Professional Documents
Culture Documents
(Review Paper)
ﻳﻤﻜﻦ ﻟﻠﻤﺨﻠﻔﺎت اﻟﺴﺎﺋﻠﺔ واﻟﺼﻠﺒﺔ أن ﺗﻠﻮث ﻣﻴﺎﻩ اﻟﺸﺮب واﻟﺰراﻋﺔ واﻟﻤﻴﺎﻩ اﻟﻤﺴﺘﺨﺪﻣﺔ ﻓﻲ أﻏﺮاض اﻟﺘﺮﻓﻴﺔ وذﻟﻚ ﻓﻲ
وﻗﺪ أدى ﻃﺮح. وﻗﺪ ﻋﺮﻓﺖ إدارة اﻟﻤﺨﻠﻔﺎت وﻃﺒﻘﺖ ﺧﻼل اﻷرﺑﻌﺔ ﺁﻻف ﺳﻨﺔ اﻟﻤﺎﺿﻴﺔ.اﻟﻤﻨﺎﻃﻖ اﻟﺮﻳﻔﻴﺔ واﻟﺤﻀﺮﻳﺔ
ﺗﻘﺪم هﺬﻩ اﻟﻮرﻗﺔ ﻣﺮاﺟﻌﺔ ﻟﻠﻌﻤﻠﻴﺎت.اﻟﻤﺨﻠﻔﺎت ﻓﻲ اﻟﻤﺤﻴﻂ اﻟﺤﻴﻮي إﻟﻰ اﻻﺗﺠﺎﻩ إﻟﻰ اﻹدارة اﻟﻤﺘﻜﺎﻣﻠﺔ ﻟﻠﻤﺨﻠﻔﺎت
آﻤﺎ ﺗﻘﺪم.اﻟﻤﺘﻌﻠﻘﺔ ﺑﺎﻟﻤﺨﻠﻔﺎت اﻟﺴﺎﺋﻠﺔ واﻟﺼﻠﺒﺔ وﺗﻠﺨﺺ اﻟﻮﺿﻊ اﻟﺤﺎﻟﻲ ﻟﻠﻤﺮاﻗﺒﺔ اﻟﺒﻴﺌﺔ واﻟﻨﺘﺎﺋﺞ اﻟﻬﺎﻣﺔ اﻟﻤﺘﻌﻠﻘﺔ ﺑﻬﺎ
اﻟﻮرﻗﺔ ﻣﺸﺎآﻞ اﻟﻤﺨﻠﻔﺎت ﻓﻲ اﻟﻤﺎﺿﻲ واﻟﺤﺎﺿﺮ واﻟﺒﻴﺌﺔ اﻟﺤﻴﻮﻳﺔ وآﺬﻟﻚ ﺗﺘﻌﺮض ﻟﻸﻣﻮر اﻟﻌﺎﻣﺔ اﻟﻤﺘﻌﻠﻘﺔ ﺑﺘﺪوﻳﺮ
.اﻟﻤﺨﻠﻔﺎت واﺳﺘﻌﺎدة اﻟﻤﻮاد
Solid and liquid wastes generated from both animal and domestic sources can significantly impair
drinking, irrigation, recreational water and other water sources in rural and urban areas. Waste as
a management issue has been evident for over four millennia. Disposal of waste to the biosphere
has given way to thinking about, and trying to implement, an integrated waste management
approach. This paper reviews the history of solid and liquid waste operations and summarizes the
current environmental monitoring program and its major findings. Various problems of wastes in
past and present, environmental ecology, general aspect of recycling and materials recovery are
defined.
Keywords: Waste management, Waste problem, Environmental ecology, Materials recovery
19
S. Syed
day into them. And one would have to wait a long proportions that not only our natural environment is
time for heaps of junk metallic material dumped to affected but its vital processes, including the very
blend in with the earth's crust again as ores. This will existence of life on this earth surface is endangered.
not happen because we are dumping wastes faster This is the reason we refer these emissions as
than nature can degrade and absorb them. Further, pollution, and we are most concerned about their
many of the modern waste materials like plastics and effects on nature, it we cannot completely eliminate
detergents are non biodegradable. All these are going pollution, it is our concern to see how can we at least
to cause serious threat to our ecosystem. reduce it, and how can we support nature in
absorbing the part that is unavoidable?.
3. ENVIRONMENT AND ECOLOGY Environmental management must draw upon
many disciplines and professions. For the
Environment is the sum total of everything that consideration of natural balance of our ecosystem it
directly influences the animal's chances of survival or requires a good knowledge of ecology, particularly of
reproduction. The intimately close and immediate systems ecology where the properties of the entire
surroundings of the organism are known as micro- ecosystem are in focus. The knowledge of zoology
environment. The sum total of the physical and biotic and botany including that of general microbiology are
condition existing external to the organism and its of essential prerequisites.
micro environment is called macro-environment. As the emission from human society consists,
Ecology by itself is a multi discipline in nature which besides energy, of various complex chemical
includes subjects like physical and chemical sciences, compounds, chemistry becomes vital for a complete
engineering, law, medicine, demography, energy understanding of environmental management. This
conversion, automation, chemical technology and has given rise to a separate sub discipline called
environmental analysis. It is through the blending of Environmental Chemistry. In this context, we are
chemical technology and environmental analysis that particularly more concerned in what may be called, to
a new area called environmental analytical chemistry use a self explanatory term, biogeochemical
has arisen as a core subject area for the ecologist. reactions. In addition, various physical processes, the
Ecology is the science of interactions among transport of energy and pollutants in the ecosystem
individuals, populations, and communities and it also also demand the application of physics in our study.
