B.Sc.

EI(AMINATION June, 2006 CHE-I : ATOMS AI{D MOLECUTES & CIjIE-2 : INORGAMC CHEMISTRY
Instntctions 1. : Sfudenfsregistered both CHE-I & CHE-zcourses for should answer both the question pspers in two seporate answer books entering their enrolment numbe4 coursecode and coursetitle clearly on both the answerbooks. Students who haue registeredt'or CHE-7 or CHE-2 should answer the releuant question paper after entering their enrolment numbeti coursecode and coursetitle on the onswer book.

2.

fr.gefr. vfrqr
W, 2006 : fr.ga.$.-r q{Trq *r qql
: fr.qa.$.-2 W6TE[{6 @ T{II.FT

qhit 1. rt sr* d.qq.d-r s?.q".{.-z qe4nql "z\swqnT rrt wrrwn + t"q nqW d; fi?' * rift grk*r.ln t arqar Wfiqin, qq4ffi 4k
dzn qqqffiq 4q vM-sM nrsi6,.{{ I

ffi:

fusT 2. rt sn dq".d-r qrs7.w.{.-2 qa + tuq trq?W siq+sd wlw # rrc sa{-gfur {,

il etqar Wfiqi*, qqqfiq ale dqr qqrfiq lrq wg-sq 67-s4rrd I

cHE-1t2

P.T.O.

BACHELOR OF SCIENCE (B.Sc.) Term-End Examination June, 2006 CHEMISTRY CHE-1 : ATOMS AND MOLECULES
Time: 7 hour Note : Attempt all the fiue questions. Maximum Marks: 25

Use the following data : Velocity of light (c) - 2'998 x 108 m 1. Ans,ver any troo parts. (a) What is the mathematical form of the Einstein's theory of photoelectnc elfect ? (b) (c) What is the Zeeman eflecl ? How many normal modes of vibration are there in

cH3oH ?

CHE-1

2.

Answer any two parts. (a) Predict the shapes of any two oI the following molecules: (i) (ii) XeFn PFo-

(iii) clF3 (iv) HsCl, (b) Identify the type of hybridisationfor each carbon atom in the followingmolecules :

(i) cH3- coct

(ii)
(c)

HC = CH

In Oo and Fo, oo molecular orbital is of lower 'P* energy tnun tl2pv ' Explain why. and ,ro, ^ot""ular orbitals.

3.

Attempt any luro parts :

(a)

What are the three componentsof molar polarisation of a substance? Write an expressionfor any one of them, giving the meaning of each symbol. absorbsin the microwave region or not. Justify your answers.

(b) For each of the following molecules,state whether it

(i) co (ii) ctz (iii) coz

CHE-1 P.T.O.

(c)

Calcutatethe force constant of a diatomic molecule (AB) which absorbsal 2'L43 t 105 m-1 and whose reducedmassis 1'139 * 10-26 kg.

4.

Attempt any turo parts. (a) Derive the following expressionfor the radius rn of the nfr stationary orbit in the Bohr model :

'n=;;7'

nZt h2

where the symbolshave their usual meanings. (bl Draw the plots of the variation of (i) R(r), and (ii) ,2 Rz(r) wth r/ao for 2s and 3p atomic orbitals' (c) Give reasonsfor the following : (i) (ii) Ionic radius of F ion is lessthan that of H- ion' PClu is formed easilybut not NClu.

5.

Attempt any one Part, (a) or (b). (a) (i) (ii) What is ionic-covalentresonance? What are the three major rules for the linear combinationof atomic orbitals (LCAO) ? 2

OR
CHE-1

(b)

(i)

The dipole moment and the bond length of a diatomicmoleculeAB are 3'5 " 10-30 cm and 125 pm, respectively.Calculate the magnitude of charge on the A and B atoms. Write balanced equations for reactionsgiven below : proton emissionUv fjK neutron emissionUv !!et 1o1B alpha emissionby the nuclear

CHE-1

ff,{rq Ffliro 1fr.9ufr.) Ttaiilwfiqt W' 2ooo

Tqrfi fudtq

fr.ga.S.-t , rlrrql *t grg

Wlzl : 1. qEf

qfetndq si6 : 25

qb :

vefi {TEw7?'+ srr dFrg t w vqlr 6l :

2 6I

ffifud.rd

rt-rm qr *'T (") = 2'998 x 108m

r. ffi

t E}sTrii wr fitrq 1

(6) 3Trqqfl + r+rvr-frgq stilq frfrrfr 'rFrrfrqsq Hr i ? (rsl -iqn q*Trq t ? Hr ti ('r) cH3oH ffi qFTrqti;qr fq-rTq ? t

CHE-1

P.T.O.

z. ffi E?,qr,il vt-r{frq r + (s) ffitud oT5eit i mA q?,Efr fr srffi +r +1fqq : {qfuqrr
(il (ii) XeFn PFo-

(iii) clF3 (iv) HgCl,

oTryifq n+s +,dq q{'TrE fdq 1s; ffifua + q6-q qE-ntrq s{urs'r :
(i) cH3 - cocl
(ii) HC : CH

(T) o, * nzo,fl

,rii,

o2nxsT{ sqrs m u.d u2pv -t sqTqit u-qf t +lT Et-fi I 41

qTflr{q I

s. ffir Ei qptr+ sfl ErFrq r (o) ffi Tqrd iffiq fltEUTfiq q-s affi f I + + qs + fdq q+s {+d + sT{* qrq afsffi ffi frfuq t

(u; ffitua -s{ESi t qt{ qv-il{'r tr fr si-q{iqq 6tqTsilr qir re stqr) o{qi strr +1 ytr +1Frq r
(i) co
(ii) clz (iii) coz
CHE-1

('r) qs ti

qRffi-d

q{ +ifqq q\ 2'143* 105 m-l fiqqilquT 6{aT t 3ft fu-sT qqTfrd {qqH xs ' 1'139 to-26 t l

6t Rq{urgs ro 1n8) qfr Renis

4. ffi

q-,if E+ t srn {Rq t (6) d{ Efse ii nfr ft+t sq fr 'n fi-w 6 *

Frqfdt( aiqs 4i -dR dfqq :

'^=#'

qti {afr } qrqrq ertft t

3tt (s) zs e+r sp q{qrg 6qqii * fo{ (il R(r)' qrq 3TR bil r2 nzt) * qfisd{ aT r/a^ * dFqq t

('r) Frqfufunt fdq +nq frRq :

(i) F- 3{r{q 41 qTqFfi fxqr H- eTrin 41 F-ql

tqqt r r-fr t (iil ecgonvrfit e-{dr aff{ Nctu t

5. ffi (s) (q) (6. tTFr eTeHr 6'Tstrt {iRe t (s) (i) 3iT{fi-q6{id$ 3rflK wr t ? +qrdi + tng-s {dff{ u-cao) } (ii) qrqruJ ftoqh4xguf+wwrt ) sTcrEt 2 3

CHE-1

P.T.O.

