Iit Jee 2010 - Paper 1 Soln

MODEL SOLUTIONS TO IIT JEE 2010
Paper I - (Code 0)
PART I 1 D 9 B, D 2 A 10 B, C 14 B 19 3 20 2 21 0 Section I
1.
3 B
4 B 11 A, B 15 D 23 4 16 C
5 C
6 C 12 C, D 17 B 18 C
7 D
8 A 13 A, C
22 3
24 3
NaNH2
25 3
CH3
26 1
CH2 C
27 0
CNa CH2 CH2
28 5
BrCH2 CH2 CH2 CH3
CH3
HBr
CH3
CH2
C C CH2 3-octyne
CH3
8.
Ring (a) is pyranose with - glycosidic link.
OH + CH3 Br
Section II
2. 3. k varies exponentially with T. Standard enthalpy of formation of elements in their standard state is taken as zero. Ligand NO 2 and counter ion Cl are mutually exchanged EDTA is HOOC H2C
N CH2 CH2 N CH2 COOH
1
CH3
9.
CH3
CH3
CH3
4.
CH3 2, 2-dimethyl butane
10. Ca(OH)2 and Na2CO3 can be used for softening temporary hard water. 11. Molar conductivity and electromotive force are intensive properties. 12. HNO3 and CH3COONa HNO3 on mixing with excess CH3COONa also results in a mixture of CH3COOH and CH3COONa.
5.
CH2 COOH
HOOC H2C
6. 7. Bond energy of C C is 83Kcalmol CH3 CH2 C CH
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OH NaOH
23. The compounds soluble in aqueous NaOH are OH COOH
13.
,
O Br2 + O Br
OH
COOH and
Br
Br
etc.
Section III
14. Cu FeS2 is converted to Cu2S, FeS and SO2. Cu2S and FeS are further oxidized to Cu2O and FeO. 15. FeO forms FeSiO3 with SiO2 25. 16. Cu( ) is reduced to Cu(0) by S oxidized to SO2
2
N CH3 CH3
24. 25.2 and 25.0 has only one digit after decimal point.
235 U 92 1 n 0 142 Xe 54 90
38
Sr 4 n
1 0
which gets
Net number of neutrons emitted = 3

O
17. Ecell > 0 and G < 0 It is given that Ecell = 70 mV For a concentration cell E cell = 0 G =0 18. Ecell =
RT C n 2 nF C1
26.
(i) O3 (ii) Zn, H2O
O NaOH heat
E2 E1
log 0.05 log0.05
E2 = 70
2 = 140 mV
Section IV
19. It is Be3Al2Si6O18 27.
Since the dicarbonyl compound formed is symmetrical, if can form only one intramolecular aldol condensation product.
dc dt
a constant (5)
20.
NH2 and
COO groups are basic groups.

3 2
28.
CH3
CH3
21. BrF5 is sp d hybridised with a lone pair occupying one of the axial positions. Due to repulsion from this lone pair all the F Br F angles are less than 90 . 22. KCN, K2CO3 and LiCN are the salts of strong bases with weak acids.
CH2
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PART II 29 A 37 A, C, D 30 B 38 C, D 42 D 47 1 48 3 49 4 Section I
29. Non homogenous linear systems of equations, three can be only 3 options. (a) unique solution (b) no solution (c) infinity may solution Hence these cannot be a stem with exactly two distinct solutions
lim
31 B
32 C 39 B, C 43 C 51 2 44 D
33 D
34 D 40 A 45 B 46 A
35 C
36 A 41 B
50 6
52 3
x
2
53 9
p3
3 3
54 5
x+1=0
3
55 3
56 2
2q
q p3
(q + p )x
(p
2q)x + (q + p ) = 0 (1)
32. Ax + By + Cz = 0 2A + 3B + 4C = 0 8A B 10C = 0 2 8 30 + 4, 26, 1, 3 1
30. Limit = x
lim
0
ln 1 x
x ln 1 x x4 4 1 4 3x 2 0 0 1 12
4 10 32 + 20, 52, 2, 26 26 1
x
lim
0 0
3x x 4
3 1 x 5x 4
x 33.
x + 2y z = 0 2y + z = 0
31.
+ = p 3 3 + =( + ) 3 q= p +3 p 3 3p = q + p
3
( + )
SinA 2 SinC CosC SinC SinC 2SinA CosC + 2SinA CosA SinA
q p3 3p
2 2
2SinA CosC + 2 CosA SinC (2Sin(A + C)
p2
=
sum of the roots =
2 q p3 3p q p3 3p
3p q p3
2Sin 120 = 2
3 = 2
x2
34. f(x) = ex
e
2
2
3p3 p3
2 q p3 3p 2q
3
g(x) = xex
x2
x2
h(x) = x2e x f = 2xex = 2 xe x

