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IBC Code first Published in 1983 Second edition 1986 Third edition l.990 Fourth edition (included Index of Dangerous Chemicals Carried in Bulk) 1994
Chemicals Caniedin Bulk Indexof Dangerous in firstpublished 1985 edition 1987 Second Third edition 1990 Fourthedition (includedwith IBC Code) 1994 combinededition 1998 Second by the IZATION MARITIME ORCAN INTERNATIONAL London SE17SR 4 AlbertEmbankmen! London MaritimeOrganization, Printedby the International 2 4 6 8 1 0 9 7 s 3 1 tsBN92-801-1456-5
AII rights reserved. No part of this publication may, for sales purposes, be produced, stored in a retrieval sYstemor transmitted in any form or by any means, clectronic, electrostatic, magnetic tape, mechanical, photocopying or otherwise, without prior permission in writing from the I nternational Maritime Ors,anization.
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Foreword
'17 On June 1983 the Maritime Safety Committee (MSC) adopted, by a l r e s o l u t i o nM S C . 4 ( 4 S )t.h e I n t e r n a t i o n aC o d e f o r t h e C o n s t r u c t i o n n d i C o E q u i p m e n t f S h i p sC a r r y i n gD a n g e r o u s h e m i c a l s n B u l k ( l B C C o d e ) . Conventionfor the of Under the provisions chapterVll of the International Safetyof Life at Sea, 1974 (SOLAS74), as amended in 1983, chemical on tankersconstructed or after 1 July 1986 must comply with the provisions of the Code. the IBC Code was On 5 December 1985, by resolution MEPC.'|9(22), to Protection Committee(MEPC) cover extendedby the MarineEnvironment o m a r i n e p o l l u t i o n a s p e c t sf o r t h e i m p l e m e n t a t i o n f A n n e x l l o f t h e 'l of International Conventionfor the Prevention Pollutionfrom Ships, 973, as modified by the Protocol o{ 1978 relating thereto (MARPOL 73178). .l Under the provisionsof regulation 3 of Annex ll of MARPOL 73/78, on chemicaltankersconstructed or after 1 July 1986 must comply with the provisions the Code. of as The MSC then formallyadoptedthe sameamendments thoseadoptedby M u t h e M E P Cb y r e s o l u t i o n S C . 1 0 ( 5 4 ) , n d e ra r t i c l eV l l l ( b ) o f S O L A S7 4 , s o of identical the purposes both MARPOLT3ITB for that the IBCCode remains and SOLAS74for appropriateprocedures established The two Committeessubsequently an a m e n d i n gt h e I B C C o d e ( M E P C . 2 5 1 2 0 , n e x Z ) t o e n s u r et h a t t h e C o d e of remainsidenticalat all times under the mandatoryrequirements the two Conventions. Under MARPOL 73/78 chemicaltankersconstructedbefore 1 July 1986 must comply with the provisionsof the Code for the Constructionand i C E q u i p m e n o f S h i p sC a r r y i n gD a n g e r o u s h e m i c a l s n B u l k ( B C H C o d e ) . t The BCH Under SOLAS74 the BCH Code remainsas a recommendation. publication. Code is issuedas a separate Carriedin Bulk - a supplementto the IBC The /ndex of DangerousChemicals referredto in the BCH and BCH Codes,containedan index of all chemicals and IBC Codes which provided the various names known for a particular chemical.This index has now been updated and incorporatedinto the p r e s e n t p u b l i c a t i o n . r e v i o u s l ya n n e x e sl l a n d l l l o f M A R P O L 7 3 / 7 8 P , containedlistsof productswhich were