Iit Jee 2010 Part 2 - 2

IIT-JEE Website (Paper-II)
Space for Rough Work

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0141-6595558
(1)
B

CHEMISTRY
SECTION I
Si ngl e Corr ect Choi ce Type
This section contains 4 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for
its answer, out of which ONLY ONE is correct.
1. Which of the following compounds was the starting material for the oxidation shown below?
?
KMnO /H
4
+
O
HO
OH + CO
2
OH
O
O
(A)

(B)

(C)

(D)

2. Pick out the incorrect statement.
(A) trans-2-butene reacts with singlet :CH
2
to give meso form of cis 1, 2-dimethyl cyclopropane.
(B) trans -2-butene reacts with triplet carbene : CH
2
to give racemic mixture of trans 1, 2-dimethyl
cyclopropane.
(C) singlet can be generated by decomposition of diazomethane
(D) Triplet is obtained by a special photochemical method using photosensitizer.

3. (X) + K
2
CO
3
+ Air
heat
(Y)
(Y) + Cl
2
(Z) Pink
Which of the following is correct?
(A) X = black, MnO
2
, Y = Blue, K
2
CrO
4
, Z = KMnO
4

(B) X = green, Cr
2
O
3
, Y = Yellow, K
2
CrO
4
, Z = K
2
Cr
2
O
7

(C) X = black, MnO
2
, Y = green, K
2
MnO
4
, Z = KMnO
4

(D) X = black, Bi
2
O
3
, Y = colourless, KbiO
2
, Z = KbiO
3



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4. In a recently conducted experiment, VO
2
could be disproportionated, in presence of concentrated
aqueous solution of NaOH and CsOH, into two different compounds Cs
4
Na(HV
10
O
28
) and
Na[V(OH)
2
]. What is the number of moles of Cs
4
Na(HV
10
O
28
) formed when number of moles of Na
V(OH)
2
formed is 0.5.
(A) 0.167 (B) 0.15 (C) 0.05 (D) 0.2
SECTION II
Mul t i pl e Cor rect Choi ce Type
its answer, out of which ONE OR MORE is/are correct.

5. In which of the following cases rate is dependent upon concentration of nucleophile?

(A)
CH
3
Ph
Cl C H
3
F/SO
2
(liquid)
(Specific rotation = 0) Product

(B)
H
CH
3
C
6
H
13
I (Specific rotation = 0)
NaI/ acetone
Product

(C)
Product
NO
2
Cl
NO
2
NaOH/

(D) Product
AgI
Ph Cl
D H
(mixture of stereoisomers)

6. Consider the given reaction:
In the above reaction which of the given ring will not undergo
reduction?
(A) ring A (B) ring B
(C) ring C (D) ring D

Pd / C
2
3H Pr oduct +
C
A
B D



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7. Which of the following statement (s) is/are incorrect?
(A) In ( )
2
CoBrCl en
+
(

geometrical isomerism exists, while optical isomerism does not exist
(B) Potassium aquadicyanosuperoxoperoxochromate (III) is IUPAC name
( ) ( )( )
2 2 2 2
2
K Cr N O O H O (

(C) There are 3 geometrical and 15 stereoisomers possible for
( )( )( )( )
2 3 2
Pt NO NH NH OH py
+
(

and ( )( )( )
2 3
PtBrClI NO NH py (

respectively
(D) cis and trans forms are not diastereomers to each other.

8. An acidbase indicator has a K
a
of 3.0 10
5
. The acid form of the indicator is red and the basic
form is blue. Then:
(A) pH is 4.05 when indicator is 75% red (B) pH is 5.00 when indicator is 75% blue
(C) pH is 5.00 when indicator is 75% red (D) pH is 4.05 when indicator is 75% blue

9. Which of the following statements is/are not correct :
(A) Physical adsorption is directly related to the critical temperature of the gas (adsorbate)
(B) One gram of charcoal at 25C will always adsorb the same amount of particular gas at a
particular pressure
(C) At particular temperature, adsorption always increases with increase of pressure
(D) In adsorption, the concentration of adsorbate is always greater at the surface of the adsorbent

