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At Southern Clay Products, Inc., our goal is to deliver solutions to our customers... we create and deliver solutions.
In the late 1940s, Southern Clay Products was created with a vision innovate and expand. We began in Gonzales, Texas as miners and suppliers of unprocessed ore and simple milled products from local reserves. We have since steadily expanded our scope, acquiring and processing minerals from a wide range of global sites from Texas to China to Spain to Morocco to Turkey. In 2000, Southern Clay Products became part of Rockwood Specialties, Inc. Headquartered in Princeton, New Jersey, Rockwood Specialties is a leading manufacturer of specialty chemicals and minerals throughout the world. Rockwood Specialties substantial commercial and financial support will allow Southern Clay Products to strengthen our position as an international leader in our fields. As 2005 drew to a close, Southern Clay Products completed the acquisition of the rheological additives business of Sud Chemie, including operating sites and laboratories in Louisville, Kentucky and Moosburg, Germany. These locations joined previously existing sites in Gonzales, Texas and Widnes, England to form a global physical presence for Southern Clay Products.
Through technical and commercial partnerships, joint ventures, and acquisitions, Southern Clay Products has grown into a world leader in specialty additives. Specialty additives manufactured by Southern Clay Products are used by customers to formulate unique products in an extensive number of markets. Today, scientists from many disciplines and diverse backgrounds work in our modern, well-equipped laboratories to develop more advanced products and technologies based on a variety of chemistries. Our scientists work with world leaders in universities and industry, including our suppliers and customer partners, to ensure that Southern Clay Products continues to be the preferred supplier of high value, multi-functional additives. From computer modeling of ore deposits and complex chemical reactions to sophisticated rheological characterizations or additive enhanced formulations, Southern Clay Products differentiates itself through state-of-the-art technology. We are committed to meeting the needs of our customers both now and in the future through world class commercial development, product design, manufacturing, technical selling, and customer partnerships.
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Clay Mineral Organic Compound
Two methods of incorporating conventional Claytone or Tixogel organoclays are commonly employed: 1. In-situ incorporation 2. Preparation of a pregel
In-Situ Incorporation
Many manufacturers wish to avoid the extra step involved in the preparation of a pregel. The inherent ease-of-dispersion characteristics of Claytone and Tixogel organoclays allow in-situ incorporation of the organoclay, which can be accomplished via the following procedure: 1. Charge solvent and portion of resin to mill. 2. Slowly add Claytone or Tixogel organoclay during agitation. 3. Add polar activator. 4. Mix at high speed for five to ten minutes. 5. Continue with grind phase. Order of addition is critical when incorporating organoclays through the in-situ method. It is very important not to add wetting agents until the Claytone and Tixogel organoclay is activated with the polar activator. The addition of surface active (high wetting) agents, prior to activation, may interfere with optimum gelation. Surface active agents prevent delamination of the clay stacks and interfere with the formation of hydrogenbonding bridges when added before the organoclay is fully activated. Unlike some organoclays, it is not necessary to add surface active agents to aid in the dispersion of Claytone and Tixogel organoclays.
Preparation of Pregels
Some manufacturers prefer to prepare pregels. Pregels are composed of Claytone and Tixogel organoclay, solvent, and a polar activator. Pregels are added to the grind phase prior to the addition of dispersants. Pregels can be prepared by the following procedure: 1. Charge solvent to mill. 2. Slowly add Claytone or Tixogel organoclay (10% by wt. of pregel) to mill under agitation. 3. Mix at high speed for five minutes. 4. Add polar activator. 5. Mix at high speed for five minutes.
