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1/17
All India Aakash Test Series for IIT-JEE 2011 Test - 13 (Paper - II) (Answers & Hints)
−ΔH ⎛ ∂ ⎞
⇒ Ecell = + T ⎜ Ecell ⎟
nF ⎝ ∂T ⎠P
For Ecell versus T,
⎛ ∂ ⎞
Slope = ⎜ Ecell ⎟ = Temperature coefficient
⎝ ∂T ⎠P
−ΔH
Intercept =
nF
2. Answer (B)
NaOH
ONa
N
CH3–C–NO2 + N – OH ⎯→ CH3–C–NO2 + H2O CH3–C–NO2
H H O N (Red solution)
(A) (Nitrous acid) OH
(Nitrolic acid)
(P)
H H–O N=O
R–C–NO2 + N = O ⎯→ R–C–NO2 + H2O
R R
(B) (Pseudo-nitrole)
Gives blue colour with aq. NaOH
R
HNO2
R–C–NO2 ⎯⎯⎯→ No reaction
R (Due to absence of α – H in C)
(C)
3. Answer (C)
213
Cl2 = = 3 mole
71
NH3 = 8 mole and 1 mole
8NH3 + 3Cl2 ⎯→ N2 + 6NH4Cl
NH3 + 3Cl2 ⎯→ NCl3 + 3HCl
N2 evolved = 28 g
NH4Cl formed = 321 g
NCl3 formed = 120.5 g
HCl formed = 109.5 g
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Test - 13 (Paper - II) (Answers & Hints) All India Aakash Test Series for IIT-JEE 2011
4. Answer (B)
Aldol condensation and cross-aldol condensation products are formed. (α–β unsaturated carbonyl compounds)
5. Answer (D)
3R × 546 2R × 546
v rms(II) = , v mp(II) =
2M 2M
6. Answer (A)
H
Syn arrangement
(I) Me (Not favourable)
H
H Br
H
Anti arrangement
(Favourable)
Me H
(II) Major product is
H OH
7. Answer (5)
8. Answer (3)
Adiabatic slope
= γ (Poisson' s ratio)
Isothermal slope
5 7 4 28 1
x × y × z = γHe × γ O2 × γ CO2 = × × = = 3+
3 5 3 9 9
9. Answer (8)
3/17
All India Aakash Test Series for IIT-JEE 2011 Test - 13 (Paper - II) (Answers & Hints)
10. Answer (7)
Phenolphthalein end point:
NaOH + HCl ⎯→ NaCl + H2O
NaCl + HCl ⎯→ No reaction
NaHCO3 + HCl ⎯→ No reaction
Na2CO3 + HCl ⎯→ NaHCO3 + NaCl
x = 1 + 4 = 5 moles
Methyl orange end-point:
NaHCO3 + HCl ⎯→ NaCl + H2CO3
y = 3 + 4 = 7 moles
xy 7 × 5
= =7
5 5
11. Answer (4)
Anti fluorite structure ⎯→ Na2O
⎯→ Na+ at all tetrahedral voids.
⎯→ O 2– in CCP.
1st C.N. of O2– at a corner = 8 = x
(All 8 Na+ in tetrahedral voids in eight cubes sharing a corner)
2nd C.N. of O2– at a corner = 12 = y
(12 O2–, each three O2– in a cube at adjacent face centres sharing a corner)
y – x = 12 – 8 = 4
12. Answer (C)
13. Answer (B)
14. Answer (D)
Solution of Q. 12 to Q.14
O – H -----------O
H3C – C = N N = C – CH3
NiCl2 + 2DMG ⎯→ Ni
H3C – C = N N = C – CH3
O -----------H – O
(Cherry red ppt.)