2
q p
2xe 2x
ex
2
x2
Product of the roots = 1 Equation is
2xe2x
=
2
2x
2
ex2
2x ex
2
g' = xex
2xe
2x ex
2
2
x2
= e x 2x 2 1 h = x2ex
2
2
2x2 1 e2x
=
x2
2x
Arg (z Arg (z Arg (z2 Arg (z z
z1) angle made by AP with x axis z2) angle made by AP with x axis z1) angle made by AP with x axis z1) = Arg (z2 z1) z1 z z1
ex
z2
z1 z2
z1
2x ex 2xex
2
2x 2xe 2xe
x2
= 2x 3e x =
= z z1 = |z z1| arg (z z1) z2 z1 = |z2 z1| arg |z2 z1| z z1 z z1
e2 x 2 x 3 ex
x
2
2x
2x
=
2
z2 z2
2
z1 z2
z1 z z1 arg z z1 z2 z1 arg z2 z1 z1
=0
z z1 arg z z1 z1 arg z2
f' 0
0 or e2x 1 2 2x =
1 e 1 Max g(x) = e e 1 Max h(x) = e e a=b=c
Max f(x) = e
38. (t1 , 2t1) 2 (t2 , 2t2) 2 2 (x t1 ) (x t2 ) + (y 2t1) (y 2t2) = 0 y=0 2 2 (x t1 ) (x t2 ) + 4t1t2 = 0 2 2 2 2 2 x (t1 + t2 ) x + t1 t2 + 4t1t2 = 0 2 2 2 2 2 (t1 + t2 ) = 4(t1 t2 + 4t1t2) 2 2 2 (t1 t2 ) = 16t1t2 (1)
t12 2
2
t 22
, t1 t 2
35. 1, 2, 3 2, 3, 4 3, 4, 5 4, 5, 6
6 6 6 6
(t1 , 2t1) r =
2
t12
t12 2
t 22
t1 t 2
2
Similarly there are 24 other cases. 48 8 2 6 6 6 36 9 36. PQ = 6i + j; QR = i + 3j; RS = 6j j; SP = i 3j PQ || RS and QR || SP. Also mid point of PR & QS in the same. But |SP| |PQ| and SP . PQ 0 It is a parallelogram but neither a rhombus nor a rectangle
t12 t 22 4
2
t1 t 2
t 22 r 2 t1 t 2 2 (2) 4 2 2 4[r (t1 t2) ] = 16t1t2 2 2 2 r = (t1 t2) + 4t1t2 = (t1 + t2) t 1 + t2 = r 2 2 2 or t1 t 2 r r
x
t12
39. f(x) = log x +

0
1 sin x dx
Section II
37. B z2 P z A z1 Since z = ( 1 t) z1 + tz2 for 0 < t < 1, z lies on the line segment joining z1 and z2 |z z1| + |z z2| = PA + PB = AB = |z1 z2|
f ' (x)
f " (x)
1 x
1
2
1 sin x exist all x

cos x
(0, )
x 2 1 sin x does not exist for x = (2n+ 1)
Let
, ( > 1) we get
2
log
1 sin x dx
0
= log
x sin 2
x 2
x cos dx 2
2 sin x 2
2 0
T4 + T2 = T6 =
1 5
1 3
T4
1 5
log
2 cos
1 T2 3
4
log
f'
2 2
f' 2 f
2
=
2 15
sec 2
0
1d
2
(1, ) )
2 13 1 15 4 15 4 Hence, on substituting in (1)

1
since f(x) and f(x) > 0, f(x) > 0 x f(x) and f(x) are increasing in (1, |f(x)| < |f(x)| Choice (C)
0
2 2
12 35
2
52 15
2 2
2 3
22 7
41. c = a + b
2bc Cos C
3 ) ab
2
f'
c = (a
2
b) + (2
option D is not correct.

