1.

2A + 2B 2C + DH < 085

[C]2 [D]
[A]2 [B]2
(B)
(A)K =

(C)r = k[A]2[B]2k
(D)
(E)EaEa H
2.

3.

86
(A)
(B)
(C)
(D)
AgCl(s) + 2NH3(aq)

+
3 2 ( aq )

Ag(NH )

+ Cl

( aq )

[Ag( NH 3 ) +2 ][Cl ]
Kc =
= 2.4 103
2
[ NH 3 ]

AgClKsp = 1.8 1010NH3Kb = 1.6 105

/ 86
(a) 0.5 M
(b) 5.0 M NH3
4.

2 1
87
(A) (B)
(C)
(D)

5.

PbCl2 0.010 M Pb(NO3)2s / PbCl2

Ksp87
(A) 4s3

6.

(B) 0.04s2

(C) 0.01s3

(D) 0.04s2 + 4s3

CO2(aq) K = 0.034CO2(aq) M
25CO2(g)
CO2(g) atm87
(A) 251 atm 0.034 M
(B) 251 atmpH = 8 NaOH 0.034 M
(C) 251 atm 0.034 M
(D)K
(E)K

7.

A(g) + 2B(g)
2C(g) + mol / L
KcatmKpAB
88
(A)C
(B)Kc
(C)Kp
(D)KcKp
36

8.

2X(aq) + Y(aq)
Z(aq) 2 MX 1 MY
0.5 MZ 1 MY 0.9 MZX
88
(A) 5 M

9.

(B) 7 M

(C) 9 M

(D) 11 M

2724.6 N2O4NO2 1.0 atm

xN2O4NO288
( 27N2O4(g)
(A) x 1.0

2NO2(g) Kp = 1.6)

(B) 1.0 > x 0.70

(C) 0.70 > x 0.40

(D) 0.40 > x

10.

88

1
2
3
4
5

M
[BrO 3 ]
[Br]
[H+]
0.10
0.10
0.10
0.20
0.10
0.10
0.20
0.20
0.10
0.10
0.10
0.20
0.40
0.30
0.20

Ms1
8.0 104
1.6 103
3.2 103
3.2 103
R

(1)
(2)
(3) 5 R
11. AgNO3 0.10 M Cl 0.10 M CrO 24
Ag+ 1.0 107 M
( AgClKsp = 1.8 1010Ag2CrO4Ksp = 2.5 1012 )89
(A) AgCl
(C) AgClAg2CrO4

(B) Ag2CrO4
(D)

PCl3(g) + Cl2(g) 337Kp = 10.0(atm) 500

12. PCl5(g)
2.085 PCl5 337(P = 31.0Cl = 35.5)89
(1)PCl5
(2)Cl2
(3)PCl5(g)PCl3(g) 375 kJ 287 kJ
(4) 250
13.
90
(A)
(B)
(C)
(D)
14. 1 1 40
2NH3(g)
(A) 0.043

N2(g) + 3H2(g) Kc90

(B) 0.12

(C) 0.80
37

(D) 17

15. 0.1 AgCl(s) 1 Ag (+aq) + Cl (aq)

AgCl(s)

AgCl(s) 90
( AgClKsp = 1.7 1010AgIKsp = 8.3 1017 )
(A) 1
(B) 0.01 AgNO3(s)
(E) 0.01 Ag(s)
(D) 0.01 NaI(s)

(C) 10 NH3(aq)

16. IO 3( aq ) + 3HSO 3( aq ) I (aq) + 3SO 24( aq ) + 3H (+aq)

1 0.428 KIO3(s) 100.0 A 0.019 Na2S2O5(s)
0.5 0.10 M H2SO4(aq) 0.400 100.0 B
2 10.0 A 10.0 B
10.0
( O = 16.0Na = 23.0S = 32.0K = 39.0I = 127 )90
(1)Na2S2O5
(2) 1 AIO3
(3) 2
(4)HSO3 2
2NH3(g) + 92 kJFe2O3 500
17. N2(g) + 3H2(g)
91
(A)
(B)
(C)
(D)
(E)
18. ABC 25
91

mol / L
mol / L

A
0.1
0.05

B
0.2
0.05

C
0
0.1

(A) 1 A 3 B 2 C
1
3
C 25 40
(B) A + B
2
2
(C)B A 3
(D) C 1 / 3
(E) 4.9

19. PbI2Ksp 2.5109 1.0103MNaI

Pb(NO3)2PbI2
Pb(NO3)293
(A)2.5103 M
(B)2.0102 M
(C)5.0102 M
(D)8.0102 M
(E)1.0101 M
38

20. N2O4 35 C
45 C 93
(A)
(B)
(C)
(D)
(E)
21.
93
(A)
(B)
(C)
(D)
22. pH93
(A)AgCl

(B)ZnS

(C)CaCO3

(D)PbI2

(E)Ag3PO4

23. SO2Cl2 173 oC 100

0.03 SO2Cl22.0 1.0 Kp 3.0
93
(A)
(B)(K c ) 0.082
(C)SO2Cl2 0.003 M
(D)SO2Cl2
(E)SO2Cl2
2 4 - 2 5
24. HCl(g)H2(g)Cl2(g)
ZZX H2(g) Cl2(g)
2HCl(g) YZZ

