II P U C CHEMISTRY

CHAPTERWISE IMPORTANT QUESTIONS BY Dr.R.S.Narsegowda, LECTURER IN CHEMISTRY, Vijaya Vittala College, Mysore I.METALLURGY;(6M) 1.what is an Ellingham's diagram? What are its salient features?----5M 2.write a note on reducing property of carbon & CO. ----3M 3.With a neat labeled diagram explain the extraction of cast iron from calcined ore? --- 5M* 4.State distribution law.Explain the separation of silver from argentiferrous lead?* --5M 5. Silver oxide (or HgO) is thermodynamically less stable . explain with the help of Ellingham's diagram. --2M II INDUSTRIALLY IMPORTANT COMPOUNDS;(6M) 1)With a neat labeled diagram explain the manufacture of a)ammonia by Haber's process----3M b)sodium hydroxide by nelsons cell--4M* c)sulphuric acid by contact process--4M d)potassium di chromate4M 2) How is conc. Sulphuric acid reacts with a)PCl5 b)HCOOH ------2M 3)How does potassium di chromate reacts with a)KCl b)KOH ----2M III.GROUP-18 NOBLE GASES;(3M) 1.Write the general electronic configuration of noble gases.------1M 2.Explain isolation of noble gases from air by Ramsay-Rayleigh's method.3M* 3. How is noble gases are separated from a mixture by Dewar charcoal adsorption method?--3M* 4. How is Xenon converted in to xenonhexafluoroplatinate?-----2M* IV.d- BLOCK ELEMENTS;(3M) 1. Write the general electronic configuration of transition elements. 2.write the electronic configuration of a)Cu b)Cr c)Fe-----1M 3.Give reason a) d- block elements forms colored compounds.---2M* b). d- block elements forms complexes-----2M V.COORDINATION COMPOUNDS;(8M) 1. What is a complex ion? -----1M 2. Give an example for a bidentate ligand. ----1M 3.Explain a)linkage isomerism b)ionisation isomerism c)hydrate isomerism---2M* 4.write the postulates of Werner's theory. ------3M* 5. calculate the EAN of a)potassium ferro cyanide b) cuprammonium sulphate 6. Explain sp3 hybridisation that takes place in Ni(CO)4 ---4m* 7.Explain d2sp3 hybridisation that takes place in potassium ferro cyanide . --4M* 8. Explain dsp2 hybridisation that takes place in cuprammonium sulphate.--4M* 9.IUPAC nomenclature of a compound-----1M VI.CHEMICAL BONDING; ( 6M) 1. Write any four differences between bonding & anti bonding molecular orbitals.---2M 2. Write the molecular orbital electronic configuration of a)Li2 b)O2 ----1M* 3. Account for the non existence of Helium molecule ----2M* 4.On the basis of LCAO explain the formation of bonding & anti bonding molecular orbitals.----4M 5.Write the energy level diagram for formation of O2 molecule . calculate the bond order. predict on magnetic property.------4M* 6.What is a metallic bond?---1M 7.Write a note on electron sea model.-----2M VII.CHEMICAL KINETICS: (7M) 1.What is a a) second order reaction . Give an ex. b)pseudo unimolecular reaction . Give an ex. c)zero order reaction . Give an ex. -----2M 2.Derive an expression for the rate constant of a first order reaction .---4M* 3.Show that k=0.693/t1/2 -2M * (+problems for two marks ) 4.Write the Arrhenius equation & explain the terms.---2M 5.What is meant by a)threshold energy b) energy of activation ---1M

BY NRS, LECTURER IN CHEMISTRY, G P U COLLEGE, SAGAR VIII.ELECTROCHEMISTRY;

