-- 11 ----J 2012

1 Lt xa + x+a 2a 1 1 = = a + a + 2a 2 2a = 3. Find xmam Lt ; m, n z+ xa xnan

-- j---
2x3 = 7
or 2x3 = -7

2x = 7+3 or 2x
= 7+3

MATHS
Real Numbers
4 Marks Questions
1 1. If y = 3 + 3 show that 3y39y = 10 3 1 3 Sol: y = 3 + ..........(1) 3 3 cubing on both the sides
3

2x = 10 or 2x = 4 x = 5 or x = 2 Objective type questions

I. Multiple choice questions 1. 6 3 6 3 = b) 36 9 a) 360 2. am/n = b) aman
1/3

Sol: We have to divide the numerator and denominator by (xa), to express the given function in the standard form [... (xa) #0] xmam

II. fill in the blanks:

1. 2. 3. 4. 5. 2x+1 = 4 then x = ...... x < a then ..... x a then ..... x > a then ..... x a then ...... If a R, b R, m, n Q and a 0

Lt xa

Lt = xa xnan

y3

( )
1 3 3 = 3 +

1 1 3 33 + 1 33

y3

( )

1 1 33 + 1 33

( ) )
33

+3

1 1 33 1 33

xa xmam Lt Lt f(x) xa xa xa f(x) = ... Lt = xa g(x) Lt g(x) xnan Lt xa xa xa

( )
xa xnan

xmam

c) 60
1

d) 0

am a) an 3. (.0001) a) 1

c) (am) /n d) (an)m

III. Match the following: 1. am an 2. (am)n 3. (ab)m am 4. an n a 5. b m n 6. a 7. n ab 8. n an, n 0 9. a0 a) am bm n a b) n b n n c) a b 1 d) am e) 1 f) am + n g) a h)

mn a

= b) 0.1

c) 0.01

d) 0.001

Divide the Denominator!

mam1 = nan1 m m = am1n+1 = amn n n 2 marks question 1. Solve the inequation x V. PADMA PRIYA 2 4 3 x x x Sol: 2 4 2 4 or 2 4 3 3 3 x x 2 2 4 2 or 2 2 4 2 3 3 x x 2 or 6 3 3 x 6 or x 18 x 6 or x 18 4. (64)0.5 a) 8 b) 16 5. If x > 0 then x = a) 0 b) x 6. x6 a) 6 Lt (2x5) = b) 7 c) 8 d) 9 c) 64 c) x d) 1 d) None

1 y3 = 3 + + 3y 3 9+1+9y 3 = y 3 3y3 = 9y +10 3y3 - 9y = 10

[from (1)]

x+a 2a 2. Evaluate Lt xa xa x+a 2a Lt Sol: xa xa x+a 2a x+a + 2a Lt = xa xa x+a + 2a x+a 2a = Lt xa (xa) [ + x+a 2a] = (xa) Lt xa (xa) [ + x+a 2a]

i) amn j) amn

7.

Lt k f(x) = xa a) k Lt f(x) xa c) kf(x) b) f(x) Lt k xa d) None

10.

am

SOLUTIONS I. Multiple choice questions: 1c; 2c; 3b; 4a; 5b; 6b; 7a; 8d; 9b; 10a II. Fill in the blanks: 1. x = 1 2. a < x < a 3. a x a 4. x > a or x < a 5. x a or x a III. Match the following: = 1f; 6h; 2i; 7c;
3 2

8. x0 + y0 + z0 = a) 0 b) 1 9. 32 a) 9 1 b) 9 b) o

c) 2 c) 3
1 a /x.

d) 3 d) 2
1 a /y.

One mark question 1. Solve 2x 3 = 7 Sol: 2x3 = 7 Average kinetic energy is directly proportional to absolute temperature (T). Q. Define R.M.S. Velocity. Calculate R.M.S. Velocity of O2 at 30C A. The Square root of mean of squares of velocities of the molecules present in the gas. 3RT C= M 3RT RMS velocity of O2 = M 3 8.314 107 303 = = 4.86 cm/sec 32

10. If xy + yz + zx = 0 then a) 1

1/ z

c) a

d) x + y + z

3a; 8g;
3 2

4j; 9e;

5b; 10d.

