1. Wind turbines provide a non-polluting source of energy. This process converts a.

chemical potential energy from rotating turbines in thermal energy. b. gravitational energy from rotating turbines into electrical energy. c. mechanical energy from rotating turbines into electrical energy. d. electrostatic energy from rotating turbines into chemical energy. 2. A chemical reaction evolves 145 kJ of heat. What is the heat evolved in calories? a. 34.7 J b. 6.1 102 J c. 3.47 104 J d. 6.1 105 J

3. The specific heat of iron is 0.449 J/g.K. What quantity of heat is required to heat 10.0 g Fe from 25.0 C to 92.0 C? a. 6.70 10-4 J b. 301 J c. 413 J d. 1.49 103 J

4. The quantity of heat required to heat 24.5 g of ethanol from 25.0 C to 37.5 C is 747 J. What is the specific heat capacity of ethanol? a. 0.813 J/g.K b. 1.22 J/g.K c. 2.44 J/g.K d. 381 J/g.K

5. A 55.0 g sample of aluminum at 92.2 C is dropped into a beaker containing 85.5 g of water at 12.0 C. What is the final temperature of the water after thermal equilibrium is reached? The specific heat capacities of Al and H2O are 0.897 J/g.K and 4.184 J/g.K, respectively. a. 21.7 C b. 28.7 C c. 52.2 C d. 87.4 C

6. The heat of vaporization of carbon tetrachloride is 30.0 kJ/mol at its boiling point of 76.6 C. What quantity of heat is absorbed when 15.0 g CCl4 evaporates at 76.6 C? a. +0.400 kJ b. +2.00 kJ c. +2.93 kJ d. +450 kJ

7. What quantity of heat (in joules) is evolved when 35.0 g H2O at 25 C is converted to ice at -35.0 C? The specific heats of water and ice are 4.184 J/g.K and 2.06 J/g.K, respectively. The heat of fusion of water is 333 J/g. a. -8.79 103 J b. -1.28 104 J c. -1.78 104 J d. -2.98 104 J

8. All of the following statements are incorrect except: a. H = q + w b. work is a state function. c. w < 0 if work is done by the system on the surroundings. d. q > 0 if heat is transferred from the system to the surroundings. 9. Which one of the following processes is endothermic? a. NH4NO3 is dissolved in water, causing the water temperature to decrease. b. Methane burns in a gas oven. c. Steam condenses to liquid water. d. Water freezes to form ice. 10. You mix 42 mL of 0.50 M HBr with 58 mL of 0.50 M NaOH in a perfectly insulated solution calorimeter. The following reaction occurs. HBr(aq) + NaOH(aq) NaBr(aq) + H2O The temperature of both solutions before mixing was 24.0 C. The temperature of the solution rises to 26.8 C after mixing. What is the enthalpy change per mole of limiting reactant? The specific heat capacity of water and the solution is 4.2 J/gK. a. -1.2 kJ b. -2.4 kJ c. -41 kJ d. -56 kJ

11. A 2.00 g sample of ethanol, C2H5OH, is combusted in a constant volume calorimeter with excess O2(g). The temperature of the calorimeter increases by 8.37 C. If the heat capacity of the calorimeter is 811 J/K and it contains 1.50 kg of water, what is the heat evolved per mole of ethanol combusted? The specific heat capacity of water is 4.184 J/gK and the molar mass of ethanol is 46.07 g/mol. a. -29.7 kJ/mol b. -59.3 kJ/mol c. -1.21 103 kJ/mol d. -1.37 103 kJ/mol

12. Carbon reacts with oxygen to produce carbon dioxide and heat. The standard molar enthalpy of combustion is -393.5 kJ. C(s) + O2(g) CO2(g) What is the enthalpy change for the following reaction? a. -1180.5 kJ b. -131.2 kJ 3 CO2(g) 3 C(s) + 3 O2(g) d. +1180.5 kJ c. +131.2 kJ

13. Hydrazine, N2H4, is used as a rocket fuel. It reacts with oxygen to make nitrogen and water. N2H4 + O2(g) N2(g) + 2 H2O The reaction of 4.00 g N2H4 evolves 77.6 kJ of heat. Calculate the enthalpy change per mole of hydrazine combusted. a. -622 kJ/mol b. -312 kJ/mol c. -19.4 kJ/mol d. -9.69 kJ/mol

14. Calculate the enthalpy of formation of calcium carbonate, Ca(s) + C(s) + 3/2 O2(g) CaCO3(s) given the enthalpies: 2 Ca(s) + O2(g) 2 CaO(s) H = -1270.2 kJ C(s) + O2(g) CO2(g) H = -393.5 kJ CaO(s) + CO2(g) CaCO3(s) H = -178.3 kJ a. -419.9 kJ/mol b. -1206.9 kJ/mol c. -1485.4 kJ/mol d. -1842.0 kJ/mol

15. Which one of the following reactions is not a standard enthalpy of formation reaction? a. C(s) + O2(g) CO2(g) b. O2(g) + 2 H2(g) 2 H2O(g) c. Ca(s) + F2(g) CaF2(s) d. Ba(s) + S(s) + 2 O2(g) BaSO4(s) 16. Determine the standard enthalpy of reaction for the following reaction, C3H8(g) + 5 O2(g) 3 CO2(g) + 4 H2O(g) given the following standard enthalpies of formation. Species a. -531.5 kJ ( kJ/mol) b. -2043.9 kJ C3H8(g) -103.8 c. -2219.9 kJ CO2(g) -393.5 d. -2459.8 kJ

H2O(g) H2O(l)

-241.8 -285.8