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Test - 13 (Paper - II) (Answers & Hints) All India Aakash Test Series for IIT-JEE 2011
16. Answer (B)
(+) (+)
.. O–H O–H :O–H O–H O
O H⊕ (+) H –H⊕
R–C R–C–O–H R–C–O–H
.. R–C–O R–C–O 18
.. + H2O R–C–O18–R′
O–H H
O18 18
O R′
.. 18
R′–O H + R′ R′
H
17. Answer (D)
O O O
COOH Δ Dry NH3 Br2, NaOH
O N–H N–Br
COOH P2O5 0°C
O O O
(Succinic (Succinic (Succinimide) (N-bromosuccinimide
acid) anhydride) or NBS)
18. Answer A(p, q, t), B(p, s, t), C(p, q, r, t), D(r, t)
Solvent
Stopping
potential
(VS)
Solution
pressure
Vapour
hc hc
A. B. Vs = −
ΔTb λ0 eλ eλ 0
Wavelength (λ)
Temperature (T)
Rate of
7 backward
pH reaction
C. D.
Vol. of base (ml) Time (t)
(titration of weak acid
and weak base)
19. Answer A(q, r), B(p, s), C(q, r), D(p, s, t)
A. All have planar shape.
All have 2 lone pairs.
h
B. μ l = l ( l + 1)
2π
Total nodes = n –1
C. Sideways destructive overlapping between p orbitals (in one plane)
2 nodes
+ –
– +
–z2
E∝
n2
z
V∝
n
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All India Aakash Test Series for IIT-JEE 2011 Test - 13 (Paper - II) (Answers & Hints)
PART - II (MATHEMATICS)
20. Answer (B)
After simplifying k = 1, n = 2
21. Answer (C)
P2
z2
P1
z1
O
By rotation it can be easily seen z2 = iz1 …(i)
and if we interchange z1 and z2 then we have z1 = iz2 …(ii)
Now, clearly |z1 – z2| = |z1 + z2| for (i) and (ii)
z1z2 + z1z2 = 0 for (i) and (ii)
⎛z ⎞
Re ⎜ 2 ⎟ = 0
⎝ z1 ⎠
22. Answer (A)
16 x
1024[ln x ] + 6[e x ] = 2011 +
1+ x 2
16 x
So, for a solution to exist must be an integer.
1+ x2
2x
Now, −1 ≤ ≤1
1+ x2
2x
So, may take values –1, 0, 1 as integral values.
1+ x2
But in all cases R.H.S. is ODD while LHS is divisible by 2.
Hence the equation has no solution.
23. Answer (B)
As the letter boxes are identical so we will be only concerned with the number of letters.
The distribution can be as follows
Ways of distribution Number of ways
5 0 0 0 0 1 = 1
4 1 0 0 0 5
C4 = 5
5
3 2 0 0 0 C3 = 10
1 5
3 1 1 0 0 ( C3 .2C1) = 10
2
1 5
2 2 1 0 0 ( C2 ´ 3C2 ) = 15
2!
5
2 1 1 1 0 C2 = 10
1 1 1 1 1 1 = 1
So, total number of ways = 1 + 5 + 10 + 10 + 15 + 10 + 1 = 52
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Test - 13 (Paper - II) (Answers & Hints) All India Aakash Test Series for IIT-JEE 2011
24. Answer (B)
6
P= ∑ (x
