VERY IMPORTANT

A. The question paper consists of 1 section (Section-1 contains CHEMISTRY ). Please fill the OMR
answer Sheet accordingly and carefully.
B. Each Section contains (19 questions in Part-A, 1 question in Part-B) and Total number of pages
are 00.
C. Please ensure that the Question Paper you have received contains ALL THE QUESTIONS in
each Section and PAGES. If you found some mistake like missing questions or pages then
contact immediately to the Invigilator.
INSTRUCTIONS
PART-A
1. Q.1 to Q.19 are single correct type questions. Each question has four choices (A), (B), (C) and (D)
out of which ONLY ONE is correct.
For each question, you will be awarded 3 marks, if you have darkened only the bubble corresponding
to the correct answer and zero mark if no bubble are darkened. In all other cases, minus one (1)
mark will be awarded.
PART-B
2. Q.1 is Matrix Match type question. Each question has four statements (A, B, C,D) given in Column-
I and Four statements (P, Q, R, S) given in Column-II. Any given statement in Column-I can have
correct matching with one or more statement(s) given in Column-II. For example, if for a given question,
statement B matches with the statement given in Q and R, then for the particular question, against
statement B darken the bubbles corresponding to Q and R in the OMR. For each row, you will be
awarded 3 marks in which you have darkened the bubble(s) corresponding to the correct answer.
Thus Q.1 carries a maximum of 12 marks.
3. Indicate the correct answer for each question by filling appropriate bubble in your answer sheet.
4. Use of Calculator, Log Table, Slide Rule and Mobile is not allowed.
5. The answers of the questions must be marked by shading the circle against the question by dark HB pencil only.
USEFUL DATA
Atomic weights: Al = 27, Mg = 24, Cu = 63.5, Mn = 55, Cl = 35.5, O = 16, H = 1, P = 31, Ag = 108, N = 14, Li = 7,
I = 127, Cr = 52, K=39, S = 32, Na = 23, C = 12, Br = 80, Fe = 56, Ca = 40, Zn = 65.5, Ti = 48, Ba = 137, U = 238,
Co= 59, B =11, F = 19, He = 4, Ne = 20, Ar = 40 , Mo = 96
CHEMISTRY
CODE
A
UNIT TEST-1
Class: XI Date: 20-05-2012 Time: 60 Minutes Max. Marks: 69
CHEMISTRY
XI (P, PH, SMS-Batch) UT-1 Page # 2
PART-A
[SINGLE CORRECT CHOICE TYPE]
Q.1 to Q.19 has four choices (A), (B), (C), (D) out of which ONLY ONE is correct.
Q.1 Which element has the following ground state electronic configuration ?
(A*)
34
Se (B)
33
As (C)
16
S (D)
32
Ge
[sol. At no. 34 element is Se.]
Q.2 What is the potential energy of an electron present in 4
th
shell of the Be
3+
ion ? (Given At. no. of Be = 4)
(A) 3.4 eV (B) 6.8 eV (C) 13.6 eV (D*) 27.2 eV
Q.3 Z/e ratio for Na
+
, Mg
2+
and Al
3+
respectively will be -
(where Z/e = number of protons/number of electrons)
(A*) 1.1, 1.2 and 1.3 (B) 1, 1 and 1
(C) 11, 12 and 13 (D) None of these
[Sol. Na
+
, Mg
2+
Al
3+
(no. of Proton) Z/e ratio 11/10 12/10 13/10 ]
Q.4 A monoatomic anion of unit charge contain 45 neutrons and 36 electrons. What is atomic mass number
of element and what is the value of n + l for its highest energy electron
(A*) Atomic mass No. 80, n + l = 5 (B) Atomic mass No. 81, , n + l = 5
(C) Atomic mass No. 82, n + l = 4 (D) Atomic mass No. 81, n + l = 6
Q.5 According to Bohr's atomic theory, which of the following is correct :
(A) Potential energy of electron
2
2
n
Z

(B) The product of velocity of electron and principle quantum number (n)

Z
2
.
(C*) Frequency of revolution of electron in an orbit
3
2
n
Z
.
(D) Coulombic force of attraction on the electron
2
2
n
Z

Q.6 If the ionization energy of He

+
is 19.6 10
18
J per atom then the energy of the Be
3+
ion in the first
stationary state is : (Given : At. no. of Be = 4)
(A*) 78.4 10
18
J/atom (B) 44.1 10
18
J/atom
(C) +78.4 10
18
J/atom (D) +44.1 10
18
J/atom
Q.7 Find the value of wave number ( ) v in terms of Rydber'g constant, when transition of electron takes
place between two levels of He
+
ion whose sum is 4 and difference is 2 :
(A)
9
R 8
(B*)
9
R 32
(C)
4
R 3
(D) None of these
CHEMISTRY
XI (P, PH, SMS-Batch) UT-1 Page # 3
Q.8 Which of the following is a set of isoelectronic species (atom or ions having same number of electrons)?
(A) N
3
, Cl

, Ar (B) N
3
, O
2
, F (C*) Sc
+3
, Ti
+4
, Ar (D) F

, Cl

, Br

[Sol. Isoelectronic = same number of electron

21
Sc
+3
= 213 = 18 electron
22
Ti
+4
= 22 4 = 18 electron
18
Ar = 18 electron ]
Q.9 A o-particle is fired towards the gold nucleus with the initial kinetic energy 3.2 MeV. Calculate the
distance (in meter) of closest approach. Given Atomic number of gold is 79 :
(A) 5.22 10
14
(B*) 7.11 10
14
(C) 3.55 10
14
(D) 9.53 10
14
Q.10 A dye absorbs a photon of wavelength and re-emits the same energy into two photons of wavelengths

1
and
2
respectively. The wavelength is related with
1
and
2
as :
(A)
2 1
2 1

+
=
(B*)
2 1
2 1
+

=
(C)
2 1
2
2
2
1
+

=
(D)
( )
2
2 1
2 1
+

=
Q.11 Wavelength of an electromagnetic radiation having energy 20 eV/photon. In what region, this radiation
falls :
(A) Visible (B) Infra red (C*) Ultraviolet (D) X-ray
[sol.

