Professional Documents
Culture Documents
C3H6
Temperature program
50oC 5 mins
5oC/min
220oC 3 mins
Analysis conditions
FID TCD
Threshold 0.01 0.01
Peak width 5 5
Peak area 0.75 0.5
Peak Height 0 0
Range 8 0
Sense 1 4
Attn 0 0
Experiment of Methane Kinetic Conversion
power @ 60 and 80W and flowrate @ 30 mL/min
frequency 20 kHz sample volume 500 uL
flow rate 30 mL/min mole sample 0 mol
power 60 W (Metex)
2n
reactant CH4 Al2O3 ZSM5
before after before after before after
FID 20 19 70.88 70.18 62.95 62.63
8.42 1767.31 1530.75 1566.43 1368.43 1583.33 1384.03
25.53 22.84 19.56 18.78
25.66
29.40 105.31 81.12 81.58
42.13 17.75
42.98 50.60 30.62 32.21
43.77
51.25 14.60
53.31 12.33
TCD
4.40 106.56 81.43 86.89
8.39 307.64 264.30 276.56 237.60 278.62 242.06
power (RMS)
V (kV) 2.85 2.79 2.79
I (mA) 23.74 23.67 23.90
total mol
FID 0 0 0 0 0 0
TCD #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
calculation 0 #DIV/0! 0 #DIV/0! 0 #DIV/0!
FID FID TCD FID TCD FID TCD
8.42 17.72 #DIV/0! 13.51 #DIV/0! 13.03 #DIV/0!
25.53 7.50 #DIV/0! 9.91 #DIV/0! 9.81 #DIV/0!
25.66 0.00 #DIV/0! 0.00 #DIV/0! 0.00 #DIV/0!
29.40 32.74 #DIV/0! 38.89 #DIV/0! 40.33 #DIV/0!
42.13 5.88 #DIV/0! 0.00 #DIV/0! 0.00 #DIV/0!
42.98 16.62 #DIV/0! 15.51 #DIV/0! 16.82 #DIV/0!
43.77 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
51.25 5.20 #DIV/0! 0.00 #DIV/0! 0.00 #DIV/0!
53.31 4.37 #DIV/0! 0.00 #DIV/0! 0.00 #DIV/0!
TCD
4.40 78.47 #DIV/0! 92.46 #DIV/0! 101.74 #DIV/0!
3rd
reactant CH4 Al2O3 ZSM5
before after before after before after
FID 105.47 106.11 104.67 105.16 117.05 120.52
8.42 1362.24 1070.21 1329.94 1062.81 1358.6 1079.62
25.53 17.78 16.29 23.45
25.66
29.40 95.57 101.06 102.63
42.13
42.98 48.91 42.08 42.20
43.77
51.25
53.31 11.69
TCD
4.40 133.49 149.43 140.95
8.39 246.40 192.88 240.66 190.17 243.69 191.94
power (RMS)
V (kV) 2.60 2.86 2.62
I (mA) 21.50 15.18 23.93
total mol
FID 0 0 0 0 0 0
TCD #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
calculation 0 #DIV/0! 0 #DIV/0! 0 #DIV/0!
FID FID TCD FID TCD FID TCD
8.42 20.96 #DIV/0! 19.71 #DIV/0! 18.18 #DIV/0!
25.53 6.78 #DIV/0! 6.76 #DIV/0! 10.58 #DIV/0!
25.66 0.00 #DIV/0! 0.00 #DIV/0! 0.00 #DIV/0!
29.40 34.50 #DIV/0! 39.69 #DIV/0! 43.84 #DIV/0!
42.13 0.00 #DIV/0! 0.00 #DIV/0! 0.00 #DIV/0!
42.98 18.65 #DIV/0! 17.45 #DIV/0! 19.04 #DIV/0!
43.77 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
51.25 0.00 #DIV/0! 0.00 #DIV/0! 0.00 #DIV/0!
53.31 0.00 #DIV/0! 0.00 #DIV/0! 5.69 #DIV/0!
TCD
4.40 114.13 #DIV/0! 138.97 #DIV/0! 142.61 #DIV/0!
report
< 10% empty Al2O3 ZSM5
CH4 conv. #DIV/0! #DIV/0! #DIV/0!
H2 #DIV/0! #DIV/0! #DIV/0!
C2H2 #DIV/0! #DIV/0! #DIV/0!