(tq) (0 S frwqruJdW AB+ ff,q Eg+ enq"t qh ent**T 3.5" t0-3i Sr ffi "qVF q{qrEsit ",n 125pmt ,t A silr B vt sfl'+{r ql qr*rei (ii) tr+ { .lr$ qrFr+tq eTFThqteil ldq +

{igfudqqtrr frfuq : qlcTr swfi or fJ^ trRr

Wrq *l csdq ffr' ERr

lje ET{T tffir sq il BirdT

CHE-1

10

BACHELOR OF SCIENCE (B'Sc') Term-End Examination June, 2006 CHEMISTRY CHEMISTRY CHE-2 : INORGANIC
Time : 2 hours Nate: (i) core Answer all the fiue questions'Take particular question' to note the internal choice in each AII the questionscorry equal marks' Maximum Marks: 50

(il

l.

Answer anYten of the following:

(i) What'is

7x70

I
i I

earth the atomic number of third alkaline

metal, Be being the first member ? the following elements in the increasing

(ii)

Arrange

order of ionisation energY i Na. Li, Rb, K.

CHE.2

11

P.T.O.

(iii) From among the foilowing, choose the correct varue for the principal quantum number of the outermost electron of potassium : 2,3,4, 5, 6. (iv) Arrange the following salts in the increasingorder,of lattice energy : KCl, LiCl, NaCl. (v) Choose the most basic hydroxide amongst the following : Be(OH)2, Mg(OH)r, Ca(OH), and Sr(OH)r. (vi) Which of the following is the strongest Lewis acid : BF3, BBrr, BCl3 (vii) Which gets more readily hydrolysed: CCl4 or SiCl4

.i
(viii) Anange the following in decreasingorder of bond angle : NH3, SbH3, pH3, AsHa. (ix) Give the oxidation state of ,p, in.HrpOn. I j

CHE-2

12

(x)

Arrange the following in increasingorder of thermal stabilitY : HzO, HrTe, HrSe, HzS.

(xi) Which one of the follswing has the highest electron affinity :

n C l , B a l
(xir) What is ihe state of hybridisationof Xe in XeFn ? (xiii) How many unpaired electronsare present in Fe3* ? (xiv) What is the coordination number of Pt in the following complex : lPt (en)rClr) (xv) Which metal is purified by Mond's process?

2.

(a)

Explain the basis on which elementsare arranged in the long form of Periodic table.

(b)

Define electron affinity. How does it vary across the period and down the grouP ?

CHE-2

13

P.T.O.

(c)

Define hydrogen bonding. Give its types. Water has abnormally high boiling point compared to the hydrides of other elementsin Group 16. Explain. OR What are the factors which influence solubilityrof a salt ? Explain taking the example of caesium halides or alkali metal carbonates. 4

(d)

Explain, with balancedequations,as to what happens when CO, is passedthrough lime water (i) (iil in small amounts, in excess. OR Why do alkaline earth metals form more complexes as compared to alkali metals ? 2

3.

(a)

Write short notes on any two of the following : (i) (ii) Froth flotation method Nitrogen cycle

3x2

(iii) Catenation property of carbon (iv) Structure of diborane

CHE-2

14

(b)

Answer (1) or (2) from the following : (1) Explain any two of the following : (i) (ii) (iii) Phosphorusforms PFu while nitrogen does not form NFu. Boronformselectron-deficientcompounds. Hydroiodicacid acts as a strongeracid than hydrochloric acid.

(21 Completethe followingreactions: (i) (ii)' NH, + Naocl ------+ Zn + HrSOn ________+

(iii) NarSrO. + t2 (iv) 4. (a) cl, + HrS _-____+

Give one reaction each to show the oxidising and reducingproperty of HNO2. OR Compare the structureof CO, and SiOr.

(b)

Discussthe structureof XeFror anhydrousaluminium chloride. Why is the bond dissociationenergy of fluorine less than that of chlorine? OR Discussthe diagonal relationshipbetween boron and silicon.

(c)

CHE-2

15

P.T.O.

(d)

What are interhalogen compounds ? How are they classified? Give the structureof IFr. OR What are /-block elements? Compare the properties of lanthanidesand actinides.

5.

(a) Write chemical formula of any one of the following :

(i) (ii) Calcium hexacyanofenate(ll) (llf Potassiumhexacyanocobaltate

(b) Write the name of any one of the following :

(i) (ii) (c) K2[N(CN)4] [P(NH3)4(Cr)2]SO4

Using valencebond theory, predict the geometry and magnetic characterof [NiCl4]z-. OR Give the postulatesof Werner's theory.

(d)

Discuss any two of the following characteristicsof 2x2 d-block elements: (i) (ii) Variable valency Magnetic property

(iii) Catalytic property (iv) Complex formation

CHE-2

16

(e)

Halogens form various types of compounds with oxygen. Is it justifiedto call them halidesof oxygen ? Give reason for vour answer. OR Why is SO, not dissolved water directly during the in preparation of sulphuric acid ?

CHE-2

17

fudHptkr.r'1fi.9ufr.)
F{ia qtl{r w 2006 v*nfi fuilq fr.g4.{.-z t wqrdFrowr{FT
wg : z qr| qfqraq ef6 : 50

ie: r (il':: ffi.qfa wn *'sil{ dfiflq- s+6 rm # sr<T w arq d eqn C rd t &q(i,) sql wit + 3ia sqtad r
fr r. FTqfdfun t ffi- sF * sm {Fqq : 7x7o

(i) ffi qTrfu qrg* ro T{ ffii suveerrrqs t ?

'

wr m.qis fi'n

sqi + c-ai W xq (ii) FTqfufudirdi s) 3TFffi{ ii qqf{em frlqq :

Nqt;i1, Bb' K'

CHE-2

18

(iii) t{qFdfud fqq rq qT;iifr t lt}Rrqq + q-{S qr-dfrFAeTq +1 gw Eizq riwr qr qtl

tn gtrq :
2 , 3 ,4 , 5 ,6 .

(iv) Frafrfud c+uit q) qrcq; o-qf t qd ESm if qqRrd dfqq :

KCl. LiCl. NaCl.

(v) FrqFdfudfr t qq$ eTfirsqTrfrq ET*iRr{s +1 gF{q :

tTeIISr(OH)2. Ca(OH), Be(OH)r, Mg(OH)r,

(vi) Frqfrbo fr t qh-eTvqt vqe"q{ 3{RT +. o

BF3, BBr3, BCl3

(vii)+h ernr*rflsf,'rt qe-qqqk etart '

ccln Qetql 5191n

FmfuF*a +) qdE +1"r t {cA gq m.qif 1uiii1

qqR{d dfqq :
NH3, SbH3, PHs, AsHt.

(ix) H3po4 'p' q1 sFr+T 3t*E[ {dFq I fr

CHE-2

19

P.T.O.

(x) Frqfrfud fi drfrq rqrtrd + Wt gq frq it

dmRqd dfqq : HzO, HrTe, HrSe, HzS.