involves the interrelations between living (biotic) The pollution problems have originated from the
components with their non-living (abiotic) human societies, and if this dominant species, Homo
counterparts or environment. Thus, ecology may be sapiens, were to disappear from the earth, then all
defined as "A multi disciplinary science which deals pollution problems would also disappear. It is our
with organism and its place to live and which focuses prime necessity to see that human societies are
on ecosystem". In the present context the term maintained on this earth and, to a reasonable extent,
organism refers to an individual unit constituted to keep them an integrated part of nature. These
carry on the activities of life. societies must therefore be properly understood and
must be taken into account in the context of any
4. ENVIRONMENTAL MANAGEMENT: A environmental management strategies. This implies
MULTIDISCIPLINARY CHALLENGE that socio-economic factors and legislation will also
Environmental management is the technology that have to be included in environmental management.
aims at eliminating or reducing the harmful effects of When we turn to find solutions to environmental
the emissions generated by human activities. problems, we may come across still further
Environmental management has three ‘legs' on which disciplines which have to be drawn up and include.
to stand. Firstly, it must take into consideration the 4.1 Principles of Ecology and Environmental
environment – that is, the ecosystem – and attempt to Science
provide management which will maintain a
reasonably, close to the natural balance for this The principles underlying ecology and environmental
system; secondly, it most reflect on the best attainable science have been developed during the twentieth
long term conditions for human society, including its century, particularly in the last two decades and the
socio-economic conditions; and finally, it must time is now ripe for the application of these
determine which solutions are technically and principles. Furthermore, tools such as ecological
economically feasible and which are not. modeling have also been developed and with the
The problems of environmental management are advent of high speed computers, such modeling have
related to the emissions of energy and mass from been refined and may offer the possibility of
human systems. Such emissions have been taking quantifying even complex ecosystems, and showing
place ever since the time of the earliest human how they operate as a whole.
settlements. Now, however, they have reached such
Moreover, it also considers sewage water and water (4)+(6) Environmental Managment
supplies, along with industrial waste water, but on the
other hand the construction and maintenance of Figure 1. Environmental management as related to other fields.
sewage systems are not under the purview of
environmental engineering. Emissions and impact are closely related to each
other (9), and environmental management attempts to
4.3 Eco-Technology determine the permissible limit of emission to ensure
Eco-technology has emerged as a new discipline an acceptable impact (10).
during the 1980s. It had been indeed applied even To avoid or control emissions completely ('Zero
earlier, but only now, it has become acknowledged discharge') is not feasible. However, by the judicious
and accepted as a separate discipline by its own right, amalgamation of environmental technology, eco-
with a full-fledged scientific explanation for its technology and environmental legislation, we may
fundamental concepts and principles. Eco-technology build up the kind of environmental management that
is defined as the design of human society within its will be able to maintain our environment in a very
natural environment, for the benefit of both. As is the near to ecological balance.
case with the older technological disciplines; Obviously, this type of environmental
ecological engineering and eco-technology have been management will become rather complicated. But it
supplied with a basis within the Theory of science. should not come as a surprise that this complexity
concerning a complex system requires a solution,
4.4 Environmental Technology which will be more complex in nature.
Environmental technology is concerned with Good environmental management system must
technical approach for overcoming or reducing the find and apply a wide spectrum of solutions
various harmful effects of emissions. Although it is simultaneously. One of the reasons for this is that all
mainly based on chemical engineering, but still also ecosystems are different and perform differently, and
requires as do almost all technological disciplines – this is true even for different ecosystems representing
assistance from process regulation, mechanical and the same types of lakes, forests, savannahs, etc.
electrical engineering and, of late from computer In addition, wide spectrums of environmental
engineering also. While striving towards pollution technologies are needed. There is no one universal
abatement during the 'Seventies and 'Eighties it has technology for all problems: each pollution situation
clearly shown that environmental technology and is different from the other. The chemical composition
legislation, even when they are at their best alone of the emission is different, the environmental
cannot by themselves solve the pollution problems. It condition is different, the associated emission are
is necessary to integrate what is termed eco- different, therefore we need specific individual
technology in the management strategy. solutions which will most often be different from
each other too, and will differ from case to case.
4.5 Relation to Other Fields The fortunate thing is that environmental
The relation between environmental management and technology and eco-technology have by now reached
the various areas (Fig.1)[5]. Environmental legislation such a high standard that we do have a wide spectrum
(2) may primarily assist environmental technology of choices at our disposal. It is a challenge to find a
(3) to regulate emissions (1), or with eco-technology good environmental management solution to a
to reduce the impact (5). Combinations results from complex environmental problem. But as resources
environmental management, (4) and (6). Impact is available to solve environmental problem are usually
assessed by means of environmental impact limited, it is of prime necessity to examine the
assessment (EIA) and/or modeling, see (7) and (8) in complexity of the problem carefully and consider
Fig. 1. various solutions available at our disposal before a
final management decision is taken. In addition, this
present context, solid and liquid wastes will be classification, the waste materials are broadly
discussed in the succeeding section. Nevertheless the classified as clean waste and hazardous waste.
classification of liquid waste demands separate
5.2.1 Clean Waste
treatment which will be dealt in detail in sections 10
to 11.3. This group covers hydrocarbons which contain only
carbon, hydrogen and oxygen. The oxidation
5.1.1 Solid Waste
products are considered clean and can be discharged
Solid wastes are those which arise from human and into the environment.
