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SRIGAYATRI EUDCATIONAL INSTITUTIONS

Hyderabad Nalgonda Karimnagar Vijayawada Guntur Vizag Kadapa Tirupati


SRIGAYATRI EUDCATIONAL INSTITUTIONS
PART I : PHYSICS
SECTION I : Single Correct Answer Type
This section contains 10 multiple choice questions. Each question has four
choices (A), (B), (C) and (D) out of which ONLY ONE is correct.
1. Three very large plates of same area are kept parallel and close to each other. They are
considered as ideal black surfaces and have very high theermal conductivity. The first and third
plates are maintained at temperatures 2T and 3T respectively. The temperature of the middle
(i.e. second) plate under steady state condition is
(A)
1
4
65
2
T
| |
|
\ .
(B)
1
4
97
4
T
| |
|
\ .
(C)
1
4
97
2
T
| |
|
\ .
(D)
( )
1
4
97 T
Sol. (C)
Under steady state condition, temperature
0
T of middle plate remains constant.
Hence heat received by second plate = heat emitted by it
( ) ( ) ( )
4
4 4 4 4 4 4 4
0 0 0
3 27 2 3 2 T T T T T = = +
4
0
97
2
T T =
2. Consider a thin spherical shell of radius r which its centre at the origin, carrying uniform positive surface
charge density. The variation of the magnitude of the electric field ( ) E r

and the electric potential ( ) V r


with the distance
r
from the centre, is best represented by which graph?
(A) (B)
(C) (D)
Sol. (D)
Inside a shell of uniform charge, the electric field is zero. Outside it varies as
2
1
E
r

.
Inside the shell of charge, potential is constant and outside
1
V
r

.
Hence (D0 is the correct answer.
3. Youngs double slit experiment is carried out by using green, red and blue light, one color at a time. The
fringe widths recorded are ,
G R
| | and
B
| , respectively. Then,
(A)
G B R
| | | > > (B)
B G R
| | | > > (C)
R B G
| | | > > (D)
R G B
| | | > >
Sol. (D)
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Hyderabad Nalgonda Karimnagar Vijayawada Guntur Vizag Kadapa Tirupati
SRIGAYATRI EUDCATIONAL INSTITUTIONS
Since
D
d

| =

R G B R G B
| | | > > > >
4. Two large vertical and parallel metal plates having a separation of 1 cm are connected to a DC voltage
source of potential difference X. A proton is released at rest midway between the two plates. It is found
to move at
0
45
to the vertical JUST after release. Then X is nearly
(A)
5
1 10 V

(B)
7
1 10 V

(C)
9
1 10 V

(D)
10
1 10 V

Sol. (C)

There are two forces acting on the particle


(1) Electrical force =
e
F and (2) Gravitational force = mg
As it moves at
0
45
hence
e
F mg =
.
X
e mg
d
=
27 2
19
1.6 10 10 10
1.6 10
d
X mg
e


= =

9
1.0 10

=
volts.
5. A bi-convex lens is formed with two thin plano-convex lenses as shown in the figure. Refractive index n
of the first lens is 1.5 and that of the second lens is 1.2. Both the curved surfaces are of the same radius of
curvature R = 14 cm. For this bi-convex lens, for an object distance of 40 cm, the image distance will be
(A) 280.0cm (B) 40.0cm (C) 21.5cm (D) 13.3cm
Key B
Sol. Say the focal length of first half lens is
1
f and that of second half is
2
f
( )
1
1 1 1
1.5 1
14 f
| |
=
|

\ .
1
28 f cm =
Similarly
2
70 f cm =


1 2
1 1 1 1 1
28 70 F f f
= + = +
F = 20 cm
1 1 1
V u F
=
1 1 1
40 20 V
| |
=
|
\ .

V = 40 cm
SRIGAYATRI EUDCATIONAL INSTITUTIONS
Hyderabad Nalgonda Karimnagar Vijayawada Guntur Vizag Kadapa Tirupati
SRIGAYATRI EUDCATIONAL INSTITUTIONS
6. A small mass m is attached to a massless string whose other end is fixed at P as shown in the figure. The
mass is undeergoing circular motion in the x y plane with centre at O and constant angular speed e. If
the angular momentum of the system, calculated about O and P are denoted by
0
L

and
P
L

respectively, ,
then
(A)
O
L

and
P
L

do not vary with time. (B)


O
L

varies with time while


P
L

remains constant
(C)
O
L

remains constant while


P
L

varies with time (D)


O
L

and
P
L

both vary with time


Sol. (C)
The resultant force (of tension and wieght) passes through the point O. Therefore torque about O is zero.
0
0 0
0
d L
L
dt
t = = =


constant vector
The torque of resultant force about P varies in direction as the mass rotates in a circle.
Hence
P
L

is not a constant vector


7. A mixture of 2 moles of helium gas (atomic mass = 4 amu) and 1 mole of argon gas (atomic mass = 40
amu) is kept at 300 K in a container. The ratio of the rms speeeds
( )
( )
helium
argon
rms
rms
v
v
| |
|
|
\ .
is
(A) 0.32 (B) 0.45 (C) 2.24 (D) 3.16
Sol. (D)
( )
( )
2
1
Helium
Argon
rms
rms
V M
V M
=
3
rms
RT
V
M
| |
=
|
|
\ .

