AIEEE 2010 PAPER -1 : CHEMISTRY, MATHEMATICS & PHYSICS Test Booklet Code

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Part A - Chemistry(114 marks)- Question No. 4 to 16 and 20 to 30 consists of FOUR(4) marks each and
Question No. 1 to 3 and 17 to 19 consist of EIGHT(8) marks each for each correct response.

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Questions No. 31 to 33 and 43 to 45 consist of EIGHT(8) marks each for each correct response.

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Questions No. 61 to 64 and 69 to 70 consist of EIGHT(8) marks each for each correct response.

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 PART - “A” PHYSICS 1
Directions : M ×V 2
= ∆mc 2
2
Questions number 1 - 3 are based on the
following paragraph
2∆mc2
An initially parallel cylindrical beam travels in V=
a medium of refractiv e index M
µ ( I ) = µ0 + µ 2 I , where µ0 and µ2 are
2∆m
positive constants and I is the intensity of V= ⋅c
the light beam. The intensity of the beam is M
decreasing with increasing radius. 5. The binding energy per nucleon for the parent
1. The initial shape of the wavefront of the beam nucleus is E1 and that for the daughter nuclei
is
(a) planar is E2 . Then
(b) convex
(c) concave (a) E1 = 2 E2 (b) E2 = 2 E1
(d) convex near the axis and concave near (c) E1 > E2 (d) E2 > E1
the periphery
Sol. (a) Sol. (d)
2. The speed of light in the medium is
2
(a) maximum on the axis of the beam + + Q=∆mc
(b) minimum on the axis of the beam M+∆m M M
(c) the same eveywhere in the beam 2 2
(d) directly proportional to the intensity I
E1 = B.E. per nucleon of Parent Nuclei
Sol. (c)
3. As the beam enters the medium, it will E2 = B.E. per nucleon of daughter Nuclei
(a) travel as a cylindrical beam
(b) diverge E2 > E1
(c) converge Directions :
(d) diverge near the axis and converge near Questions number 6-7 contain Statement-1
the periphery and Statement-2. Of the four choices given
Sol. (a) after the statements, choose the one that best
Directions : describes the two statements.
Questions number 4-5 are based on the 6. Statement - 1 :
following paragraph. When ultraviolet light is incident on a
A necleus of mass M + ∆m is at rest and photocell, its stopping potential is V0 and the
decays into two daughter nuclei of equal mass maximum kinetic energy of the photoelectrons
M is K max . When the ultraviolet light is replaced
each. Speed of light is c .
2 by X-rays, both V0 and K max increase.
4. The speed of daughter nuclei is
Statement - 2 :
∆m ∆m Photoelectrons are emitted with speeds
(a) c (b) c ranging from zero to a maximum value
M + ∆m M + ∆m because of the range of frequencies present
in the incident light.
2∆m ∆m (a) Statement - 1 is true, Statement - 2 is false.
(c) c (d) c
M M (b) Statement - 1 is true, Statement - 2 is true;
Statement - 2 is the correct explanation of
Sol. (c)
Statement -1.
Speed of daughter Nuclei
(c) Statement - 1 is true, Statement - 2 is true;
1M  2 1 M  2 Statement - 2 is not correct explanation of
V +  V = ∆mc
2
 Statement -1.
2 2  2 2  (d) Statement - 1 is false, Statement - 2 is true.

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Sol. (a)
B
7. Statement - 1 :
Two particles moving in the same direction do
not lose all their energy in a completely X X'
inelastic collision. (b)
Statement - 2 : d d
Principle of conservation of momentum holds
true for all kinds of collisions. B
(a) Statement - 1 is true, Statement - 2 is false.
(b) Statement - 1 is true, Statement - 2 is true;
X X'
Statement - 2 is the correct explanation of (c)
Statement -1.
(c) Statement - 1 is true, Statement - 2 is true; d d
Statement - 2 is not correct explanation of
Statement -1. B
(d) Statement - 1 is false, Statement - 2 is true.
Sol. (d) X X'
8. The figure shows the position - time (x-t) graph (d)
of one-dimentsional motion of a body of mass
d d
0.4 kg. The magnitude of each impulse is
Sol. (b)
10. A ball is made of a material of density ρ
2
where ρ oil < ρ < ρ water wih ρoil and ρ water
x (m) representing the densities of oil and water,
respectively. The oil and water are immiscible.
If the above ball is in equilibrium in a mixture
0 2 4 6 8 10 12 14 16 of this oil and water, which of the folowing
t (s) → pictures represents its equilibrium position ?

(a) 0.2 Ns (b) 0.4 Ns

(c) 0.8 Ns (d) 1.6 Ns
Sol. (c)
m = 0.4 kg
I = ∆ρ (a) (b)

= m ⋅ (Vt − Vi )

 2  −2  
= 0.4 ×  −   
 2  2 

= 0.4 × 2 = 0.8 N − s
9. Two long parallel wires are at a distance 2d
apart. They carry steady equal currents (c) (d)
flowing out of the plane of the paper as shown.
The variation of te magnetic field B along the
line XX ' is give by

B Sol.(c)
11. A thin semi-circular ring of radius r has a
positive charge q distributed uniformly over
X X'

(a) it. The net field E at the centre O is :
d d

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 PV γ = constant
ĵ
nRT γ
V = constant γ = 7/5
V
γ −1
iˆ TV γ −1 = constant TV
1 1 = T2V2γ −1
O
γ −1
T1  V2  7
−1
q ˆj q ˆj =  = (32) 5
(a) (b) T2  V1 
2π 2ε 0 r 2 4π 2ε 0 r 2
2 2
q q T1
= (32) 5 = (25 ) 5 = 2 2
(c) − (d) −
ˆj ˆj
4π 2ε 0 r 2 2π 2ε 0 r 2 T2

q T1 T 1
Sol.(d) λ =
=4 ⇒ 2 =
πr T2 T1 4

T2 1
−1 = −1
T1 4

X θ θ X T2 − T1 1 −3
dE cos θ θ θ dE cos θ = −1 =
T1 4 4

dE dE T1 − T2 3
dE sinθ η= = = 75%
T1 4
dE sinθ 13. The respective number of significant figure for
the numbers 23.023, 0.0003 and 2.1× 10 −3
E = ∫ d ε sin θ are
(a) 4, 4, 2 (b) 5, 1, 2
1 q rd θ (c) 5, 1, 5 (d) 5, 5, 2
=∫ sin θ
4πε 0 πr r 2 Sol. (b)
14. The combination of gates shown below yields:
q
= [ − cos θ]
4π ε 0 r 2
2
A

−q 2q
X
2[
cos θ]0
π
= =
4π ε0r
2
4 π2 ε 0 r 2 B

q (a) NAND gate (b) OR gate

E=
2π ε 0 r 2
2 (c) NOT gate (d) XOR gate
Sol. (b)

−q ˆ
E= j X = A⋅ B = A+ B
2π2 ε0 r 2
= A+ B = OR
12. A diatomic ideal gas is used in a Carnot engine
as the working substance. If during the 15. If a source of power 4 kW produces 10 20
adiabatic expansion part of the cycle the photons/second, the radiation belongs to a
volume of the gas increases from V to 32V , part of the spectrum called
the efficiency of the engine is : (a) γ -rays (b) X -rays
(a) 0.25 (b) 0.5 (c) ultraviolet rays (d) microwaves
(c) 0.75 (d) 0.99 Sol. (b)
Sol. (c)
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 1020 × 6.6 ×10−34 × 3 × 108 r 5 2 1 3 
r
4 × 1000 = 0 ∫
R ∫0
= 4πρ x dx − x dx 
λ 0 4 
19.8 ×10−6
λ= = 4.95 × 10 −9  5  x 3 r 1  x 4 r 
4 ×103 = 4πρ 0    −   
 4  3  0 R  4  0 
= 49.5Å X-ray
16. A radioactive nucleus (initial mass number A
and atomic number Z) emits 3 α − particles 5 r4 
= 4πρ 0  r 3 −
and 2 positrons. The ratio of number of
12 4 R 
neutrons to that of protons in the final nucleus
will be
4πρ 0 3  5 r 
= r  − 
A−Z −4 A− Z −8 4 3 R 
(a) (b)
Z −2 Z −4
5 r 
A−Z −4 A − Z − 12 q = πρ 0 r 3  − 
(c) (d) 3 R 
Z −8 Z −4
Sol. (c) 1 q 1 πρ 0 r 3  5 r 
E= = −
4π ∈0 r 2 4π ∈0 r 2  3 R 
Z X A → z −8Y A−12 + 3 2α 4 + 2 H β 0
↓ ρ0 r  5 r
E=  − 
Final Neutron
4 ∈0  3 R 

