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SCIENCE &
ENGINEERING
Georges Kamarinos
Laboratoire de Physique des Composants ~ Semiconducteurs, 23, rue des Martyrs, BP 257, 38016 Grenoble Cgdex 1, France
Abstract
It is well established today that the development of integrated circuits, for at least the next decade, will be mainly based on scaled-
down CMOS technology on silicon (0.1/zm channel length, 108 transistors per chip, 10 ps delays...). A mass and efficient fabrication
must be based on two principles: (1) scientific fabrication, which means a sequence of sharply controlled physico-chemical processes;
(2) physical (not empirical) modeling and simulation of the working of the devices and of their coupling. In this paper, it is first shown
that such an approach needs to go back to the "first principles" of physics (as 50 years ago when semiconductors came into view).
Among the necessary physics developments in the domain of the physical-chemistry and of solid state physics, one can cite: molecular
dynamics; very thin oxidation and its relation to microroughness and surface states; non-Fickian diffusion; microcontamination; elec-
tromigration; exact solution of the Boltzmann transport equation (taking into account the electronic structure of the material, the tran-
sient regime and the quantum effects); analysis of the electric, electromagnetic and phononic coupling of devices and their noise; etc.;
Then it is shown that these developments need: (1) a revision of the classical educational program for microelectronics materials and
processes; a list of "new" topics to-be-developed is given; (2) a very tight coupling of R&D industrial laboratories with university
teams; they have to work on the same space and with the same equipment for technology research projects (doctor degree preparation).
The above two points can constitute the framework for a new educational strategy involving, in a new base, a closer collaboration be-
tween university and industry. Finally, it is shown that Grenoble can be a strong pole in an efficient European Network for the 21st
century silicon microelectronics.
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I
1982 1987 1991 1996
($10.2B) ($2g.0B) ($52.2B) ($I07.0B)
1990
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- How to measure these concentrations in a (already The channel length of the elementary MOS transistor will
doped or processed) surface or volume? satisfy
- How to detect a particle of 0.03/zm size locally in the
clean room of the R&D laboratory? 200/~ < L < 1000 A,, ULSI line width
- How to measure two foreign particles in a milliliter
of a liquid used in a process in an R&D environ- Here the partition principle fails, indeed:
ment? - The screening effects and the corresponding lengths
(to the above metrology challenges one can add the diffi- depend on fields and geometry; the injection of
culties of temperature, and AT, measurement in situ). charge is not efficient and the "vertical quantifica-
The above very brief review of the problems arising in tion" in the channel drives many transport global co-
scientific fabrication, required by ULSI Si-/te, points out efficients and effects.
that research activities concerning fabrication cannot be - Inertial effects appear; the current is not highly cou-
performed far from the environment of the R&D labora- pled with the electrical field (in time and space); the
tory. The absolute necessity of the injection of the basic transport becomes ballistic, the electron velocity
research activities in the R&D laboratories is a new re- overshoot is observed and the collision cross sections
quirement. It is so evident that R&D laboratories con- depend on fields.
nected with the industrial centers must fund the insertion In this step of integration, the Boltzmann treatment of
of basic (university groups) research teams in their envi- electronic transport is still valid if perturbation methods
ronment; a direct consequence of this remark is also that a are applied and high electric field effects are well ap-
part of the activity and the equipment of such a laboratory proached in spite of their complexity [23].
must serve the education of future engineers and re- For higher levels of integration, the nanostructures on
searchers for ULSI Si-/ze. Si will be analyzed as quantum objects; their intercon-
nections will be seen as de Broglie wave guides and the
3.2. Physics of working ULSI devices and circuits analysis of the influence of the high electric fields is yet
unknown [24]. Evidently these structures probably will
The design and the simulation of working VLSI come after the ULSI step but even today the 9, fl struc-
ICs are based implicitly, up to now, on the partition prin- tures, the permeable base transistor and the nanoparticular
ciple [21,22]. According to this principle an IC is a net- systems (e.g. diodes on porous silicon) constitute 2D, 1D
work of discrete devices which are operating discretely; or 0D nanostructures on silicon [25-29] (Fig. 2),
they communicate only by established metallic connec- There are two important problems due to the scaling-
tions. down and the high density of integration; they are caused
This principle holds for the "macroscopic scale" of by two types of effects:
integration where the channel length L of a MOS transis- - the high electric field effects which provoke the deg-
tor is longer than the mean free path of electrons l, and l is radation (ageing) of the devices and the failure or the
very much longer than the radius of the collisions of car- loss of the reliability of an integrated circuit [30],
riers with the lattice - the inter-devices coupling effects which affect the
reliability of the IC [21,22].
