tR (min) FID (area) tR (min) TCD tR (min) FID (height)

H2 0 0 1.99 728.47 1.99 149.93

O2 0 0 2.46 85.78 2.46 17.22
CO 2.57 64.09 0 2.57 12.8
CH4 3.63 3535.88 0 3.63 467.46
CO2 6.62 3400.25 0 6.62 225.92
C2H2 10.69 6531.64 0 10.69 344.71
C2H4 10.91 6490.51 0 10.91 258.45
C2H6 13.42 6901.19 0 13.42 306.61
C3H6 24.06 9706.08 0 24.06 351.59
C3H8 25.07 9799.68 0 25.07 329.66
C3H4
iC4H10 33.37 12117.36 0 33.37 340.22
nC4H10 35.23 12060.91 0 35.23 363.87

calibration data (area method)

H2 729.54 727.39 728.47
150.17 149.68 149.93
O2 84.81 86.76 85.78
16.81 17.63 17.22
CO 63.99 64.19 64.09
12.75 12.84 12.8
CH4 3535.88 3535.88 3535.88
467.46 467.46 467.46
CO2 3165.35 3635.15 3400.25
212.53 239.31 225.92
C2H2 6520.06 6543.23 6531.64
344.13 345.28 344.71
C2H4 6490.51 6490.51 6490.51
258.45 258.45 258.45
C2H6 6865.79 6936.58 6901.19
305.72 307.5 306.61
C3H6 9706.08 9706.08 9706.08
351.59 351.59 351.59
C3H8 9731.27 9868.09 9799.68
327.93 331.4 329.66
C3H4

iC4H10 12070.94 12163.77 12117.36

339.5 340.93 340.22
nC4H10 12060.74 12061.08 12060.91
363.73 364.02 363.87
column 10ft Hayesep D + 10ft 10%Carbowax
Inject 180 oC
Detector 1 250 oC
Detector 2 250 oC
Aux 1 140 oC
Aux 2 350 oC

Temperature program
50oC 5 mins
5oC/min
220oC 3 mins

Analysis conditions
FID TCD
Threshold 0.01 0.01
Peak width 5 5
Peak area 0.75 0.5
Peak Height 0 0

Range 8 0
Sense 1 4
Attn 0 0
 tR (min) FID (area) tR (min) TCD tR (min) FID (height)
H2 1.99 0 4.4 1169.95
O2 0 0 2.5 98.18
CO 5.79 1684.13 5.72 98.79
CH4 3.39 1640.49 3.36 248.79 232.25
CO2 16.23 1732.13 16.15 94.18
C2H2 8.66 3056.34 8.63 192.9 161.3
C2H4 9 3253.34 8.97 185.84 146.98
C2H6 29.4 3279.95 29.36 384.73 306.61
C3H6 42.13 4454.86 42.08 402.9 351.59
C3H8 28.19 4232.11 28.17 308.94 329.66
C3H4 43.77 4433.96 43.72 339.57
iC4H10 32.9 5654.26 32.87 324.09 340.22
nC4H10 33.87 5165.35 33.84 281.9 363.87

calibration data (area method)

H2 729.54 727.39 728.47
150.17 149.68 149.93
O2 843.81
86.76 101.73 102.09 102.15 98.18
CO

CH4 1640.98 1640.69 1640.61 1639.77 1640.38 1640.49

248.54 249.26 248.73 248.53 248.92 248.79
CO2

C2H2 3006.26 3075.96 3086.79 3056.34

192.71 193.81 192.17 192.9
C2H4 3257.34 3257.44 3245.25 3253.34
187.15 186.11 184.27 185.84
C2H6

C3H6

C3H8 4193.32 4327.03 4327.72 4080.38 4232.11

316.98 314.8 299.64 304.34 308.94
C3H4

iC4H10 5660.91 5647.6 5654.26

323.17 325.01 324.09
nC4H10 5486.82 4843.88 5165.35
296.72 267.08 281.9

calibration data (height method)