animal activities that are normally solid and are
5.2.2 Hazardous Waste
usually discarded as useless or unwanted. The term as
used in this context is all inclusive, and it The problem with hazardous wastes is that there is
encompasses the heterogeneous mass of throwaways still no internationally accepted definition of a
from the urban community as well as the more hazardous waste. However, technical criteria such as
homogeneous accumulations of agricultural, toxicity, flammability, corrosivity, ignitability and
industrial and mineral wastes [8]. reactivity have been proposed and used to some
In discussing solid waste, generally and tradition- extent to identify and designate the waste as
ally certain categories of wastes are well recognized hazardous.
as they are very common. For example, solid wastes Though the hazardous wastes account for only a
include domestic, commercial, industrial, (due to small proportion of all wastes generated by the
construction and demolition) agricultural, institution- industries, their impact can be disastrous as they not
al and miscellaneous. Many times domestic and only affect the physical environment but also the
commercial wastes cannot be differentiated and are biotic components.
considered together as urban wastes. Included in this The United States alone generates about 60
category are the garbage materials which result from million tones of hazardous waste every year, and the
food preparation both in the homes and restaurants, European Economic Community about half of that
and also the rubbish which is produced in residences quantity. Roughly 10 to 20 per cent of the total waste
and commercial establishments. Generally, the produced can be considered as potentially hazardous.
garbage consists of rapidly decomposable materials In general, there are industries like metallurgical,
while the rubbish is either slowly decomposable or iron and steel, fertilizers, thermal power production,
non-degradable. etc. generating large quantities of solid and liquid
A second major category of waste is industrial, wastes containing low concentration that is at the
the refuse produced by industrial processes. trace level of hazardous constituents. On the other
Generally the character of the refuse produced in any hand, there is another group of industries such as
manufacturing or processing operation will depend chlor-alkali, pesticides, dyestuffs, electroplating,
very much on the type, amount, or the character of photographic chemicals, fine chemicals, etc. which
wastes produced by the industry. Obviously, the generate comparatively small quantity of wastes, but
wastes produced by steel manufacturers will differ they are highly toxic and hazardous.
considerably from those produced in the chemical Approximately one million tonne of solid waste is
industry. Usually the wastes produced by any food generated annually by the 131 industrial units
processing operation, the paper and plastics industries surveyed. Nearly 22% of wastes from these industries
are almost similar to the paper and plastic packaging are hazardous. It has been estimated that about 94%
materials found in domestic rubbish. On the other of these wastes are generated by process oriented
hand, the metal processing industry will obviously (generating during the processing of raw materials to
generate metallic wastes, but in addition will also get the finished products) industries and 6% of it is
produce large quantities of slags, processing pollution control oriented (generated from the
chemicals, and other residues, many of which are treatment of gaseous and liquid effluents) industries.
used in air pollution control and water pollution Maximum amount of hazardous waste is
control activities. The wastes produced by chemical generates by chlor-alkali, dyes and pigment, organic
industries or other more specialized industries will in chemicals, pesticide and plating industrial sectors.
general depend upon the specific nature of the end The inorganic chemical sector on the other hand,
product of the manufacturing process. generated low volume-high toxic wastes. The
synthetic drug manufacturing units in drugs and
5.2 Chemical Classification
pharma sector generate maximum quantity of
It is the key to selection of proper process design hazardous wastes.
parameters, selection of materials of construction, Thus, hazardous waste may be further classified
choice of concentration equipment, design of into waste generating gaseous contaminants, waste
incinerator hardware, the possibility of bye-product containing alkali and alkaline earth metals and waste
recovery, and the requirement of fuel gas and containing heavy metals.
discharge water treatment systems. Based on this
products.
Figure 4. Simplified diagram showing the interrelationships of the
9. SOLID WASTE MANAGEMENT functional elements in a solid waste management
system
Solid waste management is a separate discipline
dealing with the control of generation, storage,
collection, transfer and transport, processing, and 9.2 Functional Elements
disposal of solid wastes in a manner that is in The problems associated with the management of
accordance with the best principles of public health, solid wastes in today's society are complex because
economics, engineering, conservation, aesthetics, and of the magnitude and diverse nature of the wastes
other environmental considerations, and that also is coupled with the development of sprawling urban
responsive to public attitudes. In its scope, solid areas, the funding limitations for public services in
waste management includes all administrative, many large cities, the impact of technology, and the
financial, legal, planning, and engineering functions emerging limitations in both energy and raw
involved in the whole spectrum of solutions to materials. As a consequence, if solid waste
problems of solid wastes thrust upon the community management is to be accomplished in an efficiently
by its inhabitants. The solutions may involve and orderly manner, the fundamental aspects and
complex interdisciplinary relationships among such relationships involved must be identified and
fields as political science, city and regional planning, understood clearly.
geography, economics, public health, sociology, The activities involved in the management of
demography, communications, and conservation, as solid wastes from the point of generation to final
well as engineering and materials science[8]. disposal have been divided into six functional
The field of solid waste management is to serve as elements namely, waste generation, storage,
a basis for understanding the interrelationships of the collection, transfer and transport, processing and
engineering fundamentals and the management recovery and disposal. In general, each functional
aspects. These include: element involves a physical activity. By considering
• brief history of the evolution and development of each functional element separately, it is possible, first
this discipline, to identify the fundamental aspects and relationships
• description of the functional elements of solid involved in each element and second to develop,
waste management system, where possible, quantifiable relationships for the
• solid waste management planning and purposes of making engineering comparisons,
• brief discussion on various aspects of solid waste analyses, and evaluation (Fig. 4). Separation of
management system. functional elements is necessary as it allows the
development of a frame work within which to
9.1 Evolution of Solid Waste Management evaluate the impact of proposed changes and future
The beginning of solid waste management can be technological advancements.