No. of Neutron A − 12 − ( z − 8) 18. In a series LCR circuit R = 200Ω and the

= voltage and the frequency of the main supply
No. of Pr oton Z −8 is 220 V and 50 Hz respectively. On taking
out the capacitance from the circuit the cur-
A−Z −4 rent lags behind the voltage by 30°. On taking
=
Z −8 out the inductor from the circuit the current
leads the voltage by 30°. The power dissipated
17. Let there be a spherically symmetric charge
in the LCR circuit is :
distribution with charge density varying as
(a) 242 W (b) 305 W
5 r (c) 210 W (d) Zero W
ρ (r ) = ρ 0  −  upto r = R , and
4 R Sol. (a)
200
ρ ( r ) = 0 for r > R , where r is the distance 1 x 30o
from the origin. The electric field at a distance
= L

3 200
r ( r < R ) from the origin is given by
1 xc
ρ0r  5 r  4πρ 0 r  5 r  = xL
(a)  −  (b)  −  3 200
3ε 0  4 R  3ε 0  3 R  xc
⇒ xc = xL
ρ0r  5 r  4 ρ0 r  5 r 
(c)  −  (d)  −  Pav = Vrms I rms cos φ
4ε 0  3 R  3ε 0  4 R 
220 30o
R
5 r  = 220 × ×1
Sol.(c) ρ = ρ 0  −  , r ≤ R 200
4 R
220 × 220 484
ρ = 0, r > R ⇒ dq = ρ. dV = = = 242
200 2
r 19. In the circuit shown below, the key K is closed
5 x 
q = ∫ ρ 0  −  .4π x 2 dx at t = 0. The current through the battery is
0 4 R
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 V ( R1 + R2 ) V ⇒ y 2 = x2 + c
(a)
R1 R2 at t = 0 and
R2 at t = ∞ 21. Let C be the capacitance of a capacitor
discharging through a resistor R . Suppose
V R1 R2 V
t =0 R2 at t = ∞
(b) at and t1 is the time taken for the energy stored in
R +R
1
2 2
2
the capacitor to reduce to half its initial value
V V ( R1 + R2 ) and t2 is the time taken for the charge to
(c) at t = 0 and at t = ∞ reduce to one-fourth its initial value. Then the
R2 R1 R2
ratio t1 / t2 will be:
V V R1 R2
at t = ∞ (a) 2 (b) 1
(d)
R2 at t = 0 and R12 + R2 2
(c) 1/ 2 (d) 1/ 4
Sol.(c) At t = 0, current in i n d = 0
Q2
v Sol.(d) U = ∝ Q2
I= 2c
R2 2
U Q
at t = ∞, of inductor = 0 = 
U / 2  Q1 
R1 R2
Req = 2
R1 + R2 Q
2= 
 Q1 
v ( R1 + R2 )
I=
R1 R2 Q
= 2
20. A particle is mov ing with v elocity Q1


v = K ( y iˆ + x ˆj ), where K is a constant. Q0
⇒ Q0 e −t1 / τ = ⇒ e t1 / τ = 2
The general equation for its path is : 2
(a) y 2 = x 2 + constant t1
= ln 2
(b) y = x + constant
2 t

(c) y 2 = x + constant t1 = ln 2.τ

(d) xy = constant Q0
Q=
4
Sol.(a) v = k ( y iˆ + x ˆj )
Q0
vx = k y Q0 e −t2 / τ =
4
vy = k x e2 t2 / τ = 4
t2 = ln 4τ
vy x
⇒ = ⇒ x vx = y v y t1 ln 2 1 ln 2 1
vx y = = =
t2 ln 4 2 2.ln 2 4
xd x yd y 22. A rectangular loop has a sliding connector
∫ dt ∫
=
dt PQ of length l and resistance R Ω and it
is moving with a speed υ as shown. The set-
∫ xdx = ∫ ydy up is placed in a uniform magnetic field going
into the plane of the plane of the paper. The
x2 y 2 three currents I1 , I 2 and I are :
⇒ = ⇒ x2 = y 2 + c
2 2
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   t x 
P l y = 0.02 ( m ) Sm  2π  − 
  0.04 0.50  
T = Tension:
RΩ RΩ υ RΩ 2π
w=
I1 I2 0.04
Q T 2π
V= , k=
µ 0.50
Bl υ Bl υ
(a) I1 = I 2 = ,I =
T
6R 3R V2 =
µ
Bl υ 2 Bl υ
(b) I1 = − I 2 = ,I =
( )
2
R R
T = µV 2 = µ ⋅ w k
Bl υ 2 Bl υ
(c) I1 = I 2 = ,I =
( k)
2
3R 3R = µ⋅ w
Bl υ
(d) I1 = I 2 = I = 2
R  2π 0.50 
= 0.04 ×  × 
Sol. (c)  0.04 2π 

I1 I 1 0.50 × 0.50
R
I2 = 0.04 × ×
0.04 0.04
R R
ε= VBD
50 25.0
= × 0.50 = = 6.25 N
4 4
24. Two fixed frictionless inclined planes making
I2 an angle 300 and 600 with the vertical are
shown in the figure. Two blocks A and B are
I I2 placed on the two planes. What is the relative
vertical acceleration of A with respect to B?
R
A
2VBl
I = B
3R
I VBl
I1 = I 2 = =
0 0
60 30
2 3R
23. The equation of a wave on a string of linear (a) 4.9 ms −2 in vertical direction
mass density 0.04 kg m −1 is giv en by
(b) 4.9 ms −2 in horizontal direction
  t x  (c) 9.8 ms −2 in vertical direction
= 0.02 ( m ) sin  2π  − .
  0.04 ( s ) 0.50 ( m )  (d) Zero
The tension in the string is 3g
Sol.(a) Acceleration in Ist case =
(a) 6.25N (b) 4.0N 4
(c) 12.5 N (d) 0.5N g
Acceleration in IInd case =
Sol. (a) 4
m Difference = 4.9 m / s
2
µ= = 0.04 kg / m
L
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25. For a particle in uniform circular motion, the
Where iˆ, ˆj and k̂ are unit vectors along x, y
acceleration a at a point P ( R, θ ) on the


and z -axis respectively..




circle of radius R is (Here θ is measured Sol.(d) L = r
× P r = xi + 7 j
from the x-axis)
x = u0 cos θ t
υ2 ˆ υ2 ˆ
(a) i+ j 1 2
R R y = u0 sin θ ⋅ t − gt
2
υ2 υ2


(b) − cos θiˆ + sin θ ˆj p = mv = m (vx j + v y j )
R R
= m (u0 cos θ j + (v0 sin θ − gt ) j
υ2 υ2
(c) − sin θ iˆ + cos θ ˆj
R R i j k
υ 2
υ 2

L = u0 cos θ t
1
u0 sin θ t − gt 2
(d) − cos θ iˆ − sin θ ˆj 0
R R 2
Sol. (d) mu0 cos θ mu0 sin θ − mgt 0