C2H6 #DIV/0! #DIV/0! #DIV/0!
C3H8 #DIV/0! #DIV/0! #DIV/0!
C4 #DIV/0! #DIV/0! #DIV/0!
10-20%
CH4 conv. #DIV/0! #DIV/0! #DIV/0!
H2 #DIV/0! #DIV/0! #DIV/0!
C2H2 #DIV/0! #DIV/0! #DIV/0!
C2H6 #DIV/0! #DIV/0! #DIV/0!
C3H8 #DIV/0! #DIV/0! #DIV/0!
C4 #DIV/0! #DIV/0! #DIV/0!
1st trial
3% Fe/Al2O3 3% Fe/ZSM5 3% Cu/Al2O3 3% Cu/ZSM5
before after before after before after before
59.94 59.48 29.14
1539.94 1462.41 1654.38
51.25
30.82
280.81 265.69 314.29
2.61
24.02
0 0 0 0 0 0 0
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
0 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! 0
FID TCD FID TCD FID TCD FID
5.76 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! 8.42
0.00 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! 0.00
0.00 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! 0.00
58.77 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! 60.51
0.00 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! 0.00
0.00 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! 25.49
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
0.00 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! 0.00
0.00 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! 0.00
35.00 51.00
62.60 0.00 0.00
2nd trial
3% Fe/Al2O3 3% Fe/ZSM5 3% Cu/Al2O3 3% Cu/ZSM5
before after before after before after before
55.49 55.79 383.61 386.32 62.14 58.16
1525.45 1337.47 772.02 648.66 1596.97 1384.14
18.89 16.31 17.97
78.17 45.70 88.63
5.63
26.66 19.07 32.35
4.88
5.55
0 0 0 0 0 0 0
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
0 #DIV/0! 0 #DIV/0! 0 #DIV/0! #DIV/0!
FID TCD FID TCD FID TCD FID
11.85 #DIV/0! 15.39 #DIV/0! 18.89 #DIV/0! #DIV/0!
11.37 #DIV/0! 14.97 #DIV/0! 6.04 #DIV/0! #DIV/0!
0.00 #DIV/0! 0.00 #DIV/0! 0.00 #DIV/0! #DIV/0!
44.54 #DIV/0! 39.70 #DIV/0! 28.18 #DIV/0! #DIV/0!
0.00 #DIV/0! 5.22 #DIV/0! 0.00 #DIV/0! #DIV/0!
16.04 #DIV/0! 17.50 #DIV/0! 10.87 #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
0.00 #DIV/0! 4.85 #DIV/0! 0.00 #DIV/0! #DIV/0!
0.00 #DIV/0! 5.49 #DIV/0! 0.00 #DIV/0! #DIV/0!
3rd trial
3% Fe/Al2O3 3% Fe/ZSM5 3% Cu/Al2O3 3% Cu/ZSM5
before after before after before after before
20.04 20.1 28.2 24.61 118.43 115.26
1714.32 1289.47 1683.23 1485.66 1390.88 1077.8
36.67 20.88
23.48
18.19
0 0 0 0 0 0 0
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
0 #DIV/0! 0 #DIV/0! 0 #DIV/0! #DIV/0!
FID TCD FID TCD FID TCD FID
24.56 #DIV/0! 22.97 #DIV/0! 24.58 #DIV/0! #DIV/0!
9.46 #DIV/0! 0.00 #DIV/0! 6.43 #DIV/0! #DIV/0!
0.00 #DIV/0! 0.00 #DIV/0! 0.00 #DIV/0! #DIV/0!
39.90 #DIV/0! 17.25 #DIV/0! 27.65 #DIV/0! #DIV/0!
0.00 #DIV/0! 0.00 #DIV/0! 0.00 #DIV/0! #DIV/0!
18.61 #DIV/0! 7.03 #DIV/0! 11.66 #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
6.56 #DIV/0! 0.00 #DIV/0! 0.00 #DIV/0! #DIV/0!
5.06 #DIV/0! 0.00 #DIV/0! 0.00 #DIV/0! #DIV/0!
#DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0!
3% Cu/ZSM5 1% Pt/Al2O3 5% Mn/Al2O3 3% Ru/Al2O3
after before after before after before after
29.89 60.65 60.65 29.55 29.72 65.02 65.11
1477.27 1520.66 1368.15 1668.01 1491.99 1709.93 1545.33
20.17 19.45 21.46
0 0 0 0 0 0 0
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! 0 #DIV/0! 0 #DIV/0! 0 #DIV/0!
