Professional Documents
Culture Documents
The Rock River Basin covers over 3,700 square miles and is located in the south central part of Wisconsin. The Basin's natural resources are the legacy of the last period of Wisconsin glaciation. Many Native American tribal peoples lived here because of the outstanding land, water, and wildlife resources in the Basin. European settlers described the Basin as a paradise of fertile soils, large forests, and many clear sparkling rivers and lakes. Much has changed over the last 150 years. Today, most of the prairies and oak savannas are gone, the wetlands are diminished by 50%, and most forests have been cut down to make way for agriculture. Currently, agriculture dominates the land use; however urbanization in the Basin is growing rapidly. Overall, some of the Rock River Basin's natural resources are slightly improved compared to 20 years ago. Land management and forestry law changes have supported a small increase in forests in the Basin. Better treatment at wastewater treatment plants has improved water quality in some stretches of streams. Yet today, most water bodies in the Basin remain significantly impacted by soil and nutrients washing into the streams and lakes from urban and rural storm water runoff. Wildlife habitat continues to be lost and fragmentation of habitat accelerates. Today, the most serious challenges facing the Basin include:
Water quality impacts and increased runoff quantity from agriculture and urban land uses, such that many of the rivers and streams are not meeting water quality standards.
Loss of agricultural lands, with its effect on wildlife habitat, recreational usages, the rural landowners, and economy. Loss of critical sensitive habitat and connection between habitats. Lower urban groundwater levels due to increased use and decreased groundwater infiltration due to more acres of impervious land. Significant groundwater contamination in areas of the Basin.
WDNR Groundwater Section (GS) staff should work with regional staff to develop wellhead protection plans for communities in the Lower Rock River Basin. For Wellhead Protection plans in Dane County, WDNR Groundwater Section (GS) staff and others should utilize data and information from the Dane County Hydrologic Model to develop wellhead protection plans for communities in the Lower Rock River Basin. GS staff should work with communities in the Lower Rock River Basin to identify potential funding sources for wellhead protection plan implementation.
GS staff should work with regional staff to identify important source water areas in the Lower Rock River Basin. GS staff should work with regional staff and the WDNR Bureau of Communication and Education Strategy to evaluate the adequacy of existing materials concerning Lower Rock River Basin-specific groundwater educational information. GS staff should work with regional staff to identify and inventory pollution sources and potential sources in the basin. GS staff should work with regional staff to prepare and analyze maps of nitrate, pesticide, volatile organic compounds, metals and radioactive detects in the watersheds of the Lower Rock River Basin. GS staff should continue to support sampling and inventorying of wells, including the use of Wisconsin Unique Well Numbers.
Groundwater Concepts
Only 3 percent of the world's water supply is available to humans as fresh water. Of this small amount, 98 percent exists as groundwater. To understand the occurrence and movement of groundwater in a particular locality, it is first necessary to understand the interactions between water, the land and the atmosphere, called the hydrologic cycle. This cycle begins as water evaporates from waterbodies, land surfaces and vegetation on a continental scale. The water vapor moves through the atmosphere until it condenses into droplets, which then fall onto the land or sea as precipitation. Precipitation that falls on land continues through the hydrologic cycle via a number of different paths. If the ground is impermeable or already saturated, some water will flow across the land surface to streams and lakes as overland flow. If the land surface is permeable and not fully saturated, water will filter into the ground. Some of that water will be taken up by growing plants and transpired back into the atmosphere. Excess water will continue to move downward under the influence of gravity. At some depth, the downward moving water will reach the water table where the formation is saturated. Groundwater is water found in saturated rock and soil formations. These formations may be consolidated bedrock, such as limestone or sandstone, or they may be loose unconsolidated deposits of sand, gravel or silt and clay. Water is stored in areas between rock and soil particles ("interstitial spaces"). The relative volume of these spaces is known as porosity. Groundwater moves via gravity through porous materials and discharges to lakes, streams, wetlands or pumping wells. The size and interconnection of the spaces within the rock and soil controls the rate water flows through the material and is known as permeability. The layer where useable water is stored is called the aquifer. "Unconfined" aquifers occur where unsaturated porous material overlies saturated material. Where this occurs, the upper surface of the saturated zone is called the water table. The water table generally follows the contour of the ground surface terrain and can be mapped by examining well depth in these contoured areas. Aquifers may also be bounded at the top and bottom by impermeable layers called aquitards or confining beds. These beds are typically of clay or shale, but may be composed of granite or other impermeable rock. Under confining conditions the water table does not determine flow directions. A map of the piezometric surface can be made by comparing the levels to which the water rises in wells, reflecting the pressure the water is under in that portion of the aquifer.