= k (mu02 cos θ sin θ ⋅ t = mu0 cos gt 2 )

y
P ( R ,θ )
1
− mu02u0 sin θ t + m u0 cos θ .gt 2
θ 2
600 a
θ c x 1
= − mu0 cos θ gt 2 kˆ
2
27. Two identical charged spheres are suspended
v2 v2 by strings of equal lengths. The strings make
ac = − cos θ i − sin θ j
R R
an angle of 300 with each other. When

suspended in a liquid of density 0.8 g cm −3 ,

26. A small particle of mass m is projected at an the angle remains the same. If density of the
angle θ with the x-axis with an initial velocity material of the sphere is 1.6 g cm −3 , the
υ0 in the x-y plane as shown in the figure. At dielectric constant of the liquid is
(a) 1 (b) 4
υ0 sin θ
a time t < , the angular momentum (c) 3 (d) 2
g
of the particle is : Sol.(d) ρe = 0.8

y ρ = 1.6
k =?
υ0
1 q2
tan150 = ⋅ 2 2 .......(1)
4πε0 4l sin 15 × mg
In water :
θ
x q2
T sin15 = ..........(2)
4πε0 k4l 2 sin150
1
(a) mg υ0t 2 cos θ iˆ (b) − mg υ0t 2 cos θ ˆj
2 T cos15 + β = mg

1 T cos15 = mg − β
ˆ (d) − mg υ0 t cos θ kˆ
2
(c) mg υ0t cos θ κ
2
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 = v × 1.6 − v × 0.8 g = v × 0.8 g 29. The potential energy function for the the force
between two atoms in a diatomic molecule is
mg a b
T cos150 = .....(3) approximately given by U ( x ) = − 6,
2 x12
x
where a and b are constants and x is the
q2 × 2
tan150 = .....(4) distance between the atoms. If the
4πε0 k 4l 2 sin150 mg dissociation energy of the molecule is

⇒K = 2 D = [U ( x = ∞) − U at equilibrium ], D is :
28. A point P moves in counter-clockwise
direction on a circular path as shown in the b2 b2
(a) (b)
figure. The movement of ' P ' is such that it 6a 2a
sweeps out a length s = t 3 + 5 , where s is
b2 b2
in metres and t is in seconds. The radius of (c) (d)
12a 4a
the path is 20 m . The acceleration of ' P '
a b
when t = 2s is nearly Sol.(d) U ( x) = 12
− 6 U (∞ ) = 0
x x
y dU a b
B = −12 13 + 6 7 = 0 for equilibrium
dx x x
P(x,y)
+2a b
= 7
m x13 x
20
2ax 7 = x13 b
x
O A x13b = x 7 2a

(a) 14 m / s 2 (b) 13m / s 2

x 6 b = 2a
2a 4a 2
(c) 12m / s 2 (d) 7.2 m / s 2 x6 = ⇒ x12 = 2
b b
Sol.(a) S = t 3 + 5
 2a  a b2
ds U  x6 =  = =
= 3t 2 = V  b  4a 2 4 a
dt
b2
d 2s
aT = = 6t b2
dt 2 ∴ D = U ( x = ∞) − U at equation =
4a
t = 2sec
30. Two conductors have the same resistance at
aT = 6.2 = 12m / s 2 00 C but their temperature coefficients of
resistance are α1 and α 2 . The respective
v 2 ( 3t )
2 3

ac = = temperature coeefficients of their series and

R R parallel combinations are nearly :

9t 4 9 × 24 9 × 16 36 α1 + α 2 α1 + α 2 α1 + α 2
ac = = = = (a) , (b) , α1 + α 2
20 20 20 5 2 2 2

α1 + α 2 α1α 2
(c) α1 + α 2 , (d) α1 + α 2 ,
2
 26  α1 + α 2
a = a +a 2 2 = (12) +  
2
2
T c
 5  Sol. (a)
 14m / s 2
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 PART - “B” CHEMISTRY 33. The correct sequence which shows
31. In aqueous solution the ionization constants decreasing order of the ionic radii of the
for carbonic acid are elements is :

K1 = 4.2 × 10 −7 and K 2 = 4.8 × 10−11 (a) O 2− > F − > Na + > Mg 2+ > Al 3+

Select the correct statements for a saturated (b) Al 3+ > Mg 2+ > Na + > F − > O 2−
0.034 M solution of the carbonic acid
(a) The concentration of H + is double that of (c) Na + > Mg 2+ > Al 3+ > O 2− > F −

CO32 − (d) Na + > F − > Mg 2+ > O 2− Al 3+

Sol.(a) Radius ∝ effective nuclear charge.
(b) The concentration of CO32 − is 0.034 M.
34. In the chemical reaction,
(c) The concentration of CO32 − is greater than
NH 2
−
that of HCO . 3
NaNO2 HBF4
(d) The concentration of H + and HCO are − A B
3 HCl , 278 K
approximately equal.
the compounds ‘A’ and ‘B’ respectively are-
Sol.(d) Since K1 > K 2 (a) nitrobenzene and chlorobenzene
(b) nitrobenzene and fluorobenzene
2nd ionisation of H 2CO3 can be neglected
(c) phenol and benzene
in compare to first.
(d) benzene diazonium chloride and
∵ (H ) = ( HCO )
+ − fluorobenzene
3
Sol. (d)
32. Solubility product of silver bromide is
5.0 × 10−13 . the quantity of potassium bro- NH 2 N 2Cl
mide (molar mass taken as 120 g mol −1 ) to

NaNO2
HCl / 278 K
→
be added to 1 litre of 0.05M solution of silver Benzene
nitrate to start the precipitation of AgBr is : diazonium
chloride
(a) 5.0 ×10−8 g (b) 1.2 ×10−10 g F
(c) 1.2 × 10−9 g (d) 6.2 ×10−5 g → HBF4
(Balz schiemann reaction)
Sol.(c) ( Ag ) in AgBr = 0.05
+
Fluorobenzene

For AgBr to be precipitate 35. If 10 −4 dm3 of water is introduced into a

K ip > K sp 1.0 dm3 flask at 300 K, how many moles of
water are in the vapour phase when equilib-
( Ag )( Br ) > 5 ×10
+ − −13
rium is established ?

(Given : Vapour pressure of H 2O at 300 K is

5 × 10−13
( Br ) > 0.05
−

3170 Pa; R = 8.314 J K −1 mol −1 )

( Br ) > 10
− −11 (a) 1.27 ×10−3 mol (b) 5.56 × 10 −3 mol

No. of mole of Br − in 1 litre > 10 −11 mol (c) 1.53 × 10−2 mol (d) 4.46 × 10 −2 mol

∴ no of mole of KBr > 10−11 mol Sol.(a) PV = nRT

wt of KBr > 10 −11 × 120 gm 3170

1.03 × 105
(1 − 10−4 ) = n × 0.082 × 300
= 1.2 × 10 −9 gm
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 3170
n= −3 mol. (a) H 5C6CH 2CH 2
1.03 × 105 × 24.6 = 1.27 ×10
36. From amongst the following alcohols the one C = CH 2
that would react fastest with conc. HCl and H 3C
anhydrous ZnCl2, is -
(a) 1-Butanol (b) 2-Butanol H 5C6 H
(c) 2-Methylpropan-2-ol (d) 2-Methylpropanol (b)
C =C
Sol. (c)
H CH (CH 3 )2
CH 3 CH 3
CH 3 − C − OH 
HCl / ZnCl2
→ CH 3 − C − Cl C6 H 5CH 2 CH 3
(c)
CH 3 CH 3 C =C
H CH 3
Tertiary alcohol reacts fastest
37. If sodium sulphate is considered to be
completely dissociated into cations and C6 H 5 CH (CH 3 ) 2
(d)
anions in aqueous solution, the change in C =C
freezing point of water ( ∆T f ) , when 0.01 mol H H
of sodium sulphate is dissolved in 1 kg of Sol.(d)
−1
water, is ( K f = 1.86 K kg mol ) :
CH 3
(a) 0.0186 K (b) 0.0372 K CH 2 − CH − CH
CH 3
(c) 0.0558 K (d) 0.0744 K OH
H 2 SO4 (protonation)
Sol.(c) ∆T f = 3 × 0.01× 1.86 = 0.0558 K