TCD FID TCD FID TCD FID TCD
#DIV/0! 10.03 #DIV/0! 10.04 #DIV/0! 9.49 #DIV/0!
#DIV/0! 14.32 #DIV/0! 12.64 #DIV/0! 14.33 #DIV/0!
#DIV/0! 0.00 #DIV/0! 0.00 #DIV/0! 0.00 #DIV/0!
#DIV/0! 45.99 #DIV/0! 40.11 #DIV/0! 57.91 #DIV/0!
#DIV/0! 0.00 #DIV/0! 0.00 #DIV/0! 0.00 #DIV/0!
#DIV/0! 19.11 #DIV/0! 17.86 #DIV/0! 26.49 #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! 0.00 #DIV/0! 0.00 #DIV/0! 0.00 #DIV/0!
#DIV/0! 0.00 #DIV/0! 0.00 #DIV/0! 0.00 #DIV/0!
35.16
109.34
274.31 227.18
2.47
24.31
0 0 0 0 0 0 0
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! 0 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
TCD FID TCD FID TCD FID TCD
#DIV/0! 13.06 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! 13.31 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! 0.00 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! 51.14 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! 0.00 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! 20.08 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! 0.00 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! 0.00 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
48.00 52.00
0.00 60.12 0.00 0.00
19.09 19.61
11.09 16.03 15.91
0 0 0 0 0 0 0
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! 0 #DIV/0! 0 #DIV/0! 0 #DIV/0!
TCD FID TCD FID TCD FID TCD
#DIV/0! 21.32 #DIV/0! 35.42 #DIV/0! 37.36 #DIV/0!
#DIV/0! 4.62 #DIV/0! 7.19 #DIV/0! 6.03 #DIV/0!
#DIV/0! 0.00 #DIV/0! 0.00 #DIV/0! 0.00 #DIV/0!
#DIV/0! 39.99 #DIV/0! 31.38 #DIV/0! 31.05 #DIV/0!
#DIV/0! 0.00 #DIV/0! 0.00 #DIV/0! 0.00 #DIV/0!
#DIV/0! 15.90 #DIV/0! 12.91 #DIV/0! 13.64 #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! 0.00 #DIV/0! 4.68 #DIV/0! 4.57 #DIV/0!
#DIV/0! 4.25 #DIV/0! 3.91 #DIV/0! 3.69 #DIV/0!
0 0
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
FID TCD
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
0.00
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
ZnCr2O4
before after
0 0
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
FID TCD
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
0.00
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
ZnCr2O4
before after
18.9 18.03
1645.59 1219.48
30.69
164.47
68.42
22.72
20.04
211.27
309.46 226.62
2.66
23.93
0 0
#DIV/0! #DIV/0!
0 #DIV/0!
FID TCD
29.29 #DIV/0!
6.58 #DIV/0!
0.00 #DIV/0!
33.37 #DIV/0!
0.00 #DIV/0!
14.66 #DIV/0!
#DIV/0! #DIV/0!
5.27 #DIV/0!
4.63 #DIV/0!
101.51 #DIV/0!
