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Chemical Engineering
Course Structure
Third Year
Fifth Semester
1. INTRODUCTION
What is thermodynamics ? Macroscopic & Microscopic approaches, International System of
Units.
2. P-V-T RELATION OF FLUIDS
Phase, Ideal gas law, Vander Waals equation of state, Benedict-Weff-Rubin equation of state,
Redlich-Kwong equation of state, Virial equation of state, Generalized equations of state, Soave-
Redlich Kwong equation of state, Peng-Robinson equation of state
3. FIRST LAW OF THERMODYNAMICS AND ITS APPLICATIONS
First law of Thermodynamics, Control-Mass analyses, Constant volume Processes, Constant-
Pressure Process, Adiabatic Process, Constant temperature Process, Polytropic Process, Control
volume analysis, Theottling Process, Chemically reacting Systems.
4. SECOND LAW OF THERMODYNAMICS AND ITS APPLICATIONS
Limitations of the first law, Heat engine & heat Pump, Second law of Thermodynamics, Criterion
for irreversibility, Carnot cycle & Carnot theorems, Entropy and its calculations, principle of
Entropy increase, second law of thermodynamics for a control volume, Iscentropic efficiency.
5. THERMODYNAMIC PROPERTY RELATIONS
Maxwell relations, Internal energy, Enthalpy, partial derivatives method for enthalpy, entropy,
partial derivatives method for entropy, Jacobian methods, Joule Thompson Coefficient
1. DESIGN PRELIMINARIES
Design codes, Design Pressure & Temperature, Design stress and Factor of safety, Design wall
thickness and minimum thickness, corrosion allowance, Design loadings.
2. DESIGN OF SPHERICAL AND CYLINDRICAL VESSELS
Thin wall vessels, Derivation of Design equations, Design problems.
3. DESIGN OF HEADS AND CLOSURES
Types of heads, Analysis & design of the different types of heads, Design problems.
4. COMPENSATION FOR OPENINGS IN PRICESS EQUIPMENTS
Types of compensation, Theoretical determination of stress patterns around openings, Design
problems uncompensated openings, compensation for multiple openings.
5. DESIGN OF NON STANDARD FLANGES
Classification of flanges, Gasket & its selection, selection of Bolt spacing, Bolt materials, Flange
calculations, Flanges subjected to external pressure.
6. DESIGN OF TALL VESSELS
Stresses in the shell, Determination of equivalent stress under combined loadings, Determination
of longitudinal stresses, Determination of Resultant longitudinal stresses.
7. DESIGN OF SUPPORT FOR PROCESS VESSELS
Design of skirt support, Design problem, Design of saddle support, Design of saddles, Design of
Bracket Support, Design problems.