SHINEHILL ACADEMY Chemistry

Daily Practice Problem Sheet-3 (Solution)

1. Only one option is correct: 60 gm of urea (mol. wt. 60) was dissolved in 9.9 mols of water. If the vapour pressure of pure water is Po, the vapour of solutions is (a) 0 0.1P0 (b) 0 1.1 P0 (c) 0.90 P0 (d) 0.99 P0 The relative lowering of vapour pressure produced by dissolving 71.5 g of a substance in 1000 g of water is 0.00713. The molecular weight of the substance will be (a) 18.0 (b) 342 (c) 60 (d) 180 Benzene acid undergoes dimerisation in benzene solution, the Vant Hoff factor i is related to degree of association x of the acid as (a) i = (1 x) (b) i = (1 + x) (c) i = (1 x / 2) (d) i = (1 + x / 2) Arrange the following aqueous solutions in the order of their increasing boiling points (i) 10 4 M NaCl (ii) 10 4 M urea (iii) 10-3 M MgCl2 (iv) 10 2 M NaCl (a) (i) < (ii) < (iv) < (iii) (b) (ii) < (i) = (iii) < (iv) (c) (i) < (ii) < (iii) < (iv) (d) (iv) < (iii) < (i) = (ii) The boiling point of 0.1 molal K4[Fe(CN)6] solution will be (given Kb for water = 0.52C kg mol-1 ) (a) 100.52C (b) 100.104C (c) 100.26C (d) 102.6C The freezing point of a 0.01 M aqueous glucose solution at 1 atmosphere is 0.18 o C . To it, an addition of equal volume of 0.002 M glucose solution will produce a solution with freezing point of nearly (a) 0.036 o C (b) 0.108 o C (c) 0.216 o C (d) -0.422 o C

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Subjective type questions 7. Calculate the mass percentage of benzene (C6H6) and carbon tetrachloride (CCl4) if 22 g of benzene is dissolved in 122 g of carbon tetrachloride. 8. Calculate the mole fraction of benzene in solution containing 30% by mass in carbon tetrachloride. 9. Calculate the molarity of each of the following solutions: (a) 30 g of Co(NO3)2. 6H2O in 4.3 L of solution (b) 30 mL of 0.5 M H2SO4 diluted to 500 mL. 10. Calculate the mass of urea (NH2CONH2) required in making 2.5 kg of 0.25 molal aqueous solution. 11. Calculate (a) molality (b) molarity and (c) mole fraction of KI if the density of 20% (mass/mass) aqueous KI is 1.202 g mL-1. 12. Henrys law constant for CO2 in water is 1.67 108 Pa at 298 K. Calculate the quantity of CO2 in 500 mL of soda water when packed under 2.5 atm CO2 pressure at 298 K. 13. The vapour pressure of pure liquids A and B are 450 and 700 mm Hg respectively, at 350 K. Find out the composition of the liquid mixture if total vapour pressure is 600 mm Hg. Also find the composition of the vapour phase. 14. Vapour pressure of pure water at 298 K is 23.8 mm Hg. 50 g of urea (NH2CONH2) is dissolved in 850 g of water. Calculate the vapour pressure of water for this solution and its relative lowering. 15. Boiling point of water at 750 mm Hg is 99.63C. How much sucrose is to be added to 500 g of water such that it boils at 100C. Molal elevation constant for water is 0.52 K kg mol1. 16. Calculate the mass of ascorbic acid (Vitamin C, C6H8O6) to be dissolved in 75 g of acetic acid to lower its melting point by 1.5C. Kf = 3.9 K kg mol1. 17. Calculate the osmotic pressure in pascals exerted by a solution prepared by dissolving 1.0 g of polymer of molar mass 185,000 in 450 mL of water at 37C.

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