Tixogel VZ
Coating Type
High-Build Vinyls
Pounds of Activator
Pounds Methanol/H2O(95/5) Pounds Ethanol/H2O(95/5) Pounds Propylene Carbonate/H2O(95/5) .33 .50 .40 .66 1.0 .80 1.0 1.5 1.2 1.3 2.0 1.6 1.7 2.5 2.0 2.0 3.0 2.4 2.3 3.5 2.8 2.7 4.0 3.2 3.0 4.5 3.6 3.3 5.0 4.0
10
Pounds of Activator
Pounds Methanol/H2O(95/5) Pounds Ethanol/H2O(95/5) Pounds Propylene Carbonate/H2O(95/5) .33 .50 .40 .66 1.0 .80 1.0 1.5 1.2 1.3 2.0 1.6 1.7 2.5 2.0 2.0 3.0 2.4 2.3 3.5 2.8 2.7 4.0 3.2 3.0 4.5 3.6 3.3 5.0 4.0
Application Levels
Shown below are suggested starting levels for Tixogel EZ 100 and Claytone AF self-activating organoclay. A polar activator is usually not necessary when using Tixogel EZ 100 or Claytone AF. However, in some systems, low levels of activator can enhance viscosity development. Please refer to the individual product data sheets for more extensive information on all Claytone and Tixogel organoclays.
10
Description
Quaternary Ammonium Compound of Bentonite
Density
15.0 lb/gal (VP) 14.2 lb/gal (40) 15.0 lb/gal
Bulking Value
0.0667 gal/lb (VP) 0.0704 gal/lb (40) 0.0667 gal/lb
Particle Size
90%<90um (VP) 98%<200M (40) 90%<90um
Maximum Moisture
1.5% (VP) 2.0% (40)
Application
100% aliphatic to mildly aromatic systems. Automotive and equipment undercoats, trade sales alkyds, traffic paint, stains, industrial alkyds, acrylics, chlorinated rubber, epoxy esters, and aluminum coatings. Particularly suitable for very low to medium polarity systems. Anti-fouling paints, primers, backing systems, chlorinated rubber, and urethanes. Often used in systems thought to require a hectorite-based organoclay. Suitable for aromatic systems and moderately polar systems. Used in industrial, marine, and maintenance coatings. Often used to replace hectorite-based organoclays in aromatic systems. Medium to high polarity solvents. Nitrocellulose lacquers, solution vinyls, epoxies, acrylics, wash primers, inorganic zinc rich primers, and chlorinated rubber.
Tixogel TE
1.5%
Claytone HT
14.2 lb/gal
0.0704 gal/lb
95%<200M
2.0%
Tixogel VZ
14.2 lb/gal
0.0704 gal/lb
90%<90um
2.0%
Description
Quaternary Ammonium Compound of Bentonite
Density
15.0 lb/gal
Bulking Value
0.0667 gal/lb
Maximum Moisture
2.5%
Application
Highly efficient organoclay for 100% aliphatic to 100% aromatic coating systems. Often can be formulated at lower loading levels versus competitive organoclays. Typical applications are automotive and equipment undercoats, trade sales, alkyds, traffic paint, stains, industrial alkyds, and epoxy coatings. Requires polar activator concentration typical of conventional organoclays. Highly efficient organoclay developed for unsaturated polyester resins and similar applications. Tixogel MPI is designed as an easy-to-disperse rheological additive for low and medium polarity solvent-based ink systems. Tixogel MPI can help reduce misting, improve hold out, and improve yield. Tixogel MPI can be added to the pigment grind or added to finished product to adjust viscosity. Tixogel MPI efficiency can be improved by the use of 0.1% water as an activator. Highly efficient organoclay for coatings containing aromatic and/or oxygenated hydrocarbon solvents. Tixogel MPZ is particularly effective at building low shear viscosity and can be used to obtain excellent application properties or to reduce loading levels.