reproducedin chapters17 and 18 o V e of the IBCCodeas well as chapters l and Vll of pre-1993 ditions f the Vl BCH Code. However,since1993,the listsof productsin chapters and Vll to of the BCH Code have been replacedby references the IBC Code. In 'l l i o a d d i t i o nt,h e l i s t s f p r o d u c t s n a p p e n d i c e ls a n d l l l o f a n n e xl l t o t h e 9 9 7 consolidated edition of MARPOL 73/78 have also been replaced by references the IBC Code. As a result,the IBC Code is now the definitive to
ill
IBC Code
ll sourceof namesfor productssubjectto appendices and lll of Annex ll of M A R P O L7 3 1 7 8 . Circs,issuedannuallyin December; is Reference also made to the MEPC.2f of products that have been the subject of these contain inter alia,details , TripartiteAgreementsand are, in effect, a supplementto the IBC Code. includesproductsthat are expectedto become Annex 1 of these circulars shownin the to new or amendedentries the IBC Code.A futureamendment, which will only apply prior noticeof the carriage conditions as serves circular, enter into force. to that product when the next set of amendments to to closelyrelated the IBCCode are annexed A numberof otherdocuments this publication. they would The MSC and MEPCagreedthat, at their spring 1990 sessions, of system to amendments the BCH Code to introducethe harmonized adopt Under the provisionsof these proposed amendsurvey and certification. ments, they will enter into force when the 1988 SOLAS Protocol,which provisions, entersinto force, at which time section containscorresponding .l will be replaced. of model form of the Certificate Fitness .5 and the
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Contents
Page
International Code for the Construction and Equipment of Ships Carrying Dangerous Chemicals in Bulk
keamble C}IAPTER - GENENAI 1 1.1 1.2 1.4 1.5
Application
r . 3 Definitions
3 4 5 B 9
AND TOCATION CAPABITITY 2 C}IAPTER - SHIP SURVIVAT OF CARGOTANKS 2.1 2.2 2.3 2.4 2.5 2.6 2.7 2.8 2.9 Ceneral and Freeboard intactstability. deck. . belowthe freeboard discharges Shipside of Conditions loading assumptions Damage of Location cargotanks.. Flooding assumptions of Standard damage requirements Survival 13 14 14 15 15 "t6 't7 1B 19
3 CHAPTER - SHIPARRANGEMENTS l.l 3.2 3.3 3.4 1.5 . Cargosegregation. spaces and machinery Accommodation, service and controlstations. Cargopumprooms. in Access spaces the cargoarea. . to . arrangements. . . Bilge and ballast
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IBC'Code 3.6 3.7 identification Pumpand pipeline '. arrangements. . . and unloading Bow or sternloading 23 23
4 CHAPTER - CARGOCONTAINMENT 4.1 4.2 Definitions products for Tanktype requirements individual 25 25
5 CHAPTER - CARGOTRANSFER 5.1 5.2 5.3 5.4 5.5 5.6 5.7 .. scantlings Piping and fabrication joiningdetails Piping connections Flange . for Testrequirements PiPing arrangements Piping systems. Cargo-transfercontrol cargohoses. Ship's 26 28 2B 29 29 30 30
OF 6. CHAPTER MATERIALS CONSTRUCTION 6.1 6.2 Ceneral for requirements materials Special 32 32
Application venting Cargo-tank Types of tank venting systems for Venting requirements individualproducts Cargo-tank gas-freeing.
36 36 37 3B 38
CONTROT 9 CHAPTER - ENVIRONMENTAL 9.1 9.2 General for controlrequirements individual Environmental products.
