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INDEX
Å angstrom.................2, 23 current transfer ratio........16 eV electron volt..........3, 23 electrostatic potential ..21
acceptor atoms ................. 7 cutoff ..............................17 Ev valence band energy level ideal ...........................18
alloyed junction................ 3 degenerate.......................14 .................................... 6 real .............................18
alpha...............................16 del ..................................22 excess carriers.................. 9 n doping gradient factor .13
amorphous ....................... 2 density of states................ 6 excess hole concentration . 9 n0 equilibrium free electron
angstrom .....................2, 23 dependent wave function .. 4 expansions ......................23 concentration ............... 7
angular momentum........... 5 depletion charge ..............20 extrinsic........................2, 6 N0 volume impurity
annealing ......................... 3 depletion layer capacitance f(E) Fermi-Dirac concentration ..............11
avalanche breakdown ......14 ...................................12 distribution function..... 6 NA Avogadro's number....23
Avogadro's number..........23 depletion layer width.......21 Fermi energy level ........... 6 nabla operator .................22
Balmer............................. 4 diffused junction .............. 3 Fermi-Dirac distribution natural log.......................22
band diagram ..................10 diffusion .........................16 function ....................... 6 Nc total density of states,
band gap .......................... 6 diffusion capacitance.......12 flat-band voltage .............19 conduction band........... 6
band-bending ..................18 diffusion coefficient ......... 9 flourescence ..................... 3 ni intrinsic concentration . 6
base transport factor ........16 diffusion current............... 8 flux density...................... 9 ni(T) temperature-dependent
base-to-collector current diffusion equation .......9, 16 gain factor.......................17 carrier concentration .... 7
amplification factor .....17 diffusion length ................ 9 gate voltage.....................18 normal active mode .........17
beta.................................17 diode equation.................12 grad operator...................22 normal mode ...................17
BJTs ...............................16 diodes .............................14 grown junction ................. 3 NS area surface impurity
Bohr model ...................... 5 Dn diffusion coefficient ... 9 h Planck's constant .........23 concentration ..............12
Boltzmann constant .........23 donor atoms ..................... 7 hyperbolic functions ........23 Nv total density of states,
Boltzmann distribution ..... 6 donor binding energy........ 5 hν photon........................ 3 valence band ................ 6
boundary width .........10, 11 doping.............................. 2 I0 reverse saturation current p+-n junction ...................13
Bravais lattice .................. 2 gas diffusion ...............11 ...................................12 p+-n-p transistor ........15, 16
breakdown ......................14 layer diffusion.............12 ID drain current ...............20 p0 equilibrium hole
C capacitance ...........12, 20 dot product......................23 interface charge...............20 concentration ............... 7
c speed of light...............23 Dp diffusion coefficient ... 9 interface voltage..............19 Paschen............................ 4
capacitance drain current ...................20 intrinsic ........................2, 6 permittivity of free space .. 5,
junction ......................12 drift current...................... 8 intrinsic to Fermi potential 23
capacitance of p-n junctions drift velocity..................... 8 .............................19, 20 photo diode .....................14
...................................12 E donor binding energy ... 5 inversion .........................21 photoelectric .................... 4
carrier concentration E(x) electric field .......8, 11 inversion charge ..............20 photoluminescence ........... 3
at equilibrium .............. 7 Ebers-Moll equations ......17 inverted mode .................17 photon.............................. 3
temperature dependence7 Ec conduction band energy ion implantation ............... 3 pinch-off voltage .............18
cathodoluminescence........ 3 level ............................ 6 It transmitted light intensity Planck's constant .............23
channel ...........................22 EF Fermi energy level...... 6 .................................... 8 p-n junctions .................... 3
charge across a junction...11 effective density of states . 6 J current density.............. 8 p-n step junction .............10