38. Three reactions involving H 2 PO4− are given H

below : + CH 3
−C − CH − C
(i) H 3 PO4 + H 2 O → H 3O + + H 2 PO4− H H
CH 3

(ii) H 2 PO4− + H 2 O → HPO42 − + H 3O +

(ii) H 2 PO4− + OH − → H 3 PO4 + O 2 −

CH (CH 3 )2
In which of the above does H 2 PO4− act as C =C
H H
an acid ?
(a) (i) only (b) (ii) only Conjugate alkene is of lower energy.
(c) (i) and (ii) (d) (iii) only 40. The energy required to break one mole of
−1
Sol.(b) H 3 PO4 + H 2O → H 3O + + H 2 PO4 − Cl − Cl bonds in Cl2 is 242 kJ mol . The
longest wavelength of light capable of break-
(Conjugate base)
ing a single Cl − Cl bond is
H 2 PO4− + H 2O → H 3O + + HPO42 − (Base)
( c = 3 × 108 ms −1 and
H 2 PO4− + OH − → H 3 PO4 + O22− (Acid)
N A = 6.02 × 1023 mol −1 )
in only II step H 2 PO4− is acting as an acid. (a) 494 nm (b) 594
39. The main product of the following reaction is (c) 640 nm (d) 700 nm

conc.H SO 242 × 103 hC 6.63 ×10 −34 × 3 ×108

C6 H 5CH 2CH (OH )CH (CH 3 ) 2 
2 4→ Sol.(a) = =
6.023 × 1023 λ λ
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 43. On mixing, heptane and octane form an ideal
6.63 × 10−34 × 3 × 108 × 6.023 ×1023
λ= solution. At 373 K, the vapour pressures of
242 ×103 the two liquid components (heptane and
octane) are 105 kPa and 45 kPa respectively.
= 0.494 × 10 −6 m = 494 × 10−9 m Vapour pressure of the solution obtained by
= 494nm mixing 25.0 g of heptane and 35g of octane
41. 29.5 mg of an organic compounds containing will be (molar mass of heptane
nitrogen was digested according to kjeldahl’s = 100 g mol −1 and of octane
method and the evolved ammonia was ab-
sorbed in 20 mL of 0.1M HCl solution. The = 114 g mol −1 )
excess of the acid required 15 mL of 0.1 (a) 144.5 kPa (b) 72.0 kPa

M NaOH solution for complete neutraliza- (c) 26.1kPa (d) 96.2 kPa
tion. The percentage of nitrogen in the com-
pounds is : Sol.(b) PHept = 105KPa 25 g Hept
(a) 29.5 (b) 59.5
POct = 45Kpa 35 g Oct
(c) 47.4 (d) 23.7
M.w 100g/mol of heptane
1.4 × unused meq .of HCl M.w 114g/mol of octane
Sol.(d) % of N =
wt of O.C .
PT = PA0 X A + PB0 X B
1.4 × ( 20 × 0.1 − 15 × 0.1)
= = 23.72% = 105.
0.25
+ 45.
0.3
29.5 × 10−3 0.25 + 0.3 0.25 + 0.3
42. Ionisation energy of He + is
0.25 0.3
−18 −1 = 105. + 45.
19.6 × 10 J atom . The energy of the first 0.55 0.55
stationary state (n = 1) of Li 2 + is :
= 105. ( 0.45 ) + 45. ( 0.545 )
(a) 8.82 ×10 −17 J atom −1
= 47.25 + 24.525
(b) 4.41× 10 −16 J atom −1
= 71.775 ≈ 72
−17 −1
(c) −4.41× 10 J atom 44. Which one of the following has an optical
isomer ?
(d) −2.2 ×10 −15 J atom −1
(a) [ Zn(en ) 2 ]2 +
2
Z
Sol.(c) E1 of He + = E1 of H − atom × (b) [ Zn(en )( NH 3 ) 2 ]2 +
n2
= E1 of H-atom ×2 2 (c) [Co(en )3 ]3+

E1 of He + (d) [Co( H 2 O ) 4 (en )]3+

∴ E1 of H-atom =
22 n+
Sol.(c)  M ( aa )3  type will show optical isomer-
ionisation energy of He +
=− ism
4
19.6 ×10 −18
=−
4
32
E1 of Li +2 = E1 of H-atom ×
12
−19.6 × 10−18
= ×9 = −4.41× 10 −17 J
4

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45. Consider the following bromides :
K eq. . ( H 2 S )
Me Me ∴ [ HS ] = (H ) +
Me Br Me
Br Br  H 2S 
∴ R = K K eq. ( Cl2 ) .  H + 
1

A B C  
Which is not consistent
The correct order of S N 1 reactivity is : 48. The Gibbs energy for the decomposition of
(a) A > B > C (b) B > C > A Al3O3 at 5000 C is as follows :
(c) B > A > C (d) C > B > A
2 4
Sol.(b) B > C > A more is stablity of carbocation Al2O3 → Al + O2 , ∆ r G = +966 J mol −1
favour SN1 mechanism.
3 3
46. One mole of a symmetrical alkene on The potential difference needed for electrolytic
ozonolysis gives two moles of an aldehyde reduction of Al2O3 at 500 0 C is at least :
having a molecular mass of 44 u . The alkene
(a) 5.0 V (b) 4.5V
is :
(a) ethene (b) propene (c) 3.0 V (d) 2.5V
(c) 1-butene (d) 2- butene
2 4
Sol. (d) Sol.(d) Al2O3 → Al + O2
3 3
OO
CH 3 − CH = CH − CH 3 ∆G = +966 KJ
2CH 3CHO ∆G = −nFCell
molecular weight of aldehyde = 44 966 × 103 = −4 × 96500 × − ECell
47. Consider the reaction :
Cl2 ( aq ) + H 2 S ( aq ) → S ( s ) + 2 H + (aq ) + 966 × 103
ECell =− = 2.5V
− 4 × 96500
2 Cl (aq )
49. The correct order of increasing basicity of the
The rate equation for this reaction is
given conjugate bases ( R = CH 3 ) is :
rate = k [Cl2 ][ H 2 S ]
Which of these mechanisms is/are consis- (a) RCOO < HC ≡ C < NH 2 < R
tent with this rate equation ?
(b) RCOO < HC ≡ C < R < NH 2
A. Cl2 + H2 S → H + + Cl − + Cl + + HS − (slow)
(c) R < HC ≡ C < RCOO < NH 2
Cl + + HS − → H + + Cl − + S (fast)
(d) RCOO < NH 2 < HC ≡ C < R
B. H 2 S ⇔ H + + HS − (fast equilibrium)
Sol.(a) Acidic nature
Cl2 + HS − → 2Cl − + H + + S (slow)
R − COOH > H − C ≡ CH > NH 3 > RH
(a) A only (b) B only
This is order of basicity of conjugate base
(c) Both A and B (d) Neither A nor B
RCOO − < H − C ≡ C − < NH 2− < R −
Sol.(a) (i) Cl2 + H 2 S → H + + Cl − + Cl + + HS
50. The edge length of a face centered cubic cell
R = K [Cl2 ][ H 2 S ] of an ionic substance is 508 pm. If the radius
of the cation is 110 pm, the radius of the an-
Hence it is consistent ion is:

(ii) R = K
1
[Cl2 ][ HS ] (a) 144 pm
(c) 398 pm
(b) 288 pm
(d) 618 pm

 H +   HS − 
K eq. =   
[H2S ]
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Sol. (a) 55. At 250 C , the solubility product of
a Mg (OH ) 2 is 1.0 × 10−11 . At which pH, will
= rc + Anion
ra Cation Anion
2
Mg 2 + ions start precipitating in the form of

