Synoptic List of Precautions, Usage, and Health Effects of Selected Pesticides

7/26/2007 For the LRC Katlego Matsila

Information provided by product labels unless otherwise indicated

List ordered alphabetically

List ordered alphabetically

1. Aqua-Rights by Ag-Chem Africa a. Label Requirements i. Precautions: 1. Avoid prolonged contact with concentrated product. 2. In the case of contact, wash affected area with soap and water. 3. In case of contact with eyes flush immediately with water for at least 10 minutes. 4. Rinse empty container three times with a volume of water equal to at least 10% that of the container and add the rinsings to the contents of the spray tank before disposing of the container in the prescribed manner. 5. Destroy empty container by perforation and flattening and never use for any other purpose. 6. Prevent contamination of food, feeds, drinking water and eating utensils. ii. Handling and Personal Protection: 1. Ventilation system: a. In general, dilution ventilation is a satisfactory health hazard control for this substance. However, if conditions of use create discomfort to the worker, a local exhaust system should be considered. 2. Skin Protection: a. Wear suitable personal protective equipment including approved respiratory protection. 3. Hand Protection: a. Wear appropriate hand gloves where necessary. 4. Eye Protection: a. Use chemical safety goggles and/or full face shield where splashing is possible. Maintain eye wash fountain and quick-drench facilities in work area. b. Hazards and other Effects on the Health i. Direct Health Effects 1. Causes eye burns and irritation. 2. Harmful if swallowed or inhaled. 3. Causes irritation to skin and respiratory tract. ii. Potential Health Effects 1. Inhalation: a. Causes irritation to the mucous membranes of the respiratory tract. May be absorbed from the mucous membranes and depending on the amount of exposure could result in the development of nausea, vomiting and diarrhoea. 2. Ingestion: 2 List ordered alphabetically

3.

4. 5. 6.

a. Symptoms parallel absorption via inhalation. Aspiration into lungs may occur during swallowing or vomiting, resulting in lung damage. Skin Contact: a. Causes skin irritation. Not significantly absorbed through the intact skin. Readily absorbed through damaged or burned skin. Eye Contact: a. Causes irritation, redness and pain. Chronic Exposure: a. No information found. Aggravation of Pre-existing Conditions: a. No information found.

2. Boziman by Ag-Chem Africa a. Label Requirements i. Handling and Personal Protection: 1. Ventilation system: a. In general, dilution ventilation is a satisfactory health hazard control for this substance. However, if conditions of use create discomfort to the worker, a local exhaust system should be considered. 2. Skin Protection: a. Wear suitable personal protective equipment including approved respiratory protection. 3. Hand Protection: a. Wear appropriate hand gloves where necessary. 4. Eye Protection: a. Use chemical safety goggles and/or full face shield where splashing is possible. Maintain eye wash fountain and quick-drench facilities in work area. b. Hazards and other Effects on the Health i. Direct Health Effects: 1. Harmful if swallowed or inhaled. 2. Causes irritation to skin and respiratory tract. ii. Potential Health Effects: 1. Inhalation: a. Causes irritation to the mucous membranes of the respiratory tract. May be absorbed from the mucous membranes and depending on the amount of exposure could result in the development of nausea, vomiting, diarrhoea and gastric distress. 2. Ingestion: a. Symptoms parallel absorption via inhalation. 3. Skin Contact: 3 List ordered alphabetically

a. Causes skin irritation. Not significantly absorbed through the intact skin. Readily absorbed through damaged or burned skin. Symptoms of skin absorption parallel inhalation and ingestion. 4. Eye Contact: a. Causes irritation, redness and pain. 5. Chronic Exposure: a. Prolonged absorption causes weight loss, vomiting, diarrhoea, skin rash, convulsions and anaemia. Liver and particularly the kidneys may be susceptible. May cause respiratory tract irritation, coughing and chest discomfort. 6. Aggravation of Pre-existing Conditions: a. Persons with pre-existing skin disorders or eye problems, or impaired liver, kidney or respiratory function may be more susceptible to the substance. 3. Citrex by BASF a. Label Requirements i. No Relevant Precautions found. b. Hazards and other Effects on the Health i. Direct and Potential Health Effects: 1. May cause skin and eye irritation. 2. Sign and Symptoms of Poisoning: a. No cases of human acute intoxication have been reported (irritation). 3. Skin Contact: a. Moderately irritant to the, skin. Prolonged and repeated exposure may cause chronic dermatitis. Wash contaminated area with soap and water. If irritation persists, seek medical attention. 4. Eye Contact: a. Mildly irritant to the eye. Flush the eye with water. If irritation persists seek medical attention. 5. Ingestion: a. Accidental ingestion is an unlikely event. Special measures are not indicated. Do not induce vomiting. Give 1/4 litre of water to drink. Refer for medical attention. 6. Inhalation: a. Inhalation of concentrated oil mist may cause irritation of upper respirators tract. Remove affected person to fresh air. If rapid recovery does not occur refer for medical attention. 4 List ordered alphabetically