<< l < L, macroscopic scale (a) The high electric fields ( E > 106V/cm) and the
conduction by hot carders result in the:
The macroscopic scale of integrations holds so that when - injection into oxides (gate and isolation oxides),
L is higher than 0.3/zm. For this scale all transport phe- - generation of crystalline defects near the drain or into
nomena can be satisfactorily approached with the con- the gate oxide;
cepts of effective mass (m*eff), the bands of electron en- - impact ionization near the drain;
ergies, etc.; the current is strongly connected to the elec- - increase in the electrical noise of the transistor ( l l f
tric field (except for very high frequencies (f> 100 GHz) excess noise).
and the conduction regime is stationary. To avoid these effects or to remediate them one must in-
The simulations of I,V characteristics of such devices tervene at two levels:
are based on hydrodynamic-like equations or, better, on - in the design and fabrication of the device and of the
the classical integration of the Boltzmann equation. Even circuit (to find geometries softening the field near the
high field effects are classically approached with suffi- drain, drain engineering, to enhance the quality and
cient accuracy. the purity of oxides, avoid microntamination and
The future ULSI IC will include devices which will be control microroughness, to know exactly the 2D
characterized by profile of impurity diffusion),
- in the modeling of the working of the device and of
~. << l = L, intermediate scale the circuit (to lower the drain voltage, VD goes to
1 V, to identify exactly the more sensitive transport
G. Kamarinos / Materials Science and Engineering A199 (1995) 45-51 49
istics and the statistical m e c h a n i c s and irreversible ther- of Semiconductor Devices and Processes, Vol. 5, Springer-Verlag,
m o d y n a m i c s are n e e d e d to understand and exploit c o o p - Vienna, 1993, pp. 1-8.
[14] K.E. Spear and J.O. Carsson, Chemical vapor deposition in the
erative and i n t e r - d e v i c e c o u p l i n g effects. 21st century. The electrochemical Society, Interface, 2 (1993) 39-
C o n c e r n i n g the fabrication the necessity for the return 47.
[37,38], to basic "first p r i n c i p l e s " and the end o f empir- [15] D.K. Ferry, The role of interfaces in ultrasmall semiconductor
ism is obvious. devices, J. Vac. Sci. Technol. B, 2(3) (1984) 504-509.
T h e p r o g r a m s o f E d u c a t i o n m u s t therefore be drasti- [16] F.Z. Bathaei, Silicon device miniaturization and its effect on
processing technics, Microelectronics J., 20(4) (1989) 1-9.
cally revisited. O u r analysis also s h o w s that university [17] K. Maex, Silicides for integrated circuits: TiSi2 and CoSi2. Imec
research m u s t be closer to the R & D laboratories. Leuven, Mater. Sci. Rep., (1993) in press.
In the c a s e o f research (and education o f doctor d e g r e e [18] G. Abstreiter, Engineering the future of electronics, Phys. World,
students) w e s u g g e s t that the university groups must w o r k 5(3) (1992) 36--39.
in the s a m e p l a c e and with the s a m e e q u i p m e n t as the [19] G.L. Baldini, I. De Munari, A. Scorzoni and F. Fantini, Elec-
tromigration in thin films for microelectronics, Microelectr. Re-
R & D groups. F o r studies c o n c e r n i n g the electrical work- liab., 33(11/12)(1993) 1779-1805.
ing o f d e v i c e s and circuits, the two types o f groups can [20] W. Rieger, The impact of impurities in chemicals on the perform-
c o n s e r v e their g e o g r a p h i c a l i n d e p e n d e n c e . ance of DRAM's Siemens AG semiconductor grofip report, 1992,
S u c h a s c h e m e o f c o l l a b o r a t i o n is possible in several Otto-Hahn-Ring 6 D-8000 Munchen 83, Germany.
places in E u r o p e . F o r e x a m p l e G r e n o b l e , in France, is a [21] J.R. Barker, The physical limitations of integration and size re-
duction in semiconductors, Microelectronics J., 17(1) (1986) 15-
p l a c e w h e r e strong university groups ( C N R S laboratories) 25.
and large R & D laboratories ( C N E T / C N S , L E T I / C E A ) [22] J.R. Barker, The physical limitations of integration and size re-
strongly c o n n e c t e d to Industry ( S G S - T H O M S O N ) exist. duction in semiconductors, Int. Conf. on New Trends in Inte-
O n e can find there the b e g i n n i n g o f such a collaboration grated Circuits Proceedings, Pads, 1987, pp. 240-246.
w h i c h for the m o m e n t exists o n l y due to a voluntary im- [23] F. Poupaud, About Boltzmann equations for transport modeling in
semiconductors. Simulation of Semiconductors Devices and Proc-
pulsion. esses, Vol. 5, Springer-Verlag, Vienna, 1993, pp. 17-20.
[24] K. Hess and L.F. Registrer, Modeling nanostructure devices.
References Simulation of Semiconductor Devices and Processes, Vol. 5,
Springer-Verlag, Vienna, 1993, pp. 9-16.
[1] G. Courtois, CAD and testing of IC's and systems; where are we [25] P. Chenevier, G. Kamarinos and G. Pananakakis, Universal elec-
going? TIMA/CNRS/INPG Grenoble, May 1993. trical characteristics and frequency limits of the permeable base
[2] (a) IEE (Journal of Electronic Engineering); spotlighting: semi- transistor. Communication in ESSDERC'93, Proceedings, Fron-
conductors and ICs: the latest development trends on SRAMs, ti~res Editions, Paris, 1993, pp. 121-124.