508 Mg (OH ) 2 from a solution of 0.001

= 110 + ra
2 M Mg 2+ ions ?
ra = 144 pm (a) 8 (b) 9
(c) 10 (d) 11
51. Out of the following, the alkene that exhibits
optical isomerism is :
(a) 2-methyl-2-pentene
Sol.(c) ( Mg )( OH )
2+ − 2
> 1×10−11
(b) 3-methyl-2-pentene
10−11
(c) 4-methyl-1-pentene ( OH ) − 2
>
0.001
(d) 3-methyl-1-pentene

H ( OH ) − 2
> 10−8
1 2 3 4 5
Sol.(d) H 2C = CH − C − CH 2 − CH 3 ( OH ) > 10
− −4

CH 3
pOH < 4 ∴ pH > 10
All the groups at carbon 3 is diffrent hence it 0
is chiral carbon it will exhibit optical 56. The correct order of E M 2+ / M
values with
isomerism. negative sign for the four successive elements
52. For a particular rev ersible reaction at Cr , Mn, Fe and Co
temperature T , ∆H and ∆S were found to be
(a) Cr > Mn > Fe > Co
both + ve . If Te is the temperature at
(b) Mn > Cr > Fe > Co
equilibrium, the reaction would be
spontaneous when : (c) Fe > Mn > Cr > Co
(a) T = Te (b) Te > T (d) Cr > Fe > Mn > Co
Sol.(b) Mn > Cr > Fe > CO
(c) T > Te (d) Te is 5 times T
−1.18 > −0.91 > −0.44 > −0.27
∆H This is due to irregular variation of ionisation
Sol.(c) For reaction to be spontaneous T >
∆S energies and the sublimation energies of at-
oms and hydration energy of divalent ion.
∆H 57. Biuret test is not given by :
and at equilibrium Te =
∆S (a) proteins (b) carbohydrates
(c) polypeptides (d) urea
∴ T > Te
Sol.(b) Biuret test gives compound containing
53. Percentages of free space in cubic close
packed structure an in body centered packed O
structure are respectively : linkage . Since carbohydrate
−C − NH −
(a) 48 % and 26 % (b) 30 % and 26 %
(c) 26 % and 32 % (d) 32 % and 48 % O
Sol. (c) donot conatin linkage hence
−C − NH −
54. The polymer containing strong intermolecular
forces e.g. hydrogen bonding, is : donot give biuret test.
(a) natural rubber (b) teflon 58. The time for half life period of a certain reaction
(c) nylon 6, 6 (d) polystyrene A → Products is 1 hour. When the initial
Sol. (c) concentration of the reactant ‘A’ is 2.0
Nylon 6, 6 called fiber which has strong mol L−1 , how much time does it take for its
intermolecular forces such as H-bonding.
concentration to come from 0.50 to 0.25
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 mol L−1 if it is a zero order reaction ? Since 0.01 mole CoCl3 .6 NH 3 gives 0.033
(a) 1 h (b) 4h mole AgCl .
(c) 0.5 h (d) 0.25 h
Sol.(d) For zero order reaction Hence 1 mole CoCl3 .6 NH 3

a 0.033
t1/ 2 = ∴ t1/ 2 ∝ a gives = = 3.3 mole
2K 0.01
= 3 mole
( t1/ 2 )1 a Hence no. of chloride ion given by 1 mole
= 2
( t1/ 2 )2 a1 compound = 3

∴ Ans = Co ( NH 3 )6  Cl3

1 2
=
( t1/ 2 )2 0.5 60. The standard enthalpy of formation of NH 3 is

1 −46.0 kJ mol −1 . If the enthalpy of formation

( t1/ 2 )2 = = 0.25 hr..
4 of H 2 from its atoms is −436 kJ mol −1 and

59. A solution containing 2.675 g of CoCl3 . that of N 2 is −712 kJ mol −1 , the average

6 NH 3 (molar mass = 267.5 g mol −1 ) is bond enthalpy of N − H bond in NH 3 is :

passed through a cation exchanger. The
chloride ions obtained in solution were treated (a) −1102 kJ mol −1 (b) −964 kJ mol −1

with excess of AgNO3 to give 4.78 g of (c) +352 kJ mol −1 (d) +1056 kJ mol −1

AgCl (molar mass = 143.5 g mol −1 ). The 1 3

formula of the complex is : Sol.(c) N 2 + H 2 → NH 3 , ∆H = −46kJ
2 2
(At mass of Ag = 108 u)
1 3 
(a) [CoCl ( NH 3 )5 ]Cl2 ∆H = −46 =  B.E. of ( N ≡ N ) + B.E.of ( H − H ) 
2 2 
(b) [Co( NH 3 ) 6 ]Cl3
− 3 × B.E. of ( N − H ) 
(c) [CoCl2 ( NH3 )4 ]Cl
1 3 
(d) [CoCl3 ( NH 3 )3 ] −46 =  × 712 + × 436  − 3 [ N − H ]
2 2 
Sol.(b) CoCl3 .6 NH 3 + AgNO3 → AgCl
= ( 356 + 654 ) − 3 ( N − H )
2.675 4.78
n= =
267.5 143.5 3 ( N − H ) = 356 + 654 + 46 = 1056
= 0.01 = 0.033 1056
(N − H ) = = 352 KJ
3

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 Part C - MATHEMATICS (c) x ∈ S and x ≤ 0 ⇒ x is not rational
4 (d) There is a rational number x ∈ S such
61 Let cos (α + β ) = and let
5 that x ≤ 0 .

5 π Sol.(b) Every rational number x ∈ S satisfies

sin (α − β ) = , where 0 ≤ α , β ≤ . x≤0
13 4



Then tan 2α = 63. Let a = ˆj − kˆ and c = iˆ − ˆj − kˆ . Then the




56 19 vector b satisfying a
× b + c
= 0 and
(a) (b)
33 12


a ⋅ b = 3 is
20 25 (a) 2iˆ − ˆj + 2kˆ (b) iˆ − ˆj − 2kˆ
(c) (d)
7 16
(c) iˆ + ˆj − 2kˆ (d) −iˆ + ˆj − 2kˆ
4 5
Sol.(a) cos (α + β ) = sin (α − β ) =


5 13 Sol.(d) a = ˆj − kˆ and c = iˆ − ˆj − kˆ


tan 2α = tan (α + β ) + (α − β )  Let b = b1iˆ + b2 ˆj + b3kˆ







A ∵ a × b + c = 0 , a × b = −c
i j k
3 −1 = −iˆ + ˆj + kˆ
tan (α + β ) = 0 1
5 3
4 b1 b2 b3
(α+β)

i ( b3 + b2 ) − ˆj ( b1 ) + k ( −b1 ) = −iˆ + ˆj + kˆ
C 4 B

tan (α + β ) + tan (α − β ) b3 + b2 = −1 .....(a)

=
1 − tan (α + β ) ⋅ tan (α − β ) b1 = −1 .....(b)



3 5 36 + 20 a ⋅b = 3
+ 56
= 4 12 = 48 =
3 5 48 − 15 33
( j − k ) ⋅ ( b1i + b2 j + b3k ) = 3
1− ⋅
4 12 48 b2 − b3 = 3 ....(c)
Solve (a) and (c)
A
2b2 = 2 b2 = 1 b3 = −2

5 ∴ b1 = −1 b2 = 1 b3 = −2
tan (α − β ) =
13 5


12 Hence b = −iˆ + ˆj − 2kˆ
(α−β) 64. The equation of the tangent to the curve
C 12 B
4
62. Let S be a non-empty subset of R .
y= x+ , that is parallel to the x -axis,
x2
Consider the following statement : is
P : There is a rational number x ∈ S such (a) y =1 (b) y=2
that x > 0 .
Which of the following statements is the (c) y=3 (d) y=0
negation of the statement P ? dy
(a) There is no rational number x ∈ S such Sol.(c) Parallel to x -axis i.e. =0
dx
that x ≤ 0 .
dy
(b) Every rational number x ∈ S satisfies = 1 − 8 x −3 = 0 ⇒ x=2
dx
x ≤ 0.
put x = 2 in equation of curve, we get
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 y=3 Similarly, area of curve EFG = 2 −1
Hence equation of tangent is
y − 3 = 0 ( x − 2) ⇒ y=3 A
65. Solution of the differential equation B