7. Emergency Antidote: a. There is no specific antidote. ii. Precautions: 1. Wash contaminated clothing daily. 2. Avoid contact with the eyes and/or skin, do not inhale the spray mist. 3. Wash with soap and water after use or accidental skin contact. 4. Copsul 3 (Details below pretty much apply to Copsul as made by Universal Crop Protection, Plaaskem, and Villa Crop through check with individual makers if further details needed). a. Label Requirements i. Label:

ii. Handling: 1. Handle with care. Toxic when swallowed. May irritate skin and eyes. Store away from food and feedstuffs in a cool, dry place. Keep out of reach of children, animals and uninformed persons. Toxic to fish and wildlife. 2. Handling in the Course of Employment and Protective Equipment: a. Clothing: i. Employee must wear appropriate protective (impervious) clothing, boots, hat and equipment to prevent repeated or prolonged skin contact with this substance. Do not wear leather clothing. b. Gloves: i. Employee must wear appropriate chemical resistant protective gloves to prevent contact with this substance. c. Eye protection: i. The use of safety goggles is recommended. d. Emergency eye wash: i. Where there is any possibility that an employees eyes may be exposed to this substance, the employer should provide an eye wash fountain or appropriate alternative within the immediate work area for emergency use. iii. Usage: 5 List ordered alphabetically

1. Aerial application: a. Notify all inhabitants of the immediate area to be sprayed and issue the necessary warnings. Do not spray over or allow drift to contaminate water and adjacent areas. 2. Precautions when Using: a. Do not inhale dust or spray mist. Wear protective clothing, mask and rubber gloves while handling and applying the product. Wash with soap and water after use. Prevent drift onto other crops, grazing, rivers, dams or areas not under treatment. Clean applicator after use and dispose of wash water where it will not contaminate food, grazing, rivers or dams. Destroy empty container after emptying it thoroughly over the mixing tank. Do not use empty container for any other purposes. Prevent contamination of food, feed, drinking water and eating utensils and do not eat, drink or smoke whilst applying or mixing or before washing hands and face or changing clothing. b. Hazards and other Effects on the Health i. Toxicological Information 1. Acute skin and eye irritation: a. Skin and eye irritating. 2. Dermal sensitization: a. No information currently available 3. Carcinogenicity: a. Animal studies did not detect any carcinogenic activity. 4. No human data available. a. Teratogenicity: 5. Animal studies did not detect any teratogenic effects. No a. human data available. 6. Mutagenicity: a. Not mutagenic 5. Demildex 3 by Delta Chemicals a. Label Requirements i. Aerial application: 1. Notify all inhabitants of the immediate area to be sprayed and issue the necessary warnings. Do not spray over or allow drift to contaminate water and adjacent areas. ii. Precautions in Usage: 1. Do not inhale dust or spray mist. Wear protective clothing, mask and rubber gloves while handling and applying the 6 List ordered alphabetically