500C (Kc) 0.01 1.0 HCl(g) 1.0 500C

HCl(g) () 94
(A)5

(B)17

(C)25

(D)33

(E)40

25. HCl(g)94
(A)
(B)
(C)
(D)
(E)
26. 0.05g 20mL 0.01M
(Ag3PO4Ksp=31018) 94
(A)NaCl

(B)Na3PO4

(C)AgNO3

(D)HNO3

(E)H3PO4

27. 94
(A)pH
(B)
(C)
(D) (E)
39

28. 94
ZZX 2H2(g)+S2(g)
ZZX COCl2(g)
(B)CO(g)+Cl2(g) YZZ
(A)2H2S(g) YZZ
ZZX CaC2(s)+CO(g)
(C)CaO(s)+3C(s) YZZ

ZZX SO3(g)+NO(g)
(D)SO2(g)+NO2(g) YZZ

ZZX NaHCO3(s)
(E)CO2(g)+NaOH(s) YZZ

29.

(atm)

3 Al (s) + 3 NH 4 ClO 4 (s) Al 2 O 3 (s) + AlCl 3 (s) + 3 NO ( g ) + 6 H 2 O ( g ) + 2677 kJ

1 . 0 1 . 0 400K

2 ( )

()

2
94
(1) (mol/min)
(2) 5 (mol)
(3) 5 (kJ)

1.

(A)(B)(E)

(A)
[C]2 [D]
K=
[A]2 [B]2
(B)H < 0
(C)

(D)
(E)H = Ea Ea
Ea = Ea H =Ea H

2.

(B)

40

3.

(a) 3.6 1010 M (b) 0.22 M

(a) AgCl(s) Ag++Cl

x
0.5 + x
10
x(0.5 + x) = 1.8 10
x = 3.6 1010 M
Ag(NH3) +2 + Cl
(b) AgCl + 2NH3

x2
= 2.4 103
(5 2 x ) 2

Kc=

x
= 0.049
5 2x

x = 0.22 M

2x
5 2x

x
x

x
x

4.

(B)
K

5.

(D)

PbCl2(g)

Pb2+ + 2Cl
0.01 + s
2s
Ksp = (0.01 + s)(2s)2 = 0.04s2 + 4s3
6.

(A)(B)(C)(D)

[CO 2 ( aq ) ]
[CO 2 ( aq ) ]
(A) K =
= 0.034
= 0.034
1
PCO 2
[CO2(aq)] = 0.034 M
(B) 2NaOH + CO2 Na2CO3 + H2O
CO2
(C)CO2 0.03CO2 3 104 atmCO2 0.034 M
(D)
(E) CO2CO2

7.

(D)

(A)[C]
(B)Kc
(C)Kp
(D) Kp = Kc(RT)23 Kc = Kp(RT) T > 298 RT > 0 Kc > Kp

8.

(A)

2X
2
1
1

Y
1

2X + Y

1

0.5
0.5

0.5
0.5

1.8
x

0 .5
=1
0.5 12
x 3 + 1.8 = 4.8 M

K=

K=

0.9
0.1

0 .9
=1
0 .1 x 2
41

Z
0.9
0.9

x=3

9.

(C)

PV = nRT

1 24.6 = n 0.082 300 n = 1 mol

n N 2O 4
= x n N 2 O 4 = xn NO 2
n N 2 O 4 + n NO 2 = 1
n NO 2

n NO 2 =

1
1+ x

n N 2O 4 =

x
1+ x

N2O4 2NO2
x
1

1+ x
1+ x
1
(
1) 2
1
+
x
1.6 =
x = 0.44
x
1
1+ x
(C) x = 0.44 (C)

10. (1) 4
(2) 8M3s1
(3) 3.84 102 M / s

(1) c(1)(2) r [BrO 3 ]

d(1)(4) r [H+]2
e(1)(3) r [Br]
(2) 8.0 + 104 = k(0.1)(0.1)(0.1)2 k = 8.0 M3s1
(3) R = 8.0 0.40 0.30 (0.20)2 = 3.84 102 M / s
11. (A)

