(MSDS #5005367 - RTF Format)

____________________________________________________________________________________________ Date Prepared: March 29, 2001 Supersedes: January 09, 2001 MSDS Number: 05313 ______________________________________________________________________________

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME: PETROLEUM COKE COKE MSDS NUMBER: 05313 PRODUCT CATEGORY: Petroleum coke PRODUCT DESCRIPTION: Petroleum coke from a fluid-bed unit process operation ______________________________________________________________________________ MANUFACTURER/SUPPLIER Canada Imperial Oil Limited An Affiliate of Exxon Mobil Corporation 111 St. Clair Avenue West P.O. Box 4029, Station "A" Toronto, Ontario, Canada M5W 1K3 ______________________________________________________________________________ ** EMERGENCY TELEPHONE NUMBERS: (24 Hours) ** ** (519) 339-2145 ** ______________________________________________________________________________ NON EMERGENCY TELEPHONE NUMBER: (8am-5pm M-F) ** Technical Info: (416) 441-7455 ** ______________________________________________________________________________

2. COMPOSITION/INFORMATION ON INGREDIENTS
This product is not hazardous as defined in 29 CFR1910.1200

CAS NO. OF APPROXIMATE COMPONENTS COMPONENTS CONCENTRATION Coke (petroleum) 64741-79-3 100% All components of this product are listed on the U.S. TSCA inventory. ______________________________________________________________________________

3. HAZARDS IDENTIFICATION
POTENTIAL HEALTH EFFECTS: EYE CONTACT: Particles may scratch eye surfaces or cause mechanical irritation. SKIN CONTACT: Low order of acute toxicity. Frequent or prolonged contact may irritate the skin. INHALATION: Negligible hazard at normal temperatures (up to 38 deg C). Dust may be irritating to the eyes, nose, throat and lungs. INGESTION: Not considered to be a hazard. CHRONIC EFFECTS: Contains petroleum coke. Animal tests indicate that overexposure by inhalation may cause lung effects and/or damage. The relationship of these results to humans has not been fully established. Contains polycyclic aromatic compounds (PAC's). Prolonged and/or repeated skin contact with certain PAC's has been shown to cause skin cancer. Prolonged and/or repeated exposures by inhalation of certain PAC's may also cause cancer of the lung and of other parts of the body. ______________________________________________________________________________

4. FIRST AID MEASURES

EYE CONTACT: This material is an inert solid. If in eye, remove as one would any foreign object. SKIN CONTACT: Flush with large amounts of water. Use soap if available. Remove severely contaminated clothing (including shoes) and launder before reuse. If irritation persists, seek medical attention. INHALATION: If overcome by vapor, remove from exposure and call a physician immediately. If breathing is irregular or has stopped, start resuscitation, administer oxygen, if available.

INGESTION: If ingested, keep at rest and call a physician. Do not induce vomiting unless directed to do so by a medical professional. ______________________________________________________________________________

5. FIRE-FIGHTING MEASURES
AUTOIGNITION TEMPERATURE: NOT AVAILABLE FLAMMABLE OR EXPLOSIVE LIMITS (APPROXIMATE PERCENT BY VOLUME IN AIR) Flammable Limits: LEL: NA UEL: NA HANDLING PRECAUTIONS / GENERAL HAZARDS: Material will not burn. Toxic gases will form upon combustion. EXTINGUISHING MEDIA AND FIRE FIGHTING PROCEDURES: Use water spray to cool fire exposed surface and to protect personnel. Isolate "fuel supply" from fire. SPECIAL PRECAUTIONS: Respiratory and eye protection required for fire fighting personnel. DECOMPOSITION PRODUCTS UNDER FIRE CONDITIONS: Smoke, carbon monoxide, carbon dioxide and traces of oxides of sulphur "EMPTY" CONTAINER WARNING: "Empty" containers retain residue (liquid and/or vapor) and can be dangerous. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND OR EXPOSE SUCH CONTAINERS TO HEAT, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION; THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. Do not attempt to clean since residue is difficult to remove. "Empty" drums should be completely drained, properly bunged and promptly returned to a drum reconditioner. All other containers should be disposed of in an environmentally safe manner and in accordance with governmental regulations. For work on tanks refer to Occupational Safety and Health Administration regulations, ANSI Z49.1, and other governmental and industrial references pertaining to cleaning, repairing, welding, or other contemplated operations. ______________________________________________________________________________

6. ACCIDENTAL RELEASE MEASURES

LAND SPILL: Keep public away. Prevent additional discharge of material, if possible to do so without hazard. Recover spilled material and place in suitable containers for recycle or disposal. Consult an expert on disposal of recovered material. Ensure disposal in

compliance with government requirements and ensure conformity to local disposal regulations. Notify the appropriate authorities immediately. Take all additional action necessary to prevent and remedy the adverse effects of the spill. WATER SPILL: Prevent additional discharge of material, if possible to do so without hazard. Attempt to contain floating material. Skim from surface. Consult an expert on disposal of recovered material. Ensure disposal in compliance with government requirements and ensure conformity to local disposal regulations. Notify the appropriate authorities immediately. Take all additional action necessary to prevent and remedy the adverse effects of the spill. CLEAN WATER ACT / OIL POLLUTION ACT This product may be classified as an oil under Section 311 of the Clean Water Act, and under the Oil Pollution Act. Discharges or spills into or leading to surface waters that cause a sheen must be reported to the National Response Center (1-800-424-8802) ______________________________________________________________________________

7. STORAGE AND HANDLING

ELECTROSTATIC ACCUMULATION HAZARD: No, but use proper grounding procedure STORAGE TEMPERATURE: Not available LOADING/UNLOADING TEMPERATURE: Not available STORAGE/TRANSPORT PRESSURE: Not available LOADING/UNLOADING VISCOCITY: Not available STORAGE AND HANDLING NOTES: Keep containers closed. Handle and open containers with care. Store in a cool, well ventilated place away from incompatible materials. In keeping with good personal hygiene practices, wash hands thoroughly after handling the material. Do not breathe dust or fumes. Minimize dust generation during handling. Do not handle or store near an open flame, sources of heat, or sources of ignition. ______________________________________________________________________________

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

EXPOSURE CONTROLS: Local exhaust ventilation of equipment may be needed to control exposures to dusts and/or fumes below the recommended occupational exposure limits. PERSONAL PROTECTION: In open systems where contact is likely, wear safety goggles, chemicalresistant overalls, and chemically impervious gloves.

