o n 820: 50:50
Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 2 . 6
Pigment/Binder R a t i o : 0 . 1 5 / 1 .0
Percent S o l i d s , Weight: 26.5
Percent S o l i d s , Volume: 24.3
Percent V e h i c l e Sol i d s . Weight : 2 0 . 8
Percent V e h i c l e S o l i d s , Volume: 19.6
Pounds/Gallon: 8.44
pH: 8.Ot-0.5
VOC ( e x c l u d i n g w a t e r ) :
Grams/Li t e r : 72
Pounds/Gallon: 0.60
S t a i n Concentrate
Component A:
M a t e r i a1 : Lbs. Gal s.
K e l s o l 3931 -WG4-45 207.5 25.00
2-Butoxy E t h a n o l 7.5 1 .oo
Water 34.7 4.17
Ammoni um H y d r o x i de 1.9 0.25
P a t c o t e 531 1 .8 0.25
Mapico 567 50.0 1.16
Mapico 1075 25.0 0.74
Atomi t e 50.0 2.22
S y l o i d 234 10.0 0.60
Letdown :
K e l s o l 3931-WG4-45 166.0 20.00
Cobalt Hydrocure I 1 1.9 0.25
Manganese H y d r o c u r e I 1 2.1 0.25
Activ-8 0.2 0.03
2-Butoxy E t h a n o l 3.8 0.50
Premix t h e n e x t t h r e e m a t e r i a l s b e f o r e a d d i n g :
Component 0:
Water 277.6 33.33
NOTE: T h i s t y p e o f f o r m u l a t i o n m i g h t be b e n e f i c i a l t o p a i n t
m a n u f a c t u r e r s who s e l l d i r e c t l y t o b u i l d i n g o r p a i n t i n g
c o n t r a c t o r s . These s t a i n c o n c e n t r a t e s can be mixed w i t h
water a t t h e j o b s i t e .
Tannin S t a i n B l o c k i n a F o r m u l a t i o n
Pigment G r i n d : % by W e i s h t
Water 9.2
Bubond 357 1.0
Busperse 39 0.6
Bubreak 4400 0.3
I g e p a l CTA 639 0.3
Water 2.3
Cel l o s i ze QP-15000 0.2
T i P u r e R-900 18.3
N y t a l 300 9.9
L e t Down:
Ucar 376 39.2
Texanol 2.0
Ethylene Glycol 2.7
C e l l o s i ze QP-15000 0.2
Water 13.8
T i n t t o desired color
A c r y l i c Tannin S t a i n - B l o c k i n q Primer
M a t e r i a1 : % bv Weisaht
Water 8.6
Busperse 39 0.6
T r i t o n X-100 0.3
Bubreak 448 0.2
Premix f o l l o w i n g , t h e n add t o above:
Water 2.2
C e l l o s i ze QP-15000 0.2
S i f t i n f o l l o w i n g pigments:
T i -Pure R-900 17.4
N y t a l 300 6.6
Busan 11-M1 2.5
H i g h speed d i s p e r s e t o Hegman 5 . 0 . Reduce speed and l e t down
as shown b e l o w :
Rhopl ex MV-23 A c r y l ic Emu1s i o n 48.1
Water 8.8
Texanol 2.0
E t h y l e n e G1 y c o l 2.5
Water R e d u c i b l e Redwood S o l i d C o l o r S t a i n
I n c o r p o r a t i o n o f A g i t a n 701 i n t o a w a t e r r e d u c i b l e wood s t a i n
g r i n d y i e l d s improved g r i n d v i s c o s i t y as w e l l as foam c o n t r o l i n
t h e l e t d o w n . A d d i t i o n o f t h i s s i l i c o n e t y p e FCA has no e f f e c t
on r e c o a t a b i l i t y o f t h e t o p c o a t .