2.0% 2.5%
Tixogel MPZ
14.12 lb/gal
0.071 gal/lb
3.0%
Description
Quaternary Ammonium Compound of Bentonite Quaternary Ammonium Compound of Bentonite Quaternary Ammonium Compound of Bentonite Quaternary Ammonium Compound of Bentonite Quaternary Ammonium Compound of Bentonite
Density
11.9 lb/gal
Bulking Value
0.084 gal/lb
Maximum Moisture
2.5%
Application
High efficiency, easy-to-disperse organoclay for all coating systems formulated with aliphatic or aliphatic/aromatic solvent blends. Typically 10 to 20% more efficient than competitive products. Particularly effective in building very low shear viscosity. Requires no polar activator. High efficiency, easy-to-disperse organoclay that works in most applications, from aliphatic to moderately polar formulations. Activator free grade that can replace multiple competitive grades. Used in architectural, maintenance, and industrial (OEM) finishes. High efficiency, easy-to-disperse, activator free grade that is designed to function most effectively in highly polar systems, particularly in systems containing high amounts of ketones. High efficiency product for oxygenated hydrocarbon solventbased coatings. Requires no polar activator. This products outstanding ability to build very low shear viscosity can be used to obtain excellent application properties or to reduce loading levels Very high efficiency organoclay for use in aliphatic to aromatic systems. Can be used as a true stir-in for many applications. Used in automotive refinish, aerosol, and grease applications.
Claytone HY
18.0 lb/gal
0.0556 gal/lb
2.0%
Claytone APA
14.2 lb/gal
0.0704 gal/lb
2.0%
Tixogel MP 250
13.9 lb/gal
0.072 gal/lb
3.0%
Garamite LS
13.3 lb/gal
0.0752 gal/lb
2.0%
MMTs do not exhibit post-wetting or other stability issues to the extent that products such as fumed silica do. In many systems the use of a small amount (10% of the weight of MMT) of a synergist such as BYK R-605 (available from BYK Chemie) will further enhance the efficiency of Garamite MMTs. For optimal efficiency and performance, we recommend that Garamite MMTs be predispersed in solvent, monomer, or resin. Garamite MMT predispersions are indefinitely stable. Garamite additives are particularly effective in 100% solids and high solids formulations due to their ability to develop performance at low viscosity.
Application
A highly efficient, highly thixotropic additive for unsaturated polyester resin systems. Competes very well against fumed silica and organoclay thixotropes. A highly efficient, highly thixotropic additive for epoxies, vinyl esters,unsaturated polyester resin systems, and higher build thermoset systems. Competes very well against fumed silica and organoclay thixotropes. Performs well in many highly oxygenated systems. Not recommended in pure aliphatic systems. A micronized version of Garamite 1958 developed specifically for thin film (<75 micron) applications.
Description
Mixed Mineral Thixotrope Mixed Mineral Thixotrope
Density
8 lbs/ft3
Specific Gravity
1.5-1.7
Maximum Moisture
6.0%
Garamite 1958
8 lbs/ft3
1.5-1.7
6.0%
Garamite 2578
4 lbs/ft3
1.5-1.7
6.0%
Figure 1
Rheocin Thixotrope Incorporation
Figure 2
Advitrol Thixotrope Incorporation
Temperatures based on solvent strength
Rheocin generally not recommended in this area - tendency to seed
200F
160F
180F
140F
160F
120F
100F
Area of optimum performance for improved brushability, stable pigment suspension, sag penetration, thixotropic body and viscosity
140F
Recommended range
120F
80F
100F
60F 10 20 30 40
80F 10 20 30 40 50
Description
Castor Oil Derivative
Density
8.50 lb/gal
Bulking Value
0.118 gal/lb
Particle Size
99%<44um
Maximum Moisture
0.15%
Application
For aliphatic solvent systems. May be used in trade sales alkyds, stains, industrial alkyds, and any other aliphatic coating systems. Easier dispersing version for aliphatic solvent systems. May be used in trade sales alkyds, stains, industrial alkyds, and any other aliphatic coatings systems. Promotes flow and leveling of powder coatings. Improves film uniformity, edge coverage, gloss, and DOI. Suitable for a wide range of solvent systems. May be used in trade sales paints, industrial maintenance coatings, marine coatings, product finishes, high build epoxies, and vinyls. Easier dispersing version of Advitrol 100 suitable for a wide range of solvent systems. May be used in trade sales paints, industrial maintenance coatings, marine coatings, product finishes, high build epoxies, and vinyls.