π 5π
cos x dy = y ( sin x − y ) dx,0 < x < is O
x=0 π
C
π
D 4
F 3π
2 4 2 2

(a) y sec x = tan x + c

E G
(b) y tan x = sec x + c

(c) tan x = ( sec x + c ) y

Now, area of curve
(d) sec x = ( tan x + c ) y 5π / 4
BCDE = ∫
π /4
( sin x − cos x ) dx
dy y ( sin x − y )
Sol.(d) = x=
5π
dx cos x = ( − cos x − sin x ) π
4
x=
4
dy
= y tan x − y 2 sec x
dx  1 1 1 1 
= − − − − −
1 dy 1  2 2 2 2 
⇒− 2
+ tan x = sec x
y dx y 4
= =2 2
1 1 dy dv 2
=v⇒− 2 =
Let
y y dx dx ⇒ Net area

⇒
dv
+ ( tan x ) v = sec x
= ( ) (
2 −1 + )
2 −1 + 2 2 = 4 2 − 2
dx 67 If two Tangents drawn from a point P to the

I .F . = e ∫ tan x = elog sec x = sec x parabola y 2 = 4 x are at right angles, then

the locus of P is
⇒ v ( sec x ) = ∫ sec x sec x dx + c (a) 2 x + 1 = 0 (b) x = − 1
(c) 2 x − 1 = 0 (d) x = 1
1
⇒ sec x = tan x + c Sol.(d) If tangents of a parabola are ⊥ r , then it
y
meets on the directrix
⇒ sec x = ( tan x + c ) y ∴ equation of directrix ⇒ x = −1
66. The area bounded by the curves y = cos x x = −1
and y = sin x between the ordinates 68. If the vectors



3π a = iˆ − ˆj + 2kˆ, b = 2iˆ + 4 ˆj + kˆ and
x = 0 and x = is

2 c = λiˆ + ˆj + µ kˆ are mutually orthogonal,
(a) 4 2 + 2 (b) 4 2 − 1
then (λ, µ ) =
(c) 4 2 + 1 (d) 4 2 − 2
Sol.(d) Area of curve (a) ( 2, −3) (b) ( −2,3)

(c) ( 3, −2 ) (d) ( −3, 2 )

π /4
OAB = ∫
0
( cos x − sin x ) dx


Sol.(d) a
⋅ b = 0
= [sin x + cos x ]0
π /4

⇒ ( i − j + 2k ) ⋅ ( 2i + 4 j + k ) = 0
1 1
= + − ( 0 + 1) = 2 − 1

a ⋅c = 0
2 2
( )
⇒ i − j + 2kˆ ⋅ ( λi + 4 j + µ k ) = 0
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 ⇒ λ − 1 + µ ⋅ 2 = 0 ⇒ λ − 2 µ = 1 .....(a) q are integers such that n, q ≠ 0 and



b ⋅c = 0 m p
= 
( 2i − 4 j + k ) ⋅ ( λi + ˆj + µ k ) = 0 n q
Similarly it is an equivalance relation.
2⋅λ + 4 + µ = 0 70. Let f :R→R be dif ined by
2 λ + µ = −4 .....(b)
k − 2 x, if x ≤ −1
λ = −3  f (x) =  . If f
Solve (a) and (b), we get  2 x + 3, if x > −1
µ =2 
has a local minimum at x = −1 ,
69. Consider the following relations :
then a possible value of k is
R = {( x, y ) | x, y are real number and
1
x = wy for some rational number w} ; (a) 0 (b) −
2
 m p   (c) −1 (d) 1
S =   ,   | m, n, p
 n q   Sol.(c) f is minimum at x = −1
and q are integers such that n, q ≠ 0 and Hence f ( −1) ≤ lim+ f ( x )
x →−1
qm = pn} . Then
⇒ K +2 ≤1 ⇒ K ≤ −1
(a) Neither R nor S is an equivalence
71. The number of 3 × 3 non-singular matrices,
relation.
with four entries as 1 and all other entries as
(b) S is an equivalence relation but R is
0, is
not an equivalence relation. (a) 5 (b) 6
(c) R and S both are equivalence rela- (c) at least 7 (d) less than 4
tions. Sol.(c)
(d) R is an equivalence relation but S is
not an equivalence relation.
1 1 0  1 0 1  1 0 0  1 0 0 
 0 1 0   0 1 0   0 1 1  1 1 0 
Sol.(c) For relation R,     
xRx ⇒ x = ωx ⇒ w = 1 is a rational  0 0 1   0 0 1   0 0 1  0 0 1 
number i.e. R is reflexive
Again xRy ⇒ x = wy ⇒ w is a rational  1 0 0   1 0 0  1 0 0 
 0 1 0   0 1 0  0 1 1 
1 1     etc.
number yRx ⇒ y = x ⇒ is a rational 1 0 1   0 1 1  0 1 0 
w w
number are non-singular matrices.
So, xRy ⇒ yRx i.e. R is symmetric So, at least 7 are non singular matrices.
Also, xRy ⇒ x = wy Directions :
⇒ w is a rational number .....(a) Questions number72 to 76 are Assertion-
yRz ⇒ y = wz Reason type questions. Each of these
questions contains two statements.
⇒ w is a rational number .....(b)
Statement 1 : (Assertion) and
By (a) and (b) ⇒ x = w2 z ⇒ w 2 is a Statement 2 : (Reason) .
rational number Each of these questions also has four
alternative choices, only one of which is the
So, xRy , yRz ⇒ xRz Hence R is correct answer. You have to select the correct
equivalence relation. choice.
 
For relation S , S =  m , p m, n, p and 72. Four number are chosen at random (without
 
 n q  replacement) from the set {1, 2, 3,.....20}.

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 Statement 1 : (a) Statement-1 is true, Statement-2 is true;
The probability that the chosen numbers when S t a t e not a correct explanation for
m e n t - 2 i s

Statment -1.
1 (b) Statement-1 is true, Statement-2 is false.
arranged in some order will form an AP is .
85 (c) Statement-1 is false, Statement-2 is true.
Statement 2 : (d) Statement-1 is true, Statement-2 is true;
If the four chosen numbers form an AP, then Statement-2 is a correct explanation for
the set of all possible values of common Statment -1.
Sol.(a) Equation of line passing through A and B
difference is {±1, ±2, ±3, ±4, ±5} .

(a) Statement-1 is true, Statement-2 is true; B(1, 3, 4)

Statement-2 is not a correct explanation for
Statment -1.
(b) Statement-1 is true, Statement-2 is false.
p
(c) Statement-1 is false, Statement-2 is true.
(d) Statement-1 is true, Statement-2 is true;
Statement-2 is a correct explanation for
Statment -1.
A(3, 1, 6)
Sol.(b) d = 1 , least possible A.P. 17,18,19,20
i.e. no. of A.P.’s =17
x −1 y − 3 z − 4
d = 2 , least possible A.P. 14,16,18,20 ⇒ = =
i.e. no. of A.P.’s =14 3 −1 1− 3 6 − 4
d = 3 , least possible A.P. 11,14,17,20 x −1 y − 3 z − 4
i.e. no. of A.P.’s =11 ⇒ = = =k
2 −2 2
d = 4 , least possible A.P. 8,12,16,20
i.e. no. of A.P.’s =8 d.R’s AB ⇒ ( 2, − 2, 2 ) = (1, −1,1)
d = 5 , least possible A.P. 5,10,15,20 d.R’s of plane x − y + z = 5 ⇒ 1, − 1, 1
i.e. no. of A.P.’s =5
d = 6 , least possible A.P. 2,8,14,20 ∴
a1 b1 c1
= = 2 −2 2
= =
i.e. no. of A.P.’s =2 a2 b2 c 2 1 −1 1
d = 7 Not possible ∴ Plane and line are ⊥ r
⇒ n ( A) = 57
any point on line ( 2k + 1, −2k + 3, 2k + 4 )
Now,
it lies on the plane,
20.19.18.17
n ( s ) = 20C4 = = 19 (17 )(15 ) 2 k + 1 − ( −2 k + 3 ) + 2 k + 4 = 5
4.3.2.1
1
57 1 ⇒ 6k + 2 = 5 ⇒ k = ∴ p ( 2, 2, 5)
Probability = 19 17 15 = 85 2
( )( ) Middle point of
Statement (a) is correct
 3 +1 1+ 3 6 + 4 
Now d = {1, 2,3, 4,5,6} or AB ⇒ p  , , 
 2 2 2 
{−1, −2, −3, −4, −5, −6} ⇒ (b) is wrong ⇒ p ( 2, 2, 5 )
73. Statement 1 :
p , lie on the plane 2 − 2 + 5 = 5
The point A ( 3,1,6 ) is the mirror image of
∴ Plane bisect the line segement AB
the point B (1,3, 4 ) in the plane 10 10
74. Let S1 = ∑ j ( j − 1) 10C j , S2 = ∑ j 10C j
x− y + z =5. j =1 j =1
Statement 2 :
10
The plane x − y + z = 5 bisects the line and S3 = ∑j
j =1
2 10
Cj
segment joining A ( 3,1,6 ) and B (1, 3, 4 ) .