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Groundwater is made up of rainfall or snowmelt that percolates down through the soil until it reaches the saturated zone of an aquifer. This process is known as aquifer recharge. Recharge may take place throughout the aquifer, but occurs principally in aquifer recharge areas. These are usually located in the uplands. Lowlands tend to be discharge areas where groundwater is discharged to surface waters. Surface watersheds can usually be used to approximate shallow groundwater hydrologic boundaries when specific information is not available. Surface watershed boundaries and groundwater divides do not, however, always coincide. Specific site investigations require the use of detailed hydrologic maps or field data to properly identify groundwater flow patterns. Regional groundwater flow in Wisconsin is similar to surface topography. Groundwater usually enters the aquifer in upland areas and flows toward low points in a drainage basin. Sometimes it reaches the surface in the form of springs or artesian wells or seeps into swamps or rivers and lakes. These are called discharge areas. That portion of stream flow comprised of groundwater contributions is called base flow. Streams in the Lower Rock River Basin are comprised of base flow and overland flow.
Glacial Deposits
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Glaciers of the Pleistocene Era were formed by the continental accumulation of snow and reached a maximum thickness of two miles. The ice sheet that spread over Canada into Wisconsin during this time transported a great deal of rock debris called drift. As the ice melted, large amounts of sand and gravel were deposited forming outwash plains. The glacial drift that forms the surface layer of the Rock River Basin is either stratified or unstratified. Stratified drift is from ice-contact deposition or from outwash ("outwash drift") carried by glacial meltwater. This stratified drift occurs primarily in areas of lakes and impoundments in river headwaters. Unstratified drift consists of ground moraine, a sheet of unsorted sandy clay till laid down directly by ice; end moraine, ridges of boulder-strewn till laid down by ice during pauses in glacial advance or retreat; and unpitted or pitted outwash, or lake deposits. Pits were formed in the outwash where buried blocks of ice melted; many of these pits are now lakes or wetlands. Large lakes formed in front of the glaciers and clayey lacustrine deposits settled out in these basins. These glacial deposits were transported by glacial ice or meltwater within the last million years. The most recent deposits were left as the Green Bay and Lake Michigan Lobes retreated from the area around 10,000 years ago. The entire basin falls within the glaciated part of the state, although much of the older till in southern Rock County has been eroded away. South of the terminal moraine the glacial deposits consist of patchy old clayey tills, pitted outwash to the southeast and deep alluvial sand and gravel in the river valley. The moraine is composed of course gravel, sand and stony till. To the north are lacustrine deposits, spotty outwash and sandy till. A large drumlin field--hills elongated in the direction of ice flow--and several recessional moraines cross eastern Dane and Jefferson Counties.
Aquifers
Most of the basin is covered by a layer of glacial deposits. Glacial deposits often supply sufficient amounts of water for domestic purposes where they are thicker and more extensive. Within the basin, sand and gravel deposits are abundant, particularly in the river valleys. Wells finished in the unconsolidated materials can supply sufficient amounts of water for domestic supplies and municipal supplies in the river valley. A well at Janesville yields 5,450 gallons per minute (gpm) for 24 hours with only seven feet of drawdown. Aquifer tests in Beloit indicated a transmissivity of 1,200,000 gpd per foot. The underlying sandstone has a has a transmissivity of about 33,000 gpd per foot sustaining yields up to 1,200 gpm. The dolomite aquifers are much more variable and will range from 0-50,000 gpd per foot depending on the amount of fracturing and karst development. Wells in the basin are finished, or draw water from three of the four aquifers of the state. Sand and gravel wells are distributed throughout the basin, but are less common in Dane County. Most of these wells are shallower and the majority are domestic with the exception of high capacity wells in the alluvial deposits in Rock County. The shallow wells are susceptible to contamination. Many subdivisions have histories of nitrate and other human-caused contamination. The Eastern Dolomite Aquifer is confined to the very eastern part of the basin. The aquifer is well protected from surface contamination by fairly thick clayey till deposits. Moving west, bedrock wells are finished in the upper part of the sandstone aquifer. The upper sandstone aquifer is comprised of the Sinnippe group (dolomites), the St. Peter sandstone and the Prairie du Chien dolomite. This aquifer is the most commonly drilled to in the
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basin. The distribution of wells in this aquifer is even throughout the basin except where the formations are absent, such as in the Yahara and Rock valleys. The lower sandstone aquifer is primarily tapped by municipal systems in the western and southern parts of the basin. In Dane County, where the Cambrian rocks are nearer the surface, many domestic wells also draw water from these formations.
Sandstone Aquifer
The Sandstone is made up of the Cambrian and Ordovician sandstones and dolomites. It is separated from the Silurian aquifer by the Maquoketa shale, which subcrops in a north-to-south line through western Waukesha and central Walworth Counties. The younger Ordovician system has more dolomite formations than the Cambrian system. This makes the hydrologic properties somewhat different than the lower system as well as making the shallower system more vulnerable to contamination. Yields are variable depending on the formation and well construction, but they are always sufficient.
Agricultural Practices
Agriculture accounts for 73 percent of the land use in the basin. The use of best management practices (BMPs) can help protect groundwater resources. The UW-Extension and the Department of Agriculture Trade and Consumer Protection (DATCP) provide assistance in the application of agricultural BMPs.
