LEARNING TASK 2 THERMOCHEMISTRY

I. Multiple Choice. (5 points each) 1. All of the following statements are true EXCEPT _____. a. the value of q is negative in an endothermic process. b. heat flows from the system into the surroundings in an exothermic process. c. the value of q is positive when heat flows into a system from the surroundings. d. enthalpy is a state property. 2. The first law of thermodynamics states that E of the system is equal to _____. a. Esystem E surroundings b. m + C2 c. H1 + H2 d. q+w 3. Heat capacity is defined as _____. a. 4.18 J/gC. b. 4.18 cal/gC. c. the amount of heat necessary to raise the temperature of 1 gram of a substance by 1C. d. the amount of heat necessary to raise the temperature of a system by 1C. 4. Aluminum has a specific heat of 0.902 J/gC. How many joules of heat are required to change the temperature of 8.50 grams of aluminum from 25.0C to 93.4C? a. 5240 J b. 524 J c. 192 J d. 483 J 5. Copper has a specific heat of 0.382 J/gC. The temperature of an unknown mass of copper increases by 4.50C when it absorbs 3.97 J of heat. What is the mass of the copper? a. 2.31 g b. 4.90 g c. 6.82 g d. 8.85 g 6. The heat capacity of 5.00 grams of iron is 2.23 J/C. How much heat is required to heat the iron by 50.0C? a. 0.223 J b. 22.3 J c. 112 J d. 558 J 7. If 35.0 J is required to heat 50.3 g Hg by 5.00C, what is the specific heat of mercury? a. 0.139 J/gC b. 0.250 J/gC c.0.572 J/gC d. 0.878 J/gC 8. A coffee-cup calorimeter contains 10.0 g of water at 59.00C. If 3.00 g Au at 15.20C is placed in the calorimeter, what is the final temperature of the water in the calorimeter? The specific heat of water is 4.18 J/gC; the specific heat of gold is 0.128 J/gC. a. 55.37C b. 58.60C c. 59.40C d. 60.80C 9. A chemical reaction in a bomb calorimeter evolves 3.15 kJ of heat. If the temperature of the calorimeter is raised from 19.19C to 22.03C, what is the heat capacity of the calorimeter? a. 1.11 kJ/C b. 2.01 kJ/C c. 8.95 kJ/C d. 14.5 kJ/C 10. Using molar enthalpies of formation, determine the heat of reaction for the combustion of 1.0000 mole of methanol. 2CH3OH(l) + 3O2(g) 2CO2(g) + 4H2O(l) Hf ( kJ/mol) -238.7 -393.5 -285.8 a. -2407.6 kJ b. -1452.8 kJ c. -918.0 kJ d. -726.4 kJ 11. Determine the heat of reaction for the decomposition of one mole of benzene to acetylene C6H6(l) 3C2H2(g) given the following thermochemical equations: 2C6H6(l) + 15O2(g) 12CO2(g) + 6H2O(g) H = -6271 kJ 2C2H2(g) + 5O2(g) 4CO2(g) + 2H2O(g) H = -2511 kJ a. 631 kJ b. 1262 kJ c. 3760 kJ d. 6902 kJ 12. Calculate E of a gas for a process in which the gas absorbs 25 J of heat and does 7 J of work by expanding. a. -32 J b. -18 J c. +18 J d. +32 J 13. Calculate E of a gas for a process in which the gas evolves 12 J of heat and does 8 J of work by expanding. a. -20 J b. -4 J c. +4 J d. -20 J 14. The thermite reaction is an exothermic process that yields iron metal as a product. Fe2O3(s) + 2Al(s) 2Fe(s) + Al2O3(s) Hf (kJ/mol) -824.2 -1675.7 Using enthalpies of formation, determine the heat released when 5.00 g of Fe2O3(s) reacts with excess Al. a. -26.7 kJ b. -171 kJ c. -243 kJ d. -850.8 kJ 15. How many kJ are equal to 3.27 L atm of work? a.7.331 kJ b 0.331 kJ c. 331 kJ 16) For which process would the heat be negative? a) Changing the temperature of ice water to 500 C d. 0.0323 kJ

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b) Condensing steam. c) Boiling water. d) more than one of the above. 17) A calorimeter is used to: a) Determine the heat of a reaction b) Determine the heat given off/absorbed during some process c) Store the heat from a chemical reaction. d) none of these 18) When 2.0 grams of methane are burned in a bomb calorimeter containing 2000 grams of water, it causes the temperature of the water to rise by 13.30 C. What is the molar heat of combustion of methane? Cp(H2O) = 4.18 J/g0C. a) 111 kJ b) 888 kJ c) 13.9 kJ d) none of these

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