1
(2x + 1) = (x + 2) + (2 2 (x + x + 1) (2x + 1) (x + 2) = (2 2 (x + x + 1)
2 2
3 ) (x 3 ) (x 3 ) (x
2
1) 1)
2
40.
0
x4 1 x 1 x2
1
dx
4 2 2 2
3(x + 1) (x
1) = (2
3)
1) (x + x + 1)
=
0 1
x 1 x
2x
dx
6
x + x + 1 = 3 (2 + x +x
2
1 x
x 4 1 x2
(5 + 3 3 ) = 0
=
0
4x
1 x2 dx 2 3
4 x 5 dx
x=
1
1
= =
1
12 35
4
0
x6 1 x
2
21 12 3 2 2
3 2 3 2
2
= = (2 + But x = (2 +
12 35
x6
2
4
dx
2 3
(1)
3 ) and (1 +
3)
3 ) c = 2x + 1 is negative
I=
0
1 x
x=1+
3 is the only possible value
=
0
tan6 d
4
T6 (say )
Section III
Qns. 42, 43, 44
Tn =
0
tann d
4
Let us take p = 5 Tp =
=
0
tann
sec 2
4
1d
a b : a, b, c c a
0,1 2, 3, 4 ,
= Tn + Tn
tann 1 n 1
2
Tn
0
1 n 1
Total number of matrices A that can be formed 3 = 5 = 125 Matrices are of the form 0 b 1 b 2 b 3 b 4 b , , c 0 c 1 c 2 c 3 c 4 where b c = 0, 1, 2, 3, 4 42. |A| will be of the form 0 bc Oor (1 bc) or (4
1 T6 + T4 = 5
bc)
Or (9 bc) Or (16 bc) Symmetric or skew symmetric matrices where |A| is divisible by 5 (=p) 0 0 1 1 1 4 2 2 3 3 are , , 0 0 1 1 4 1 2 2 3 3
12 sec + 8 sec 15 = 0 2 12 sec + 18 sec 10 sec 15 = 0 (6 sec ) (2 sec + 3) 5(2 sec + 3) = 0 As |sec | 1, 3 sec = is the only solution 2
4 1 4 4 , 1 4 4 4
There are 9 numbers 43. |A| divisible by p, (=5) but, trace of A is not divisible by p (=5) Form 1 4 1
5 2 Equation of the common tangent is

tan =
x 3 x 2
2x
3 2
y 2 5y 4 1
5 2
5 y+4=0
2 2 3 3 4
4 4
4 4 Total number = 16 44. Total number of matrices = 125 s Consider all A whose determinants are divisible by p (=5) = 16 + number of matrices of the form 0
46. Let a common point of intersection be (3sec , 2tan ) This point lies on the circle 2 2 x + y = 8x = 0 2 2 9sec + 4tan 24sec = 0 2 13s 24s 4 = 0 where s stands for sec sec = 2 tan =
3
Points A and B are 6, 2 3 and 6, 2 3 Required circle is 2 2 (x 6) + y 12 = 0 2 2 x + y 12x + 24 = 0
0 = 16 + 9 = 25 Hence, the number of A in Tp such that det (A) not divisible by p (=5) is = 125 25 = 100 3 [For p = 5, (p 5p) also gives 100. However, when p = 3, the number of such matrices is verified as 18, which is obtained by setting p = 3
Section IV
z
2 2
47. C1
C1 + C2 + C3
z z z 1
1 z
=0
2 2
45. Any tangent to
x 9
y 4
z 1 z 1 1
1 z
=0
1 is of the form
R2 R2 R1, R3
2
R3
2 2
R1 we get =0
x sec y tan 1 (1) 3 2 (1) is a tangent to the circle (x 4 sec 1 3 4
4) + y = 16
1 z 0 (z 0 1
) 1 z
2
2 2
sec 2 9
tan2 4
2
i.e. z z
z z2
z
1
2
2
1
0
4 sec 9
(4 sec 2 16 sec 36 sec
2
36 4 sec
2
2
9 tan
2
2
16
z z2
2
2 2
1 2
3) = 4(4 sec + 9 tan ) 2 2 24 sec + 9 = 16 sec + 36 tan 2 2 = 16 sec + 36 (sec 1) + 24 sec 45 = 0
zz . 3 3 0 3 i.e. z = 0 number of z satisfying is 1
48. tan = tan =n + 6 =2 + =