product. Wash with soap and water after use. Prevent drift onto other crops, grazing, rivers, dams or areas not under treatment. Clean applicator after use and dispose of wash water where it will not contaminate food, grazing, rivers or dams b. Hazards and other Effects on the Health i. Direct and Potential Health Effects: 1. Inhalation: Dust will cause irritation and coughing. 2. Ingestion: The ingestion of a large quantity of Copper Oxychloride is followed by nausea and vomiting. A metallic taste and a burning sensation in the oesophagus and stomach. LD50 value = 1 667mg/Kg. 3. Skin and eye contact: Powder is irritating to skin. 4. Dust is irritating to eyes. 5. Chronic Toxicity: Frequent persistent contact with the skin can cause skin irritation. 6. Carcinogenicity: Not Applicable. 7. Mutagenicity: Not Applicable. 8. Reproductive hazards: Unknown. 9. The ingestion of a large quantity is followed by nausea and vomiting. A metallic taste and a burning sensation in the oesophagus and stomach. 10. Flammability: Non-flammable. 11. Chemical Hazard: None, if powder is kept dry. Wet powder is corrosive to most metals. 12. Biological Hazard: None. 13. Reproduction Hazard: None. ii. Precautions and Directions for Accidental Exposure: 1. Personal Precautions: Avoid breathing dust, wear dust mask if necessary. 2. Avoid contact with eyes wear goggles if necessary. 3. Avoid contact with skin; wear rubber gloves and long sleeved shirt and trousers. 4. Environmental Precautions: Do not allow to enter drains, sewers or watercourses. 5. Small Spills: Sweep spills up, place in clean container and remove to chemical waste site. 6. Large Spills: Sweep spills up, place in clean container and remove to chemical waste site. 6. Dicarzol 1b by Bayer CropScience a. Label Requirements i. Label:

7 List ordered alphabetically

b. Precautions: i. Handle with extreme care. ii. Poisonous when swallowed, inhaled or through skin contact. iii. Toxic to fish, bees and wildlife. Do not apply when bees are actively visiting treated areas. iv. Store under lock and key in a cool, dry place, away from food and feed. v. Keep out of reach of children, uninformed persons and animals. vi. Do not expose product to humidity. Because of the hygroscopicity of the product, the container should be tightly sealed if any product is left after use. vii. In case of poisoning - CALL A DOCTOR AND MAKE THIS LABEL AVAILABLE TO HIM. c. General Usage: i. Do not inhale fumes or spray mist. ii. Wear protective clothing (overall, boots, rubber gloves, respirator, face shield) when handling or applying the product. iii. Wash contaminated clothing daily. iv. Wash immediately with soap and cold water after use or accidental skin contact. v. In case of eye contact, flush immediately with plenty of water for at least 15 minutes. vi. Do not eat, drink or smoke whilst mixing or applying or before washing hands and face and changing clothes. vii. Prevent contamination of food, eating utensils, feed and drinking water. viii. Clean applicators thoroughly before re-using with other material and do not pollute the environment with wash water. ix. When empty, rinse the container three times with a volume of water equal to at least one tenth of that of the container and add the rinsings to the contents of the spray tank. Destroy the container by puncturing and burying or burning it. Do not use the container for any other purpose. d. Re-entry, Aerial Application, and Drift: 8 List ordered alphabetically

i. Re-entry Do not enter treated area within 2 days after treatment unless wearing protective clothing. ii. Aerial application - notify all inhabitants of the immediate area to be sprayed and issue the necessary warnings. Do not spray over or allow drift to contaminate adjacent areas or water. iii. Prevent spray drift onto other crops, grazing, rivers, dams or other areas not under treatment. e. Hazards and other Effects on the Health i. Symptoms of Poisoning with High Toxicity Carbamate Compounds. 1. Headache, fatigue, faintness, giddiness, excessive sweating, nausea, abdominal pain, vomiting, blurred vision, muscle twitching, usually small pupils, respiratory distress, coma. ii. Symptoms of Poisoning with High Toxicity Carbamate Compounds (from an independent source). 1. High Toxicity Carbamate Pesticides: a. Malaise, muscle weakness, dizziness, and sweating. b. Headache, salivation, nausea, vomiting, abdominal pain, and diarrhoea. c. Miosis with blurred vision, incoordination, muscle twitching and slurred speech. d. In more severe cases: Central nervous system depression (coma, seizures and hypotonicity), hypertension and cardiorespiratory depression. Also dyspnea, bronchospasms and bronchorrhea with eventual pulmonary edema. 7. Dichlorvaros by Universal Crop Protection a. Label Requirements i. Label:

ii. General Usage and Precautions: 1. Do not inhale spray mist or fumes. 2. Wear protective clothing, suitable mask, rubber gloves and boots. Wash contaminated clothing daily. 3. Wash with soap and water after use. 4. Prevent contamination of food, feed, drinking water and eating utensils and do not eat, drink or smoke while applying, mixing or before washing hands and face and changing clothing. iii. Drift, Re-entry, and Aerial Application 9 List ordered alphabetically