i , j =1
i − x j )2
i< j
6 6
= 5 ∑
i =1
xi 2 − 2 ∑xx
i , j =1
i j
i <1
⎛ ⎞
⎜ 6 6 6
⎟
= 6 xi − ⎜
i =1 ⎜
∑ 2
∑
i =1
xi + 22
i , j =1
∑
xi x j ⎟
⎟
⎝ i< j ⎠
2
⎛ 6
6 ⎞
= 6 xi − ⎜
i =1
⎜∑ xi ⎟
⎝ i =1 ⎠
⎟
2
∑
= 6k – k2
P = 9 – (k – 3)2
So, Pmax = 9
25. Answer (B)
⎧ − x.51/ x
⎪ 1/ x x >0
⎪5 −1
⎪⎪ −2 x − x 51/ x
f (x) = ⎨ x <0
⎪ 5 −1
1/ x
⎪0 x =0
⎪
⎪⎩
f(0+) = f(0–) = 0 function is continuous at x = 0,
f′(0+) = –1, f ′ (0–) = 2, hence the function is not differentiable at x = 0
26. Answer (1)
g( x )
Consider the function h, where h( x ) =
h( x )
g
Now since g and f are differentiable so, must be differentiable in [a, b]
f
Using Rolle’s theorem for h in [a, b]
f (c )g ′(c ) − g (c )f ′(c )
h ′(c ) =
(f (c ))2
7/17
All India Aakash Test Series for IIT-JEE 2011 Test - 13 (Paper - II) (Answers & Hints)
27. Answer (9)
a sin B + b sin A
=3
sin A sin B
2kab 3 9
⇒ =3 ⇒ (ab )1/2 = ⇒ ab =
k ab 2 4
9 1
⇒ a 2 + b2 − c 2 = 2ab cos c = 2 × ×
4 2
⇒ 4(a 2 + b2 − c 2 ) = 9
1 e
e
A = ∫ (ln x − (ln x )2 )dx = 3 – e
1
⇒ k = 3
31. Answer (B)
x 4 − 4 x 3 y + (6y 2 + 1)x 2 − 4 xy 3 − 2 xy + y 2 (1 + y 2 ) = 0
⇒ ( x − y )2 + ( x − y )4 = 0
⇒ x=y
x x2 ⎛ 1⎞
Put x = y = ⇒ f (x) = f ⎜ ⎟
2 4 ⎝x⎠
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Test - 13 (Paper - II) (Answers & Hints) All India Aakash Test Series for IIT-JEE 2011
32. Answer (A)
x f (1/ t )
Given : f ( x ) = 3 x − 1 + ∫1/ x dt
t2
1
Let =u
t
1/ x
f ( x ) = 3x − 1− ∫ f (u)du
x
⎡ ⎛ 1 ⎞ ⎛ −1 ⎞ ⎤
f ′( x ) = 3 − ⎢f ⎜ ⎟ ⎜ 2 ⎟ − f ( x )⎥
⎣ ⎝ ⎠⎝ x ⎠
x ⎦
⇒ 4f ′( x ) = 12 + 5f ( x )
33. Answer (D)
f ′( x )
4∫
12 + 5f ( x ) ∫
= dx
4
⇒ ln 12 + 5f ( x ) = x + C
5
Put x = 1
⇒ f(1) = 2
4
⇒ C= ln 22 − 1
5
4 4
⇒ ln 12 + 5f ( x ) = x + ln22 − 1
5 5
34. Answer (D)
(–ae,0) (ae,0)
F1 F2
PF2 = a − ae cos θ = q
PF1 = a + ae cos θ = r
F1F2 = 2ae
If (h, k) be the coordinates of the incentre of PF1F2, then
px1 + qx 2 + rx 3
h=
p+q+r
⇒ A(x1,y1)
h = ae cos θ ... (i)
py1 + qy 2 + ry 3
k= r q
p+q +r
(h, k)
eb sin θ B C
⇒ k= ... (ii) p
e +1 (x2,y2) (x3,y3)
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All India Aakash Test Series for IIT-JEE 2011 Test - 13 (Paper - II) (Answers & Hints)
Eliminating θ from (i) & (ii), we get
x2 y2
2 2
+ 2
=1
a e ⎛ be ⎞
⎜ e + 1⎟
⎝ ⎠
⇒ Locus represents ellipse.
35. Answer (C)
b2e2
= a2e2 (1 − e12 ) e1 is eccentricity of locus.