Animal Feedlots
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Animal feedlots are outdoor areas where animals are concentrated for feeding or other management purposes. The principal groundwater pollutants originating from feedlots are nitrates, chlorides, bacteria, oxygen demanding materials, and phosphorus. Water percolating through soil into groundwater may also carry a bad odor and taste. The potential for groundwater pollution from feedlots depends on the design and construction of the lot as well as characteristics in the immediate area and the depth to groundwater. Abandoned feedlots/barnyards contribute more nitrate to groundwater as soil permeability increases. Surface permeability is low as long as livestock are trampling or compacting the surface soils. Factors that may inhibit or increase the occurrence of groundwater contamination are:
Soil characteristics of the feedlot Geology at or near the lot (e.g. depth to bedrock, depth to groundwater) Runoff control practices present Waste handling practices Rainfall Number of animals Spreading waste on snow-covered and sloping terrain that results in runoff to streams and groundwater
Spreading waste on shallow permeable soils. Spreading waste at rates that exceed crop needs or the soil's ability to attenuate nitrogen. Not crediting nitrogen from livestock waste when calculating crop fertility needs.
Spreading livestock waste upgradient from a potable well, allowing runoff to carry wastes to the well. Polluted runoff may infiltrate along the well casing if the casing is not properly grouted. Spreading in areas of bedrock outcrops or known sinkholes.
Irrigation
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Irrigation contributes to groundwater contamination in two ways. First, irrigation water percolating down may carry pollutants such as fertilizers and pesticides through the soil to the groundwater. Second, the malfunction or lack of back-siphoning valves on the irrigation wells may permit contaminated water to flow back into the well, affecting groundwater directly. Studies conducted in the heavily irrigated Central Sands Region of Wisconsin have identified higher concentrations of nitrogen in the soil and groundwater relative to levels in non-irrigated areas. It also found increased levels of pesticide residues in ground and surface water as a result of irrigation. Irrigated agriculture is not very common in most of the basin. The exceptions is on outwash plains south of the terminal moraine in Rock County. Numerous agricultural management strategies and practices have been developed and/or suggested to minimize groundwater contamination. These strategies are addressed in publications from the UW-Extension's Environmental Resource Center, Agricultural Management Practices to Minimize Groundwater Contamination (1987) and Nutrient and Pesticide Best Management Practices for Wisconsin Farms (UW-Extension and DATCP 1989).
Forestry
Forestry is limited in the basin. Logging operations can have adverse affects on groundwater by altering infiltration and recharge rates. Best Management Practices for Water Quality (PUB-FR-093 95) has been developed to assist loggers and landowners in minimizing impacts of logging operations on water quality. It is available from the WDNR Bureau of Forestry. WDNR provides training on the use of best management practices for forestry at sites around the state.
Materials Storage
A wide variety of materials, both solids and liquids are temporarily stored on the ground. Examples include stockpiles of raw materials, chemicals and waste at industrial sites; piles of raw materials at construction sites; stockpiles of chemicals, manure, agricultural products and empty containers in agricultural and industrial areas; and stockpiles of salt for road de-icing (Wis. Admin. Code Trans. 277 regulates storage of highway rock salt piles). Materials are kept in the open or in enclosures such as tanks or sheds. Many of these materials are hazardous, even toxic. If the stored material or waste is water soluble, it will leach out when exposed to rain and infiltrate the soil, which may lead to groundwater pollution.
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The large volume and high concentration of hazardous materials that can be released in a small area from a storage tank creates a high on-site pollution risk. These leaks are not usually detected until a large amount of the chemical has been released. Water supply wells near leaking storage tanks may become contaminated. Industry sources estimate the average cost of "simple" tank cleanup is $70,000 (Knopp). If cleanup operations entail removing and disposing of the leaking tanks and surrounding soil, installing pumping wells and subsequently treating the contaminated water, the cleanup cost can become astronomical.
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Nonmetallic mining includes sand and gravel operations and crushed rock quarries. WDNR is developing rules regarding these operations. Metallic mining is regulated in five distinct parts: 1. exploration--searching for minerals by drilling is regulated under NR 130; 2. prospecting--collection of bulk samples for analysis is regulated under NR 131; 3. mining--the extraction of the minerals is under NR 132; 4. waste disposal-- management of materials and process wastes is regulated under NR 182; 5. and finally the long-term liability of mining companies is established in Stats. 107.30 107.35. Several deposits have been discovered within the basin.
Groundwater Contaminants
WDNR maintains a groundwater database. Sampling is conducted for the purpose of problem assessment, at risk monitoring and some regulatory monitoring. Many of the sampling events are focused on problem areas. The Groundwater Retrieval Network (GRN) inventories more than 10,000 wells within the basin. Sampling for specific parameters is not uniform across the basin and some watersheds have had very little sampling done. Following are the most common categories of groundwater contaminants:
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Biological Hazards
Several areas within the basin have potential for contamination due to shallow depth to fractured dolomite bedrock. Biological agents include bacteria, viruses and parasites. These agents can cause acute illness and life-threatening conditions in some people. Statewide, 23 percent of private well samples test positive for coliform bacteria, a non-pathogenic organism. While not harmful itself, its occurrence indicates the possible presence of dangerous pathogenic organisms. Groundwater contamination by bacteria can occur wherever conditions are favorable, primarily shallow soils and fractured bedrock. Unabandoned wells, open to the surface, serve to directly inject surface bacteria to the aquifer. This may occur also in areas of permeable soils spread with large amounts of manure. Contamination problems are usually worse during groundwater recharge, usually in spring or fall). Note: the highest detection rate is in August and September. Sources of bacterial contamination include animal waste, wastewater from land disposal systems, on-site systems, sewer systems, septage and wastewater spreading, and naturally occurring bacteria. Bacteriological problems affecting humans can usually be avoided if wells are constructed and located according to code. WDNR recommends that well owners test for biological quality annually or when there is a change in water taste, color or odor.