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41
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Contents CHAPTER . EIECTRICAI 10 INSTATTATIONS 10.1 Ceneral 1O.2 Hazardous locations typesof equipment and and wiring 10.3 Bonding 1O.4 Electrical requirements individual for products CHAPTER - FIREPROTECTION 11 AND FIREEXTINCTION I 1.1 1'|, .2 I 1.3 11.4 Application Cargopumprooms. Cargoarea Special requirements. . . .. 46 46 47 49 .J'. 42 43 45 45
CHAPTER - MECHANICAT 12 VENTIIATION THECARGOAREA IN 12.1 Spaces normally entered duringcargo-handling operations 12.2 Pumprooms and otherenclosed spaces normally entered. 12.3 Spaces normally not entered CHAPTER - INSTRUMENTATION 13 13.1 Cauging 13.2 Vapourdetection CHAPTER - PERSONNEL 14 PROTECTION 14.1 Protectiveequipment 14.2 Safety equipment . CHAPTER - SPEC|AL 15 REQUTREMENTS 15.1 Acetone cyanohydrin lactonitrile and solution (80%or less) 15.2 Ammonium nitrate (93"/" less). . solution or 15.3'Carbon isulphide. d 15.4 Diethylether.. 15.5 Hydrogen peroxide solutions. 15.6 Motor fuel anti-knock compounds (containing alkyls) lead 15.7 Phosphorus, yellowor white
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52 52
54 54
57
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58 59 59 63 64 vii
IBC Code
Revisedstandardsfor the design, testing and locating of devices to prevent the passageof flame into cargo tanks in tankers Revisedfactors to be taken into considerationwhen arrangements. . . . designingcargo tank venting and gas-freeing Calculation of the capacity of foam systemsfor chemicaltankers for cleaning,passivation and loading Procedures inspection, of tanks for the carriage of hydrogen peroxide solutions 8-600/o, which have containedother cargoes,or for the carriage of other cargoesafter the carriageof hydrogen peroxide . . . . . r 2O7 222 224
227
IBC Code
Preamble
I The purposeof this code is to provide an international standardfor the safe carriageby sea in bulk of dangerous and noxiousliquid chemicals listedin chapter1 7 of the Code by prescribing designand construction the standards ships,regardless tonnage,involvedin such carriageand the of of equipmentthey shouldcarryso as to minimizethe riskto the ship,to its crew and to the environment, havingregardto the natureof the productsinvolved. 2 The basicphilosophy to assign each chemicar is to tankerone of the ship typesaccording the degreeof the hazards the productscarriedby to of such ship. Eachof the productsmay have one or more hazard properties, which includeflammability, toxicity,corrosivity and reactivity, well as the as hazardthey may presentto the environmentif accidentallv released. 3 Throughoutthe developmentof the Code it was recognizedthat it must be based upon sound naval architectural and engineering principles and the best understanding availableas to the hazards of the various productscovered;furthermore that chemicaltankerdesigntechnology not is only a complextechnologybut is rapidlyevolvingand that the code should not remain static.Thereforethe organization will periodicallyreview the Code, takinginto accountboth experience and technicaldevelopment. 4 Amendmentsto the Code involvingrequirements new products for and their conditions carriage of will be circulated recommendations, an as on interim basis, when adopted by the Maritime safety committee (MSC)and the Marine Environment Protection Committee(MEpc) of the organization, in accordance with the provisions of article vlll of the International Conventionfor the Safetyof Life at Sea, 1924 (SOLAS74\, and article 16 of the International Conventionfor the preventionof pollutionfrom ships, 1973, as modified by the Protocol relating thereto (MARPOL 73/78), respectively, pendingthe entry into force of theseamendments. 5 The code primarily dealswith shipdesignand equipment.In order to ensurethe safetransport the products, total systemmust,however,be of the appraised. other importantfacetsof the safetransport the products, of such as training, operation, trafficcontroland handlingin port,are beingor will be examinedfurther by the Organization. 6 The development of the Code has been greatly assistedby rerevant work of the International Association classification of (IACS) Societies and of the International Electrotechnical (lEC). Commission 7 Chapter 16 of the Code, dealingwith operationalrequirements of chemical tankers, highlightsthe regulationsin other chapters that are operational natureand mentions in thoseother importantsafetyfeatures that are peculiarto chemicaltankeroperation.
