Unitsd States Office cf May 1979

Envíronmental Prot€tt¡on Toxic Substances

Agency Washington DC 20460

Toxic Substances

.?EPA Toxic Substance$

Control Act
Chemical Substance
lnventory
lnitial lnventory
Volume I
/
l¡
l¡
tl
,

TOXIC SUBSTAI.ICAS CONTnOT AcT ffscA)

.STI3STANCtr
CI{EMTCAT INVNNTORT

voru!{n r
INüTAI INYENTORY

etay t9?9

. I¡.s. F,nvíiose¿nt¡it p¡r¡tcction .Agen6y

O,ffiee of
Toxie .Substå¿sss
Teshiugtorç I),C. å046t)
 SÐA SUBSTANCE IÐENTIF'ICATION PROCEDURE

FOR CLASS 2 CãEMICAL SUBSTANCES DERIVED FRGM NATURAL

F'ATS AND OILS AND SYNTHE"TIC SUBSTITUTES

i: ,'.;
-
..''
' The subst¿ìnce identification system presented here is an For example,- the SDA Substsnce Name for a fatty atrrinr
abeinãt* and relatively simple rnethod which s¡as used to which.contains predominantly C¡s-C¡5 saturaiåîifi
i¿ã"iiir fci ttre l¡ventorv cõrtain multicomponent Class 2 chain-lenrth
' is:
*trã¡nlcät À"¡stances deriíed from natural fats and oils and Cro-Cre alkyl amine
srmthetic lone-chain alkvl substitutes. The system was whe¡e the phrase -"Cro-Cre" couesponds to tlre Atbvt
developed bvïhe Soap aird Detergent Association in con= Ðescriptor.(A), and "amine', to the Functionality $Ë
;,*"ti i" øth tite EPÄ and iË inteided to standardize the ecripto¡ (F),
i¿*"iin""lio" of substarces manufactured and used extenc
;i";i; ilih; soap and detergent índustry. Accordinglv, the $imilarly, the SDA Suì-staace Name for the sodiun sålt of
a fatty larboxylic acid comprisgd. p¡e{oml:r*ntty oi C,¡
multtcomponent soaps-ancl sufiace
swteLr was used to identify-their
àitii,è (*nd *to preci:rsors and derivatives) saturated and Ctg unsaturated alkyl chains is:
"su;ts i*potteA,
;;uf;ci*ed, or procässed for such usesaç wettlng
unsaturated alkyl carboxylic acid sodium Êslt
*ãot*. ã*ultitiets, ¿itóu.sãnts, and penetrants - Its appli= C1¡ and C1s
.ã¡iiiiv, t'toÇà"er, óxteirded beyond the soap and detergent
industry. where the phrase 'C1¡ and els u*saturatedn conespondr
This"svstem wag not to be used to identify any single to the Alliyl Descriþtor (A); 'carboxylic acid' tp the
***n"át Chss 1 chemical substãnce (i'e., a substance whose Fu¡¡c{ionaliúy Descriptor (F); and "sodium sâlt', to tbe Sslt
mav be represeated by a definite chemical Descriptor (S).
"å*-tãiitiot
i[iüöt-"tr diaeram) cr ariy combination of such substånces
¡v ñixini withoirt cbemÍcal reaction' Futthermore,
"i""ãe¿
ífwas tå Ue uee¿l i-n those csses where the person reporting
"ot itJ applicability to be marginal or in question'
*"r¡¿ÀiÀ¿
The Class 2 chemical substånces which were reporl€€l us¡ng
tf¡ii liJtem a¡J cõ*pl"*, multicomponenl. m ateri als whose
indiviãud components have a common siructural feature: one f""*ãllo ¿eicribe more tha¡ 5,000 multÍconponent Class 2
ãiãät*-loitãj.t"ìn atkvl sxoups to wþich is attached a chemical *ulstÐrces.
ãtremic¿ll fü¡ctional g¡óup or groups. These components
differ from one a¡other with respect to one or mo¡e ol the AIhvI Descriptíon
6[Jñ;-io;;tchain alþl grou-p char-acteristics: lq"e-tþ fa¡,ie t lisis the Alkyl Descriptors covered by this system
iã*Uol""u"tbir), iaturatiõn,itruiture (linear or bra¡rched), or ãubitalie identiÍrcätion; assìgned to each^Þ a two-digit
à''ãi;;th; úsiiion of funciional sroup attachment(s). Alkvl Descriptor Code used in generating the liDA-lteporttng
-Ú"d.t tÀd SDA Subst¿nce ldentiñcatiôn Procedure, certain Nuirbers. discribed later. Each Descriptor identities a
oi iË**ã Clãsi Þ ctremicat substances are jdentified- bv SDÀ ãi*üì¡"tib" òi alkyl sroups in terms of carbon chai" length'
È*b;4""* Ñames and by corresponding SDA Numbers and saturation and/or rinsaturatíon, and linea-r or- branched
Substance Delinitions. ;tu;turã. Afitf grout distributions are inelusive of both even
*fnäbãtà1ioørs
snd odd alkvl chain lensths'
SDA SUBSTANCE NAMES of fÀÉt" t were cho$en to cove¡ the
ult vl group distributions actuallv
"r".iätln-*ñ-i*Á-"ttãi"
ãiãJ"î|ilîi-tbzEi i" ili"t coí"tñ"rciil multicomponent class
SDA Substance Names are systematically-deríved, and,
*iãiti" ttã tiãitaiions of the sistem' are as precisely de= i suUËtanc"s of tliis type, and to provide for each as plecise
predtcatea
scripÈive of the chemical composition of a substance as a description as practiial' Use.oÍ.this sy.stg7L is