Nitrate
Nitrate-nitrogen is the second most commonly found groundwater contaminant, and frequently exceeds the state drinking water enforcement standard (ES) of 10 milligrams/liter (mg/l) for nitrate + nitrite nitrogen. (Nitrate + nitrite nitrogen will henceforth be referred to as nitrate in this section.) Consumption of water containing high concentrations of nitrate by infants under 6 months can induce methemoglobinemia or "blue baby syndrome," a condition in which hemoglobin is oxidized to a form unable to carry oxygen to body tissues. All infants under 6 months of age are at risk of nitrate poisoning, but some babies may be more sensitive than others. Serious poisonings in infants have occurred following ingestion of water containing nitrate concentrations as low as 50 mg/l, just 5 times the current standard. Fatal poisonings usually involve ingestion of water containing 100-150 mg/l nitrate. The effects of ingesting lower concentrations are not known, but some experts believe a chronic oxygen shortage could result, which could injure an infant's nervous system. Some scientific studies have found evidence suggesting that women who drank nitrate-contaminated water during pregnancy are more likely to have babies with birth defects. Nitrate ingested by the mother may also lower the amount of oxygen available to the fetus. Nitrate is not usually harmful to adults or older children. Although scientists are unsure about the chronic health effects of nitrate, long-term ingestion of water containing high nitrate levels is not recommended. The Department of Health and Family Services (DHFS) and WDNR recommend that all newly constructed private wells and wells that have not been tested during the past five years be tested for nitrate. Testing is recommended for wells used by pregnant women and is essential for wells that serve infants under 6 months old. One study in humans has reported an association between increased methemoglobin levels and spontaneous abortions. Spontaneous abortions were found to possibly be related to ingestion of nitrate contaminated well water (MMWR).
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Nitrate can enter groundwater from many sources, including nitrogen-based fertilizers, animal waste storage and feedlots, municipal and industrial wastewater and sludge disposal, refuse disposal areas, and private sewage systems. Recent studies have shown that about 10 percent of private wells in the state contain nitrate above the ES. This number can be highly variable between counties, but if true, 75,000 of Wisconsin's 750,000 wells exceed the standard of 10 mg/l of nitrate. The rate of 10 percent above the ES was confirmed by work done through the Wisconsin Geologic and Natural History Survey (WGNHS) and DHSS as a summary project using data from existing databases at the Central Wisconsin Groundwater Center (CWGWC), the U. S. Geological Survey (USGS), the Department of Agriculture, Trade and Consumer Protection (DATCP), WGNHS, and WDNR. This summary work indicated that the rate at which nitrate exceeds the ES from each of these existing agency databases ranges from 9 to 14 percent, depending on the dataset used. This data summary project was initiated to compare or validate the data from a U.S. Centers for Disease Control and Prevention (CDC) sampling project, which indicated a statewide rate of 6 percent above the ES. In response to widespread flooding in the summer of 1993, the CDC sponsored a private well sampling program across the nine Midwestern flood-affected states. WDNR Water Supply staff took 636 private well samples--at least eight in each county. Each well was analyzed for nitrates, coliform bacteria, E. coli bacteria, atrazine, radon and some for sulfates and arsenic. A GIS coverage consisting of point locations for each private well sampled was created by the WDNR Water Resources Management Program. The CDC study showed that concentrations of nitrate in groundwater are not uniform across the state. Some undeveloped areas have low nitrate levels, whereas up to 50 percent of rural wells in some agricultural areas of southern Wisconsin exceed the ES for nitrate. Statewide data compiled for the "Nitrate in Wisconsin's Groundwater: Strategies and Challenges" conference in 1994 shows the percentage of wells exceeding the ES range from 3.8 percent in the Bark River watershed to more than 65 percent in the Blackhawk Creek subwatershed. Local areas may have substantially higher percentages of wells exceeding the ES. Data from GRN indicates 24 percent of the wells or 379 wells sampled in the basin had nitrate levels exceeding the ES. Many of the watersheds have had less sampling done and more data is required to fully evaluate groundwater quality. Many of the differences across the basin can be related to variations in nitrogen loading and to differences in soil, geology and groundwater conditions. Due to the concern over nitrate, the Groundwater Coordinating Council (GCC) endorsed a resolution in 1989 recommending that newly constructed water supply wells be sampled for nitrate in addition to coliform bacteria. Also, the Department of Industry, Labor and Human Relations (DILHR) continues evaluating state-of-the-art septic system designs for nitrate removal. DILHR drafted revised private system regulations that would require compliance with the groundwater standards in NR 140. In addition, DATCP has been evaluating the need for regulation of nitrogen-based fertilizers. WDNR and DHSS produced a joint Nitrate in Drinking Water brochure (PUBL-WS-00793REV) to address nitrate education concerns. As is the case with any contaminant in groundwater discharging to a stream, nitrate loading from groundwater can be a significant source in surface water. A study in the Missouri Valley showed groundwater accounted for 84-95 percent of nitrate loading to surface water. Up to 40 percent of the
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nitrates in Chesapeake Bay are attributed to groundwater discharge (USEPA 1994). Locally, research is being conducted on this problem in the Little Plover River watershed.