40
10 3.16
4
= = =
8. A thin uniform rod, pivoted at O, is rotating in the horizontal plane with cosntant angular speed e, as
shown in the figure. At time
0 t =
, a small insect starts from O and moves with constant speed v with
respect to the rod towards the other end. It reaches the end of the rod at
t T =
and stops. The angular
speed of the system remains e throughout. The magnitude of the torque
( )
t

on the system about O, as


a function of time is best represented by which plot?
SRIGAYATRI EUDCATIONAL INSTITUTIONS
Hyderabad Nalgonda Karimnagar Vijayawada Guntur Vizag Kadapa Tirupati
SRIGAYATRI EUDCATIONAL INSTITUTIONS
(A) (B)
(C) (D)
Sol. (B)
J Ie =
( )
sec rod in t
I I e = + ( )
2 2
rod
I mv t e = +
2
2
dJ
mv t
dt
t e = =
t t
When insect stops, I becomes constant, hence J
0 t =
. Hence B is the correct answer
9. In the determination of Youngs modulus
2
4MLg
Y
ld t
| |
=
|
\ .
by using Searles method, a wire of length
2 L m =
and diameter 0.5 d mm = is used. For a load M = 2.5 kg, an extension
0.25 l =
mm in the length of the
wire is observed. Quantities
d
and
l
are measured using a screw gauge and a micrometer, respectively. .
They have the same pitch of 0.5 mm. The number of divisions on their circular scale is 100. The contributions
to the maximum probable error of the Y measurement
(A) Due to the error in the measurements of
d
and
l
are the same
(B) Due to the error in the measurement of
d
is twice that due to the error in the measurement of
l
.
(C) Due to the error in the measurement of
l
is twice that due to the error in the measurement of
d
.
(D) Due to the error in the measurement of
d
is four times that due to the error in the measurement of
l
.
Sol. (A)
2
Y l d
Y l d
A A A | |
= +
|
\ .
( ) , , have fixed values M L g
pitch
no. of divisions an circular scale
l A =
3
0.5
5 10
100
l mm

A = =
3
5 10 d l mm

A = A =
Now
l
l
A
=
relative error in
3
5 10
0.25
mm
l
mm

=
1
50
l
l
A
=
Similarly
3
5 10 1
6.5 100
d mn
d mn

A
= =

SRIGAYATRI EUDCATIONAL INSTITUTIONS


Hyderabad Nalgonda Karimnagar Vijayawada Guntur Vizag Kadapa Tirupati
SRIGAYATRI EUDCATIONAL INSTITUTIONS
10. A small block is connected to one end of a massless spring of un-stretched length 4.9 m. The other end of
the spring (see the figure) is fixed. The system lies on a horizontal frictionless surface. The block is stretched
by 0.2 m and released from rest at
0 t =
. It then executes simple harmonic motion with angular frequency
/
3
rad s
t
e =
. Simultaneously at
0 t =
, a small pebble is projected with speed v from point P at an angle
of
0
45
as shown in the figure. Point P is at a horizontal distance of 10 m from O. If the pebble hits the
block at
1 t s =
, the value of v is (take
2
10 / g m s = )
(A)
50 / m s
(B)
51 / m s
(C)
52 / m s
(D)
53 / m s
Sol. (A)
For the block,
2 2
6
3
T s
w
t t
t
= = =
6
1.5
4 4
T
s = =
Therefore in 1 second it travels a distance less than A.
Let
cos x A wt =
for the block
1
0.2cos 1 0.2 0.1
3 2
x m
t | |
= = =
|
\ .
Therefore when the pebble hits the block, the block is at a ditance of ( ) 4.9 0.2 0.1 m m m +
5m = from 0.
Now time of flight = T = 1 sec.

( )
0
cos 45 1 V = Range = ( ) 10 5 5 R m m = =
5 2 50 / V m s = =
SRIGAYATRI EUDCATIONAL INSTITUTIONS
Hyderabad Nalgonda Karimnagar Vijayawada Guntur Vizag Kadapa Tirupati
SRIGAYATRI EUDCATIONAL INSTITUTIONS
SECTION II : Multiple Correct Answer(s) Type
This section contains 5 multiple choice questions. Each question has four
choices (A), (B), (C) and (D) out of which ONE or MORE are correct
11. For the resistance network shown in the figure, choose the correct option(s).
(A) The current through PQ is zero (B)
1
3 I A =
(C) The potential at S is less than that at Q (D)
2
2 I A =
Sol. (A,B,C,D)
Due to symmetry in the circuit P and Q are at same potential also S and T are at same potential.

There is no current in PQ. Hence A is correct.