traced to antiquity that is the practice of recycling
9.3 Solid Waste Management Planning
human wastes. One of the early attempts to manage
solid wastes in the United States took place at the In solid waste management planning workable
turn of the century when New York City built a alternative programs are planned and developed to
wooden-crib bulkhead around Rikers Island in the solve solid waste problems. In most situations the
East River and filled in the area behind the marshes alternative programs and plans must be presented to
with ashes, rubbish, and street sweeping. The wastes the public and to decision makers for consideration,
were transferred from wagons to scow (barges) in selection, and adoption. At present the
New York City, towed to the island, unloaded by interrelationships between technical, economical,
clamshell dredges onto a conveyor or into rail cars, environmental, social and political factors involved in
and dumped. Clearly some sort of management plan these problems are not well understood.
was followed to accomplish this large operation. Here
again, it is evident that solid waste management
planning is not new.
Source of waste
Liquid Waste Storage
Underground
Contaminant
Physical mixture
Alternatively the description may be limited to waste and to notify the appropriate authority of this
[33]
synthetic organic materials, natural organic materials, , this includes classification by phase, content,
and inorganic materials and this characteristic proportion of pollutants and such other information
corresponds to classification by origin, as in (10.1) as will adequately define the hazards involved in the
above. chosen method of disposal.
Finally, waste is usually wastes because it consists
of unusable and often unpleasant mixture of Table 3. ‘Toxic’ wastes described to the key committee
chemicals. Wastes ‘chemical’ slurry Highly acid organic residues
10.3.4 Quantity and Concentration of Pollutant Tarry liquids Sludge from tar distillation
Waste paint Phenol-formaldehyde sludge
Data are required on flow rates of waste and Solid tarry matter Nicotine waste
concentration of pollutants, together with their Oil-impregnated rubbish Kier liquor
variation with time both throughout the day and over Arsenic waste Spent sheep dip
the year. This information is necessary for the design Wastes containing cyanide Sulphides
of treatment plant and setting up of storage facilities, Beryllium wastes Mercaptans
Waste oil Acid tars
making arrangements for disposal and also for
Residues from pesticide Alkaloid wastes
budgeting. These data are also valuable in order to formulation
evaluate the possibility of recycling, either by the Photographic waste Silver thiosulphate
producer or by any outside organization. The Carbides Fluorides
information by itself may not very helpful, but it Sludges containing copper, zinc Plating sludges
definitely complements the other aspects of Cadmium, nickel, etc. Pickling sludges
classification of content of waste. It is, however, compounds
possible to estimate the capital cost of a number of Aromatic hydrocarbons Spent acids
processes, including effluent treatment plant, on the Noxious organic solvents Sludge from leaded petrol
basis of capacity only. White spirit Waste alcohols
Lacquer Beta-naphthylamine sulphate
10.3.5 Toxicity and Hazard Lubricants Diaminodiphenylmethane
Chrome acid Propyl isocyanate
Indiscriminate dumping of toxic waste led to the Complex cyanides Sodium acetylide
formulation and adoption of Deposit of Poisonous Water-kerosene mixtures Chlorphenols
Waste Act 1972 [21] and this aspect has been Trichloroethylene Chlorcresols
extensively discussed [22,27,33,40]. The Key Report [27] Oily slops from petroleum
which preceded the Act listed a wide range of industry
chemicals and waste liquids reported to the
committee as toxic (Table 3). It is of limited value as Classification of a waste by toxicity and /or
complex and vaguely defined wastes, such as kier hazard is important for safety and also to comply
liquor and alkaloid wastes are included alongside with legislation [34-40]. In practice, it is better to use
specific chemicals such as chrome acid and propyl the characterization ‘hazardous’ and ‘non’ hazardous’
isocyanate. Perhaps an easier approach will be the list having regard to both toxicity and the environmental
of exempted materials (Table 4) [34, 41] provided. implications of the waste on disposal.
It is not clear as to what proportion of industrial Therefore the Control of Pollution Act
waste can be considered deleterious or toxic; the distinguishes waste as poisonous, noxious or
World Health Organization has estimated 15 % polluting and whose presence on land is likely to give
which, equivalent to about 20 kg per head per year rise to an environmental hazard. It also encompasses
[42]
. The actual figure in the UK was between 2 and 5 highly flammable or explosive materials which may
tonnes per year [43], but even there is some confusion have little toxicological significance.
with regard to terminology. Thus, ‘toxic’ has been 10.4 Treatment
considered synonymous with ‘poisonous’ without
specifying toxic concentration. This is the most common system of classification of
Hazards are more difficult to define. The Key waste. A list of treatment methods is given in Table
Report[27] simply classified wastes as flammable, acid 1.5 together with some examples. The list includes
or caustic, and indisputably toxic. The Provisional only those operations known to be used in effluent
Code of Practice[22] suggests the adoption of the Blue treatment, and has been divided under three main
Book classification [44]. Which is simplified into the categories-chemicals, physical and biological.
following broad groups; Explosive, Flammable, Practically all the listed methods are accepted
Oxidising, Infections, Corrosive and Radioactive chemical engineering unit operations or unit
processes. Treatment of a waste for recycling, or
Information on hazards and precautions to be taken in prior to disposal, may be subjected to a sequence of
handling hazardous materials is given in the Yellow operations.
