1 A solution is made by dissolving 40.0 g of potassium chloride in 225 g of water.

What
is the mass percent of potassium chloride?
11.1 %
12.2 %
14.7 %
15.1 %
17.8 %
2 What is the mole fraction of potassium chloride in the above solution?
.0336
.0412
.0498
.0513

3 What is the molality of the above solution ?

.995 m
1.87 m
2.39 m
3.45 m
4.98 m
4 Hydrochloric acid has a density of 1.19 g/cm3 and is 38.0 % by mass. What is the
molality of this solution?
14.3 m
16.7 m
21.5 m
25.2 m

5 What is the molarity of the above HCl solution?

12.4 M
14.2 M
16.8 M
18.2 M
19.5 M
6 What is the mole fraction of the HCl in the above solution?
.122
.175
.217
.232
.264
7 A 250.0 mL solution is made by adding 225.0 mL of toluene (density =0.867 g/mL)
and 25.0 mL of benzene (density = .874 g/mL). Calculate the mass percent of benzene
in the solution.
9.88 %
10.1 %
10.3%
10.5 %
8 Calculate the molality of the above solution (treat benzene (C6H6) as the solute).
1.15 m
1.23 m
1.44 m
1.57 m

9 The solubility of potassium chloride at 20 ºC is 34.0 g per 100.0 g of water. The

density of the solution is 1.17g/cm3. What is the molality of this solution?
3.45 m
4.56 m
5.04 m
5.67 m

10 What is the mole fraction of potassium chloride in the above solution?

.0589
.0602
.0648
.0759

11 What is the molarity of the above solution?

3.88 M
3.97 M
4.02 M
4.20 M

12 What would the molality be of a solution made by mixing equal volumes of 30.0% (by
mass) of sulfuric acid (density = 1.218 g/cm3) and 70.0% (by mass) sulfuric acid
(density = 1.610 g/cm3)?
7.99 m
8.71 m
9.88 m
11.5 m

13 If the resulting density of the above solution is 1.414 g/cm3, what is the molarity of the
solution?
7.65 M
8.82 M
9.20 M
10.4 M

14 The lattice energy of sodium chloride is -184 kcal/mol. What amount of energy is
needed (per mole) to cause the following reaction to occur?

NaCl(s) --> Na+(g) + Cl-(g)

366 kcal
184 kcal
91.5 kcal
15 Given the information from the previous problem and the hydration energy of
sodium chloride (-183 kcal/mole) what would the heat of solution be for sodium
chloride?
1 kcal
367 kcal
282 kcal
none of the above

16 The heat of solution for cesium iodide is 33 kJ/mol and the heat of hydration is -571
kJ/mol. What is the lattice energy for cesium iodide?
-604 kJ/mol
-538 kJ/mol
-234 kJ/mol
-186 kJ/mol

17 The lattice energy of cesium hydroxide is -724 kJ/mol. The heat of hydration is -796
kJ/mol. What is the heat of solution of cesium hydroxide?
140 kJ/mol
120 kJ/mol
-88 kJ/mol
-72 kJ/mol

18 A solution is made by dissolving 40.0 g of glucose (C6H12O6) in 220. g of water at 25

ºC. Calculate the vapor pressure of this solution. (Vapor pressure of pure water at 25
ºC = 23.8 torr).
23.4 torr
23.5 torr
23.6 torr
23.7 torr

19 A solution is made by dissolving 120.0 g of potassium chloride in 150. g of water at 25

ºC. Calculate the vapor pressure of this solution. (Vapor pressure of pure water at 25
ºC = 23.8 torr).
11.5 torr
13.6 torr
16.2 torr
17.2 torr

20 A solution is made by mixing 25.0 g of methanol (CH3OH) and 15.0 grams of

propanol (C3H7OH). The vapor pressures of methanol and propanol are 303 torr and
44.6 torr, respectively, at 40.ºC. Assuming ideal behavior, what is the total pressure of
the solution ?
220. torr
240. torr
260. torr
280. torr

21 What is the mole fraction of the methanol in the vapor in the above problem?
 .767
.823
.885
.954

22 What is the mole fraction of methanol in a liquid solution of methanol and propanol
at 40 ºC if the pressure of the solution is 175 torr? See above for vapor pressures.
.462
.505
.587
.613

23 What is the mole fraction of the propanol in the vapor of the solution above?
.126
.255
.289
.319

24 Calculate the freezing point of an aqueous solution of ethylene glycol (molar mass =
62.07 g/mol) which is 65.0% by mass. (Kf = 1.86 ºC/m)
-55.8 ºC
-43.5 ºC
-32.8 ºC
-12.4 ºC

25 Calculate the boiling point of an aqueous solution containing 12.7 grams of sodium
chloride in 50.0g of water. (Kb =.512 ºC/m)
103.51 ºC
104.44 ºC
105.21 ºC
105.89 ºC

26 If 12.0 g of a nonvolatile molecular solute is dissolved in 400.0 grams of water, the

freezing point falls to -0.138 ºC. What is the molar mass of this solute?
125 g/mole
256 g/mole
388 g/mol
404 g/mole
465 g/mol
27 What is the osmotic pressure of a solution containing 28.0 g of sucrose (C12H22O11) in
enough water to form 125 mL of solution at 25 ºC.
16.0 atm
18.8 atm
19.1 atm
20.4 atm

28 What is the molar mass of a substance which creates an osmotic pressure of 828 torr
when 15.0 g of the substance is dissolved in 400.0 mL of water at 50.0 ºC?
 424 g/mol
568 g/mol
739 g/mol
888 g/mol
915 g/mol
29 What is the expected van't Hoff factor for magnesium chloride?
1
2
3
4
5