SOLUTIONS & ANSWERS FOR AIEEE-2011

VERSION – P
PART A − CHEMISTRY
Sol: 2Cl3C – CHO + NaOH
→ Cl3C – CH2OH + Cl3C – COONa
nd
1. Ans: 2

Sol: RNA contains β–D–ribose while DNA 11. Ans: Al2O3 < MgO < Na2O < K2O
contains β–D–2–deoxyribose.
Sol: K2O is more basic than Na2O. Al2O3 is
2. Ans: AlCl3 amphoteric.

Sol: Fajan’s rules. 12. Ans: 743 nm

3+
Al is the smallest cation and it has high
charge. 1 1 1
Sol: = −
355 680 λ
3. Ans: The stability of hydrides increases from λ = 743 nm
NH3 to BiH3 in group 15 of the periodic
table. 13. Ans: The oxidation state of sulphur is never
less than +4 in its compounds
Sol: Stability of hydrides decreases from NH3
to BiH3. Sol: Sulphur exhibits oxidation state lower than
+4 in its compounds.
4. Ans: 2, 4, 6–Tribromophenol
–1 –1
14. Ans: 38.3 J mol K
Sol: Phenol forms 2, 4, 6–tribromophenol when
treated with a mixture of KBr, KBrO3 and
V2
HCl. Sol: ∆S = 2.303 nR log
V1
5. Ans: 0 .086 = 2.303 × 2 × 8.314 × log 10
–1
= 38.3 J K
Sol: Mole fraction of methanol
moles of methanol 5 .2 15. Ans: The complex is an outer orbital complex
= =
total moles 1000
5 .2 +
18 Sol: [Cr(NH3)6]Cl3 is not an outer orbital
= 0.086 complex.

6. Ans:
2
sp , sp, sp
3 16. Ans: pentagonal bipyramid

Sol: IF7 is pentagonal bipyramidal.

NO3− – sp , NO2+ – sp and NH+4 – sp
2 3
Sol:
17. Ans: 32 times
7. Ans: 804.32 g
Sol: 2 times increase for 10°C
5
W2 1 2 = 32 times increase for 50°C
Sol: ∆Tf = Kf × ×
M2 W1
18. Ans: CH3CH2CH(Cl)CO2H
W2 1
6 = 1.86 × ×
62 4 Sol: Presence of Cl having –I effect on the
W 2 = 800 g α–carbon makes 2–chlorobutanoic acid
Wt. of glycol required is more than 800 g the strongest acid among the given
compounds.
+
8. Ans: p(H2) = 2 atm and [H ] = 1.0 M
19. Ans: 2–Pentanone
2H + 2e → H2
+ –
Sol:
[H+ ]2
O
0.0591
ECl = log
2 [H2 ] Sol:
CH3 C CH2 CH 2 CH3
+ 2
[H2] > [H ]
ketoform
9. Ans: Neutral FeCl3 OH

Sol:Neutral FeCl3 solution gives violet colour CH3 C CH CH2 CH 3

with phenol. enol form
10. Ans: 2, 2, 2–Trichloroethanol
20. Ans: 1.8 atm 30. Ans: Acetaldehyde

Sol: CO2 + C → 2CO Sol: Acetaldehyde reduces tollen’s reagent to

a–x 2x metallic silver on warming.

a = 0.5 atm PART – B – PHYSICS

a + x = 0.8 atm
x =0.3 atm 31. Ans: 8.4 kJ
p2 (0.6)2
Kp = CO = = 1.8 atm Sol: ∆U = mC∆T
pCO2 0 .2 = 4184 × 20 × 0.1
= 8.4 kJ
21. Ans: Availability of 4f electrons results in the
32. Ans: 20 min
formation of compounds in +4 state for all
the members of the series
N0
Sol: N= t / T1 / 2
Sol: All the lanthanoids does not exhibit +4 2
oxidation state. N0 N log 3
= t /020 ⇒ t 2 = 20
3 2 2 log 2
22. Ans: a for Cl2 > a for C2H6 but b for Cl2 < b for
C2H6 2 N0 20(log 3 − log 2)
N0 = t / 20 ⇒ t1 =
3 21 log 2
Sol: ‘a’ is a measure of attraction between the 20
molecules and ‘b’ the size of the t2 − t1 = (log 3 − log 3 + log 2)
molecules. log 2
= 20 min
23. Ans: 2.82 BM