H i g h speed 15 M i n u t e s t o 6 Hegman
Letdown : &
Add w h i l e m i x i n g :
McWhorter 73-7358 90.0 10.45
OK 412 (Degussa C o r p . ) 25.0 2.90
B u t y l C e l l os01 ve 80.0 9.29
Premix and add:
Manganese Hydro Cure I 1 (Mooney) 9.5 1. l o
Butyl Cellosolve 24.0 2.79
Polyphase AF-1 ( T r o y Chemical ) 8.0 0.93
Add f o l l o w i n g w h i l e m i x i n g :
Aqueous Ammonia 28% 11.5 1.33
D e i o n i z e d Water 468.4 54.38
Aquabead 519 ( M i c r o Powders) 20.2 2.32
Properties:
% N o n v o l a t i l e ( b y w e i g h t ) : 29.54
( b y v o l u m e ) : 25.41
Pigment t o B i n d e r R a t i o : 0 . 4 4
Pigment Volume C o n c e n t r a t i o n : 11.92
Weight p e r G a l l o n (pounds): 8.61
T h e o r e t i c a l VOC ( p o u n d s / g a l l o n ) : 2 . 8 4
( g r a m s / l i t e r ) : 341
Water-Cosolvent Weight R a t i o : 8 0 . 6 8 : 1 9 . 3 2
pH, 25C: 8.8
V i s c o s i t y , # 2 Zahn Cup, 25C ( s e c o n d s ) : 33
P a r t A: & Gals
Dow XUS19000.01 Epoxy Resin* 346.93 38.70
Benzyl A l c o h o l 17.35 1.99
Water 216.83 25.98
Part 8 :
Anquami ne 401 C u r i n g Agent ( A i r P r o d u c t s ) 177.00 19.37
Water 35.40 4.24
Dowanol PM S o l v e n t (Dow) 35.40 4.66
Benzyl A l c o h o l 44.25 5.07
Typical Properties:
W t s o l i d s ( % ) : 57.45
VOC s o l i d s ( % I : 52.43
VOC ( l b / g a l ) : 1.05
VOC ( g / l ) : 126
P a r t A: &
€pi-Rez 3520 621.68 69.30
Water 89.20 10.69
P a r t 8:
Anquami ne 401 79.06 8.74
Water 61.59 7.38
Defoamer 4.25 0.53
PnP S o l v e n t 24.85 3.36
T y p i c a l P r o p e r t ies :
W t S o l i d s ( % ) : 70.0
Volume S o l i d s ( % ) : 41.35
VOC ( l b / g a l ) : 1.13
VOC ( g / l ) : 136
Anquami ne 401 C1 e a r Coat P r o p e r t ies :
Pot L i f e , h r : >5
G l o s s , 60 spec, 1 day: 100
G l o s s , 60 spec, 8 wk: >SO
M i x R a t i o : 4:l
Mixed V i s c o s i t y , CP: 390
Tack F r e e Time, h r : 0.5
Hard D r y Time: 6-8
P e n c i l Hardness, o v e r n i g h t : F
VOC, l b / g a l : 1 . 1
Volume S o l i d s , %: 42
Anquami ne 401
L i q u i d EDOXV C l e a r Coat
Letdown :
Water 416.50 50.00
Typical Properties:
W t S o l i d s (%): 47.5 VOC ( l b / g a l ) : 0.47
Volume S o l i d s ( % I : 44.2 VOC ( g / l ) : 56
R e s i n S t o i c h i o m e t r y : 1.6:l
L i q u i d Epoxy C1 e a r Coat P r o p e r t i8s :
Gloss, 60 s p e c u l a r : >90 Hard D r y : O v e r n i g h t
Pot l i f e , h r : 1 VOC l b / g a l : 0.47
Set t o Touch, h r : 3
Aaueous P o l y e s t e r - U r e t h a n e P i qment D i s p e r s i on
B l a c k G l o s s Enanel
M a t e r i a1 : Lbs. Gals.