SECTION III
Mat r i x-Mat ch Type
This section contains 2 questions. Each question contains statements
given in two columns, which have to be matched. The statements in
Column I are labelled A, B, C and D, while the statements in Column II
are labelled p, q, r, s and t. Any given statement in Column I can have
correct matching with ONE OR MORE statement(s) in Column II. The
appropriate bubbles corresponding to the answers to these questions
have to be darkened as illustrated in the following example: If the
correct matches are A p, s and t; B q and r; C p and q; and D s
and t; then the correct darkening of bubbles will look like the following.



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10. Match Column I with Column II
Column I Column II
(A) XeF
2
(p) Square pyramidal
(B) PCl
5
(q) Linear shape
(C) XeOF
4
(r) sp
3
d hybridization
(D) XeF
4
(s) sp
3
d
2

11. Match the particle in column I with their effects in column II
Column I
(Particle)
Column II
(Effect)
(A) Alpha particle emission (p) Number of proton
increases
(B) Beta particle emission (q) Number of proton
decreases
(C) Positron emission (r) Number of neutron
increases
(D) Electron capture (s) Number of neutron
decreases
SECTION IV
I nt eger Answer Type
This section contains 8 questions. The answer to each of the questions is a single digit integer, ranging
from 0 to 9. The appropriate bubbles below the respective question numbers in the ORS have to be
darkened. For example, if the correct answers to question numbers X, Y, Z and W (say) are 6, 0, 9 and
2, respectively, then the correct darkening of bubbles will look like the following.



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12.

(C H N )
4 12 2
O / Zn H / KMnO 2 mole of sodamide Alkaline
3 4
H O NaNH Bromin e
2 2 C H O C H O (C H O N )
7 12 2 6 10 4 6 12 2 2
Br NaOH
2
A B C D
+
+

CH
3
C
7
H
12
prop 2 enal conc. H SO
2 4
C H (C H O ) C H O
4 6 4 10 2 7 10
G F E

2
NaNO HCl +

How many type of functional group are present in compound G.

13. The number of water molecules present as water of crystallization in Borax Na
2
B
4
O
7
.10H
2
O.

14. Enthalpy neutralization of H
3
PO
3
is 106.68 kJ/mol using NaOH. If enthalpy of neutralization of HCl
by NaOH is 55.84 kJ/mol. AH ionization of H
3
PO
3
into its ions is x kJ/mol. Find the value of x.

15. The maximum possible number of hydrogen bonds a water molecule can form in ice is

16. 10% sites of catalyst bed have adsorbed by H
2
. On heating H
2
gas is evolved from sites and
collected at 0.03 atm and 300 K in a small vessel of 2.46 cm
3
. Number of sites available is 6.0
10
15
per cm
2
and surface area is 1000 cm
2
. Find out the no. of surface sites occupied per molecule
of H
2
. (Given N
A
= 6 10
23
)

17.
What is the value of i for Ca
3
(PO
4
)
2
assuming complete ionisation ?



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18. Haemoglobin contains 0.25% iron by weight. The molecular weight of haemoglobin is 89600.
Calculate the number of iron atom per molecule of haemoglobin.
19. Freon-12 is used as a refrigerant in central home air conditioners. The rate of effusion of Freon-12
to Freon-11 (molar mass =137.4 g/mol) is 1.07 : 1. The formula of Freon-12 is one of the following :
CF
4
, CF
3
Cl, CF
2
Cl
2
, CFCl
3
, or CCl
4
. Find the number of fluorine atoms in a molecules of Freon-12.



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MATHEMATICS
SECTION I
20. Let f(x) = (x + 1) (x + 2) (x + 3) . . . (x + 100) and g(x) = f(x). ( )
2
f (x) f (x) , '' ' then g(x) = 0, has
(A) no solution (B) exactly one solution
(C) exactly two solutions (D) minimum three solutions
21. If g(x) be a continuous function for all real values of x and satisfies
x 8 2
2
3 x
x
g(t)dt t g(t)dt,
2
= +
} }
then
1
1/ 2
g(x)dx
}
is equal to
(A)
5
ln
8
| |
|
\ .
(B)
8
2ln
5
| |
|
\ .
(C)
1 8
ln
2 5
| |
|
\ .
(D)
1 5
ln
2 8
| |
|
\ .