IBC Code
Code for the The layout of the Code is in line with the lntemational I c o f s h i p sc a r r y i n gL i q u e f i e d a s e si n B u l k( l c C C o n s t r u c t i oa n d E q u i p m e n t n session. Committeeat its forty-eighth Code),adoptedby the MaritimeSafety coveredby this Code,as may alsocarry in bulk liquid chemicals Cas carriers prescribed the IGC Code. in g The 1998 editionof the Code is basedon the originaltext as adopted b v M S C r e s o l u t i o n M S C . 4 ( 4 8 ) .I n r e s p o n s et o r e s o l u t i o n 1 5 o f t h e lnternationalConference on Marine Pollution, 1973, the MEPC, at its 9(22), rhe IBC Code adopted,by resolutionMEPC.1 session, twenty-second for pollutionpreventionaspects the implementaextendedto cover marine l l t o M A R P O L7 3 / 7 8 . tion of Annex t0 S u b s e q u e n tt o t h i s , t h e 1 9 9 8 e d i t i o n o f t h e C o d e i n c l u d e s adopted by the following resolutions: amendments
Resolution Adoption Deemedacceptance Entw into force 2 9 A p r i l1 9 8 8
12 April1990 12 AprilI990
M S C . 1 o ( s 4 ) 29 April 1987
MSC.14(57) 1 1 A p r i l 1 9 8 9 MEPC.32(271 1 7 M a r c h 1 9 8 9
30 October1988
13 October 1990 13 October 1990
3
4
1994 I January 1994 1 .lanuary 1998 1 January 1998 1 January .1998 1 lanuary 1998 10 January
As from the date of entry into force of the 1983 amendmentsto ll n S O L A S7 a ( i . e . 1 J u l y 1 9 8 6 )a n d t h e d a t e o f i m p l e m e n t a t i oo f A n n e x l l o f 73178, this code became subject to mandatory requirements MARPOL to Amendments the Code,whetherfrom the point undertheseConventions. of view of safetyor of marine pollution, must thereforebe adopted and laid down in articleVlll with the procedures broughtinto force in accordance of SOLAS74 and article16 of MARPOL 73178respectively.
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Chapter1
Ceneral
l.l
Application
f .l.l The Code appliesto shipsregardless size,includingthose of less of than 500 tons grosstonnage,engagedin the carriageof bulk cargoesof or dangerous noxiousliquid chemicalsubstances, other than petroleumor p f similarlammable roducts sfollows: a .l products having significant fire hazards in excessof those of petroleumproductsand similarflammableproducts; productshaving significant hazardsin addition to or other than flammability.
.2
that have been reviewedand determined Products not to presentsafetyand pollutionhazards suchan extentas to warrantthe application the Code to of a r e f o u n d i n c h a p t e r1 8 . 1.1.2 Liquidscoveredby the Code are those havinga vapour pressure not 2 exceeding .8 barabsolute t a temperaturef 37.8"C. a o f .f .2A For the purpose of the 1974 SOLASConvention,the Code does not apply to shipswhich are engagedin the carriageof products included in chapter17 solelyon the basisof their pollutioncharacteristics identified and as such by an entry of "P" only in column d, f.f.2B For the purposes of MARPOL 73/78, the Code applies only to as 1(1 chemicaltankers, definedin regulation ) of Annex ll thereof,which are fallinginto category B engagedin the carriage noxiousliquidsubstances of A, or C and identifiedas such by an entry of "A", "8" or "C" in column c. 1.1.3 For a product proposedfor carriagein bulk, but not listedin chapter 17 or 18, the Administration and port Administrations involved in such carriage shouldprescribe preliminary the suitable conditions the carriage, for having regard to the criteriafor hazard evaluationof bulk chemicals. The Organizationshould be notified of the conditions for considerationfor inclusionof the product in the Code. For the evaluationof the pollution hazard of such a product and assignment its pollution category,the of p r o c e d u r e p e c i f i e dn r e g u l a t i o n ( 4 )o f A n n e xl l o f M A R P O L 7 3 l 7 8m u s tb e s i 3 followed. provided otherwise, 1.1.4 Unlessexpressly the Code appliesto shipsthe keelsof which are laid or which are at a stageat which: .l construction identifiable with the ship begins;and
IBC Code
'lo/" of at has ,2 assembly commencedcomprising least50 tonnesor whicheveris less; material, massof all structural the estimated on or after 1 July 1986. which is convertedto of 1.1.5 A ship,irrespective the date of construction, a chemicaltanker on or after 1 July 1986 should be treated as a chemical This commences. on tankerconstructed the date on which such conversion of provision does not apply to the modification a ship referredto conversion o 1 i n r e g u l a t i o n ( 1 2 ) l A n n e xl l o f M A R P O L7 3 1 7 8 . 1.1.6 Where reference is made in the Code to a paragraph,all the shouldapply. of provisions the subparagraphs that designation of
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1.2 Hazards
Hazardsof productscoveredby the Code include: 1.2.1 Firehazard,defined by flashpoint,boiling point, flammabilitylimits o t a n d a u t o i g n i t i o ne m p e r a t u r e f t h e c h e m i c a l . 1.2.2 Healthhazard,defined by: .l of irritantor toxic effecton the skinor on the mucousmembranes the eyes, nose, throat and lungs in the gas or vapour state or combinedwith vapour pressure;
effectson the skin in the liquid state;or .2 irritational .3 toxic effect, taking into account values of LD56(oral):a dose which is lethal to 50"h of the test subjects orallv; when administered LD56 (skin):a dose which is lethal to 5O"hof the test subjects to when administered the skin; to which is lethalby inhalation 50% of the the LC56: concentration test subjects. 1.2.3 Waterpollution hazard,defined by human toxicity,water solubility, volatility, odour or taste,and relativedensity. 1.2.4 Air pollution hazard,defined by: or .1 emergencyexposurelimit (E.E.L.) LC5e; .2 vapour pressure; .3 solubilityin water; d o .4 relative ensity f liquid; .5 vapour density. 4
Chapter1 - Ceneral
hazard,defined by reactivitywith: 1.2.5 Reactivity .l other products;or
.2 water; or polymerization). .3 the product itself(including 1.2.6 Marine pollution hazard,as defined by: .1 with attendant risk to aquatic life or human bioaccumulation healthor causingtaintingto seafood;
.4 reductionof amenities.
1.3
Definitions
The following definitions apply unless expressly provided otherwise' chapters.) (Additional are definitions given in individual t.3.1 Accommodation spaces are those spaces used for public spaces, cinemas,Samesand hobbies cabins,offices,hospitals, corridors,lavatories, and similar containingno cooking appliances rooms,barbershops,pantries which spaces are Publicspaces thoseportionsof the accommodation spaces. enclosed are used for halls,dining rooms, loungesand similarpermanently spaces. means the Covernmentof the Statewhose flag the 1.3.2.1Administration ship is entitledto fly. meansthe appropriateauthority of the country in 1.3.2.2Port administration the port of which the ship is loadingor unloading. at 1.3.3 Boiling pointis the temperature which a productexhibitsa vapour pressure. pressure equal to the atmospheric f .3.4 Breadth/B) means the maximum breadth of the ship, measured to amidships the mouldedline of the frame in a shipwith a metalshelland to The the outer surfaceof the hull in a ship with a shellof any other material. in breadth(8) should be measured metres. 1.3.5 Cargo areaisthat part of the ship that containscargo tanks,slop tanks, or pump-rooms, ballast void spaces cofferdams, including cargopump-rooms adjacentto cargo tanks or slop tanks and also deck areasthroughoutthe entire lengthand breadthof the part of the ship over the above-mentioned cofferdams, tanks are installedin hold spaces, Where independent spaces. at ballastor void spaces the after end of the aftermosthold spaceor at the forward end of the forwardmost hold space are excluded from the cargo area.
IBCCode
f .3.6 Cargopumyroom is a space containingpumps and their accessories for the handlingof the productscoveredby the Code. 1.3.7 Cargo servicespaces are spaces within the carSo area used for of workshopsllockersani store-rooms more than 2 m' in area, used for g cargo-handlinequipment to 1.3.8 Cargo tankis the envelopedesigned containthe cargo. 1.3.S Chemicaltanker is a cargo ship constructedor adapted and used for .l the carriagein bulk of any liquid product listedin chapter 7. 1.3.10 Cofferdam is the isolating space between two adjacent steel or bulkheads decks.This spacemay be a void spaceor a ballastspace' 1.3.11 Contro! stationsare those spaces in which ship's radio or main sourceof power is locatedor where equipmentor the emergency navigating This does not or the iire-recording fire-controlequipment is centralized. located be most practically fiiecontrol equipmentwhich can includespecial in the cargo area. /imits are the conditions defining the state of fuelf.3.12 Flammability ignition strongexternal of oxidantmixtureat which application an adequately just capable of producing flammability in a given test source is only apparatus. at in is 1.3.f Flashpoint the temperature degreesCelsius which a product 3 Valuesgivenin the Code vapourto be ignited. will giveoff enoughflammable "closed-cup test" determined by an approved flashpoint are those of apparatus. 1.3.14 Hold spaceis the spaceenclosedby the ship'sstructurein which an cargo tank is situated. independent is for meansthat a pipingor ventingsystem, example, in 1.3.15 lndependent system and that there are no provisions no way connected to another for available the potentialconnectionto other systems' (t,) f .3.16 Length means96"hof the total lengthon a waterlineat 85% of the from the top of the keel,or the lengthfrom leastmoulded depth measured the stem to the axis of the rudder stock on that waterline,if the foresideof with a rakeof keel,the waterlineon which ln that be greater. shipsdesigned this length is measuredshould be parallelto the designedwaterline.The in length(t) shouldbe measured metres. A spacesof category are those spacesand trunks to such 1.3.1? Machinery which contain: spaces .1 ' .2 or used for main propulsion; machinery internal-combustion other than main usedfor purposes machinery internal-combustion machineryhas in the aggregatea total propulsionwhere such power output of not lessthan 375 kW; or
Chapter 1 - Ceneral 1.3.18 Machinery spaces all machinery are spaces category and all other of A spacescontainingpropellingmachinery,boilers,oil fuel units, steam and generators internal-combustion engines, and major electricalmachinery, oil f i l l i n g s t a t i o n , r e f r i g e r a t i n gs t a b i l i z i n g , e n t i l a t i o na n d a i r - c o n d i t i o n i n g , v machinery, and similarspaces, and trunksto such spaces. 1.3.18A MARPOL73/78 meansthe InternationalConvention for the Prevention of Pollutionfrom Ships,1973, as modified by the Protocol ol 1978 relatingthereto. 1.3.188 Noxious liquid substancemeans any substance designated in y a p p e n d i xl l t o A n n e x l l o f M A R P O L7 3 1 7 8o r p r o v i s i o n a l la s s e s s eu n d e r d of 3(4) of that Annexas fallinginto category B, C the provisions regulation A, or D. 1.3.19 Oil fuel unit is the equipmentusedfor the preparation oil fuel for of delivery to an oil-firedboiler, or equipment used for the preparationfor deliveryof heatedoil to an internal-combustion engine,and includes any oil pressure pumps,filtersand heaters dealing with oil at a pressure more than of 1 . Bb a r g a u g e . (lMO). is 1.3.20 Organization the International MaritimeOrganization 1.3.21 Permeability a space means the ratio of the volume within that of to spacewhich is assumed be occupiedby water to the total volume of that 50ace. 1.3.22 Pumyroom is a space,locatedin the cargo area,containingpumps a n d t h e i ra c c e s s o r i e o r t h e h a n d l i n g f b a l l a s a n d o i l f u e l . fs o t 1.3.22ARecognized standards are applicable international or national standardsacceptableto the Administration standardslaid down and or maintained an organization by which complieswith the standards adopted by tire Organization* and which is recognizedby the Administration. densityof liquid is the ratio of the mass of a volume of a 1.3.23 Re/ative product to the mass of an equal volume of fresh water. For a product of the relativedensityindicates whether it floatson water or limited solubility, sinks. meansthat a cargo piping systemor cargo vent system, 1.3.24 Separate for is to example, not connected anothercargopipingor cargovent system. This may be achievedby the use of designor operationalmethods. separation Operationalmethods should not be used within a cargo tank and should consistof one of the followingtypes: .l removingspool-pieces valvesand blankingthe pipe ends; or
in .2 arrangement two spectacle of flanges series, with provisions for leakage into the pipe betweenthe two spectacle detecting flanges.
