SECTION A “Answer ALL qestons, Write your newer ine spaces provid. L @ o @ ow -A-CHEM 1-2 ‘lememal oxy exis in the atmosphere in vo foms,O; ad ©, Draw the eloczonie structure of >, “The tond lengthen Os nd Ore 0.121 nm and 0128 am epectvely. Explain why ‘hese bond lenis are difient. ‘Suge wy Os mor sluble in wae thn mars) L w o Conjugate cit L_] -HsPO.an ois in three stages sve HP a), HPO? and POL). ‘Some ofthe above phayphorus-cootining species ae ampboeic. Complete the tbl below by isting one of the spotercspeten, is canst acd cd conju base. Aphotnre species ® w At 298 K, he dsociton constants, Ky of 1,904), HPO aan HPO) we ‘flo: oo a HPO(aq)+ HOM = HOY) +H4POLIe—) 19x10 HPO, (09) HO) = 1h0'(e) +HPOS (0g) 62x10% HPO,"(aq)* HHO) = HLO'Ga) + POs) sano” plan wy the discon constant decries wih he soccesive less of drogen fone Sketch the expec pH ron curve wen HPO) rated with NaOH, mis)® 0 © 2o03-AL-CHEM 14 Based on te information piven below, sketch + lbelled phase diag for carbon ‘ede triplepoit: 217 Kand 5.1 am frou pont: 306Kand 729 ean ‘lla earton dioxide fe dene tan gl carbon oxide | fie extinguisher comaie liga eabun dx. Upon opening tbe noe, ome ‘ie pomdar, which slime eps observed. Fp ths phenomcaon. 2 ® o ® ns. AL-CHEM 1s “Te following mechanism wae proposed forthe resto of Ha) with (0 sive HK), Sept: Yi) = 24) (a) ep; Hy) +21) + 21K) (ow ‘Wt an expression for the uum consany, Ke, for Sp 1 ‘sed om thls mechanism, show hat the raction of Hg) with 1) fret oner wi respect oH and to 1. wt)Ca* | ° CI (©) rice ioe, C0, canbe prep arising feline: | PH 3. (© Prinecn ar align in comple oes. ro ea 2AgOIO(0)* CU) > AACHEN + 20040) +04) A= HOKE Ge Ciena he sd enty ings of fomon 298K of AaCI) and ABC) ike fie DOM mat wa -127Himel" regen case SH Fay (C1). He, | enero te sty O(n smd oto aN eee : (A scoot on complex she ma (F491) tere ON ty cn (Whats ae esdcion sn ton in his complex? | | | | | { (1) Draw ail possible three-dimensional structures of this complex. | mt) | (©) Ponusum doa), KEIO wd a ewok ad mach ad Suet ing an i ‘a ew ROO) cs pop fot seo ican pied (main 200-ALCHEN 1-7 ‘nos AL-CHHM 16