50.00
63.65
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
ZnCr2O4
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
Experiment of Meth
power @ 60 and 80W a
6
reactan CH4 C2H2 C2H4
before after before after before after
FID (flow rate) 27.61 28.3 27.83 26.13
CH4 232.25 195.31 13.28
C2H2 0.58 230
C2H4 0.37 6490.51 5828.42
C2H6 4.00 50.18
C3H6 39.66
C3H8 4.93 69.69
iC4H10 2.18 86.85
nC4H10 1.53 236.21
TCD
H2 98.08
conv. 13.80 15.70
power
V (kV) 2.83 3.54
I (mA) 40.23 28.55
total mol
FID 0 0 0 0 0 0
TCD
calculation 0 #DIV/0! 0
FID FID TCD FID TCD FID TCD
CH4 13.80 #DIV/0! 1.12
C2H2 2.51 #DIV/0! 21.06
C2H4 2.14 #DIV/0! 15.70
C2H6 19.37 #DIV/0! 4.35
C3H6 0.00 #DIV/0! 3.67
C3H8 33.32 #DIV/0! 6.38
iC4H10 19.03 #DIV/0! 8.57
nC4H10 12.50 #DIV/0! 23.43
TCD
4.40 50.00 #DIV/0! 0.00
8
reactan CH4 C2H2 C2H4
before after before after before after
FID 27.61 28.4 30.54 30.07 23.49 21.36
CH4 232.25 178.6 216.17 5.21
C2H2 0.63 6531.64 5834.66 20.75
C2H4 0.71 3.80 146.98 90.34
C2H6 5.10 3.09
C3H6 0.45 13.48 3.25
C3H8 3.76 5.50
iC4H10 1.41 61.68 3.39
nC4H10 1.28 95.58 12.65
TCD
4.40 106.56 22.79 86.89
conv. 20.90 12.05 44.11
power (RMS)
V (kV) 2.85 3.74 2.79
I (mA) 23.74 35.40 23.90
total mol
FID 0 0 0 0 0 0
TCD
calculation 0 0 0 0
FID FID TCD FID TCD FID TCD
8.42 2.09 24.99 2.02
25.53 1.80 12.05 21.82
25.66 2.70 12.02 44.11
29.40 16.38 0.00 3.65
42.13 1.89 1.70 5.03
42.98 16.86 0.00 9.08
43.77 8.16 8.32 7.22
51.25 6.92 12.95 25.21
TCD
4.40 36.01 12.79 21.62
report
60 W CH4 C2H2 C2H4
Conversion 13.80 15.70
H2 50.00 0.00
C2H2 2.51 21.06
C2H4 2.14 15.70
C2H6 19.37 4.35
C3H6 0.00 3.67
C3H8 33.32 6.38
iC4H10 19.03 8.57
nC4H10 12.50 23.43
80 W
Conversion 20.90 12.05 44.11
H2 36.01 12.79 21.62
C2H2 1.80 12.05 21.82
C2H4 2.70 12.02 44.11
C2H6 16.38 0.00 3.65
C3H6 1.89 1.70 5.03
C3H8 16.86 0.00 9.08
iC4H10 8.16 8.32 7.22
nC4H10 6.92 12.95 25.21
13.85 50
C2H4 14.72 2.70 12.02
C2H6 16.38 3.38 19.76
40
C3H6 3.60 1.89 1.70
Selectivity (%)
C3H8 16.86 1.86 18.72
i-C4H10 16.48 4.16 20.64 30
n-C4H10 19.87 3.92 15.95
87.91 88.80 20
10
0
H4 H6 H6 H8
C2 C2 C3 C3
Compounds
Experiment of Methane Kinetic Conversion
power @ 60 and 80W and flowrate @ 30 mL/min
60 Watt
C2H6 C3H6 C3H8 iC4H10
before after before after before after before
27.68 28.39 29.49 29.29 28.98 32.5 28.21
33.16 24.89 9.62
4.28 5.56 1.45
5.30 6.46 4.69
6901.19 6094.11 32.30 2.61
15.46 9706.08 8810.13 7.97
84.93 220.01 215.22 169.36
6.25 120.77 0.26 259.06