Book[45]. The Deposit of Poisonous Waste Act 1972
[21]
requires the producer to know the ‘nature’ of his
Table 5. Treatment methods for liquid effluent To illustrate the application of this scheme, a
range of example is presented in Table 6, based on
Chemical treatment methods Example
extracts from the records of a disposal contractor.
Absorption Solvent recovers
Cementation Gold recovery
Chlorination Cyanide oxidation Table 6. Examples of characterization of liquid waste
Coagulation-see Flocculation
Origin Inorganic, metal treatment
Demulsification Soluble oil recovery Destination Disposal
Electrolytic processes Metal recovery Phase Aqueous
Flocculation Sewage treatment Physical nature Dissolved gases and solid pH2
Total solids 11.57%
Hydrolysis Cellulose waste Chemical nature Acidity as HCl 5.81%
Incineration Waste oil Composition Iron 1.72%
Ion exchange Metal recovery Zinc 0.112%
Leaching Metal-bearing sludges Lead 0.024%
Cadmium Present
Neutralisation Waste oil Chromium Present
Oxidation Phenol removal Nickel Present
Ozonisation Cyanide oxidation Quantity 6.8 m3 (1500 gal)
Precipitation Metals Toxicity and hazards Poisonous, Corrosive
Reduction Hexavalent chromium Method of treatment None
Value None, value of potentially
Thermal decomposition Recycling hydrochloric acid Recoverable materials may be Calculated. [18]
Physical treatment methods Origin Natural organic, cess
Absorption Removal of volatile organics Destination Disposal
Cooling Water reuse Content : Phase Aqueous
Physical nature Solution of solids, suspended solid, pH 8.65
Crystallisation Recovery of inorganic salts Total Solids 0.23%
Desoption-see Absorption Suspended matter 0.07%
Dewatering-see Filtration Ash 0.678%
Dialysis Desalination lashpoint 110oC
Distillation Solvent recovery Electrical conductivity 4085µm hos/cm3
Drying Pig manure Chemical nature Ether extract 0.31% Composition
Electrodialysis Desalination Quantity 6.8 m3 (1500 gal)
Evaporation Sulphuric acid recovery Toxicity and hazards Bacterial infection
Method of treatment None
Filtration Sewage sludge Value None
Flotation Dairy wastes Origin Inorganic, metal treatment
Foam fractionation Metal separation Destination Disposal
Fractionation-see Distillation Content : Phase Aqueous
Physical nature Dissolved solids, miscible liquids, pH 0.7
Freezing Desalination
Electrical conductivity 178 000 µmhos/ cm3
Heating Demulsification
Total solid 19.1%
Phase separation Oily wastes Chemical nature Acidity as H SO 14.5%
Reverse osmosis Desalination 2 4
Composition Chromium 6.2%
Screening Sewage
Copper 0.46%
Sedimentation Suspended solids removal Zinc 0.26%
Solvent extraction Metal recovery Iron 0.51%
Stripping Ammonia removal Quantity 4 m3 (800 gal)
Ultrafiltration-see Dialysis, Toxicity and hazards Oxidising, Poisonous, Corrosive
Method of treatment None
Reverse osmosis
Value None, value of potentially recoverable materials
Biological treatment methods may be calculated. [18]
Activated sludge Sewage Origin Synthetic organic, organic chemical
Anaerobic digestion Food wastes Destination Disposal
Content : Phase Mixed aqueous-nonaqueous
Chemical production Ethanol
Physical nature Suspended solids, immiscible, liquid, pH 6.0
Disinfection Sewage plant effluent Total solids 37.6%
High rate filtration Phenol removal Ash 0.62%
Oxidation-see Activated sludge, - Flashpoint 110oC
High rate filtration, - Chemical nature Phenol 0.48%
Trickling filter - Quantity 5.6 m3 (1250 gal)
Toxicity and hazards -
Reduction-see Anaerobic digestion -
Method of treatment Demulsification and oil separation
Single-cell protein production Organic waste Value Small heat content oil from burning
Trickling filter Sewage
Table 7. Examples of materials recovered from solid and liquid 11. MATERIALS RECOVERY:
waste AN INTRODUCTION
Chemical Example of source
Acetic acid Paper Material recovery has only recently been proposed,
Acetone Petrochemicals including special examples where ‘one man’s waste’
Ammonia Coke ovens can be turned into ‘another man’s profit’ by virtue of
Ammonium sulphate Coke ovens circumstances, special knowledge or economy of
Anthracene Coal tar scale. The diversity of recyclable materials from solid
Anthranilic acid Dyestuffs and liquid waste is shown in Table 7.
