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MATERIAL SAFETY DATA SHEET

PRODUCT
B600

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

BRAND NAME : BOYSEN

PRODUCT NAME : B600 Quick Drying Enamel Paint

APPLICATION : Solvent- based paint

DATE REVISED : 03-27-08

COMPANY IDENTIFICATION

COMPANY NAME : Pacific Paints (Boysen) Philippines, Inc.

ADDRESS : 292 D. Tuazon Street, Quezon City, Philippines

TELEPHONE NUMBERS : + 63- 2- 364-3505


: + 63- 2- 413-6560 to 65

WEBSITE : www.boysen.com.ph

EMAIL : inquiry@boysen.com.ph

2. COMPOSITION/INFORMATION ON INGREDIENTS

MATERIAL WEIGHT (%)


Pigment 20 - 25
Alkyd Resin 45 - 50
Solvent 10 - 20
Drier 1–5
3. HAZARDS IDENTIFICATION

May be harmful if vapor and mist are inhaled. May cause allergic reaction, mild skin and eye
irritation. Harmful to aquatic life.

PRIMARY ROUTES OF EXPOSURE

INHALATION
Inhalation of vapor or mist can cause the following: headache, nausea, irritation of the nose, throat
and lungs.

EYE CONTACT
Direct contact with the chemical can cause eye irritation.

SKIN CONTACT
Repeated exposure to the chemical can cause mild skin irritation and allergic reaction.

4. FIRST AID MEASURES

EYE CONTACT
In case of eye contact, rinse immediately with plenty of water for at least 15 minutes. Obtain medical
treatment immediately.

SKIN CONTACT
In case of skin contact, wash thoroughly with soap and water. Remove contaminated clothing. Wash
clothes before reuse. Keep victim warm and quiet.

INGESTION
If swallowed, do not induce vomiting. If vomiting occurs spontaneously, keep head below hips to
prevent aspiration of liquid into the lungs.

INHALATION
If overcome by vapor and spray mist, bring victim to fresh air. Apply artificial respiration if victim is
not breathing. Administer oxygen if breathing is difficult.

Call emergency medical care. Ensure that medical personnel are aware of the material (s) involved,
and take precautions to protect themselves.

5. FIRE FIGHTING MEASURES

SUITABLE EXTINGUISHING MEDIA


In case of small fire use dry chemical, CO2, water spray or alcohol-resistant foam.

In case of large fire, use water spray, fog or alcohol-resistant foam. Do not use straight streams.
Move containers from fire area if you can do it without risk.
In case of fire involving tanks, cars or trailer loads, fight fire from maximum distance or use
unmanned hose holders or monitor nozzles. Cool containers with flooding quantities of water until
wet after the fire is out. Withdraw immediately in case of rising sound from venting safety devices or
discoloration of tank. ALWAYS stay away from the ends of tanks. For massive fire, use unmanned
hose holders or monitor nozzles; if this is impossible. Withdraw from area and let fire burn.

SPECIFIC HAZARDS
The material is flammable. If heated, toxic gases/ vapors may be formed.

PERSONAL PROTECTIVE EQUIPMENT


Fire fighters must wear appropriate protective equipment such as boots, overalls, gloves, eye and
face protection and Self-Contained Breathing Apparatus (SCBA).

6. ACCIDENTAL RELEASE MEASURES

PERSONAL PROTECTIVE EQUIPMENT


For emergency responders, wear suitable protective equipment (including personal protective
equipment, see Section 8 of the SDS) to prevent any contamination of skin, eyes and personal
clothing.

PERSONAL PRECAUTIONS
Avoid inhalation of vapors and contact with skin and eyes. Provide adequate ventilation.

SPILL CLEAN UP METHODS


In case of spill eliminate all sources of ignition (no smoking, flares, sparks or flames in immediate
area). All equipment used when handling the product must be grounded. Do not touch or walk
through spilled material. Stop leak if you can do it without risk.

Prevent entry to waterways, sewers, basements or confined areas. A vapor suppressing foam may be
used to reduce vapors.

Keep spectators away. Dike and contain spill with inert material (e.g. sand or earth). Transfer
recovered chemical and diking material to a separate suitable container for disposal according to
local regulations. Use clean non-sparkling tools to collect absorbed material.