CH4 232.28 232.21 232.24 232.25 232.23 232.25
C2H2
C2H4 146.88 146.94 147.12 146.98
C3H8 206.69 206.69 197.87 203.75
iC4H10 259.9 258.22 259.06
nC4H10 256.69 235.01 245.85
 Experiment of Methane Kinetic Conversion
ZnCr2O4 @ 30 mL/min

frequency 20 kHz sample volume 500 uL

flow rate 30 mL/min mole sample 0 mol

power 60 W 80 W 90 W
before after before after before after
FID (flow rate) 41.16 37.7 41.17 37.7 41.17 34.7
3.62 3079.14 2336.32 3079.14 2134.15 3079.14 2020.87
11.11 0 50.77 50.24
13.66 247.01 274.28 281.29
25.50 56.33 123.72 126.81
34.03 5.37 6.48
35.75 5.73 23.01 24.39

TCD
1.99 126.34 149.16 156.69
3.68 190.23 146.47 190.23 134.58 190.23 129.97
power
V (kV) 2.77
I (mA) 24.82
total mol
FID 0 0 0 0 0 0
TCD 0 0 0 0 0 0
calculation 0 0 0 0 0 0
FID FID TCD FID TCD FID TCD
3.62 30.50 29.48 36.52 35.21 44.67 42.40
11.11 0.00 0.00 4.48 5.29 3.33 4.00
13.66 24.68 29.09 22.89 27.04 17.67 21.20
25.50 5.95 7.01 10.91 12.89 8.41 10.09
34.03 0.00 0.00 0.51 0.60 0.46 0.56
35.75 0.66 0.77 2.20 2.60 1.75 2.10

TCD
1.99 29.90 35.24 29.48 34.83 23.31 27.96
3.68
power (Watt) 50.00
RMS 68.85 0.00 0.00
integration
C total 31.29 36.87 40.99 48.42 31.63 37.95
H total 47.14 55.55 51.95 61.38 40.68 48.81

non
 run 1 2 3
before after before after before after
FID 41.17 39.34 41.17 40.21 41.17 40.82
3.62 2923.25 1577.61 2923.25 1559.63 2923.25 1593.22
11.11
13.66
25.50
34.03
35.75

TCD
1.99 244.12 246.61 248.9
3.68 189.37 100.56 189.37 99.32 189.37 98.83
power (RMS)
V (kV)
I (mA)
total mol
FID 0 0 0 0 0 0
TCD 0 0 0 0 0 0
calculation 0 0 0 0 0 0
FID FID TCD FID TCD FID TCD
3.62 48.43 49.26 47.89 48.78 45.96 48.25
11.11 0.00 0.00 0.00 0.00 0.00 0.00
13.66 0.00 0.00 0.00 0.00 0.00 0.00
25.50 0.00 0.00 0.00 0.00 0.00 0.00
34.03 0.00 0.00 0.00 0.00 0.00 0.00
35.75 0.00 0.00 0.00 0.00 0.00 0.00

TCD
1.99 39.98 42.70 41.75 44.53 44.58 46.12
3.68
power
RMS
integration
C total 0.00 0.00 0.00 0.00 0.00 0.00
H total 39.98 42.70 41.75 44.53 44.58 46.12

cataly
run 1 2 3
before after before after before after
FID 41.17 38.93 41.17 40.37 41.17 40.73
3.62 2923.25 1546.35 2923.25 1617.68 2923.25 1658.58
1.99 230.72 227.17 221.43
3.68 189.37 98.9 189.37 103.15 189.37 105.62

run 12 13 14
FID 41.17 42.95 41.17 43.37 41.17 43.56
 3.62 2923.25 1728.79 2923.25 1692.92 2923.25 1819.67
1.99 212.25 219.38 195.22
3.68 189.37 108.44 189.37 105.96 189.37 113.68

run 23 24 25
FID 41.17 44.25 41.17 44.1 41.17 44.39
3.62 2923.25 1827.82 2923.25 1838.79 2923.25 1813.80
1.99 192.28 190.23 194.14
3.68 189.37 114.32 189.37 115.21 189.37 113.45

run 34 35 36
FID 41.17 44.09 41.17 44.36 41.17 44.25
3.62 2923.25 1843.03 2923.25 1849.86 2923.25 1883.87
1.99 188.69 185.43 179.63
3.68 189.37 114.95 189.37 115.80 189.37 118.15

run 45 46 47
FID 41.17 43.26 41.17 43.2 41.17 42.2
3.62 2923.25 1951.41 2923.25 2003.92 2923.25 2043.30
1.99 168.23 159.40 154.20
3.68 189.37 121.60 189.37 124.91 189.37 128.04

run 1 2 3
49.98 50.61 45.73 46.59 43.86 44.81
36.24 38.87 40.44 43.12 41.48 44.09

run 12 13 14
38.30 40.26 38.99 41.05 34.13 36.48
48.01 49.61 49.22 50.78 50.24 51.06

run 23 24 25
32.79 35.11 32.61 34.82 33.10 35.41
55
52.32 53.07 51.88 52.77 52.50 53.31
50

run 34 45 35 36
CH4 conversion (%)