(e + 1)2
2e
⇒ e12 =
e +1
2e
⇒ e1 =
e +1
36. Answer (B)
⎛ be ⎞ 2abe 2
Maximum area of rectangle = 2(ae). ⎜ ⎟=
⎝ e + 1⎠ e +1
37. Answer A(s, t) , B(q), C(p, q, r, s), D(q, r, s, t)
(A) nC = nCn–r
r
12C + 12C +13C8 +14C9 = 15C
k 6 9
f −1( x ) u
lim = lim
x →0 (x) 1/3 u → 0 (u − sin u )1/3
u
= lim 1/3
u →0
⎛ u 3
u5 ⎞
⎜⎜ u − u + − + ...... ⎟⎟
⎝ 3! 5! ⎠
= (6)1/3
k =6
(C) Digit in unit place of 2011! = 0
Digit in unit place of 32011 = 7
Digit in unit place of 2011! + 32011 = 7
(D) y 2 − 9 xy + 18 x 2 = 0
(1,6) y=6
⇒ y = 6x, y = 3x (2,6)
1
Area of tringle = × base × height
2 (0,0)
1
= × 1× 6 = 3
2
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Test - 13 (Paper - II) (Answers & Hints) All India Aakash Test Series for IIT-JEE 2011
38. Answer A(t), B(p, q, r, s, t), C(p), D(q, r, s, t)
Plane π : r .(iˆ + 4 jˆ + kˆ ) = 4
1− 4 + 1− 4
= 2
1 + 16 + 1
(B) px 2 + 2qxy + ry 2 + λ( x 2 + y 2 ) = 0
( p + λ )x 2 + 2qxy + (r + λ )y 2 = 0
x2 − y 2 xy
=
( p + λ ) − (r + λ ) q
x 2 − y 2 xy
=
p−r q
Thus, the two line pairs are equally inclined to each other for any value of λ.
(C) 2z2 + 6z + b = 0
z1 + z2 = −3
b
z1z2 =
2
ΔOAB is equilateral,
⇒ ( z1 + z2 )2 − 2z1z2 = z1z2
⇒ ( z1 + z2 )2 = 3z1z2
b
⇒ ( −3)2 = 3.
2
⇒ b=6
0<k<5
11/17
All India Aakash Test Series for IIT-JEE 2011 Test - 13 (Paper - II) (Answers & Hints)
4T
Pressure difference between inside and outside of the spherical bubble = ΔP = ... (1)
r
where T is the surface tension and r is the radius of the bubble.
Using Bernoullis relation between a point in capillary and inside the bubble.
1 2
ΔP = ρv , where v is the flow velocity inside ... (2)
2
The capillary and ρ is the density of air.
Volume reduction in bubble will be equal to outflow of gas through capillary.
⇒ t = 2π 2ρR R 3 ⎛ 1 − 1 ⎞
⎜ ⎟
7A T ⎝ 8 2⎠
40. Answer (A)
Let ρ be the instantaneous density
Instantaneous mass = Vρ
In short interval dt volume increase by C dt
As mass remains constant in a short interval dt, so Vρ = (V + Cdt) (ρ + dρ)
dρ C
= − dt
ρ V
Pressure ∝ density
dP C
= − dt
P V
P2
dP Ct V P
∫−
P1
=
P V or
t = loge 1
C P2
87
t= loge 1000 = 8.7 × 2.3log10 1000 = 60
10
41. Answer (A)
By application of Gauss theorem,
q
E × 4πr 2 =
ε0
⇒ q = E × 4πr 2 ε0
A ⎛ ∂V ⎞
= × 4πr 2ε0 ⎜∵ E = ∂r ⎟
r 2 ⎝ ⎠
= 4πε0 A
Charge distribution may be non-uniform for such a system.
