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Processing Factors (continue) Processing Factors (continue)
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Processing Factors (continue) General Types of Evaporators
Scale deposition and materials of construction • In evaporation, heat is added to a solution to
• Some solutions deposit solid materials called scale on vaporize the solvent, which is usually water.
the heating surfaces.
surfaces These could be formed by • The heat is generally provided by the condensation of
decomposition products or by decreases in solubility. a vapor such as stream on one side of a metal
• The result is that the overall heat-transfer coefficient surfaces, with the evaporating liquid on the other side.
decreases, and the evaporator must eventually be
cleaned. • The type of equipment used depends primarily on the
configuration
fi ti off theth heat-transfer
h t t f surface f andd on the
th
• The materials used in construction of the evaporator means employed to provide agitation or circulation of
should be chosen to minimize corrosion. the liquid.
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General Types of Evaporators (continue) General Types of Evaporators (continue)
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General Types of Evaporators (continue) General Types of Evaporators (continue)
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General Types of Evaporators (continue) General Types of Evaporators (continue)
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General Types of Evaporators (continue) General Types of Evaporators (continue)
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Methods of Operation of Evaporators (continue) Methods of Operation of Evaporators
Single-effect evaporators Forward-feed multiple-effect evaporators
• The concept of an overall heat-transfer coefficient is • If the feed to the first effect is near the boiling point at
used in the calculation of the rate of heat transfer in the pressure in the first effect,
effect 1 kg of steam will
an evaporator. The general equation can be written evaporate almost 1 kg of water.
q = UAT = UA(Ts-T1) (8.2-1) • The first effect operates at a temperature that is high
enough that the evaporated water serves as the heating
q = the rate of heat transfer in W (btu/h) medium to the second effect.
heat transfer coefficient in W/hft2FF
U = the overall heat-transfer
A = the heat-transfer area m2 (ft2) • Here, again, almost another kg of water is evaporated,
Ts = the temperature of the condensing steam in K (F) which can then be used as the heating medium to the
T1 = the boiling point of the liquid in K (F) third effect.
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Methods of Operation of Evaporators (continue) Methods of Operation of Evaporators (continue)
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Methods of Operation of Evaporators (continue) Calculation Methods for Single-Effect Evaporators
Parallel-feed multiple-effect evaporators Heat and Material Balances for Evaporators
• Parallel feed in multiple-effect evaporators involves • The basic equation for solving for the capacity of a
the adding of fresh feed and withdrawal of single effect evaporator is Eq.(8.2.1),
single-effect Eq (8 2 1) which can be
concentrated product from each effect. written as
• The vapor from each effect is still used to heat the next q = UAT (8.4-1)
effect. This method of operation is mainly used when
the feed is almost saturated and solid crystals
y are the Where T K(F) is the difference in temperature
product, as in the evaporation of brine to make salt. between the condensing steam and the boiling liquid
in the evaporator.
Calculation Methods for Single-Effect Evaporators Calculation Methods for Single-Effect Evaporators
(continue) (continue)
Heat and Material Balances for Evaporators Heat and Material Balances for Evaporators
• In order to solve Eq.(8.4-1) the values of q in W (btu/h) must • The steam gives off only its latent heat, , where
be determined by making a heat and material balance on the
evaporator shown in Figure 8.4-1. = Hs-hs (8.4-2)
• Since the vapor V is in equilibrium with the liquid L,
the temperature of vapor and liquid are the same.
Also, the pressure P1 is the saturation vapor pressure
of the liquid of composition xL at its boiling point T1.
(This assume no boiling-point rise)
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Calculation Methods for Single-Effect Evaporators Calculation Methods for Single-Effect Evaporators
(continue) (continue)
Heat and Material Balances for Evaporators Heat and Material Balances for Evaporators
• For the material balance, since we are at steady state, • For the heat balance, since the total heat entering =
the rate of mass in = rate of mass out.
out Then,
Then for a total heat leaving,
leaving heat of feed + heat of steam
total balance, =heat in concentrated liquid + heat in
F=L+V (8.4-3) vapor + heat in condensed steam (8.4-5)
• For a balance on the solute (solids) alone, • This assumes no heat lost byy radiation or convection.
FxF = LxL (8.4-4) Substituting into Eq.(8.4-5)
FhF + SHs = LhL + VHV + Shs (8.4-6)
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Boiling-Point Rise of Solutions (continue) Boiling-Point Rise of Solutions (continue)
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Calculation Methods for Multiple-Effect Evaporators Calculation Methods for Multiple-Effect Evaporators
(continue)
Temperature Drops and Capacity of Multiple-Effect Temperature Drops and Capacity of Multiple-Effect
Evaporators Evaporators
• Temperature drops in multiple-effect evaporators.
evaporators The • Assuming that the solutions have no boiling-point rise
amount of heat transferred per hour in the first effect and no heat of solution and neglecting the sensible
of a triple-effect evaporator with forward feed as heat necessary to heat the feed to the boiling point,
Figure 8.2-3 will be approximately all the latent heat of the condensing
steam appears as lalent heat in the vapor.
q1 = U1A1T1 (8 5-1)
(8.5-1)
• This vapor then condense in the second effect, giving
• Where T1 is the difference between the condensing up approximately the same amount of heat:
steam and the boiling point of the liquid, Ts - T1.
q2 = U2A2T2 (8.5-2)
Calculation Methods for Multiple-Effect Evaporators Calculation Methods for Multiple-Effect Evaporators
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Temperature Drops and Capacity of Multiple-Effect Temperature Drops and Capacity of Multiple-Effect
Evaporators Evaporators
• This same reasoning holds for q3. Since q1 = q2 = q3, Hence the temperature drops T in a multiple-effect
• Hence,
then, approximately, evaporator are approximately inversely proportional
U1A1T1 = U2A2T2 = U3A3T3 (8.5-3) to the values of U, Calling T as follows for no
boiling-point rise,
• In commercial ppractice the areas in all effects are T = T1 + T2 + T3= Ts - T3 (8.5-5)
usually equal and
q/A = U1T1 = U2T2 = U3T3 (8.5-4) T1 = T 1/U1 (8.5-6)
1/U1 + 1/U2 + 1/U3
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Calculation Methods for Multiple-Effect Evaporators Calculation Methods for Multiple-Effect Evaporators
Capacity of multiple-effect evaporators Capacity of multiple-effect evaporators
• A rough estimate of the capacity of a three-effect • If we make the assumptions that the value of U is the
evaporator
p compared
p to a single-effect
g can be same in each effect and that the values of A are equal,
equal
obtained by adding the value of q for each evaporator: Eq.(8.5-7) becomes
q = q1+q2+q3=U1A1T1+U2A2T2+U3A3T3 q = UA(T1 + T2 + T3) = UA T (8.5-8)
(8.5-7) • Where T = T = T1+T2+T3 = Ts - T3
• If a single-effect evaporator is used with the same area
A, the same value of U, and the same total
temperature drop T, then
q = UA T (8.5-9)
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