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SAFETY DATA SHEET 1-CHLOROBUTANE

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
Product name In-house No. Applications Supplier

1-CHLOROBUTANE 4469 @@@Laboratoriekemikalie@@@ Fisher Scientific AB gtf.info@thermofisher.com Sdra Lngebergsgatan 30 SE-421 32 Vstra Frlunda Tel: 031-689400 Fax: 031-680717 @@@+ 32 14 57 52 99@@@ 602-059-00-3 203-696-6 C4H9Cl 109-69-3

Emergency telephone number EU index No. EC No. Gross formula CAS No.

2. HAZARDS IDENTIFICATION
EYE CONTACT: vapors and liquid may irritate the eyes. SKIN CONTACT: irritating to the skin, harmful if absorbed through the skin. May cause dermatitis. INGESTION: may cause nausea, vomiting and diaorrea. INHALATION: CNS-disturbances with nausea, headache, dizziness, and coma. May be irritating to the respiratory system. Highly flammable.
CLP Hazard pictograms

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking. P240 Ground/bond container and receiving equipment. P241 Use explosion-proof electrical/ventilating/lighting// equipment. P280 Wear protective gloves/protective clothing/eye protection/face protection. P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P405 Store locked up. @@@Innehllet/behllaren lmnas till lokalt renhllningsverk.@@@

3. COMPOSITION/INFORMATION ON INGREDIENTS
Ingredients

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CLP Section 16 contains detailed classification phrases.

4. FIRST AID MEASURES

Inhalation Ingestion

Move the exposed person to fresh air at once. Provide rest, warmth and fresh air. Get medical attention. Promptly get affected personnel to drink large volumes of water to dilute the swallowed chemical. Get medical attention immediately! NEVER MAKE AN UNCONSCIOUS PERSON VOMIT OR DRINK FLUIDS! NOTE! Keep affected person away from heat, sparks and flames! Promptly flush contaminated skin with soap or mild detergent and water. Promptly remove clothing if penetrated and flush the skin with water. Use suitable lotion to moisturise skin. Get medical attention if irritation persists after washing. Promptly wash eyes with plenty of water while lifting the eye lids. Contact physician if irritation persists.

Skin

Eyes

5. FIRE-FIGHTING MEASURES
Extinguishing media Special fire fighting procedures Specific hazards

Powder, foam or CO2. DO NOT use water if avoidable. Use water to keep fire-exposed containers cool and disperse vapours. Move container from fire area if it can be done without risk. Avoid breathing fire vapours. May travel considerable distance to source of ignition and flash back. May react violently with oxidising materials. Heat may cause the containers to explode. Vapour could create explosive mixture with air even far below room temperature.

6. ACCIDENTAL RELEASE MEASURES

Spill cleanup methods

Extinguish all ignition sources. Avoid sparks, flames, heat and smoking. Ventilate. Clean-up personnel should use respiratory and/or liquid contact protection. Collect with absorbent, non-combustible material into suitable containers. Should be prevented from entering drain.

7. HANDLING AND STORAGE

Usage precautions

Keep away from heat, sparks and open flame. Avoid spilling, skin and eye contact. Eye wash facilities and emergency shower must be available when handling this product. Static electricity and formation or sparks must be prevented. Use explosion proof electric equipment. Flammable/combustible - Keep away from oxidisers, heat and flames. Keep in cool, dry, ventilated storage and closed containers. Ground container and transfer equipment to eliminate static electric sparks. Keep containers tightly closed. Store in a safe place away from children and not together with or near food, animal feed or medicines etc. Do not use aluminum containers. May attack some plastics, rubber and coatings. Flammable liquid storage.

Storage precautions

Storage criteria

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Ventilation Respirators Protective gloves Eye protection Other Protection Hygienic work practices
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Explosion proof general and local exhaust ventilation. Well ventilated area. If ventilation is insufficient, suitable respiratory protection must be provided. Gas cartridge (organic substances). Use protective gloves made of: Polyvinyl alcohol (PVA). Wear approved safety goggles. Wear appropriate clothing to prevent reasonably probable skin contact. Wash at the end of each work shift and before eating, smoking and using the
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toilet. DO NOT SMOKE IN WORK AREA! Use appropriate hand lotion to prevent defatting and cracking of skin.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance Colour Odour Solubility description Molecular weight Boiling point (C, interval) Melting/freezing point (C, interval) Density (g/cm3) Vapour density (air=1) Vapour pressure Flash point (C) Auto ignition temp. (C) Flammability limit (%)

Liquid. Colourless. Characteristic. Insoluble in water. Miscible with: Ethanol. Ether. 92.57 77 - 78 -123 0.88 3.20 81.00 -12 245 1.90 - 10.10
Temperature (C) Method Temperature (C) Pressure

20

20

10. STABILITY AND REACTIVITY

Stability Materials to avoid Hazardous decomp. products

Avoid: Heat, sparks, flames. Strong oxidising agents. Powdered metal. Strong alkalis. High temperatures generate: Very toxic gases/vapours/fumes of: Carbon monoxide (CO). Carbon dioxide (CO2). Phosgene (COCl2). Irritating gases/vapours/fumes of: Hydrogen chloride (HCl).

11. TOXICOLOGICAL INFORMATION

Toxic dose - LD 50: Toxic conc. - LC 50: Health warnings Route of entry Target organs

2670.00 mg/kg (oral rat) > 8000.00 ppm/4h (inhalation rat) This chemical may cause skin/eye irritation. Inhalation. Skin absorption. Ingestion. No specific target organs noted.

12. ECOLOGICAL INFORMATION

Bioaccumulative potential

No bioaccumulation expected.

13. DISPOSAL CONSIDERATIONS

Disposal methods

Confirm disposal procedures with environmental engineer and local regulations.

14. TRANSPORT INFORMATION

Label for conveyance

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ROAD TRANSPORT (ADR): UN no. road ADR class no. ADR class Classification code ADR packing group Hazard no. (ADR) RAIL TRANSPORT (RID): RID class no.

1127 3 Class 3: Flammable liquids. F1 II, (D/E), LQ4, TK2 33 3

15. REGULATORY INFORMATION

EC no. Other information

203-696-6 EC label

16. OTHER INFORMATION

* Information revised since the previous version of the SDS Information sources

Registry of Toxic Effects of Chemical Substances (RTECS). Handbook of Reactive Chemical Hazards, L. Bretherick, 3. ed., 1985. The Merck Index, 11. edition, 1989. Dangerous Properties of Industrial Chemicals, 7th edition, Sax & Lewis, 1988. Handling Chemicals Safely, Stuurgroep-Kemikaarten, 1980. Sigma-Aldrich Material Safety Data Sheets on CD-ROM. 2011-12-28

Revision date

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