Aromatic organics Coke ovens
Aromatics Naphtha pyrolysis quench 11.1 Hydrometallurgical Processing
Benzene Styrene manufacture All methods of metal recovery are based on
Bromine Potash hydrometallurgy [50-66]. There is a rapidly growing
Calcium sulphate Phosphates interest in hydrometallurgical extraction of metal
Carboxylic acids Petrochemicals which generally involves three stages - pretreatment,
Casein Milk recovery and refining of metals from aqueous
Chromic acid Electroplating
solution. The technology, principles and practice are
Copper salts Secondary copper
equally applicable to all waste metals and alloys. A
Copper Sulphate Secondary copper number of problems related to metal scrap have been
Creosote Coal tar recently investigated and reported. Some of which
Cresol Coal tar whose separation and recovery are reported include
Elthanol Cellulose nickel/cobalt, cadmium/zinc alloy and bearing
Ethylbenzene Styrene manufacture metal[73,67,68]. Other examples where leaching,
Ethylene dichloride Oxychlorination waste-water purification and reduction processes adopted are:
Fluorides Phosphate • Leaching, preferably selected to reduce
Gold cyanide Electroplating subsequent purification. Examples include acid
Hydrochloric acid Pickle liquor leaching, ammoniacal leaching (gold, silver) and
Hydrofluoric acid Aluminium caustic leaching (aluminium, zinc and tin).
Hydroulic oil Engineering • Purification, remove impurities. Examples include
Hydrogen Refineries most chemical engineering operations, such as ion
Hydrogen peroxide Spent photographic solution exchange, solvent extraction and precipitation.
Iodine Saltpetre • Reduction, to produce an acceptable metallic
Iron oxides Titanium product. This final step is unnecessary if metal
Iron sulphates Pickle liquor salts are being produced. Selective reduction is
Lubricating oil Vehicle maintenance also possible to overcome impurities. Examples
Magnesium chloride Sea water include electrolysis and hydrogen reduction.
Methanol General purpose solvent
11.2 Gold Recovery
Methylaniline Dyestuffs
Naphthalene Coke ovens Because of relatively high value and ease of recovery
Nickel salts Electroplating of metals, there have been many proposals for the
Paint Automotive reclamation of metals like gold, silver and other
Phenols Petroleum refineries precious metals from specific waste solutions like
Potassium hydroxide Dyestuffs spent electroplating solution, spent photographic
Protein Fermentation solution, spent mirror solution and drag-out. Gold is a
Quench oil Metal treatment precious metal. Liquid of solid waste containing even
Sodium chloride Desalination one ppm of gold is of considerable interest as an
Sodium cyanide Gold containing broken porcelain economic source. In recent years, many industries are
Sodium hydroxide Dyestuffs making use of gold as metal and its salts.
Sulphuric acid Silverbearing materials Consequently, the scrap and the industrial effluent
Sulphur Desulphurisation processes contain substantial concentrations of gold the
Sulphuric acid Pickling liquor recovery of which may be paramount interest to the
Sulphur oxides Ore smelting entrepreneurs and technocrats. The materials which
Tar Coke ovens contain substantial amount of gold include electronic
Toluene Benzole from coke ovens scraps, electric scrap, gold containing broken
Trichlorobenzene Pigments porcelain spent electroplating solutions, spent gold
Trichloroethylene Degreasing mirror solutions, etc. The precipitation and metallic
White spirit General purpose solvent replacement processes for the recovery of gold from
Xylene Benzole from coke ovens gold containing broken porcelain and drag-out/ spent
Yeast Brewing electroplating solutions is represented in Figs. 8 and
Zinc slats Rayon 9[69,70].
There are, however, probably a few such Attempts have been made to recover some of the
reclaimable wastes remain unexploited. There are valuable constituents such as silver by
about 70 such instances where byproduct recovery hydrometallurgical techniques. A flowsheet diagram
including many metals and metal compounds from is shown in Fig. 10 and 11 [72,78] of acidic recovery of
aqueous effluents were reported several years ago [71]. metal silver from spent photographic solution.
Warren Spring Laboratory has applied a range of
11.3 Silver Recovery
adaptations of the basic principles in a variety of
Considerable quantities of metals are lost annually in situations [72-76]. It is, however, exceptional for such
aqueous effluent. India is ranked as the third largest recovery processes to be justified economically. A
country in the world for the use of silver. There is survey conducted in Egypt showed that the solutions
little information on the geographic distribution and produced are nearly 2160 m3 containing about 16.2
environmental effects of silver discharges in India. tons of pure metal silver. The price of this pure metal
However, recent worldwide studies show that the silver is nearly $3 million. Hence it is desirable to
toxicity of silver depends on its chemical form, recover the silver form spent solutions[77]. Recent
concentration, salinity, recox-potential and pH of the proposal for the recovery of silver has been made and
receiving water. Recovery of silver is of paramount the flow diagram for the recovery of silver from spent
importance, as it happens to be a highly priced metal. photographic solution is given in Fig. 12 and Fig. 13.
Gold containing
Broken porcelain
Water Sodium
Dissolution of gold layer
Cyanide O2H2
Filteration of Water
gold containing solution st wash step1
Water
Water Washing nd wash step 2 Water
Melting
Gold free
Broken
porcelain
Gold 99.5%
Figure 8. Flow sheet of gold recovery from gold containing broken porcelain.
Dissolution
Filtration residue for
Al Precipitation recovery of
impurities
Water Ag2 SO4 precipitation
Decant
Filtration Filteration for
recovery of
impurities
Sludge 2H
Ag2 SO4 dissolution
Melting
Dissolve in aquaregia
Silver %99.5
Filteration
Na2So4 Reduction Figure 10. Flow sheet of silver recovery from silver bearing
materials
Acidic or alkaline
HNO3 Boiling reagent
Adjust pH to 3.6
Ag sludge precipitation
Washing Water
Filtration of the sludge and
washing
Drying
Precipitation with
Dissolution in boiling HNO3
NaOH
Thermal decomposition =
Other
% 99.5 Gold 9800C
Silver
Figure 9. Precipitation process for gold recovery from drag-out /
spent electroplating solutions Figure 11. Flow sheet diagram of acidic recovery of metal silver
from spent photographic solutions.