-
oos¡ible- â" *tïí¡ii lnd norro*"si oin.y atstria"t.ían (Alkvl De=,
Sb¡' Substance Names con$ist of Lwo or, in.sorrr-e câses' scriptor) wLich descríbes the predomînant lnng-choln atR)'t
t¡i"u pa"ts. ihu tsro parts common to all SDA Substance ;;i;Á ¿tf tht s¿bstãnce reported- In this contexü,
ioteão-itaotn
the term
pe¡cent 0l âlr
means that about 80 to 100
Ñ;*d;;' (r) ihe elËyt Desgiptor, A, which desqibes the
lJ#--"Ë;iläknl'e.o"i--åiä¡"ãtuãlã*ii¡inthedescription'
Ío"n--"-¡räi" àicvl storrís of tlie substance, and (2) the
þ"üñ.tìã"ui¡¿u if*=ciiptót, F, which identifies the functional lä *t" e*vl beécriótor' a saturated, linear ìong-charn all(-vr
irãt-pi*i"riË* s[Uiá.u. Á tt'itd part, the Saìt Descriptor, srouo is denóted bv 't." where the subscript x indicates tne
-ú;s"tsqt"d
É, identifies the cation(s) of any salt'.
-svstematically
i,äË# äiäË'";t ã1 i" iÈl-.ä.îi"ü;- qenotecl Dylxd \'¡
-' Sbî -
Si¡tt""cã Nanlát constructed multiple b¡anched alkyl groups âre
"te
according to the follorring folmats: unsatirrated" and "C, branched", lespectively'
Bv convention. th" t*"Ë;;}ìå"b;ti.to*t i" a long--chain
(A) arkyl (F),
or in the case of salts,
(A) alkvl (F) (S)' "*år:ru**::##mlr*#lnjåtxÏmöTü,
it'itictt-at" coànected to eacå other in a unbroken châtn or
-
¡'ot- ä*ãäp¡e; tbeãlkyt chainlensth'
where A denot¿s tLe'Allryt Descriptor; F, the Functionality äiË"1'tìä.¡"á":¡ìÃã..
ã-J.id;t"d b; "niîn t¡ã iepiesentåtitte strudtural diagrams
Desc¡iptor; and S, the Salt Descriptor' I
eb

found in Table 2, includes the aryl carbon of carboxylic acida
and tbeir derivatives, and the tstal number af carbon atams
i¡ such structures as B-CH2-OH or R-CH:CH2. The aìkyl
sroup does not Ínciude, however, functional group carbon
ãtoms which are partofa phenyl ring, or are separated from
tJre alkyì chain by a phenyl group ór an atom other ihan
carbon, e.g', R-Ph, R-N(CH¡)r' or R-O{CH2).NH2.
Unleqs spgcified otherwise, the alkyl groups identified by
each Alkyl Desøiptor are linear, or essentially linear, hy=
d¡ocarbon chains. The natural fats and oils listed below
provide such aìkyl groups:
is a representative structure diagram or diagrams. In rna*y
cases, these diagrems depict only one of several possible
igomers of a substance identified by a given Functionality
DescrÍptor. For example, a C1a-CÉ slkyl amine identified by
this system may contain components which have the smine
functiona.l eroup (-NHJ att¿ched to a terminaì alìcjrl carbon,
as shown in Table 2 for Functionality Descriptor Code 029,
or üo any other carbon atom in the alkyl chain. ?he op=
plicability and limitotior* of each representatiue structural
diagram are defined by a Substonce Definition. (See
Substance Definition, below.)

Vzgetable ,4nimaI Salt Ðesoíption

Tablelists the Salt Descriptors covered by this system
S
Avocedo Grease two-digil Salt
of substáncË identification; assigned to eacl¡ is a
Babassu Lard Descriptor Code used in generaÉing the SÞA Repo¡ting
Castor Neatsfoôt Number. SDA Substance Names for Class 2 chemical sub=
Coconut Poultry stance which a¡e not sglts contain no Salt Dæcriptor part¡ the
Corn Tallow Salt Ðescriptor Code for such substances is 00.
Cottonseed Mixed salts of monovalenl anisns are considered mixtu¡es
C¡ambe Mrrir¿e' of the individual salts, eaeh of rr¡hich were to be identified
Linseed separately. Mixed salæ of divalent aaions, however could be
Olive Herritag identified as a single substance.
Oiticica Menhaden
Palm Salmon SDA REPORTING NT}MBER
Palm-kernel Sardine
Pea¡ut S,perrn Body The SDA Reporting Numbe¡ is de¡ived using the two-or
Rapeseed (whale) úhree-digit codes associat€d with each Alkyl, Functionality,
Rice Bran Sperm Head or Salt Desgiptor contained in Tables 1, 2, and 3. The SDA
Safflower (whale) Reporting Nuinber is generated by systematically combining
Safflower Whale thCse codes for a given substå.nce in a manner simila¡ tn that
(high oleic) used to derive the SDA Substance Name. SÐÀ Reporting
Se¡ame Numbers have the fcllor+ing formats:
Sorghum
Soybean SD.À aa-fff-sg
Sunflower or for mixed salts of divalent a*ions,
Tung SD,{ aa-fff-ss,s's'
Wheat Germ wh€re "aan denates tbe appropriate Alkyt Descriptor Code;
.fff', the appropriate Functionality Ðescriptor Code; and
These sources provide both satu¡ated ard unsaturated altyl "ssn (and "s's'"i the appropriate Salt Descriptor Code{s}.
groups; cåçúor oil provides a Cr¿ hydroxy substituted alkyl
group. Alkyl groups derived from othe¡ natu¡al sources are For. example, tt¡e SDA Reporting Number for.Cls-C15 alkyl
not covered by this sy$tem. åmrne ts:
Synthetic sources can provide linear or essentially linear sDA 1ã-029-Û0
alkyl groups, i.e., chain branching, if any, is linited to no more This number was generated using t}e Ðescriptar Codæ found
than one secondary methyl (CHs-) or ethyl (Czlls-) gtoup per in Tables 1 to 3- Table t identifíes the Alkyl Descriptor Cæde
alkyl chain. For purposes of this system, the laÈter t3pe of fq¡ nÇ'ô*Ç¡¿": i5- Table 2 identifies the Function*lity
alkyl chain is included within the de*ignation "linear". Descriói¡r eode fo¡ "(alkyl) aminen: 029. Table 3 identifies
Multiple brar¡ched alkyl groups, derived exclusively from the Salt Descriptor Code to be used when the substance is
synthetic qources, bave separate Alkyi Desoiptore. not a sål* 00. Insertine ti¡ese numbe¡s in the sta¡da¡d format
Some Clirs$ 2 chemical subståxces covered by this procedure yields the co¡rect SDÀ Reporting Number.
are comprised of componentç which have two or more
long-chain alkyì groups, e.s., (dialkyl) amine, or (dialkyli SIJBSTANCE DEFINITION
dimethyl ammonium chloride. This system could be used to
identify such subst¿r¡cæ prouided that eaeh lonpchain alkyl Each Functionality Descriptor lisùed in Table 2 is assigned
group is de¡cribable, in itr predcminant composition, by an a Substance Definition Format number ranging from 1 to 6.
Alkyl Descriptor found in Table I and that none of these Through thit number, the SÐA Substance Name is linked to
long-ehain alkyl groups is a single component st¡ucture one of six gene¡alized Substance Definitione appearing in
describable by a defînite chemical struetural diagram- Tabte 4. F-or each substance reporied by thie procedure, a
unique definition ean be generated by inserting the Alkyl,
Functianality D escription Funõtionality, a¡d Salt Descriptor parts of its SDA Substance
Tahle 2 lists ùhe Funetionality Ðes*iptors which could be Name, and dlie correspondin! representative structural ili=
ed in this system of substance id
used identificatior¡;; assigned to agram found in Table 2 into the appropriate generalized
Funetionality Desuiptor Code used in
each is a thre*-digit Functionality Substance Ðefinition. Examples contained in Table 4 il=
generating SÐA Reporting Numbers. The partial chemical iustrate how such definitions å¡e generated, The Substanee
iubsÈancgnomenclatwe
suÐsEance tl uncuonåIr¿y Desgiptors}
Romeücìarure {Functionality IJes fcr each Definitiow prouide a ehemieøl descriptíon of each s*bsfanee
identifies a specific funetional group
group or glgroups. Different ídentìÍied 6y øn" SDA Suàstance Name and specify the
Ðescriptors are provided fo¡ salts, and for their corresponding applicability çnd limitstion of the correspandíng tepre'
acids. s entatiue structure diagram.
Associated with each Functionality Descriptor in Tabte 2 [Note: In Tabie 4" the ærm "posilional isomers", appearing
in so¡ne Substaace Delinitione refers to substances whirå
similü except for the position of funciønal
- sroup altachment(s)
arJóiheroris€
oñ the long-chain alkyl sroup(s).]
à seven step ¡nethod, described in .{ddendum III of the
foi;ã SuUsta¡ices Contiol Act Candidate Liet of Cheaical
Substå$ces {March 19?8i, *as rudul
menclature of this systern to tåe identÍ
of partieula¡ chemical subçtances, Ar
fuither illust¡ate the applicability
system are also pre*ented there.
f
 ÎÄ¡LD I
À:.¡qft !:rc¡i?rort