charge density .................21 effective mass .................. 5 JFET...............................18 polycrystalline.................. 2
charge density in a transition Eg energy band gap.......... 6 k Boltzmann constant .....23 potential barrier height....14
region .........................11 Einstein relation............... 7 Laplacian ........................23 punch through .................14
charge storage capacitance12 electric field..........8, 11, 21 light ................................. 3 Q charge across a junction11
Cj junction capacitance .. 12, electroluminescence ......... 3 light transmission............. 8 Q charge density, MOSFET
13 electron Ln diffusion length........... 9 ...................................21
common-base current gain16 bonding........................ 7 log function.....................22 q elementary charge .......23
common-emitter current gain centripetal force ........... 4 Lp diffusion length........... 9 Qd depletion charge ........20
...................................17 effective mass of .......... 5 luminescence ................... 3 Qi interface charge .........20
conductivity ..................... 7 energy.......................... 4 Lyman.............................. 4 Qn inversion charge ........20
constants .........................23 intrinsic concentration of6 m* effective mass............ 5 Qs surface charge ...........20
contact potential..............10 mobility ....................8, 9 m0 electron mass ............23 quantum mechanics .......... 3
cross product...................23 orbit radius .................. 5 metal semiconductor work r electron orbit radius...... 5
csch ................................23 electron mass ..................23 function ......................19 R Rydberg constant ........23
ctnh.................................23 electron volt ..................... 3 miscellaneous..................22 recombination .................. 9
current electron-hole pairs............ 9 MOSFET ........................18 direct ..........................13
density......................... 8 electrostatic potential ......21 capacitance .................20 indirect .......................13
diffusion ...................... 8 emitter injection efficiency17 charge density.............21 recombination lifetime ..... 9
diode ..........................12 energy band gap ............... 6 current ........................20 relative permittivity.......... 5
drain ...........................20 energy gap........................ 2 depletion layer ............21 reverse saturation current 12
drift ............................. 8 epitaxy............................. 2 design considerations ..22 Rydberg constant.............23
reverse saturation........12 equililbrium ....................10 electric field................21 saturation ........................17
transistor......... 15, 16, 17 Euler's equation...............22
In a crystal, atoms are arranged in a periodic array Silicon is not a metal because there is a gap between
called a lattice structure. Some types of lattice the bonding states and the non-bonding states. Two
structure are 1) simple cubic having one atom at states of the same energy are said to be degenerate.
each corner of a cube for a total internal content of 1 Semiconductors have a small energy gap.
atom/cube, 2) body-centered cubic having an Insulators have a large energy gap. In metals there
additional atom in the center of the cube, 2 is overlap between bonding states.
atoms/cube, 3) face-centered cubic having an atom Intrinsic semiconductors such as pure Si and Ge,
at each corner and another in the center of each have an identical number of electrons in the
outer face, 4 atoms/cube, 4) diamond having a face- conduction band and holes in the valence band. At
centered structure with 4 additional internal atoms, 8 0K, all electrons return to the valence band.
atoms/cube. The length of each side of the cube is Doping is the controlled introduction of impurities into a
the lattice constant, denoted by a, and expressed in pure substance. This generally results in an
units of angstroms (1Å = 10-8 cm). We are extrinsic semiconductor, i.e. a material having
sometimes interested in the nearest neighbor either a surplus of electrons (n-type) or a surplus of
distance, the center-to-center distance between the holes (p-type).
two closes atoms in a cube, expressed in terms of a. Single crystal means that the atoms are arranged in a
In the diamond lattice, this is ¼ the length of the single array. Polycrystalline means that atoms are
diagonal connecting the most distant opposing in multiple arrays, having grain boundaries between
corners of the cube, a 3 / 4 . them. Amorphous means the atoms are arranged
Crystals are tailored in with no definite form.
order to control 1) Bravais (bra-VAY) is a lattice with one atom per cell.
electron transport, 2) A cubic close-packed plane has layers of atoms
absorption and arranged in 3 offset arrays as shown in the
radiation of light. illustration at right.