Sol: There are two unpaired electrons is 1/ 2

2– M+m
[NiCl4] hence the paramagnetic moment 33. Ans:  
is 2.82 BM.  M 

24. Ans: A2 B5 Sol: Mv1 = (M + m) v2

v1 M + m
=
Sol: A1B5 = A2 B5 v2 M
2

7 1 2
1
(M + m)v 22 = 1 KA 22
25. Ans: 4f 5d 6s 2 2
1 1
Mv12 = KA12
Sol: The outer electronic configuration of 2 2
7 1 2
64Gd is 4f 5d 6s
1 1
Mv1 = KA12
2
2 2
26. Ans: BF63− 2
A12 M M+m 
⇒ =  
A2 2 M+m  M 
Sol: Boron cannot form BF63− since boron has
M+m
no available d–orbitals. =
M
1/ 2
27. Ans: a vinyl group A1  M + m 
∴ = 
A2  M 
Sol: Formation of HCHO in ozonolysis shows
the presence of CH2 = CH – group.
34. Ans: 108.8 eV
28. Ans: Ethyl ethanoate
13.6 Z2  1
Sol: CH3COCl + C2H5ONa Sol: = 13.6 × 9 1 − 
n2  9
→ CH3COOC2H5 + NaCl
8
= 13.6 × 9 ×
i −1 9
29. Ans: α= = 108.8 eV
( x + y − 1)
35. Ans: Wave moving in −x direction with speed
Sol: i = 1 – α + nα; n = x + y
i −1 b
α= a
x + y −1
 y(x, t) = e− ( a x + b t )
2 dv
Sol: = −2.5 dt
v
[ ]
This is of the form y(x, t) = f(x + vt), where
b ⇒ −2.5t = 2 v 0
6.25
v= travels in negative x direction.
a 2 6.25
t=
2 .5
2.7 × 10 Ω
6
36. Ans: 2 × 2 .5
= =2
2 .5
V = V0(1 − e− )
t/RC
Sol:
120 = 200(1 − e− )
t/RC

2 40. Ans: −6 ε0a

e−
t/RC
=
5 2
t/RC Sol: V = ar + b
e = 2.5
dV
t E= − = −2ar
= 0.4 × 2.5 × 2.303 dr
RC
⇒ R = 2.7 × 10 Ω
6 Q
4πr .E =
2
ε0
µ0Ι Q = −4πr .2ar.ε0
2
37. Ans: 2
π R − 8πar 3ε0
ρ=
4 3
Ι µ πr
Sol: B= Rdθ 0 sin θ 3
πR 2πR
= −6 ε0a

dθ • 1
• R
m s−
1
•
41. Ans:
• 15
• •
• •
1 1 1
Sol: + =
µ0 Ι π/2 v − 2 .8 0 . 2
=
2π2R ∫0sin θdθ 1 15
⇒ =
µ0Ι v 2 .8
=
π2R v=
2 .8
15
38. Ans: 372 K and 310 K v 1
=
u 15
T2 1
Sol: 1− = v2 1
T1 6 =
u2 15 2
T2 − 62 1
1− = 1 1 1
T1 3 + =
v u f
T2 5
= dv
T1 6 v2
⇒ dt = − 2
du u
T2 − 62 2
= dt
T1 3
dv v 2 du
= 2.
dt u dt
T2 5
= 1 1
T2 − 62 4 × 15 = m s−
1
=
152 15
4T2 = 5T2 − 310
42. Ans: Increases by 0.2%
T2 = 310 K
R∝λ
2
Sol:
⇒ T1 = 372 K R’ ∝ λ’
2