Pesticides
Pesticide contamination of groundwater may result from general field use according to label directions, or from spills, misuse or improper storage and disposal. Serious concerns about pesticide contamination from runoff in Wisconsin were first raised in 1980 when aldicarb was detected in groundwater near Stevens Point. WDNR, DATCP and other agencies responded to these concerns by implementing monitoring programs and conducting groundwater surveys. WDNR expanded its sampling programs in 1983 to include analysis of pesticides commonly used in Wisconsin. Since many of the pesticides are known to be carcinogenic and some to have a disrupting effect on endocrine systems, federal and state groundwater quality standards for many of these compounds were also adopted. To date, standards for more than 30 pesticides are included in Chapter NR 140, Wis. Adm. Code. Beginning in 1985, DATCP installed about 150 monitoring wells at 50 highly susceptible sites across the state where pesticide use characteristics (e.g., specific compounds and application rates) were known. Data from these wells have been collected quarterly and are used to identify problem pesticides and field use activities that may contribute to groundwater contamination in Wisconsin. To date, the herbicide atrazine has been found at 29 of 40 monitoring sites, with the ES being exceeded at 12 sites. Alachlor (trade name Lasso) has been detected at 10 of 27 sites. Since the late 1980s, DATCP has also initiated a number of surveys to investigate runoff-related pesticides in groundwater. In 1994, DATCP completed a groundwater survey of alachlor and its metabolite or breakdown product, ethane sulfonic acid (ESA), in southern Wisconsin. The study was funded by DATCP, WDNR and Monsanto, and was designed to determine the extent of alachlor and ESA contamination in Wisconsin private wells most at risk. The study was conducted in the following 11 counties where alachlor sales and use have been concentrated: Columbia, Dane, Dodge, Grant, Green, Jefferson, Iowa, Lafayette, Rock, Sauk and Walworth. Immunoassay test kits were sent to about 1,300 homeowners whose wells had either a previous detection of triazines or nitrates above 10 mg/l. A total of 669 samples were returned for immunoassay analysis at DATCP's Bureau of Laboratory Services. Triazines, a class of herbicides including atrazine and simazine, were detected in 45 percent of these samples. Well owners with a detection were offered free follow-up sampling and more comprehensive laboratory analysis for alachlor, ESA, nitrate and other commonly used pesticides. Follow-up analysis indicated that about 1.8 percent of the original 669 wells had detections of alachlor and 32 percent had detections of ESA. Alachlor was detected above the ES of 2.0 micrograms/liter (g/l) in six follow-up samples, while ESA was detected above the Interim Health Advisory of 20 g/l in two follow-up samples. DATCP plans to conduct site investigations around wells that exceed the alachlor ES, or around those that exceed the ESA Interim Health Advisory to identify the source(s) of groundwater contamination. Information from the investigations will be used to determine what actions DATCP will take in response to alachlor and ESA contamination in groundwater. In 1994, DATCP also completed Phase 1 of a survey designed to evaluate the effectiveness of the atrazine rule (Chapter ATCP 30, Wis. Adm. Code). This evaluation is required in ATCP 30 and will attempt to determine if a "statistically significant change" has occurred in groundwater concentrations of atrazine and its three chlorinated metabolites between Phases 1 and 2 of the
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survey. The focus of this evaluation is groundwater exploitable by private water supply wells. In Phase 1, DATCP collected 289 groundwater samples statewide to establish a statistically reliable basis for comparison with samples that will be collected in 1996 for Phase 2. The private wells were chosen using a stratified-random selection process, and groundwater samples were analyzed for atrazine, its breakdown products, and a number of other pesticides. Phase 1 survey results indicate that between 8 and 16.4 percent of wells in Wisconsin contain detectable levels of atrazine and/or its metabolites, with .6 to 2.8 percent exceeding the ES of 3.0 g/l. In addition, 4.2 to 9.4 percent of private water supply wells in Wisconsin had detections of alachlor's ESA metabolite; 50.7 to 67.8 percent of private wells contain nitrate, with between 6.7 and 13.1 percent exceeding the ES of 10 mg/l. DATCP also collects groundwater samples from private wells that are associated with pesticide investigations. Most of these investigations are initiated based on wells exceeding the pesticide ES. DATCP investigators may take confirmation samples from those wells or from wells on adjacent property. The sample data help DATCP staff identify probable sources of pesticides in groundwater, provide background water quality information and assist in the development of regulatory actions, such as atrazine rule amendments. In addition to runoff sources of pesticides in groundwater, a significant point source problem was identified during two surveys of groundwater quality at pesticide storage and handling facilities. The Agricultural Chemical Cleanup Program (ACCP), administered by DATCP, was created in 1993, primarily to address point source contamination at these facilities and in nearby wells. Point source contamination on farms is also handled by ACCP. To date, more than 200 cases involving soil or groundwater remediation related to spills, misuse, improper storage and other point sources have been initiated at facilities and farms. Monitoring groundwater from adjacent private wells and/or installation of monitoring wells are often associated with these cases. GRN sample records indicate that 1,083 wells sampled in the Lower Rock River Basin had detects of one or more of the major pesticides. Of the 1,636 wells sampled, 105 exceeded the preventive action limit (PAL) for some form of pesticide. Another 80 wells exceeded the ES.