1. Drift: Prevent drift onto other crops, grazing, rivers, dams or areas not under treatment. 2. Re-entry: Keep treated buildings closed for about 12 hours and ventilate well before re-entry. 3. Aerial Application: Notify all inhabitants of the area to be sprayed and issue the necessary warnings. Do not spray over or allow drift to contaminate adjacent areas or water. b. Hazards and other Effects on the Health i. Direct and Potential Health Effects: 1. Toxicity class: a. WHO Ib, EPA I: Dichlorvos is a compound which inhibits cholinesterase enzyme activity in the nervous tissue. It is of very high toxicity. Contact with skin, inhalation of dust or spray, or swallowing may be fatal. Slightly toxic to fish and birds and toxic to bees. 2. Likely routes of exposure: a. May be absorbed from the gastrointestinal tract, through the intact skin, and through inhalation of fine spray mist or dust. 3. Eye contact: a. Highly toxic. Mildly irritating to eyes. 4. Skin contact: a. Highly toxic, due to possible absorption. Mildly irritating to skin. 5. Ingestion: a. Highly toxic by ingestion. See point 4 for symptoms. 6. Inhalation: a. Highly toxic by inhalation, depends on volatility of compound. See point 4 for symptoms. ii. Symptoms of Poisoning: 1. Nausea, headache, tiredness, giddiness, blurred vision and papillary constriction, vomiting, abdominal pain, diarrhoea, sweating and salivation. Confusion, ataxia, slurred speech, loss of reflexes are some of the central nervous system effects which may lead to misdiagnosis of acute alcoholism. 2. After inhalation of vapours effects appear within minutes: ocular and respiratory effects. These include marked miosis, ocular pain, conjuctival congestion, diminish vision, ciliary apasm and brow ache. With acute systemic absorption: rhinorrhea, hyperemia of upper respiratory tract, tightness in the chest and wheezing respiration. iii. Symptoms of Severe Intoxication: 1. Salivation, involuntary defecation and urination, sweating, lacrimation, penile erection, bradycardia and hypotension. 10 List ordered alphabetically

iv. Other noted Symptoms: 1. Overexposure effects: a. After inhalation of vapours or aerosols effects appear within minutes: ocular and respiratory effects generally appear first. This include marked miosis, ocular pain, conjunctival congestion, diminished vision, ciliary spasm and brow ache. 2. With acute systemic absorption: a. Miosis may not be evident due to sympathetic discharge in response to the hypotension. In addition to rhinorrhea and hyperemia of the upper respiratory tract, respiratory effects consist of tightness in the chest and wheezing respiration, caused by the combination of bronchoconstriction and increased bronchial secretion. 3. Gastrointestinal symptoms occur earliest after ingestion, and include anorexia, nausea and vomiting, abdominal cramps, and diarrhoea. 4. With percutaneous absorption of liquid, localised sweating and muscular fasciculation in the immediate vicinity are generally the earliest manifestations. 8. Dithane by Dow AgroSciences a. Label Requirements i. Label:

ii. Usage and Precautions: 1. Precautions: a. Avoid contact with the skin, eyes and clothes, as well as inhalation of dust and spray mist. b. Wear face mask and rubber gloves when mixing product. c. Wash thoroughly with soap and water after application and in case of eye contamination, rinse the eyes thoroughly with plenty of cold water and obtain medical aid if necessary. d. Wash contaminated clothing. e. Prevent contamination of food, feeds, drinking water and eating utensils. f. Clean application equipment after use and dispose of wash water where it will not contaminate crops, pastures, rivers, dams or other water sources. 2. Drift, Aerial Treatment, and Re-entry: 11 List ordered alphabetically