(xi)Fr<frfur fr t ffi srftr*t :

F, Cl, Br, I.

vq+ Ffrqiq .igdT

qi if (xiil XeFn xe * {is':tur wr siq{qT ? t il (xiii)Fe3* ffi ergFrd{frqi{ sqfurd t ?

ql Fr<ffiaa risd fr p1 qqqq sr qr t : 1xiv1

. tft (en)rCl2l

qrdr (xv)rf- nffiqrilr t+q slg d qREatq,qr t z srgvrr mif 2. (s) sq 3ITcm qnoqr eihq ffi +1 s) s{r*d qnufr + {d Fs fr qqR{d f+,qr qrdr i, I 2 (ul y*+g14dTdr +1 qft'qrfrd dfqq r en+d* qn

dqr q1i t tr+ si fr{ qd ++ qR-qffin d-fr z t ?

CHE-2

zo

(rT) ET$qr smie]-{ qnrnma +} 4ifqq r gst rqn {dFq I q{d ro * srq ilmi + EEgTFs) Ei gor fr wT sr er*rrqrqsq t sq Feniq dilr t I qr.ilr qltqq r sIsrET eqq +1ffiqdT d qqTRd qrd qno qilq_t q-{i tri t ? e1trqqtdrrd sTsrqr eTasTdii-cT qR
6T s-Erdiur ?F51qrql qirrq I

(q) {igfud Hqffi (il qq qr*r if, (ii) 3Trfirfr it

ERrqrcqr 4ifuq f* co, d

qi+qrfitsrditwr*crt r
sTcrqr qiltq qTrflq 5eil m -sTEqrT TqTqTg($rfirs RSdq+etrfrt ?
3.

(ol ffitu-c

tutuq :

fr n ffi

qi q-t {iRTqffirqf
3x2

(i) $'a-u6q{ ffi (ii) ilF+q-{ q-m (iii) +,dq +.r "jum+ grr (iv) Fdfq q1 gs+
CHE-2 21 P.T.O.

6r (uy Frq6p*oif t trl qcrqt(2) sfl {Fqq : (1) Frqfmfud t ffi qlal qrsr dirqq: fr
(il sffirq PF'EI;IrcIT t scfd qr{dwT NF5

a6 v+rfr r t
(iil ffiq ff{-qq (iiil flE"ffifts
EFisfldfs

qtFrs sr<t fr

sTERT

r{f, 3dRT edq gd 3Tftrs

+1att qrdowr t r : dt (2) Frqfufuf,sIFIFrqPii t't +1Fqq

(i) (ii) NH. + Naocl ------+ zn + HrSon ------+

(iii) NarS2O3 lz +

(M c! + Hrs ------+ 4. (ql HNo, * #nq" e 3{qqf*5g ' g*-tr* sTF{ffrqr {iRe t
gIqET

d wi'fi
2'

t +1Fqq mi co2densio, d {r+aPgl g<l-+r ffi{Es ft1 r+{r (u) xer, qqt Ffd EgFTFr+q
H] Tqi qitqq t

ffi-qq ('r) dfrq +1 gr+r fr qeifra fr sTrttq sqi6qdfrart u

sTcril

fr{q aqr Rfufi{ * fr ffi

qiFq t
CHE-2

qkr*I m Tqt

22

(q) oriilrtdts{ d^F- HTt z G *S Efrs.d fsqT qnr t ? rr',+1{irqqT r$q | 4

eTgrqr

id.s Rr r Elet ? d++rte) tm-qTqd w + g"il +i gel qlFwg r s. (ml nq6o

ldfuq :

t t fuifi f*. s.r {rq.Hf{sW c\

1

(i) +fuw twrsnrq)+te tlr) (ii) qHRrqq twrsr+il*ffi trnt (ul f+qp'6o q i ffi
(i) K2[Ni(cN)4]

qq.sr nq lefuq :

(ii) [P(NHd4(ct)2]so4

(T) S+rsdr s+raiq fuqio qr sq+t aG, 1Nicrnlzq1 qrFTfr dqT {q-+tqmpr *1 yqfu +lFwqr z
sTqET

eCr+ fuqid+ silrrTfid lefuq r

(q) a ffi* ilE) + fdqffuH qnrdqruit t A-6 fr q} ql wt qfrFqq : zx2 (i) qffid +fqqffir (ii) 1io-+irguT (iii) s&c*1.inr l (iv) qsd q+mr ,
cHE-2 23 P.T.O.

qTqtcF{q r+n } qlfirs tel tetqq g:ffitr{ * q-{iA t r wr g 3ffitr{ + t-dqs 6FlI sfdd t ? 3[q+strt q,t 6'RuIqfrr{q I sTcrdn q-qRs erq cqri $ qqq so, +) frt we ii

t eit Tfr *or snar ?

<.

CHE-2

24

5,000

BACHELOR OF SCIENCE (B.Sc.) Term-End Examination June, 2OO6 CHEMISTRY CHE-4 : PHYSICALCHEM|STRY
Time : 2 hours Note : Maximum Marks : 50

Attempt all the parts. Answerfiue questions from each of the three parts,A, B and C. From part D, ansu)er any four questions. = 8.314 J mol-l K 1) (R

PART A Answer any fiue questions. 1. 2. 3. 4. State Charles'law. State Trouton'slaw. What are smecticliquid crystals ? A heterogeneous catalyst takenas a finely dividedpowder is rather than as a smooth surface.State the reason. 7 1

CHE-4

P.T.O.

D.

Define colligativeproperty.

1
).
a

6 . What is a zeroth order reaction ? Give one example' 7 . State the eff.ecloI concentrationof a solution on its molar
conductance

1 1

8.

acids. State the dilferencebetweenLewis and Br@nsted

CHE-4

PAR-T B Answer any fiue questions. g. What is an ideal solution ? State the conditionsfor two liquidsA and B to form an idealsolutionon mixing.

lO. State any two differences betr4reen physisorption and chemisorption. 11. Define surfacetension of a liquid. What are its units and dimensions ? 12. DeriveBragg equation. n)" : 2d sin 0 13. For the reversible isothermal expansion derive the expression

W : 2 3 0 3 n R Tl o g$

,2

14. Define entropy of a system.Discuss statement the that the entropy of the universe tendsto a maximum. 15. Define the terms, molarityand molality. 16. What are emulsions Give two examples emulsions. ? of 2

CHE.4

P.T.O.