∝ (1.001) λ
2 2

∆R
39. Ans: 2s = 0.002
R
∴ 0.002 × 100
dv
Sol: = −2.5 v = 0.2%
dt
 n1T1 + n2T2 + n3T3 Gm G4 m
43. Ans: Sol: =
n1 + n2 + n3 x2 (r − x )2
Sol: P1V = n1KT1
(r − x )2=4
P2V = n2KT2 x2
P3V = n3KT3 r − x = 2x
1 3 3 3 r
mv 2 = KT1 × n1 + KT2n2 + K − T3n3 x=
2 2 2 2 3
3 −Gm G4 m
= K(n1 + n2 + n3)T V= −
2 r 2r
n1T1 + n2T2 + n3T3 3 3
T=
n1 + n2 + n3
= −
Gm
(3 + 6 )
r
44. Ans: v∝x −9 Gm
=
r
Sol: T cosθ = mg
T sinθ = F 48. Ans: First increases and then decreases.
F
tanθ =
mg Sol: Angular momentum is conserved.
x F Ι decreases ω increases then Ι increases
=
2λ mg ω decreases.
F∝x
49. Ans: 45°
∫ vdv ∝ ∫ xdx
v ∝x
2 2
Sol: [ ] [ ]
µ1 N̂ × K1 = µ2 N̂ × K 2 . But plane of
v∝x separation need to be XY.

45. Ans: 0.4π mJ π

50. Ans:
2
E = T.8π(r2 − r1 )
2 2
Sol:
 25 9  Sol: Particle 1 is at equilibrium position (φ = 0).
= 8πT  4 − 4 
 10 10   π
Particle 2 is at maximum position.  φ = 
= 8 × 16 × π × 0.03 × 10−
4
 2
= 0.4π mJ
51. Ans: Statement-1 is true, Statement-2 is true
π
46. Ans: LC and Statement -2 is not the correct
4
explanation of statement - 1
Sol: q’ = q0 cosωt
Sol: Statement-1 is true, Statement-2 is true
q0 2
E= and Statement -2 is not the correct
2C explanation of statement - 1
E 1 q0 2
=
2 2 2C
i.e. q’ = 0
q 1 Mv 2 (γ − 1)
52. Ans:
2 2 R
q0
= q0 cosωt
2 Sol: Volume is constant
R
π Cv =
⇒ ωt =
4
(γ − 1)
π 1
t= LC KE = Mv 2
4 2
∆Q = nCv ∆θ = 1 × Cv ∆θ
−9 Gm KE 1 Mv 2 (γ − 1)
47. Ans: ∴ ∆θ = =
r Cv 2 R
53. Ans: 0.052 cm dω t3
= 4 t − t 2 ⇒ ω = 2t 2 −
dt 3
1
Sol: LC = = 0.01 mm (Θ At t = 0, ω = 0)
100
At t = 6 s. ω again become zero
Reading = PSR × pitch + CSR × LC
= 0 + 52 × 0.01 dθ t3 2t 3 t 4
ω= = 2t 3 − ⇒ θ− −
= 0.52 mm dt 3 3 12
= 0.052 cm ∴ θ in 6 s = (144 − 108) = 36 rad
θ 36
54. Ans: 0.15 mV ⇒N= = = 5.72rotation.
2π 2π
Sol: E = Bλ v
3.6 × 10− m
3
60. Ans:
= 5 × 10− × 2 × 1.50
5

= 0.15 mV 1
Sol: P0 + ρv12 + ρgh
2
55. Ans: Statement 1 is true. Statement 2 is true. 1
= P0 + ρv 22
and statement 2 is the correct explanation 2
for statement – 1. ⇒2gh = (v2 − v1 )
2 2