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Test - 13 (Paper - II) (Answers & Hints) All India Aakash Test Series for IIT-JEE 2011
42. Answer (D)
P
In cylindrical waves I = where P is the power of the source and l is the length of the line source
2πrl
1 1
So, I ∝ ⇒ amplitude ∝
r r
Hence equation of wave may be
A ⎛ x⎞
y= sin ω ⎜ t − ⎟
r ⎝ v⎠
43. Answer (A)
For achromatism,
ω ω′ ω 2
+ =0 =
f f′ ω′ 1
2ω′ ω′
+ = 0 ⇒ 2f ′ = −f
f f′
1 1 1
Also, = +
F f f′
1 −1 1
= + ⇒ f ′ = 5 and f = −10
10 −2f ′ f ′
44. Answer (A)
⎡ 2 1 3⎤
⎢⎣(πR )2R − 3 πR ⎥⎦ ρg = F
⎛ 1⎞ 5
= πR 3 ⎜ 2 − ⎟ ρg ⇒ F = πR 3ρg
⎝ 3⎠ 3
45. Answer (8)
ω′
ω0 v ′ + ω′r
m
v0 v′
m
1 1 1 1 1 1
mV02 + ( mR 2 )ω02 + mgR + m(V0 − ω0 R )2 = mV ′2 + (mR 2 )ω′2 + mgR + m(V ′ + ω′R )2 + mg × 2R
2 2 2 2 2 2
For rolling v0 = ω0R & v′ = ω′ R
So v 02 = 3v ′2 + 2gR
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All India Aakash Test Series for IIT-JEE 2011 Test - 13 (Paper - II) (Answers & Hints)
ω′2 R
At topmost point acceleration of CM towards centre ag =
2
mv ′2
F.B.D. at that point 2mg − N =
R
Ring will not bounce so long as N′ ≥ 0
mv ′2
⇒ 2mg ≥ or v′ 2 ≤ 2gR
R
Or 3v′ 2 ≤ 6gR
Or v 02 – 2gR ≤ 6gR
v 02 ≤ 8gR
Or v 0 ≤ 8gR
v 0(max) = 8gR
α=8
46. Answer (1)
( m + mw )g
Pressure on the base = , where mw = mass of water
πR 2
( m + mw )g
⇒ ρg(H + h) = ... (1)
πR 2
m + mw
H +h =
πR 2ρ
As the piston is in equilibrium so,
m
π(R 2 − r 2 )ρgh = mg ⇒ h = ... (2)
π(R − r 2 )ρ
2
m + mw m
H= −
2
πR ρ π(R − r 2 )ρ
2
1 ⎧⎪ 3 × 12 × 10
−4
⎫⎪
= ⎨0.7 − ⎬
π × 42 × 10−4 × 1000 ⎩⎪ (42 − 12 ) × 10 −4 ⎭⎪
= 10 cm
⇒ x=1
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Test - 13 (Paper - II) (Answers & Hints) All India Aakash Test Series for IIT-JEE 2011
47. Answer (3)
⎛ ρl ⎞
Rate of heat supplied by current = I 2R = I 2 ⎜ 2 ⎟
⎝ πr ⎠
Where I is current
l is length of conductor
r is radius of conductor
ρ is resistivity
Rate of heat loss by radiation = k(2πrl)(θ4 – θ04)
Where k = constant
θ = temperature of conductor
θ0= temperature of surrounding
At the steady state rate of heat supplied = rate of heat loss
⎛ ρl ⎞
I 2 ⎜ 2 ⎟ = k (2πrl )(θ4 ) θ0 = 0 for vaccum
⎝ πr ⎠
θ ∝ r –3
4 θ ∝ r –3/4
β=3
48. Answer (4)
Let the current be 2 A at t = τ
π
then 2 = 2sin τ2 ⇒ τ =
2
dW = Lidi
τ
W = ∫ Lidi
0
τ
= ∫ L 2sin t 2d (2sin t 2 )
0
τ
= ∫ t8 L sin t 2 cos t 2 dt
0
τ
= 4L ∫ sin2t 2 tdt
0
θ = 2t2 ⇒ dθ = 4t dt
(3v )2
So it will rise to height, H = d +
2g
but v 2 = 2gh
So H = d + 9h
So β = 9
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All India Aakash Test Series for IIT-JEE 2011 Test - 13 (Paper - II) (Answers & Hints)
fs max 0.3 × 25 × 10
Maximum acceleration of (25 kg + 5 kg) block system for them to move together is = = 15 m/s2
5 5
So blocks 25 kg and 5 kg will always move together no matter what is the value of M.
For above system if M = 45 kg then
450 – T = 45a μ = 0.3
25
T = 30a (If blocks move together)
5
450 = 75 a T
a = 6 m/s2
45
and friction force f = 5 × 6 = 30 N
56. Answer A(t), B(s), C(q), D(p)
⎛ dB ⎞ 8 2
Emf induced in wire = ⎜ ⎟ Area = π1 = 8
⎝ dt ⎠ π
8
Current in wire = A=2A
4
8 4
VAB = − 2× = 0
8 8
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Test - 13 (Paper - II) (Answers & Hints) All India Aakash Test Series for IIT-JEE 2011
57. Answer A(q, t), B(r, t), C(s, t), D(p)
Based of fundamentals
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