n 6
2
5
=2
{ x } cos xdx
1
2
,n 0, 1 , 2
=2 (1) =2 = sin
x.
sin x
0 1
1
1
sin x
dx
12
cos x
4
0
Again, sin2 = cos4
2
n
4
4
4
50. Required equation of plane is x 1 y 2 z 3
2 = n + ( 1)
2
2 2
n = 2
=
2 3
3 4
4 5
n 2
1n
4
are
(2)
Common values of 5 , , = 12 4 12
i.e., x 2y + z = 0. This plane is parallel to the given plane Ax 2y + z = d A=1 distance between the plane is d 6 d 6 1 4 1
Number of solutions = 3 51. 2x + y = 1 is a tangent to
x2 a2
y2 b2
{ x} if [ x] is odd 49. Here f(x) = 1 {x} if [ x] is even

The graph of f(x) follows
i.e. 1 = 4a b (1) Since 2x + y = 1 intersects the directions a x= at x axis implies e a 1 = i.e. 2a = e (2) e 2
10
10
2 1
0 1 2
2 10
10
0 2
f ( x ) cos xdx
10
10
10
f ( x ) cos xdx
1
1=e b b =e 2 2 2 a (e 1) = (e 1) 2 a =1 a = 1 and e = 2
{ x} cos xdx
1 0
(1 { x} cos xdx
y = x, dy = dx { x} = 1 {x}
1 1
k 1 1 52. Sk = = k1 = 1 k 1! 1 r 1 k
a
100 k 1
k2
3k 1 = k 1!
100 k 1
1 k 3!
1 k 1!
(1 { x }) cos xdx
0 1 0
(1 { y } cos y dy
(1 { y } cos ydy
0
0
=
1
{ y } cos y dy
Note: 2 k 3k + 1 = A (k 1) (k 2) + B(k 1) + C k=1 C= 1 k=2 B=0 2 Equating coefficient of k A=1 Required summation 1 1 1 1 1 =0+1+1 2! 1 3! ! 97! 99! Answer =
.2
1
x cos xdx
1002 100!
1 98!
1 99!
1002 100!
99 100 100!
100 100!
= 4a + b = 5 55. 2 equation is xyz sin 3 = 2z cos3 + 2y sin 3 Substitute in the first equation (y +z) cos3 = 2zcos3 + 2ysin3 y(cos3 2sin3 ) = zcos3 (1) (y + 2z) cos3 + y sin3 = (y + z) cos3 zcos3 + ysin3 = 0 (2) From (1), (2)
y z cos 3 cos 3 2 sin 3 cos 3 sin 3
nd
1002 1002 =3+ =3 100!

53. Y y=
dy X x dx
X=0 Y=y y x x x
dy dx
dy 3 =x dx
dy dx dy dx y x C
y= x
1 y x x2
x2 1 dx x
cos3 = 0 , but cos3 0 (as per given system) cos3 2sin3 = sin3 cos3 = sin3 tan3 = 1 =C
x2 2
3 = 2n
2n = 3
2
6
3 =n +
n = 3
y = Cx
x3 2
y(1) = 1 1 1 C 2 3 C= 2
12 5 3 , , = 12 12 4
Total number of solutions = 3 56. y = =

9
2 2 sin 2 3.2 sin cos 2 5.2 cos2
x 2 9 27 y( 3) = 2 2
y= 54.
3x 2
18 2
1 cos 2
=
2 6 3 sin 2
3. sin 2
4 cos2
5 1 cos2
a b
a 2b
a 2a b b b.b a a.b a 2 b a
= a b = a a = b
Maximum of y =
2 6 5
a.b a 2 a.b b 2a
= 2a b since a b
2a b a b
= 2a
b
2
a 2b
PART III 57 B 65 A, C 58 C 66 A, D 70 C 75 6 76 6 77 4 Section I