32.48 40 34.99 31.82 34.11 30.73 32.94

51.65 35 52.07 52.13 52.81 52.16 52.86
30
run 45 25 46 47
29.86 32.53 28.07 30.79 28.34 30.68 Column B
20 Column H
49.15 49.01 49.47 48.99 46.31 46.46
15
10

report power 5

conversion
0 error C2H2 error C2H6
60.00 Row29.99
Row Row Row
0.72 Row Row
0.00 Row Row
0.00 Row Row
26.89
159 160 161 162 163 164 165 166 167 168
70.00
80.00 35.86 Sampling
0.93 time
4.88(min.) 0.57 24.97
90.00 43.54 1.60 3.67 0.47 19.43
100.00
 110.00 43.62 1.72 3.63 0.48 20.45
120.00
130.00 45.27 1.32 4.14 0.50 22.13

run conversion H2 error time run

1 48.84 41.34 1.92 16 1
2 48.34 43.14 1.96 32 2
3 47.11 45.35 1.09 48 3
4 46.19 45.23 2.24 64 4
5 46.15 44.78 2.33 80 5
6 45.06 46.39 2.18 96 6
7 43.56 46.56 2.05 112 7
8 43.04 46.98 2.08 128 8
9 42.97 47.00 2.85 144 9
10 43.04 47.50 1.53 160 10
11
12
13
14
15
16
17
18
19
20
21
22
23
100.00% 24
25
90.00%
26
80.00% 27
70.00% 28
unknown
Selectivity

60.00% 29
n-C4H10
50.00% 30
i-C4H10 31
40.00%
C3 32
30.00% 33
C2H6
20.00% 34
C2H2
10.00% 35
H2 36
0.00%
60.0 70.0 80.0 90.0 100. 110. 120. 130. 37
0 0 0 0 00 00 00 00 38
39
Supplied power (kW)
40
41
42
70
43
60 44
45
Conversion (%)

50

40

30

20
 70

60

Conversion (%)
50 46
40 47

30

20

10

0
40 50 60 70 80 90 100 110 120 130
Supplied power (kW)

50
45
40
H2 selectivity (%)

35
30
25
20 Column C
Column I
15
10
5
0
Row Row Row Row Row Row Row Row Row Row
159 160 161 162 163 164 165 166 167 168

Sampling time (min.)

e Kinetic Conversion
0 mL/min

power effect
110 W 130 W
before after before after before after before
41.17 37.68 41.17 38.13
3079.14 1855.93 3079.14 1788.21
45.86 53.71
273.10 303.33
131.36 147.65
21.20 21.83
32.90 35.94

179.77 202.66
190.23 119.71 190.23 114.30

2.61
24.02

0 0 0 0 0 0 0
0 0 0 0 #DIV/0! #DIV/0! #DIV/0!
0 0 0 0 #DIV/0! #DIV/0! #DIV/0!
FID TCD FID TCD FID TCD FID
44.83 42.41 46.20 44.34 #DIV/0! #DIV/0! #DIV/0!
3.29 3.96 3.79 4.49 #DIV/0! #DIV/0! #DIV/0!
18.56 22.34 20.24 24.02 #DIV/0! #DIV/0! #DIV/0!
9.43 11.35 10.41 12.35 #DIV/0! #DIV/0! #DIV/0!
1.64 1.98 1.66 1.97 #DIV/0! #DIV/0! #DIV/0!
2.56 3.08 2.74 3.26 #DIV/0! #DIV/0! #DIV/0!

28.93 34.83 32.02 38.00 #DIV/0! #DIV/0! #DIV/0!

35.00 51.00
62.60 0.00 0.00

35.47 42.71 38.83 46.08 #DIV/0! #DIV/0! #DIV/0!