a. Do not spray over water or allow spray drift onto water or adjacent areas not under treatment. b. Re-entry: Do not enter treated field/orchard until spray deposit has dried unless wearing protective clothing. c. Aerial Application: Notify all inhabitants of the immediate area to be sprayed and issue the necessary warnings. Do not spray over or allow drift to contaminate water or adjacent areas. b. Hazards and other Effects on the Health i. Direct and Potential Health Effects 1. May cause sensitization of the skin and irritation of eyes and air passages. ii. Direct and Potential Health Effects (Independent Source) 1. Symptoms of Poisoning a. Irritation of skin, eyes and respiratory tract. b. Skin sensitization. c. Chronic skin disease has been observed in occupationally exposed workers. 2. Other Reactions to Exposure: a. Inhalation: Cough. Sore throat. b. Skin: Redness. c. Eyes: Redness, Pain. d. Ingestion Diarrhoea: Nausea, Vomiting. 9. Dursban 480 EC by Dow AgroSciences a. Label Requirements: i. Label

ii. Usage and Precautions: 1. Wear protective clothing whilst mixing and applying protective gloves and face shield. Wash with soap and water after use or accidental skin contact. 2. Avoid contamination of food, feedstuffs, drinking water and eating utensils. iii. Mist Drift, Aerial Application, and Re-entry: 1. Avoid inhalation of spray mist. 2. Re-entry period: Do not enter treated fields/orchards within 1 day after application unless wearing protective clothing. 12 List ordered alphabetically

3. Aerial Application: Notify all inhabitants of the immediate area to be sprayed and issue the necessary warnings. Do not spray over or allow drift to contaminate water or adjacent areas. b. Hazards and other Effects on the Health i. Symptoms of Human Poisoning: 1. Headaches, fatigue, faintness, giddiness, excessive sweating, nausea, abdominal pains, vomiting, diarrhoea, tightness of chest, anxiety, blurred vision, muscle twitching beginning in eyelids and tongue, usually small pupils, respiratory distress, convulsions, coma. ii. Notice to Physician: 1. This material contains both a cholinesterase inhibitor and a solvent. Atropine, only by injection, is the preferable antidote. Oximes, such as 2-PAM/protopam, may be therapeutic if used early; however, use only in conjunction with atropine. If lavage is performed, suggest endotracheal and/or oesophageal control. Danger from lung aspiration must be weighed against toxicity when considering emptying the stomach. Supportive care. Treatment based on judgement of physician in response to symptoms of patient. 10. Folpan Label Not Found 11. Flint by Bayer CropScience a. Label Requirements i. Label

ii. Usage and Precautions 1. Wear an overall, rubber gloves and boots, face mask and shield when preparing spray mixture and overall and rubber boots when spraying. 2. Do not inhale product dust or spray mist. 3. Avoid contact of skin, eyes and clothing with product or spray mist. 4. Wash hands and entire body with soap and water after use. 5. Wash contaminated clothing after use. iii. Drift and Re-entry: 1. Avoid drift of spray onto other crops, grazing, rivers, dams, boreholes and areas not under treatment. 2. Re-entry: Do not enter treated area until spray deposit has dried unless wearing protective clothing b. Hazards and other Effects on the Health 13 List ordered alphabetically

i. Direct and Potential Effect on Health: 1. May cause sensitization by skin contact. 2. Poisonous if swallowed, inhaled or absorbed through the skin. 3. Very toxic to fish and other aquatic organisms. 4. Slight skin irritation on rabbit. No skin sensitization on guinea pigs. 5. Irritant to the mucus membrane of the rabbit. 12. Glucomag by AG Chem Africa a. Label Requirements i. Relevant Data Not Fount b. Hazards and other Effects on the Health i. Direct Health Effects: 1. Causes eye burns and mild irritation. 2. Mildly harmful if swallowed. 3. Causes mild irritation to skin. ii. Potential Health Effects 1. Inhalation: Not harmful if inhaled. 2. Ingestion: Mildly harmful if swallowed. 3. Skin Contact: Causes mild skin irritation. Not significantly absorbed through the intact skin. 4. Eye Contact: Causes mild irritation to eyes. 5. Chronic Exposure: No information found. 6. Aggravation of Pre-existing Conditions: No information found. 13. Legend 250 SC by Dow AgroSciences a. Label Requirements i. Label:

ii. Usage and Precautions: 1. Avoid contact with eyes, skin and inhalation of fumes and spray mist. 2. Wear protective clothes and face shield when preparing the spray mixture and during spraying. 3. In case of direct contact with skin, wash with soap and water. 4. In case of direct eye contact, rinse for several minutes with clean water. 5. Wash contaminated clothing daily. 6. Prevent contamination of food, feed, drinking water and eating utensils. iii. Drift and Re-entry:

14 List ordered alphabetically

1. Re-entry: Do not enter treated area until spray deposit has dried unless wearing protective clothing. 2. Avoid drift of spraymist onto other crops, grazing, rivers, dams and other areas not under treatment. b. Hazards and other Effects on the Health i. Direct and Potential Health Effects: 1. Harmful if swallowed. 2. May cause skin sensitivity. 3. Very poisonous for aquatic organisms and algae. ii. Direct and Potential Health Effects(Independent Source): 1. Inhalation: Cough, Nausea. Vomiting. Laboured breathing. Shortness of breath. Weakness. 2. Skin: May be absorbed! Redness. Pain Skin burns. (Further see Inhalation). 3. Eyes: Redness. Pain. Blurred vision. 4. Ingestion: Cough. Nausea. Vomiting. Laboured breathing. Shortness of breath. Weakness. 14. Melody Duo 69 WG by Bayer CropScience a. Label Requirements i. Label:

ii. Precautions and Usage: 1. Do not inhale dust or spraymist. 2. Wash contaminated clothing daily. 3. Wash with soap and water after use. 4. Do not eat, drink or smoke during application before washing hands and face. 5. Prevent contamination of food, feed, drinking water and eating utensils. iii. Re-entry, Aerial Treatment, and Drift: 1. Prevent spray drift towards and contamination of water supplies, rivers, dams and other crops not being treated. 2. Aerial Application: Notify all inhabitants of the immediate area to be sprayed and issue the necessary warnings. Do not spray over or allow drift to contaminate adjacent areas or water. Please refer to the SANS Code of Practice for the aerial application of agricultural chemicals. 3. Re-entry: Do not enter treated area until spray deposit has dried unless wearing protective clothing. b. Hazards and other Effects on the Health i. Direct and Potential Effects on Health 15 List ordered alphabetically

1. No particular hazards known. 15. Milraz 4 a. Label Requirements b. Hazards and other Effects on the Health 16. Prospur 500 EC by Bayer CropScience a. Label Requirements i. Label:

ii. Precautions and General Usage: 1. Do not inhale fumes or spraymist. 2. Wear rubber gloves and boots and a face shield when preparing spray mixture and rubber gloves and face shield when spraying. 3. Wash contaminated clothing daily. 4. Wash with soap and water after use. 5. Prevent contamination of food, feed, drinking water and eating utensils. iii. Aerial, Re-entry, and Drift: 1. Re-entry: Do not enter treated area within 1 day after treatment unless wearing protective clothing. 2. Aerial Application: Notify all inhabitants of the immediate area to be sprayed and issue the necessary warnings. Do not spray over or allow drift to contaminate adjacent areas or water. 3. Avoid drift of spraymist to other crops, grazing, rivers, dams and areas that will not be treated. b. Hazards and other Effects on the Health i. Direct and Potential Health Effects: 1. Poisonous when swallowed. Toxic to fish and wild life. 2. Prosper 500 EC is irritating to the eyes, skin and mucous membranes. 3. Harmful by inhalation, in contact with skin and if swallowed. Irritating to skin. Risk of serious damage to eyes. Very toxic to aquatic organisms, may cause long-term adverse effect in the aquatic environment 4. Health Effects on Skin: Irritant 5. Health Effects on Ingestion: Harmful if Swallowed 6. Effects on Eyes: Damaging 17. Round-up by Monsanto Europe S.A. a. Label Requirements i. Precautions and General Usage:

16 List ordered alphabetically

1. Engineering controls - Have eye wash facilities immediately available at locations where eye contact can occur. 2. Eye protection - Wear chemical goggles. 3. Skin protection - If repeated or prolonged contact: Wear chemical resistant gloves. 4. Respiratory protection - No special requirement when used as recommended 5. When recommended, consult manufacturer of personal protective equipment for the appropriate type of equipment for a given application. b. Hazards and other Effects on the Health i. Potential Heath Effects: 1. Likely routes of exposure - Skin contact, eye contact 2. Eye contact, short term - Risk of serious damage to eyes. 3. Skin contact, short term - Not expected to produce significant adverse effects when recommended use instructions are followed. 4. Inhalation, short term - Not expected to produce significant adverse effects when recommended use instructions are followed. ii. Experience with Human Exposure: 1. Ingestion, excessive, intentional misuse: a. Respiratory effects: pneumonitis (aspiration) b. Gastro-intestinal effects: nausea/vomiting, diarrhea, abdominal pain, bloody vomiting (haematemesis) c. Cardiovascular effects: abnormal heart rhythm (cardiac dysrhythmia), decreased heart output (myocardial depression) 2. General/systemic effects: disturbances of fluid and electrolyte regulation, abnormally decreased blood volume (hypovolaemia), elevated serum amylase, fluid loss (haemoconcentration), no cholinesterase inhibition. 3. Laboratory effects - blood chemistry: elevated serum transaminases, mild acidosis. iii. Eye contact, short term, epidemiological: 1. Note: No cases of irreversible eye effects could be attributed to glyphosate formulations in an extensive epidemiological survey of reported accidental eye contact with these formulations. iv. Direct and Potential Health Effects of Active Ingredient Isopropylamine (Independent Source) 1. Irritation of skin, eyes and respiratory tract. 2. Inhalation may cause burning sensation in nasopharynx and chest, coughing, and/or dizziness. 3. Headache, vomiting, diarrhea. 17 List ordered alphabetically

4. Confusion, bizarre or aggressive behavior. 5. Kidney failure, increased heart rate. 6. Metabolic acidosis resulting in peculiar odor on breath. 18. Rubigan by Klub M5 CC a. Label Requirements b. Hazards and other Effects on the Health 19. Roval Aqua 4 a. Label Requirements i. Precautions and General Usage 1. No not inhale spray mist. 2. Wear rubber gloves, rubber boots and face shield when preparing mixture, and rubber gloves when applying. 3. Wash contaminated clothing after use. 4. Wash any contamination off skin and eyes immediately. 5. Prevent contamination of food, feeds, drinking water and eating utensils. ii. Drift 1. Avoid spray drift onto other crops, grazing, rivers, dams and areas not intended for treatment. 2. b. Hazards and other Effects on the Health i. Direct and Potential Health Effects: 1. Poisonous when swallowed or inhaled. 2. May cause severe irritation with corneal injury, resulting in permanent vision impairment or blindness. 3. May cause skin irritation with short single exposures and severe skin irritation with prolonged or repeated exposure. 4. Excess inhalation may cause irritation to upper respiratory tract (nose and throat) and lungs. 20. Storby WG by BASF a. Label Requirements i. Label:

ii. Precautions and General Usage: 1. Avoid prolonged contact with skin and protect eyes. 2. Do not inhale spray mist or dust. 3. Wash with soap and water after handling of product. 4. Do not eat, drink or smoke whilst mixing and applying or before washing hands and face. 5. Destroy empty containers and never use for any other purpose.

18 List ordered alphabetically

6. Prevent contamination of food, feed, drinking water and eating utensils. iii. Drift 1. Prevent spray drift onto other crops, grazing, rivers and dams. b. Hazards and other Effects on the Health i. Direct and Potential Health Effects: 1. Limited evidence of a carcinogenic effect. 2. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 21. Teldor by Bayer CropScience a. Label Requirements i. Label

ii. Precautions and General Usage 1. Do not inhale fumes or spraymist. 2. Wash contaminated clothing daily. 3. Wash with soap and water after use. 4. Clean applicator after use, dispose of wash water where it will not contaminate crops, grazing, rivers and dams. 5. Prevent contamination of food, feeds, drinking water and eating utensils. iii. Re-entry, Drift 1. Re-entry: Do not enter treated area until spray deposit has dried unless wearing protective clothing. 2. Avoid drift of spray on to other crops, grazing, rivers, dams and areas not under treatment. b. Hazards and other Effects on the Health i. Direct and Potential Health Effects: 1. Harmful when swallowed. 22. Thioflo SC by Bayer CropScience a. Label Requirements i. Label