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 Statement 1 : Statement 1 :
S3 = 55 × 2 9
Tr ( A ) = 0
Statement 2 : Statement 2 :
S1 = 90 × 2 and S2 = 10 × 2
8 8
A =1
(a) Statement-1 is true, Statement-2 is true; (a) Statement-1 is true, Statement-2 is true;
Statement-2 is not a correct explanation for Statement-2 is not a correct explanation for
Statment -1. Statment -1.
(b) Statement-1 is true, Statement-2 is false. (b) Statement-1 is true, Statement-2 is false.
(c) Statement-1 is false, Statement-2 is true.
(d) Statement-1 is true, Statement-2 is true; (c) Statement-1 is false, Statement-2 is true.
Statement-2 is a correct explanation for
Statment -1. (d) Statement-1 is true, Statement-2 is true;
10 Statement-2 is a correct explanation for
(1 + x ) = ∑ 10 C j x j
10
Sol.(b) Statment -1.
j =1
 a b   a b  1 0
10 (1 + x ) = ∑ j =1 j C j x
9 10 10 j −1 Sol.(c)   = 
On diff.  c d   c d  0 1
10 a 2 + bc = 1, bc + d 2 = 1
for x = 1 10.2 =
9
∑j =1
j10C j = S2 .....(a)
⇒ a2 = d 2 ⇒ a = ±d
⇒ S2 = 10.29 which is wrong. So, Tr ( A ) ≠ 0 for a = d
Statement (a) is wrong
(1 + x ) = ∑ j =1 10 C j x j
10 10
2
A2 = I ⇒ A2 = I ⇒ A = 1 ⇒ A = 1
10 (1 + x ) = ∑ j =1 j 10C j x j −1
9 10
On diff. Statement (b) is true
Again diff. 76. Let f : R → R be a continuous function
10.9 (1 + x ) = ∑ j =1 j ( j − 1) 10C j x j −2
8 10
1
defined by f ( x) = .
e + 2e − x
x
for x = 1
Statement 1 :
10 10
90.28 = ∑ j ( j − 1) 10C j = ∑ ( j 2 − j ) 10C j 1
f ( c ) = , for some c ∈ R .
j =1 j =1 3
Statement 2 :
⇒ S1 = 90.28
1
10 0 < f (x) ≤ for all x∈R .
Now (a)+(b) ⇒ 10.2 + 90.2 =
9 8
∑j
j =1
2 10
Cj 2 2
(a) Statement-1 is true, Statement-2 is true;
Statement-2 is not a correct explanation for
10
Statment -1.
⇒ 10.28 = ∑ j 2 10C j (b) Statement-1 is true, Statement-2 is false.
j =1
(c) Statement-1 is false, Statement-2 is true.
10 (d) Statement-1 is true, Statement-2 is true;
⇒ 55.29 = ∑ j 2 10C j ⇒ S − 1 is true Statement-2 is a correct explanation for
j =1 Statment -1.
75. LetA be a 2 × 2 matrix with non-zero entries ex
and let A2 = I , where I is 2 × 2 identity
Sol.(d) f ( x ) = and f ′ ( x ) = 0
2 + e2 x
matrix. Define Tr ( A ) = sum of diagonal we get e 2 x = 2 2 x = log e 2

elements of A and A = determinant of ⇒ x = log e 2

matrix A f ( x ) > 0 it is a exponential funtion

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 α 2009 + β 2009 = ( −ω 2 ) + ( −ω )
2009 2009
1
Hence 0 < f ( x ) <
So,
2 2
2( 2009 )
= −ω − ω 2009
1
f (0) =
Also
3
At x = 0
( ) (
= − ω 3(1339 )+1 − ω 3(669 )+ 2 )
which is true.
77. For a regular polygon, let r and R be the = −ω − ω 2
radii of the inscribed and the circumscribed = − (ω + ω 2 ) = − ( −1) = 1
circles. A False statement among the following
is - 79. The number of complex numbers z such that

r 1 z − 1 = z + 1 = z − i equals
(a) There is a regular polygon with =
R 2 (a) 1 (b) 2
(c) ∞ (d) 0
r 2
(b) There is a regular polygon with = Sol.(a) Let z = x + iy Now z − 1 = z + 1
R 3
⇒ ( x − 1) + iy = ( x + 1) + iy
r 3
(c) There is a regular polygon with =
R 2
( x − 1) ( x + 1)
2 2
⇒ + y2 = + y2
r 1
(d) There is a regular polygon with = ⇒ x2 − 2 x + 1 + y2 = x2 + 2x + 1 + y 2
R 2
Sol.(b) From figure, for a regular polygon ⇒ 4x = 0 ⇒ x=0 .....(a)

r π Again z + 1 = z − i
⇒ = cos
R n
⇒ ( x + 1) + iy = x + ( y − 1) i

( x + 1) + y 2 = x 2 + ( y − 1)
2 2
π
n ⇒
R
r ⇒ x2 + y2 + 2 x + 1 = x2 + y 2 − 2 y + 1
⇒ x = −y ......(b)

π 1 Also z − 1 = z − i
for n = 3 cos =
3 2
⇒ ( x − 1) + iy = x + ( y − 1) i
π 1
for n = 4 cos =
( x − 1) + y 2 = x 2 + ( y − 1)
2 2
4 2 ⇒
π 3 = x2 + y2 − 2 x + 1 = x2 + y 2 − 2 y + 1
for n = 6 cos =
6 2 ⇒x= y ......(c)
r 2 BY (a), (b), (c)
So, there is a regular polygon with =
R 3 ⇒ x = 0, y = 0 ⇒ x + iy = 0 + i 0
is false. Only one complex number
78. If α and β are the roots of the equation 80. A line AB in three-dimensional space makes
angles 45° and 120° with the positive x -
x 2 − x + 1 = 0 , then α + β 2009 =
2009
axis and the positive y -axis respectively. If
(a) -1 (b) 1
(c) 2 (d) -2 AB makes an acute angle θ with the positive
Sol.(b) x − x + 1 = 0
2 z -axis, then θ equals
(a) 45° (b) 60°
1 + 3i 1 − 3i
⇒x= = −ω 2 , x = = −ω (c) 75° (d) 30°
2 2

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Sol.(b) α = 45°, β = 120°, γ = θ 82. A person is to count 4500 currency notes.
cos α + cos β + cos θ = 1
2 2 2
Let an denote the number of notes he counts