[Ag+][Cl] = 1 107 0.1 = 1 108 > 1.8 1010

[Ag+]2[CrO 24 ] = (1 107)2 0.1 = 1 1015 < 2.5 1012
AgCl
(2) 0.916 atm
(3) 88 kJ
12. (1) 1.0 atm

(1) PCl5 = 208.5

PV = nRT
500
2.085
P
=
0.082 (337 + 273)
1000 208.5
(2) PCl5
PCl3 + Cl2
1.0

(4)

1.0 atm

x
x
x
1x
x
x
2
x
= 10 x = 0.916 atm
1 x
(3)H = 287 ( 375) = 88 kJ
(4)
13. (A)

42

14. (B)

15.

2NH3

N2 + 3H

1
0.4
0.6

0
0
0.2 0.6
0.2 0.6

[ N 2 ][H 2 ]3 (0.2)(0.2) 3
=
= 0.12
Kc =
[ NH 3 ] 2
(0.6) 3

(A)(C)(D)

(A) [Ag+][Cl]
(B)
(C) Ag+ + 2NH3 2Ag(NH3) +2
(D) AgCl(s) + NaI(s) AgI(s) + NaCl(s)
(E)

16. (1) Na2S2O5 + H2O 2NaHSO3

(2) 0.02 M
(3)(I2)
(4) 104 M / s

(2) KIO3 = 214V = 100= 0.1

[IO 3 ] =

0.428 / 214
= 0.02M
0 .1

(3) [IO 3 ]
5I (aq) + 6H (+aq) + IO 3( aq ) 3I2(s) + 3H2O(l)
I2(s) +
IO 3
0.02 0.01
1
=
=1>

3
HSO 3 0.02 0.01
I2

(4)

[HSO 3 ] 0.02 0.01 / 0.02

=
= 104M / s
t
10

17. (A)(B)(C)(E)

(A)(B)(C)

(D)

(E)()
43

18. (A)(B)(E)

aA(g)+bB(g) cC(g)
0.1 M
0.2 M
0
0.05 M
0.05 M
0.1 M

(A)

[A ]
[B]
+ [C]
=
=
at
bt
ct
(0.05 0.1) (0.05 0.2) + (0.1 0)
=
=
a
b
c

abc = 132
A(g) + 3B(g) 2C(g)
(B) Kc =

(0.1) 2
= 40
(0.05)1 (0.15)3

(C) PV = nRT P = CMRT

P CM PA = PB
(D) PV = nRT
P n CM
XC =

0 .1
1
= 0.5 =
0.05 + 0.05 + 0.1
2

(E) Pt = CtRT
= (0.05 + 0.05 + 0.1) 0.0820 (273 + 25) = 4.9atm
19. (B)

(1)(Ksp)
(2)()
Pb(NO3)2X M
KspPb2I2 1/2 X 1.01031/222.5109
x2.0102 M
20. (B)(E)

N2O42NO2
(A) 35C
(B)
(C)
(E)
21. (C)

(A)
(B)(D) pH 35C55C
pH 58
44

22. (B)(C)(E)

P.20
23. (B)(D)

(A)SO2Cl2(g) U SO2(g) Cl2(g)

62 1

42

SO2 Cl2
(B)KpKc(RT)n
3.0Kc(0.082446)(111) Kc0.082
0.03
0.0003M
100
[SO 2 ][Cl2 ]
[0.02] [0.01]
(D)Q

0.667Kc
[SO2 Cl2 ]
[0.0003]

(C)[SO2Cl2]

SO2Cl2
(E)SO2Cl2
24. (B)

2HCl(g)

1M
(12x)M

U H2(g) Cl2(g)
0
0
xM
xM
xx
1
= 0.01 x
Kc
2
12
(12x)
%

100%

1
12 100% 17%
1

25. (A)

HCl(g)HCl(g)
26. (C)

Ag+PO43
Ag3PO4Ksp[ Ag]3[PO43][Ag]
27. (A)(C)

CaCO3 U Ca2 CO32

(A)pHHCO32
2HCO32CO2H2O
(B)(E)
(C)
(D)
45

28. (B)(E)

()
29. (1)7.610-4 ( mol / min )
(2)3.8103 ( mol )
(3)3.4 kJ

(1)NO(g)H2O(g)
9331

08 minngas

PV
0.6 1.0
3

mol
RT 0.082 400 164

1 3

mol
1
3
164
rAl

7.6104mol/min
8 min
1312
5
3.8103 mol
1312
(3) 3 mol 2677 kJ

(2) 5 rAl 5

2677
5

3.4kJ
1312
3

46