2 2
⇒ 2gh + v1 = v2 ;
Sol: Statement 1 is true. Statement 2 is true.
v1 = 0.4 m s− , h2 = 0.2 m
1

and statement 2 is the correct explanation

⇒ v2 = 2.0396 m s−
1

for statement – 1.
2 d12 v1
A1v1 = A2v2 ⇒ d2 =
2 v2
56. Ans: g
3 v1
⇒ d2 = d1.
v2
Sol: mg − T = ma
0 .4
mR 2 a = 8 × 10− ×
3
TR = . 2.0396
2 R
≅ 3.6 × 10− m
3
3
⇒ mg = ma
2
Part – C – Mathematics
2
⇒a= g
3 61. Ans: β ∈ (1, ∞)

πv 4 Sol: If 1 + ai is root (a, real)

57. Ans: 2 Then (1 + i a) + α (1 + I a) + β = 0
2
g
2a + aα = 0 ⇒ α = − 2 a ≠ 0
1−a +α+β=0
2

v2 1−a +β=0
2
Sol: Rmax =
β = a + 1 > 1 ∴ β ∈ (1, ∞)
2
g
Area = π(Rmax)
2
62. Ans: π log 2
πv 4
=
g2 1
log (1 + x )
Sol: I= 8 ∫ 1+ x2
58. Ans: Statement – 1 is false, Statement-2 is 0
true. π
4

Sol: If υ ⇒ 2υ,
∫
= 8 Log(1 + tan θ) dθ
0
V0’ > 2V0, well known result = π log 2
⇒ Statement 1 is wrong.
Statement 2 is true.  d2 y   dy  −3
63. Ans: − 2  
 dx   dx 
59. Ans: more than 3 but less than 6.  

τ = Fr = 40t − 10t
2
Sol: d2 x d  dx 
Sol: =  
τ dy 2 dy
α = = 4t − t
2
 dy 
Ι
   67. Ans:
3
square units
d  1 
= 2
dy  dy 
 dx 
−1 d  dy 
= 2
.  
 dy  dy  dx 
  1
 dx  y=
x
−1 d2 y  dx 
= 2
. 
 dy  dx 2  dy  A x=c
 
 dx 
 d2 y   dy  −3
= − 2  
 dx   dx  Sol: y=x
 
1 2
y= ⇒x =1
kT 2 x
64. Ans: I− ⇒ x = 1 (x > 0)
2
1
y= ,x=e⇒x=e
dv ( t ) x
Sol: = − k (T − t) e
dt  1
∴area A = ∫  x − x  dx
V(t) = ∫ − k (T − t ) dt 1

k (T − t ) 2 e2 − 1
+C = − log e
2 2
t = 0, V(t) = I e2 − 3
=
kT 2 2
⇒I= +C
2 1 2 e2 − 3 3
Required area = .e − =
kT 2 2 2 2
C=I−
2
Therefore, 68. Ans: Statement-1 is true, Statement-2 is false.
2 2
k (T − t ) kT
V(t) = +I− Sol: P is (-2, -2) and Q (-1, 2) since R bisect
2 2 ∠POQ, PR ¨RQ = OP : OQ
kT 2 = 4 + 4 : 1+ 4 = 8 : 5
⇒ V(T) = 0 + I −
2 ∴ Statement 1 is true
kT 2 But statement 2 is false.
=I−
2
3 1
69. Ans: p= − ,q=
65. Ans: − 144 2 2