4
AB
R = O
1
12
3
4
I A = =
also,
2 3
6 12 I I =
2 3
2 I I =
2 3 1 2
2 I I I I A + = =
2
2 I A =
Q P
V V = & Kirchhoffs rule 4
P S
V V =
4
P S
V V = +
P Q S
V V V = >
12. A person below into open-end of a long pipe. As a result, a high-pressure pulse of air travels down the
pipe. When this pulse reaches the other end of the pipe
(A) a high-pressure pulse starts traveling up the pipe, if the other end of the pipe is open
(B) a low-pressure pulse starts travelling up the pipe, if the other end of the pipe is open
(C) a low-pressure pulse starts traveling up the pipe, if the other end of the pipe is closed
(D) a high-pressure pulse starts traveling up the pipe, if the other end of the pipe is closed
SRIGAYATRI EUDCATIONAL INSTITUTIONS
Hyderabad Nalgonda Karimnagar Vijayawada Guntur Vizag Kadapa Tirupati
SRIGAYATRI EUDCATIONAL INSTITUTIONS
Sol. (B,D)
Since at open end pressure node is formed hence high pressure pulse is relfected as low pressure pulse

B is correct & A is wrong

At closed end pressure antinode is formed.


Hence high pressure pulse is relfected as high pressure pulse D is correct & C is wrong
13. Consider the motion of a positive point charge in a region where there are simultaneous uniform electric
and magnetic fields
0

E E j =

and
0

B B j =

. At time
0 t =
, this charge has velocity
v

in the x-y plane,


making an angle
u
with the x-axis. Which of the following option(s) is (are) correct for time
0 t >
?
(A) If
0
0 u =
, the charge moves in a circular path in the x-z plane.
(B) If
0
0 u =
, the charge undergoes helical motion with constant pitch along the y-axis
(C) If
0
10 u =
, the charge undergoes helical motion with its pitch increasing with time, along the y-axis
(D) If
0
90 u =
, the charge undergoes lilnear but accelerated motion along the y-axis.
Sol. (A, C, D)
If
0 u =
,
V Vi =

, = 0, 0
el
F = ; 0
mag
F =
If
0 u =


x y
V V i V j = + ,
y
V is varying due to
E
and
x
V gives circular path in zx-plane.

helical path with increasing pitch


At
0
90 u =
, 0
mag
F = ; but 0
el
F =

accelerated linear motion.


14. A cubical region of side a has its centre at the origin. It encloses three fixed point charges, q at
( ) 0, / 4, 0 a , 3q + at ( ) 0, 0, 0 and q at ( ) 0, / 4, 0 a + . Choose the correct option(s)
(A) The net electric flux crossing the plane
/ 2 x a = +
is equal to the net electric flux crossing the plane
/ 2 x a =
(B) The net electric flux crossing the plane / 2 y a = + is more than the net electric flux crossing the plane
/ 2 y a = .
(C) The net electric flux crossing the entire region is
0
q
c
(D) The net electric flux crossing the plane
/ 2 z a = +
is equal to the net electric flux crossing the plane
/ 2 x a = +
Sol. (A,C,D)
As ( ) q is placed symmetrically w.r.t. origin

flux through y z planes or


/ 2 x a = +
equal to flux through
/ 2 x a =
. Hence A is correct
SRIGAYATRI EUDCATIONAL INSTITUTIONS
Hyderabad Nalgonda Karimnagar Vijayawada Guntur Vizag Kadapa Tirupati
SRIGAYATRI EUDCATIONAL INSTITUTIONS
As the
in
Q q =
0

0
Net
q
| =
e
. Hence C is correct
As the planes at
/ 2 z a = +
and
/ 2 z a =
are symmetric w.r.t. charge distribution.

Flux at planes
/ 2 Z a = + =
Flux at plane
/ 2 z a =
. Hence D is correct.
15. A small block of mass of 0.1 kg lies on a fixed inclined plane PQ which makes an angle
u
with the
horizontal. A horizontal force of 1 N acts on the block through its centre of mass as shown in the figure.
The block remains stationary if ( )
2
take g = 10m/s
(A)
0
=45 u
(B)
0
>45 u
and a frictional force acts on the block towards P. .
(C)
0
>45 u
and a frictional force acts on the block towards Q.
(D)
0
<45 u
and a frictional force acts on the block towards Q.
Sol. (A,C)
From the figure, cos sin N mg u u = + or
sin cos N u u = +
For
0
45 u =
:
sin cos u u =
Block is stationary. .
Hence option (A) is correct
For
0
45 u >
:
sin cos u u >
Block will be stationary if frictional force acts towards Q.
Hence (C) is correct
If
0
45 , cos sin u u u > > Block will be stationary if frictional force acts towards P. .
Hence option (D) is wrong
SECTION III : Integer Answer Type
This section contains 5 questions. The question to each question is a single
digit integer, ranging from 0 to 9 (both inclusive)
16. A cylindrical cavity of diameter a exists inside a cylinder of diameter 2a as shown in the figure. Both the
cylinder and the cavity are infinitely long. A uniform current density J flows along the length. If the magnitude
of the magnetic field at the point P is given by
0
12
N
aJ
, then the value of N is
SRIGAYATRI EUDCATIONAL INSTITUTIONS
Hyderabad Nalgonda Karimnagar Vijayawada Guntur Vizag Kadapa Tirupati
SRIGAYATRI EUDCATIONAL INSTITUTIONS
Sol. (5)
Magnetic field at P (B) =
1 2
B B
1
B = Magnetic field due to whole cylinder without cavity
2
B = Magnetic field due to cavity assuming carrying current in opposite direction
0
1
2
Ja
B

