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MMA is;
Colorless and transparent liquid. Its polymer is hard and transparent resin like glass and has excellent weatherability, transparency and high gloss. Methyl H H C H Acrylate H C H C C O H C H H O Metha
Mixed C 44 Mixed C
Raffinate -- 1 Raffinate 1 MeOH MeOH MTBE Sythesis MTBE Sythesis MTBE MTBE
H
MMA MMA
PMMA is;
PMMA(PolyMethylMethAcrylate) is an acrylic resin, which is made from MMA(MethylMethAcrylate) monomer mainly. Now LG PMMAs are manufactured through co-polymerization of MMA with MA or MMA with EA. PMMA is widely used for its high colorability, elegant appearance, good weatherability as well as excellent transmission of 93% among many other resins.
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Thermoplastics Liner polymer Amorphous Excellent light transmission Resistance to weathering High surface hardness Scratch resistance Excellent colorability and elegant appearance Heat resistance High rigidity Chemical resistance Recyclable
H H C H O H C H H n H C C O C H
Polymerization Polymerization
C H H n
Bead Bead
PMMA PMMA
Extrusion Extrusion
Pellet Pellet
PMMA GRADES
PROPERTIES PROPERTIES
HEAT RESISTANCE HEAT RESISTANCE GENERAL-PURPOSE, GENERAL-PURPOSE, HIGH IMPACT & WHITE HIGH IMPACT & WHITE FLUIDITY FLUIDITY HIGH FLUIDITY HIGH FLUIDITY
HIGH IMPACT HIGH IMPACT HIGH IMPACT & FLUIDITY HIGH IMPACT & FLUIDITY
MOLECULAR WEIGHT
MOLECULAR WEIGHT
IMPACT STREGHTH
CO-MONOMER
CO-MONOMER
IMPACT STREGHTH
CO-MONOMER
FLUIDITY
MOLECULAR WEIGHT
Types
Grades IH830
Properties Heat Resistance General-Purpose Good Fluidity Excellent Fluidity Heat Resistance General-Purpose MFI MFI
EH910
Fluidity Index
Fluidity Index
910 920 Heat Deflection Temperature 830 840 850 870 910 920 VICAT Softening Point 910 920 830 840 850 870
Types HI835H, HI835M, HI835S HI855H, HI855M, HI855S, HI855HX Physical Transparent Properties PMMA(855HX) ABS Remarks Transmission 90 1.2 2.45 Impact Strength 6 Haze Fluidity 88 2.0 7.3 11
HI835 M
Impact Strength
HI855 M
HX
HI855 M
HX
HX
VICAT Softening Point HI855 M HI835 M S S H H HX HI855 M S S H HX Impact Strength M M S S H H HX HI835 HI855 M S H HX M S H HI855 HI835 H Fluidity Index HI835 M Heat Deflection Temperature
BEAD GRADES
We produce acryl powder for artificial marbles, acrylic coatings, acrylic adhesives and paints on the basis of unique polymerization technology. BASIC BEAD GRADES LG Grades IH830B IG840B IF850B IF870B EH910B EG920B Methylmethacrylate Copolymer Coatings Coatings Coatings Artificial Marbles, Coatings, Adhesives Coatings, Adhesives Basis Monomers
LG Basis Remarks Grades Monomers Methylmethacrylate BN490B Ink Binders, Coatings Copolymer PVC Leathers, Coating BN630B n -buthylmethacrylate /mma polymer Methylmethacrylate PVC Leathers, Coating BN890B Copolymer
490B
890B
Tg
Tg
910B
920B
Tg 490B
630B
890B
Bead Applications
Artificial Marbles
. Beads specifically IH830B and EH910B and MMA are applied to artificial marbles.
PVC Coatings
. PMMA is easy to process. It is applied to PVC coatings and solidifying agents, while urethane resin is good to the touch but hard to process.
Others
. Paints, Inks, Sheet Costings and so on
VN (Viscosity Number)
- Melt PMMA in chloroform solvent and measure relative viscosity of the solution. - Beads with higher VN have larger molecular weight. For instance, a bead with VN of 52-74 has 80-120 thousand molecular weight. Moisture Contents - Measuring Device : karl-Fischer Tg (Glass Transition Temperature) - Measuring Device : DSC - Tg represents the elasticity of a polymer and it is equal to its softening temperature. Acidity value - Melt PMMA in acetone and titrate it with KOH solution. ( Unit : mgKOH/g ) MFI (Melt Flow Index) - MFI represents the fluidity of polymer. To get MFI, melt PMMA at 230 , and give a force of 3.8kg on the molten PMMA for ten minutes. - Bead with higher MFI has better fluidity.
Characteristics of PMMA
LIGHT TRANSMISSION
(It transmits 93% of visible ray and reflects the rest of it. Thus it hardly absorb visible ray.)