22. If |z 3i| = 3 and ampz 0,
2
t | |
e
|
\ .
then
6
cot(amp z)
z
is equal to
(A) i (B) 1 (C) 1 (D) i
23. If line y = x + 2 do not intersect any member of family of parabola y
2
= ax, (aeR
+
) at two distinct
point, then maximum value of latus rectum of parabola is
(A) 4 (B) 8 (C) 16 (D) 32

SECTION II
This section contains 5 multiple correct answer(s) type questions Each question has 4 choices (A), (B),
(C) and (D), out of which MORE THAN ONE is/are correct.



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24. The values of a for which the integral
2
0
x a dx 1 >
}
is satisfied are
(A) [2, ) (B) ( , 0] (C) (0, 2) (D) none of these

25. Let the algebraic sum of the perpendicular distances from the points A(2, 0), B(0, 2), C(1, 1) to a
variable line be zero. Then all such lines
(A) are concurrent (B) passes through a fixed point (1, 2)
(C) touches some fixed circle (D) passes through a fixed point (1, 1)

26. Sum to m terms of the series S = 1
2
+ 2(2)
2
+ 3
2
+ 2(4)
2
+ (5)
2
+ 2(6)
2
+ . is
(A)
1
4
m
2
(m + 2) ; m is odd (B)
1
2
m
2
(m + 1) ; m is odd
(C)
1
2
m(m + 1)
2
; m is even (D)
1
4
m(m + 2)
2
; m is even
27. The eccentric angles of the extremities of a chord of an ellipse
2 2
2 2
x y
1
a b
+ = are o and |. If this
chord passes through the focus, then
(A)
1 e
tan tan 0
2 2 1 e
o |
+ =
+
(B)
sin sin
e
sin( )
o+ |
=
o+|

(C) cos e cos
2 2
o| o+|
= (D)
e 1
cot cot
2 2 e 1
o | +
=

28. The value of
7 14
k 0 r k
7
r 14 k
14 k r
k
= =
( | |
( |
| | | |
\ .
(
| |
(
| |
\ . \ .
( |
\ .

, where
n
r
| |
|
\ .
denotes
n
r
C , is
(A) 6
7
(B) greater than 7
6
(C) 8
7
(D) greater than 7
8



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SECTION III
This section contains 2 questions. Each question contains statements
given in two columns, which have to be matched. The statements in
Column I are labelled A, B, C and D, while the statements in Column II
are labelled p, q, r, s and t. Any given statement in Column I can have
correct matching with ONE OR MORE statement(s) in Column II. The
appropriate bubbles corresponding to the answers to these questions
have to be darkened as illustrated in the following example: If the
correct matches are A p, s and t; B q and r; C p and q; and D s
and t; then the correct darkening of bubbles will look like the following.

29. Let y(x) be the solution of differential equation
dy
dx
= 2x (y 1) with y(0) = 1
g(x) = min{|x|, x
2
, y(x)} and h(x) = e
x
, p(x) = 3 ln x
Column I Column II
(A) y(x) equals (p) 4
(B) If area bounded by p(x) = 3 lnx, y (x) and the
yaxis is oe
1/3
, then o equals
(q) 3
(C) If area bounded by the curves y(x); g(x),
x = 0, x = 2 and xaxis is |/3, then |
equals
(r) 1
(D) If h(x) = y(x), then x equals (s) 0

30. Match Column I with Column II
Column I Column II
(A) P(A/B) + P(A'/B) (p) P(A) P(A B)
(B) P(A) . P(B/A) + P(A') . P(B/A') (q) 1
(C) P(A B) (r) P(B)
(D) P(A B) P(A B) (s) P(B) P(A B)
(t) P(A B') + P(A' B)