19 List ordered alphabetically

ii. Precautions and General Usage 1. Do not inhale fumes or spray mist. 2. Wear protective clothing (overall, boots, rubber gloves, respirator and face shield) when handling or applying the product. Wash contaminated clothing daily. 3. Wash with soap and cold water immediately after accidental skin contact. 4. Do not eat, drink or smoke whilst mixing or applying or before washing hands and face and changing clothes. 5. Prevent contamination of food, eating utensils, feed and drinking water. 6. Clean applicator/aircraft thoroughly after use and do not pollute the environment with wash water. 7. Do not calibrate aircraft or clear hopper over grazing, crops not under treatment or water sources. iii. Protective Measures and Equipment: 1. Do not inhale aerosols 2. Hygiene measures a. Do not eat, drink or smoke during work time. b. Remove soiled clothing immediately. c. Clean hands and face at work intervals and after work. 3. Hand protection: Chemical resistant gloves 4. Eye protection: Safety glasses 5. Skin protection: Protective clothing iv. Re-entry, Aerial Application, and Drift 1. Re-entry - Avoid skin contact with treated crops in glasshouses or tunnels for a minimum of 24 hours following application by wearing protective rubber gloves, long-sleeved shirts, long trousers and rubber boots. Do not enter treated area within two days after treatment unless wearing protective clothing. In case of poisoning - CALL A DOCTOR AND MAKE THIS LABEL AVAILABLE TO HIM. 2. Aerial application - notify all inhabitants of the immediate area to be sprayed and issue the necessary warnings. 3. Do not spray over or allow drift to contaminate adjacent areas or water. Prevent spray drift onto other crops, grazing, rivers, dams or other areas not under treatment. b. Hazards and other Effects on the Health i. Direct Health Effects 1. Poisonous when swallowed, inhaled or by skin contact. 2. Symptoms: a. Symptoms of Poisoning: i. Headaches, vertigo, nausea, possibly coupled with diarrhoea, anaesthesia of the tongue, 20 List ordered alphabetically

cerebral and cervical tremor and tremor of the extremeties, tonic and clonic cramps, perhaps with unconsciousness. b. Information to the Physician: i. Administer phenobarbital (e.g., "Luminal") to control convulsions. Loss of water and salt should be corrected by the infusion of IN physiological saline solution. The use of adrenaline and foods or purgatives containing fat or oil should be avoided. Pay special attention to respiratory failure and cardio-vascular collapse. 23. Thiovit Jet by Syngenta a. Label Requirements i. Label:

ii. Precautions and General Usage: 1. Do not inhale dust or spray mist. 2. Wear rubber gloves and face mask when handling granules. 3. Wash with soap and water after use. 4. Wash contaminated clothing after use. 5. Do not eat, drink or smoke while mixing or applying the product or before washing hands and face. 6. Prevent contamination of food, feed, drinking water and eating 7. utensils. iii. Re-entry and Drift: 1. Re-entry: Do not enter treated areas until spray deposit has dried unless wearing protective clothing. 2. Avoid drift of spray onto other crops, grazing, rivers, dams, boreholes and areas not under treatment. b. Hazards and other Effects on the Health i. Direct and Potential Health Effects (Independent Source): 1. Symptoms by Route of Exposure: a. Inhalation: Burning sensation. Cough. Sore throat. b. Skin: Redness. c. Eyes: Redness. Pain. Blurred vision. d. Ingestion: Burning sensation. Diarrhoea. 24. Tracer 480 SC by DowAgroSciences a. Label Requirements 21 List ordered alphabetically

i. Label:

ii. Precautions and General Usage: 1. Avoid inhalation of spray mist. 2. Wash with soap and water after use or accidental skin contact. 3. Wear gloves and face shield when handling. 4. Avoid contamination of skin and eyes. In case of accidental contact with eyes, wash with running water for at least 15 minutes. Get medical attention if irritation persists. 5. Do not eat, drink or smoke whilst mixing or applying. 6. Wash hands and face before eating, drinking, smoking or using the toilet 7. Prevent contamination of food, feedstuffs, drinking water and eating utensils by handling, storage or diposal. iii. Re-entry and Drift: 1. Avoid spray drift onto adjacent crops, grazing, rivers and dams. 2. Re-entry interval: Do not enter treated area until spray deposit has dried unless wearing protective clothing. b. Hazards and other Effects on the Health i. Potential Health Effects: 1. May cause slight eye irritation

22 List ordered alphabetically