Triazine Screening
Triazines are a class of herbicides that include atrazine and simazine. Beginning in January, 1991, the Wisconsin State Laboratory of Hygiene (SLOH) initiated a testing program for the public based on the immunoassay screening test for triazine-based compounds. This program is available to the public through a toll-free telephone number (1-800-442-4618). Since the start of this program, about 10,000 groundwater samples have been screened for triazine compounds. SLOH has expanded the immunoassay screening program to include other pesticides as requested. Data from the SLOH program indicate that about 18 percent of the samples have exceeded the PAL for atrazine of .3 g/l, and about 2.2 percent have exceeded the ES of 3 g/l for atrazine. These numbers are used only for reference since the test screens for compounds other than atrazine specifically and does not screen for two of the three breakdown metabolites included in the groundwater standard.
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Metals
Metals in groundwater can be naturally occurring or the result of human activities. For example, iron is a common, naturally occurring metal, while cadmium and chromium are associated with metal plating operations. Other elements are often found affiliated with metals. Arsenic and lead were commonly used in pesticides on orchards. The geology of the basin does not include any major sources of naturally occurring metals and levels in groundwater are relatively low. Several localized areas have shown elevated levels of metals associated with plating and foundry operations.
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active cleanups. Of the active sites, 1,029 are in a long-term monitoring phase that precedes site close-out. The contaminants most commonly associated with leaking underground storage tanks (LUSTs) are components of gasoline and diesel fuel including benzene, toluene, ethyl benzene, and xylene (i.e. BTEX compounds). There are more than 3,000 LUST sites that exceed BTEX groundwater standards. About 285 private water supply wells have been affected by contamination from LUST sites. Another VOC source is hazardous waste storage and handling facilities. The WDNR Hazardous Waste Section is investigating or remediating 28 of these contamination sites. Statewide, 140 sites have been identified as subject to corrective action authorities. Not all of these sites will undergo the corrective action process, due to minimal contamination at the site or to jurisdiction under other regulatory authorities. VOC-containing petroleum products comprise 65 percent of all reported spills in Wisconsin. Section 144.76, Wis. Stats, the Hazardous Substance Spill Law requires those who spill hazardous substances to report spills and to take immediate actions necessary to restore the environment. The number of spills reported per year has increased from 360 during 1978 to around 1,400 in 1993. Groundwater monitoring is performed when necessary to delineate the contamination extent.
Hardness
The quality or chemical composition of groundwater largely depends upon the composition and physical properties of the rocks and materials through which the water moves and on the duration of the contact. Generally, the deeper the water penetrates into the ground, the more minerals it is likely to pick up. In Wisconsin, the chemistry of groundwater results from the water's interaction with the unconsolidated materials and the rock formations that contain large amounts of calcium and magnesium carbonates. This makes the groundwater fairly high in calcium-magnesium carbonate. Groundwater that exhibits this characteristic is said to be "hard," having dissolved solids greater than 200 milligrams/liter (mg/l). This is a natural phenomenon of groundwater and poses no adverse health effects, although excessively hard water can corrode pipes and reduce the cleaning ability of detergents and soaps. As a result, water softening is required, or at least recommended for many uses. Water throughout most of the basin is classified as very hard (more than 180 mg/l calcium carbonate). Slightly harder water can be found to the northeast due to more dolomite bedrock and in the glacial deposits.
Iron
About 30 percent of Wisconsin wells exceed the standard for iron of 0.3 g/l. Iron concentrations above recommended limits are objectionable because of taste and discoloration, but have no
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adverse effects on human health. Problems with iron in groundwater cannot be predicted because of random distribution and conditions under which it can occur. Iron concentrations range from 0 to almost 7,000 mg/l in the state. Levels within the basin are variable but are generally low. Iron tends to vary seasonally and is greatly affected by the oxidation state of the iron and water chemistry. Naturally-occurring iron (and sulfate) bacteria are often associated with iron, manganese and sulfur. These bacteria may form a slime around well screens, causing decreased well yields. They also contribute to staining of plumbing fixtures and odor problems. Brochures about iron and sulfur bacteria and controlling the problem are available from the WDNR Bureau of Drinking Water and Groundwater.
Manganese
Manganese and iron in small amounts are essential to plants and animals. Higher concentrations may cause staining of plumbing fixtures. The distribution of manganese is similar to that of iron. Levels range between 30 and 45 mg/l in the basin.