12. CONCLUSIONS
last century, when the practice of public health grew
The management of waste is one of the earliest of up to ameliorate, in particular, the housing and living
man’s branches of knowledge. In some ways it can conditions of the working poor in British cities. The
also be considered as one of the latest. The reason for public health movement later on spread rapidly to
this seeming paradox is the success which rewarded Europe and to the United States, where the need for
the efforts of public health specialists and sanitary improvement was not as strong as in Europe, but
engineers in overcoming the abysmally unhygienic where danger signs were visible in the increasingly
conditions into which man has allowed his crowded conditions of the eastern cities. It was only
habitations to degenerate at different times in his during the last three decades that Indian community
history. This could be particularly seen during the and planners started taking a serious view of the
later part of the waste management.
Stock solution
Stock solution
Grinding of solids
Filtration of Ag sludge
Silver Silver
Figure 12. Flow sheet diagram of recovery of metallic silver from Figure 13. Flow sheet diagram of recovery of metallic silver form
spent photographic solutions with H2O2 spent photographic solutions by thermal process
The improvements which were brought about had Our previous complacency resulted in being
such strikingly good impact, noticeable mainly in the caught virtually unawares by these new problems.
reduction in disease rates and in the cleanliness of the During the last two decades we have witnessed an
cities, that codes of good practice were established unprecedented rapid growth in first concern and later
handbooks were written, school of public health were action, which transformed the entire field of waste
opened and the general population relaxed under the management. It was the transformation which
belief that the problems associated with our waste necessitated undertaking this study.
had been solved forever.
This situation lasted for about two generations REFERENCES
long enough for most research groups to die out or be 1. Agarwal, S.K. (1996). Industrial Environment
disbanded. An approach tied to tradition and Assessment and Strategy (Ed.) APH Publishing
unresponsive to change was followed. But change Corporation, New Delhi, 415.
came in the form of increased intensity of the very 2. Kumar, (1986). Pollution Control Handbook, Utility
industrial revolution which had enabled the problems Publications, Secunderabad, 57.
of the last century to be resolved with such relative 3. Wiley, N.Y., (1960). The Disposal of Municipal Refuse
(Ed.) H.D.B. Parsons.
ease.
4. Lency, L.E. (1971). Plating Operations in Industrial
These new problems brought about fundamental Control Handbook, McGraw-Hill Inc., N.Y., 12, 16.
and for reaching changes in the nature of domestic 5. Hasen, P.E. and Jorgensen, S.E. (1991). Introduction to
refuse, which in the days of coal fires had consisted Environmental Management, (Eds.) Elsevier, N.Y.,5.
predominantly of only ashes and food waste and 6. Syed, A.A. (2001). Analytical Techniques in
which became increasingly composed of large Monitoring the Environment, S.O. Printers, India, 216.
quantities of paper, plastics and glass packaging 7. Hagerty., D.J. Pavoni J.L. and Heerjr, J.E. (1973) Solid
materials. These problems also included changes in Waste Management, (Eds.) Van Nostrand Reinhold
industrial wastes, which began to incorporate Co., N.Y.,.
previously unknown variety of substances with, in 8. Tchobanoglous, G. Theisen, H. and Eliassen, R. (1977).
Solid Wastes: Engineering Principles and Management
many cases still unknown properties and hazards. The
issues, (Eds.) McGraw Hill, Inc., N.Y.
substances which were disposed of with relative 9. Seconds International Conference on Waste Water and
safety in minute quantities by the industrialists of the Wastes, Stockholm. (1975). Institute of Water Pollution
last century began to be discharged in vast tonnages Control.
with immediate catastrophic effects in some cases, 10. Water Treatment Handbook, Degremont, (1973).
and disturbing implications for the longer term in 11. Lund, H.F. (1971). Industrial Pollution and Control
others. Handbook, McGraw-Hill.
12. Southgate, B.A. (1948). Treatment and Disposal of 44. Carriage of Dangerous Goods in Ships (Blue Book),
Industrial Waste Water, HMSO. HMSO, (1971).
13. Linder, G. and Nyberg, K. (1973). Environmental 45. Dangerous Chemical Substances and Proposals for their
Engineering, Reidel. Labelling (Yellow Book), HMSO, (1971).
14. Ciaccio L.L. (1971). (Ed.) Water and Water Pollution 46. Bridgwater A.V. (1968). Chemical Enginerring 217.
Handbook, Vol.1, Dekker. 47. European Chemical News (UK and Europe) (weekly).
15. Tomlinson, T.G. (1973). Water Treatment Handbook, 48. Chemical Marketing, Reporter (USA) (weekly).
Degremont. 49. Metal Bulletin (UK) (biweekly).
16. Oldham, G.F. (1972). The Effect of Effluent 50. Bekcer, E. Knothe, M. and Lobel, J. (1983).
Restrictions upon Industry, Symposium, Southampton, Hyderometallurgy, 119. 265.
Institution of Chemical Engineers. 51. Niederkorn, J.S. and Huszar, S. (1984). Gold Bull., 17,
17. Beychok, M.R. (1967). Aqueous Waste from Petroleum 128.
and Petrochemical Plants, Wiley. 52. Hill, J.W. and Lear, T.A (1988). J. Chem. Edu., 65 802.