=
and
0
2
12
Ja
B

=


0
5
12
Ja
B

=
5 N =
17. A proton is fired from very far away towards a nucleus with charge 120 Q e = , where e is the electronic
charge. It makes a closest approach of 10 fm to the nucleus. the de Broglie wavelength (in units of fm) of
the proton at its start is : (take the proton mass, ( )
27
5/ 3 10 ;
p
m kg

=
15
/ 4.2 10 . / ; h e J s C

=
9
0
1
9 10 / ;
4
m F
tc
=

15
1 10 fm m

= )
Sol. (7)
KE of proton = Potential energy of system at distance of closest approach
( )( )
2
0 0
120
2 4
e e p
m r t
=
e
( )( )
2
0 0
2 120
4
m e
p
r t
=
e
( ) de-Broglie wavelength
h
p
=
( )( )
2
0 0
2 120
4
h
m e
r t
=
e
Substituting the values
15
7 10 m

=

7
18. A circular wire loop of radius R is placed in the x-y plane centered at the origin O. A square loop of side
( ) a a R << having two turns is placed with its center at
3 z R =
along the axis of the circular wire loop,
as shown in figure. The plane of the square loop makes an angle of
0
45
with respect to the z-axis. If the
mutual inductance between the loops is given by
2
0
/ 2
2
p
a
R

, then the value of p is


SRIGAYATRI EUDCATIONAL INSTITUTIONS
Hyderabad Nalgonda Karimnagar Vijayawada Guntur Vizag Kadapa Tirupati
SRIGAYATRI EUDCATIONAL INSTITUTIONS
Sol. (7)
2
0
3
2 1
4 8
i r
B
r
t
t

=
0
16
i
B

t
=
2 0
1
. 2
16 2
i
a
r

| =
= M.i.
( )
( )
2 2
0 0
7/ 2
2 8 2
a a
M
r r

= =
Hence
7 P =
19. An infinitely long solid cylinder of radius R has a uniform volume charge density . It has a spherical
cavity of radius R/2 with its centre on the axis of the cylinder. as shown in the figure. The magnitude of the
electric field at the point P, which is at a distance 2r from the axis of the cylinder, is givenby the expression
0
23
16
R
k

c
. The value of k is
Sol. (6)
2
0 0
1 1
.
2 2 4 4
P
q
E
R R

t t
=
e e
2
R t = and
3
6
R
Q
t
=
0
23
6
96
P
R
E K

= =
e
SRIGAYATRI EUDCATIONAL INSTITUTIONS
Hyderabad Nalgonda Karimnagar Vijayawada Guntur Vizag Kadapa Tirupati
SRIGAYATRI EUDCATIONAL INSTITUTIONS
20. A lamina is made by removing a small disc of diameter 2R from a bigger disc of uniform mass density and
radius 2R, as shown in the figure. The moment of intertia of this lamina about axes passing through O and
P is
O
I and
P
I , respectively. Both these axes are perpendicular to the plane of the lamina. The ratio
P
O
I
I
to the nearest integer is
Sol. (3)
4
0
13
2
R
I
ot
=
4
37
2
P
I R ot =
0
37
/
13
P
I I =
3 ~
PART - II : CHEMISTRY
SECTION - I : Single Correct Answer Type
This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and
(D) out of which ONLY ONE is correct.
21. For one mole of a van der Waals gas when b = 0 and T = 300 K, the PV vs
1
V
plot is shown below. The
value of the van der Waals constant a (atm. liter
2
mol
2
) is
A) 1.0 B) 4.5 C) 1.5 D) 3.0
Key: C
Sol. For 1 mole vandewaals euqations is
| |
2
a
P V b RT
V
(
+ =
(

b = 0
2
a
P V RT
V
(
+ =
(

a
PV RT
V
+ =
SRIGAYATRI EUDCATIONAL INSTITUTIONS
Hyderabad Nalgonda Karimnagar Vijayawada Guntur Vizag Kadapa Tirupati
SRIGAYATRI EUDCATIONAL INSTITUTIONS
1
. PV RT a
V
=
Slope =
2 1
2 1
1.5
y y
a
x x

= =

1.5 a =
22. The number of optically active products obtained from the complete ozonolysis of the given compound is
A) 0 B) 1 C) 2 D) 4
Key : A
Sol. Ozonolysis products
3
3
|
3 3
|
CH H
H CH
CH CHO OCH C CHO OCH C CHO CH CHO
V

