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1. Gate Oxide and Field oxide layer: Gate oxide is the layer below which channel is formed and Field oxide is for isolation of devices. They are formed by using thermal oxidation: Provides highest quality oxides using lowest interface trap densities.
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2. Dielectric layers: For insulation between conducting layers and diffusion and ion implantation masks, for capping doped films to prevent loss of dopants, for passivation to protect devices from impurities, heat, moisture and contamination and scratches. : CVD techniques
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3. Poly silicon: For gate electrode and contact material of shallow junctions etc. : CVD techniques. 4. Metallization: For interconnections, ohmic contacts, etc. 5 :PVD techniques.
Summary of Conventional Microfabrication Modules Basic Process Modules: growth, wafer fabrication Semiconductor manufacturing, wafer cleaning and gettering Lithography Thermal Oxidation Etching (Chemical , Plasma) Ion Implantation Diffusion Physical Vapor Deposition PVD Chemical Vapor Deposition CVD & Epitaxial Growth Chemical Mechanical Polishing CMP
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Crystal
Ge
1950s Narrow BG (0.66 eV) High junction leakage currents Operate up to 100C Intrinsic resistivity 47 Ohm-cm. Hence, HV rectifying devices not possible. Germanium Oxide unsuitable for device applications EGG more costly Difficult to grow high quality oxide
GaAs
One element oxidizes faster to other, leaving a metallic phase at the interface Difficult to dope Difficult to get high crystal perfection and large diameters Wide BG (1.1 eV)
Si
Less junction leakage currents Operate up to 150C Intrinsic resistivity = 2,30,000 Ohm-cm. Hence, High voltage rectifying devices are possible. Si dioxide suitable for device applications (more planar) EGS Cheap
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Si Crystal Structure
Thick Around The nMOS And pMOS Active Regions And Thin Respectively Through Thermal Oxidation.
Metallization
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PHOTOLITHOGRAPHY IC Is Set Of Patterned Layers Of Doped Silicon, Polysilicon, Metal And SiO2. All Areas Are To Be Defined By Proper Masks. A Layer Must Be Patterned Before Another Is Applied On The Chip. Every Layer Will Undergo Lithography With Different Mask.
SiO2
SiO2
Si Substrate
Si Substrate
Unpatterned Structure
Photolithography
Patterned Structure
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Si Substrate
Si Substrate
Soluble Photoresistv
For High Density Patterns Required In Sub Micron Devices, E-beam Lithography Is Used Instead Of Optical Lithography.
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a) Positive photoresist
b) Negative photoresist
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PHOTORESISTS Positive :
Exposed regions become more soluble. Hence , easily removed in the developing process. Patterns formed are same as that of masks. Consists of photosensitive compound, a base resin, and an organic solvent. Initially photosensitive compound is insoluble in the developer solution. After exposure, its chemical structure changes due to absorption of the radiations. After development, exposed areas are removed.
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Negative : Exposed regions become less soluble. Hence , cant be removed in the developing process. Patterns are mirror images of the mask patterns. It consists of polymers combined with photosensitive compound . Initially less insoluble in the developer solution. After exposure, its chemical structure changes due to absorption of the radiations. Optical energy is converted into chemical one which initiates a polymer cross linking reaction. Cross linked polymers have more molecular weight and they become more insoluble in the developer solution. After development, unexposed areas are removed. Developer solution is absorbed here and there is 16 swelling of the resist mass. Hence limited resolution.
Si Substrate
Deposition of polysilicon
Si Substrate
SELECTIVE ETCHING FOR DEFINING ACTIVE AREA ON WHICH MOSFET WILL BE FABRICATED
Si Substrate
Patterned and etched
polysilicon
oxide
gate oxide
Si Substrate
Si Substrate
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Insulating oxide
gate oxide n+ n+
Si Substrate
n+
n+
By creating another insulating oxide layer, cutting contact holes (via), depositing and patterning metal, two more layers of metallic interconnects can also be added on the top of this structure.
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CHALLENGES:
Electrical isolation on a single chip containing many devices is necessary To prevent undesired conducting paths; To avoid creation of inversion layers outside the channels; To reduce leakage currents.
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LOCOS technique is based on the principle of selectively growing the field oxide in certain regions , instead of selectively etching away active areas after oxide growth. For selective growth of oxide, active areas are covered with Silicon nitride.
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Protects Si surface from stress caused by nitride during subsequent process steps. Si3N4
Si Substrate
Si3N4
p+
Si Substrate
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Si3N4
Si3N4
p+
p+
Si Substrate
p+
p+
Si Substrate
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SOME FACTS: Due to various process steps chip surface is highly nonplanar. It may inhibit local thinning and discontinuities at uneven surface edges. Deposition of multiple metal interconnect lines is not desirable on such irregular topography. They will lead to hills and valleys on the chip surface. Hence surface is usually planarised before every new metal deposition step. For this, a fairly thick SiO2 layer is grown on the wafer surface to cover all existing surface nonuniformities. Its surface is then planarised by any one of: Glass reflow (heat treatment), Etch back, Chemical mechanical polishing (CMP). CMP: Actual polishing of wafer surface using abrasive silica slurry. 32 Adopted in recent years.
EXERCISE:
*Epitaxial layer ** Difference between ion implantation and diffusion processes of doping. *** Design masks for all patterning and etching steps in the fabrication of nMOS transistor for positive and negative photoresist material.
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