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d v = 6V / π 3
d Sauter = 6V / A
V and A … real particle volume and surface
area.
Chee 3920: Particle Size and Shape 5
Example of equivalent diameters for a particle
with a shape of rectangular box
Dimension (mm) 20 x 30 x 40
2
Surface area (mm ) 5200
3
Volume (mm ) 24000
dv (mm) 35.8
ds (mm) 40.7
dSauter (mm) 27.7
18µU
d Stokes =
g (ρ −δ )
Is described by sphericity.
ψ VA = π ( d32 ) / A
2
ψ AV = π ( d32 ) / ( 6V )
3
i =1
i =1
∑γ d
3
i i
d32 = i =1
m
∑γ d
2
i i
i =1
Sieve Analysis
Chee 3920: Particle Size and Shape 14
- Good for particle >25 µm, cheap & easy.
- Carried out by passing sample via a series of
sieves (Fig 2.1)
- Weighing the amount collected on each sieve
- With wet or dry samples.
• Test sieves
• Designed by the norminal aperture size (Fig
2.2)
• Popular designs: BSS (British), Tyler series
(American), DIN (German).
Smallest
aperture
u=
( ρ − δ ) gd 2
18µ
where ρ and δ are particle and liquid density, g
is gravity acceleration and µ is liquid viscosity.
• Experimental steps:
- Sample is uniformly dispersed in water in a
beaker.
- A siphon tube is immersed into 90% of the
water depth.
Chee 3920: Particle Size and Shape 21
- Particle with size d is sucked from the beaker
at time interval t calculated from the
immersed depth and Stokes’ velocity: t = h / u .
Two-way stopcock
i =1 i =1
• Frequency distribution
- Histogram: mass of size range versus size
range.
- Normalised histogram: mass fraction vs size
range.
- Continuous distribution function: mid-points of
mass fraction vs mid-points of size range
Chee 3920: Particle Size and Shape 24
40
Mass versus size range
30
10
0
0 - 50 50 - 100 100 - 150 150 - 200
Size range (micron)
0.2
0.1
0
0 - 50 50 - 100 100 - 150 150 - 200
Size range (micron)
0.4
Midpoint of mass fraction versus
midpoint of size range
0.3
f(d)
0.2
0.1
0
0 50 100 150 200
d (microns)
1
1 d − d
2
f (d ) = exp −
σ 2π 2 σ
σ … standard deviation of the distribution
d … mean (median) diameter
∞
Property: ∫ f ( d ) dd = 1
−∞
or ∑ f ( d ) ∆d = 1 .
i
0.5
0
0 50 100 150 200
d (microns)
1
1 x − x
2
f ( x) = exp −
σ 2π 2 σ
where x = log ( d ).
σ … standard deviation of the distribution
d … mean (median) diameter
∞
Property: ∫ f ( x ) dx = 1
−∞
or ∑ f ( x ) ∆x = 1 .
i
1.5 1.5
f(d)
f(d)
1 1
0.5 0.5
0 0
0 50 100 150 200 0.5 1.5 2.5
d (microns)
log(d/microns)
No details of fines
can be seen in the
normal-normal plot
d + d 2 + ... + d n ∑d i
Arithmetic mean d= 1
n
= i =1
( d1 ) + ( d 2 ) + ... + ( d n )
2 2 2
1 n
Quadratic mean ( d ) ∴ ∑ i ( )
2
d=
2
= d
n n i =1
∑ (1/ d ) i
i=1
0.5
0.4
0.3
f(d)
0.2
0.1
0
0 50 100 150 200
d (microns)
f(d) 2
0
0 50 100 150 200
d (microns)
• Cumulative distributions
- Undersized cumulative distribution
m
Q ( di ) = ∑ γ i
i =1
0.400
0.200
0.000
0 50 100 150 200
d (microns)
{ }
log − ln P ( d ) = n log ( d ) − n log ( d ')
0.8 0
log{-ln[P(d)]}
0.6 -1
P(d)
0.4 -2
0.2 -3
0 -4
0 50 100 150 200 0 1 2 3
d (microns) log(d/micron)
n =1
n>1
d
Chee 3920: Particle Size and Shape 45
• Relationship between frequency and
cumulative distributions
d d min
P(d ) = ∫ f ( x ) dx ; Q ( d ) = ∫ f ( x ) dx .
d max d
Differential relationships:
dP
= f ( d ) => f(d) is also called differential frequency distribution!
dd
dQ
= − f (d )
dd
(M Rhode, 1998)
Surface distribution: f s ( d ) = k S d f N ( d )
2
∫ f ( d ) dd = 1
0