=
hc
E
20 1.6 10
19
=

8 34
10 3 10 626 . 6
= 62.11 nm
Q.12 The angular momentum of an electron in a Bohr's orbit of He
+
is 3.16 10
34
kg-m
2
/sec. What is the
wave number in terms of Rydberg constant (R) of the spectral line emitted when an electron falls from
this level to the first excited state. [Use h = 6.62 10
34
J.s]
(A) 3R (B)
36
R 5
(C*)
9
R 5
(C)
9
R 8
[Sol.
t
=
2
R n
L
n
so,
14 . 3 2
10 626 . 6 n
10 16 . 3
34
34

shell no. n = 3
2 n
3 n
=
+
=
(

2
2
2
1
2
n
1
n
1
z R
1
(

=
2 2
2
3
1
2
1
2 R
1
v

9
R 5
v =

Q.13 Find out the maximum number of electrons with +

2
1
spin in Na atom.
(A*) 6 (B) 5 (C) 4 (D) 11
CHEMISTRY
XI (P, PH, SMS-Batch) UT-1 Page # 4
Q.14 The total number of electrons in Mg atom which have magnetic quantum number equal to zero value :
(A) 2 (B) 4 (C) 6 (D*) 8
[Sol. Mg = 1s
2
2s
2
2p
5
3s
2
s
2
s
2
px pz py s
2
Value of l. 0 0 0 0
Total e

having l = 0 are 8
Q.15 If radiation corresponding to first line of "Balmer series" of Li
2+
ion, remove electron from first excited
state of H-atom, then kinetic energy of ejected electron would be :
(A) 2.55 eV (B) 4.25 eV (C) 6.81 eV (D*) 13.61 eV
[Sol. Energy of radiation = E
3
E
2
13.6 3
2
(13.6 2
2
)
Bonding energy of e in first orbit of H atom
K.E. energy of radiation bonding energy of e

in H atom
Q.16 Which of the following may represent the possible quantum numbers for the last electron of Ga.
(Atomic number of Ga = 31)
(A) 3, 1, +1, +
2
1
(B) 4, 0, +1, +
2
1
(C*) 4, 1, 0,
2
1
(D) 4, 1, 2, +
2
1
[Sol. 1s
2
2s
2
2p
6
3s
2
3p
6
4s
2
3d
10
4p
1
n = 4
l = 1
m = 0, 1
s =
2
1

Q.17 An element has mass number 23 and its unipositive ion(+1) has electronic configuration 1s
2
2s
2
2p
6
.
Select the incorrect statement(s).
(A) It is isotonic with Mg
24
.
(B) It contain 12 neutrons
(C*) Atom of the above element is isoelectronic with H
2
O.
(D) Period number of the elements is 3
rd
.
[Sol. Element is Na
Number of neutrons = 12
Number of protons & electrons = 11,11
(A) Mg
24
also have 12 neutrons (B) Na is a s-block elements.
(C) H
2
O has 10 electrons (D) The period number of Na is 3. ]
Q.18 Choose the incorrect option regarding energy of empty orbitals.
n l m s n l m s
(I) 4 0 0
2
1
+
(II) 3 2 0
2
1

(III) 3 1 1
2
1
+
(IV) 3 0 0
2
1

(A) I > IV (B) II > I (C) II > III (D*) I = III

[Sol. Energy is decided only by shell no. in empty subshell
CHEMISTRY
XI (P, PH, SMS-Batch) UT-1 Page # 5
Q.19 If S
1
is the magnitude of specific charge (q/m) of cathode ray and S
2
is that of positive ray then which
is true:
(A) S
1
= S
2
(B) S
1
< S
2
(C*) S
1
> S
2
(D) Either of these
PART-B
[MATRIX TYPE]
Q.1 has three/four statements (A,B,C OR A, B, C, D ) given in Column-I and four / five statements
(P, Q, R, S OR P, Q, R, S, T) given in Column-II. Any given statement in Column-I can have correct matching
with one or more statement(s) given in Column-II.
Q.1 If in Bohr's model for unielectronic species following symbols are used
r
n, z
Radius of nth orbit with atomic number Z;
U
n, z
Potential energy of e

; K
n, z
Kinetic energy of e

;
V
n, z
Velocity of e

; T
n, z
Time period of revolution
Column - I Column - II
(A) U
1,2
: K
1,1
(P) 1 : 8
(B) r
2,1
: r
1,2
(Q) 8 : 1
(C) V
1,3
: V
3,1
(R) 9 : 1
(D) T
1,2
: T
2,2
(S) 8 : 1
[Ans. (A) Q, (B) S, (C) R, (D) P]