Sol: (1 − x − x + x ) = (1 − x) (1 − x )
2 3 6 6 2 6 sin(p + 1) x + sin x
Sol: f(x) = ,x<0
= (1 − 6x + ..− 20x … − 6x ) x
3 5
x
(1 − 6x + 75x − 20x ….)
2 4 6
= q, x = 0
= 120 − 300 + 36 x + x2 − x
= 156 − 300 = − 144 3
,x>0
x2
66. Ans: local maximum at π and local minimum at is continuous.
2π x
⇒ p + 1 + 1 = q = lim
x →0 3  
x 2  x + x2 + x 
Sol: f’(x) = x sin x  
2x cos x + sin x 1
f’’(x) = =
2 x 2
f’(x) = 0 ⇒ x = nπ, n ∈ Z 3 1
ie., x = π, 2π in 0 5π
2
( ) ∴p= −
2
,q=
2
f’’(π) < 0 and f’’(2π) > 0
∴ f(x) has maximum at x = π
And minimum at x = 2π
 Sol: (1 + ω) = A + Bω
7
2
70. Ans:
(− ω ) = A + Bω
2 7
3
− ω = A + Bω
14

− ω = A + Bω
2
3
Sol: The angle is sin−
1
1 + ω = = A + Bω
14
∴A=1 B=1
1 + 4 + 3λ 3 ∴ (1, 1)
∴ =
(1+ 4 + λ )(1+ 4 + 9)
2 14
76. Ans: −5
14 (3λ + 5) = 9 × 14 (5 + λ )
2 2
2 2
9λ + 30λ + 25 = 9λ + 45 Sol: |a| = |b| = 1 a. b = 0
2 (2a − b). ((a × b) × (a + 2b))
⇒ 30λ = 20 ⇒ λ =
3 = (2a − b) ×
[(a. a) b − (a. b) a + (2b. a) b − (2b. b)]
71. Ans: (-∞, 0) (2a − b). (b − 2a) = − 5

Sol: |x| − x > 0 77. Ans: 7

⇒|x| > x
⇒ x ∈ (-∞, 0) dy
Sol: = y+3
dx
3 2 dy
72. Ans: = dx
8 y+3
Sol: Slope of the line perpendicular to log (y + 3) = x + c
y – x = 1is (-1) ∴y+3=ce
x
Hence t = 1 x=0 y=2 ⇒ c=5
Point on the parabola corresponding to t = 1 is
∴y=5e −3
x

 1 1 ∴ y (log 2) = 5 e
log 2
−3
⇒  , 
4 2 =5×2−3=7
1 1
− +1 78. Ans: 3x + 5y − 32 = 0
2 2
4 2 3 2
∴ shortest distance = =
2 8
x2 y2
Sol: + =1
73. Ans: 21 months a2 b2
9 1
Sol: Total savings = 11040 + =1
a2 b2
Savings in the first 2 months = 400
1 9
Hence, savings in the next n months
2
= 1−
= 10640 b a
We have
1 a2 − 9
n
2
[400 + (n − 1)40] = 10640 1
(
a 1− 2
5
) =
a2
[200 + (n−1) 20] n = 10640 3
a −9=
2
200n + 20 n − 20 n = 10640
2
5
20n + 180 n − 10640 = 0
2
3 32
a =9+ =
2
n2 + 9n − 532 = 0 5 3
9 ± 81 + 2128 3 32 3 32
b =a × = × =
2 2
n=
2 5 3 5 5
− 9 ± 2209 −9 ± 47 Equation of the ellipse is
= = x y2
2 2 + =1
= 19 32 32
Therefore, answer is 21 months 3 5
3x + 5y − 32 = 0
2 2

74. Ans: ~ (Q ↔ (P ∧~R))

79. Ans: 4
Sol: The given statement is
(P ∧~R) ↔ Q ≡ Q ↔(P ∧~R) 25a + 26b
Sol: Median =
∴ The required negative is 2
~ [Q ↔ (P ∧~R)] 51a
=
75. Ans: (1, 1) 2
Numerical value of the sum of the derivation
 1 3 5 49  1
= 2a  + + + .... +  ≤
2 2 2 2  32
1  1
2a × 252 P≤ = 0,
= = 25 2 a 2  2 
2
Choice (3)
252 a
Mean derivation about median = 84. Ans: a =c
50