99.47 69.81 0.00
42.34 44 70
9.43 9.84 11.73 16.67
0 0 0 0 0 0 0
0 0 0 0
FID FID TCD FID TCD FID
5.10 2.37 10.04 4.64
13.51 10.85 4.11 9.26
22.31 16.81 17.70 15.83
9.43 3.15 8.30 6.50
2.60 9.84 33.19 18.83
14.14 22.65 11.73 8.20
1.12 13.41 1.52 16.67
17.94 7.79 0.00 46.82
80 Watt
C2H6 C3H6 C3H8 iC4
before after before after before after before
27.33 28.58 30.04 29.46 30.6 34.68 29.68
112.22 52.38 13.15
5.81 9.73 2.66
9.76 11.12 9.58
6901.19 5448.36 56.52 3.74
32.64 9706.08 8041.06 10.24
172.20 258.56 215.00 165.22
26.81 171.47 0.45 259.06
199.70 106.11 0.27
78.36 44 92.82
17.45 18.75 12.90 15.23
0 0 0 0 0 0 0
0 0 0 0
FID FID TCD FID TCD FID
9.51 2.58 12.63 4.77
10.10 9.84 6.93 2.36
22.63 15.00 33.27 4.67
17.45 2.86 10.96 4.04
3.02 18.75 39.23 18.42
15.80 13.80 12.90 7.00
2.65 9.87 2.36 15.23
19.85 6.13 1.34 34.47
Column B
Column D
H6 H6 H8 10 10
C2 C3 C3 4H 4H
i-C n-C
Compounds
iC4H10 nC4H10
after before after
37.48 27.35 29.17
8.3 5.56
6.10 3.50
7.82 5.56
3.81 3.67
8.44 4.48
3.45 4.50
162.49 7.42
16.28 245.85 211.26
114.15
190.58 8.37
2.77
24.88
0 0 0
0 0
TCD FID TCD
5.61
9.57
20.27
11.29
18.01
19.31
41.13
8.37
0.00
60.00 60.00
68.79 0.00
125.19
61.82
iC4H10 nC4H10
after before after
31.83 27.35 29.17
9.64 5.56
1.76 3.50
2.61 5.56
2.68 3.67
9.33 4.48
3.33 4.50
204.79 7.42
13.56 245.85 211.21
8.39
2.47
24.31
0 0 0
0
TCD FID TCD
5.59
9.55
20.22
11.26
17.96
19.26
41.01
8.39
0.00
80.00 80.00
0.00 60.12
124.84
61.67
iC4H10 nC4H10
8.37
0.00
9.57
20.27
11.29
18.01
19.31
41.13
8.37
8.39
0.00
9.55
20.22
11.26
17.96
19.26
41.01
8.39
Experiment of Meth
power @ 60 and 80W a
6
reactan CH4 C2H2 C2H4
before after before after before after
FID (flow rate) 27.61 28.3 27.83 26.13
CH4 232.25 195.31 13.28
C2H2 0.58 230
C2H4 0.37 6490.51 5828.42
C2H6 4.00 50.18
C3H6 39.66
C3H8 4.93 69.69
iC4H10 2.18 86.85
nC4H10 1.53 236.21
TCD
H2 98.08
conv. 13.80 15.70
power
V (kV) 2.83 3.54
I (mA) 40.23 28.55
total mol
FID 0 0 0 0 0 0
TCD
calculation 0 #DIV/0! 0
FID FID concentration FID concentration FID concentration
CH4 13.80 86.20 #DIV/0! 1.12 2.67
C2H2 2.51 0.17 #DIV/0! 21.06 3.31
C2H4 2.14 0.15 #DIV/0! 15.70 84.30
C2H6 19.37 1.34 #DIV/0! 4.35 0.68
C3H6 0.00 0.00 #DIV/0! 3.67 0.38
C3H8 33.32 1.53 #DIV/0! 6.38 0.67
iC4H10 19.03 0.66 #DIV/0! 8.57 0.67
nC4H10 12.50 0.43 #DIV/0! 23.43 1.84
TCD
4.40 50.00 13.80 #DIV/0! 0.00 0.00
8
reactan CH4 C2H2 C2H4
before after before after before after
FID 27.61 28.4 30.54 30.07 23.49 24.36