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SECTION IV

31. The number of common tangents that can be drawn to the circle
x
2
+ y
2
4x 6y 3 = 0 and x
2
+ y
2
+ 2x + 2y + 1 = 0 is
32. The area of the region in the xy plane defined by [x]
2
+ [y]
2
= 5 is ________ sq. units.
33. Four lines x = a, y = a forms a square in x-y plane. A point P is moving in such a way that its
distance from any of these sides of square is greater than its distance from the centre of the
square. Then number of curves bounding the above region is

34. The equation of an ellipse is 10x
2
+ 6y
2
= 15, then the distance between the directrices is
35. On a chess-board if two squares are chosen, the probability that they have a side in common is
1
2P
then P will be..



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36. If
3 2
iz z z i 0 + + = , then |z| equals

37. If
1 2 3
1 2 3
1 1 1
| z | | z | | z | 1
z z z
= = = + + = then
1 2 3
| z z z | + + is equal to .
38. If A is a square matrix of order n such that |adj (adj A)| = |A|
9
, then the value of n can be

PHYSICS
SECTION I
39. A sphere of mass M and radius R is placed at rest on a smooth horizontal
surface. It is given a horizontal impulse F at a height h above the centre of
mass. Identify the correct statement :
(A) the centre of mass moves with velocity,
0
F
V
M
=
F
h
smooth
(B) it rotates with an angular velocity,
0 2
5 Fh
2 MR
e =
(C) the sphere will start rolling motion if
2
h R
5
=
(D) all of these

40. Two identical blocks P and Q have mass m each. They are attached to two identical springs initially
unstretched. Now the left spring (along with P) is compressed by
A/2 and the right spring (along with Q) is compressed by A. Both the
blocks are released simultaneously. They collide perfectly
inelastically. The time period of both the blocks oscillating
independently on there respective springs is T. The time period of
oscillation of combined mass is
(A)
T
2
(B) 2 T

(C) T (D)
T
2

A
P Q
2
A



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41. A wedge of mass m, lying on a rough horizontal plane, is acted
upon by a horizontal force F
1
and another force F
2
, inclined at an
angle u to the vertical. The block is in equilibrium, then minimum
coefficient of friction between it and the surface is
(A) (F
2
sin u) / (mg + F
2
cos u)
F
1
F
2
u

(B) (F
1
cos u + F
2
) / (mg F
2
sin u)
(C) (F
1
+ F
2
sin u) / (mg + F
2
cos u)
(D) (F
1
sin u F
2
) / (mg F
2
cos u)

42. A uniform conducting rectangular loop of sides , b and mass m
carrying current i is hanging horizontally with the help of two vertical
strings. There exists a uniform horizontal magnetic field B which is
parallel to the longer side of loop. The value of tension which is least is
(A)
mg Bb
2
(B)
mg Bb
2
+

b
B

(C)
mg 2iBb
2
(D)
mg 2Bb
2
+

43. The wavelengths of K
o
X-rays from lead isotopes Pb
204
, Pb
206
and Pb
208
are
1
,
2
, and
3

respectively. Choose the correct alternative
(A)
1
<
2
<
3
(B)
1
>
2
>
3
(C)
1
=
2
=
3
(D) none of these

SECTION II
its answer, out of which ONE OR MORE is/are correct.



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44. A long block A is at rest on a smooth horizontal surface. A small block B, whose mass is half of A,
is placed on A at one end and projected along A with some velocity u. The coefficient of friction
between the blocks is
B
A
v

(A) the blocks will reach a final common velocity
u
3

(B) the work done against friction is two-thirds of the initial kinetic energy of B
(C) before the blocks reach a common velocity, the acceleration of A relative to B is
2
g
3

(D) before the blocks reach a common velocity, the acceleration of A relative to B is
3
g
2

45. A particle is dropped from a height equal to the radius of the earth
above the tunnel dug through the earth as shown in the figure.
R : Radius of earth.
M : Mass of earth.
(A) Particle will oscillate through the earth to a height R on both
sides
(B) Particle will execute simple harmonic motion
(C) Motion of the particle is periodic
(D) Particle passes the centre of earth with a speed =
R
GM 2

R

C

46. A charged particle of unit mass and unit charge moves with velocity of v
=
( )

8 6 i j +
m
s
in a
magnetic field of B
= 2
k T. Then choose the correct statement.