252 a Sol: Two circle should touch each other

= 50
50 a 
Centres are  ,0  and (0,0)
50 × 50 2 
|a| = =4 ∴ also second circle passes through (0, 0)
25 × 25
∴c=a⇒ a =c
80. Ans: Does not exist
85. Ans: Statement-1 is true, Statement-2 is true;
sin( x − 2) Statement -2 is not a correct explanation
Sol: lim 2
x →2 ( x − 2) for Statement-1.
Limit does not exist
Sol: if AB = BA
T T T
(AB) = A B
81. Ans: Statement-1 is true, Statement-2 is true;
⇒ AB is symmetric
Statement -2 is a correct explanation for
Statement-2 is true
Statement-1. T T T T
(ABA) = A B A
Take A = I and B = some non – symmetric
Sol: x1 + x2 + x3 +x4 = 6
xI ≥ 0 ∴ABA always
9
no. of ways = C3 ∴A(BA) and (AB)A are symmetric
S2 is true Statement-1 is true nut does not depend
S1 is true on Statement-2
S1 follows from S2
86. Ans: P(C|D) ≥ P(C)
82. Ans: Statement-1 is true, Statement-2 is true;
P(CD)
Statement -2 is not a correct explanation Sol: P(C | D) =
for Statement-1. P(D)
P(C)
A = (x, y) y – x ∈ z =
P(D)
Sol:
B = (x , y) x = αy for rational α
A : x – x = 0 ∈ z ⇒ (x, x) ∈ A reflexive ≥ P(C)
y–x∈z⇒x–y∈z
⇒ (y, x) ∈ A symmetric a⋅c
87. Ans: c − b
y – x ∈ z and z – y ∈ z ⇒ z – x ∈ z a.b
∴ (x, z) ∈ A transitive
A is equivalence relation Sol: b ×c = b×d
Statement – 1 is true
a⋅d = 0
B: x = 1, x ⇒ (x, x) ∈ B reflexive
x = αy⇒ y =
1
∴ (y, x) ∈ B
( )
b× c −d = 0
b and (c − d) are collinear
x
α

b = k (c − d)
symmetric
x = αy and y = αz ⇒ x = α z
2

∴ (x, z) ∈ B transitive a ⋅ b =k (c − c ) − a ⋅ d]
k [c − c ]
B is equivalence relation
Statement – 2 is true but I does not
follow from 2. a⋅b
k=
a ⋅c
 1 ac
83. Ans: 0, 2  b c−d= b
  a ⋅b
5 31 a⋅c
Sol: 1 -P ≥ d=c− b
32 a.b
31
P ≤1-
5
32
88. Ans: Statement-1 is true, Statement-2 is true;
Statement -2 is not a correct explanation
for Statement-1.

Sol: A (1, 0, 7) B,(1, 6, 3)

x y −1 2 − 2
= =
1 2 5
P (λ, 2λ + 1, 3λ + 2)
drs (λ - 1, 2λ + 1, 3λ - 5)
∴ λ - 1 + 2 (2λ + 1) + 3(3λ - 5) = 0
14λ - 14 = 0 ⇒ λ = 1
P (1, 3, 5) is mid point of A and B
Statement-1 is true
Statement-2 is also true but
statement-1does not follow from 2

3
89. Ans: ≤A≤1
4
2 4
Sol: A = sin x + cos x
4 2
= cos x – cos x + 1
2
 1 3
=  cos2 x −  +
 2  4
3
∴ ≤ A≤ 1
4

90. Ans: 2

4 k 2
Sol: k 4 1 =0
2 2 1
4(4 – 2) – k (k -2) + 2 (2k – 8) = 0
2
= 8 – k + 2k + 4k – 16 = 0
2
⇒ - k + 6k – 8 = 0
2
k – 6k + 8 = 0
⇒ (k – 4) (k – 2) = 0
⇒ k = 2, 4
∴k=2