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Aqueous Glycerine
H. R. TILL JR., J. B. SEGUR, and C. S. MINER JR., The Miner Laboratories, ~ Chicago, Illinois
CaSO4
waters to crude glycerine. A knowledge of their Temp.
% wt.
glyc. i n I n~ Sp. gr, CaSO~ g . / 1 0 0 ml.
solubilities in aqueous glycerine would therefore be °C. solvent I 25/25 % b y wt. at 25"0.
helpful in the design of processing equipment. Solu- 20 0 I ........ 0.30(4) ......
bilities have been determined at 20 °, 40 °, 60 °, 80 °, 20 40,1 ~ 1.3850 1.1039 0.22 0.24
20 69.7 / 1.4280 1.1824 0.10 0.12
and 100°C. with glycerine concentrations of approxi- 20 94.6 t 1.4651 1.2486 0.08 040
mately 40%, 70%, and 95% by weight in water. 40 0 ........ 0.22(4) ......
40 39.8 1.3845 1.1014 0.16 0.18
40 69.6 1.4275 1.1819 0.08 0.09
Materials 40 94.3 1.4646 1.2473 0.05 0.06
for each solution composition. The average devia- required to make these physical measurements at
tion in the groups of four was 0.01%. Single analy- 25°C.
ses were made on each of the duplicate solutions of Acknowledgment
calcium sulfate. The average difference between these The work was sponsored by the Glycerine Division,
determinations was 0.009%. The solubility data for Association of American Soap and Glycerine Pro-
sodium and calcium sulfates are given in Tables I ducers, New York, N. Y.
and II.
Specific gravity a t 25°C. and refractive index at REFERENCES
25°C. were also determined for each saturated solu- 1. Bosart, L. W, and Snoddy, A. O., Ind. Eng. Chem., 19, 506-
510 (1927).
tion. It was possible to make these determinations 2. Seidell, A., "Solubilities of Inorganic anti 5fetal Organic Com-
at 25°C. on solutions saturated at higher tempera- pounds," Supplement to the Third Edition, p. 482, New York, O. van
Nostrand Co. Inc. (1952).
tures because of the negative coefficient of solubility 3. Seidell, A., ibid., Third Edition, vol. I, p. 1301 (1940).
4. Hill, A. E., g. Am. Chem. Sot., 59, 2242 (1937).
of both salts. None of the solutions saturated at
20°C. showed signs of precipitation during the time [Received June 20, 1956]