Elemental Epitaxy is the technique of growing an oriented, single-
semiconductors have crystal layer on a substrate layer having an identical
a diamond lattice or similar lattice structure. Epitaxy methods include
structure. Binary 1) CVD Chemical Vapor Deposition (also used for
compounds polycrystaline and amorphous deposition), 2) LPE
composed of 3-layer close-packed plane Liquid-Phase Epitaxy - growth from a melt, 3) MBE
combinations from Molecular Beam Epitaxy - elements are evaporated
groups II-V and II-VI have a zinc blende structure in a vacuum.
similar to diamond structure.
p0 n0 = ni − E g / 2 kT 1
2
ni = N c N v e f (E ) = ( E − E F ) / kT
1+ e
p0 = concentration of holes in the valence band at
equilibrium [cm-3] This value is often taken to be equal f(E) = Fermi-Dirac distribution function, the distribution of
to Na, the acceptor doping concentration, since at room electrons over a range of allowed energy levels at
temperature it may be assumed that each acceptor will thermal equilibrium, having a value from 0 to 1.
host an electron from the valence band. E = an available energy state [eV]
n0 = concentration of electrons in the conduction band at EF = Fermi level—the energy level at the center of
equilibrium [cm-3] This value is often taken to be equal distribution of the free electron population [eV]
to Nd, the donor doping concentration, since at room k = Boltzmann’s constant 8.62 × 10-5 eV/K
temperature it may be assumed that each donor has
T = absolute temperature [K]
contributed an electron to the conduction band.
ni = intrinsic concentration of electrons in the conduction kT = constant (0.02586 when T = 300 and k is in eV/K)
band (constant for a particular material at Ec = the energy level at the conduction band [eV]
temperature) [cm-3] Ev = the energy level at the valence band [eV]
Nc = effective density of states in the conduction band Ec Ec
[cm-3]
Ec
Nv = effective density of states in the valence band [cm-3]
EF
EF
Eg = band gap energy [eV] EF
k = Boltzmann’s constant 8.62 × 10-5 eV/K Ev Ev Ev
T = absolute temperature [K] Intrinsic n-type p-type
kT = constant (0.02586 when T = 300 and k is in eV/K) semiconductor semiconductor semiconductor
2πm p * kT
3/ 2 k = Boltzmann’s constant
N v = 2 2
1.38 × 10-23 J/K
h T = 300 K at room
temperature
[cm-3] h
Nv = effective density of states in the valence band [cm-3] ni = intrinsic concentration of electrons in the conduction
Ec = the conduction band energy level [eV] band (constant for a particular material at
Ei = the intrinsic energy level [eV] temperature) [cm-3]
EF = Fermi level—the energy level which is the center of k = Boltzmann’s constant 8.62 × 10-5 eV/K
distribution of the free electron population [eV] T = absolute temperature [K]
kT = constant (0.02586 when T = 300 and k is in eV/K) h = Planck's constant, 6.63×10-34 J-s or 4.14×10-15 eV
mn* = effective mass of an electron [kg]
mp* = effective mass of a hole [kg]
SPACE CHARGE NEUTRALITY Eg = band gap energy [J, eV]
The sum of the holes (p0) and ionized donor atoms
(Nd+) equals the sum of the negative charges (n0) and
ionized acceptor atoms (Na-). It is expected that all THE EINSTEIN RELATION
donors and acceptors are ionized at room
D = diffusion coefficient [cm2/s]
temperature.
D kT µ = electron or hole mobility [cm2/V-s] p8.
+
p0 + Nd = n0 + N a
−
= kT/q = constant [V] (0.02586 V when
µ q T = 300 and k is in J/K)
Certain techniques are employed when working with q = electron charge 1.60 × 10-19 [C]
this equation, e.g. if the material is n-type, then the
value of Nd+ will be high and p0 can be taken to be
zero. Also, the relation n0p0 = ni 2 can be used to
σ CONDUCTIVITY
reduce the number of unknowns.
σ = (sigma) conductivity [(Ω-cm)-1]
q = electron charge 1.6022 × 10-19 [C]
n = concentration of electrons [cm-3]
σ = qnµ n p = concentration of holes [cm-3]
µn = electron mobility [cm2/V-s] p8.