+ + +
None of the products are asymmetric hence ans = zero
23. The colour of light absorbed by an aqueous solution of CuSO
4
is
A) orange - red B) blue - green C) yellow D) violet
Key: A
Sol: Orange - Red
24. Which ordering of compounds is according to the decreasing order of the oxidation state of nitrogen ?
A)
3 4 2
HNO , NO, NH C , N l B)
3 2 4
HNO , NO, N , NH Cl
C)
3 4 2
HNO , NH C , NO, N l D)
3 4 2
NO, HNO , NH C , N l
Key: B
Sol.
5 2 0 3
3 2 4
HNO NO N N H Cl
+ +
> > >
25. As per IUPAC nomeclature, the name of the complex ( ) ( )
2 3 3
4 2
Co H O NH C (

l is
A) Tetraaquadiaminecobalt (III) chloride B) Tetraaquadiamminecobalt (III) chloride
C) Diaminetetraaquacobalt (III) chloride D) Diamminetetraaquacobalt (III) chloride
Key : D
Sol. Diamminetetraaquacobalt (III) chloride
26. The carboxyl functional group (-COOH) is present in
A) picric acid B) barbituric acid C) ascorbic acid D) aspirin
Key: D
Sol.
O
COOH
O
C CH
3
Barbituric acid
O=C
NH-C
O
O
NH-C
2
CH
Picric acid
2
NO
2
NO
2
NO
OH
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Hyderabad Nalgonda Karimnagar Vijayawada Guntur Vizag Kadapa Tirupati
SRIGAYATRI EUDCATIONAL INSTITUTIONS
27. The kinetic energy of an electron in the second Bohr orbit of a hydrogen atom is [a
0
is Bohr radius]
A)
2
2 2
0
h
4 ma t
B)
2
2 2
0
h
16 ma t
C)
2
2 2
0
h
32 ma t
D)
2
2 2
0
h
64 ma t
Key: C
Sol.
2
1
.
2
K E mv =
and also
2
nh
mvr
t
=
2
nh
mv
r t
=
,
2 2
2 2
2 2
4
n h
m v
r t
= ,
2 2
2
2 2
4
n h
mv
mr t
=
( )
2 2 2 2 2
2 2 2 2 2 2 2
2
0 0
0
1 1 4
2 4 2 32 32
4 4
n h h h
KE
mr ma ma
m a
t
t t t
t
(
(
= = = = (
(
(

28. In allene (C
3
H
4
), the type(s) of hybridisation of the carbon atoms is (are)
A) sp and sp
3
B) sp and sp
2
C) only sp
2
D) sp
2
and sp
3
Key : B
Sol. CH
2
= C= CH
2
sp
2
sp sp
2
29. A compound M
p
X
q
has cubic close packing (ccp) arrangement of X. Its unit cell structure is shown
below. The empirical formula of the compound is
A) MX B) MX
2
C) M
2
X D) M
5
X
14
Key: B
Sol. M is at M edge centers = 4 = M
M is at body center = 11 = M

Total 2M
X at 8 corners and 6 face centers =
1 1
8 6 1 3 4
8 2
X
| | | |
= + = + =
| |
\ . \ .
Formuale = M
2
X
4
= MX
2
30. The number of aldol reaction(s) that occurs in the given transformation is
A) 1 B) 2 C) 3 D) 4
Key : C
3 Aldol condensations as there are 3o hydrogens
31. Choose the correct reason(s) for the stability of the lyophobic colloidal particles.
A) preferential adsorption of ions on their surface from the solution
B) preferential adsorption of solvent on their surface from the solution
C) attraction between different particles having opposite charges on their surface
D) potential diffrence between the fixed layer and the diffused layer of ooposite charges around the
colloidal particles.
Key : A & D [Conceptual]
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32. For an ideal gas, consider of P - V work in going from an initial state X to the final state Z. The final state
Z can be reached by either of the two paths shown in the figure. Which of the following choice(s) is (are)
correct ? [Take
S A
as change in entropy and w as work done]
A)
x z x y y z
S S S