Radioactivity
Naturally occurring radioactive substances in groundwater-- including uranium, radium and radon--is a concern in Wisconsin. The state has initiated programs to test groundwater for radioactivity. Recent sampling has identified radionucleides in north central Wisconsin groundwater. High levels of radium have also been found in eastern Wisconsin water supplies. These detects are associated with wells drawing from the deeper sandstone aquifer. Elevated levels have not been found in the silurian or sand and gravel aquifers. Studies are examining the occurrence and extent of these naturally occurring contaminants. The WDNR Bureau of Drinking Water and Groundwater has published a brochure about radon and provides guidance on sampling and management of the problem. Two recent studies have examined radon in private wells. The first, discussed earlier as the CDC Private Well Survey, sampled wells in a grid pattern across the state at 10-mile intervals. The second radon study is being conducted by the Department of Health and Family Services (DHFS) and the Wisconsin Environmental Health Association (WEHA). This study involves selecting wells drawing water from specific geological formations. The state's formations are being mapped by WGNHS using a geographic information system. The data layer is called the Primary Bedrock Aquifer coverage. This mapping scheme will be used to select approximately 1,000 wells for radon sampling.
Sulfate
Sulfate is the most common form of sulfur in groundwater. Under reducing conditions, which are often mediated by biologic activity, hydrogen sulfide is produced. Sulfate can have a laxative effect on persons not accustomed to it. It is also reported to reduce milk production in cows. Levels generally increase from west to east in the basin ranging from about 15 to 60 milligrams per liter, with levels elevated to more than 30 mg/l from Janesville south.
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Chloride
Sources of chloride include weathering of minerals, animal wastes and road salt used for de-icing. Since human activity and animal wastes are the primary source it is often used as an indicator of contamination. Levels within the basin are low and increase slightly to the north. Concentrations range from to just below 10 milligrams per liter to just over 10 mg/l. Higher levels can be found in eastern Dane, southern Rock and Northern Waukesha counties. The secondary drinking water standard for chloride is 250 mg/l.
Fluoride
Fluoride concentrations are low throughout the state. Fluoride is beneficial in preventing tooth decay. The recommended amount for addition to water supplies in Wisconsin is 1-1.2 mg/l. Concentrations in the basin are less than 0.5 mg/l.
Standards
Under Chapter 160, WDNR must establish state groundwater quality standards based on recommendations from the Department of Health and Family Services (DHFS). Standard-setting is a continuing process based on a priority list of substances established by WDNR and other state agencies. The state groundwater standards are in chapter NR 140, Wis. Admin. Code. An enforcement standard (ES) is a quantitative level indicating when a violation has occurred. If an ES is exceeded, the activity responsible will be stopped. The preventive action limit (PAL) is a selected percentage of the enforcement standard. The PAL serves as a "trigger" for remedial action and allows time to investigate a problem before the enforcement standard is reached.
Regulatory Programs
Once groundwater quality standards are established, all state agencies must manage their regulatory programs to comply. Each state regulatory agency must promulgate rules to assure that the groundwater standards are met and require appropriate responses when the standards are not met. The state regulatory agencies are WDNR (solid and hazardous waste, industrial and municipal wastewater, spills); the Wisconsin Department of Commerce (DCOMM) (private sewage systems, petroleum product storage tanks); the Wisconsin Department of Agriculture, Trade and Consumer Protection (DATCP) (pesticide use and storage and fertilizer storage); and the Wisconsin Department of Transportation (DOT) (salt storage). A summary of state regulatory controls of pollution sources can be found at the end of this report.
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Aquifer Classification
One of the most important features of Wisconsin's groundwater law is an item that was omitted: aquifer classification. When Wisconsin was debating the groundwater protection legislation, the U.S. Environmental Protection Agency (EPA) tried to develop a nationwide groundwater approach. A keystone of U.S. EPA's proposal was aquifer classification, whereby each aquifer would be classified according to its use, value or vulnerability and would then be protected to that classification level. This would have entailed "writing off" certain aquifers as industrial aquifers not entitled to protection and never again usable for human water supply. Wisconsin said "no" to aquifer classification. The philosophical underpinning of Wisconsin's groundwater law is the belief that all groundwater in Wisconsin must be protected to assure that it can be used for people to drink.
Research
Although all state agencies must comply with the groundwater standards--the processes by which groundwater becomes contaminated--the technology for cleanup, the mechanisms to prevent contamination and the environmental and health effects of the contamination are often poorly understood. In addition, the basic data on geology, soils and groundwater hydrology are often not available. The University of Wisconsin System and other state agencies have recognized that additional efforts in these research areas are badly needed. The Governor and the Legislature included a new groundwater research appropriation for the UW-System beginning with the 19891991 biennial budget. Since then, the UW-System and the Departments of Agriculture, Trade and Consumer Protection, Industry Labor and Human Relations, and Natural Resources have participated in an annual joint solicitation to select groundwater-related research and monitoring proposals for funding during each fiscal year.
Coordination
In establishing the groundwater law, the Legislature recognized that management of the state's groundwater resources was a responsibility divided among a number of state agencies. Therefore, the Groundwater Coordinating Council (GCC) was created in 1984 to advise and assist state agencies in the coordination of non-regulatory programs and the exchange of information related to groundwater.