Spensol L52 175.4 20.00
Aerosol OT-75 2.3 0.25
S u r f y n o l 104H 2.0 0.25
Ammoni um H y d r o x i de 1.9 0.25
Regal 330 Carbon B l a c k 15.0 1 .oo
Letdown :
Spensol L52 679.7 77.50
Anal y s i s :
P;gment Volume C o n c e n t r a t i o n , P e r c e n t : 3 . 5
Pigment/Binder R a t i o : 0 . 6 / 1 . O
P e r c e n t S o l i d s , Weight: 31.9
Percent S o l i d s , Volume: 2 8 . 4
V i s c o s i t y @ 25C, #4 Ford, Secs.: 25-30
Pounds/Gal 1on : 8.82
pH: 8 . 5 t - 0 . 3
VOC ( e x c l u d i n g w a t e r ) :
G r a m s / L i t e r : 275
Pounds/Gallon: 2.3
F o r m u l a t i o n 21 54-1 0
C l e a r B a r r i e r / T i e Coat f o r V i n y l
Analysis:
P e r c e n t S o l i d s , Weight: 33.9 Percent S o l i d s , Volume: 31.2
V i s c o s i t y I3 25C, #2 Zahn. Secs.: 20-25
Pounds/Gallon: 8 . 7 PH: 8.5-9.0
VOC ( e x c l u d i n g w a t e r ) : G r a m s / L i t e r : 209
Pounds/Gallon: 1 . 7
F o r m u l a t i o n 2262-831)
C l e a r T i n t Base
A c t iv - 8 2.1 0.36
C o b a l t Hydrocure I 1 1.3 0.17
Manganese H y d r o c u r e 5.0 0.66
Add t h e f o l l o w i n g i n o r d e r :
Analysis:
P e r c e n t S o l i d s , Weight: 23.3
P e r c e n t S o l i d s ] Volume: 21.6 ( a p p r o x )
pH: 8 . 2 - 8 . 6
V i s c o s i t y @ 25C, #2 Zahn, Secs.: 20-25
VOC ( e x c l u d i n g w a t e r ) :
Grams/Li t e r : 185
Pounds/Gal 1on : 1 . 5 4
FCA’s f o r Waterborne B u i l d i n g P r o d u c t F o r m u l a t i o n s
C l e a r Waterborne Cement S e a l e r
P r o p e r t ies :
% N o n v o l a t i l e (by w e i g h t ) : 45.78
V i s c o s i t y , CPS: 150+-10%
pH: 7 . 7 - 8 . 7
Waterborne B l a c k Topcoat
Grind: &
Water 121.8 11.85
N a t r o s o l 250MR ( H e r c u l e s ) 1.1 0.11
Ammoni a (28%) 0.5 0.05
Tamol 731-25 (Rohm and Haas) 12.1 1.18
FCA (Foam C o n t r o l A g e n t ) 3.8 0.37
B a y f e r r o x 318M ( M i l e s ) 174.5 16.98
WG-325 M i c a (KMG M i n e r a l s ) 48.3 4.70
G r i n d a t h i g h speed f o r 15 m i n u t e s
Letdown :
Rhoplex AC-3001 (Rohm and Haas) 605.1 58.88
Butyl Cellosolve 43.6 4.24
S u r f y n o l 104H ( A i r P r o d u c t s ) 3.2 0.31
Water 13.7 1.33
Properties:
% N o n v o l a t i l e ( b y w e i g h t ) : 50.0
(by volume): 37.9
pH, 25C: a p p r o x . 9 . 0
V i s c o s i t y , #4 F o r d cup, 25C, seconds: 18
C o a l e s c e n t , % on polymer s o l i d s : 15
T h e r e t i c a l VOC ( g r a m s / l i t e r ) : 119.8
(pounds/gallon): 1.0
R e s u l t s d e m o n s t r a t e t h e v e r s a t i l i t y o f A g i t a n 260 as a
p e r s i s t e n t foam c o n t r o l agent and i t s a b i l i t y t o improve c o l o r
( r e p r e s e n t e d by t h e L Value and y e l l o w i n d e x ) and p r e v e n t
pigment f l o a t .