57. As increases, XC =
1 decreases c increases.
d F T d T
59 A
60 D 67 A, B, C 71 B 79 9 72 D
61 C
62 A 68 A, B 73 A 74 B
63 D
64 C 69 A, C
78 5
80 3
62.
81 7
82 4
83 8
84 3
decreases 58.
3R
dr
4R
dV = =
G 2 rdr r'
G 2 4 R tan .4 R sec 2 d 4 R sec

sin cos
2
F = Bd = BRd Component of T, radial, will add upto d 2T sin T.d 2 (cosd components cancel) L BRd = Td T = BR = B 2 59. P1 + mg cos = mgsin P1 and f are in same direction. P and f are in opposite direction. (In case P1, f acts upward; In case of P2, f acts downward). 60. Ideal gas assumes no intermolecular interaction i.e., at low pressures and high temperatures of real gas. 61. Formula: R= . A Here = L, A = Lt R=
L Lt t
= G .2 .4 R
45
V=
37
G 2 .4 R
sin d cos2
45
GM 7 R2
.2 . 4 R
37
sin d cos2
Let cos = t sin d = dt Substituting

1
V=
GM .8 7R
2 4 5
1 2 4 5
dt t2
8 GM 1 . 7R t
8 GM . 7R
5 4
2 GM 4 2 7R
5 5
W=
2 GM 4 2 7R
63. Since R
1 R100
1 , R100 < R60 < R40 Power 1 1 . This inequality holds at R 60 R 40
any temperature (assuming same material) because 1 1 1 . R100 1 R60 1 R 40 1 64. Ammeter is a galvanometer with a low shunt resistance. Voltmeter is a galvanometer with a high resistance in series. Only option C meets the requirement.
i1 = 60 , n = 3 r1 = 30 r2 r1 = A = 15 (formula for incident ray as shown) r2 = 45 internally reflected at 45 1 (Since sin C = C < 45 ) 3 From geometry incident angle on AD is 30 emergent angle = 60 Angle between incident and emergent rays is the same as the angle between the two faces = 90 . 68. AB: Isothermal, BC: isobaric, CA: isochoric. 4 V0 A) correct, W AB = nRT0n = P0V0 n4, V0 B) correct: Note : C) and D) are correct only if BC passes through the origin 69. Least count 1 s T=
T T 1s = 0.025 40 s
Section II
65. Apply formulae for v1 and v2 for elastic collision. m m2 2 m2 u1 u2 and similarly for v2) (v1 = 1 m1 m2 m1 m2 v1 = 2 m s gives 1 u1 = +3 m s and using this u2 = 1 m s B is incorrect.
1 1
40 s =2s 20 cycles
1 kg 3 m s 6 kg vcm is unchanged.
vcm = K.E =
1 ms 2
2
T = 0.025 g= 4 2 2 T
T = 0.05 s g 2 T = 0.05 = 5% g T
Section III
70. E < V0 so that motion is periodic Clearly E > 0 ( At x = 0, V = 0 and K.E > 0) 71. [Use dimensional analysis] B is the only correct option. 72. For |x| > x0, V = V0 = constant dV 0 F= dx no acceleration. 73. Superconducting transition temperature when magnetic field is increased. falls
1 6 2
1 2
3 J 4
C is incorrect. 1 1 32 = 4.5 J Total K.E = 2 D is incorrect. 66. Direction of lines of force show Q1 +ve and Q2 ve density of lines around Q1 > that around Q2 |Q1| > |Q2| Null point can only be on the right side of Q2. 67.
15 B 60 30 45 45 45 30 75 A 60 D C
74.
Field 0
TC 100 K
7.5 T
75 K
As field varies from zero to 7.5 T, TC variation is from 100 K to 75 K, which clearly shows for a field of 5 T, TC must be in between 75 K and 100 K.
Section IV
75. Let angular velocity be . Let distances from CM be dB and dA. Then the required ratio is
v p = 3 km s esc
81. Let the speed of a car be v Frequency received by a car f =
mA d2 A
2 mBdB
c v f0 c
2 mBdB
But mAdA = mBdB ( CM definition) d dB dA mB 1 1=6 Ratio = A dB dB mA

