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b) decrease in pressure –
Effect of Temperature
a) increase in temperature –
b) decrease in temperature –
This reaction takes place in a 5.0 L flask. At equilibrium the flask was found to contain 0.0070 mol N2(g)
and 0.0022 mol Cl2(g). If the Keq is 3.0 x 1011, what is the number of moles of NCl3(g) present at
equilibrium?
* remember to change moles to conc.
c
* n=
v
[ Prod.]
* also Keq=
[ React.]
* rearrange correctly and solve
Part B: ICE Problems
6. Initially the concentrations of N2 and O2 are both 1.8 mol/L. If at equilibrium the concentration of
NO is 1.8 mol/L find Keq for the reaction.
7. When 2.0 mol of PCl5(g) is headted in a 2.0 L container the following equilibrium is established. If
there is a 60% reaction what is the Keq for this reaction?
8. 1.00 mol/L sample of N2(g) and H2(g) are placed in a flask. If 25% of N2(g) reacts what is the Keq for
this equilibrium?
2.00 mol of H2(g) and 3.00 mol of I2(g) are placed in a 1.00 L reaction. What is the equilibrium
concentration of each gas?
Remember that...
– if there is a shift to the products, that means the Keq will increase
– if there is a shift to the reactants, the Keq will decrease
– a reaction going to completion has a very high Keq
– a reaction that barely reacts has a very low Keq
Also:
– change in concentration has NO effect on Keq
– change in temperature will have an effect on Keq... You have to go through the generalizations
for temperature, and find where the shift is – then the Keq can be determined
p. 535: 3
p. 538: 8, 19, 30
Generalizations
Pressure:
1) If the pressure of a system is increased, there is a shift to the side with the lowest number of gas
phase molecules
Inc. pressure = shift to LESS gas molecules
2) If the pressure of a system is increased, there is a shift to the side with the lowest number of gas
phase molecules
Dec. pressure = shift to MORE gas molecules
Temperature:
Equilibrium constant: