Please discuss the problems below! 1.

What do you know about System Adiabatic processes First Law of Thermodynamic

2. A system receives 600 joule of heat and do the work 200 J to the surrounding, what the change of internal energy of system? 3. Gas in a container is at a pressure of 1.50 atm and a volume of 4.00 m3. What is the work done by the gas a. if it expands at constant pressure to twice its initial volume? b. if it is compressed at constant pressure to one quarter of its initial volume? 4. A gas is compressed from 9.00 L to 2.00 L at a constant pressure of 50 kPa. In the process, 400 J of energy leaves the gas by heat. a. What is the work done by the gas? b. What is the change in its internal energy? 5. One mol of gas in a piston compressed from 2 L to 0.5 L at constant temperature (300 K). Known that R = 8.31 J/mol_K. a. What is the work done by or on the gas? b. What is the heat released to surrounding? c. What is the change in its internal energy? 6. (a) Determine the work done by a fluid that expands from i to f as indicated in figure below (b) How much work is performed by the fluid if it is compressed from f to i along the same path?

Thermodynamic

1. A. System is a condition that become the central of our concentration. B. adiabatic processes is the gas expansion or compression processes which there is no thermal energy transfer by heat or thermally insulating the system from its surroundings or by performing the process rapidly, so that there is little time for energy to transfer by heat C. 1st Law of thermodinamic is a generalization of the law of conservation of energy that encompasses changes in internal energy. 2. A system receives 600 joule of heat and do the work 200 J to the surrounding, what the change of internal energy of system? Known: Q = 600 J W= -200 J Ask: U = ? Answer: U=Q+W = 600 J 200 J = 400 J 3. Gas in a container is at a pressure of 1.50 atm and a volume of 4.00 m 3. What is the work done by the gas
c. d.

if it expands at constant pressure to twice its initial volume? if it is compressed at constant pressure to one quarter of its initial volume?

Given: P = 1.50 atm = 1.545 105 Pa Vi = 4.00 m3 Find: a. W = ? (Vf = 8.00 m3) b. W = ? (Vf = 1.00 m3)

Thermodynamic

Answer: a. W = -P (Vf Vi) = - 1.545 105 Pa (8.00 m3 4.00 m3) = - 6.18 105 J This means that system work to the surrounding. b. W = -P (Vf Vi) = - 1.545 105 Pa (1.00 m3 4.00 m3) = 4.635 105 J This means that the surrounding work on the system. 4. A gas is compressed from 9.00 L to 2.00 L at a constant pressure of 50 kPa. In the process, 400 J of energy leaves the gas by heat. c. d. What is the work done on the gas? What is the change in its internal energy? Find: a. W = ? b. U =?

Given: P = 5.0 104 Pa Vi = 9.00 L = 0.009 m3 Vf = 5.00 L = 0.002 m3 Q = - 400 J Answer: a. W = -P (Vf Vi) = - 5.0 104 Pa (0.002 m3 - 0.009 m3) = - 5.0 104 Pa (0.007 m3) = 350 J b. U = Q + W = - 400J + 350 J = -50 J

5. One mol of gas in a piston compressed from 2 L to 0.5 L at constant temperature (300 K). Known that R = 8.31 J/mol_K. a. b. c. d. What is the initial pressure of gas? What is the work done by or on the gas? What is the heat released to surrounding? What is the change in its internal energy? Thermodynamic

Given: Vi = 2 L = 0.002 m3 Vf = 0.5 L = 0.0005 m3 T = 300 K R = 8.31 J/mol K Answer: a. Initial pressure P = n R T/V

Find: a. W = ? b. Q = ? c. U = ?

= 1 mol. (8.31 J/mol K).300 K/0.002 m3 = 1.2465 106 Pa b. Work W = nRT ln (Vi/Vf) = 1 mol. (8.31 J/mol K).300 K ln (2/0.5) = 249,300 ln 4 joule = 345,603 J c. Heat Q = -W = - 345,603 J d. Change of internal energy In isothermal processes, the temperature of system is constant so the change of internal energy is zero. 6. (a) Determine the work done by a fluid that expands from i to f as indicated in figure below (b) How much work is performed by the fluid if it is compressed from f to i along the same path?

Thermodynamic

Given:

Find: a. W (i to f) =? b. W (f to i) =? Answer: a. Work done by fluid from i to f (expanding) Because the gas done the work to the surrounding so the value of work is negative W = - the area under the path = 1st process + 2nd process + 3rd process =- (6 106 J ) - ( 4 106 J ) - (2 106 J ) = - 12 106 J b. Work done by fluid from f to i (compressing) Because the work is done on the system (gas) so the value of work is positif W = the area under the path = 1st process + 2nd process + 3rd process = (6 106 J ) + ( 4 106 J ) + (2 106 J ) = 12 106 J

Thermodynamic