CH4 232.25 178.6 216.17 5.21
C2H2 0.63 6531.64 5834.66 20.75
C2H4 0.71 3.80 146.98 90.34
C2H6 5.10 3.09
C3H6 0.45 13.48 3.25
C3H8 3.76 5.50
iC4H10 1.41 61.68 3.39
nC4H10 1.28 95.58 12.65
TCD
4.40 106.56 22.79 86.89
conv. 20.90 12.05 36.26
power (RMS)
V (kV) 2.85 3.74 2.79
I (mA) 23.74 35.40 23.90
total mol
FID 0 0 0 0 0 0
TCD
calculation 0 0 0 0
FID FID concentration FID concentration FID concentration
8.42 2.09 79.10 24.99 6.02 2.80 1.16
25.53 1.80 0.19 12.05 87.95 30.27 6.24
25.66 2.70 0.28 12.02 1.45 36.26 63.74
29.40 16.38 1.71 0.00 0.00 5.07 1.05
42.13 1.89 0.13 1.70 0.14 6.98 0.96
42.98 16.86 1.17 0.00 0.00 12.60 1.73
43.77 8.16 0.43 8.32 0.50 10.02 1.03
51.25 6.92 0.36 12.95 0.78 34.97 3.61
TCD
4.40 36.01 15.05 12.79 3.08 29.99 12.37
report
60 W CH4 C2H2 C2H4
Conversion 13.80 86.20 0.00 15.70 2.67
H2 50.00 13.80 0.00 0.00 0.00
C2H2 2.51 0.17 0.00 21.06 3.31
C2H4 2.14 0.15 0.00 15.70 84.30
C2H6 19.37 1.34 0.00 4.35 0.68
C3H6 0.00 0.00 0.00 3.67 0.38
C3H8 33.32 1.53 0.00 6.38 0.67
iC4H10 19.03 0.66 0.00 8.57 0.67
nC4H10 12.50 0.43 0.00 23.43 1.84
80 W
Conversion 20.90 79.10 12.05 6.02 36.26 1.16
H2 36.01 15.05 12.79 3.08 29.99 12.37
C2H2 1.80 0.19 12.05 87.95 30.27 6.24
C2H4 2.70 0.28 12.02 1.45 36.26 63.74
C2H6 16.38 1.71 0.00 0.00 5.07 1.05
C3H6 1.89 0.13 1.70 0.14 6.98 0.96
C3H8 16.86 1.17 0.00 0.00 12.60 1.73
iC4H10 8.16 0.43 8.32 0.50 10.02 1.03
nC4H10 6.92 0.36 12.95 0.78 34.97 3.61
60 Watt
C2H6 C3H6 C3H8 iC4H10
before after before after before after before
27.68 28.39 29.49 29.29 28.98 32.5 28.21
33.16 24.89 9.62
4.28 5.56 1.45
5.30 6.46 4.69
6901.19 6094.11 32.30 2.61
15.46 9706.08 8810.13 7.97
84.93 220.01 215.22 169.36
6.25 120.77 0.26 259.06
99.47 69.81 0.00
42.34 44 70
9.43 9.84 11.73 16.67
0 0 0 0 0 0 0
0 0 0 0
FID concentration FID concentration FID concentration FID
5.10 0.96 2.37 0.70 10.04 2.31 4.64
13.51 1.27 10.85 1.60 4.11 0.47 9.26
22.31 2.10 16.81 2.48 17.70 2.03 15.83
9.43 90.57 3.15 0.46 8.30 0.95 6.50
2.60 0.16 9.84 90.16 33.19 2.54 18.83
14.14 0.89 22.65 2.23 11.73 88.27 8.20
1.12 0.05 13.41 0.99 1.52 0.09 16.67
17.94 0.85 7.79 0.57 0.00 0.00 46.82
80 Watt
C2H6 C3H6 C3H8 iC4
before after before after before after before
27.33 28.58 30.04 29.46 30.6 34.68 29.68
112.22 52.38 13.15
5.81 9.73 2.66
9.76 11.12 9.58
6901.19 5448.36 56.52 3.74
32.64 9706.08 8041.06 10.24
172.20 258.56 215.00 165.22
26.81 171.47 0.45 259.06
199.70 106.11 0.27
78.36 44 92.82
17.45 18.75 12.90 15.23
0 0 0 0 0 0 0