PART C Answer any fiue questions. 17. Define dipole-dipole interactions.Discuss the effect of molecular interactionson the physicalproperties. 18. Calculate the vapour pressure of water al 298 K. Molar enthalpy of vaporisationof water at its normal boiling point is 4.10 t 104 J mol 1. At 1'00 * 105 Pa, water boils at 373 K. that the efficiency 19. Statethe stepsleadingto the relationship of a Carnot engine is equalto W/qr"u where W is the total work done by the systemand qrnuis the heat absorbedfrom the source at higher temperature. 20. State distribution law. Derive it using thermodynamic considerations. 21. I t 10-3 m3 of a solutioncontaining4'0 x 10-3 kg of a non-volatile organic solute exerts an osmotic pressure of the 6'66 x 104 Pa at 300 K. Calculate molar massof the solute. 22. DeIine the terms :
(i) (ii) (iii)

Phase Components Degreesof freedom of a system

CHE-4

23. What is meant by standardelectrodepotential ? Construct a cell for the cell reactionin which copper metal displaces metallic silver from silver nitrate solution. 24. ln a reaction

A+2BizC+o
A and B are taken in a closedvessel 300 K. The initial at concentration B is 1.5 times that of A. At equilibrium, of the concentrations A and D are equal. Calculatethe of equilibriumconstantat 300 K.

CHE-4

P.T.O.

PART D Answer any four quesfions. 25. (a) Derive the expressionsfor Vr, pc and T. using van der Waalsequation. Calculate the root mean squar speedof hydrogen e molecules 300 K. at Molar massof hydrogen= 0 002 kg mol 1.

(b)

process 26. Foran adiabatic reversible showthat pV v : constant where y is the ratio of molar heat capacity at constant pressure that at constantvolume. to 27 - (a) Derive GibbsHelmholtzequation 5

L a r -o : - v 1
(b)

fal/c / T)1

^H

The standardenthalpy of formation of H2O (l) at the standard 298 K is - 285'8 kJ mol 1. Calculate internal energy change for the formation of water at 298 K. 2

28. (a)

Describethe "ActivatedComplex theory" of reaction rates of a chemical reaction. For the decomposition N2O at 773 K, of k = 1.00 t 1g-5 ,:1 uni Eu : 250 kJ mol-l. CalculateA using Arrhenius equation.

(b)

CHE-4

29. (a)

Show that for the hydrolysis a salt of a strong acid of with a weak base,the pH of the solutionis given by

p H = * p K . . , -l p n -

1'

*nn':"'., ;*:"": ,:;

(b)

.,:"']i,'o

Explain, using a curve, the principle of conductometric titration of a weak acid by a strong base.

3O. (a) (b)

State EinsteinLaw of Photochemical Equivalence. Define the term "()uantum Efficiencv" of photochemical reactiona

(c)

Describe experimenlal the methodof determination of quantumefficiency.

CHE-4

frdrr FTrilfi(fl.gq rfr.) rdiil rfrqTr

ET, 2006

TqrrFT frdrr

tfr.ga.t'-+ sifrd.THrq{ ,
HWt : Z qr)

qferadqeis : so

ie :

Ye+ + rnr i I B =8.314 mol-1 1) J K

$II|I i5'

0. qia rr+ + yar i I stn n t Aar. *

wt1 qrri *) aa ai I yda srn 6, er s;trr

qiq rsn + rar d&e t

l I

r. lTEd+ frqq sT3-Ac dfqq I 2. ?Ts.{ft-qq+.rs-ed.c r *t

3. Ftks rq fu-so wr t ? J q-6frqqfufr 4. -dg d d) s"t fr R,+rfun qr Wl sq q fu frnil ge fr ti t t | 6RUr sdo or +itqq | "o 1
CHE-4 P.T.O.

5. 6. 7.

sil"$i{fl yterd +1 qru{TFc t vfq dfa 3{i{hqr qr e ? qs s<ttt"i {frq qiq-dT stTrq t ffi f{dfi +1 q}-f,{qlqrrdrqr ssqi or sdo eiFq t eiil 6r -e" Eiq q d-+}s sTdi fr dfrq t

7 7

1 L

8.

CHE-4

10

qM EI

aia tT-di+ 3-a{#&g /

t E-dq{ Hr t ? n eil{ B A trd q1 FTdTts. qTEqi nff or 3_ds vrq enEqifrq?rq + fdq 3T|{{qtF dGq r deTr 1s. $ft-s srftniquT {fr{tqq + qtq ffi A 3idti

or sdo frfrq t

4ifqq r gs* qn-+ rr. (s q-q+ YE Fn+ 4] qRqTfr'd

s f u 6 q q w r tz

rz. *q qfi-+,{urffi

qifrq I

nX=2dsin0

rs. sffiqufrq R-qmm xqR t ftq aiqm dr AilR df,qq : nnr w = 2'303 rosf, z qi 14. gd iil 41 q*ifi d qRrTfra {frq I fqrq ^qqTfi .Tf-Isiq qi oti r{f, A {fr t | {q sfi 4t {ql 2 qiRq r dfrq r 4} rs. qldtdr s+{ qYd-ddT qfu{TRf, {tqq r 16. qF|{Ier t ? qTqit* q] s-<r6{'T
2 2

CHE-4

11

P.T.O.

rT $TrrT

fuA qia rr+ + rar d&q I

rz. Eg+-fagqo{qtrrffiqrcii41 qRqTqr ffqq I sTrtr{s erqtiTF*-qrcti 'ifd-s g"ir w xqrq+1 qqi qifuq r + rs. 2s8K q{ sf, * qlq qH mr qFcitr{ dfqq I qrqfeT HPf{is qt qET qi ddfq qrq{ trffi
4'10 x 10a.l -of1 t | 1.00 x 105pu qq qEI 373K

Tr w661 $ , rg. qrif {q-{ qi emriff w/e,n * sq il qm q-G + FeqqW qruii qr diliq r qd w.ir anr Se $"
fuq' rFil ild

qririlRdg.qr t I

3ft q,evB-,.,fiRdtq q{ q}-d-t

zo. katurfir+qm.r so+s dGq r gc*1qilfr sqrrrFc* srerR sqqlTq,+ +ifqq I sr

21. 7 x 10-3rn3fu644 fr +.0 10-3r.g3{qTq{frsdfitF, " ffi+ t{q+tr t r qO 300 K qq 6.66 x 104pa s{Rr(ur

Etrrst?rdr rffi-q en ltor ilqn-{ qffid t 22. qftqfr6 drRq :

(i) (iil qFR{Tr q&F

dfqq r

(iii) dr +1 EiiTdTqi q1ffi

CHE-4

12

23. qicn F@s t{qq t FTT 3Tftqrq t ? t-m sTfiTffrqT teq q+ td 6 fasqq 6ifqq fqqfr * srTgqTfu.s kiqr q} fuc{ 4q"> fr.-dq-{t qiTqT

klqTfr.d o-{-fr I t 24.gs e+nn*q fr

A + 28 =t ZC + o

3ooK qt a s*{ e q} qs qq qr q At t r s a1 qRFrs qirdTe t r,5 gfr t I qrq .R n q1 qtrdT o * qnqr t I 3ooK qt qrq REri6 61 qft66a sil

CHE-4

13

P.T.O.

q $TTIT

ffi 25. (o,)

an rfl+ # sar d&g I

+ fnq ffi

qrf,Tsfr+.{ur sqfrrr*G 4,0..+h t or

dr 6Tnfrdfrq r

erget + tdq 300K T q.f-qTq-5o (sl or-Wteq

q?T 6I qRq-mq dtqq
{{EII4

I EI{^+qq 6I q}-d{

= 0'002 kg mol-l.

