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Basics of Mechanical Engineering

Dr Muhammad Sajid

Chapter 3

PROPERTIES OF PURE SUBSTANCES

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Objectives
• Introduce the concept of a pure substance.
• Illustrate the P-v, T-v, and P-T property diagrams and
P-v-T surfaces of pure substances.
• Demonstrate the procedures for determining
thermodynamic properties of pure substances from
tables of property data.

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Pure substance

A pure substance has a fixed chemical
composition throughout.

Water, nitrogen, helium, and carbon dioxide, etc

A homogeneous mixture of various chemical elements or
compounds is also a pure substance.

Air (a mixture of several gases) is a pure substance.

But a mixture of oil and water is not a pure substance.

A mixture of two or more phases of a pure substance is
still a pure substance.

A mixture of ice and liquid water is a pure substance.

A mixture of liquid air and gaseous air is not a pure
substance.

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Phase change processes

Saturated liquid: At 100°C water is still a liquid, but
any heat addition will cause evaporation A liquid that
is about to vaporize is called a saturated liquid.

Saturated vapor: Any heat loss from water vapor at
100°C will cause condensation. A vapor that is about
to condense is called a saturated vapor.

Saturated liquid–vapor mixture: The saturated liquid
and vapor phases coexist in equilibrium.

Superheated vapor: When vapor is so hot that a loss
of heat lowers temperature without condensation. A
vapor that is not about to condense is called a
superheated vapor.
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T-v diagram for the

heating process of
water at constant
pressure.

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Property diagrams
• The variations of properties during phase-change
processes are best studied and understood with the
help of property diagrams.

• Next, we develop and discuss the T-v, P-v, and P-T

diagrams for pure substances.

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T-v diagram of
constant-
pressure
phase-change
processes of a
pure
substance at
various
pressures
(numerical values
are for water).

The point at which

the saturated liquid
and saturated vapor
states are identical.

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T-v diagram of a
pure substance.

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P-v diagram
of a pure
substance.

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Extending phase diagram to solids

• The two equilibrium diagrams developed can be
extended to include the solid phase as well as the
solid–liquid and the solid–vapor saturation regions.
• The basic principles discussed in conjunction with
the liquid–vapor phase-change process apply equally
to the solid–liquid and solid–vapor phase-change
processes.
• Most substances contract during a solidification (i.e.,
freezing) process. Others, like water, expand as they
freeze.

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P-v diagram of a
substance that
contracts on
freezing.

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P-v diagram
of a
substance
that expands
on freezing
(such as
water).

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P-T diagram
of pure
substances.

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P-v-T surface of a
substance that
contracts on
freezing.

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P-v-T surface of a
substance that
expands on freezing
(like water).

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Property tables
• The relationships amongst thermodynamic
properties are too complex to be expressed by
simple equations.
• Therefore, properties are presented in the form of
tables.
• In the following discussion, the steam tables are used
to demonstrate the use of thermodynamic property
tables.

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Enthalpy
• In the steam tables you will notice two new
properties: enthalpy h and entropy s.
• Entropy is a property associated with the second law
and we will not use it until it is properly defined.

In the analysis of processes, in

refrigeration and power, we
encounter a combination of u
& Pv.

For convenience, this
combination is defined as a new
property,
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and givenEngineering - Chp III
of Mechanical 18

the symbol h.

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A partial list
of Table A–4.

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A partial listing
of Table A–6.

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Percentage of error
involved in assuming
steam to be an ideal
gas, and the region
where steam can be
treated as an ideal gas
with less than 1
percent error.

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Comparison of
Z factors for
various gases.

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Percentage of
error involved
in various
equations of
state for
nitrogen.

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Ideal-gas
constant-pressure
specific heats for
some gases

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