µp = hole mobility [cm2/V-s]
Since all holes eventually combine (in a wide n-region), ∆n = excess carrier concentration at t=0 [cm-3]
δp=0 at x=∞ so C1=0. At x=0, δp=∆p by definition, so C2=∆p. t = time [s]
Therefore the final solution is: (see EXCESS CARRIERS)
τn = recombination lifetime (applies to minority carriers
δ p ( x ) = ∆ pe
− x / Lp
only) [s]
DIFFUSION LENGTH
Ln ≡ D nτ n Lp ≡ Dpτ p
Lp, Ln = diffusion length; the average distance a hole, or
electron, diffuses before recombining; the distance at
which the excess hole (or electron) distribution is
reduced to 1/e of its value at the point of injection
(carrier injection always implies minority carriers) [cm]
Dn, Dp = diffusion coefficient for electrons, holes [cm2/s]
τn = recombination lifetime (applies to minority carriers
only) [s]
2 IE IC
+
p n p emitter base collector
emitter base collector p+ n p
(1) injected holes lost to recombination in the base
(2) holes that fail to be recombined in the base are swept ∆ pE Wb ∆pC
across the reverse-biased collector junction by the
electric field
(3) thermally generated electrons and holes are swept
( )
∆pE = pn e qVEB / kT − 1 , ∆pC = pn e qVCB / kT − 1 ( )
across the CB junction by the electric field make up the ∆pE, ∆pC = excess hole concentration at the edge of the
reverse saturation current of the collector junction
(4) electrons supplied by the base contact recombine with emitter (∆pE) and collector (∆pC) depletion regions
holes from (1), hence (1) and (4) are equal in [cm-3]
magnitude VEB, VCB = emitter to base voltage, normally positive (VEB),
(5) electrons injected across the forward-biased emitter collector to base voltage, normally negative (VCB) [V]
junction; this current is small due to the heavily doped
emitter
Wb = the width of the neutral base region; very important to
the speed and efficiency of the transistor; this region is
For a n-p-n transistor, simply reverse the roles of electrons short so that most of the injected holes pass through to
and holes. the collector (assisted by the electric field at the CB
junction) without recombining in the base. [cm]
C1 = −W / L
C2 = −Wb / Lp IC = collector current [A]
e b p −e b p −e
W /L Wb / L p
e IB = base current [A]
∆pE, ∆pC = excess hole concentration at the edge of the q = electron charge 1.6022 × 10-19 [C]
emitter (∆pE) and collector (∆pC) depletion regions A = cross-sectional junction area (uniform for both
[cm-3] junctions) [cm2]
Wb = the width of the base region not taken up by transition Dp = diffusion coefficient for holes [cm2/s]
regions [cm] Lp = diffusion length; the average distance a hole diffuses
Lp = diffusion length; the average distance a hole diffuses before recombining [cm]
before recombining [cm] ∆pE = concentration of excess holes at the boundary of the
emitter-base depletion region [cm-3]
( )
∆pE = pn e qVEB / kT − 1
∆ p DIFFUSION IN THE BASE REGION
∆pC = concentration of excess holes at the boundary of the
The following is applicable to a p-n-p transistor; these collector-base depletion region (∆pC = -pn when the
values are used in other equations. The ∆ symbol collector is strongly reverse-biased) [cm-3]
usually indicates a difference between two values; in (
∆pC = pn e qVCB / kT − 1 )
this case it would be the difference between the total
number of holes and those not available for Wb = width of the base region [cm]
conduction, two values in which we are not interested.
∆ pE = excess hole concentration at the boundary of the
emitter-base depletion region [cm-3] α CURRENT TRANSFER RATIO
∆ pC = excess hole concentration at the boundary of the The ratio of collector to emitter current, or common-
collector-base depletion region (∆pC = -pn when the base current gain. To make α close to 1, make the
collector is strongly reverse-biased) [cm-3] base narrow so not many holes recombine in the
(
∆pE = pn ( e qVEB / kT − 1) ∆pC = pn e qVCB / kT − 1 )
base.