CHEMISTRY STATES OF MATTER, STOICHIOMETRY

4 Marks Questions Q. State Grahams law of diffusion. If 300cm3 of H2 diffused in 20 minutes through a fine hole, how much time does the same volume of O2 take for diffusion? A. The rate of diffusion or effusion of a gas (at given P & T) is inversely proportional to the square root of its density. 1 r d MO2 tO2 t 32 = = O2 MH2 tH2 2 2O

A. Total pressure (p) is exerted by a mixture of non reacting gases is the sum of the partial pressures of individual gases present in it. P = P1+P2+P3; P1, P2, P3 are partial pressures of 1st, 2nd, 3rd gases. Where P1 = X1.P n1 X1 = mole fraction 1st gas = n1 + n2 + n3 Application: Pdry gas = Ptotal PH O 2 Q. An organic Compound on analysis gave C = 70.59%, H = 5.88% and O = 23.53%. Its molecular weight is 136. Calculate its molecular formula.

A. K.E. = nTR = 5 300 2 = = 5 300 2 = 4500 cal. 2 Q. Explain the different terms in Vander Waals equation. an2 A. P + ( V nb) = nTR v2 P = pressure, V = volume, a & b = Vander Waals parameters, R = gas constant, T = Absolute temperature.
3

Q. Calculate oxidation numbers of C in C2H12O6 and Cr in K2Cr2O7 A. (a) 2x + (1 12) + (2 6) = 0 2x + 12 12 = 0

Molecules move randomly!

A. C H O Q. What is Joule - Thomson effect? 70.59 5.88 23.53 2.5 grams of a gas is present in 750 ml flask at 32C and 770 mm 12 1 16 of Hg pressure. Calculate molecu5.88 5.88 1.47 lar mass of the gas. 1.47 1.47 1.47 A. The process of cooling of a real gas 4 4 1 by allowing it to expand adiabati E . F. = C4 H4O caly through a fine hole from high A.N.S. Sankara Rao pressure region to low pressure E.F.Weight = 48 + 4 +16 = 68 region is called Joule-Thomson effect. M.F.wt 136 W PV = nTR = TR n= = =2 M E.F.wt 68 WTR Molecular formula = (E.F.)n = (C4 H4O)2 M= PV = C8H8O2 2.5 (32 + 273) 0.0821 = 2 Marks Questions 770 750 Q. Which gas diffuses faster among N2, O2, CH4 gases? why? 760 1000 A. CH4, due to lowest molecular weight (16). = 82.38 grams Q. Find the Kinetic energy of 5 moles of N2 gas Q. State and explain Daltons law of partial in calories at 27C. pressures.

x = 0 Oxi.No.of C = 0 (b) (1 2) + 2x + (2 7) = 0 2 + 2 14 = 0 x = 6 Oxi.No.of Cr = +6

Q. Calculate equivalent weights of (a) H3PO2 and (b) Na2C2O4.2H2O Mol.wt of H3 PO2 A. (a) EH PO = 3 2 Basicity 3 + 31 + 32 = = 66 1 Mol.wt.of Na2 C2 O4.2H2O (b) E = Na2C2O4.2H2O total charge on cation 2(23) + 2(12) + 4(16) + 2(18) 170 = = = 85 2 2 Q. Calculate the weight of 0.1 mole of Sodium Carbonate. weight A. No. of moles = g.m.wt.

tO2 = 4 20 = 80 min.
Q. Give the important assumptions of Kinetic molecular theory of gases. A. Tiny particles of a gas called molecules. Molecules move randomly in all the directions. No attractions or repulsions are observed between the molecules. Molecular motions are unaffected by gravitational force. Molecular collisions are perfectly elastic. Volume of individual molecule is negligible compared to volume of the Vessel. Pressure exerted by the gas is due to the collisions made on the walls of the vessel.

( ) (

Weight of Na2CO3 = 0.1 106 = 10.6g

(Writer - A.N.S. Sankara Rao, Sr Lecturer In Chemistry)