48.63 58.55 53.55 63.55 #DIV/0! #DIV/0! #DIV/0!

non catalytic
 4 5 6 7
before after before after before after before
41.17 41.12 41.17 41.11 41.17 41.52 41.17
2923.25 1583.38 2923.25 1582.55 2923.25 1603.16 2923.25

241.54 239.05 239.39

189.37 101.47 189.37 101.72 189.37 102.48 189.37

0 0 0 0 0 0 0
0 0 0 0 0 0 0
0 0 0 0 0 0 0
FID TCD FID TCD FID TCD FID
45.90 46.48 45.94 46.37 44.69 45.42 43.11
0.00 0.00 0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00 0.00 0.00

43.65 46.81 43.13 46.42 44.85 47.93 45.11

0.00 0.00 0.00 0.00 0.00 0.00 0.00

43.65 46.81 43.13 46.42 44.85 47.93 45.11

catalytic reaction
4 5 6 7
before after before after before after before
41.17 41.19 41.17 41.85 41.17 42.13 41.17
2923.25 1631.2 2923.25 1697.68 2923.25 1719.45 2923.25
229.01 217.13 211.61
189.37 103.61 189.37 107.29 189.37 108.93 189.37

15 16 17 18
41.17 43.41 41.17 43.69 41.17 43.54 41.17
 2923.25 1834.27 2923.25 1824.57 2923.25 1840.53 2923.25
191.53 194.40 190.54
189.37 114.60 189.37 114.38 189.37 115.37 189.37

26 27 28 29
41.17 44.62 41.17 44.43 41.17 44.49 41.17
2923.25 1775.35 2923.25 1822.73 2923.25 1837.19 2923.25
201.63 193.32 189.41
189.37 111.24 189.37 113.90 189.37 114.91 189.37

37 38 39 40
41.17 43.9 41.17 44.09 41.17 43.94 41.17
2923.25 1950.47 2923.25 1923.22 2923.25 1925.53 2923.25
174.21 173.90 172.96
189.37 120.20 189.37 120.66 189.37 119.96 189.37

48 49 50 51

4 5 6 7
44.17 45.26 40.96 42.40 39.80 41.13 38.66
43.07 45.66 44.75 46.96 45.18 47.49 46.95

15 16 17 18
33.84 36.19 33.75 35.89 33.41 35.57 32.29
49.55 50.32 50.76 51.84 50.07 51.09 51.20

26 27 28 29
34.17 36.33 32.70 35.08 32.08 34.42 30.85
53.11 54.26 52.98 53.64 52.98 53.63 53.72

37 38 39 40
28.84 32.31 29.54 31.76 29.70 32.39 28.95
53.47 51.86 52.33 52.87 51.60 51.39 51.50

Column B
Column H

error C3 error i-C4H10 error n-C4H10 error

w Row 3.12 19.43 18.33 0.00 0.00 3.57 4.04
7 168

2.94 17.85 8.53 2.79 3.15 11.98 13.56

2.50 27.76 26.20 2.55 2.89 9.64 10.91
 2.68 20.78 14.76 9.04 10.23 14.09 15.95

2.67 11.38 1.37 9.07 10.26 15.00 16.98

conversion H2 error time

50.30 37.56 1.86 18
46.16 41.78 1.89 34
44.33 42.78 1.85 50
44.71 44.36 1.83 66
41.68 45.85 1.56 82
40.46 46.34 1.63 98
39.51 47.90 1.35 114
40.08 47.46 1.20 130
38.29 48.21 1.31 146
36.99 48.90 1.17 162
36.85 48.80 0.91 21
39.28 37.56 1.86 37
40.02 41.78 1.89 53
35.31 42.78 1.85 69
35.01 44.36 1.83 85
34.82 45.85 1.56 101
34.49 46.34 1.63 117
33.39 47.90 1.35 133
34.17 47.46 1.20 149
33.68 48.21 1.31 165
32.90 48.90 1.17 16
36.85 48.80 0.91 32
33.95 52.69 0.53 48
33.72 52.33 0.63 64
34.25 52.91 0.58 80
35.25 53.68 0.81 96
33.89 53.31 0.47 112
33.25 53.30 0.46 128
31.88 54.20 0.68 144
32.47 52.32 0.32 160
32.21 53.02 0.25 17
31.85 52.48 0.56 33
32.37 51.90 0.33 49
33.74 51.86 0.30 65
32.97 52.47 0.48 81
31.84 52.51 0.50 97
30.58 52.67 1.14 113
30.65 52.60 0.38 129
31.04 51.50 0.15 145
30.14 51.59 0.12 161
30.73 41.47 14.14 18
29.60 41.05 14.14 36
28.24 40.42 14.14 54
29.71 39.35 14.14 72
31.19 49.08 25.37 90
29.43 49.08 27.86 108
29.51 49.08 27.73 126
after before after before after before after