Where only incidental contact is likely, wear safety glasses with side shields. No other special precautions are necessary provided skin/eye cont is avoided. Where concentrations in air may exceed the occupational exposure limits given in Section 4 and where engineering, work practices or other means of exposure reduction are not adequate, approved respirators may be necessary to prevent overexposure by inhalation. OCCUPATIONAL EXPOSURE LIMIT: Exxon Recommends: For Delayed or Flexicoke generated coke, an occupational exposure limit of 2 mg/m3 (respirable) is recommended. For Flexicoke generated coke, 0.05 mg/m3 as (V2O5) is recommended. ______________________________________________________________________________

9. PHYSICAL AND CHEMICAL PROPERTIES

The following data are approximate or typical values and should not be used for precise design purposes. BOILING POINT: Not available VAPOR PRESSURE: psi at F ( C) (RVP) EVAPORATION RATE (n-BUTYL ACETATE = 1): PH: NOT AVAILABLE POUR, CONGEALING OR MELTING POINT: Not available SOLUBILITY IN WATER @ 1 ATM 77 F (25 C): Negligible VISCOSITY: APPEARANCE/ODOR: Powdered black dust ______________________________________________________________________________

10. STABILITY AND REACTIVITY

STABILITY: This product is stable. Hazardous polymerization will not occur. INCOMPATIBLE MATERIALS AND CONDITIONS TO AVOID: Strong oxidizing agents

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11. TOXICOLOGICAL INFORMATION

VARIABILITY AMONG INDIVIDUALS Health studies have shown that many petroleum hydrocarbons and synthetic lubricants pose potential human health risks which may vary from person to person. As a precaution, exposure to liquids, vapors, mists or fumes should be minimized. ACUTE TOXICITY DATA: This product is judged to have an acute oral LD50 (rat) greater than 5 g/kg of body weight, and an acute dermal LD50 (rabbit) greater than 3.16 g/kg of body weight. ______________________________________________________________________________

12. ECOLOGICAL INFORMATION

PLEASE CALL THE NON-EMERGENCY TELEPHONE NUMBER ON PAGE 1 IF INFORMATION IS REQUIRED. ______________________________________________________________________________

13. DISPOSAL INFORMATION

PLEASE REFER TO SECTIONS 5, 6, AND 15 FOR DISPOSAL AND REGULATORY INFORMATION. ______________________________________________________________________________

14. TRANSPORT INFORMATION

TRANSPORTATION INCIDENT INFORMATION: For further information relative to spills resulting from transportation incidents, refer to latest Department of Transportation Emergency Response Guidebook for Hazardous Materials Incidents DOT P 5800.3. U.S. DOT HAZARDOUS MATERIALS SHIPPING DESCRIPTION: Transported by highway or rail: Bulk packaging (capacity greater than 119 gallons): NOT REGULATED Non-bulk packaging (capacity less or equal to 119 gallons): NOT REGULATED Transported by air or marine vessel: Bulk and non-bulk packagings: NOT REGULATED

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15. REGULATORY INFORMATION

The following information may be useful in complying with various state and federal laws and regulations under various environmental statutes. REPORTABLE QUANTITY (RQ), EPA REGULATION 40 CFR 302 (CERCLA Section 102): Not applicable THRESHHOLD PLANNING QUANTITY (TPQ), EPA REGULATION 40 CFR 355 (SARA Sections 301-304): No toxic chemical is present greater than 1% or 0.1% (carcinogen). TOXIC CHEMICAL RELEASE REPORTING, EPA REGULATION 40 CFR 372 (SARA Section 313): No toxic chemical is present greater than 1% or 0.1% (carcinogen) HAZARDOUS CHEMICAL REPORTING, EPA REGULATION 40 CFR 370 (SARA Sect. 311-312): EPA HAZARD CLASSIFICATION CODE: Acute Chronic Fire Pressure Reactive Hazard Hazard Hazard Hazard Hazard NNNNN TOXIC SUBSTANCES CONTROL ACT: This product does not contain any TSCA 12b Reportable Chemical Substances ______________________________________________________________________________

16. OTHER INFORMATION

OSHA REQUIRED LABEL INFORMATION: In compliance with hazard and right-to-know requirements, the following OSHA Hazard Warnings should be found on label, bill of lading or invoice accompanying this shipment. Note: Product label may contain non-OSHA related information also. NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) - HAZARD INFORMATION: Health Flammability Reactivity BASIS 1 1 0 Recommended by manufacturer HAZARDOUS MATERIALS IDENTIFICATION SYSTEM (HMIS): Health Flammability Reactivity BASIS 1 1 0 Recommended by manufacturer The information and recommendations contained herein are, to the best of our knowledge and belief, accurate and reliable as of the date issued.

We do not warrant or guarantee their accuracy or reliability and we shall not be liable for any loss or damage arising out of the use thereof. The information and recommendations are offered for the user's consideration and examination, and it is the user's responsibility to satisfy itself that they are suitable and complete for its particular use. If buyer repackages this product, legal counsel should be consulted to insure proper health, safety and other necessary information is included on the container.