1  1
2 in the n th minute. If
⇒   +  −  + cos2 θ = 1
2  2 a1 = a2 = .... = a10 = 150 and a10 , a11 ,.....
are in an AP with common difference −2 , then
1 1 3
+ + cos2 θ = 1 ⇒ + cos2 θ = 1 the time taken by him to count all notes is
2 4 4 (a) 34 minutes (b) 125 minutes
(c) 135 minutes (d) 24 minutes
1 1
⇒ cos2 θ = ⇒ cos θ = ± Sol.(a) S = 4500
4 2
a1 + a2 + a3 + .... + a10 = 10 (150 ) = 1500
θ = 60° (acute angle).
Now for remaining notes
x y
81. The line L given by + = 1 passes S = 4500 − 1500 = 3000
5 b
a11 = 148, d = −2 then
through the point (13,32 ) . The line K is
n
parallel to L and has the equation S=  2 (148 ) + ( n − 1)( −2 )
2
x y
+ = 1 . Then the distance between L ⇒ 3000 = n (149 − n )
c 3
and K is ⇒ n 2 − 149n + 3000 = 0
17 ⇒ n 2 − 125n − 24n + 3000 = 0
(a) 17 (b)
15 ⇒ n ( n − 125 ) − 24 ( n − 125) = 0
23 23 ⇒ n = 24
(c) (d) So minimum time to count currency notes =
17 15
24 + 10 = 34 minute.
x y 13 32
Sol.(c) + =1 ⇒ + =1 83. Let f : R → R be a positive increasing
5 b 5 b
32 −8 f ( 3x )
⇒ = function with lim = 1 . Then
b 5 ⇒ b = −20 x →∞ f ( x)

b f (2x )
Slope of line L ⇒ − ⇒m=4 lim =
5 x →∞ f ( x)
Slope of line K ⇒ m′ =
−3
2 3
c (a) (b)
3 2
(∵ m = m′ for parallel lines)
(c) 3 (d) 1
3 3 Sol.(d)
⇒− =4 ⇒c=−
c 4 84. Let p ( x ) be a function defined on R such
4x y
∴ Line K ⇒ − + =1 .....(a) that p′ ( x ) = p′ (1 − x ) f or all
3 3
⇒ −4 x + y = 3 ⇒ 4 x − y = −3 x ∈ [0,1] , p ( 0 ) = 1 and p (1) = 41 . Then
1
x y
Line L ⇒ +
5 −20
= 1 ⇒ 4 x − y = 20 ∫ p ( x ) dx equals
0
So distance between line L and K is, (a) 21 (b) 41

c1 − c2 −3 − 20 23 (c) 42 (d) 41
d= = =
a 2 + b2 42 + 12 17
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Sol.(a) P′ ( x ) = P′ (1 − x ) Sol.(c) Total no. of ways = 3C2 ⋅ 9C2

∫ P′ ( x ) dx = ∫ P′ (1 − x ) dx = 3C1 ⋅ 9C2 = 3
9.8
2.1
= 108
⇒ P ( x ) = − P (1 − x ) + C .........(a) 87. Consider the system of linear equations :

⇒ P ( 0 ) = − P (1) + C for x = 0 x1 + 2 x2 + x3 = 3
2 x1 + 3x2 + x3 = 3
⇒ 1 + 41 = C ⇒ C = 42
By (a) 3 x1 + 5 x2 + 2 x3 = 1
P ( x ) = − P (1 − x ) + 42 The system has
(a) exactly 3 solutions
1 1 1
⇒ ∫ P ( x ) dx + ∫ P (1 − x ) dx = ∫ 42dx
(b) a unique solution
0 0 0 (c) no solution
1 1
(d) infinite number of solutions
⇒ ∫ P( x ) + ∫ P ( x ) dx = 42 ( x )0
1

0 0 Sol.(c) x1 + 2 x2 + x3 − 3 = 0
1
⇒ 2∫ P ( x ) dx = 42 2 x1 + 3x2 + x3 − 3 = 0
0

1
3 x1 + 5 x2 + 2 x3 − 1 = 0
⇒ ∫ P ( x ) dx = 21
0
1 2 1
85. Let f : ( −1, 1) → R be a differentiable ⇒∆= 2 3 1
R2 → R2 + R1
function with f ( 0 ) = −1 and f ′ ( 0 ) = 1 . Let 3 5 2

g ( x ) =  f ( 2 f ( x ) + 2 ) . Then g′ ( 0 ) =
2
1 2 1
(a) -4 (b) 0 ⇒∆= 3 5 2 =0
(c) -2 (d) 4 3 5 2
( )
2
Sol.(a) g ( x ) =  f 2 f ( x ) + 2 
 (Two rows are identical)

⇒ g ′ ( x ) = 2 f ( 2 f ( x ) + 2) ⋅ 2 1 −3
Now ∆x1 = 3 1 −3
f ′ ( 2 f ( x ) + 2) ( 2 f ′ ( x ))
5 2 −1
⇒ g ′ ( 0) = 2 f ( 2 f ( 0) + 2) ⋅
R1 → R1 − R2
f ′ ( 2 f ( 0) + 2) ( 2 f ′ ( 0))
−1 0 0
⇒ g ′ ( 0 ) = 2 f ( 2 ( −1) + 2 ) ⋅
⇒ ∆x1 = 3 1 −3
f ′ ( 2 ( −1) + 2 ) ( 2 (1) ) 5 2 −1
⇒ g′ (0) = 2 f (0) ⋅ f ′ (0) ⋅ 2 = ( −1) ( −1 − ( −6 ) ) = −5 ≠ 0
⇒ g ′ ( 0 ) = 4 ( −1) ⋅ (1) = −4 ∆ = 0, ∆ x1 ≠ 0 ⇒ linear
86. There are two urns. Urn A has 3 distinct red equations has no solution.
balls and urn B has 9 distinct blue balls. From 88. An urn contains nine balls of which three
each urn two balls are taken out at random are red, four are blue and two are green.
and then transferred to the other. The number Three balls are drawn at random without
of ways in which this can be done is replacement from the urn. The probability
(a) 36 (b) 66 that the three balls have different colours is
(c) 108 (d) 3 2 1
(a) (b)
7 21

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 2 1 90. The circle x 2 + y 2 = 4 x + 8 y + 5 inter-
(c) (d)
23 3 sects the line 3 x − 4 y = m at two distinct
Sol.(a) Event A is all three balls are of different colour points if
i.e. 1 Red, 1 Blue, 1 Green (a) −35 < m < 15 (b) 15 < m < 65
Now, n ( S ) = 9C3 (c) 35 < m < 85 (d) −85 < m < −35

n ( A) = 3C1 × 4C1 × 2C1 Sol.(a) If circle intersected by a line, then p < r

3
C1 × 4C1 × 2C1
So, probaility = 9
C3
C (2, 4)
3 ⋅ 4 ⋅ 2 ⋅ ( 3)( 2 )(1) 2
= = r
9 ⋅8⋅ 7 7 p

89. For two data sets, each of size 5, the variances A M B

are given to be 4 and 5 and the corresponding
means are given to be 2 and 4 respectively.
The variance of the combined data set is 3× 2 − 4 × 4 − m
⇒ < 22 + 4 2 + 5
11 3 +4
2 2
(a) (b) 6
2
6 − 16 − m −10 − m
13 5 ⇒ < 25 ⇒ <5
(c) (d) 5 5
2 2
⇒ 10 + m < 25
∑ x12 −  ∑ x1  = 4
2

Sol.(a) We have ,
⇒ −25 < 10 + m < 25
5  5  ⇒ −35 < m < 15

∑x −∑ 2  =5
2
2
2  x 
5  5 

Also,
∑x 1
=2,
5

∑x 2
= 4 ⇒ ∑ x1 + ∑ x2 = 30
5

⇒
∑x 2
1
= 4 + 4 = 8,
5

⇒
∑x 2
2
= 5 + 16 = 21
5
⇒ ∑ x12 = 40, ∑ x22 = 105
⇒ ∑ x12 + ∑ x22 = 145
Now, Varience of combined data set
2
 145   30 
= − 
 10   10 
= 14.5 − 9 = 5.5 = 11/ 2

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