SAT II: CHEMISTRY TEST

Note : For all questions involving and/or chemical equations, assume that the system is in pure water unless otherwise stated. Part A Directions: Each set of lettered choices below refers to the numbered questions or statements immediately following it. Select the one lettered choice that best answers each question or best fits each statement, and then fill in the corresponding oval on the answer sheet. A choice may be used once, more than once, or not at all in each set

DIAGNOSTIC TEST
Questions 1 thru 5 are based on the following choices.

TEST # Diagnostic # of correct answers: _____ # of incorrect answers: _____ # of blank answers: _____

A. Bromine B. Chlorine C. Cesium D. Fluorine E. Manganese

SCORE: _________
6. Which of the following species has highest second ionization energy? A. Na B. Na+ C. K D. K+ E. Ne

1. the most electronegative element 2. reacts vigorously with water at room temperature 3. element with largest atomic radius 4. the d-block element 5. liquid element at room temperature

7. Which of the following readily soluble in water? A. NH4Cl B. CaCO3 C. CCl4 D. CHCl3 E. I2 8. Which of the following molecules is polar? A. SeF6 B. PF5 C. TeF4 D. BF3 E. all of the above

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CHEMISTRY TEST- Continued

Questions 9 thru 13 refer to the following molecules. Questions 14 thru 18 refer to the following choices.

A. B. C. D. E.

C2H2 C2H4 C4H10 C6H6 C6H12O6

A. 0.1 m NaCN B. 0.1 m C6H12O6 C. 0.1 m AlCl3 D. 0.1 m HCl E. 0.1 m BaCl2 14. has a pH = 1 15. has a pH > 7

9. an aromatic compound 16. has the lowest freezing point 10. its C atoms are sp hybridized 17. does not conduct electricity 11. has only single bonds 18. precipitates sulfate ions 12. a water soluble solid at room T 13. an alkane

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CHEMISTRY TEST- Continued 19. Which of the following correctly completes the below reaction?
2 1 4 H X 2 He 01n energy

23. Which of the following molecules can NOT exist? A. OF2 B. P2O3 C. N2O D. Ne2 E. KrF2

A. deuterium B. neutron C. proton D. tritium E. electron

24. Which of the following homogeneous mixture? A. HCl (aq) B. Na2CO3 (s) C. CO2 (g) D. Cgraphite (s) E. Granite (s)

is

an

20. Which one of the following particles has no mass and no charge? A. alpha B. beta C. gamma D. positron E. proton

25. What is the mole fraction of NaCl in an 10% (w/w) saline solution? 21. Which anion has a -3 charge? A. sulfite B. sulfate C. nitrite D. nitrate E. phosphate A. 0.027 B. 0.171 C. 6.170 D. 6.340 E. none of these

22. The oxidation state of O is the highest in A. O2 B. O3 C. Na2O D. H2O2 E. OF2

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CHEMISTRY TEST- Continued

PLEASE GO TO THE ANSWER SHEET AND ANSWER QUESTIONS 101 - 115. Part B Directions: Each question below consists of two statements, I in the left column and II in the right column. For each question, determine whether the statement I is true or false and whether statement II is true or false and fill the corresponding T or F ovals on your answers sheet. Fill in oval CE only if statement II is a correct explanation of statement I. EXAMPLE:

HF is a weak acid
SAMPLE ANSWER:

BECAUSE

F is the most electronegative element

Iff f
EX

IIfff

CE

I 101. KMnO4 has a deep purple color 102. BF3 is a Lewis acid 103. SF6 is a nonpolar molecule BECAUSE BECAUSE BECAUSE

II Mn has +3 oxidation state in KMnO4. the central atom B has only three bonding electrons. S atom is sp3d2 hybridized.

104. At room temperature, Cl2 is a gas, however, Br2 is a liquid

BECAUSE

Cl2 and Br2 are diatomic elements.

both

105. SiO2 is a solid and CO2 is gaseous

BECAUSE

SiO2 is network covalent and CO2 is molecular covalent compound Na is smaller than K.

106. NaCl has a higher melting point than KCl

BECAUSE

I 107. Molten KCl conducts electricity 108. Warmer air rises 109. The b.p. of water is 202 oF which is surprisingly high for such a small molecule BECAUSE BECAUSE BECAUSE

II KCl has metallic bonding. the density of gases decreases with increasing T. during boiling, covalent bonds between O and H are broken. N2 violates the octet rule.

110. The bond length in N2 is shorter than NO3-

BECAUSE

111. Under same T and P CO2 is heavier than CO

BECAUSE

CO2 is nonpolar and CO is polar.

112. Li is much more reactive than Au

BECAUSE

Li can easily lose valence electrons.

its

113. Magnesium has lower melting point than Al 114. The activation energy of the forward reaction must be equal to the activation energy of the reverse reaction

BECAUSE

Al has one unpaired electron on its 3d orbital. at equilibrium the rates of the forward and reverse reactions are equal.