SOURCE: K i n g I n d u s t r i e s : F o r m u l a t i o n WR-33
Miscellaneous 219
E x t e r i o r / I n t e r i s r Block F i l l e r
Paint Properties:
PVC. %: 70.6
Volume S o l i d s , %: 47.2
Weight S o l i d s , %: 67.0
Weight p e r Gal on, l b : 13.17
Stormer, KU: 115
I C I , p o i s e : 1.55
pH V a l u e : 9.2
Freeze-Thaw S t a b i l i t y , 3 c y c l e s : F a i l
Heat-Aged S t a b i l i t y , 4 weeks a t 140F: Pass
Film Properties:
R e f l e c t a n c e , %: 83.5
G l o s s , 60: 2 . 3
Mudcracking, 50 m i l : Pass
Sag R e s i s t a n c e , m i l s : 16
F i l l e d Appearance on B l o c k : Exc
High S o l i d s Self P r i m i n g A l k y d
Inaredients: j& Gal
Pigment G r i n d :
C a r g i l l 57-5766/High S o l i d s A l k y d 224.26 27.35 18.71
Ye1 k i ns-TS/Soya L e c i t h i n 2.99 0.35 0.25
Bentone 38 1.99 0.14 0.17
Methyl Alcohol 1.50 0.23 0.12
T i - P u r e R-SOO/Titanium D i o x i d e -
Rutile 199.35 5.99 16.63
B u t r o l 23/Modi f i e d B a r i um Meta-
borate 99.68 3.24 8.32
A t o m i t e / C a l c i u m Carbonate 149.51 6.62 12.47
N y t a l 300/Talc-Magnesium S i l i c a t e 149.51 6.31 12.47
M i n e r a l S p i r i t s ( R u l e 66) 37 * 88 5.89 3.16
L e t Down:
C a r g i l l 57-5766/High S o l i d s R e s i n 224.26 27.35 18.71
Z i r c o n i u m 6% 6.98 0.98 0.58
Cobalt Naphthenate-6%/Drier 1.99 0.27 0.17
A n t i s k i n n i ng Agent 1.99 0.26 0.17
M i n e r a l S p i r i t s (Rule 66) 96.68 15.04 8.07
P a i n t P r o p e r t i es:
Total Vehicle 49.94 77.71
Pigment 50.06 22.29
Vol a t i 1e 15.95 29.35
Organic Solvent 15.95 29.35
Non-Volati l e 84.05 70.65
Non-Volatile Vehicle 33.98 48.36
D e n s i t y ( l b / U . S . g a l ) : 11.99
S p e c i f i c G r a v i t y : 1.44
P.V.C.: 31 .55%
P / B R a t i o : 1.473
Spread @ 1 M i 1 : 1133 F2
C o a t i n g VOC: 229 G / L
M a t e r i a l VOC: 229 G / L
Masonry B l o c k
M a t e r i a1 : Pounds Gal l o n s
P a r t A:
2-Propoxyet hanol 11.6 1.50
T r i t o n X-100 S u r f a c t a n t 3.5 0.39
Tamol 731 (25% N . V . ) S u r f a c t a n t 3.5 0.38
C o l l o i d 640 Defoamer 4.0 0.50
R u t i l e Titanium Dioxide 50.0 1.46
Atomi t e C a l c i um C a r b o n a t e 100.0 4.44
Water 50.0 6.00
Add u n d e r r e d u c e d speed:
P a r t B:
€ p i - C u r e 8536-MY-60 C u r i n g Agent 124.5 15.00
ASP 1 7 0 Aluminum S i l i c a t e 50.0 2.38
325 Mesh Water Ground M i c a 100.0 4.24
Water 166.0 20.00
Resin Composition ( s o l i d s ) :
Epoxy R e s i n , % : 65.7
C u r i n g Agent, %: 34.3
T o t a l , %: 100.0
Masonry B l o c k f i 11
Part 8:
Epi -Cure 8537-W-60 C u r i n g Agent 129.0 14.25
Tap Water 166.0 20.00
Mix we1 1 and add:
ASP 170 Aluminum S i 1 i c a t e 50.0 2.38
325 Mesh Water Ground M i c a 100.0 4.24
A t o m i t e C a l c i u m Carbonate 125.0 5.56
H i speed d i s p e r s e 10 m i n u t e s ; t h e n add:
Short S t u f f Polyethylene Fibers 1.o 0.13
Tap Water 28.7 3.44
Composi t e 81 end :
Part A 532.0 50.00
Part B 599.7 50.00
T y p i c a l Coat ng P r o p e r t i es :
Viscosity P a r t A: 128 Krebs U n i t s
P a r t B: 108 Krebs U n i t s
P a r t s A and B: F r e s h : 108 Krebs U n i t s
P . V . C . . % 42.2
T o t a l Weight S o l i d s , %: 6 7 . 4
T o t a l Volume S o l i d s , %: 46.2
R e s i n C o m p o s i t i o n : Epoxy Resin, %: 65
C u r i n g Agent, %: 35
V o l a t i l e s C o m p o s i t i o n : Water. l b s . : 393.6
O r g a n i c , l b s . : 63.6
V o l a t i l e O r g a n i c Compounds (VOC):
Pounds/Gal 1on : 1 .21
G r a m s / L i t e r : 145
A p p l i c a t i o n : Brush and R o l l e r
L e t Down:
C a r g i l l 74-7450/Water R e d u c i b l e
A1 k y d 252.67 29.71 23.86
n-Butyl Alcohol 84.55 12.53 7.99
Ammoni urn H y d r o x i de-28% 9.83 1.31 0.93
Water 216.29 25.97 20.43