(A) The path of the particle may be x
2
+ y
2
4x 21 = 0 (B) The path of the
particle may be x
2
+ y
2
= 25
(C) The path of the particle may be x
2
+ z
2
= 25 (D) The time period of the
particle will be 3.14 s

47. A thin paper of thickness 0.02 mm having refractive index 1.45 is pasted across one of the slit in a
Youngs double slit experiment. The paper transmits 4/9 of light falling on it.
(
light
= 600 nm).
(A) Amplitude of light wave transmitted through the paper will be 2/3 time of incident wave.
(B) The ratio of maximum and minimum intensity in the fringe pattern will be 25.


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(C) The total number of fringe crossing the centre if an identical paper is pasted on the other slit is
15.
(D) The ratio of maximum and minimum intensity in the pattern will be 5.

48. X ray from a tube with a target A of atomic number Z shows strong K lines for target A and weak K
lines for impurities. The wavelength of K
o
lines is
z
for target A and
1
and
2
for two impurities.

z z
1 2
1
4 and
4

= =

.
Screening constant of K
o
lines to be unity. Select the correct statement(s)
(A) The atomic number of first impurity is 2z 1. (B)The atomic number of first impurity is 2z
+ 1.
(C) The atomic number of second impurity is
(z 1)
2
+
(D) The atomic number of
second impurity is
z
1
2
+



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SECTION III
This section contains 2 questions. Each question contains statements given in
two columns, which have to be matched. The statements in Column I are
labelled A, B, C and D, while the statements in Column II are labelled p, q, r, s
and t. Any given statement in Column I can have correct matching with ONE
OR MORE statement(s) in Column II. The appropriate bubbles corresponding
to the answers to these questions have to be darkened as illustrated in the
following example: If the correct matches are A p, s and t; B q and r; C p
and q; and D s and t; then the correct darkening of bubbles will look like the
following.

49. In the circuit shown in the figure, switch S is closed at t = 0.

Column I Column II
(A) Ratio of the charge in capacitor 2C and C at
any time t is
(p) 1 : 2
(B) Time constants of both the capacitor are in
the ratio of
(q) 1 : 1
(C) Steady state charge in C and 2C are in the
ratio of
(r) 2ln 2 : 1
(D) Ratio of
t
t
when the current in the C is
1
4
th
of the maximum current in it
(s) 2 : 1

50. The diagrams in Column I show transverse sinusoidal standing/travelling waveforms on stretched
strings. In each case, the string is oscillating in a particular mode, and, its shape and other
characteristics are shown at time t = 0. The maximum amplitude (in all the cases) is A, the velocity
of the waveform on the string is e, the mass per unit length of the string is and the frequency of
vibration is f (angular frequency = e).


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The kinetic energy of the string (of length L) is represented by the functions in Column II. Match the
correct entries in Column II.

Column I Column II

(A)
A
L
Fixed
end
Fixed
end

(p)
2 2
2
9 c
A
4 L
t

(B)
A
L
Fixed
end
Free
end

(q)
2 2
2 2
9 c
A sin t
4 L
t
e

(C)
A
L
Free
end
Free
end
A

(r)
2 2
2 2
9 c
A sin t
16 L
t
e

(D)
A
L
Travelling wave

(s)
2 2
2 2
c
A sin t
4 L
t
e



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SECTION IV

51. A particle is projected at 60to the horizontal with a kinetic energy K. The kinetic energy at the
highest point is
k
n
. What is the value of n?
52. Two uniform spheres shown in figure rotate
separately on parallel axis. The upper sphere has
angular speed e
0
and lower sphere is at rest. Now the
two spheres are moved together so that their surfaces
touch. After a short time the two spheres now in
contact are rotating without slipping.
Find the final rate of rotation of upper sphere in rad/s.
[given moment of inertia of upper sphere I
1
= 4 kg m
2
,
moment of inertia of lower sphere I
2
= 2 kg m
2
, a = 2
m, b = 1 m, e
0
= 12 rad/s].
R=a
e
a
0