BECAUSE

115. 1,1-dibromoethane and 1,2-dibromo ethane are constitutional isomers

BECAUSE

both compounds one double bond.

contain

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CHEMISTRY TEST- Continued

26. When the following reaction is balanced using smallest whole-number coefficients, the coefficient of O2 is __ C3H4 + ___ O2 ___ CO2 + ___ H2O A. 1 B. 2 C. 3 D. 4 E. 5 27. The molar concentration of the chloride ions in 0.2 M AlCl3 is A. 0.02 B. 0.06 C. 0.2 D. 0.3 E. 0.6 30. Which of the following salt is NOT soluble in water? A. Na2CO3 B. NH4NO3 C. CH3COOK D. BaSO4 E. Ca(ClO4)2

Questions 31 and 33 are related.

A. H2CO3 B. HCl C. HNO3 D. H2SO4 E. H3PO4 31. is the weakest acid. 32. is a strong binary acid.

28. Which of the following solution is colored? A. Na2CO3 B. Li3PO4 C. Na2HPO4 D. BaCl2 E. CoCl2

33. is a strong diprotic acid.

29. 2.87 g of ZnSO4.7H2O (MW = 287g/mol) is dissolved in distilled water in order to prepare 100 mL aqueous solution. What is the molarity of this solution? A. 0.010 B. 0.033 C. 0.100 D. 1.000 E. 2.870
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CHEMISTRY TEST- Continued

Questions 34 and 35 are related.

36. Consider the following figure.

The line equation of a voltaic cell is given below. - Zn | Zn2+ || Au3+ | Au + The standard reduction potentials are: Eo Zn2+/Zn = - 0.76 V Eo Au3+/Au = +1.52 V 34. The double parallel line represents a A. semi-permeable membrane B. metal wire connecting two electrodes C. salt bridge D. redox reaction E. zero-potential region 35. The Eocell for this voltaic system is A. -0.76 V B. +1.52 V C. -0.24 V D. -2.28 V E. +2.28 V V=2L PH2 = 5 atm V=2L PO2 = 15 atm

Initially the valve is closed and each container is occupied by two different gases. When the valve is turned on the gases start to diffuse into each other. What is the partial pressure of the H2 in the final mixture? A. 1.0 atm B. 2.5 atm C. 5.0 atm D. 10.0 atm E. 20.0 atm 37. How many mole of CO2 at STP, can be obtained by burning 3.01 x 1023 atoms of C? A. 0.1 B. 0.2 C. 0.5 D. 1.0 E. 2.0 38. Which of the following gas will occupy the largest volume at STP? A. 1.0 g of hydrogen B. 16.0 g of oxygen C. 4.0 g of helium D. 10.0 g of neon E. 18.0 g of argon

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39. Which gas has the heaviest density at 127 oC and 1.1 atm of pressure? A. B. C. D. E. CH4 CO2 C2H4 SO2 SO3

42. A buffer of pH < 7 can be prepared using which of the following BronstedLowry conjugate acid-base pair? A. H2CO3/CO32B. H2PO4-/PO43C. H2SO4/HSO4D. H2PO4-/HPO42E. HC2H3O2/C2H3O2-

40. According to VSPER theory, which of the following molecule has a trigonal pyramidal shape? I. NH3 II. PCl3 III. H2O A. B. C. D. E. only I only II only III I and II I, II and III 43. The solution with the highest boiling point is A. 0.1 m NaCl B. 0.1 m C2H5OH C. 0.2 m CaCl2 D. 0.4 m AlCl3 E. 1.0 m NaCl

41. When dissolved in pure water, it will give an acidic aqueous solution A. B. C. D. E. NaCl KCN Al(NO3)3 Ca(OH)2 RbF

44. Which of the following labware is NOT needed during the titration of an acidified H2C2O4 solution with 0.1 M KMnO4 solution? A. Erlenmeyer B. Burette C. Indicator D. Heater E. C and D 45. What is the correct name for Cu2O? A. copper(II) oxide B. copper(I) oxide C. dicopper monoxide D. copper oxide E. copper monoxide

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CHEMISTRY TEST- Continued

46. When NaOH dissolves in water the temperature of the solution will increase. Which of the following choice best describes this observation? A. B. C. D. E. H S G + + + + + + + 50. The triple point is represented by letter 47. For the heterogeneous equilibrium represented by the following equation can be correctly given by the following expression: CaCO3 (s) CaO (s) + CO2 (g) A. K = [CaO]/[CaCO3] B. K = [CO2]/[CaCO3][CaO] C. K = [CaO]+[CO2]/[CaCO3] D. K = [CaCO3]/[CaO] E. K = [CO2] A. A B. B C. C D. D E. E
Questions 50 -52 refer to waters phase diagram (not to scale).

