National Textile University Faisalabad

Assignment 01 Spring 2012

(Due date: 07-05-2012) Course Code: Class: Total Marks: 10
RM-572 MS Textile Engineering,

Course Title: Analytical Techniques Semester:

2nd

You are being provided with forty set of problems. Each problem consists of different spectra (IR, 1H-NMR, 13C-NMR, Mass etc). Give assignments to every peak in the spectra and finally deduce the actual structure of the said compound and submit the assignment within the due date positively.

Problem 1

C 5 H 10 O

Problem-2,

C7 H 14 O

Problem 3:

C 4 H 10 O

Problem 4: C6 H 14 O

Problem 6: C4 H 8O 2

Problem 7: C 5 H 10 O 2

Problem 8: C 5 H10 O

Problem 9:

C8H8O

Problem 10: C 9 H 10O 2

Problem 11: C3 H 6 O 2

Problem 12 : C 11 H 14 O 2

Problem 13: C8 H 8 O 2

Problem 14: C7H9N

Problem 15: C5H13N

Problem 16: C8H14O

Problem 17: C4H9Br

Problem 18: C 10 H 14 O,

Problem 19 : C 13 H 10 O 3

Problem 20: C8H14,

Problem 21: C9H13N,

Problem 22

C3H5BrO2, MW = 152

Problem 23, C8H14O4,

MW = 174

Problem 23 - 1H NMR spectrum (CDCl3, 500 MHz)

Problem 24 - 13C NMR spectrum (CDCl3, 125 MHz)

Problem 25, C9H12, MW = 120 Problem 25 - 1H NMR spectrum (CDCl3, 500 MHz)

Problem 26 - IR spectrum

Problem 26 - 13C NMR spectrum (CDCl 3 , 125 MHz

Problem 27 C 7 H 13 Br, MW = 176

Problem 27 - IR spectrum

Problem 27 - 1H NMR spectrum (CDCl 3 , 500 MHz)

Problem 27 - 13C NMR spectrum (CDCl 3 , 125 MHz)

Problem 28, C 5 H 8 O, MW = 84

Problem 28 - IR spectrum

Problem 28 - 1H NMR spectrum (CDCl 3 , 500 MHz)

Problem 28 - 13C NMR spectrum (CDCl 3 , 125 MHz)

Problem 29 C 9 H 13 NO MW = 151

Problem 29 - IR spectrum

Problem 29 - 1H NMR spectrum (CDCl 3 , 500 MHz)

Problem 29 - 13C NMR spectrum (CDCl 3 , 125 MHz)

Problem 30 MW = 82

C 6 H 10
Problem 30 - IR spectrum

Problem 30 - 1H NMR spectrum (CDCl 3 , 500 MHz)

Problem 30 - 13C NMR spectrum (CDCl 3 , 125 MHz)

Problem 31 MW = 137

C 8 H 11 NO
Problem 31 - IR spectrum

Problem 31 - 1H NMR spectrum (CDCl 3 , 500 MHz)

Problem 31 - 13C NMR spectrum (CDCl 3 , 125 MHz)

Problem 31 - positive EI Mass Spectrum

Problem 32

C 10 BrH 7
MW = 206

Problem 32 - IR spectrum

Problem 32 - 1H NMR spectrum (CDCl 3 , 500 MHz)

Problem 32 - 13C NMR spectrum (CDCl 3 , 125 MHz)

Problem 32 - positive EI Mass Spectrum

Problem 33 MW = 265

C 14 H 19 NO 4
Problem 33 - IR spectrum

Problem 33 - 1H NMR spectrum (CDCl 3 , 500 MHz)

Problem 33 - 13C NMR spectrum (CDCl 3 , 125 MHz)

Problem 33 - positive EI Mass Spectrum

Problem 34 MW = 116

C 6 H 12 O 2
Problem 34 - IR spectrum

Problem 1 - 1H NMR spectrum (CDCl 3 , 500 MHz)

Problem 34 - 13C NMR spectrum (CDCl 3 , 125 MHz)

Problem 34 - positive EI Mass Spectrum

Problem 35 MW = 167

C 7 H 5 NO 4
Problem 35 - IR spectrum

Problem 35 - 1H NMR spectrum (DMSO-d 6 , 500 MHz)

Problem 35 - 13C NMR spectrum (DMSO-d 6 , 125 MHz)

Problem 35 - positive EI Mass Spectrum

Problem 36

C 5 H 10 O 4
MW = 134

Problem 36 - IR spectrum

Problem 36 - 1H NMR spectrum (DMSO-d 6 , 500 MHz)

Problem 36 - 13C NMR spectrum (DMSO-d 6 , 125 MHz)

Problem 36 - positive EI Mass Spectrum

Problem 37

C8H6O2
MW = 134

Problem 37 - IR spectrum

Problem 37 - 1H NMR spectrum (CDCl 3 , 500 MHz)

Problem 37 - 13C NMR spectrum (CDCl 3 , 125 MHz)

Problem 37 - positive EI Mass Spectrum

Problem 38 MW = 214

C 13 H 10 O 3
Problem 38 - IR spectrum

Problem 38 - 1H NMR spectrum (CDCl 3 , 500 MHz)

Problem 38 - 13C NMR spectrum (CDCl 3 , 125 MHz)

Problem 38 - positive EI Mass Spectrum

Problem 39

C7H6O2
MW = 122

Problem 39 - IR spectrum

Problem 39 - 1H NMR spectrum (CDCl 3 , 500 MHz)

Problem 39 - 13C NMR spectrum (CDCl 3 , 125 MHz)

Problem 39 - positive EI Mass Spectrum

Problem 40 MW = 166

C 9 H 10 O 3
Problem 40 - IR spectrum

Problem 40 - 1H NMR spectrum (CDCl 3 , 500 MHz)

Problem 40 - 13C NMR spectrum (CDCl 3 , 125 MHz)

Problem 40 - positive EI Mass Spectrum