2008/09/18

Outline

4162

20102010

2020

1996 (UNFCCC)

2100 1990 50


Energy SecurityExxonMobilOil Discoveries and Oil Prices
Aug. 30, 2006
(78USD/Barrel)

GDP
US

Japan

China
India

(hydrogen energy)
(fuel cell)

(internal combustion engine)

(Hydrogen Economy)
6


20~30%

5~10
()

+
7


---

2000
2.64MW
2001 2.4MW

2002 3.5MW

200MW
10%

10


--

11

12

13

14

15

21

16

3C

2010150
Lithium ion 2~3
, 8
,
17

18

Chemical Eng.
Material Eng.

Electrochemistry,
Catalyst, Membrane ,

Polymer, Carbon,
Ceramics,
Metal hydride,
Nano tube

Mechanical Eng.

Transport Phenomena Fluid & thermal,

Electric Power,
Microprocessor,
MEMS, Sensor

Design and manufacture,

System control

Electrical Eng.
19

,,

20

PEM
Anode reaction:
2H2

4H+ + 4e-

Cathode reaction:
O2 + 4H+ + 4e-

2H2O

Overall reaction:
2H2 + O2

2H2O + Heat

,
21

22

Metal hydride
1.5wt%MH

The compressed hydrogen

tank can power a fuel cell
car for 300 ~500 miles.
Chemical hydride
10,000 psi composite
slurry 5wt%CH
hydrogen tank
23

-
(Alkaline Fuel CellAFC), 1960~

Apollo

(NaOHKOH)
CO2

CO2

24

(Phosphoric
acid fuel cellPAFC), 1970~
200KW

United
Technologies
200
25

(Molten
carbonate fuel cellMCFC), 2000~
200KW-MW

1 MW Fuel Cell Energy

26


(Solid oxide fuel
cellSOFC),
(Proton exchange
membrane fuel cellPMFC),
(Direct methanol fuel cell,
DMFC)3C

27

AFC

PAFC MCFC SOFC PEMFC

( ~1000MW)

(3~7KW)

(50~500KW)

(150W)

V
V

3C(1~30W)
(1~10MW)

(~2KW)

V
V

(50~200KW)
(~1MW)

DMFC

V
28


1.
2.
3.

29


1970
20051.45
32%
10kW
1)

Portable1
1000

2)

Mobile
1100

3)

Stationary
1 (distributed power
generation)
30

1.
20053,000

Smart Fuel CellVoller Energy

DMFC

200510
2006
IECDMFC2007
3C
2010

31

(Taiwan) Antigs prototype fuel cell

for notebook PCs (component-like
DMFC module).190x128x30mm,
weighs 435g, and power 12W .

Casios fuel cell prototype with

notebook PC.

Power Pack (Source: Medis

Technologies)

PDA
GENIO e

Fuel Cell Power unit developed

by Jadoo

75W SOFC prototype generator

sourceFuel Cell Today Market Survey: Portable Applications, 2005/09

32

2.
20 21

(PEMFC)

Daimler ChryslerToyotaHondaMazda
OPELNissanGeneral MotorsFord

2005 Region of Development

2005 Region of Use

sourceFuel Cell Today Market Survey: Light Duty Vehicles, 2006/03

33

HyGenius B-Class FCV from DaimlerChrysler

released at the 2005 Tokyo Motor Show

The good, the practical and interesting! Concepts cars from the 2005 Tokyo Motor
Show. From left to right Honda FCX, Toyota Fine-X and Suzuki Ionis.
sourceFuel Cell Today Market Survey: Light Duty Vehicles, 2006/03

34

Manhattan Scientifics
Aprilia
MOJITO FC
3kW
120193km35/
56.3km/h

CITARO

35

3.
20053,000
UPS
1kW800
1,0002005
48050%
210kW UPS80%
2006
kW1,000

75%SOFC1kW
5kW

36

1 KWCHP

GM300 KW PEMFC

Aperion UPS
Fuel Cell Energy (DFC) 300A500 kW MCFC

37

--
MCFC 250KWFuel Cell Energy Co. 550600

Siemens-Westinghouse MW Tubular SOFC

Steam turbine and Gas turbine

Ztek 100KWSOFC (GT)

SECA DOE5KWSOFC
SOFC+GTCO2

38

SOFC--

L-12.2m
W-2.3m
H-2.6m
One interesting trend in the large stationary arena is the development of modular fuel
cells linked in parallel to a gas turbine. Four current high profile proponents of this
technological strategy are FuelCell Energy (MCFC), GE Energy (SOFC), Rolls Royce
(SOFC) and Siemens Westinghouse (SOFC).
The purported benefits of hybridisation include higher efficiency, lower life-time cost
sand higher recovery of waste heat.
sourceFuel Cell Today 2005 Worldwide Survey, 2006/01

39


()
1.
2.

()
1.
2.