A = A + A B)
x z x y y z
w w w

= +
C)
x y z x y
w w

= D)
x y z x y
S S

A = A
Key : A & C
Entropy changes from x yand y z
x y y z
s s s

A = A + A
Work done from y z 0 =
x y z x y
w w

=
33. Which of the following hydrogen halides react(s) with AgNO
3
(aq) to give a precipitate that dissolves in
Na
2
S
2
O
3
(aq) ?
A) HCl B) HF C) HBr D) HI
Key : AgF is soluble in H
2
O hence A,C,D
34. Identify the binary mixture(s) that can be separated into individual compounds, by differential extraction,
as shown in the given scheme.
A)
6 5
C H OH and
6 5
C H COOH B)
6 5
C H COOH and
6 5 2
C H CH OH
C)
6 5 2 6 5
C H CH OH and C H OH D)
6 5 2 6 5 2
C H CH OH and C H CH COOH
Key : B,D
35. Which of the following molecules, in pure form, is (are) unstable at room temperature ?
A) B) C) D)
Key : B & C are anti aromatic and
36. The periodic table consists of 18 groups. An isotope of copper, on bombardment with protons, undergoes
a nuclear reaction yielding element X as shown below. To which group, element X belongs in the periodic
table ?
63 1 1 1
29 1 0 1
Cu H 6 n 2 H X + +o + +
Key :
63 1 1 4 1
29 1 0 2 1
Cu H 6 n He 2 H + + + +
52
26
Fe = 8
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37. An organic compound undergoes first - order decomposition. The time taken for its decomposition to 1/
8 and 1/10 of its initial concentration are t
1/8
and t
1/10
respectively. What is the value of
1/ 8
1/ 10
[t ]
10?
[t ]
(take log
10
2 = 0.3)
Key :
3
1/ 8 1/ 8
1/10 1/10
t t log8 log(2)
10 10 9
t log10 t 1
(
(
= = =
(
(
(

38. 29.2% (w/w) HCl stock solution has a density of 1.25 g mL
1
. The molecular weight of HCl is 36.5 g
mol
1
. The volume (mL) of stock solution required to prepare a 200 mL solution of
0.4 M HCl is
Key :
10dx 10 1.25 29.2
M 10
GMW 36.5

= = =
V
1
M
1
= V
2
M
2
1
V 10 200 0.4 / = /
V
1
= 8ml
39. The substituents R
1
and R
2
for nine peptides are listed in the table given below. How many of these
peptides are positively charged at pH = 7.0 ?


3
| | | |
1 2
H N CH CO NH CH CO NH CH CO NH CH COO
H R R H

Key : 4 [IV, VI, VIII, IX]


40. When the following aldohexose exists in its D-configuration, the total number of stereoisomers in its
pyranose form is
|
2
|
|
|
2
CHO
CH
CHOH
|
CHOH
CHOH
CH OH
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Key : 8
O
OH
OH
OH
H
H
H
H
H
*
*
*
*
H
HOH C
2
Total no.of stereoisomers = 2
4
= 16
No.of stereoisomers of D - Pyranose = 8
PART - II : MATHEMATICS
SINGLE ANSWER TYPE QUESTIONS :
41. Let
( )
2
cos , 0
, ,
0, 0
x x
f x x x
x
t
=

= e


then f is
(A) differentiable both at
0 x =
and at
2 x =
(B) differentiable at
0 x =
but not differentiable at
2 x =
(C) not differentiable at
0 x =
but differentiable at
2 x =
(D) differentiable neither at
0 x =
nor at
2 x =
Sol : ( )
( ) ( )
0
0
' 0 lim
0
x
f x f
f
x

2
0
cos
lim 0
x
x
x
finite
x
t
+

= =
2
0
cos
lim 0
x
x
x
finite
x
t

= =

0. =
Similarly at
2 x =
.
42. The function | | | | : 0, 3 1, 29 , f defined by ( )
3 2
2 15 36 1, f x x x x = + + is
(A) one-one and onto (B) onto but not one-one
(C) one-one but not onto (D) neither one-one nor onto
Sol : ( )
3 2
2 15 36 1 f x x x x = + +
( )
2
' 6 30 36 f x x x = + ( )( ) 6 2 3 x x =
neither increasing nor decreasing in | | 0, 3
f is not one - one
Range
=
codomain

onto.
43. The ellipse
2 2
1
: 1
9 4
x y
E + = is inscribed in a rectangle R whose sides are parallel to the coordinate axes.
Another ellipse
2
E passing through the point ( ) 0, 4 circumscribes the rectangle R. The eccentricity of the
ellipse
2
E is.
(A)
2
2
(B)
3
2
(C)
1
2
(D)
3
4
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Sol:
2 2
2 2
: 1
16
x y
E
a
+ = .
It passes ( ) 3, 4
2
2
9 4
1 12
16
a
a
+ = =
2 2 2
2 2
: 1 1
12 16
x y b
E e
a
+ = =
12 1
1 .
16 2
e = =
44. The point P is the intersection of the straight line joining the points ( ) 2, 3, 5 Q and ( ) 1, 1, 4 R with the
plane 5 4 1. x y z = If
S
is the foot of the perpendicular drawn from the point ( ) 2,1, 4 T to , QR then
the length of the line segment PS is
(A)
1
2
(B)
2
(C) 2 (D)
2 2
Sol: Any point on QR is ( ) 2 , 3 4 , 5 t t t + + +
it lies on plane
2
3
t =
.
it is perpendicular to line joining T to this
9 1 9 1
, ,
2 2 2 2 2 2
| | | |
=
| |
\ . \ .
4 1 13 3 9
, , ,1,
3 3 3 2 2
P S
| | | |
= =
| |
\ . \ .
1
2
PS =
45. The locus of the mid-point of the chord of contact of tangents drawn from points lying on the straight line
4 5 20 x y = to the circle
2 2
9 x y + = is
(A) ( )
2 2
20 36 45 0 x y x y + + = (B) ( )
2 2
20 36 45 0 x y x y + + =
(C) ( )
2 2
36 20 45 0 x y x y + + = (D) ( )
2 2
36 20 45 0 x y x y + + =
Sol: Let ( ) , o |
Then ( ) 4 5 20 1 o | =
Chord of contact of w.r.t circle ( ) 9 2 x y o | + =
Equation of chord in terms of midpoints is
( )
2 2
1 11 1 1
3 xx yy x y + = +
( ) ( ) 2 & 3 same
1
2 2
1 1
9x
x y
o =
+
1
2 2
1 1
9y
x y
| =
+
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substitute in ( ) 1 we get locus as
( )
2 2
1 1 1 1
20 36 45 0 x y x y + + =
46. Let
ij
P a
(

