Professional Documents
Culture Documents
Section A
1. (a) 1s2 2s2 2p6 3s1 5 orbitals 2s and 2p Sodium-24 is radioactive/has short half-life/decay/disintegrate xx x x Cl x (i) x xx xx x x x Cl x Cl x x xx Te xx xx xx x or x x Cl Cl x Te Cl x x xx xx xx x x Cl x x x x Cl x xx x xx (i) (ii) (iii) (iv) xx x x Cl x x [1] [1] [1] [1]
(b)
[1]
(ii)
x Cl x xx
xx x Cl x xx xx
Te
or
x x Cl x x xx
(iii)
polar molecule
[1]
(c)
bond between sp(C) and sp(N) orbitals [1] -bond between px(C) and px(N) orbitals -bond between py(C) and py(N) orbitals [1] [1]
10 marks
2 (a)(i)
[1] [1]
[1]
(b) (i) Aluminium fluoride is more ionic than aluminium chloride. /Aluminium chloride is predominantly covalent whereas, aluminium fluoride is ionic (ii) - F- ion is smaller than Cl- ion. - Therefore is more difficult of be polarized by the Al3+ ion. Hence, AlF3 has less covalent character. (iii)
[1]
3+ (iv) - Al ion has high charge density
[1] [1]
/ Aluminium atom has empty orbitals/(does not have octet arrangement) 3+ - /Al ion is able to attract lone pair electrons from the water to form coordinate bonds / AlCl3 is easlily hydrolysed by water - AlCl3 + 3H2O Al(OH)3 3+ / AlCl3 + 6H2O Al(H2O)6 + 3Cl
[1] 10
Total
3 (a)
(ii) t1/2 = ln 2 k OR k = 0.693 35.0 = 0.0198 s-1 (iii) ln C = -kt + ln C0 ln 5 = - 0.0198t + ln 100 or t = 151.3 s (i) The equilibrium is shifted to the right / (forward) because forward reaction results in a increase in the number of moles gas particles The amount of CO in the mixture is increased (ii) PCO = PH2 = 183 kPa Kp = PH2 x PCO PH2O = ( 183kPa ) x (183 kPa) (90.0 kPa) = 372 kPa
[1] [1]
..2
[1] [1]
..2
[1] [1]
(b)
..2
[1] [1]
[1]
..3
10
3 4(a)(i)
CH3COOH < HO-
COOH <
COOH <
O2N-
Correct comparison: Aliphatic < aromatic Among the aromatic acids (ii) CH3COOH (iii) NO2 is an electron withrawing group. NO2 increases the acidity / The molecule dissociates more easily to produce H+ ions / The O-H bond is more easily broken (b)(i) Condensation polymerisation (ii) Oor OO || C n O || C O || C
...2
O-
(iii)
Ester or
O || CO
+
(c)(i)
Section B
5 (a) (i)
Vapour pressure
[1] [1] [1] ...3 [1] [1] [1] [1] [1] [1] [1] [1]
- The mixture shows positive deviation - The force of attraction between the ethanol molecules and the water molecules is stronger - than the force between the molecules of pure substances - The vapour pressure of the mixture is higher than ideal
...4
(iii) A mixture (solution) with a constant boiling point The equilibrium vapour has the same composition as the liquid (iv) 1 st distillate : (Azeotropic mixture), 95-96 % ethanol, temperature 76 oC 2 nd distillate: Pure water, temperature 100 oC (b) (i)
(ii)
...2
...2 1
1
2H2O + 2e H2 + OHTo prevent the OH ions from entering the anode compartment + / To allow the Na ions to flow into the cathode compartment /To allow the ions to flow through Sodium chlorate(I) Cl2 + NaOH NaClO + NaCl + H2O [1] [1]
-
(iii)
...2 15
6. 2
3 2
3
(iv) phenolphthalein
15 marks
7(a)
6 [ Fe3+ + e Fe2+ E = + 0.77 V ; I2 + e I- E = + 0.54 V] (i) 2Fe3+ + 2e 2Fe2+ E = + 0.77 V 2I I2 + 2e E = - 0.54 V 2I- + 2Fe3+ I2 + 2Fe2+ Ecell = + 0.23 V Since Ecell is positive, it is a spontaneous reaction / reaction will takes place. [Ag+ + e Ag E = + 0.80 V Fe3+ + 3e Fe E = 0.04 V] (ii) 3Ag 3Ag+ + 3e E = - 0.80 V } 3+ Fe + 3e Fe E = - 0.04 V } Ecell = - 0.84 V } Since Ecell is negative, it is a non-spontaneous reaction } (b) Ag+ (aq) + e Ag (s) 108 g requires 1F @ 96500 C 0.60 g requires 0.60 x 96500 C 108 0.60 x 96500 C = 0.25 x t 108 t = 2144 s = 35.74 min = 35 min 44 s (i) Energy / kJ Ca2+(g) + 2F(g) Ca2+(g) + F2(g) Ca+(g) + F2(g) Ca(g) + F2(g) Ca(s) + F2(g) Ca F2(s) 4 (ii) - 1220 kJ = + 178 kJ + 590 kJ + 1150 kJ + 2(+158 kJ) + 2(-328 kJ) + L.E. L.E. = -1220 178 590 1150 - 2(158) + 656 kJ = - 2798 kJ mol-1 ...4
1 1+1 1
...6
1 1 1 ...3
(c)
1. Atomization of Ca & ionization of Ca 2. Atomisation of F and electron affinity of F 3. Formation & lattice energy of CaF2 Ca2+(g) + 2 F-(g) 4. Correct energy circle
1 1 ...2 15
7 8. (a) (i) - The high temperature of the car engine causes the N2 and O2 in the air to react together to form NO2. 1 - NO2 can be removed from the exhaust gases by the use of a catalytic converter which reduces NO2 to N2 1.2 (ii) pV = nRT n= Mr = 1 1 1....3
. (b) (i)
Energy required to remove 1 mol of electrons from 1 mol atoms in the gaseous state M(g) M+(g) + e 1 1. 2
(ii)
`Labelled axes Correct shape of graph 2nd ionisation energy of Na is high because is removed from a completely filled shell 2nd ionisation energy of Al is high because is removed from a completely filled s orbital Increase from Si to Ar is due to increase in effective nuclear charge (or decrease in atomic radius)
Proton number
1 1 1 1 1...5
(c)
Atomic radii Na - Ar : Atomic radius Because nuclear charge Screening effect is constant 1 1 1...3 15
9(a)
8 n=2 Molecular formula = C14H12 (b) (i) Structural formula of W and C=C H cis Structure of X H H trans 1 C=C H C=C H 1+1
...2
...7
9(c)(i)
HO- C COOH
9
2 + HNO2 + N2(g) + H2O
(ii)
15
10. (a) Concentated H2SO4 and HNO3., 55C Mechanism: HNO3 + H2SO4 NO2+ + HSO4 + H2O
1 1 1 1
H NO2 + HSO4
NO2 + H2SO4
1...5
(b) (i) K:
Isomers :
1 1
Warm isomers separately with alkaline iodine, 1 CH3CHCH3OH gives a yellow precipitate but CH3CH2CH2OH does not. 1 CHI3 + 5I + 5H2O + CH3COO O (ii ) L : functional group : C O O Isomers : CH3CH2C - H and CH3CCH3 Warm isomers separately with Tollens reagent. CH3CH2CHO gives a silver mirror but CH3COCH3 does not. CH3CH2CH2OH + 4I2 + 6OH 1...5
1 1 1