ENVIRONMENTAL PRECAUTIONS
Keep spills and cleaning runoffs out of sewers and open bodies of water. Spillages or uncontrolled
discharges into watercourses must be reported to the Department of Environment and Natural
Resources- Environmental Management Bureau (DENR-EMB) or other appropriate regulatory body.
7. HANDLING AND STORAGE

SAFE HANDLING
Ensure good ventilation during application and drying. Avoid breathing vapor and spray mist. Avoid
contact with skin and eyes.

Wear eye protection and gloves during application or sanding. A dust/particulate respirator should be
worn when sanding or spraying.

Keep away from heat, sparks and open flame. Avoid spilling. Do not eat, drink or smoke when using
this product.

HYGIENE MEASURES
Wash hands and other contaminated areas with soap and water after using. Remove contaminated
clothing. Wash clothes before reuse.

USAGE DESCRIPTION
Ensure that wastes and contaminated materials are collected are removed from the work area in a
suitably labeled container.

STORAGE CONDITIONS
Store container tightly closed in well-ventilated place. Keep away from heat, sparks and open flame.
Protect from freezing and direct sunlight. Keep upright.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

EXPOSURE LIMIT INFORMATION


CAS
MATERIAL UNITS OSHS ACGIH
NUMBER
TLV TWA STEL
Pigment 13463-67-7
mg/m3 15 10 -

ENGINEERING MEASURES
Provide adequate ventilation. Observe Threshold Limits Values (TLVs) and minimize the risk of
inhalation of vapors.

RESPIRATORY EQUIPMENT
Fire fighters must wear appropriate protective equipment such as boots, overalls, gloves, eye and
face protection and Self-Contained Breathing Apparatus (SCBA).
A dust/particulate respirator should be worn when sanding or spraying.

HAND PROTECTION
Use protective gloves to minimize risk of skin contact.
EYE PROTECTION
Wear approved, tight fitting safety glasses when splashing is probable.

OTHER PROTECTION
Wear appropriate clothing to prevent skin contact.

HYGEINE MEASURES
Wash hands and other contaminated areas with soap and water after using. Remove contaminated
clothing. Wash clothes before reuse.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : Liquid
Color : White
Odor : Aromatic odor
Odor threshold : Not determined
Viscosity : 86 – 96 KU
pH : Not applicable
Melting point : Not determined
Freezing point : Not determined
Initial boiling point : 149ºC
Boiling range : 149ºC – 192°C (based on solvent)
Flash point : 42ºC (based on solvent)
Flammability : Flammable (Category 3)
UEL : Not determined
LEL : Not determined
Vapor pressure : Not determined
Vapor density : Not determined
Relative density : 9.40 – 9.60 lbs/ gal
Evaporation rate : Slow
Solubility : Miscible with most organic solvent, insoluble
in water
Partition Coefficient –octanol water partition) : Not determined
Auto-ignition temperature : Not determined
Decomposition temperature : Not determined

10. STABILITY AND REACTIVITY

STABILITY
Stable under normal temperature conditions and recommended use.

CONDITIONS TO AVOID
Avoid heat, sparks, open flames and other sources of ignition.

MATERIALS TO AVOID
Strong alkalies. Strong acids. Strong oxidizing agents.
HAZARDOUS DECOMPOSITION PRODUCTS
Thermal decomposition or combustion may release carbon oxides and other toxic gases and vapors.

11. TOXICOLOGICAL INFORMATION

ORAL TOXICITY
Not classified

DERMAL TOXICITY
Not classified

INHALATION TOXICITY
Maybe harmful if vapor and mist are inhaled.

SKIN IRRITATION/ CORROSION


Causes mild skin irritation.

EYE IRRITATION/ CORROSION


Causes eye irritation.

SKIN SENSITIZATION
May cause allergic reaction.

RESPIRATORY SENSITIZATION
Classification not possible.

MUTAGENICITY
Not classified.

CARCINOGENICITY
Not classified.

REPRODUCTIVE TOXICITY
Classification not possible.

TARGET ORGANS SYSTEMIC TOXICITY (TOST) – Single Exposure


Not classified.

TARGET ORGANS SYSTEMIC TOXICITY (TOST) – Repeated Exposure


Not classified.
12. ECOLOGICAL INFORMATION

ACUTE TOXCITIY – FISH


Not classified

ACUTE TOXICITY- CRUSTACEA


Not classified

ACUTE TOXICITY- ALGAE


Harmful to aquatic life

BIODEGRADABILITY
The product is expected to be biodegradable.