= be a
3 3
matrix and let ,
ij
b Q (

= where 2
i j
ij ij
b a
+
= for 1 , 3. i j s s If the determi-
nant of P is 2, then the determinant of the matrix Q is.
(A)
10
2
(B)
11
2
(C)
12
2
(D)
13
2
Sol: 2 P =
2 3 4
11 12 13
3 4 5
21 22 23
4 5 6
31 32 33
2 2 2
2 2 2
2 2 2
a a a
Q a a a
a a a
(
(
=
(
(

2 3 4 13
2 .2 .2 .2.4. 2 Q P = =
47. The integral
( )
9
2
2
sec
sec tan
x
dx
x x +
} equals (for some arbitrary constant K)
(A)
( )
( )
2
11 2
1 1 1
sec tan
11 7
sec tan
x x K
x x

+ +
`
) +
(B)
( )
( )
2
11 2
1 1 1
sec tan
11 7
sec tan
x x K
x x

+ +
`
) +
(C)
( )
( )
2
11 2
1 1 1
sec tan
11 7
sec tan
x x K
x x

+ + +
`
) +
(D)
( )
( )
2
11 2
1 1 1
sec tan
11 7
sec tan
x x K
x x

+ + +
`
) +
Sol:
sec tan x x t + =
1
sec tan x x
t
=
1 1
sec
2
x t
t
| |
= +
|
\ .
sec
dt
x dx
t
=
48. The total number of ways in which 5 balls of different colours can be distributed among 3 persons so that
each person gets at least one ball is
(A) 75 (B) 150 (C) 210 (D) 243
Sol: Number of onto functions from set having 5 elements to set having 3 elements

5 3 5 3
1 2
3 2 243 96 3 150 c c = + = + =
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49. If
2
1
4,
1
lim
x
x x
ax b
x

| | + +
=
|
+
\ .
then
(A) 1, 4 a b = = (B) 1, 4 a b = = (C) 2, 3 a b = = (D) 2, 3 a b = =
Sol:
2 2
1
lim 4
1
x
x x ax ax bx b
x

+ +
=
+
Equating the coeff of
2
0 x =
and coeff
4 x =
1 0 1 a a = =
1 4 4. a b b = =
50. Let z be a complex number such that the imaginary part of z is non zero and
2
1 z a z + + =
is real. Then
a cannot take the value
(A)
1
(B)
1
3
(C)
1
2
(D)
3
4
Sol: If Z x iy = + then ( )
2 2
1 2 . a x y x i xy y = + + + + real
(
1
2 0 0.
2
xy y x y

+ = = =
2
3 3
3 4
4 4
a y y a a = = e <
and 0 y =
MULTIPLE TYPE QUESTIONS :
51. Let S be the area of the region enclosed by
2
,
0, 0,
x
y e y x

= = =
and
1. x =
Then
(A)
1
S
e
>
(B)
1
1 S
e
>
(C)
1 1
1
4
S
e
| |
s +
|
\ .
(D)
1 1 1
1
2 2
S
e
| |
s +
|
\ .
Sol:
tan 2 sec
dy
y x x x
dx
=
. . G S
is
2
cos y x x c = +
( ) 0 0 0 y c = =
2
cos
x
y
x
=
( )
2
4
8 2
y A
t t | |
= =
|
\ .
2
2
cos .2 sin
'
cos
x x x x
y
x
+
=
( )
2
4 2
'
3 3
3 3
y D
t t t | |
= = +
|
\ .
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52. If ( ) y x satisfies the differential equation y y tan 2 sec x x x = and ( ) 0 0, y = then
(A)
2
4
8 2
y
t t | |
=
|
\ .
(B)
2
4 18
y
t t | |
=
|
\ .
(C)
2
3 9
y
t t | |
=
|
\ .
( D )
2
4 2
3 3
3 3
y
t t t | |
= +
|
\ .
Sol: (A)
( )
( )
( ) ( ) ( )
( )
1 2 3
1
2
1 2 3 1 3 1 2 3 1 2 3
C
P E E E
P X X
P E E E P E E E P E E E P E E E

=
+ + +
1
32
1
8
8
32
= =
.
(B)
Exactly twoengines of theship are functioning
P
X
(
(