26. s6qufrq udq r*.q + lsq <vrkUfd pv r = ftqi6 qh .rd v Rpnqrq!T frfrq B;qr tTltrdr nqi 3{rikFT qt ffiq sqr qrtrdrer egn t r zz. (q) fiqpT-tedq{ ffim'{ur4i gc+fr dfqq :

^H ;-a1rczD1- v

L ar lo=
() 298 K q{ Hro (l) 4i - 285'8kJmol-1 | t

q'g}d {rrfi 2g8Kq{ q h tqo+

qFffi

+ fu qns 3Tif,Rs g-qi qFf,dTqRsFf,f,

trs1
q{ 41 28. (s) {rqrqfrs 3TFIBqT 3TFTfuqT + tdq dfqq | "qBfrf, liar fudia" fr q15q1
(s) 773 K q{ N2o } qqq-6 + ldq k : 1.oo' io-u t1 dgT Ea: 250x.l mo[i t dfqq
CHE-4

2
3

I 2

3ffi3rg q{6rruTqr xfu .F-{A ql qFg-oa

1
14

2s. (6) 5v,tfl fr w ncff, srRr dm Sfd eTKs dEur t + wr-eTrrErzr+ tfl fqdqq fi pH Frq qqtm{urERT RqTqrdr d ,

,"=ipK*- |,r^o_ )rcn.-0 zri'o e-qq*1 qi{dr t r (G) qmor sqq)''r gdf, erq * n6rcT ERr qrR-s s{+
q?ffidr-Tils 3tqrw + Fqq +1qrcqr qifrq r 30. (s) y6mr-{rvr-qft-s g@-f,r+ 3Tr{nsr1{ t{qq 6r B-d +ifqq (u) n.FRl-{qtufrs3TFThqI "6pq (e111,, 4l +) qRrilfr-d dfrq r ('r) F{frT<eTdt qkftH t frq Hq}Fr+ * frlsT6r
qutT q-t I

CHE-4

15

3,OOO

BACHELOR OF SCIENCE (B.Sc') Term-End Examination June, 200,6 CHEMISTRY CHE-S : ORGANICCHEMISTRY
Time: 2 hours Note : 1. (a) Attempt oll the four questions' : 1+1 Give the IUPAC namesof any two of the following Maximum Marks: 50

CHs
I

(i) cHs-c-qH
t

9H. -cHz-cHz-9-Ct,
l -

cH3 cH3

cHs

(ii) <)Br

N(c2H5)2

(iii) H3-c= c-cHz-cH c

= cH- cHz- c-NH2 lt

cHE-s

P'T'O'

(b)

Write the structural formula of any two of the following : (il (ii) 3-oxo-2-nitropent-4-enoyl chloride N-methyl-4-hydroxyaniline

(iii) hept-6-ene-3-ynoicacid . (c) what is the reagent used to convert nitrobenzeneto azoxybenzene?

1 { 2

2.

Attempt any fiue of the following : (a)

( i le O # - a { 4 a
--+Y (ii)<_JJ L ft
NH, l r O l

Answer any two of the following three parts :

'"/Hzo> ?

(ii) cHs- cH - cH - cHs *u*"?, , Na/iq.l'{Hr, , Br

(b)

Br
z

Explain why cyclooctatetraene not aromatic. is

CHE.5

(c)

Below

are given carbocations:

the

examples

of

sgme

CH" + 1 " + + C H z , C H 3 - C + , C H s - C H 2 a n dC H 3

cHe
Place them in the decreasingorder of their stability and give reason(s) support of your answer. in 2

(d)

How

will you synthesise butanone from ethyl 3-oxobutanoate?

(e)

Explain Cannizzaro's reaction using a example.

suitable

(fl

Assign E or Z configuration to the following compound :

cH.

j.:.1

cH?oH

H/

\ a".

(g)

DiscussHell-Vollhard-Zelinsky reaction using a suitable example.

CHE-5

P.T.O.

3.

Attempt any fiue of the following : (a) Differentiate between the following pairs bV- U'V' spectroscopy, and give reasons in support of your answer.

(D G

!1'.",*.'bcH:cH2

(ii) 52..-' .$1.n,

cH3 cH3

(ii,) OO
(b)

and O-O
S"o',
3

Complete the following reactions:

(i) coHs- - an. f o o

(ii)cHs-fi-ct,w,
OH
(ii,) ^\ I (, . Br2 1?

H"o

(c)

also write the and Explain mutarotation and conformationsof a-D-(+)-glucopyranose - glucoPYranose' P - D - (+) Give the reaction of methyl magnesiumbromide with (i) HCHO, (ii) CH3CHO, (iii) CH3COCH3.

(d)

c HE - s

(e)

Give the mechanism of any one the following reactions : (i) Friedel- Crafts reaction (ii) Aldolcondensation Arrange the following molecules in the increasing order of their boiling points. Also explain the order and give reasonsin support of your answer. (i) 2-Methylhexane (ii) Heptane (iir) 2,2-Dimethylpentane (M 2,2,3-Trimethylbutane

(0

(s)

Arrange the following alkenesin the decreasingorder of their stabilities.Give reasons in support of your answer. (i) (ii) 2,3-Dimethylbut-2-ene 2-Methylbut-2-ene

(iii) But-2-ene (iv) But-1-ene 4. Attempt any liue of the following : (a) An organic compound A having molecular formula, CaH6, on treatment with hydroiodic acid followed by aqueousKOH, gave compound B. Compound B can easily be obtained from A by passing through dilute HTSOnA{sSOa. Give the structuresof compoundsA and B. Give two tests for compound B to confirm its structure. CHE-5

P.T.O.

(b)

CamT-eulthe following conversions: (i) Toluene to phenol (ii) Chloroform to ethyne . , , (iii) Aniline to 4;nitroaniline Give the mechanismof the Hofmann rearrangement. (i) (ii) Explain how l-propanol and 2-propanol can be by distinguished lH-NtvtR 'finger-print region' in I'R' What is the term 'is this useful in the spectrum ? How identification of compounds?

(c) (d)

4 2

2 -

(e)

the Discuss order of the easeof dehydrationof primary' secondaryand tertiary alcohols.Give the dehydration . 4 product(s) 2-pentanot. of Discuss the relative basic character of pyridine and pyrrole. Explain why position-3 in pyridine is preferredduring electrophilicsubstitution. Draw the various Fischer projection structures for tartaric acid. Give the R/S configurationof C2 and C3 carbonsin these Fischerprojection structures.Explain which one of the structuresis optically inactive.