Alkyl.. Prrdo¡d¡¡¡n!
C¡rlon Chrln1lsgrb D13Èrtbut:oB
DÊscrlptor Codè Sàrnqltå* lrsB¡rpFârGd ÞrrncÞeil Alkyl De¡crlp,tor (â) llpacnclrture
0t Ð-18 t8 lo Cg-Clg ¡nit Clg uns8rur¡ted
o2 10-16 l¿-20 Ao CfO-C¡t and Crr-cr' unaatutrtéd
û3 14-18 L2-29 l|o Cf¿-Clg eai Crr-CaO un¡rt*¡¡ted
04 I¿-T8 r6-18 ¡ío Cl¿-Clg aad CrU-Cu un6etür¡cGd
05 1t-18 Lt-22 No Cf¿-tlg exd Crr-Cz2 Hñêrtll.têd
ûÉ 1i'18 L5-16 Ë¡o Cf4-tIB and Crr-C* rrtloeeur.tÊ¿
l4-22 t6-22 Ho Cl¿-Cl¿ ard (16-.q22 rmsatüratra{
08 16-2? 18 llo Ch6-CZ2 ¿l:d Clg üila¡Èürå,Èed
o9 1é 18 Io cI6 ¡nd cIE unsaturâÈ¿d
l0 l6 18, l8* Ho
!6 rlue Cru unsatura:ed rrrä
clg hydro¡y raarèur¡ted
r:. 16-18 r.8 Ìlo Cf¡*Ctg and Cm unçaËure!¿d
t2 t8 18 Nê CrU rnd C1, u¡|Êrtur.tcd
13 6-12 l¡t cg*ctz
Ltt 8*26 No cg-cz$
15 1Þ16 Ng -10 -16
1é l2-18 No clz-era
17 1¿-18 t¡o cl¿-cra
r8 lô-t6 llç cr¿*cz
5
I9 l6-¡8 llÕ cte-c:8
2A 16-18,18. l¡o CfO-Cfe *ail Cra þdroxy
2I r6-22 ïo -16 -22
zz I Iet Cg brâncheal
23 I Y¿3 C, brenched
2l' 12 TÊs C* brunched
ë 1l-13 ?e¡ a.ll-Ç¡3 brênchåd
26 ltþ16 ¡{o CIO-Cl6 uns¡¡u!åËed
1î l4-18 !*ô Cf¿-ClB utlsátutåÈed

*ilydrÞry EuÞsÊltutÊd rlhyl Stoup dcrlvéd fro!¡ Cåßtor 0f1

 ÎÂ.BLE 2

Flactloaetlty Þ*crlptorr

Func.
Desc. lunctlcneltty Deacrl.ptcr (F)
Code llç¡cnsl¡!Bre Co¿¡æn Nue

ooI {trl,¡lkyt} glyèertde r¿fln¡d fâr or õ11 R-C-O-CÎi^

¡ z;,
O
:
0 8C-H-R
R-C-O-CÏ^ I
o0
002 (alkyl) end (dialkyl) g.lyccrlde ,l
R-C-{-CH" R-c-o-cH^
il
o :,
a a t ln ¿

BCOH
It
EC_ô-C*R
tsocxã
tz HOCH.
O6
{¡,
o03 (a1ky1) ãnd (diâlkyl) ttJrccrldê R-C-o-Clll R-C-O-g$, O
e¿hoxylå ç€ ¡Z 1