0 0 0 0
FID concentration FID concentration FID concentration FID
9.51 3.32 2.58 1.45 12.63 3.19 4.77
10.10 1.76 9.84 2.77 6.93 0.87 2.36
22.63 3.95 15.00 4.22 33.27 4.20 4.67
17.45 82.55 2.86 0.80 10.96 1.38 4.04
3.02 0.35 18.75 81.25 39.23 3.30 18.42
15.80 1.84 13.80 2.59 12.90 87.10 7.00
2.65 0.23 9.87 1.39 2.36 0.15 15.23
19.85 1.73 6.13 0.86 1.34 0.08 34.47
Atom balance
iC4H10 nC4H10 Cout/Cin Hout/Hin
0.26 0.43 0.95 1.01
0.00 0.28 0.87 1.13
0.67 1.84 0.95 0.98
0.05 0.85 0.97 0.98
0.99 0.57 0.89 1.01
0.09 0.00 0.97 0.96
83.33 5.94 1.04 1.00
2.33 91.63 1.03 0.98
6.1 10.1
0.0 5.7
6.6 18.0
0.8 13.4
10.9 6.4
1.0 0.0
28.4
21.0
1.04 1.73
0 1.12
2.69 7.35
0.21 3.38
3.96 2.3
0.35 0
0 23.78
9.3 0
9.6 15.9
0.0 15.0
11.3 30.8
1.5 23.4
17.4 10.1
2.0 0.0
42.5
32.9
ntration [%] Atom balance
C3H8 iC4H10 nC4H10 Cout/Cin Hout/Hin [1]
0.93 0.26 0.43 0.95 1.01
0.00 0.00 0.28 0.87 1.13
0.67 0.67 1.84 0.95 0.98
0.89 0.05 0.85 0.97 0.98
2.23 0.99 0.57 0.89 1.01
88.27 0.09 0.00 0.97 0.96
1.39 83.33 5.94 1.04 1.00
1.46 2.33 91.63 1.03 0.98
iC4H10 nC4H10
after before after
37.48 27.35 29.17
8.3 5.56
6.10 3.50
7.82 5.56
3.81 3.67
8.44 4.48
3.45 4.50
162.49 7.42
16.28 245.85 211.26
114.15
190.58 8.37
2.77
24.88
0 0 0
0
concentration FID concentration
2.36 5.61 1.27
2.35 9.57 1.08
4.02 20.27 2.29
1.65 11.29 1.28
3.19 18.01 1.36
1.39 19.31 1.46
83.33 41.13 2.33
5.94 8.37 91.63
60.00 60.00
68.79 0.00
iC4H10 nC4H10
after before after
31.83 27.35 29.17
9.64 5.56
1.76 3.50
2.61 5.56
2.68 3.67
9.33 4.48
3.33 4.50
204.79 7.42
13.56 245.85 211.21
8.39
2.47
24.31
0 0 0
0
concentration FID concentration
2.21 5.59 1.27
0.55 9.55 1.08
1.08 20.22 2.29
0.94 11.26 1.28
2.85 17.96 1.36
1.08 19.26 1.46
84.77 41.01 2.33
4.00 8.39 91.61
80.00 80.00
0.00 60.12
iC4H10 nC4H10
2.36 8.37 1.27
20.82 0.00 0.00
2.35 9.57 1.08
4.02 20.27 2.29
1.65 11.29 1.28
3.19 18.01 1.36
1.39 19.31 1.46
83.33 41.13 2.33
5.94 8.37 91.63
2.21 8.39 1.27
0.00 0.00 0.00
0.55 9.55 1.08
1.08 20.22 2.29
0.94 11.26 1.28
2.85 17.96 1.36
1.08 19.26 1.46
84.77 41.01 2.33
4.00 8.39 91.61
60W
0 0.06 0.18 0.5 0.02 0.3 0.13
1.31 0 0.17 0.18 0.31 0.06 0.14
0.08 1.79 0 0.01 0.22 0.02 0.25
0.11 0.3 1.03 0 0.07 0.67 0.15
0.09 0.23 0.33 0.14 0 0.53 0.54
0.06 0.97 0.16 0.49 0.48 0 0.7
0.06 0.67 1.28 0.89 1.28 1.45 0
0.74 1.07 2.27 0.39 1.05 0.33 1.38
CH4
0 0.11 0.01 0.17 0.05 0.22 0.03
0 0 4.29 3.86 2.39 0.82 5.84
0.03 0.49 0 0.05 0.01 0.09 0.02
4.33 0.04 0.13 0 2.96 0.43 0.05