(0

(S)

CHE-5

f{flT Fflirin 1fi.9u fr.) wiil qfrqt w 2006 wr{FTf|q rfr.!F.{.-s ' qTdFrowr{FT
rtz{: z qot atfttqaq aid : So

qh :

vql 4R v'eii + var d&q I

qFq :

fi Frr+frfua t ffi t. 1my

qrq s) * siT-$.tfr.q.fr.
L+7

(i) cHs

?"' -:"
i

- cHz- cHz- -."t ?

cHe

fn'

cH3 cH3

(ii) GN(c2Hi2 Br (iii) H3-c =c-cH2c cH : cH- cHz-c-NHz tl

cHE-s

P.T.O.

t 1u1Fr<Fefuo t ffi El + Titqq|trdW ftTnsq : 2 (il Fffi-2_n{At-4_tiqn d{{s (ii) ry-fift56-a-6qfafiQfiffi (iii) te-o {q s e'nrqt{s s{R (r) qr{A+dr t &fma*q q Fqrci{ur firq + sTFffids sqft s.C t ? t +}q-eT 2. FTqfrtudfr $ mA qf?wit * wr {fqq : tr{ '{Fit t t ffi E}* s'n 1qyffitur 2 {Rq: '

a^ (ii) \-JJ- Ln

NH" t -

O l

Feftfzor?

Y o
.NuNHzl, *uF , "r, *nt, ,

(ii) cHs - cH - cH Br Br

(s) qrflr{qqrE+t'reffi{

tt'dtrs e{t +fr t r 2

CHE-5

(r) fri go +,rqlnT+if sq-d{nr 'rq t ' * fqq

+ t

CH.

CH2, CH3-C+,

cHs

CH3-CH2 defiCH3

sffi1 q-et gq r+rfud * mq fr qqRsrddrfdq nqr e{qi (q) qir s +f*tqlilqc t 3rq qh{ 6T

S$fuq*fr qti ?

(s) 3qEil s-{flur + +FNTftsnpTFfqr q-qr u'1 drfuq I z (q) ffirfua qlFrq sr e sqql z fuqrs FTqfRr

+ifuq:
CH. \ , CHoOH

z
=t
/

n/'

\.n,

(E) sqgffi seraq t tm fu-+ftr61 EUir dfqq I

eTF{ffiqr 6r z

CHE-5

P.T.O.

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+ifuq aqr enqis+t * ffiq qtq S {Fqq t

qfuwit * sm {Fqq: g'if FTqfrfuH + ffq 3iil

!it", .ft'tiqn
(ii) ? 3ft
cH3 cH3

='cHz

.$.n,
31h OC
3
SeOe

(iiil OC

s{F{ffiqrsit Wf diFq : d (rs) FreFofua

(i) CoHs- - tn. -4 f ?

(ii)cHs-fi-ct,w,
o

z,r4 (iii) 6. (rr) qFrtrryT El! t.qr

a-D-(+)-rqfiIq|{|{R|

OH I

z
eiR

@u nvt
3

(q) iFrn ffiRHq frwr{s ail Paq66o + qTq

sTF{Ffrqr {Fqq :
(i) HCHO, (ii)CH3CHO' (iii)cH3cocH3. cHE-s 10

frtuq t

P-D-1*1-tffirtu

$ * etqil{qrq

(v1 frq66o t t ffi

qO sTF{hqr ffiRr fi

{frq:
(i) xtle-*rW
(ii) Wd ttqfi

s
sTFrFfiqr

1q1fr<frF*a eqeit +1fi+ Tifii+1+ q-Etmqii

q-qRrd dfqq r xq d Hqflr{q sfu stqi Btt

+ fdq qnurrfr {Fqq r

(i) 2-ifqf,N{ (ii) Pq (iii) z,z-gr{iFmHa (iv) 2,2,3-grEtFroq!

(e) Frt+frR*a + k6tn +) fi+ TqrFr6{ TcAxq il

E{qRqd+fqq I 3{q+ sfl * loe q,RurS ffqqr

(i) z,s-sr{iFrtrqr-z-t{
(ii) 2-qP56ry-z {a (iiDqc-2 {r
(iv) qc-l-{r

4. FrTtutudfr t ffi qfn+ sffi {Fqq . (s) qs *,dF{s dFffi. A, aF-* F . cnHu, orFililttrs 3{R + wq B,qr oqi + qK, wfrq xor-r qrq dFrs B sndTg I qJpr+ * e *i ca fzsoa/Hsson srTrF{d vt e d t o{t s{rqrfr rrw fuqt qr e6-dr I t t qlFr+ eqh d.*r ffqq rdf,'r* s+1 qcqn + fdq "frqftttrf{fqq | 4 A
CHE-5 11 P.T.O.

: (s) FrqfuRraFq<{q +1Fqq (i) dqia t qtf-a (ii) R)ffid t qErra (iii) tFrdq t 4-ilTAQFrdq ('r) tTq.qH gqff"Trqqi ffrqTfqE {Fqq t t (q) (i) qrflr{q fs 1H-NMn r-iifo

31h

ol zr)+f. + trq *+ 3i-trt v*.t t r (ii) oFN-(m it 'effi-om *{' wr ntar dq t z qofds rqn + qlffi al q6qn6qt fi sq+,fr ? t (e) xqFr+, frfrr+ cilr E-fiqs ednfd F ftfmor'T* qfl qr rqt sitrq 1 2-Pfrq $
vetq {fqq t (ql Ffistr 3ft Frtd + qTtRffi eTftqq{6R qt Tqi drtuq I {fr-qTr+fr qfr{qrq{ * fdq Fdfrfiq
qqflr{q I

qi-r6 srffd *it frfr t ? fr FTFS{ 3-Rqfr

(o) azt* sdRT fqnr* FF{Rrdt +1 {rq{r * fir{q r rq fwn oqq {t+floii ii c, *t c. sdq + frq nzsf{qm ffqq I qrflEq fr tq q q{ut-s*ai t t {rq{r}if t Hh-i Tdrur

CHE-5

12

4,000

BACHELOR OF SCIENCE (B.Sc.) Term-End Examination June, 2006

CHEMISTRY C H E- 6 : O RGA N T C E A C T T ON R MECHANTSM

Time : 2 hours Note : Attempt any four equol marks. Maximum Marks : 50 questions. All questions csrry

l.

(a)

Arrange the following in increasingorcier of reactivity towards electrophilic substitution. Give reasons.

CH"

(i)

t "

@
CI

(ii) l o l

(iii)

(iv) (9

NO,

CHE-6

P.T.O.

(b)

Pyridine is less reactive than benzene towards electrophilic substitutionreactions' Give reason.

(c)

What

is

meant by

kinetically controlled and

thermodynamicallycontrolled reactions ? Explain by taking the example of addition of HCI to

1,3-butadiene. (d) Methanal is more reactive than butanal towards nucleophilic addition reactions.Explain.

a12

2.

