XII Chemistry M.M. 70 Q.

1-8 1 Mark
1. 2. 3. 4. 5.

Complete Syllabus

Test-I Time: 3 Hrs. Q.28-30 5 Marks

Q.9-18

2 Marks

Q.19-27

3 Marks

What is effect of temperature on conductance of metals and semiconductors? What is electrophoresis? What is meant by term hydrometallurgy? Why is electron gain enthalpy of sulphur higher than that of oxygen? Give IUPAC name of the following compound:

6. 7. 8. 9.

10. i) ii) iii) iv) 11. i) 12. i) 13. i) 14. i) 15. 16. 17.

Write the structure of 2-phenyl ethanal. Give an example of thermosetting plastic. Arrange the following compounds in an increasing order of basic strengths in their aqueous solution: NH3, C2H5NH2, (C2H5)2NH, (C2H5)3N. What type of cell is mercury cell? Write the anode and cathode reactions and the overall cell reaction occurring in mercury cell. Why does its voltage remain constant for a long period of time? OR Two half cell reactions of an electrochemical cell are given below: Cr2O72- (aq) + 14H+ (aq) + 5e- 2Cr3+ (aq) + 7 H2O (l) E = 1.38 V Sn2+ (aq) Sn4+ (aq) + 2e-, E = + 0.15 V Construct the redox reaction from the two half cell reactions and predict if this reaction favours formation of reactants or product shown in the equation. Observe the graph shown in diagram and answer the following questions: What is order of reaction? What are units of rate constant? How does t1/2 of reaction vary with concentration of reactants? Derive expression for t1/2 for the reaction. Complete and balance the following chemical reactions: XeF6 + H2O ii) Cl2+NaOH (hot and conc.) Complete the following chemical reactions and balance them: Cr2O72- + C2O42- + H+ ii) MnO4- + Fe2+ + H+ Describe the underlying principle each of the following metal refining methods: Liquation ii) Zone refining Which one in the following pairs undergo SN2 substitution reaction faster and why? ii) Name the four bases present in RNA. Which one of these is not present in DNA? Name two water soluble vitamins, their sources & the diseases caused due to their deficiency in the diet. Complete the following chemical reactions:

i) 18. 19. 20.

21.

ii) CH2=CH2 + Br2 Differentiate between addition and condensation polymerisations. Give one example of each. A first order gas reaction has k = 1.5 10-6 s-1 at 473 K. If the reaction is allowed to continue for 10 hours, what percentage of the initial concentration would have changed in the product? Metallic gold crystallizes in face centred cubic lattice. The edge length of the cubic unit cell is 407 pm. Calculate the density of gold & radius of gold atom. [Atomic mass of Au = 197 g mol-1 and NA = 6.02 1023] For what concentration of Ag+ (aq) will e.m.f. of the cell be zero at 250 C if concentration of Cu2+ (aq) is 0.01 M? Cu(s)|Cu2+ (0.01M)||Ag+ (aq)|Ag(s) [Given: E0(Ag+|Ag) = 0.80 V & E0(Cu2+|Cu) = 0.338 V].

Note: Try to attempt all optional questions also, if any, after you have completed your test within the stipulated time limit.

22. i) ii) iii) 23.

i) 24. i) ii) iii) 25. i) ii) iii) 26.

What happens in the following activities and why? Fe(OH)3 sol. is mixed with As2S3 sol. River water meets sea water. A beam of light is passed through dust particles suspended in air. Compare the following complexes with respect to structural shapes of units, magnetic behaviour and hybridised orbitals involved in units: [Fe(CN)6]4-, [NiCl4] 2-, [Pt(NH3)2 Cl2] [Atomic numbers: Fe = 26, Ni = 28 and Pt = 78] OR Giving a suitable example of each, explain the following: Coordination Isomerism ii) Hexadentate ligand iii) Crystal field splitting. Explain the following observations: The boiling point of n-butyl alcohol is higher than that of tertiary butyl alcohol. p-nitrophenol is more acidic than p-methoxy phenol. Methanol has higher dipole moment than phenol. How would you account for the following: Most of the transition metals form coloured compounds. The separation of lanthanoids is difficult. Potassium permanganate is stored in dark coloured bottles. Complete the following chemical reactions:

27. i) 28. a) i) b)

a) i) b) 29. a) i) b) i) ii) iii) a) b) i) ii) iii) 30. a) i) b) i) a) i) b)

Describe the following substances with one suitable example of each type: Cationic detergents ii) Artificial sweateners iii) Antiseptics. Define the following terms: Osmotic pressure ii) Molarity of solution Calculate the molecular weight of cellulose acetate, if its 0.2% (mass/volume) solution n acetone shows an osmotic pressure of 0.136 atm at 27C. (R = 0.0821 L atm mol-1K-1) OR What is meant by: Elevation in boiling point ii) Vapour pressure Henrys law constant for CO2 in water is 1.67 108 Pa at 298 K. Calculate the quantity of CO2 in 500 ml of soda water when packed under 2.5 atm pressure of CO2 at 298 K. Draw the structures of the following: ii) H3PO3 ClF3 How would you account for the following: H2S is more acidic than H2O. HClO is stronger oxidising agent than HClO4. Phosphorus has greater tendency for catenation than nitrogen. OR Draw the structures of the following: i) XeOF4 ii) ClO3. Explain the following observations: PH3 has lower boiling point than NH3. Nitrogen has higher value of first ionisation enthalpy than that of oxygen. Noble gases have very low boiling points. Write chemical equations to illustrate the following name bearing reactions: Aldol Condensation ii) Wolff-Kishner Reduction. Give chemical tests to distinguish between the following pairs of compounds: Formic acid & Ethanoic acid ii) Acetophenone & Benzaldehyde iii) Ethanol & acetone. OR How will you bring about the following conversions: Benzaldehyde to Acetophenone ii) Toluene to m-nitro Benzaldehyde. Compound A (C6H12O2) on hydrolysis in the presence of an acid gives B and C. The compound B on heating with Cu powder gives D which on treatment with aqueous alkali and subsequent heating gives E. E on catalytic hydrogenation gives C. D was oxidised to F which is monobasic acid with molecular weight 60. Deduce the structures of A to F.

Note: Try to attempt all optional questions also, if any, after you have completed your test within the stipulated time limit.