R=b
b



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53. A U-tube is partially filled with a liquid. The horizontal part of the tube is 2 m. The tube is
accelerated horizontally with a constant acceleration of 5 m/s
2
. What is the difference in the heights
of the liquid in the two arms of the U-tube?
54. Two containers A and B are connected by a conducting solid cylindrical rod of length
242
7
cm and
radius 8.3 cm. Thermal conductivity of the rod is 693 watt/moleK. The container A contains two
mole of oxygen gas and the container B contains four mole of helium gas. At time t = 0 temperature
difference of the containers is 50C. After what time (in seconds) temperature difference between
them will be 25C. Transfer of heat takes place through the rod only. Neglect radiation loss. Take R
= 8.3 J/moleK and
22
7
t = .
A B
O
2 He

55. There are two uniformly charged solid spheres having radius a and 2a. They contain charges Q
and 16Q respectively. Distance between their centres is 10 a. The distance of a point P from the
center of smaller sphere, on the line joining the centers of two spheres, such that point has
minimum potential, is
a 2a
10a

56. A ring of mass 4 kg is uniformly charged with = 4 c/m and
kept on rough horizontal surface with friction coefficient
4
t
= . A time varying magnetic field B = B
0
t
2
is applied in a
circular region of radius a (a < r) perpendicular to the plane
of ring as shown in figure. Find out the time when ring just
starts to rotate on surface. (take a = 5 cm and g = 10 m/s
2

|
0
= 125 SI Unit).
+
+
+ +
+
+
+
+
+
+ +
+
+
+
B
a
r



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57. A convex lens of focal length 15 cm is split into two halves and the two halves are placed at a
separation of 120 cm. Between the two halves of convex lens a plane mirror is placed horizontally
and at a distance of 4 mm below the principal axis of the lens halves. An object AB of length 2 mm
is placed at a distance of 20 cm from one half lens as shown in figure. The final image of the point
A is formed at a distance of n/3 mm from the principle axis. Determine the value of n.
f=15 cm
4 mm
20 cm
2 mm
120 cm
f=15 cm
A
B

Hydrogen atoms absorbs radiation of wavelength
0
and consequently emit radiations of 6 different
wavelengths of which two wavelengths are shorter than
0
. The final excited state of the atoms is n =



0141-6595558
(20)
B

Answers
(chemistry)

1. (c) 2. (a) 3. (c) 4. (b) 5. (b, c) 6. (b, c, d) 7. (a, b, c, d)
8. (a, b) 9. (b, c, d) 10. (a-q,r; b-r; c-p, s; d-s)
11. (a-q, s; b-p, s; c-q, r; d-
q, r)
12. (2) 13. (8) 14. (d) 15. (4) 16. (3) 17. (5) 18. (4) 19. (2)

(Mathematics)

20. (a) 21. (c) 22. (a) 23. (b) 24. (a, b, c) 25. (a, d) 26. (b, c)
27. (a, b, c, d) 28. (a, b) 29. (A-r; B-q; C-p; D-s) 30. (A-q; B-r; C-p; D-t)
31. (3) 32. (8) 33. (4) 34. (5) 35. (9) 36. (1) 37. (1) 38. (4)

(Physics)

39. (d) 40. (c) 41. (c) 42. (c) 43. (a, b, d) 44. (a, c, d) 45. (a, b, d)
46. (a, b, c) 47. (a, c) 48. (A-s; B-q; C-p; D-r) 49. (A-q; B-r; C-s; D-p)
50. (4) 51. (4) 52. (1) 53. (3) 54. (2) 55. (4) 56. (8) 57. (4)

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k T. Then choose the correct statement.

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