Cobalt Napthenate-6%/Drier 1.97 0.27 0.19
Z i r c o n i u m 6% 3.93 0.55 0.37
NCO/OH R a t i o : 1 . 6
A c r y l ic/PU-Di s p e r s i on: 80/20
Component A : Wt%
Emulsion E-3275 69.31
K-Flex XM-4316 16.89
Sodium N i t r i t e ( 5 % aq) 0.00
P r o g l y d e DMM 1 .23
Edaplan LA 402 0.07
S i l w e t 7001 ( 5 % aq) 0.00
S i l w e t 7605 (25% aq) 0.00
S i l w e t 7604 (25% aq) 0.00
D i m e t h y l e t h a n o l ami ne 0.00
Component B:
Bayhydur XP-7063 12.50
Formulation Characteristics:
N o n v o l a t i l e , t h e o r e t i c a l , % : 48.7
T h e o r e t i c a l VOC, g/L, ( l b . / g a l l o n ) : 48, (0.4)
F o r m u l a t i o n P r o p e r t i e s , A i r - D r y 20-25C, 2 weeks:
S u b s t r a t e : B o n d e r i t e 1000 c o l d r o l l e d s t e e l
F i l m t h i c k n e s s , m i c r o n ( m i l . ) : 32+-2 ( 1 . 3 + - 0 . 1 )
Dry Time ( m i n u t e s ) : Set t o t o u c h : 4.5
S u r f a c e d r y : 12
Through d r y : 18
G l o s s 60, %: 96 Knoop Hardness: 5 . 5
20, %: 74 MEK Double Rubs: 120
Koenig Hardness ( s e c ) : 108 Impact, D i r e c t , i n c h . l b . : >160
P e n c i l Hardness: 2H-3H Impact, Reverse, i n c h . l b . : >160
Formulation Preparation:
Add component B t o component A under l o w shear mechanical
a g i t a t i o n f o r approx. 5 minutes.
SOURCE: K i n g I n d u s t r i e s : P r e l i m i n a r y F o r m u l a t i o n WR-41
226 Water-Eased Paint Formulations
AC 1024 A c r y l ic r e s i n Rohm&
A r c o s o l v DPM D i p r o p y l e n e g l y c o l monomethyl e t h e r A r c 0
BK5000 Pigment P f iz e r
B u t y l C a r b i t o l A c e t a t e D i e t h y l e n e g l y c o l monobutyl e t h e r Union
acetate
Trade Named Raw Materials 229
Camel F i l C a l c i um c a r b o n a t e Genst a r
C a r g i 11 57-5766 WR H i g h s o l i d s a l k y d C a r g i 11
C a r g i 11 72-7203 WR O i l f r e e p o l y e s t e r C a r g i 11
C a r g i 11 74-7450 WR S h o r t soya a l k y d C a r g i 11
C a r g i 11 74-7474 WR c h a i n - s t o p p e d a l k y d C a r g i 11
D i c y a n d i ami de AmCyan
D o w i c i l 75 A n t i m i c r o b i a l agent DowChem
D r i k a l it e C a l c i u m c a r b o n a t e e x t e n d e r pigment ECC
E k t a s o l v e DB A c e t a t e Solvent Eastman
E p o d i l 759 R e a c t i v e d i 1u e n t
FC-430 F1 u o r o s u r f a c t a n t 3M
F l u o r a d FC-129 F1 uorochemi c a l 3M
H a l o x 8W-100 C a l c i u m b a r i u m phospho-si 1 ic a t e H a l ox
I n t e r c i d e T-0 M icrobiostat
5-31 03 M i nPi g
L a n s f o r d L243 S i 1b e r
M i c r o t a l c MP12-50 Low m i c r o n t a l c P f iz e r
M i c r o w h i t e 25 GeoMarb
Nacure X49-11O/XP-l81/Catalysts f o r p o l y m e r i c c o a t i n g s K i ng
XP-188/155/25OO-X/
2547
Trade Named Raw Materials 237
N e o c r y l XA-6085 A c r y l ic c o p o l y m e r I C I Res-
N i c r o n 400 T a l c Luzenec
O r g a n o f u n c t i o n a l S i l a n e A-187 OSISpec
PM A c e t a t e Arco
P o l y g l o s s 90 C1 ay Huber
91 48 Defoamer Troy
SF-69 S i 1i c o n e GE
S k i n o #2 A n t i s k i n n i ng a g e n t OMGr ou p
S o l v e n t 142HT She1 1
Sparmi t e B a r i um s u l f a t e Harcros
T i n u v i n 328 UV a b s o r b e r C i ba-
T i o n a RCL-9 T i t a n i um d i o x i d e S CM
T i o x i d e TR-92 T i t a n i um d i o x i d e Ti oxide
T i - P u r e CR-800/ T i t a n i um d i o x i d e s duPont
R-700/R-702/R-706/
R-900/R-901/R-902/
R-960
T i t a n o x 2020/2060/ T i t a n i um d i o x i d e s Kronos
21 01 /2160
TS 610 Cabot
W o l l a s t o c o a t 10AS Nyco
W o l l a s t o k u p IOES NyCQ
W/R P o l y e s t e r 72-7203 C a r g i 11
XAMA- 7 Rohm&
YD-2288 Harcros
Z i n c Hydro-Nap Mooney
Z i n c O x i d e 417-W Eag1e
Trade Named Raw Materials 245
GE S i 1i c o n e s H i 1t o n - D a v i s Co.