Rheocin T
12.20 lb/gal
0.082 gal/lb
99%<44um
0.20%
Rheocin PC
8.50 lb/gal
0.118 gal/lb
Flakes
0.20%
Advitrol 100
8.48 lb/gal
0.118 gal/lb
99%<44um
0.15%
Advitrol 50
12.20 lb/gal
0.082 gal/lb
99%<44um
0.20%
Y-25 X
Y-25 X is an organic paste in xylene. It is very effective in promoting anti-settling and sag control without having an appreciable effect on package viscosity.
Y-20 XP
Y-20 XP is a pourable, anti-settling additive that functions much like the Y-25 X paste product. The pourable nature of Y-20 XP imparts much easier handling characteristics and decreases product loss due to difficulties encountered in completely transferring paste products from the drum. Both Y-25 X and Y-20 XP are water free.
160F
Area of optimum performance for sag control, thixotropic body, pigment suspension and improved brushability
140F
120F
100F
80F
Y-20 XP
7.4 lb/gal
Easy to use, pourable version that has excellent antisettling properties without increasing apparent viscosity. May also be used to increase sag resistance. Applications are primers (especially zinc-rich primers), traffic paint, and finishes where xylene is compatible. Excellent anti-settling properties without increasing apparent viscosity. May also be used to increase sag resistance. Applications are primers (especially zinc-rich primers), traffic paint, and finishes where xylene is compatible. Can be used to correct poor sag resistance in finished batches of paint without appreciably increasing the apparent viscosity. Can also be used to improve pigment suspension in low viscosity systems, such as stains or aerosols. Most widely used in trade sales alkyds and stains, but is also generally compatible with most coatings systems. Contains approximately 28% water.
Y-25 X
7.4 lb/gal
0.135 gal/lb
110oF
Adjust-4
8.7 lb/gal
0.115 gal/lb
N/A
See guide on previous page for recommended incorporation temperatures for Y-type products. Values above are typical properties, not specifications.
Description
HEAT** HEUR HEAT** HEAT** HEUR HEUR HEAT**
% Solids
20.0% 20.0% 17.5% 20.0% 25.0% 17.5% 15.0%
Solvent
VOC Free VOC Free VOC Free water/DB*** water/DB*** VOC Free VOC Free
Application
For small particle size acrylic and styrene acrylic latex systems. Used to generate high shear viscosity and excellent flow for brush applications. Low odor. For small particle size acrylics and styrene acrylic latex systems. Highly efficient in generating high shear viscosity. For use in building Stormer and ICI viscosity for vinyl acrylic, acrylic and styrene acrylic systems. For use in building Stormer and ICI viscosity for vinyl acrylic and acrylic systems. For use in building Stormer and ICI viscosity for vinyl acrylic and large particle size acrylic systems, especially for greater sag resistance for spray applications. VOC Free version of H3300. For use in building Stormer and ICI viscosity efficiently while maintaining viscosity stability when tinted. Used as a key co-thickener with L100 to give balance of flow and sag resistance. Generates high-shear viscosity in PVA, EVA, and other low response acrylic and styrenated resins. Tinted Viscosity Stabilizer. Designed particularly for stabilizing the viscosity of factory or in store tinted paints by eliminating or greatly reducing loss of viscosity upon addition of colorants. Highly KU efficient acrylic thickener with excellent tint and color acceptance for interior formulations.