Ëco- (cn,c¡râo)_-H uc-o-Ln

rlén,
H2@-(ffi¡c¡t¿o)r-B HzCo{CHzCn?o)n_B
o
o04 (rll<yf) g¡ycerid€ tr
R-C-O-CH?
tó ¡
ücott
I
l{0cH^
I
o
o0t (a1ky1) carborylir acttl farty ocld R-C-OH r
t
o06 (afkyl) carboxyllc acld (s¡Ir) sÕ¡p tr-C-Olla I
oo
t07 {alkyt} dlcarborylie acfd fãrtt dtbâslc a*td ltt-c-R*C*elt I
o
¡l
0ü8 {alhyl} carboxyttÈ ¡cld a-bury1 fat.ty buryl ester R-C-o-(cr{2)3fiì3
eater I
o
ú
çtt^c]{_
Ô09 (alkyl) carboxylle acld 2- fatry ?- elhyì-hextl 11 5
R-C-o-CB2C¡i(C¡¡2)3cË3
ëìhylhèxT1 çsrer asÈêt ¡
o
Olû (allyl) earbøryllc ¡r41d Eêrhy} f,âtry BÈt¡yl ester R-C-o-cR"
e¡¡.er 5 I
oo
¡a
6l¡ (dlalhyl) csrþonl'lte acld f.tty €th}¡lcne glycol R-C-O-(CH1)a- (Þc-R
ta

ethylGnc g¡ycû1 d1¿6ÈËr I

dlestrr {1

àfZ (a1ky1) dleârbÖrrytlc

:clê 2- frrty 2-erhylhetyl r t8-*cq-[l3äür,.-.*,,,
êrfylhsxtl dlestcr dlec¡cr
013 (al.kv1) dlcrrbox¡lic ecld f¡¡trT hèrqyl dr.cgrGr n- (t-o-tcg:ls-c¡l¡)z
h;¡çyl d{êster
ocH-o
014 (trl*lkyl) csrbcryltc ¡clat t ¡J
R-Cro-ct{2ccH2-o-c-R
.t

trlEerhylolcthane trle¡¡er
cn2-+-c_R
ô
o
).
cH-cH- O
015 (trl¿lkyl) cårboxyllc rÈl.d ltJâ
R-C-O-Cil2gcil2-ù^c*R
trtrleÈhylolprôpånê trLeslar
c¡t?-o_c*t
ô
6sa1¡¡ rr¿
dGptcrèd in terr¡ of !gdtü¡! crtloû(s).
bR"f"a ¿o eorrccpondfug SuÞ¡rr¡ec S¡ff¡iiloa Fo¡¡¿t ¡r¡¡ber (l_6) in lable 4.
 I
(Éarr¡á1hyl) errboxyllc åct.l
I 3t*t-*
R-c-o-cfl^ccï^-o-B-R 2
parÈaerythrltsl Ècrr*¡ter ar t ,,
R-C-O-Cll¿ O
-_
o
û
(alfyt) cårboxt¡lle .cld Êrho¡ryLs¡.¿d fattT R-fr.o-{Clt2CBZO)n-H
ethoxylåÈ! rcld oß"
l,¡J
(rffyt) ca:boxtllc rcid parpoxylatcd fatty n-c-o-(cfc8?û)n-H
prgpôxyl Ête reld offir
ItJ
(al.kyl) carboxyllc ec{d :tàöxylrtcd prôpôxyl, ¡-c-'o*{clt?en20)â tc3(¡r¡o)E-ü
e thô:çlata proSaxylatc etrd fatty acld o
at
(ally}) carboxy3.ir ¡cld ralde fåÈiy asld. R-C-mt2

(¿lkyf) carÈorcylf.c eeld ¡¡fde ethoxyl¡tËd f¡ity

$
R.C-N
,{cH"crro)--n
egheXrrlsra å¡¡fdê .
t{cïrcrro)r-tt

(altyl) c*tbo:çIl* ¡eld rslde

fl -cllocrrott
ütroËthânol felt] R-C-m{
øncetharcl lrÃfde
I ,oratoH
(alkyf) carbe)ryli,c ¿cld ¡aide ænol*opropenol n-c-Ì¡H -:-.
Lna
ænol.soFrope¡ìo¡ frtry aald*
Lcn,ot,ótt
(alkyl) carbctyllc åctd sr*1dê dtêghanol f¡tÈy R.C-N
tanrñtrott
dlt thaucl æide
cll'

(a1kv1) carbo:qyllc ¡¡etd ¡nlde dllrepropãûol fåtiy

!
R-C-N
,o,,åd"
dliËûFropårrô¡ aalde 'cu-gHoH
¿a
cHa
o'
(a].kyl) cerborylle acld ¡olde n-ä+rir-n
{atkyl) co
tlil
li,Nr- (digtkyl) ethytene blr n-c-Ng{e$2) 2-Bll-c-R
ã!l¿a oo
It tr
tl,ll'- (dialky]) prolyLene bls R-C-llr(Clr2)tilB-C-r
¡¡l,de
(¿lkyl) aolnc fartY rulnt R-ffi2

_ -^ /(cÍzcllzo)nll
(afkll) åDlne e¡äôrtlst. êtt¡ûxylarèd fatty R-¡l r-
¿¡¡lne (cil2cu2o)tolt

(allyl) arino ètby:.êûe rltrfle fåltl Fñ:rna D1¡rlla n-xn-(cuz)?c¡ll

l{-{¿lkyl) prêÞyltüè dL¡¡¡tnt R-lft-(ctl¿) l-l{tt2

X-{alkyl) proÞylen¡ df:¡iÈt -'-'(cn").-tI

n-il'(c*zdzo) 1To^o-ol
¿ ¿-Y "
êthÞ¡(ylãt€
' (€ftzcu2o)
lil
(alkyl) clkþty ethyleuc n1!r11¿ fat¡y èÈhet nltrlt¿ R-€*(CtZ)2-cd¡

035 (a1!yl) alloxy prorTlene l¡ins R-.o-(cn¿)3-Ns?

