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Electromagnetic waves
Lecture topics Generation of EM waves Terminology Wave and particle models of EM radiation EM spectrum
Generation of EM waves
Acceleration of an electrical charge EM wavelength depends on length of time that the charged particle is accelerated Frequency depends on number of accelerations per second Antennas of different sizes Nuclear disintegrations = gamma rays Atomic-scale antennas = UV, visible, IR radiation Centimeter/Meter-scale antennas = radio waves http://www.phy.ntnu.edu.tw/ntnujava/index.php?topic=35
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Water molecule
There is no fundamental constraint on the frequency of EM radiation, provided an oscillator with the right natural frequency and/or an energy source with the minimum required energy is present
Electromagnetic Spectrum
EM Spectrum
Continuous range of EM radiation From very short wavelengths (<300x10-9 m) High energy To very long wavelengths (cm, m, km) Low energy Energy is related to wavelength (and hence frequency)
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EM wave terminology
EM waves characterized by: Wavelength, (m) Amplitude, A (m) Velocity, v or c (m s-1) Frequency, f or (s-1 or Hz) cycles per second Sometimes period, T (time for one oscillation i.e., 1/f)
v
Wavelength units
EM wavelength specified using various units
cm (10-2 m) mm (10-3 m) micron or micrometer, m (10-6 m) nanometer, nm (10-9 m) Angstrom, (10-10 m, mostly used in astronomy) f (or ) is waves/second, s-1 or Hertz (Hz) also MHz, GHz Wavenumber (inverse wavelength) also commonly used: given by 1/ (sometimes also 2/) e.g. cm-1 (symbol: ) What is the wavenumber (in cm-1) equivalent to = 1 m?
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Electromagnetic energy
EM radiation defined by wavelength (), frequency (f) and velocity (v) where: v = f i.e. longer wavelengths have lower frequencies etc. v and can change according to medium f is constant Generally more useful to think in terms of (numbers are easier) NB. Where v = c, this relationship refers to wavelength in a vacuum.
AM
FM
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AM = Amplitude modulation (530 1700 kHz) FM = Frequency modulation (87.8 108 MHz) EM wave amplitude can be affected by many things passing under a bridge, re-orienting the antenna etc. No natural processes change the frequency Radiation with frequency f will always have that frequency until it is absorbed and converted into another form of energy
Angular frequency = 2f = 2/T Frequency with which phase changes Angles in radians (rad) 360 = 2 rad, so 1 rad = 360/2 = 57.3 Rad to deg. (*180/) and deg. to rad (* /180)
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Wave-particle duality
Property of EM radiation Reflection Refraction Interference Diffraction Polarization Photoelectric effect Consistent with WAVE Yes Yes Yes Yes Yes No PARTICLE Yes Yes No No No Yes
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Photons
The energy of a single photon is: hf or = (h/2) where h is Planck's constant, 6.626 x 10-34 Joule-seconds One photon of visible light contains about 10-19 Joules - not much is the photon flux, or the number of photons per unit time in a beam.
P P = hv hc
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Bohr quantized shell model of the atom (1913): electrons jump from one orbit to another only by emitting or absorbing energy in fixed quanta (levels) If an electron jumps one orbit closer to the nucleus, it must emit energy equal to the difference of the energies of the two orbits. When the electron jumps to a larger orbit, it must absorb a quantum of light equal in energy to the difference in orbits.
Electron energy levels are unevenly spaced and characteristic of a particular element. This is the basis of spectroscopy. To be absorbed, the energy of a photon must match one of the allowable energy levels in an atom or molecule.
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Electromagnetic energy
EM radiation also considered in quantum terms, where each photon carries an energy E (in Joules) given by: E = hf (or h) where h is Plancks constant (6.626x10-34 J s), f = frequency
Electromagnetic energy
E=
hv
i.e. the energy of a photon is inversely proportional to Implications for sensor design, pixel size etc.