18. Bridgwalen, A.V. and Gaskartn, J.W. (1974). 53. Harris, W.I. Stanlbush, J.R. Pike W.C. and Stevens,
Conservation of Materials UKAEA Harwel. R.R. (1992). React. Polm., 17,21.
19. Institute of Industrial Solid Wastes Management Private 54. Kristofova D. and Karnik, T. (1996). Miner. Slovaca.,
Communication (1973). 28, 429.
20. Backhurst, J.R. and Harken, J.H. (1974). Environ, 55. Lee, C.K. Rhee, K.I. and Sohn, H.J. (1997). Chawon
Pollu. Manag. 4. 221 Risaikring, 6, 36.
21. Deposit of Poisonous Waste Act 1972: Control of 56. Zhao, C. Wu, Z. and Chen, J.C. (1999). Sep. Sci.
Pollution Act, (1974). Technol., 34, 2061.
22. A provisional Code of practice for Disposal of Wastes 57. Leao V.A. and Ciminelli, V.S.T. Solv. (2000). Extr. Ion
Institution of Chemical Engineers (1971). Exch., 18, 567.
23. Handbook of Chemistry and Physics (1976). Chemical 58. Yavuz, O.and Ziyadanogullari, R. (2000). Sep. Sci.
Rubber Co. Technol., 35, 133.
24. Perry, J.H. (1970). Chemical Engineers Handbook, 59. Krupkowa, D. Chelminski, B. Kuzma, Z. Kuzma M.,
McGrawHill. Wajcik, M. Kukula, M. Kowalski, K. Zdancewicz, C.B.
25. Refuse Disposal, HMSO (1971). and Adamuszek, W. (1987). Polish patent, PL 142656
26. Brendish, K.R. (1973). Industrial Pollution Control, (IPC 23G-001/02), 4 pp.
Business Book. 60. Hanna, M.M. (1995). Canadian patent, CA 2154608, 23
27. Report of the Technical Committee on the Disposal of pp.
Solid toxic Wastes, HMSO, (1970). 61. Sheng, P.P. and Etsell, T.H. (1998) Waste Process,
28. Noonan, J.L. (1973). Environmental Engineering, Recycl. Miner. Metall. Ind. III, Proc. Int. Symp., 3rd,
Reidel. 559.
29. Economic Aspects of Treatment and Disposal of 62. Hisshain R.J. and Wallter, C.G. (1984). Min. Mag.,
Certain Industrial Effluents (1967). United Nations. 237.
30. Mortensen, B.F. (1973). Environmental Engineering, 63. Khalemskii, A.M. Payusov, S.A. Kadnikov, S.A.
Reidel. Talanov A.G. and Tumashov, Y.S. (1998). Russian
31. Painter, H.A. (1971). Water and Water Pollution patent, RU 2109826 CI, 2 pp.
Handbook, Vol.1, Dekker. 64. Leibovitz, J. (1998). World Intellectual Property
32. Marshall, V.C. (1974). Water Borne Wastes, Institution Organisation Patent, WO 9805569 A1, 46 pp.
of Chemical Engineers. 65. Novoselov R.I. and Peshchevitskll, B.I. (1998). Union
33. Department of the Environment (1972). Circular 70/72, of Soviet Socialist Republics, SU 683247 A1, 407 pp.
Deposit of Poisonous Waste Act 1972, HMSO. 66. Mcinnes, C.M. Sparrow G.J. and Woodcock, J.T.
34. Mumford, C.J. (1973). Industrial Pollution Control, (1994). Hydrometallurgy, 35141.
Bussiness Books. 67. Pearson D. (1971). Reclamation Industries, 31.
35. Schwer, F.W. (1974). Chemical Engineer, 91. 68. Fletcher, A.W. (1975). Industrial Recov., 22, 10.
36. B. Laverick in Industrial Pollution Control Year Book, 69. Parthasarathy, P. (1997). Trans. Met. Finish. Assoc, of
Industrial Newspapers Ltd., (1974). India 6, 131.
37. Myers, S.D. and ISAAC, P.C.G. (1972). The Effect of 70. Becker, E. Knothe M. and Lobel, J. (1983)
Effluent Restrictions upon Industry, Symposium, Hydrometallurgy, 11, 265.
Southampton, Institution of Chemical Engineers. 71. Leworie W. (1969). Chemistry and Industry, 565.
38. Tearle, K. (1973). (Ed.) Industrial Pollution Control 72. Warren Spring Laboratory, internal reports and
Business Books,. publicity information, (1970-77).
39. Newsom, G. and Sherratt, J.G. (1972). Water Pollution, 73. Fletcher A.W. (1973). Chemistry and Industry.
Sherratt & Sons. 74. Fletcher A.W. (1975). Institution of Chemical
40. Deposit of Poisonous Waste, Symposium (1973). Engineers Symposium Series No. 41, T1.
Bristol Polytechnic. 75. Flett D.S. and Pearson D. (1975). Chemistry and
41. Higginson, A.E. (1973). Chemical Engineer, 305. Industry, 639.
42. Department of the Environment Industrial Waste 76. Jackson, D.V. (1972). Met. Finish. J., 18, 235.
Survey unit, (1974). Hazardous Wastes in Great Britain, 77. Rabah, K.A. Barawy E.L. and Aly, F.H. (1989). Int. J.
HMSO. Miner. Process. 26, 17.
43. Royal Commission on Environmental Pollution, 4th 78. Kunda, W. (1981). Hydrometallurgy, Vol. 7, 77.
Report (1974). Pollution Control, Progress and
Problems, HMSO.