Dr.

Taylor

Solubility Homework

Chem 112

From Chapter 17 Change Essential Concepts (34,36,38,40,42,46 and 48)

1.

Equal volumes of 1 M BaCl2 and 1 M Na2SO4 are mixed. What effect will the addition of more Na2SO4 solution have on the concentration of Ba2+ remaining in solution? (A) (B) (C) (D) (E) no effect increase the concentration of Ba2+ ions decrease the concentration of Ba2+ ions Ba2+ will remain the same concentration, but be ionized less. There are no Ba2+ ions in solution, so the Na2SO4 has nothing with which to react.

2.

The addition of solid Na2SO4 to an aqueous solution in equilibrium with solid BaSO4 will cause (A) no change in [Ba2+] in solution. (B) more BaSO4 to dissolve. (C) precipitation of more BaSO4. (D) an increase in the Ksp of BaSO4. The solubility of BaCO3 is 7.9 103 g/ L. Calculate the solubility product constant, Ksp. Typical hard water contains about 2.0 103 mol of Ca2+ per liter. Calculate the maximum concentration of fluoride ion which could be present in hard water. Solubility Product Constant, Ksp for CaF2= 4.0 1011 What is the concentration of Ag+ in a 0.010 M KCl solution saturated with AgCl where Ksp for AgCl = 1.81010? Will a precipitate form in a solution containing 3.4 x 10-4 M CrO42- and 4.8 X 10-5 M Ag+ Ksp for Ag2(CrO4) = 1.2 x 10-12

3.

4.

5.

6.

7.

Calculate the molar solubility of AgI in 0.20 M NaI solution given the Ksp for AgI is 8.3 x 10-17

8. The solubility of lead(II) iodide is 0.064 g/100 mL at 20 C. What is the solubility product for lead(II)

iodide?

9. The molar solubility of magnesium carbonate is 1.8 104 mol/L. What is Ksp for this compound?

10. The molar solubility of manganese(II) carbonate is 4.2 106 M. What is Ksp for this compound?

11. The molar solubility of lead(II) iodate in water is 4.0 105 mol/L. Calculate Ksp for lead(II) iodate.

12. The Ksp for silver(I) phosphate is 1.8 1018. Calculate the solubility (g/ mL) of silver(I) phosphate.

13. Calculate the silver ion concentration in a saturated solution of silver(I) sulfate (Ksp = 1.4 105).

14. Calculate the concentration of chloride ions in a saturated lead(II) chloride (Ksp = 2.4 104) solution.

15. Calculate the minimum concentration of Mg2+ that must be added to 0.10 M NaF in order to initiate a precipitate of magnesium fluoride. (For MgF2 , Ksp = 6.9 109.)

16. Calculate the minimum concentration of Cr3+ that must be added to 0.095 M NaF in order to initiate a precipitate of chromium(III) fluoride. (For CrF3 , Ksp = 6.6 1011.)

17.

Will a precipitate of magnesium fluoride form when 300. mL of 1.1 103 M MgCl2 are added to 500. mL of 1.2 103 M NaF? (Ksp (MgF2) = 6.9 109)

18.

Will a precipitate of magnesium fluoride form when 200. mL of 1.9 103 M MgCl2 are added to 300. mL of 1.4 102 M NaF? (Ksp (MgF2) = 6.9 109)

Answers:

1.C 2. C -4 4. 1.4 x10 5. 1.8 x 10-8 6. ppt will not form because Q < Ksp 9. 3.2 108 8. 1.1 108 11. 2.56 1013 12. 6.7 x 10-6 g/ mL 14. 7.8 102 M 15. 6.9 107 M 17. No, Q < Ksp 18. Yes, Q > Ksp

3. 1.6 x 10-9 7. 4.2 x 10-16 M 10. 1.8 1011 13. 3.0 102 M 16. 7.7 108 M