¿ ¿'ttR
^(cil^c¡i^o)
R-O-(fi^)^-n,'
036 {afkyl} a]kcxt pro?ylenc ôr!!n. t 5
elho¡cylet; '{cttrcttro)"H
e37 (alfyl) âl¡6ry crhylenê rrltrã fr¡ty êrller ¡.,a*(dz ) !-Hu- (Ë$r) r-crll
nf trlle rirrtle
03ð (¿lkll) alhå¡(y propylèûc slnÈ frttt ètlrr dir¡lnr R-O- (Cã2)
3-¡¡B-
{tllz) 3-xttt
PrsPylele lelnc

t,
0!9 {¡llY}.} nltrll. frÈÈy nlrllle R*Câll

040 (¡llyl) dl¡cthyl e¡Lnt fatiy dlocthyl rnto* n+¡-(cll:)z

glla

0&l (¡ltyl) dbttlryl r.Elnc oxlde fatty dtæthy1 r¡¡Jtrc *-l-to

oxldc ctj
R\
ã¿.2 tdl¡lkyl) r¡far dlalkyl, !¡lïe trffi
E ?

: R
043 {dlalkyl) aethyl AElBâ dlalkyl EèthT1 rnlñs 'N-CH- ;
R.J
R
&r1 (trt.lkyl] an{n! trl¿l¡.y1 6r[1¡e 'x-r
R.
a;::a: ,
I r'x'cfl^l+
rl
..î

c¿5 (alkyl) trlo;thy1 atoonlu¡¡ rlkylrrtr¡êÈhy1 I ct-

.hlort¿e s@orìlue chlqttrde Lcnr' 'carJ

(¡lkyl) ¡rlu.thyl aæniu¡

brooid:
rlkyl ÈrrffÈbyL
ræn1u¡ br¿¡aldg
[L8í*-n1orl*
m¡J
,,-
+
ln or-J
(dl¡lkyf) dltlcthTl em¡irs dlalkyl dloeEhyl cr-
ù¿¿7
rhlorld" aæniu¡ chledd* [;":*,.l
\+
-lR Cfl- I
o¿8 (dt¡llryl) dl$el,hyl amniun dlalkyl dlÉethy1 l'r¡'totrJ
'l Br-
5rsnide aEronluü broE{dc [x' *
fn trt-1
(dråtkyf , dinethYl ænl'ur¡ dlålkyl dloe¡hyl aa-
uathyl sulfale sriiun ËÈhy1 su¡-
fat¿
|.-rU.| 'u,'oo

050 Itrlalkyl) ûcthyl ä¡monlun *-

cl¡Loride l-o.l,,l-
05x (rrtrllyl) Eêrhyl â:¡ã¡onlutû *-
brsside [.,-d,,,]-
(s1k¡l) bèRzïl diÐethYl CI
aænlrs chloride [*-T,'-:î:].
t53 (dlalkyl) benzyl
âEã6n18 chlorlde
uethYl" fO-cur.",n
L *' 'ctrJ
l. ct

05¿ (ü1rlky1) ben:yl aænlun fO-.tr.n'*l* .,- 3

chlorfde L n "nJ
O55 (atkyfl chlôrlde ¡lkyÌ chlorlde RCnz-Cl 3

05ó (elkYl) bronldi elkyl bronlde RE¡2-år 3

t57 (alkyl) alPha olefln alpha olefln a-cH.C$, 3.

058 (alky!) âlk€né â¡d (alkYt) R(Cll2) I

xcE,{H(c82}*so3B'
hydroxy sulfonfc actrd
B(ætz)scu(su2)¡5orlt
OB

099 (alkyl) ¿1kent ¡¡rd (allYt) olcfin ¡r¡lfonate R{crr2)

re}i-c8
(c¡t
r} ¡sorna
3
bTdroi:y ¡ulfonle *cld (eslts)
R (CE2 )
xCA
(eX2 )¡soul{a
CH
 fatty alcohol ': 3 ¡,:
(¿fkyl) alcohol R-CHz-OH

(e¡kyl) atrcöhûl sulf,utie âcld n-cE2-oso3tl 3

i.
(alkyl) alcohol sulfurlc sefd a1kyl sulfate R*Cr{r-os0rlla
(eel t)

(¿lkyl) alcot¡ol phosPhmlc aeid B-CU2-O?O3lt2 3

,;.
(¡ltyt) slcâhol PhÕsPhorlc acid alkyL phesphate esÈer R-cttr-oP0rN5, 3
(sa1t)
(elkyl) alc<¡hol ethoaYlåÈe ethÒry'låÈed fätty R-Cg?-o- ( cl{zclt20)
n-ll
A
a lcoho I
(alkyl) alcohol êtt¡ô:ryIåte R*CH2-0^ (CIr zsE?0) 4
n-s03ll
sulfurlc acld
(alkyl) ethoxylale -âulfurås- erhoxylsteú ålkyl tr-cHz-0-(cH2Ç*2o)
n-so rl¡.
4
gcåd (salt) sulface
(¿lhyl) elcohol ethoxYl¿r€ s-cn2-0- (cltZcï20) n*?o3H2 h

phosphorlc *c1d
(alkyl) alcohol ethô)ry1åÈê eÊhôxylated al,kyl B*CHZ- g- (ürZCA2€)n-PO3Nå2
phosphoric åcld tâalt) phogphate ester
cH.
(atkyl) alcobol. ethoxYlae€ eÈhoxtlatêd PrôPôry- R-Ctt2-0- {cH2cHZ0) (cttc¡t' 0) t
n
prtPoxylate lared fatty *leohol -
"*¡t
CHt

(alkyl) åIcohol ethö:(Y}âÈe

- R-çg (Gt2cll2o)n (cHcRzo )d-so 4
2-0- 3Il
propoxylate sulfuric acid
P¡
(cHcltzo 4
(dkyf ) dcôhôl èthoxy¡.ãre Pro- € ÈhoxyLa red FrÇpo:ry- R-CH (CII2CU ) a
2-0- Zo)n E-5O3f
poxylãte euLf,u¡lc acld (salt) Iated älkyl sulfate