0 0 0 0 0 0 0
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
TCD FID TCD FID TCD FID TCD
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!

#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!

50.00 36.00 50.00 50.00

0.00 0.00 0.00 0.00

#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!

#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
7 8 9 10
after before after before after before after
41.99 41.17 42.21 41.17 42.43 41.17 42.37
1630.29 2923.25 1635.97 2923.25 1615.78 2923.25 1640.43

229.63 227.81 226.24 229.42

103.96 189.37 104.40 189.37 104.92 189.37 103.33

0 0 0 0 0 0 0
0 0 0 0 0 0 0
0 0 0 0 0 0 0
TCD FID TCD FID TCD FID TCD
44.00 42.62 43.47 43.03 42.90 42.24 43.83
0.00 0.00 0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00 0.00 0.00

48.01 45.51 48.45 44.98 49.01 46.42 48.58

0.00 0.00 0.00 0.00 0.00 0.00 0.00

48.01 45.51 48.45 44.98 49.01 46.42 48.58

7 8 9 10
after before after before after before after
42.77 41.17 42.58 41.17 42.78 41.17 43.07
1726.05 2923.25 1719.93 2923.25 1759.71 2923.25 1785.69
210.45 212.45 205.26 199.72
108.72 189.37 107.97 189.37 110.92 189.37 112.42

18 19 20 21
43.78 41.17 44.2 41.17 44.43 41.17 44.31
 1860.99 2923.25 1822.64 2923.25 1827.44 2923.25 1852.34
187.21 192.40 191.60 187.21
116.62 189.37 114.15 189.37 114.34 189.37 116.08

29 30 31 32
44.59 41.17 44.26 41.17 44.39 41.17 44.22
1866.42 2923.25 1868.71 2923.25 1871.10 2923.25 1883.72
184.30 182.50 182.94 179.74
117.29 189.37 116.83 189.37 116.92 189.37 118.24

40 41 42 43
43.83 41.17 44.05 41.17 43.75 41.17 43.4
1950.64 2923.25 1928.75 2923.25 1968.67 2923.25 2023.37
168.64 170.68 164.16 155.98
122.11 189.37 120.27 189.37 123.37 189.37 126.73

51 52 53 54

8 9 10
40.36 39.14 41.02 37.45 39.14 36.09 37.89
48.85 46.62 48.31 47.28 49.14 48.07 49.73

19 20 21
34.50 33.06 35.28 32.52 34.83 31.79 34.02
52.05 51.88 52.80 52.79 53.55 52.63 53.42

30 31 32
32.92 31.27 33.67 30.99 33.43 30.78 32.93
54.68 52.09 52.55 52.85 53.20 52.08 52.88

41 42 43
31.34 29.41 32.05 28.43 30.76 27.04 29.45
51.67 51.56 51.38 50.95 51.14 50.49 50.34

H2 error unknown
32.57 3.77 17.54

32.16 3.78 5.37

30.64 7.80 6.32
31.88 4.17 0.13

35.01 4.23 3.27

before after

0 0
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
FID TCD
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!

#DIV/0! #DIV/0!