( ) ( ) ( )
( ) ( ) ( ) ( )
3 2 1
1 2 1 3 2 3
3 2 1
1 2 1 3 2 3 1 2 3
P E E E P E E E P E E E
P E E E P E E E P E E E P E E E
+ +
+ + +
7
8
=
(C)
( )
( ) ( ) ( )
( ) ( ) ( ) ( )
1
1 2 3 2 3 1 2 3
2
1 2 3 1 2 3 1 2 3 1 2 3
P E E E P E E E P E E E
P X X
P E E E P E E E P E E E P E E E
+ +
=
+ + + +
5
8
=
(D)
( )
( ) ( ) ( )
( ) ( ) ( ) ( )
1 2 3 1 2 3 1 2 3
1
3
1 2 3 1 2 3 1 2 3 1 2
P E E E P E E E P E E E
P X X
P E E E P E E E P E E E P E E E
+ +
=
+ + +

7 32
7
16
16 32
= =
53. Tangents are drawn to the hyperbola
2 2
1,
9 4
x y
= parallel to the straight line 2 1. x y = The
points of contact of the tangents on the hyperbola are
(A )
9 1
.
2 2 2
| |
|
\ .
(B)
9 1
.
2 2 2
| |

|
\ .
(C)
( )
3 3, 2 2 (D)
( )
3 3, 2 2
Sol: ( ) 2cos 1 sin 2sin cos 1 u u u u =
( ) 2 co s 1 2 sin u u | + = +
( )
1
c o s s i n
2
u u | + = +
3
1 sin
2
u < < ,
tan 0 u <
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5
3
2 3
x t
u < <
1
cos .
2
o u < <
1 1
cos 1
2 2
u < + <
( )
1
sin 1
2
u | < + <
5
2 2 , 0,1, 2
6 6
n n n
t t
t u | t + < + < + =
54. Let | | , 0, 2 u t e be such that
( )
2
2cos 1 sin sin tan cot cos 1,
2 2
u u
u u
| |
= +
|
\ .
( ) tan 2 0 t u > and
3
1 sin .
2
u < < Then cannot satisfy..
(A)
0
2
t
< <
(B)
4
2 3
t t
< <
(C)
4 3
3 2
t t
< <
(D)
3
2
2
t
t < <
Sol:
2 1
0
.
x
S e dx

=
}
( )
2
x
f x e

= is decreasing function
( ) ( )
1
A S b a m
e
> >
( ) 0 1 B x < <
2 2
x x x x < <
2
x x
e e

>
1
0
1
1
x
S e dx
e

> =
}
( ) ( )
2
11
1 1
4
2 2
x
D f x e x x

| | | |
= +
| |
\ . \ .
1 1 1
1
2 2
S
e
| |
s +
|
\ .
55. A ship is fitted with three engines
1 2
, E E and
3
. E The engines function independently of each
other with respective probabilities
1 1
,
2 4
and
1
.
4
For the ship to be operational at least two of
its engines must function. Let
X
denote the event that the ship is operational and let
1 2
, X X
and
3
X denote respectively the events that the engines
1 2
, E E and
3
E are functioning. Which
of the following is (are) true ?
(A)
1
3
16
c
P X X ( =

(B)
P
[Exactly two engines of the ship are functioning
7
8
X ( =

(C) | |
2
5
16
P X X =
(D) | |
1
7
16
P X X =
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Sol: Any line Parallel to 2 1 x y = is 2 0 x y k + =
4 2 k =
2 4 2 0 x y =
Point of contact
9 1 9 1
, ,
2 2 2 2 2 2
| | | |
=
| |
\ . \ .
INTEGER TYPE QUESTIONS
56. The value of
3
2
1 1 1 1
6 log 4 4 4 ....
3 2 3 2 3 2 3 2
| |
|
+
|
\ .
is
Sol:
2 2 2
2 4 0, 8 x y x y y x + = =
solving
4 2
2
4 0
64 4
y y
y y + =
3
0, 48 256 0 y y y = + =
( ) ( ) ( ) 0, 0 2, 4 2, 0 P Q S = = =
Area
1
8 4 . .
2
sq u = =
57. Let S be the focus of the parabola
2
8 y x = and let PQ be the common chord of the circle
2 2
2 4 0 x y x y + = and the given parabola. The area of the triangle PQS is
Sol: Let ( ) ( ) ( ) ( )
1 2
1 3 9 3 P x k x x k x x = = +
Then
( )
3
2
2 3
3
x
P x K x x C
(
= + +
(

( )
1
1 2 3 6
3
P K C
(
= + + =
(


4
6
3
K
C + =
( ) ( ) 3 2 0 2 P K C = + =
4
4 3
3
K
K = =
( ) ( ) ( ) ( )
1
3 1 3 0 3 3 9. P x x x P = = =
58. If
, a b

and
c

are unit vectors satisfying


2 2
2
9, a b b c c a + + =


then 2 5 5 a b c + +


is
Sol:
( )
2
2
2
2
1 1
1 1 0
1 0 1
1 1
x x if x
x x x
f x
x x x
x x x
<

< <
=

+ < <

+ >

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