ASSP LSIS, ASICs, Flash memories, MOSFETs etc. Collection of [26] G. Bomchil et al., Porous silicon material properties, visible
technical review articles 29(308) (1992). (b) IEEE MICRO: chips, photo, and electrohiminescence, AppL Surf. Sci., 65/66 (1993)
systems, software, and applications. Special issue, Microelectron- 394-407.
ics in Europe, August (1992). [27] L. Canham, Silicon optoelectronics at the end of the rainbow?
[3] A. Harstein, Ultra-short channel Si MOSFET. Electrochemical Phys. World, 5(3) (1992) 41-44.
Society Spring Meeting, Washington, DC, 1991, pp. 432-433. [28] R. Herino, M. Rigeon, F. Muller and J.C. Vial, Vers une optoEiec-
[4] Electronics: At IEDM, future IC's reach limits of theoretical tronique tout silicium? La Recherche, 23(240) (1992) 248-249.
physics, (1993) p. 3 (review article). [29] M.H. Devoret, D. Esteve and C. Urbina, L'Electronique /~ un
[5] D.J. Franck, S.E. Laux and M.V. Fischetti, MontE-Carlo simula- Electron, Bull. Soc. Fr. Phys., 93 (1994) 7-11.
tion of a 30 nm Dual-Gate MOSFET: how short can Si do ?. In- [30] S. Cristoloveanu, Physical mechanisms of hot-carrier-induced
ternational Electron. Devices Meeting: IEDM 92, 1992, sponsored degradation in deep submicron MOSFETs. Invited conference in
by E.D Soc. of IEEE Technical Digest, 1992, pp. 553-556. ESSDERC'93, Proceedings, Fronti~res Editions, Pads, 1993, pp.
[6] D. Bois, Perspectives techniques et 6conomiques des composants 797-808.
intEgrEs. L'onde dlectrique 73(6) (1993) 4-10. [31] D. Chen, Z. Yu, K. Gwn, R. Gooscens and R.V. Dutton, Dual
[7] C. Morgan, Giin Shan Chen, C. Boothroyd, S. Bailex and C. energy transport model with coupled lattice and carrier tempera-
Humphreys, Ultimate limits of lithography, Phys. World, 5(11) tures. Simulation of Semiconductor Devices and Processes, Vol.
(1992) 28-32. 5, Springer-Verlag, Vienna, 1993, pp. 157-160.
[8] E.A. Lewis and E.A. Irene, Models for the oxidation of silicon, J. [32] G. Ghibaudo, H. Jaouen and G. Kamarinos, Integration density
Vac. Sci. TechnoL A, •4(3) (1986) 916-925. limitation in 3D ICs due to heat dissipation, Europhys. Lett., 2(3)
[9] T. Ohmi and T. Shibata, Scientific ULSI manufacturing in 21st (1986) 209-211.
century. The electrochemical Society, Interface, 1 (1992) 32-37. [33] G. Kamarinos, Final report of EEC ESPRIT BRA No. 3017
[10] S. Verhaverbeke, Dielectric breakdown in thermally grown oxide "Noise", ENSERG/LPCS/CNRS, Grenoble, 1992.
layers. Thesis, Katholieke University Leuven, Imec, 1993. [34] G. Kamadnos, Noise in advanced microelectronics: submicron, 2-
[11] L. Laanab, G. Bergaud, M.M. Faye, D. Faure, A. Martinez and A. D gas and low temperature electronics. In T. Musha et al. (eds.)
Claverie, A model to explain the variation of "end of range" Int. Conf. on Noise in Physical Systems and 1/f Fluctuation,
densities with ion implantation parameters, Mater. Res. Soc. Kyoto, Japan, 1991, pp. 303-308.
Syrup. Proc., 279 (1993) 381-386. [35] J. Brini, G. Ghibaudo, G. Kamarinos and O. Roux-Dit-Buisson,
[12] S. List, P. Pichler and H. Ryssel, Atomistie evaluation of diffusion Scaling-down and low frequency noise in MOSFET's. Are the
theories for the diffusion of dopants in vacancy gradients. Simu- RTS's the ultimate components of the l/f noise? In P. Handel
lation of Semiconductor Devices and Processes, Vol. 5, Springer- (ed.), Quantum 1/f Noise and Other Low Frequency Fluctuations
Verlag, Vienna, 1993, pp. 97-100. in Electronic Devices, AlP Conference Proceedings 282, Am.
[13] M.E. Law, Achieving accurate 3D process simulation. Simulation Inst. of Phys., New York, 1993, pp. 31--48.
G. Kamarinos I Materials Science and Engineering A199 (1995) 45-51 51
[36] C.T. Sah, Fundamentals of Solid State Electronics, World Scien- [38] A.B. Fowler, A semicentury of semiconductors, Phys. Today,
tific, Singapore, 1991. October (1993) 59-62.
[37] G. Busch, Early history of the physics and chemistry of semicon-
ductors: from doubts to fact in a hundred years. Condensed Mat-
terNews. 2(1) (1993) 15-27.