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Frequency decomposition
Naturally occurring EM radiation hardly ever consists of a single frequency or wavelength But, any arbitrary EM fluctuation can be thought of as a composite of a number (potentially infinite) of different pure periodic functions This is known as Fourier decomposition So any EM wave can be regarded as a mixture of pure sine waves with differing frequencies, and the propagation of each frequency component can be tracked completely separately from the others. In remote sensing, the implication is that individual frequencies can be considered individually, then the results summed over all relevant frequencies.
Time
This light wave has many frequencies. And the frequency increases in time (from red to blue).
EM radiation composed entirely of a single frequency is termed monochromatic (one color) Radiation that consists of a mixture of frequencies is called broadband. So transport of broadband radiation can always be understood in terms of the transport of individual constituent frequencies (monochromatic radiation)
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Photochemistry
Many chemical reactions that take place in the atmosphere, including those that produce smog, are driven by sunlight. The stratospheric ozone layer also owes its existence to photochemical processes that break down oxygen molecules (O2). The photon energy E = h is a crucial factor in determining which frequencies of EM radiation participate in these processes.
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Mostly absorbed by O3 in stratosphere; small fraction (0.31-0.32 m) reaches surface and causes sunburn (effect of ozone depletion?); energetic enough for photochemistry
Visible light
Wavelengths and frequencies of visible light (VIS) Atmosphere mostly transparent optical remote
sensing techniques, surface mapping etc. Includes wavelength of peak emission of radiation by the Sun (~50% of solar output in this range) Cloud-free atmosphere mostly transparent to VIS wavelengths, so most are absorbed at the Earths surface Clouds are highly reflective in the VIS implications for climate?
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Reflective (shortwave IR, SWIR) Emissive or thermal IR (TIR; 4 50 m) absorbed and emitted by water
vapor, carbon dioxide, ozone and other trace gases; important for remote sensing and climate Note boundary (~4 m) separates shortwave and longwave radiation
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The transition wavelengths are a bit arbitrary Now, well run through the entire electromagnetic spectrum, starting at very low frequencies and ending with the highest-frequency gamma rays.
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Long-wavelength EM spectrum
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Microwave ovens
Microwave ovens operate at 2.45 GHz, where water absorbs very well.
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Wavenumber (cm-1)
Interestingly, blackbody radiation retains a blackbody spectrum despite the expansion of the universe. It does get colder, however.
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Old Faithful
Infrared Lie-detection
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Stars that are just forming emit light mainly in the IR.
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The Tactical High Energy Laser uses a high-energy, deuterium fluoride chemical laser to shoot down short range unguided (ballistic flying) rockets.
Laser welding
Near-IR wavelengths are commonly used.
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Auroras
Solar wind particles spiral around the earths magnetic field lines and collide with atmospheric molecules, electronically exciting them.
Auroras are due to fluorescence from molecules excited by these charged particles. Different colors are from different atoms and molecules. O: 558, 630, 636 nm N2+: 391, 428 nm H: 486, 656 nm
Fluorescent lights
Use phosphors (transition metal compounds that exhibit phosporescence when exposed to UV light) Incandescent lights (normal light bulbs) lack the emission lines
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(Sunburn)
Skin surface
Were opaque in the UV and visible, but not necessarily in the IR.
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Flowers in the UV
Since bees see in the UV (they have a receptor peaking at 345 nm), flowers often have UV patterns that are invisible in the visible.
Arnica angustifolia Vahl
Visible
UV (false color)
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EUV Astronomy
The solar corona is very hot (30,000,000 degrees K) and so emits light in the EUV region.
EUV astronomy requires satellites because the earths atmosphere is highly absorbing at these wavelengths.
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Black hole
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The plasma cloud grazed the Earth, and its high energy particles created a massive geomagnetic storm.
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e-
e+
h = 511 kev
More massive particles create even more energetic gamma rays. Gamma rays are also created in nuclear decay, nuclear reactions and explosions, pulsars, black holes, and supernova explosions.
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In 10 seconds, they can emit more energy than our sun will in its entire lifetime. Fortunately, there dont seem to be any in our galaxy.
X-Ray
Visible
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Microwave
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