1 1 1 u v f 1 1 1 25 v 20 1 1 1 50 v ' 20 m 25 =6 m 50 AY k where k = m
76. Using (i) (ii)
v = 100
m25 = 4 m50 =
2 3
This is the frequency reflected by the car frequency received by observer c c v . .f0 = c v c v 1 Since v <<c, c f 2 v f0 c Substituting values v 7
v'
100 3
82.
E 1 E 1
Series 77. =
R
7 9
AY m
140
4.9 10 n 10 1 0.1
i1 R = J 1
n=4 78. y2 = 3 sin 2x 6t = 3 cos (2x Y = y1 + y2 6t) amplitude A =

32 42 = 5
2E R 2
J1
r 1 = 2 2
2
Parallel
T 79. From Wiens law: 1 T2
1500 =3 500
2 4
R
J1 J2
E 1 2
R = J2
Energy radiated from surface = 4 r . T Ratio of energy emitted =

r1 r2
2
T1 T2
2.25
4 R 22
1 3
1 2
R=4
.3 4
9
83. 420 =
m 1000 0 5 2100 1 3.36 105 1000
80. g =
GM R
2
gp ge
p e
Rp Re
84.
m=8
Rp Re
vesc =
6 3 . 11 2
2 gR vp esc ve esc gpRp geRe
p2 2m
qV;
2
p pp
[4 2] = 8
p pp
p
m q . mp qp
= =
6 6 3 . . 11 11 2
2 2
9 121
3 11

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MODEL SOLUTIONS TO IIT JEE 2010

BrCH2 CH2 CH2 CH3

Ring (a) is pyranose with - glycosidic link.

CH3 2, 2-dimethyl butane

23. The compounds soluble in aqueous NaOH are OH COOH

Net number of neutrons emitted = 3

(i) O3 (ii) Zn, H2O

log 0.05 log0.05

COO groups are basic groups.

32. Ax + By + Cz = 0 2A + 3B + 4C = 0 8A B 10C = 0 2 8 30 + 4, 26, 1, 3 1

2SinA CosC + 2 CosA SinC (2Sin(A + C)

sum of the roots =

h(x) = x2e x f = 2xex = 2 xe x

Product of the roots = 1 Equation is

Arg (z Arg (z Arg (z2 Arg (z z

= z z1 = |z z1| arg (z z1) z2 z1 = |z2 z1| arg |z2 z1| z z1 z z1

1 e 1 Max g(x) = e e 1 Max h(x) = e e a=b=c

39. f(x) = log x +

1 sin x exist all x

x 2 1 sin x does not exist for x = (2n+ 1)

2 13 1 15 4 15 4 Hence, on substituting in (1)

option D is not correct.

3 is the only possible value

5 2 Equation of the common tangent is

Points A and B are 6, 2 3 and 6, 2 3 Required circle is 2 2 (x 6) + y 12 = 0 2 2 x + y 12x + 24 = 0

45. Any tangent to

x sec y tan 1 (1) 3 2 (1) is a tangent to the circle (x 4 sec 1 3 4

3) = 4(4 sec + 9 tan ) 2 2 24 sec + 9 = 16 sec + 36 tan 2 2 = 16 sec + 36 (sec 1) + 24 sec 45 = 0

zz . 3 3 0 3 i.e. z = 0 number of z satisfying is 1

48. tan = tan =n + 6 =2 + =

Again, sin2 = cos4

Number of solutions = 3 51. 2x + y = 1 is a tangent to

{ x} if [ x] is odd 49. Here f(x) = 1 {x} if [ x] is even

1002 1002 =3+ =3 100!

Total number of solutions = 3 56. y = =

PART III 57 B 65 A, C 58 C 66 A, D 70 C 75 6 76 6 77 4 Section I

G 2 4 R tan .4 R sec 2 d 4 R sec

Let cos = t sin d = dt Substituting

1 , R100 < R60 < R40 Power 1 1 . This inequality holds at R 60 R 40

81. Let the speed of a car be v Frequency received by a car f =

But mAdA = mBdB ( CM definition) d dB dA mB 1 1=6 Ratio = A dB dB mA

76. Using (i) (ii)

n=4 78. y2 = 3 sin 2x 6t = 3 cos (2x Y = y1 + y2 6t) amplitude A =

T 79. From Wiens law: 1 T2

Energy radiated from surface = 4 r . T Ratio of energy emitted =

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