E-clr2-0- (sH2clt20)n (cltcl¡20) -?o3¡{2

fl: tt
(affyLl alcohol et-boxyläEê Pro-
potylâtè PhosPhorlc ecld
CE.
tJ
(alkyl) alcohol eÈhoxy:âÈe Pra- eÊhô¡ßylâted propolçy* n-cHZ-0* (clt2clrz0) (c'ttcHz0);P0 4;
tr rlra,
poxf¡,åÈe phosphotlc acld latcd alkyl Phos-
(eatt ) thsle É8!êr
0It
¡
R-o-cH2ctlcli?-c1 3
(alhyl) glyeêryl erher chloride
o
3
(alkyl) glyc{dyL ether R-O-CH2CHCH2

0Ë
t
Ol7 (afbyl) glyceryl èthê¡ sulfonie fatty glycerol sul- R-ù'CllrCHCt{t-SOrNa
âcld (sa1È) f,onåEe

A
q78 (alkyl) Èpoxlde Ê-cl{ctt2

(eIkY,I) cna (ÇÈ2)*fl(cH2)rch3

t79 ben¿eoe LÀB

t
080 (alkyl) beazene Êulfo¡llc âcld cH, (cH2) (ctl2 )
*ül rcE3

çs03Ë
081 (¿Ikyf) benzeRe euLfonfe ¡eid LÀS ctr3 (c¡r2)xclr (cnr)"Gl
(s*l t)
çS0tlfa

{
 082 (¡llryl) rbaaol lfneer alkyl pbanol ¿tt3 (cnz) (cr!
xCH )
¡.cir, ' 3.'.:dl
q
OH ' -.lv
083 (¡Lkyl) phenol ethoxylete .tùonyl.tcd llfiç¿r c¡t3 (c¡t2 '':
)xcil {c$2)yeü3
rllyl phanol ¿'
q
o(fir?cH20)n¡t
{g1kyl) phcool er}roxylarc cu3 (c¡tz):cc$ (cHz)
eulfu¡lc ecld ycuS 4 '"'

q
O(CltZcH?ü)h-sO3N
(a1ky],) phènel €rhortl¡rè ,
¡ul- ethoryhÈcd lineát cn3 (cH2)rcH (crr2)ycH3
furlc ecld (ralt) rlkyl sulfera 4
èa3êr
ço(cH2ct?0)n-sorr¡r .i
(¡1ky1) phenol, cricrylrþ
c¡t3 (c1{2}xcH (c¡t?
phorpherlc rcld )
yç[3 4

q
o(ctl2çfl20)ñ*Po3t{t
087 (¡lkyl) phenoL crhcxylete phoe- cthü(ylârêd l*nsar
phcrlc ¡eld (¡dt) cl! (c¡t2)rcH(ËH2)ycü3
âlhyl phôrph¿rc
attef q
O(C*ZCH20)û-po3Nå2
(affy¡¡ phenol cthcrylace eçhortlãied prûpaxy- (Gt?)xgË (cï2 )ycn3
c¡r3
pröplrryIar€ lared ltnear allyt
phenol
Agi o (cü3fir20rn {cåcllzo)¡ã
(elkyl) Fhenol etbo:sylete pro-
poxylrte sillfurle ¿cid tl{3 (cH2)
xcH {cflz }yff¡
ûtt cn:
0 (ca3üt20)n (c'EcHzo)ü so3B
(rlkyl) phenol ethsxylaÈe 9ro- èthoxylrred propôxy- cn3 (cn2)l(ctt {c¡rz)
pcxylata aulfurl¿ rcid {salt) l¡led slktl ycnl
Fhesol
ralfåtê qll c':H3

o (cfl (cHütr0)r sortia

?cs20)n
(afkyl) phÊno¡ .rhûx)'lete pro-
Pc:rylete phorphoriç ¡cld
cn3 (cHX)
rcH
(ctt2 )Ïüt3
/^,
te., cill
åtc*r"*roln tåoo.ol,ror",
61kyf) phenol cÊhorgtrte pro- (c*:)"c*l
psryl¡r€ pbo-phorlc tcld (aalt) erhor.yletcd p¡$po¡cy*
lrtcd lincar aikyl
cHj (cH2)xÎH
phenoL phorpharê
?Fter
\-lJ cH3
åt o,r.rro)o (häro)"ror*.,
I
093 (dtalkyl) phenot Ilnaar dlalkyl pheuol
I

or*
å*

O94 (d1å:.ky¡) phenol etloxyhte cthoryl.tFd lfnËrr

l
dlalþ1 phenol t, -n
0(C¡l2ct¡10)n¡l

S95 (braachad elkyl) bcsrenü á¡ x1¡trnch¿dþ

¡
¡I
#r
ttr.
3:!:
ffi,.
lË'
ifæ:. rre
Ë 096 {breached alkyf) Þenzene eu1- R(ure..ìed)êsor¡r
x*i fontc acld
7:
t-

i¿
" (branched alkYl) benzene .
B{br¡nched).rro
.il.
osr sorN,
sulfônic acld (ea1t)

.
Rlbranched)-cr
qrlou
(branched alkYl) Phenal branched alkYl Phensl
098

!,(bra¡ched)--r
-
(brênchèd slkyl) Phaool ethôxYlêÈed þranched tirÞo(c¡t?c820)DB
erhoxyl.ate alkYl PhenoL

x (uranchcd
100 (br¿¡ched alky.l) Pheaol
ethèxYl'ate sulfu¡1c acld
\!o (cs2cÍ
zo) È-sûr'

t0l (þranched alkYl) Phenol erhètry1acêd br¡ached -

R(br¡nched)-<.t
\+ o(cgrcnro)r-sorxa
eÈhÞxtlae€ sulfurlc acid alkYl Ph¿nol sulf¡te
(salr)

R.(bræched)<s
' (,Lo(cu2cEzo)r-Po3H2
rÙ2 {branehed ålkyl) PhenÓl
ethôxylat€ PhosFhôrlc åcLd

r03 (br¡nrhed alkYl) Phenol etho*ylaÈed br¿netred

alkyl Phenol Phos-
-
R{branched)<,¡.
vLo(cu2cn?o)D-Po3Nå2
eÈho¡çYtaled PhosPhorle acld
(sa1t) phå,tê est€r