51. At point B, which phases are at equilibrium? A. Solid and liquid B. Solid and gas C. liquid and gas D. solid, liquid and gas E. none of these

48. The easiest method to separate water from acetone is A. Filtration B. Chromatography C. Fractional distillation D. Evaporation E. Combustion

52. The line segment BC has a negative slope. The best explanation for this observation is that A. water is liquid at room T B. the density of the ice is lower than the density of the liquid water C. ice sublimes D. water has very high supercritical pressure E. water is molecular compound

49. What is the oxidation state of P in K3PO4? A. -3 B. +1 C. +3 D. +4 E. +5

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CHEMISTRY TEST- Continued

53. Based on the figure given below, the activation energy of the reverse reaction is 56. A solution containing 10.0 g of NaOH in 250.0 mL has a pH of A. 1 B. 2 C. 12 D. 13 E. 14

A. 10 B. 30 C. 120 D. 150 E. 160 54. Which of the following is a ketone? A. CH3-OH B. CH3-O-CH3 C. CH3-CHO D. CH3-COOH E. CH3-CO-CH3 55. Two amino acids are joined together with a A. coordinate covalent bond B. pure covalent bond C. peptide bond D. network covalent bond E. amphoteric bond

57. How many mL of 0.50 M of NaOH is needed in order to neutralize 100.0 mL of 0.5 mL H2SO4 solution? A. 50 B. 100 C. 150 D. 200 E. 250

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CHEMISTRY TEST- Continued

58. HPO42- + H2O PO43- + H3O+ 61. What is the empirical formula of a compound that contains 0.69 g of Na, 0.48 g of S and 0.72 g of O? A. NaSO B. Na2SO3 C. Na2SO4 D. Na2S2O3 E. Na2S2O8

In the above reaction, HPO42- acts as a A. Bronsted acid B. Bronsted base C. Lewis acid D. Lewis base E. none of the above

59.

79 34

Se 2 ion has
A. 34p, 34e and 79 n B. 34p, 36e and 79 n C. 36p, 34e and 45 n D. 36p, 36e and 79 n E. 34p, 36e and 45 n

62. Which of the following electron configuration has four unpaired electrons? A. Sc3+ B. Fe C. Fe2+ D. Fe3+ E. Mn5+ 63. As series of experiments are performed with an unknown colorless aqueous solution? I. A gas evolution is observed when the unknown solution reacted with dilute HCl solution. II. Bunsen burner flame is colored into green-yellow. Based on the above evidences the unknown is a solution of A. CaCl2 B. CaCO3 C. KMnO4 D. CuSO4 E. BaCO3

60.

2A (g) B (g)

The above reaction is an endothermic reaction. Which of the following change will increase the concentration of B? A. an increase in [A] B. an increase in [B] C. a decrease in T D. a decrease in P E. a catalyst

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CHEMISTRY TEST- Continued

64. What is density of CO2 at a pressure of 8.2 atm and a temperature of 167 oC? R = 0.082 L.atm/mol.K A. 0.82 g/L B. 1.12 g/L C. 2.24 g/L D. 5.60g/L E. 10.0 g/L
Questions 67 and 68 are related. ___ ClO3 ___ ClO4 + ___ Cl
-

67. The above equation represents a ______ reaction. A. precipitation B. single replacement C. double replacement D. combustion E. oxidation-reduction 68. When the above reaction is balanced with smallest whole-number coefficients, the coefficient of ClO3- will be A. 1 B. 2 C. 3 D. 4 E. 5 69. If the equilibrium constant for the 2A + B 4C is K, what will be reaction the equilibrium constant for 2C A + B ? A. K B. K2 C. 1/K D. 1/ K E. K/2 70. What is the approximate pH of 1M of a weak acid represented by HA? Ka = 1.6x10-11 A. 2.5 B. 4.5 C. 5.5 D. 6.5 E. 12.5

65. When dissolved in water, it will give an acidic solution. A. CaO B. NO2 C. Li2O D. BaO E. Na2O

66. How many grams of Zn will react with 100.0 mL 0.1 M H2SO4 solution? A. 0.65 g B. 1.00 g C. 3.25 g D. 6.50 g E. 65.0 g

END OF THE TEST

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ANSWER SHEET (1) A 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. 14. 15. 16. 17. 18. 19. 20. B C D E 21. 22. 23. 24. 25. 26. 27. 28. 29. 30. 31. 32. 33. 34. 35. 36. 37. 38. 39. 40. A B C D E

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ANSWER SHEET (2) A 41. 42. 43. 44. 45. 46. 47. 48. 49. 50. 51. 52. 53. 54. 55. 56. 57. 58. 59. 60. 101. 102. 103. 104. 105. 106. 107. 108. 109. 110. T F T F CE B C D E 61. 62. 63. 64. 65. 66. 67. 68. 69. 70. A B C D E

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ANSWER SHEET(3) 111. 112. 113. 114. 115.

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