LEMBAR JAWABAN Ujian Tengah Semester Genap 2010-2011 Mata Kuliah Teknologi Informasi Hari/tanggal : Selasa, 1 Mei 2012

Waktu : 08.00 09.30 wib Pengampu : Nor Basid Adiwibawa Prasetya, S.Si., M.Sc. Peserta Ujian/NIM : Laksmi Dewi P / J2C009037 Email : laksmi037@gmail.com Jawaban: 1. a. Judul Artikel: Photocatalytic self-cleaning properties of cellulosic fibers modified by nano-sized zinc oxide

b. Abstrak: Nano-sized zinc oxide was synthesized and deposited onto cellulosic fibers using the solgel process at ambient temperature. The prepared materials were characterized using several techniques including scanning electron microscopy, transmission electron microscopy, diffuse reflectance spectroscopy, X-ray diffraction and thermogravimetric analysis. X-ray diffraction studies of the ZnO-coated fiber indicate formation of the hexagonal crystal phase which was satisfactory crystallized on the fiber surface. The electron micrographs show formation of zinc oxide nanoparticles within 1015 nm in size which have been homogeneously dispersed on the fiber surface. The prepared materials show significant photocatalytic selfcleaning activity, which was monitored by diffuse reflectance

spectroscopy. The photoactivity was studied upon measuring the photodegradation of methylene blue and eosin yellowish under UVVis irradiation. The photocatalytic activity of the treated fabrics was fully maintained performing several cycles of photodegradation. Keywords: Cellulosic fiber; Coating; Photocatalysis; Selfcleaning; Nano-sized zinc oxide

2. Judul Artikel: Novel 3-alkanoyl/aroyl/heteroaroyl-2H-chromene2-thiones: synthesis and evaluation of their antioxidant activities. Singh OM, Devi NS, Thokchom DS, Sharma GJ. a. Nama jurnal: Europen Journal Medical Chemistry
b. Volume: 45 c. Issue: 6 d. Tanggal terbit: 2010 June e. Halaman: 22502257 f. Abstrak: A facile, convenient and high

yielding synthesis of a combinatorial library of3alkanoyl/aroyl/heteroaroyl-2H-chromene-2-thiones has been developed by the condensation of easily accessible oxodithioesters and salicylaldehyde/substituted 2hydroxybenzaldehydes under solvent-free conditions. The assessment of radical scavenging capacity of the compounds towards the stable free radical2,2-diphenyl-1-picrylhydrazyl

(DPPH) was measured and these compounds were found to scavenge DPPH free radical efficiently. Five selected compounds were able to protect curcumin from the attack of sulfur free radical generated by radiolysis of glutathione (GSH). The newly synthesized compounds exhibited profoundantioxidantactivities. Five of them rendered comparatively high antioxidant capacity. 3. a. Nama Jurnal: Carbohidrate research Scope: which includes all aspects of carbohydrate chemistry and biochemistry. Articles published in the journal cover sugars and their derivatives (also cyclitols, and model compounds for carbohydrate reactions), oligo- and polysaccharides, nucleosides, nucleotides, and glycoconjugates. These systems are considered from the viewpoints of:

chemical synthesis; the study of structures and stereochemistry; reactions and their mechanisms; isolation of natural products; physicochemical studies; macromolecular dynamics;

analytical chemistry; biochemistry (biosynthesis, metabolism, degradation, structural and functional biochemistry, enzyme mechanisms, glycosidases and glycosyl transferases, etc.);

action of enzymes; immunochemistry; technological aspects;

glycomics; glycoinformatics; glycobiology

The journal includes normal length research papers, mini reviews, notes, rapid communications and book reviews together with notices of meetings concerned with carbohydrates. b. Nama Jurnal: chemical reviews Scope: Chemical Reviews is one of the most highly regarded and highest-ranked journals covering the general topic of chemistry. The mission of Chemical Reviews is to provide comprehensive, authoritative, critical, and readable reviews of important recent research in organic, inorganic, physical, analytical, theoretical, and biological chemistry. In addition to the general reviews, the journal has published since 1985 periodic thematic issues focusing on a single theme or direction of emerging research c. Nama Jurnal: Green Chemistry Scope: based on, but not limited to, the definition proposed by Anastas and Warner (Green Chemistry: Theory and Practice, P. T. Anastas and J. C. Warner, Oxford University Press, Oxford, 1998): Green chemistry is the utilisation of a set of principles that reduces or eliminates the use or generation of hazardous substances in the design, manufacture and application of chemical products. d. Nama Jurnal: Journal of Herbs, Spices and Medicinal Plants

