SMA NEGERI 3 SEMARANG

SMA3SMG/WKAKA-KIM/QSR/004-00/08

LESSON PLAN School Subject Topic Sub topic Class/ Semester Times Allocated : SMA Negeri 3 Semarang : Chemistry : Chemical Laws and Stoichiometry : Chemical calculation/ Stoichiometry : X/ I : 2 x 45 minutes

A. Standard Competence 2. Comprehend chemical base laws and its appliying in calculation B. Basic Competence 2.2. Prove and communicate the implementation of chemical base laws passed experiment and apply mole concept in finalizing calculation chemistry. C. Indicators 1. Determine restraint reactant of a reaction 2. Calculate the sum of reactant and product in a reaction D. The Purpose of Teaching-Learning 1. Students are able to determine restraint of a reaction 2. Students are able to calculate the sum of reactant and product in a reaction E. Main Material Chemical Calculation F. Resources and Media Susilowati, Endang, 2009, Theory and Application of Chemistry for Grade X of Senior High School and Islamic High School (p133- 141 ), Solo: PT. Tiga Serangkai Pustaka Mandiri Sri Juari Santosa dkk, 2006, Kimia Kelas X Semester I untuk SMA dan MA (p. 94 -99 ), Klaten: Intan Pariwara Setyawan, Fuad, Buku Evaluasi Siswa Kimia Kelas X untuk SMA/MA Semester I, Klaten: Sinar Mandiri Presentation Slide, Students work sheet, LCD, Computer

Internet

G. Teaching Learning Method Exploratory Combination of discourse Problem Based Instruction Structured exercise method H. Learning Activities No Activities

PBKB Value

Time

Method

Resources

Assesment

01. Introduction Discipline Greeting Teacher checks the students attendance Students and teacher brush Up the previous material Students are asked by teacher about their preparation in facing the material 2. Main Activities Toleran a. Moles Concept ce Exploration Students listen to short explanation about limiting reactant Students describe the concept of limiting reactant Elaboration Students get some examples about limiting reactant Students are given a chance by teacher to ask questions Students try to determie the limiting reactant of a reaction and try to calculate the sum of reactant and product reaction Confirmation Some students come forward practice to determine the limiting reactant

10 minutes

Giving informa tion

Observation on students attitude and response

15 minutes

Explorat ory

Group Discussi on

Chemistry Books http://www .chemicalel ements.co m http://www .chemi-istry.org http://baha najarsma.di kmenum.g o.id/index. php?pelid= 1

Observation 100% of students do the analyze

Effective questioning . 90% of students are active in class discussion

3.

Students and teacher corrrerct the right answer Closing Activities Students and teacher Honest conclude the materials Post test Students get homework for next meeting Teacher gives information about the matter for next meeting

5 minutes

Answer question

Literature Observation 100% of students do the task

I. References Susilowati, Endang, 2009, Theory and Application of Chemistry for Grade X of Senior High School and Islamic High School (p145- 168 ), Solo: PT. Tiga Serangkai Pustaka Mandiri Sri Juari Santosa dkk, 2006, Kimia Kelas X Semester I untuk SMA dan MA (p. 102 -115 ), Klaten: Intan Pariwara Setyawan, Fuad, Buku Evaluasi Siswa Kimia Kelas X untuk SMA/MA Semester I, Klaten: Sinar Mandiri http://www.chemicalelements.com http://www.chemi-is-try.org http://bahanajarsma.dikmenum.go.id/index.php?pelid=1 J. Evaluation Evaluation Technique : Written test Instrument : Essay Respond : Minimum Completion Criteria Less than minimum Completion Criteria (76) More than Minimum Completion Criteria (76) K. SUBJECT MATTER Limiting Reagent Compotation of many reactants required or derived products recation conducted based on coeddicient of balanced equation (equivalent). In reacting chemical substances (reaction), we do not always mix appropriate reactants accordig to its reaction coefficient. Occasionally, number of reactants is less or more than needed so they run completelty. The reactant used Up first in a reaction and restricts the running reaction so that no further one called limiting reagent. When this reactant is used Up, no more products can be formed. Other reactants, present in quantities greater than those needed to react with the quantity of the limiting reagent are called excess reagent. For determining limiting reagent,

=76 = Remedial (examination) = Enrichment

available moles for reaction compared with reaction coefficient of balanced equation. After determining the limiting reagent, products weight can be determined.

L. INSTRUMENT Essay! 1. Zinc and sulphur react to produce zinc sulphide that is used to coat inner wall of TV tube. Its equation is : Zn(s) +S(s) ZnS(s) If 12, 0 g of Zn mixed with 6.50 g of S. a. Determine its limiting reagent b. How many ZnS is produced? c. How many grams the restof other reactants are still not reacting on above reaction? 2. At 150C, gold reacts with heat chlorine gas according to the following equation. 2Au(s) +3Cl2(g) 2AuCl3(s) If there any 10.0 gram of gold and 10.0 grams of chlorine in closed vessel and heated until complete reaction, determine: a. The limiting reagent b. Weight (in grams) of resulted gold (III) chloride c. Excessive weight (in grams) of remainder reactant. (Ar Au=197, Cl=35, 5)

Key of Essay No. 01. Key a. Moles of Zn = Moles of S = mol Score 20

b.

Above equation is already balanced so that ratio of moles of Zn:S = 1:1. It means that each moles of Zn will react with 1 mol of S. Because the number of mole of Zn is smaller than S, zinc is the limiting reagent. Thus, the number of mole of sulphur is more than enough and will be remainder, while whole Zn will completely react. Because zinc is the limiting reagent, we use the number of available zinc to compute number of moles of product produced. Based on the above coefficient of balanced equation, the number of moles of Zn = the number of moles of ZnS

15

c.

02.

a.

Because zinc is the limiting reagent, sulphur will be remainder. The number of remainder is difference between available number and utilized number in reacting with Zn. Remainder of S mol = 0.203 0.183 =0.02 mol Remainder sulphur mass is 0.02 mol x 32 g/mol =0. 64 g Tus, after reaction ends remainder of sulfur by 0.64 g is still found. Moles of Au = Moles of Cl = Coefficient ratio Au:Cl2= 2:3 = 0,67: 1 Mole ratio Au ::Cl2 = 0.05 : 0.14 =0.36 : 1 Both above ratios indicate that 0, 67 mol of gold is required to react with 1 mol of chlorine, but only 0, 36 mol of gold is available. Thus , gold is the limiting reagent. All gold will be finished to react, while chlorine is still remainder. Gold (III) chloride weight is counted based on the number of moles of gold as the limiting reagent. Moles of AuCl3 = Weight of AuCl3= 0, 05 mol x 303, 5 g/mol = 15, 2 g produced Number of remainder chlorine = available Cl2 weightreacting Cl2 weight Weight of reacting Cl2= 0.075 mol x 71 g/mol= 5. 3 grams Weight of remainder Cl2= 10.0 g-5.3 g =4.7 g Tuhus, agter reaction ends, the remainder of chlorine gas is 4.7 g Total

15

20

b.

15

c.

15

100

Semarang, Approved by, School Principal of SMAN 3 Semarang

July 2011

Teacher

Drs. HARI WALUYO, M. M NIP. 19640207 198803 1 016

Dra. WIDYA PRAHASTUTI NIP: 19600813 198803 2 005