260 Hudson R i v e r Rd. 2235 Langdon Farm R d .
W a t e r f o r d , NY 12188 C i n c i n n a t i , OH 45237
(518)-237-3330/(800)-255-8886 (513)-841-4000/(800)-477-1022
KMG M i n e r a l s , I n c . Morton I n t e r n a t i o n a l
P.O. Box 729 333 W. Wacker D r i v e .
1433 G r o v e r Rd. Chicago, I L 60606
K i ngs M o u n t a i n , NC 28086 (312)-807-2000
(704)-739-3616/(800)-443-MICA
N a l c o Chemical Co.
Kronos, I n c . One N a l c o C t r .
P.O. Box 60087 N a p e r v i l l e , I L 60563
3000 N . Sam Houston Pkwy (708)-305-1000
Houston, TX 77205
(713)-987-6300 New J e r s e y Z i n c Co.
F o u r t h S t . 8 F r a n k l i n Ave.
M a n v i l l e F i l t r a t i o n 8, M i n e r a l s P a l m e r t o n , PA 18071
P.O. Box 519
Lompoc, CA 93438 NL Chemicals, I n c .
(303)-978-4900/(800)-6 4-31 03 P.O. Box 700
H i g h t s t o w n N J 08520
McWhorter
400 E a s t C o t t a g e P l a c e Nyco M i n e r a l s , I n c . ,
C a r p e n t e r s v i l l e , I L 60 10 P.O. Box 368
W i l l s b o r o , NY 12996
Michelman, I n c . (5181-963-4262
9089 S h e l l Road
C i n c i n n a t i , OH 45236 O c c i d e n t a l Chemical Corp.
(5131-793-7766 300 Berwyn P a r k
Berwyn, PA 19312
M i c r o Powders, I n c . (215)-251-1000
580 W h i t e P l a i n s Rd.
T a r r y t o w n , NY 10591 OM Group I n c .
(914)-793-4058 2301 S c r a n t o n Rd.
C l e v e l a n d , OH 44113
Miles Inc. (216)-781-8383/(800)-321-9696
Mobay Road
P ittsburgh, PA 15205 Omya I n c .
(412)-777-2000/(800)-662-2927 61 M a i n S t .
P r o c t o r , VT 05765
M i n e r a l P i gments Corp. (802)-459-3311/(800)-451-4468
Davis Colors
7011 M u i r k i r k Rd. Paci f ic Anchor Chemical Corp.
B e l t s v i l l e , MD 20705 1224 Mendon R d .
Cumberland, R I 02864
Monsanto Chemi c a l Co. (401)-333-4100/(800)-874-66668
800 N . L i n d b e r g h B l v d .
S t . L o u i s, MO 63167 Pfizer, Inc.
(314)-694-1000/(800)-325-4330 235 E. 42 S t .
New Y o r k , NY 10017
Mooney C h e m i c a l s I n c . (212)-573-7217
2301 S c r a n t o n Rd.
C l e v e l a n d , OH 44113
Suppliers' Addresses 251
Wacker S i l i c o n e s C o r p .
3301 S u t t o n Rd.
A d r i a n , M I 49221
(517)-264-8500/(800)-248-0063