0.00

#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
 11
before after
41.17 42.82
2923.25

224.38
189.37 105.02

0 0
0 0
0 0
FID TCD
100.00 42.31
0.00 0.00
0.00 0.00
0.00 0.00
0.00 0.00
0.00 0.00

19.38 49.75

0.00 0.00
19.38 49.75

11
before after
41.17 43
2923.25 1796.62
198.86
189.37 112.63

22
41.17 44.25
2923.25 1874.67
184.21
189.37 117.39

33
41.17 44.16
2923.25 1875.31
180.92
189.37 117.28

44
41.17 43.3
2923.25 1989.57
160.95
189.37 124.23

55

11
35.81 37.88
48.15 49.44

22
31.06 33.36
52.92 53.52

33
31.18 33.57
51.67 52.14

44
28.41 31.00
49.46 49.24
 Experiment of M
power @ 90 and 120W

frequency 20 kHz sample volume 500 uL

flow rate 30 mL/min mole sample 0 mol

run 1 2 3
before after before after before after
FID (flow rate) 38.55 37.7 38.55 37.7 38.55 34.7
3.62 3054.16 1683.35 3054.16 1794.31 3054.16 1846.76
11.11 92.16 76.56 62.43
13.66 341.27 332.71 311.05
21.65 45.82 39.31 24.21
34.03
35.75

TCD
1.99 235.78 205.94 193.88
3.68 191.87 106.48 191.87 114.57 191.87 115.79
power
V (kV)
I (mA)
total mol
FID 0 0 0 0 0 0
TCD 0 0 0 0 0 0
calculation 0 0 0 0 0 0
FID FID TCD FID TCD FID TCD
3.62 46.09 45.72 42.54 41.60 45.57 45.67
11.11 6.93 7.83 6.24 7.15 4.37 4.89
13.66 24.30 27.43 25.67 29.40 20.62 23.04
21.65 3.45 3.89 3.20 3.67 1.70 1.89
34.03 0.00 0.00 0.00 0.00 0.00 0.00
35.75 0.00 0.00 0.00 0.00 0.00 0.00

TCD
1.99 39.76 44.89 37.63 43.10 30.44 34.01

power (Watt)
RMS
integration
C total 34.68 35.11 51.63
H total 56.22 54.42 43.11

run 1 2 3
before after before after before after
FID (flow rate) 38.55 37.7 38.55 37.22 38.55 41.15
3.62 3054.16 1834.18 3054.16 1751.48 3054.16 1762.59
11.11 77.64 58.58 47.35
13.66 328.20 293.64 278.70
21.65 169.08 152.06 138.10
34.03 39.68
35.75 44.33

TCD
1.99 203.02 200.95 184.24
3.68 191.87 115.95 191.87 112.11 191.87 116.28
power
V (kV)
I (mA)
total mol
FID 0 0 0 0 0 0
TCD 0 0 0 0 0 0
calculation 0 0 0 0 0 0
FID FID TCD FID TCD FID TCD
3.62 41.26 40.89 44.63 43.58 38.39 35.31
11.11 5.84 6.59 4.77 5.47 3.32 3.71
13.66 23.37 26.38 22.65 25.95 18.47 20.65
21.65 12.72 14.36 12.39 14.19 9.67 10.81
34.03 3.22 3.63 0.00 0.00 0.00 0.00
35.75 3.61 4.08 0.00 0.00 0.00 0.00

TCD
1.99 34.23 38.65 36.71 42.05 28.93 32.32

power 80.00 80.00 80.00

RMS 0.00 0.00 0.00
integration
C total 48.75 79.67 51.38
H total 60.93 58.53 46.24

report
90 W conversion C2H2 C2H2 C2H6 C2H6 C3H8
1 45.91 6.93 7.83 24.30 24.43
2 42.07 6.24 4.89 25.67 24.40
3 45.62 4.37 7.00 20.62 23.04
4 42.17 5.11 5.75 23.77 26.76
5 41.86 5.22 6.04 22.33 25.81
6 35.65 6.79 7.97 25.76 23.74
7 35.13 8.01 7.47 23.33 24.03
8 31.46 8.28 5.83 24.75 21.26
 120 W conversion C2H2 error C2H6 error C3H8
1 41.08 6.22 1.76 24.87 2.62 12.72
2 44.10 5.12 2.31 27.53 5.13 12.39
3 36.85 3.51 1.62 21.83 3.56 9.67
4 33.30 4.58 1.28 25.27 5.83 10.78

plasma CH4 selectivity (%)

only conversion (%) H2 C2H2 C2H6 C3H6
plasma 54.97 35.29 4.85 20.89 2.01
51.11 29.22 7.36 23.19 3.36
25.01 34.77 5.06 25.48 1.73
22.37 38.46 9.30 42.75 2.98
thermal 54.95 65.73 0.00 0.00 0.00
50.42 68.58 0.00 0.00 0.00
25.60 77.57 0.00 0.00 0.00
13.35 84.04 0.00 0.00 0.00
7.05 91.60 0.00 0.00 0.00

28

25
23
20
Selectivity (%)

18
15
13

10
8
5

3
0
Row 94 Row 95 Row 96 Row 97 Row 98 Row 99 Row 100 Row 101

Sampling time (min.)