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Zoning authority for cities, villages, towns and counties was expanded to "encourage the protection of groundwater." Counties can adopt ordinances regulating disposal of septage on land, consistent with WDNR requirements. Cities, villages or towns may do so if the county does not. Counties can regulate, under WDNR supervision, well construction and pump installation for certain private wells. Property assessors must consider the time and expense of repairing or replacing a contaminated well or water supply when assessing the market value of real property. They must consider the "environmental impairment" of the property value due to the presence of a solid or hazardous waste disposal facility.
Through the efforts of the GCC, WDNR and other state agencies developed a Comprehensive State Groundwater Program Plan (CSGWPP) and submitted it to U.S. EPA in 1994. Wisconsin received U.S. EPA endorsement of the CSGWPP as a core program plan that same year. The CSGWPP consists of a state profile, a self-assessment and a vision statement. Wisconsin is one of only four states to receive this endorsement.
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Local units of government in Wisconsin are playing an increasingly larger role in groundwater management and protection. Counties are authorized to adopt private well code and septage disposal ordinances. Cities, villages, towns and counties are authorized to adopt zoning ordinances to protect groundwater. Some Wisconsin counties are developing groundwater management plans with assistance from the University of Wisconsin-Extension, WDNR and the Wisconsin Geological and Natural History Survey. Groundwater protection activities are also incorporated into the state's areawide water quality management plans through WDNR. The publication, A Guide to Groundwater Quality Planning and Management for Local Governments (Born 1987), is available from WDNR and the Wisconsin Geological and Natural History Survey. There is no single best approach to groundwater protection, as local situations vary. One theme should, however, provide the basis for any groundwater planning effort: groundwater management should emphasize prevention and protection of groundwater contamination, not remedial action.
THE ROCK RIVER BASIN AN OVERVIEW (PPT) by JIM CONGDON (UPPER ROCK BASIN SUPERVISOR) 194 Dams on Rock River and Tributaries Population 800,000 and growing 68 Municipal and Industrial Point Source Discharges Construction Site Runoff a Major Source of Pollutants in Developing Urban Areas Over 50% of Wetlands in the Rock River Basin have been destroyed Land Use in the Rock River Basin: Agriculture (73%), Residential (12%), Wetlands (7%), Commercial/Industrial (5.5%), and Woodlands (1.6%) Agriculture in the Rock River Basin a. 19% of Wisconsins farmland b. 22% of Wisconsins agricultural products c. Dane/Dodge Co. in top five dairy, cattle, and hog producers Causes of Impairments in Rock River Basin a. Nutrients (phosphorus) b. Sediment c. PCBs d. Dams (194 dams) e. Habitat (channelization, stream alteration) f. Loss of Wetlands Total phosphorous (2000 estimate) 1,680,000 pounds annually Total sediment (RRP Nutrient Trading Project-August 2000) 160,000 tons annually Soil Phosphorous Levels in Rock River Basin Increasing a. 1974 (37ppm) to 2002 (52ppm) b. NR151 requires that after 2008 all lands draining to impaired waters have a nutrient management plan Soil Phosphorous Sources a. Agricultural Inorganic Fertilizer
23 b. Animal Manure c. Municipal Biosolids a. Example 23 municipal spread in Dodge Co. d. Industrial Biosolids a. Example 15 industries spread in Dodge Co. e. Septic Waste a. Example 11 septic pumpers spread in Dodge Co. Table 1. Nonpoint Source Pollutants and Major Sources a. Sediment a. Construction sites b. Mining Operations c. Croplands d. Logging operations e. Streambank erosion f. Shoreline erosion g. Woodland b. Nutrients (fertilizers, grease, organic matter) a. Croplands b. Nurseries c. Orchards d. Livestock operations e. Gardens, lawns, forests f. Petroleum storage areas g. Landfills c. Acids and salts a. Irrigated lands b. Mining operations c. Urban runoff (roads, parking lots) d. Landfills d. Heavy Metals (Pb, Hg, Zn) a. Mining operations b. Vehicle emissions c. Urban runoff d. Landfills e. Toxic chemicals (pesticides, (in/)organic compounds) a. Croplands b. Nurseries c. Building sites d. Gardens e. Landfills
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Excess fertilizers, herbicides and insecticides from agricultural lands and residential
areas Oil, grease and toxic chemicals from urban runoff and energy production Sediment from improperly managed construction sites, crop and forest lands, and eroding streambanks Salt from irrigation practices and acid drainage from abandoned mines Bacteria and nutrients from livestock, pet wastes and faulty septic systems Atmospheric deposition and hydromodification States report that nonpoint source pollution is the leading remaining cause of water quality problems. The effects of nonpoint source pollutants on specific waters vary and may not always be fully assessed. However, we know that these pollutants have harmful effects on drinking water supplies, recreation, fisheries and wildlife.
Middleton Economy
The American Girl, Capital Brewery, Springs Window Fashions, andElectronic Theatre Controls company headquarters are located in Middleton. Middleton is also home to Morey Field, a multi-runway,general aviation airport.