IC b BI Ep β
pn = concentration of excess holes in the base region [cm-3]
α= = = = Bγ =
I E a I En + I Ep β +1
q = electron charge 1.6022 × 10-19 [C]
a = (qADp/Lp) ctnh(Wb/Lp)
VEB = emitter-to-base voltage [V] b = (qADp/Lp) csch(Wb/Lp)
VCB = collector-to-base voltage [V] B = ic/iEp = bpn, the base transport factor, the fraction of
injected holes that make it across the base to the
collector
IEp = emitter current due to holes [A]
IEn = emitter current due to electrons [A]
γ = emitter injection efficiency
I C = I CN + I CI (c1)
γ EMITTER INJECTION EFFICIENCY
= α N I ES ( eqVEB / kT − 1) − ICS ( e qVCB / kT − 1) (c2)
γ ≈ 1 is the emitter current due entirely to hole
= α N I E − I CO ( e qVCB / kT − 1)
injection (carrier injection always implies minority carriers). (c3)
To make γ as large as possible, make the emitter
heavily doped. The superscripts indicate which side of To measure the current, use equations e2 and c2. To get
the emitter-base junction is being referred to. IES, measure IE with the collector open and the EB junction
−1 −1 reverse-biased. That way, eqVEB / kT is very small. To get α I,
Ln n µ p W Ln n µ p make VEB large and negative (reverse-biased), then αI = -
γ = 1 + pp n nn tanh nb ≈ 1 + pp n nn
Ln p p µ p Ln pp µ p
L p dIE/dIC. To get α N, make VCB large and negative (reverse-
biased), then αN = -dIC/dIE. To get IES, measure IC with the
I Ep emitter open and the CB junction reverse-biased. This
= information comes from The Physics of Semiconductor Devices, D.A. Fraser,
I Ep + I En
p. 101, and may not be correct—variables were named differently.
collector junction is
reverse-biased. operating
point is on the load line.
xn
saturation – collector
junction voltage is zero or 0 Wb
forward-biased Cutoff
Normal Active
VG GATE VOLTAGE
The gate voltage can be broken down into
components of the voltage drop across the interface,
the voltage drop across the depletion region, and the
voltage required to achieve flat-band conditions.
VG = Vi + φs + VFB
W = channel width;
STRONG INVERSION corresponds to where
band-bending takes
When a positive gate voltage is applied, band- place [cm] p.21. x
bending takes place. When the gate voltage VG 1/2
reaches the threshold voltage VT, the intrinsic 2ε φ
energy band has bent down below the Fermi level by W = s s
a distance equal to the separation of the intrinsic and qN a
W
Fermi energy bands, and the channel area becomes
as strongly n-type as the rest of the substrate is p-
type, that is, the free electron concentration equals MOS ELECTROSTATIC POTENTIAL
the acceptor doping concentration. This condition is
V(x)
called strong inversion and at this point the channel VG = Vi + φs (ideal)
conducts.
−Qs d −Qs
ns = nie( EF −Ei ) kT
/ oxide semiconductor
Ec Vi = = Vi φs
VG
εi Ci
qφF
Strong Inversion: VG = gate voltage [V] x
Ei
depletion
insulator
Ei∞ − Ei 0
region
SiO 2
EF Vi = interface voltage; gate
= 2φF 2 qφF voltage drop across
q Ev the SiO2 interface [V]
φs = surface potential [V] W
φs = 2φF ⇔ ns = N A p.20. see INTERFACE VOLTAGE p19.
0 x=∞
ns = surface concentration of carriers (electrons) in the Qs = surface charge; the
-3 total charge density in
substrate at the semiconductor/SiO2 transition [cm ]
the substrate [C/cm2]
ni = intrinsic concentration of electrons in the conduction p.20.
10 -3
band, 1.5 × 10 for Si [cm ]
Ei∞ = the intrinsic energy level at infinity (far away from the
semiconductor/SiO2 interface) [eV]
Ei0 = the intrinsic energy level at the semiconductor/SiO2
interface [eV]
φs = surface potential [V] p.20.
φF = Fermi potential; Ei – EF, [V] p.19.
Na = acceptor concentration in the substrate [cm-3]
(B • aˆ )aˆ
1 nm = 10Å = 10 cm
ψ ψ
â â 1 eV = 1.6022 × 10-19 J 1 W = 1 J/S = 1 VA
The dot product is commutative and distributive: 1 V = 1 J/C 1 N/C = 1 V/m 1 J = 1 N· m = 1
A • (B + C) = A • B + A • C
C· V
A •B = B• A