(a)

Complete and suggestthe possiblemechanismof the following :

(i)

= (c6Hd2c NoH

PCl5

o
ll

/ii\ uu
(b)

cF3co3H

\J

>

Starting from

diethyl malonate, how will you 21 2

1

synthesiseadipic acid ?
(c)

from ethyl ethyl acetoacetate How will you synthesise acetate ?

2'
on the aromatic nature of

.(d) Commgnt

cvclo-octatetraene.

7 '

CHE-6

3.

(a)

What are cycloaddition reactions? Why is thermally l induced(2+2) cycloaddition 4; symmetryforbidden? Write notes on any four of the following : (i) (ii) Chemical action of X-rays Syntheticpolymers B

(b)

(iii) Carbenes (iv) Neighbouring group participation (v) 4. (a) Benzynes

Give the product and outline a suitablemechanismof . any three of the following : 2:x3 (i) Reaction of ethyl ethanoate with excess of methanol. Reaction of neopentyl alcohol with hydrochloric acid.

(ii)

(iii) Reactionof l-butene with mercuricacetateand water followed by reduction with sodium borohydride. (iv) Reaction of propene with diborane followed by oxidationwith alkalinehydrogenperoxide. (v) Reaction of o,,B-unsaturated carbonyl compound with diethyl malonate. 2lx2

(b)

Write mechanism any tusoof the following , of (i) (ii) Norrish type I Norrish type II

(iii) Paterno-Buchi reaction cHE-6 3 P.T.O.

5.

(a)

Completethe followingreactions: (i) CH,C = CH

NaNH2
-----. A -----D

cH3cH2cl

lH2/Pd lCaCO" v
C

(ii) C6HqCHO

CHqMgBr HrO/H+

CrO"/If+ D --#

CHO

(iii) (

2
'

\^,/

Y
ll
CHO

Heat r.

,/'\ H

(iv) CH3CHrf, 44\

(b) How will you prepare (i) (iil 6. (a)

aniline from toluene? from phenol ? o-hydroxybenzaldehyde

3 22 L

and narcoticanalgesic What is the differencebetween example of each. simple analgesic? Give one Comment on cleansing action of soaps and detergents. What are the advantagesof detergents over soaps ? e Discussthe factorsthat influenc the rate of a reaction a1 proceedingby S*2 mechanism.
2

(b)

(c)

CHE-6

(fi.W rfr.) f{dm Frkrrs'

Fdiil qfrqTr

E;T'2ooo t*nfi fu{rr m.W.{.-6 , o,rdko eTF{fuqrsil 61 ffiqe

rlzl : z q")

arfEadq ei6 : 50

qlz:

ffi Err rr+ + yar d&e r wfi r{-+ + sifl sqnd r

qfrrqrqqeTFThqT l. 16y Fwfufun d f@fr * qfr ffif,dT + qqA mq fr s{-qR 6ifqq I rd onq <ifqq | 4
CH"

t "

(i)

@
CI

(ii) t o l

I
(iii)

NO,

(9

t P.T.O.

(iv) (9

CHE-6

(rs) RRSqiffi-fr
ffi4 t oq ffid

qfu{prTq-{ sTFThureitqfd +

2 {fqq | t I q'RUT (r) sqFTfu-fid: fuiB-d B+{ qFdq-tr f+rihf,' sTFTfuqieii *il 3TFTqTq ? ucr + t t ql-sn 1,3-qlt-sr{i{ qt riffi-q t c<rotq HRT +iRq , n; (q) i+t-d iTFffifrfr sd{ 3TFTffiqreii qFd + qi+o t sTFffiffid 2 t r qrflr{q |

2. 161Fratutuad Wt dfqq sfu elqQtn ffifll

gflE( : (i) = (c6Hd2c NoH g

----------)

cF3co3H

() sr{qfqeHiz

t xtq s{ 3rrrT QEtr+ e+q

2 '
1

*t ffifrd 6ti ? (rT)qi-rd tfr)c t qf.m t$dtS> ffitrd sti ?

(q) qTqR}3@{ +

3TT.T *t
2'
z

tt.fr*

qtron

qt
-

trqutffrRq r
CHE-6

1 2

i '

s. (6) !-*1 ftT{ 3rftt""flq wr t ? nrq }Rd (2+2)ffi {+-anR} RqFfrqffint ? ni (sl fr=tfuRs-o an q{ ffirqf fdfuq : ffi 8 (it x-fu-roii nqqFs frqT +1
(ii) $RE {gfs
(iii) *tflq

(iv) Yfra{frRTl q-ilTrFTn (v) AFr{q 4. (m) ffifu-a ffi ff{} serq eir sqm ffifiT +1 6!tGTffqq : 2!xS (i) qfq-n qtfrqe +1 n+freT+1 eTfir+-dT t e{i+hq r (ii) FCif{ h)Efd dr ur-fteik+ erq t e{i+hqr r

(iii) l qzt{ +1 wT s+{ qqRs W}c t

3+Itl-q;T I

qrq eTfiThqr, fr qlRqq +i-dTtqst qrer

qrer Ei (iv) nlqr qi sl{diq t eTf\fu-qr, qrdq 6E+qr fr 3qffa 1 qrdftrd +Frs q1 stqtfiffi (v) oc,B-sftiqq mfu t sTfiTB-qT I (u) frnfufun ffi Ei q1 ffifsT ldtuq : 2lx2 (i) dRv *nn r (ii) frRvr q-srir (iii) qrlif-gb sTFThqT
CHE-6 7 p.T.O.

+i 5. (o) Frqfufua3Tl,TBqPit ti qlFq : NUNH', = (i) cH3c cn o ,1nroo *rarfi

JCaCo3
C

(ii)c6H5cHo ffio
H
(iii)

t'otff* ru

/z
\

tfi'
.

CHO

* , / \ H CHO

il, F

(iv) cH3cHrB,

AgcN

, G

() oil.q+t cqr(i :

(i) .iEa n tFdfr{

(ii) stfrn t oerei+elNktTss
6. ( 6 ) {qIgF ffi ()

3 2'
1

4 {Fqq | t u rAm t rdq !s sqr6$r qi qrgq sfl{ sTqqTfs frCd{ fiq qr M * +ifqq I Wr +i gwr fr s{qqr+s wr ent
E /
r\. ^

sft qtefiqur ffi

fr wt eiffi

(r) qrcii +1qqf 6ifwqu) s,,.2 ffiRT t EHqrd

3TFTBqT a1{'ryf{d's.G | +1qr t
8

4+
3,ooo

CHE-6

BACHELOR OF SCIENCE (B.Sc.) Term-End Examination June, 2006 CHEMISTRY C H E -9 : B IOC H E MIS TRY
Time: 2 hours Noie : Answer any liue equol marks. Maximum Marks : 50 questions. All questions carry

1.

(a)

What is anaplerosis Explain with the help of an ? example.

(b)

What is an antibiotic? Explainthe action of any one antibiotic.

(c)

How are normal cells and transformed cells different from each other ?

(d)

Structure of

haemoglobin has

evolved from

myoglobin.Justify.

CHE-9

P.T.O.