 Experiment of Methane Conversion
power @ 90 and 120W and flowrate @ 30 mL/min

90 W
4 5 6 7
before after before after before after before
38.55 37.68 38.55 37.83 38.55 41.49 38.55
3054.16 1803.77 3054.16 1788.84 3054.16 1802.94 3054.16
62.31 63.82 64.91
306.47 288.33 290.54
12.27 5.64 3.94

191.17 190.37 185.5

191.87 113.73 191.87 114.95 191.87 116.20 191.87

0 0 0 0 0 0 0
0 0 0 0 0 0 0
0 0 0 0 0 0 0
FID TCD FID TCD FID TCD FID
42.27 42.06 42.52 41.20 36.47 34.82 36.08
5.11 5.75 5.22 6.04 6.79 7.97 8.01
23.77 26.76 22.33 25.81 28.76 33.74 31.33
1.01 1.13 0.46 0.53 0.41 0.48 0.24
0.00 0.00 0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00 0.00 0.00

35.12 39.54 34.92 40.36 43.50 51.02 48.98

71.16 70.53 72.44 75.66

49.04 47.73 59.88 66.83

120 W
4
before after before after before after before
 38.55 41.95
3054.16 1834.09
52.63
258.91
131.56
6.95
9.01

172.06 190.37 185.5

191.87 119.96 191.87 114.95 191.87 116.20 191.87

0 0 0 0 0 0 0
0 0 0 0 0 0 0
0 0 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
FID TCD FID TCD FID TCD FID
34.65 31.96 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
4.31 4.86 0.00 0.00 0.00 0.00 0.00
20.08 22.61 0.00 0.00 0.00 0.00 0.00
10.78 12.14 0.00 0.00 0.00 0.00 0.00
0.61 0.69 0.00 0.00 0.00 0.00 0.00
0.80 0.90 0.00 0.00 0.00 0.00 0.00

31.61 35.59 34.92 40.36 43.50 51.02 48.98

80.00 80.00 80.00

0.00 0.00 0.00

36.59 0.00 #DIV/0! #DIV/0!

51.66 34.92 43.50 48.98

error i-C4H8 error n-C4H8 error H2 error

 error i-C4H8 error n-C4H8 error H2 error
10.36 3.43 4.63 3.84 2.19 36.44 2.71
12.19 0.00 0.00 0.00 0.00 39.38 3.77
10.81 0.00 0.00 0.00 0.00 30.62 2.40
12.14 0.65 0.05 0.85 0.07 33.60 2.81

lectivity (%)
C3H8 n-C4H10 i-C4H10
12.42 5.90 4.64
13.33 6.11 7.37
13.89 4.42 4.95
19.79 5.85 7.67
0.00 0.00 0.00
0.00 0.00 0.00
0.00 0.00 0.00
0.00 0.00 0.00
0.00 0.00 0.00

0 Row 101
7 8
after before after
43.45 38.55 44.32
1732.07 3054.16 1796.25
72.36 65.79
298.83 291.74
2.16 0.00

197.28 183.39
112.04 191.87 115.90

0 0 0
0 0 0
0 0 0
TCD FID TCD
34.18 32.38 30.55
9.47 8.28 9.83
37.03 34.75 41.26
0.28 0.00 0.00
0.00 0.00 0.00
0.00 0.00 0.00

57.90 51.74 61.43

75.42
71.19

after before after

 197.28 183.39
112.04 191.87 115.90

0 0 0
0 0 0
#DIV/0! #DIV/0! #DIV/0!
TCD FID TCD
#DIV/0! #DIV/0! #DIV/0!
0.00 0.00 0.00
0.00 0.00 0.00
0.00 0.00 0.00
0.00 0.00 0.00
0.00 0.00 0.00

57.90 51.74 61.43

80.00 80.00
0.00 0.00

#DIV/0!
51.74