Scope: The Journal of Herbs, Spices & Medicinal Plants is an essential reference filled with recent research and other valuable information associated with herbs, spices, and medicinal plants. The Journal serves as a focus point through which investigators and others may publish material of importance to the production, marketing, and utilization of these plants and associated extracts. The journal covers the following topics: growth, development, horticulture, ecology, physiology, genetic, chemistry, and economics. Original articles, review articles, and book reviews provide information of interest to an international audience of researchers, teachers, technicians, and managers involved with production and/or marketing of herbs, spices, and medicinal plants. Managers of food companies, food processing facilities, medical research laboratories, government agencies, and others interested in new chemicals, food additives, international trade, patents, and other items can easily review new findings. The Journal of Herbs, Spices & Medicinal Plants is a forum in which recent research and other information associated with herbs, spices, and medicinal plants is shared. TheJournal represents a centralized database accessible by investigators within the international community that work with or have an interest in

herbs, spices, and medicinal plants. e. Nama Jurnal: Journal of Organic Chemistry Scope: The Journal of Organic Chemistry (JOC) welcomes original contributions of fundamental research in all branches of the theory and practice of organic chemistry. The Journal of Organic Chemistry now publishes JOC Featured Articles-full papers selected by Editor-in-Chief C. Dale Poulter and the JOC Associate Editors for special consideration as exceptional contributions to the journal as identified during the review process. Upon acceptance, the galley proofs of these selected manuscripts are prepared and sent to the author on an expedited schedule to facilitate more rapid online and print publication. JOC Featured Articles are listed online as Article ASAPs on the JOC home page as soon as the corrected galley proof is returned. f. Nama Jurnal: Current Medicinal Chemistry Scope: Current Medicinal Chemistry covers all the latest and outstanding developments in medicinal chemistry and rational drug design. Each issue contains a series of timely in-depth reviews written by leaders in the field covering a range of the current topics in medicinal chemistry. Current Medicinal Chemistry is an essential journal for every medicinal chemist who wishes to be kept informed and up-to-date with the latest and most important developments g. Nama Jurnal: Tetrahedron Letter Scope: Tetrahedron Letters provides maximum dissemination of outstanding developments in organic chemistry. The journal is

published weekly and covers developments in techniques, structures, methods and conclusions in experimental and theoretical organic chemistry. Rapid publication of timely and significant research results enables researchers from all over the world to transmit quickly their new contributions to large, international audiences h. Nama Jurnal: Chemical Communication Scope: Chemical Communications publishes preliminary accounts of original and significant research that will appeal to a wide general readership or be of exceptional interest to the specialist. Following publication of a communication a full paper should be prepared and submitted to an appropriate journal. Acceptance in Chemical Communications does not guarantee subsequent publication in the RSC's journals. Short articles that are detailed enough should be submitted as a complete account to the appropriate RSC journal i. Nama Jurnal: Journal of Organometallic Chemistry

Scope: the journal has been enlarged to encompass important research on organometallic complexes in bioorganometallic chemistry andmaterial sciences, and of heavier main group elements in organometallic chemistry. j. Nama Jurnal: Electroanalysis Scope: Electroanalysis is an international, peer-reviewed journal covering all branches of electroanalytical chemistry, including both fundamental and application papers as well as reviews dealing with analytical voltammetry, potentiometry, new electrochemical sensors and detection schemes and practical applications.

Serving as a vital communication link between the research labs and the field, Electroanalysis helps you to quickly adapt the latest innovations into practical clinical, environmental and industrial applications. Electroanalysis provides the most comprehensive coverage of the field and is the number one source for information on electroanalytical chemistry 4. a. CAS Registry number: 67-66-3 Nama senyawa: Kloroform Rumus molekul senyawa: CHCl4 b. Gambar Spektra: Spektra MS MS-NW-0078 SDBS NO. 894 chloroform CHCL3 (Mass of molecular ion: 118)

Source Temperature: 210 C Sample Temperature: 25 C Spektra CNMR

ppm Int. Assign. 77.22 1000 1

Spektra HNMR

Assign. A

Shift(ppm) 7.256

Spektra IR

Spektra RAMAN

Spektra ESR N