5.24 0.39 0.12 0.16 0 1.85 0.84
0.04 0.37 0.41 0.14 1.04 0 0.42
1.44 0.95 1.71 5.28 0.04 0.88 0
0.63 6.79 0.6 0.73 0.14 2.25 0.79
C2H4
0 0.08 0.42 0.2 0.01 0.55 0.13
0.42 0 2.57 0.43 0.97 3.03 0.77
0.07 0.24 0 0 0.14 0.03 0.26
2.87 0.35 0.61 0 1.72 4.21 0.25
0.79 1.31 0.83 1.1 0 0.76 0.49
1.96 2.02 1 0.68 0.97 0 1.65
0.68 1.93 2.82 1.21 0.89 1.01 0
0.19 0.24 2.9 0.93 2.02 0.01 1.09
C2H6
C3H6
C3H8
iC4H10
0 0.02 0.32 0.19 0.02 0.38 0.02
0.07 0 0.67 0.71 0.8 0.6 0.41
0.02 0.23 0 0 0.37 0 2.56
0 0.5 0 0 0 0 0.09
0.02 0 0.2 0 0 0.38 0
0.04 0.03 0.46 0 0.01 0 0.19
0.07 0.01 0.15 0.06 0.05 0.05 0
0.92 0.06 2.35 0.19 2.69 0.01 0.23
n-C4H10
0 0.03 0.17 0.08 0.02 0.52 0.02
0.06 0 0.72 1.26 0.7 0.71 0.35
0.02 0.18 0 0 0.2 0 1.94
0 0.6 0 0 0 0 0.09
0.05 0 0.26 0 0 0.29 0
0.03 0.02 0.35 0 0.02 0 0.2
0.08 0 0.21 0.08 0.06 0.11 0
0.05 0.06 0.08 0.02 0.04 0.01 0.05
1 2 3 4 5
0.29 1 0.0 5.3 11.6 6.5 7.5
1.47 2 8.1 0.0 12.0 8.4 38.6
1.01 3 8.5 8.6 0.0 18.9 6.2
0.94 4 17.3 6.1 9.2 0.0 18.0
0.53 5 21.8 35.1 7.8 7.0 0.0
0.97 6 13.5 11.3 28.2 8.1 10.8
2.45 7 20.6 36.2 7.7 21.7 8.2
0 8 7.2 21.8 6.4 8.0 18.3
0
0.47
0.03
3.53
0.13
2.39
6.18
0
0.4
0.13
0.02
0.25
0.59
3.28
4.14
0
0.6
0.1
0.01
0
0.4
0.03
3.86
0
0.89
0.06
0.02
0
0.04
0.02
2.18
0
0.04
0.08
0.01
0
0.04
0.02
0.26
0
0.06
0.04
0
0
0.14
0.07
0.32
0
0.04
0.07
0
0
0.1
0.05
0.23
0
6 7 8
kij
9.8 10.7 11.1 (1) CH4 (2) C2H2
20.7 16.1 9.1 (1) CH4 0 ( 0.0 ) 0.06 ( 5.3 )
15.6 9.1 9.9 (2) C2H2 1.31 ( 8.1 ) 0 ( 0.0 )
21.7 4.7 13.7 (3) C2H4 0.08 ( 8.5 ) 1.79 ( 8.6 )
10.9 8.5 7.1 (4) C2H6 0.11 ( 17.3 ) 0.3 ( 6.1 )
i
0.0 7.9 13.3 (5) C3H6 0.09 ( 21.8 ) 0.23 ( 35.1 )
8.3 0.0 8.9 (6) C3H8 0.06 ( 13.5 ) 0.97 ( 11.3 )
23.8 7.7 0.0 (7) i-C4H10 0.06 ( 20.6 ) 0.67 ( 36.2 )
(8) n-C4H10 0.74 ( 7.2 ) 1.07 ( 21.8 )
j
(3) C2H4 (4) C2H6 (5) C3H6 (6) C3H8 (7) i-C4H10 (8) n-C
0.18 ( 11.6 ) 0.5 ( 6.5 ) 0.02 ( 7.5 ) 0.3 ( 9.8 ) 0.13 ( 10.7 ) 0.29
0.17 ( 12.0 ) 0.18 ( 8.4 ) 0.31 ( 38.6 ) 0.06 ( 20.7 ) 0.14 ( 16.1 ) 1.47
0 ( 0.0 ) 0.01 ( 18.9 ) 0.22 ( 6.2 ) 0.02 ( 15.6 ) 0.25 ( 9.1 ) 1.01
1.03 ( 9.2 ) 0 ( 0.0 ) 0.07 ( 18.0 ) 0.67 ( 21.7 ) 0.15 ( 4.7 ) 0.94
0.33 ( 7.8 ) 0.14 ( 7.0 ) 0 ( 0.0 ) 0.53 ( 10.9 ) 0.54 ( 8.5 ) 0.53
0.16 ( 28.2 ) 0.49 ( 8.1 ) 0.48 ( 10.8 ) 0 ( 0.0 ) 0.7 ( 7.9 ) 0.97
1.28 ( 7.7 ) 0.89 ( 21.7 ) 1.28 ( 8.2 ) 1.45 ( 8.3 ) 0 ( 0.0 ) 2.45
2.27 ( 6.4 ) 0.39 ( 8.0 ) 1.05 ( 18.3 ) 0.33 ( 23.8 ) 1.38 ( 7.7 ) 0
(8) n-C4H10
( 11.1 )
( 9.1 )
( 9.9 )
( 13.7 )
( 7.1 )
( 13.3 )
( 8.9 )
( 0.0 )