Values above are typical properties, not specifications. **Hydrophobically modified Ethoxylated Aminoplast Thickener ***DB = diethyleneglycol monobutyl ether
Smectite Additives
Smectite Additives
Description
Organically Modified Sodium Bentonite Organically Modified Sodium Bentonite Organically Modified Sodium Bentonite Unmodified Sodium Bentonite
Density
15.0 lb/gal
Bulking Value
0.0666 gal/lb
Particle Size
90% < 250m
Maximum Moisture
9%
Application
Specially designed for use in latex emulsion systems. Can be used alone or in combination with cellulosic materials to improve pigment suspension and to impart dripless application properties. Requires preservatives in aqueous dispersion. Designed to impart high yield value in aqueous systems. Effective in preventing settling of heavy pigments and fillers, also increases sag resistance. Effective thickener for flat and semi-gloss latex paints, plasters, tile adhesives, and household cleaners. Resistant to bacterial attack. Highly effective thickener at low shear rates. Provides excellent anti-settling and sag resistance in waterborne coating systems while maintaining a low mid-range viscosity. Provides suspension characteristics in cosmetic creams or lotions and household cleaning products. Effective thickener for building anti-settling and sag resistance in economic waterborne coating systems. Effective thickener of mid to high PVC paints. Can be used as a partial replacement of cellulosic thickeners while enhancing hiding. Will generate anti-settling and anti-syneresis properties with little to no thickening.
Optigel WX
18.4 lb/gal
0.0545 gal/lb
10%
Optigel WA
20.0 lb/gal
0.0499 ga/lb
10%
Optigel CK
21.7 lb/gal
0.0461 gal/lb
10%
10% 6% 6%
Description
Unmodified Purified Sodium Smectite Unmodified Purified Sodium Smectite Contains Polymer Unmodified Purified High Brightness Smectite Unmodified Purified High Brightness Smectite Slurried Sodium Smectite
Density
21.7 lb/gal
Bulking Value
0.0461 gal/lb 0.0461 gal/lb
Particle Size
60% -200M
Maximum Moisture
10.0%
Application
Designed for applications above 35% volume solids that require a high efficiency thickener to generate sag resistance, anti-settling, and anti-syneresis properties Designed for applications below 35% volume solids that require a high efficiency thickener to generate sag resistance, anti-settling, and anti-syneresis properties For systems requiring the whitest possible additives. Particularly effective in cosmetic and consumer products. For systems requiring the whitest possible additives. Particularly effective in cosmetic and consumer products. Gelwhite H is a bacteria controlled grade. Designed for manufacturers requiring the functionality of smectite thickeners in a liquid package. Particularly effective in mid to high PVC architectural coatings which require excellent dry hiding and spray properties. Designed for manufacturers requiring the functionality of smectite thickeners in a liquid package. Particularly effective in mid to high PVC architectural coatings which require excellent dry hiding and spray properties. May be a better choice in some systems with anionic additives.
Mineral Colloid MO
21.7 lb/gal
60% -200M
8.0%
Gelwhite GP
21.7 lb/gal
75% -200M
8.0%
Gelwhite H
21.7 lb/gal
75% -200M
8.0%
Permont SX10A
8.88 lb/gal
N/A
Permont SC20
9.52 lb/gal
0.1050 gal/lb
N/A
Laponite additives are totally synthetic and have none of the contaminants that might typically be found in a naturally occurring product. Through careful control of raw materials and processing, Laponite synthetic silicates offer customers the most consistent solution to opportunities which demand superior rheological performance in aqueous environments.