40


2010
3202020950
2050

2004~2010
130
20152,500

41

-1
UltraCell
UltraCell

25W
45W

UltraCell XX25
2-3

UltraCell XX25
42

-2
MTI MicroFuel Cells

20061113172006
Fuel Cell Seminar

MOBION 30MMOBION 1M
100%MOBION 30M
30W120W9cm25
cm17cm4.4kg
MOBION 1M 0.7W
34mm95mm153mm345g

20061110

MTI MicroFuel Cells2012

8000

43

-3
Plug Power-1

GE Power Systems
7KW
Home-Gen7000

7kW

7000 PEM

NOxSOxCOCO2

Plug Power 7000PEM

44

-4
ZTEK's Zero-Emission Solid Oxide Fuel
Cell and Hydrogen Co-Production Unit

ZTEKs Solid Oxide Fuel Cell-Gas Turbine System:For Power Generation

45

-5
Fuel Cell Energy

Fuel Cell Energy(Internal Reformer)MCFC

Direct Fuel Cell (DFC)
250kW1.0MW2.0MW67demo/sale unit
2006KawasakiMCFC
Fuel Cell EnergyMarubeniPOSCO
MCFC
USACanadaEnbridgeNatural GasMW
-Direct Fuel Cell/Energy Recovery Generation (DFC-REG)
DFCGas Turbine

46

-1
Angstrom Power
A2 Fuel Cell Flashlight

G2 Portable Fuel Cell Charger

47

-2
Ballard Power

Xcellsis Ecostar Ballard

Automotive
24 5kW
Mark V70kW Mark 900
Benz A1
Ballard Alstom
MatsushitaEbaraTokyo Gas
1996 250kW

Ballard1 KW CHP PEM

Ebara BallardBallard

48


Ballard PowerBallard

Jeep

HONDA

DaimlerChrysler

Ford

DaimlerChrysler

Nissan

49

-1
Smart Fuel Cell

SFC

Camcorder

SFC(Direct Methanol Fuel Cell)

EFOY
25~75W1.6KWh/per day

SFC C25125ml
25W50W

50

-2
Siemens-Westinghouse

Siemens SPFC
SOFC

SOFC
Siemens
Pittsburgh
300kW
60%

(20MW)
SOFC/GT HYBRID
70

SFC-200
125 KWe AC
100 KWt
44-47%
80%
(Expected availability)>98%

51

-1

200672627HITACHI uVALUE
Convention(DMFC)

9cm9cm2cm
3Wh1

52

-2

(DMFC)
MP3
DMFC117mm113mm25mm250g
20mL99%20Wh
MP3100mW
752310mm3.599.5
35300mW756010mm 10
602007

53

-3
Nippon Oil

Nippon OilPEMFC(Eneos Eco LP-1)LPG

1 KWEbara Ballard300
NipponEbara BallardKerosene PEMFC2006
2013100,000
NipponMHIKerosene10
KW-10

Tokyo Gas

Tokyo GasEbara BallardMatsushita Electrical LiFuel

PEMFC CHP
Tokyo Gas10010
200TokyoKanagawaChiba Saitama
31%45%75%
20082010

54

-4
2005~2007

a.
b. 1kW
c. 1600

d. 6
30
10
e. 413
480
150

55

-5
PEMTokyo Gas2005

Tokyo Gas

67

Osaka Gas

28

Matsushita Electric Industrial

40

Ebara

27

Sanyo Electric

20

Toshiba Fuel Cell Systems

Matsushita Electric Industrial

Shin Nippon Oil

44

Sanyo Electric

LPG

44

Japan Energy

12

Toshiba Fuel Cell Systems

LPG

12

Idemitsu Oil

Toshiba Fuel Cell Systems

LPG

Kyusyu Oil

Toshiba Fuel Cell Systems

LPG

Taiyo Oil

Toshiba Fuel Cell Systems

LPG

Total

175

175

200670020071000

56

-6
HONDA

FCXFCX
FCX-V4Honda200212
FCX19136
20027Honda
(Environmental Protection AgencyEPA)
(California Air Resources BoardCARB)FCX
2005
6FCX

57

-7
HONDA
1. 2008
2. V flow 30%20%
60%3
3. -30570KM
4. 100KW160km/H

58


1990

1995

2000

2005

2010

2015

PAFC
PEMFC
DMFC
SOFC

3C
3C(PEMFC)
(DMFC)
59

-1
Fuel Cell Test Station

Specification
Dimension

1180mm(L) 630mm(W)
940mm(H)

Power type

PEMFC + Ni-MH Battery

PEMFC

Nominal output: 24V, 250W

Ni-MH Battery

12 Ah

Fuel

Hydrogn gas

Fuel Cell Educational Demonstrator

Specification
Dimension

1576 440 1087 mm

Power type

PEMFC + Ultra-capacitor hybrid

PEMFC

Nominal output: 24V, 2kW

Ultracapacitor

32V, 27F

Fuel

Hydrogen gas

60

-2

Converter & Inverter

Reformer
60 x 50 x 50cm
Start-up time under 50min
H2 Conc. 60%

2kW mobile methanol

fuel cell system

H2 flow-rate 24(L/min)
CO <= 50PPM
61

-3

31
}
}

}
99.99

300L/hr

50-100L/hr
60mmODx100
140mmL

100L~500L/hr

62

-4

HB-SG02-0010-Q
10 lilter
> 0.1,0.5Mpa
0.1 liter/min

HB-SG02-0250-N

HB-SG02-0500-N

250 lilter

500 lilter

> 0.1,0.5Mpa

> 0.1,0.5Mpa

0.5 liter/min

0.25 liter/min

63

-5

3W SoC PCB DMFC Module

64

-6

CD-ROM size DMFC Power Pack

Semi-Active Open Structure

(EMS)

DMFC Power Charger

65

66

Thanks for your attention !

67