1. State Faraday's a) first law of electrolysis b) second law of electrolysis ---2M 2. Write the assumptions of Arrhenius theory of electrolytic dissociation .--4M* 3. Write the merits of Arrhenius theory of electrolytic dissociation 2M 4 Write the limitations of Arrhenius theory of electrolytic dissociation 2M 5. Explain Brownsted -Lowry concept of an acid & a base with ex.---2M* 6. Explain Lewis concept of an acid & a base with ex.---2M* 7. Writing conjugate acid& base---1M* 8. Problems on PH ---2M* 9.explain the buffer mechanism of a)acetic acid sodium acetate buffer solution b)ammonium hydroxide- ammonium chloride buffer solution ---3M* 10.what is common ion effect?---1M* 11.what is solubility product of a sparingly soluble salt? 12.Problems on solubility (AB type, AB2 type and A2B type )----2M 13.what is standard hydrogen electrode? How it is constructed?-----4M* 14.what are the limitations of SHE?--2M* 15.explain the working of Daniel cell-----3M 16.problems on calculation of cell potentials using single electrode potentials-2M IX.THEORY OF DILUTE SOLUTION (5M) 1. What are colligative properties?---1M 2. Define the term a) vapor pressure b)relative lowering of vapor pressure c)osmotic pressure--2M 3. State Raoults law.----2M 4. How is relative lowering of vapor pressure measured by Ostwald's Walker dynamic method?* X.CHEMICAL THERMODYNAMICS: (5M) 1.What is a) entropy b)a spontaneous process?--1M 2. what is the unit of entropy?---1M 3.state second law of thermodynamics.--1M 4. what is Gibbs free energy?---1M 5. write the equation which relates standard free energy change& equilibrium constant Kp---2M* (+problems)* 6.what are the values of H & S for a non spontaneous process? XI. COLLOIDS: (4M) 1. Write any four differences between lyophilic & lyophobic sols.---2M 2. How is gold sol prepared by Bredigs electric arc method?---2M 3.Explain a)Tyndall effect b)Brownian movement c)electrophoresis ---2M 4. state Hardy-Schulz rule.-----1M 5. what is gold no. ? XII.SOLID STATE: (3M) 1. Distinguish between crystalline & amorphous solids ---2m 2.what is a) a unit cell b)meant by co ordination no. of a crystalline solid --1M 3.calculate the no. of particles per unit cell in a) body centered cube b) face centered cube ---2M 4. what is meant by radius ratio ? 5. write the structure of a) sodium chloride b)cesium chloride---2M XIII.CONCEPTS IN ORGANIC CHEMISTRY: (2M) 1. explain with example a)inductive effect b)mesomeric effect c)electromeric effect ----2M XIV.SYNTHETIC ORGANIC CHEMISTRY: (4M) 1.How do you convert a)methane to ethane ---2M b)ethane to methane---4M* c)methanol to ethanol---4M* d) ethanol to methanol---4M* XV.ISOMERISM:(4M) 1.Explain optical isomerism with an example---2M 2.Explain geometrical isomerism with an example.---2M 3. What is a chiral carbon atom ? 1M BY NRS, LECTURER IN CHEMISTRY, G P U COLLEGE, SAGAR XVI.HYDROCARBONS -2 (6M)

1. With the help of Bayer's strain theory explain the stability of cyclo alkanes -3M 2.Elucidate the structure of benzene.----4M 3. explain the mechanism of a)halogenation b) nitration c)sulphonation d)Friedel crafts reaction -------4M* 4. Explain Sache-Mohrs theory of strain less rings----2M XVII.HALO ALKANES:(4M) 1.Explain with example a) wurtz reaction b)wurtz- fittigs reaction ---2M 2. Explain SN1 mechanism of hydrolysis of tertiary butyl bromide ---3M 3. Explain SN2 mechanism of hydrolysis of methyl bromide ------3M XVIII.ORGANIC COMPOUNDS CONTAINING OXYGEN: (12M) 1. How is phenol manufactured by cumene process?--2M 2. Explain a) Kolbes reaction b)Reimer-Tiemanns reaction2M 3. Explain Aldol condensation with an example.---2M 4.Explain a) Perkin's reaction b)Cannizzaro's reaction----2M 5.Explain the mechanism of Cannizzaro's reaction ----3M 6. How is acetic acid manufactured from methyl magnesium iodide ?---2M 7. Explain how the relative strength of acetic acid, chloro acetic acid, di & tri chloro acetic acids.--2M XIX.AMINES: (3M) 1. How is acetamide converted in to methanamine?--2M 2. what is the action of acetyl chloride on ethanamine?---2M 3. Write a note on relative basicity of ammonia , methyl ammine, ethyl ammine & aniline----3M XX.CARBOHYDRATES: (3M) 1. What are a) monosaccharides b)oligo saccharides c) poly saccharides1M 2. Write the Howarths structure of a) a- D- glucose b) - D- Glucose c)a- D-fructopyranose d) - D-fructopyranose f)a- D-fructofuranose g) - D-fructofuranose h)sucrose i)maltose--2M XXI.OILS & FATS: (3M) 1. Write the general formula of tri glycerides ---2M 2.what is saponification ? Give an example.2M 3.what is rancidity? How it is prevented?---2M 4. How is oils are refined?---2M 5.what are drying oils ? Give an example. 6. what is iodine value?---1M XXII.AMINO ACIDS & PROTEINS: (3M) 1. What is a)a zwitter ion b) iso- electric point? ---1M 2. what is a tri peptide ?how many amino acid molecules & peptide bonds are present in a tri peptide?---2M QUESTIONS ON PRACTICAL PART FOR TEN MARKS (very ,. Imp.) 1. How is m-dinitro benzene prepared from nitro benzene?---3M 2. How is p- bromoacetanilide prepared from acetanilide?---3M 3. Explain a) Molisch test b) Benedicts test c)Seliwanoff's test d)Acrolin test e)Biuret test f)xanthoprotic acid test g)Millon test---2M 4. Estimate the mass of KMnO4 present in one litre of given solution using standard oxalic acid solution . ----5M 5.Estimate the mass of KMnO4 present in one litre of given solution using standard ferrous ammonium sulphate solution . ----5M 6. Estimate the mass of ferrous ammonium sulphate solution present in one litre of given solution using standard K2Cr2O7 solution . ----5M BY NRS, LECTURER IN CHEMISTRY, G P U COLLEGE, SAGAR