€thoÐ'lsted ProPoxt- cu^ 6

10r¡ (bra¡chçd alkYl) Phenol
€Eìroxry1ãte ProporylãÈê lated btanehed aL1Y1
R(branched) I o(c'z*rzo)r(¿uäro)rrr
Þhe*1

r05 (branched alkYl) ?henoI

e tl¡oìry14tê Propot'Ylstè
R(branched )g r (c'rc'ro); (f;1*ror,-ror,
sulfutlc aeld '

6
r06 (branclred a1kY1) Phenol erhoxglated ÞtoPorY- R(branched)4a
eEhoxyfate ÞrgPorylatê L¿ted branched alþ} o (crzc*zo) tr- (ill."ror,-ror*"
phenoL eulf,ete
sul,furlc acld (s¡ls)

10? (branehed alkYl) Phenol R(braoched)ê*o

ethoxYlate groPo:ryloLe (c*2c'2o)¡- {ä:cËro) -?o3lr2
phosphorlc ecld

(bræclred alkyl) Phenol êtho:tYlåted PrÖPô:q'- (brånchèd

cu^ 6
!08
etho:ry1ate PrûPÓxTlåte laEed branelt¿d elkYl
R )
f> o (cg2cuzo)n- (6ts1ffi ,o¡ r-rottat
pbosPhorle ¡¿1¿ (aa1t) phenol PheePhate
ê¡È3t
lO9. {br¿nched dt*lkyL) phenol brrnêþed dkfhyl p¡enof R {branched }ç- B (br*nched )

110 (braacìred dl.al.kyl) ph*nol ethorylst€d bråûched B (branchedþ¡ R(brrochcd)

étho¡rylatê ifalkyl phenol Y
o(cn:çg20)nB

. ;.. .' . ;y:

,so3f, ¿so3H
111 (alhyl) and (dlålky]) ph€troxy
benzeoe ¡ulfonlc ¡cld
R-o-o-p , R-o-û-o-R ç. : ). .-''
s03l{ 5ç3lt

,SOrNa
112 (alkyl) and (dtalkyl) ph€noxy
benzene sulfonlc ¿ctd (ealt)
.-o*-p , R-Go-CÞR
,SOrHa

dorr. íoru"

113 (braached alky3.) and (br¿nched ,to3" ,to3[

d1âtkyl) phenoxy benrs¡e nt¡r.)"(F o€ , n(ur.)-$-oÊ R(br.)
sulfonLc acld s03$ so3s

114 (branched alkyl) and {br¿nched , SO-l{a SO-H¡ 5

dtalkyt) phenory be*aen¿ ntu..lóoþ, ntur.)óoþ*r0,.,
sulfonf.c acld (sal.t)
9OrNa SOINå

115 (alLyl) alpha and {a1lcyl) ¡-C¡¡-C[z, Cllf (çH2]xCH-Ctl (Clìa]rCH,

Lalernatr ûle!{o
 TÂILE !
3r1e Dacrl?tor¡

$.lt Sel¡ Þc¡erlp¡or (S)

Dê¡crlþtôr Codà

00 (¡aue)

0l s¡ão[1r¡! ralt.
o? llthlue .!1t
ç3 poterrlua aalt
0{ eod.lrs ¡alt
05 btrfe sslt
o6 c¡rlc!,ur! erlt
Eâtoastul ar¡t.
o8 nlcl¡l eslt
09 :inc *¿lr
L0 ¡Lulnuq e¡lt
u tltanLu¡ B¿¡.r

L2 EeD€cibtnol aEln€ 3¡lr

1l d1êth¡nol rrllüá rá,1¡
L¿ trtðtbrnol, æ1¡r erlt
 llll¿ ¡ (cgstt¡ud)

SD¡. STÀ
låDorrlqr Hrûbtr 8ub¡tr¡er Xae suÞEttac¿ Deft!*tlori I -' I

sDâ oo-.ooHû (it) r*yr, {t} (S) or. Thc cocblnatÍoa of alkyl (Fi(S) havt¡e
{¡l) rr}yr (F) prcdoa{naa:.1y {¡f) r1Þ1 chalnlengthr that
gcoarally confsn to' or s¡e poslci.onal
trol¿¡¡ of, Èbe follorlng êt¡l¡cËr¡rs1 dlå-
g¡aD:

[-Io""tt rhe Repreaencas{ve Struãl

Iturel Diagræ froÞ Teble 2 strteh I
lcorrceponde to F; ltdLcate pro- l
aalt foro(s), if alrltcabreal
þr
EIHIPLE¡

SDÂ 13{6û.00 Cr-Ca* rlÞ1 rlrohol Ît¡q coÉÞlûåttou of ålkyl alcot¡ols harlrtg
predoaluntly C.-C, alkyl êhålûlêûgthÊ
" Eo, or are posl-
th¡t EaDerally ðonfõn
tloÉl ,.¡æÊ!a of,, the follouíng acruc-
tural dfrgrøt
R-çn!-o¡l

sm 00400-00 (A) rltyl (Ð (SJ or thê eoEblâÊÈloa of alkyl () CS) hætng

(A) rtleyl tr) predoainantly (A) alkyl èhalnlÉt8lhs ênd
cthoryl¿È¿ mdlor P¡oPoxylÐts höEólogues
(¿s ¿pproprlarê) tbat gener*lly confo¡ú
tor or arê poslclôt¡ål f€otûers of' rhe
follogfng ¡tructu¡¿1 dlagræ;
fÏ*"rr lhe RepreÉentelive struc:l
Itural Dlagræ fror TôbIe 2 vhfchI
lcorrerponds t0 F; fndlc¿te Pro- I
þr aarr fom(s), 1f
aPPllcable;-J
I

EILÀI'PI.E:

sDÂ 1:t-ô30-00 Ca-Crr-rlkll rtne the embln¿tlon of ¡lkyl â¡ô1ae ethaxy¡3¿ëa

Gtl¡ort¡tlc having predool,nånrty c<-c, r ôIÌyl cbåtn-
lenBths and ethoxylâte"hoÊ6loguea that
EêrÊrally coÈforu to, or tre Po6,1lioral
laor€r8 of, the folloting õtru.ÈsfaÌ d1a-
gre:

/'$u?a'l?o)Jå
B-!r

\*"r*ror¡

il
i: I
l;!
I:i
['i
iil
,ir'
 1å5LE ¿
Chcrlcrl 6uÞ¡tlnce tdcebf flê¿tlon
vlÈb t¡¡lp¡GÊ

Substa¡ce st .
SDÀ
Þef1nlrion Foro¡t RepgTtåEJ ll@b.r $ubrtp{e NtÂÈ Subsisûce D..flnfttgn
gDÄ 0c-000-00 (t) rl,kyl (F) (S) ¡r ?he cpnbfnarlon of elkyì (r) (S) h¡vinr-
(r) d'Ly! (r) ÞrêdÞafnântly {Á) alkyf chainl€ngthã Èhâr
generally coõfÈrn Lo rhr follewlng struc_
¡ural dls8rå¡:
lîn""tr lhe Represrntartve Srruclì
lrural Dfa8,rau fron Tabla 2 vhtch I
lcorr€sponds ro F¡ fndicår" p¡o_ |
lj.r 6åIt forø(s), if alnlicableaJ
EJI¡T}IPLÈS:

sDr 13-0t6*o¿ C.-C," rllcyl crrboryllc The co¡¡bi¡at1cr of alkyl carboxyllc atÊd
rË1d'Éodlr¡¡ a¡k aodlue salrr havlBg predoEinðnrly C--C__
.lkyl chåhlengrha Èher geaeratly
"BofåË"
to Èh€ falloFing ctrotÈ$ral diagras;

o
¡*8*o¡¡"
sDå 13-t 93-00 CU-C* dtalkrl pheaol The coÊbinarlon of dialkyl phenola
havlnr
grêdoulnänrly C^-C, alkyl chainlengrh5 -
that genelally ðonfôro ro rhe fo!loÞing
sîructurêl dlagrta:
R

0-
olt

sEA 00*000-0û (À) ¡Lkyl (F) (s) or 1ïÊ corlbin¡llân of aì.kyl (r) (S) h¡vi¡ç pre-
(Â) arkyl (F) donLnenrly (A) al¡tyl ch,ainì*ngrbt ¡çrd erhop
ylate and/ot prÕpor)'latâ honoleguac (ae ap-
groprlare) thsr g*.ierãtly conloro lo rhe
fclloving st,rueEurâl dfn6ræ;
[in..rt rhe ReprescnÈartve Struc:l
lturâI Dlatrro iroo Tablc 2 uhlchl
lcorresponds ro F¡ lndfcåÈe pro- |
þer salt foro(s), íf applicabfe.l
E¡ßXPLÊ:

sD¡. 13-011-00 callz llkyl ccrboxyllc
rcld et.honyl¡ta
the coËbtnrtlon of alkyl carbcxylic arld
Gthoxylsce3 having predminanEly Ca-Cì,
alkyl chafnlengths and echoxylate llooôi
Ioguet that generrlly canfor¡ Eû rhe fo¡-
¡gr1Ðg rrrqcrural diagra:l:

o
n-ë-o- {orrcriuo}n-n
 1ABLE ¿ (costl,¡r¡cd),.

S¡¡ÞaE¡icc SDÅ gþÀ

Ðèfl¡iÈlór Põ!Èrt nåÞorcl¡t llgbcr Ì
Sulrt¡¡c? ,Hor , SuÞrllnce Ðef1nlrlon .
. .1. .ri.
5 sDÀ 00-Õ00-Ð0 (a) dllyr (r) (s) o¡ The cot¡biurtloa of rlkyl (F)(S) fosf_
.
'.. '::
(å) rI¡.Í1 (e) ßlsull 1ao¡.ra havlng Þredøfn¡nilv-rrr
r1þ1 chrtnlengrhr rhrt generally ¡"]i;r,
tÊ th! follæfîB arructurâf or¡¡igei'---"
lÏno¿rt rhe RêpreaeþraÈfve Stxuc-ì
I rurel Diagran froa Tåbta Z vhfch I
lærrcrponds tô l; i¡dl,câc" pto- I
þr crlc foro(¡), lf applf cable. J

I,Iru{PLE:

sÞA 26-095-{}0 Ca, brroehed alkyl lhe cocbfs¿¡1en of allcyl be3ze!ì€ Þosr¡-
Þè8.2 Cnê tloul 1¿ooers hÂvlñg predmlnant¡y C.-
brrnched tlkyl cbatnleng,rhs rhôt g"ouÈátfy
coafor¡ to t,he follovlng Ëtrüitutêl dta-
Srtr*:
8.(banched)

Ê'8't
(cB3)3 (CËt )
?ÇH 2

sÐÂ s0-000-o0 {Â) ¡ltyl {r) (s) ar th: ec¡bln¡tlon of slkyi (F)(S) h¡vf*A
(Â) rlLyI (F) ptêdoELnånlty {A) a}kyl chsl$lênglhs êEd
cthoxylâtè end/or prepo*'Iâ¿ê horologu€s
(as approprle¡e) th¡¿ general,ly cðntarE
to, gs lrc Aos1Elonål lscuers gf. lhe
fellovtag slrucÈrrsl dtlgræ:
JÏ.s.rt the Reprcscnrátlve Srrue:l
I tural Dlagrao froo Table 2 uhfch I
lcolrerponds ro F¡ tndlcare pro-.1
þer ortt fom(¡). lf ewllcable;_l
UTÂHPI,E:

sDÁ 2¿-o99-OO C,. brrnched rlkyl
pÊánol othoryl¡tc
lhc coûblnatlon of elkyl Fhfaôl erhq¡t-
lrtee havln¡ predoâ1n¡îrly Cr, branched
allyl ctralnlentÈhË ¡nd athoxlfarc hmo-
lOguea that generally ccaftrn ÈOr or ¿re
p981t1or¡¡¡1 lâooera ofr rhê follovlng
arrrctur.l dla6ræ:
*1¡r-"h"d
fr" '0(clr2cB2o)nH

:.8,,
1",
(cn3) (cH3)
SccHzcHçHcH2cH 2

çë{cH2cx2s)nB