Transmission %
LG PMMA UV Absorption Types 100% at 280nm (UVA-280) 100% at 360nm (UVA-360) 100% at 390nm (UVA-390) Applications
IF850 and IF870 for internal application IH830 and IG840 for external application IH830U for sunglasses
AMECA Test period (3yrs) : `89.4 ~ 92.4 Test places : Florida (hot and humid), Arizona (hot and dry) Grade/ Color - Grade : 4 types (IH830 etc.) - Color : 19 types (Clear 2, Amber 7 and Red 10)
Weatherability
Haze(%) 30 25 20 15 10 5 0 500 1000 1500 Time of Exposure(hr) Acrylic Rubber PMMA 2000 PC
PMMA has outstanding weatherability among the plastic resins Haze test results after two thousand hours xposure show that the haze for PMMA e
makes an steady and slight increase, while that for PC increases sharply on and after fifteen hundreds hours.
Weatherability
Y.I 6.0 5.0 4.0 Acrylic Rubber 3.0 2.0 1.0 0 500 1000 1500 2000 PMMA PC
Time of Exposure(hr)
PMMA having low initial yellow index has excellent transparency. It hardly change despite of long-time exposure over 2000 hours, while PC makes sharp change in the beginning and shows relatively slight change afterwards.
Ease to Process - Such machine works as cutting, sewing, carving and grinding are easy to be done.
-Good to the adhesives, paints and dyestuffs.
- No relation to any of environmental hormone - food containers, artificial teeth, dental filling materials, artificial eyes and artificial bones
-Environmental Hormone: chemical substances exposed to the polluted environment come into the body and act like hormones. They are called environmental hormone or endocrine disrupter scientifically. -Influences to the body; sperm count decrease, deformation of sexual organs and hormone-related cancer increase.
Polyvinylalcohol, Cellophane Celluros Resin, Poly Vinyl Acetic Acid, Poly Vinyl Formalin, Nylon PVC, Styrene Copolymer, PMMA, PC, PET, Phenolic Resin, Urea Resin, Melanin, PA PE, PP, PolyChloroethylene, PS...
* The molecular structure of resin with moisture content of 0.1 ~ 1% includes ester combination like PC,PET and PMMA, and ether combination like polyacetal, urea resin and phenol resin. * Thus PMMA absorbs moisture easily because its molecular structure has ester combination and it is amorphous resin.
30,80%RH
23,80%RH
60 40 20
(20 is fixed)
92% RH
60% RH 40% RH
10
15
20
25
30
Days
35
Control of Moisture Content During the Molding Safe and precise molding requires moisture content
control. Moisture absorption and the quality of molding product
Silver streaks and blowholes may appear. Lower melt viscosity may cause; -over filling, defective molding release and defective size -deterioration of mechanical physical property Environmental causes Humidity difference between rainy season and winter time Temperature difference between summer time and winter time Humidity difference by weather Temperature difference between the day and night time Requiring time to final use after initial exposure
Necessity of Dehumidifying Dryer Reasons to bring blowholes and silver streaks occupying most
of defects in PMMA in summer time are as follows; . 80% of defective products is caused by moisture content . Thermal degradation of resin due to poor heat stability and activation is one of the minor causes. Limit Moisture Absorption is 0.08~0.05% for general molding but it is estimated to be under 0.03~0.01% for a safe and precise m olding of specific product. ex) Especially, to control moisture content is important to the long-sized product as SANTAMO garnish panel. s
Moisture Absorption summer time, as hot-air dryer using hot and humid air removes In
moisture of the pellet surface only, dehumidifying dryer using air below -40 is required to the safe and precise molding. ex) In case of PC While drying with hot-air dryer for 4 hours reduces the moisture content from 0.18% to 0.018%, drying with dehumidifying dryer reduces it from 0.18% to 0.006%. Note Recently, Japan attaches importance to control moisture content of hydrolytic resins as well as resins with high moisture absorption like PMMA.
Light Transmission of Various Materials (ASTM D1003) Light Transmission of Various Materials (ASTM D1003)
PMMA
PS
SAN
PC
Rigid PVC
PMMA has the highest light transmission among the plastics, especially its light transmission is superior to glass. Light transmission of PMMA is 93% between 380 nm ~ 780 nm but that of PC is only 87% between 480 nm ~ 680 nm.
PMMA
85 ~ 105
PS
65~80
AS
80~90
PC 10 /
75~85 M Scale
PMMA PS AS PC PVC
PMMA
910~1330
PS
560~980
AS
980~1330
PC
950 /
Workability
4 3 2 1
Heat resistance
PMMA PMMA PC PC PVC PVC PS PS SAN SAN
Weatherability
Rigidity
High impact
AMECA Standard
UL : Underwriters Laboratories
CSA : Canada Standard Association JHPC : Japan High Polymer Center AMECA : Automotive Manufactureres Equipment Compliance Agency