Maximum Application Moisture
10.0% 10.0% 10.0% 10.0% 10.0% 10.0% Designed to develop thixotropic rheology efficiently in applications with adequate free water. For general and industrial use. Designed to develop thixotropic rheology efficiently in applications with limited free water. For general and industrial use. High sol forming grades for electrically conductive, anti-static, and barrier films Designed for personal care products requiring extremely low levels of heavy metals. Sol forming grade designed for personal care products requiring extremely low levels of heavy metals. Designed for rapid dispersion in sorbitol solution for toothpaste applications Sol grade designed for rapid dispersion in sorbitol solution for toothpaste applications
Description
Synthetic Layered Silicate Synthetic Layered Silicate Synthetic Layered Fluorosilicate Synthetic Layered Silicate Synthetic Layered Silicate Synthetic Magnesium Silicate with Fluoride Ions Synthetic Magnesium Silicate with Fluoride Ions
Density
21.7 lb/ gal 21.7 lb/ gal 21.7 lb/ gal 21.7 lb/ gal 21.7 lb/ gal 21.7 lb/ gal 21.7 lb/ gal
Bulking Value
0.0461gal/lb 0.0461gal/lb 0.0461gal/lb 0.0461gal/lb 0.0461gal/lb 0.0461gal/lb
Particle Size
98% -250 M 98% -250 M 98% -250 M 98% -250 M 98% -250 M 98% -250 M
Laponite DS
0.0461gal/lb
98% -250 M
10.0%
Glossary
Glossary
GLOSSARY
To help the user of rheological additives to better understand the terminology, the following definitions are provided. Viscosity The resistance to flow of a fluid: mathematically defined as the ratio of shear stress to shear rate. viscosity= shear stress shear rate Shear Stress A measurement of the force on a fluid which results in flow. Newtonian Fluid An ideal fluid characterized by a constant viscosity; that is, the shear stress and shear rate are directly proportional. Pseudoplastic Fluid A fluid which decreases in viscosity with increasing shear rates and increases in viscosity (proportionately) with decreasing shear rates. Dilatant Fluid A fluid which increases in viscosity with increasing shear rates. Thixotropic Fluid A fluid which decreases in viscosity with increasing shear rate, however, upon decreasing shear rate will slowly re-build viscosity offering a delayed recovery effect.
Shear Rate A measurement of the rate of fluid flow; for example, when two parallel surfaces are separated by a fluid film and are moving relative to one another, the shear rate is defined as the ratio of the relative velocity between the plates and the thickness of the fluid film. shear rate= plate velocity film thickness
Rheology In Coatings
The adjacent figure illustrates the relationship between shear rate and some important paint properties. At the lowest shear range, settling properties are indicated. At a slightly higher shear rate, sag and leveling can be measured. At an intermediate shear rate, the apparent, or stirred-paint viscosity can be evaluated. At the highest shear rates one can measure the application viscosity, which relates to the flow characteristics of the coating while in the process of being applied through brushing, rolling, or spraying.
10,000
1,000
Viscosity (cps)
100
10
Settling
0 .001 .01 .1 1 10 102 103 104
Castor-Based Thixotropes
Elementis Southern Clay Products
Rheocin Bentone 34
Elementis
Thixcin R Thixcin GR Thixatrol ST Thixatrol GST
Rheocin T
Claytone HT Tixogel VZ
Bentone 38 Bentone 27
Self-Activating Types
Tixogel EZ100/Tixogel MP100/ Claytone AF Claytone HY Tixogel MP250/Claytone APA Bentone SD1 Bentone 34/38/SD1/SD2/SD3 Bentone SD2
Anti-Settling Additives
Southern Clay Products
Y-20 XP Y-25X
Elementis
MPA 2000X MPA 60X POST 4
Poly Resyn
Suspeno 201X, Suspeno 202X
Specialty Types
Tixogel MPI/Claytone PS3 Tixogel MPI/Garamite LS Benathix Baragel 3000
Adjust-4
Smectite Additives
Southern Clay Products
Optigel WX Optigel LX Optigel WA/Mineral Colloid BP/Mineral Colloid MO
Elementis
NDO Bentone LT Bentone EW Benaqua NDO NDO
Elementis
Rheolate 244 NDO Rheolate 278 Rheolate 255 Rheolate 255 NDO NDO CVS-1, CVS-2, CVS-3 NDO
Cognis
DSX-3000, DSX-3075 NDO DSX-1514 DSX-1550 DSX-1550 NDO NDO NDO NDO
Aqualon
NHS-300, NHS-310 NDO NDO NLS-210 NLS-210 NDO NDO XLS NDO
NAFTA Southern Clay Products, Inc. 1212 Church Street Gonzales, TX 78629 Telephone: 1-800-324-2891 Direct Line: 1-830-672-2891 Fax: 1-830-672-1903
1600 W. Hill Street Louisville, KY 40210 Telephone: 1-800-468-7210 Direct Line: 1-502-772-4403 Fax: 1-502-772-4440
Executive Offices 11719 Bee Cave Rd. Suite 103 Austin, TX 78738 www.scprod.com