2.

Differentiate betweenthe following i (i) (iil Ribosomesof prokaryotesand eukaryotes Celluloseand glYcogen

2;x4

(iii) Glycolysisand gluconeogenesis (iv) ct-helixand p-pleatedsheets 3. (a) via How is ATP synthesised electrontransport chain ? Explain brieflY.

(b)

Name various factors which influence enzrJme 5 catalysedreactions.Describeany one of them' and alanylglycine' Write the structuresof glycylatanine What is recombinant DNA ? Write down the steps involved in the cloning of a gene' What are the chemical constituentsof bacterial cell wall ? Describe the experiment of Griffith and Avery 'DNA is a geneticmaterial'' indicatingthat 2

4.

(a) (b)

(c)

5.

(a)

(b)Namethewatersolublevitaminwhichisnotidentified function.Also mention its biological with a coenzvme role. (c) (d) Write the biochemicalbasisof lactoseintolerance' What is a codon and an anticodon and what are their roles ?

2
2

CHE-9

6.

(a)

Write short notes on sulPhur''

'biological functionsof zinc and

(b)

Give two differences between replication and transcriPtion' Describe Name different types of immunoglobulins' the function of anYone of them'

(c)

7.

with folic (a) Identify the biochemicalreaction associated acid' acid, riboflavinand pantothenic (b) (c) Explain the regulationof pyruvatedehydrogenase' Name different types of RNA and briefly describetheir functions.

3
J

CHE-9

fq-drq Frrilo (fi.qs fr.) wiil qfiqt

E{, 2006 {qr{r;Tf{ilq

, *fr.ga.d.-gafrqr{nfi
Wlzt : Z qoi s$Wdq 4"F : 50

qle:

fudl^qfa tr-t # rar d&q t s,fr t{-di + 3i4t

sqqd t

t e1 l. (m) tndtfu'e wr t ? l|* sqrdrul vorqnr qrcqr dfre t (u) qfr$k-d wr el-cn ? ffi q1qs qfd$R-d t dfre t fi ffrqr q1 aqrcqr (rr) FqFTFT dM nqrwiaRo dM tfuqx*nlqat ?
(q)

qs (si

H1 {rqrT qTqHR-{ 41 E-iT i Ei

gi tr-dtud t I ytr dfqq t

CHE-9 P.T.O.

2. Flafufud fr nid{ ws +Tqq , (i) mM.A HqT TMii + {dq}q (ii) +gdq dqTrdr{fr-r4 (iii) rdTqsffiflTdqr rgfrFntitR-s (iv) '-gsffi d{I p.6-frfu6 6.

z}"+

3. fql ffit "ju-or anr ArP 4t ffiq'T ii fus r+ri rlor t z +ielq q"h dfqq | q) tsl q.siqqrdRR sTFTffiqpii qqrf{d +at qd lfuq r q+t t ffi qs 6l slt+] * q|-q FcFTn
qufq dfqq |

4. fqi.erffi+q

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CHE-9

3,000

BACHELOR OF SCIENCE (B.Sc.) Term-End Examination June, 2006 CHE-10 SPECTROSCOPY :

Time : 2 hours Note : Maximum Marks : 50

Attempt any fiue questions. AII questions carry equal marks.

h = 6.626

10-34 Js " N A = 6 ' 0 2 2* 1 0 2 3

Am2 P": 9'27408x 10-24 mc= 72 mo: 75.9994 l. (a) What is Zeemaneflect ? Calculate the number of levels obtained for 2Pr, and 2P312 statesin a
magneticfield. (b) Write the expressionof energy for an electron in the nth level of a hydrogen atom. Explain various terms appearing in it. Give an exampleof a moleculebelongingto Dan point group. State the symmetry elementspresent in it. 4

3 3

(c)

cHE-10

P.T.O.

2.

(a)

What are n-fold axis of symmetryand n-fold improper axis of symmetry ? Illustratewith the help of suitable examples.

(b)

Which one of the following willhave higher rotational constant (B) and why ?

72co or 13co
(c) Give one example each for the following categoriesof polyatomic molecules: (0 (ii) Spherical top Spherical top (prolate)

(iii) Spherical top (oblate) (iv) Asymmetric toP (d) CO molecule absorbs at 2130 "--1. force constant. Detn'rnine its

3.

(a)

Discussthe vibration-rotationspectrum of a diatomic molecule.What are E Q and R branches? Draw the modes of vibration of CO2 molecule assumingit to be linear. State the essential condition for a molecule to be microwave active. Which of the following molecules are microwave active ? CCl4, HBr, CO2, SO2

(b)

(c)

cHE-10

4.

(a)

How will you differentiate between alkynes and nitriles on the basisof their IR sDectral data ?

(b)

A moleculeArB, shows the following spectraldata : cm

-1

Infra-red

Raman Strong

3374 3287 7973 729 612

Very strong; PQR contour Very strong; PR contour

Very strong

Weak

On the basis of the above spectral data, predict whether the molecule would be linear or angular ? State the principle used in arriving at the conclusion and give reason for your answer.
(c)

Calculatethe CFSE for Ni2+ ion in a high spin octahedralcrystal field.

(d)

What is Pascal triangle ? Using Pascal triangle, predict the number and intensityratio of the splitted signals causedby 5 equivalentprotons.

cHE-10

P.T.O.

5.

(a)

Explain any three of the following : (i) (ii) Red shift Chromosphere

(iii) Auxochrome (iv) Chemical shift (b) Discussthe IH-NMR spectrum of pure ethanol with the help of a diagram. Indicate whether the following electronic transitions are allowed or not ? Give reason for your answer'

(c)

(il I* eI*
(ii) I" e> f

(iii) g <+ u (iv) ueu (a) (b) Draw the block diagram for Raman spectrometer' How would you experimentally record the IR spectrum of a given organic compound ? What is Mclafferty realrangement? Explain with the help of an example. Discussthe ESR spectrumof ethyl radical. 3

6.

(c)

2 3

(d)

cHE-10

7.

(a)

The ESR spectral line of benzeneanion is centred at 9'350 GHz when the magnetic induction is 3.334 t 10-1 T. Calculate g value. its Explain the origin of m/z = 44 peak in the mass spectrum of butanal. A compound having molecularformula CzHsO shows the following spectraldata : W IR ltt-NtutR.l_* at 254 and202 nm 3420 (broad),3064,1500and 1455 cm-1 (d, cDcl3) : 1.85 (s, 1H), 4.7 (s,2Hl andT'25 (s,5H)

(b)

(c)

The compound is non-acidicin nature. Predict the structureof the compound on the basisof the above spectral data. Give a proper explanation for the structureyou have arrived at.

cHE-10

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h = 6.626 r 10-3a Js Ne= 6'022 1023 " Pe= 9'27408 x 10-24Am2 mc=12 mo = 15.9994

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3374 3287 1973 729 612

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P.T.O.

cHE-10

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cHE-10

10

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cHE-10

11

3,000