MOBILITY
The product contains substances which are soluble and may spread in water systems.

13. DISPOSAL CONSIDERATION

GENERAL INFORMATION
In case of spill eliminate all sources of ignition (no smoking, flares, sparks or flames in immediate
area). All equipment used when handling the product must be grounded. Do not touch or walk
through spilled material. Stop leak if you can do it without risk.

Prevent entry to waterways, sewers, basements or confined areas. A vapor suppressing foam may be
used to reduce vapors.

Keep spectators away. Dike and contain spill with inert material (e.g. sand or earth). Transfer
recovered chemical and diking material to a separate suitable container for disposal according to
local regulations. Use clean non-sparkling tools to collect absorbed material.

DISPOSAL METHODS
Dispose according to local and national regulations.

14. TRANSPORT INFORMATION

PROPER SHIPPING NAME : PAINT


UN NUMBER : 1263
ROAD TRANSPORT NOTES : Avoid releasing to the environment.
RAIL TRANSPORT NOTES : Avoid releasing to the environment.
SEA TRANSPORT NOTES : Do not release to the environment.
15. REGULATORY INFORMATION

TOXIC SUBSTANCES AND HAZARDOUS AND NUCLEAR WASTES CONTROL ACT OF


1990 (R.A. 6969)
When this product, in its liquid state, becomes a waste, it is categorized as non-hazardous waste
based on the classification for a hazardous waste, that is, ignitability, corrosivity, reactivity and
toxic. However, paints/ resins/ lattices/ inks and dyes have waste number F601 to F699.

PERSISTENT ORGANIC POLLUTANTS (POPs)


No chemicals used in the manufacture of this product are included in the list of POPs.

PRIORITY CHEMICAL LIST (DAO 98-58)


No chemicals used in the manufacture of this product are included in the list of priority chemicals.

PHILIPPINE INVENTORY OF CHEMICALS AND CHEMICAL SUBSTANCES (PICCS)


All chemical substances and preparations used in the manufacture of this product are listed in the
Philippine Inventory of Chemicals and Chemical Substances.

CHEMICAL CONTROL ORDER FOR MERCURY & MERCURY COMPOUNDS (DAO 97-39)
No chemicals used in the manufacture of this product are included in the list of controlled chemicals.

CHEMICAL CONTROL ORDER FOR CYANIDE AND CYANIDE COMPOUNDS (DAO 97-38)
No chemicals used in the manufacture of this product are included in the list of controlled chemicals.

CHEMICAL CONTROL ORDER FOR OZONE DEPLETING SUBSTANCES (DAO 2000-18)


No chemicals used in the manufacture of this product are included in the list of controlled chemicals.

CHEMICAL CONTROL ORDER FOR ASBESTOS (DAO 2000-2)


No chemicals used in the manufacture of this product are included in the list of controlled chemicals.

CHEMICAL CONTROL ORDER FOR POLYCHLORINATED BIPHENYLS (DAO 2004-01)


No chemicals used in the manufacture of this product are included in the list of controlled chemicals.

ECOLOGICAL SOLID WASTE MANAGEMENT ACT OF 2000 (R.A. 9003)


Used containers, drained and/or rigorously scraped out and containing dry residues of the product,
are categorized as non-hazardous waste.

REVISED EFFLUENT REGULATIONS OF 1990 (DAO 90-35)


Disposed treated waste according to the effluent standards.

OCCUPATIONAL SAFETY AND HEALTHS STANDARDS (P.D 42)


Workplace Exposure Limits (RULE 1070), Personal protective Equipment (RULE 1080), Hazardous
Materials (RULE 1090), Identification of Piping System (RULE 1230), Fire Protection and Control
(RULE 1940)
16. OTHER INFORMATION

The information provided in this Safety Data Sheet is to the best of our knowledge. Information
given are designed only for as guidance for safe handling, use, processing, storage, transportation,
disposal and release and is not to be considered a warranty or quality specification. Information
relates only to the specific material designated and may not be valid for such material used in
combination with other materials or in any process. However, no warranty guarantee or
representation is made to its accuracy, reliability or completeness.

The preparation of this Safety Data Sheet is in accordance with the requirements of the Globally
Harmonized System for Classification and Labelling of Chemicals (GHS).

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