Refer to the Minimum standards for recognized organizations acting on behalf of the Administration,set out in appendix 1 to the Cuidelines for the authorization of organizations a n a c t i n go n b e h a l fo f t h e A d m i n i s t r a t i o n d o p t e d b y t h e O r g a n i z a t i o nb y r e s o l u t i o n . Z : O 1 tS ; . '
IBC Code
1.3.25 Servicespacesare those spacesused for 8ai6t crtito*aiing ' rro" ''ops mail and specierooms,t' lockers, cookingappliances, rrd lrtattgace* and other than those forming part of the machineryspaces trunksto such spaces. I Conventionmeansthe lnternationalCdrf,rfrrr fot the 1.3.26 1g74 SOLAS Safetyof Life at Sea,1974. to the 1.3.27 1g83soLAs amendmentsmeans amendments the f szlUUS adoptedby the MaritimeSafetyCommitteeof the O.earizatpn Convention MSC-6: on session 17 June 1983 by resolution at its forty-eighth meansthe Standardstor and Arrangements for 1.3.21A Standards Procedures P r o c e d u r e sa n d A r r a n g e m e n t sf o r t h e D i s c h a r g e o f N o x i o u s L i r l u i d calledfor by Annex ll of MARPOL73178adoptedby the Marine Substances by session resoluProtectionCommitteeat its twenty-second Environment a t i o n M E P C . 1 8 ( 2 2 \s m a y b e a m e n d e db y t h e O r g a n i z a t i o n . or 1.3.28 Vapour density the relativedensityof vapour is the ratio of the mass to of a volume of vapour or gas (with no air present) the massof an equal Vapourdensitybelow or and at the samepressure temperature. volume of air whether the vapour or gas is lighteror heavierthan air. above 1 indicates vapour of is 1.3.29 Vapour pressure the equilibriumpressure the saturated temperature. in above a liquid expressed barsabsoluteat a specified spacein the cargo areaexternalto a cargo is 1.3.30 Void space an enclosed tank,other than a hold space,ballastspace,oil fuel tank,cargo pump-room/ pump-room,or any spacein normal use by personnel.
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1.4
Equivalents
, , t 1 . 4 . 1 W h e r e t h e C o d e r e q u i r e sh a t a p a r t i c u l afri t t i n g m a t e r i a la p p l i a n c e , item of equipmentor type thereofshouldbe fitted or carriedin a apparatus, o s r s h i p ,o r t h a t a n y p a r t i c u l ap r o v i s i o n h o u l db e m a d e ,o r a n y p r o c e d u r e r n a r r a n g e m e ns h o u l d b e c o m p l i e dw i t h , t h e A d m i n i s t r a t i o m a y a l l o w a n y t other fitting, material,appliance,apparatus,item of equipment or type thereof to be fitted or carried, or any other provision, procedure or to arrangement be made in that ship, i{ it is satisfiedby trial thereof or item of equipment apparatus, appliance, that suchfitting,material, otherwise is procedureor arrangement provision, or type thereofor that any particular at least as effective as that required by the Code. However, the t l m A d m i n i s t r a t i o n a y n o t a l l o w o p e r a t i o n a m e t h o d so r p r o c e d u r e s o b e item apparatus, appliance, fitting,material, to made an alternative a particular such by or of equipment, type thereol which are prescribed the Code,unless allowed by the Code. is substitution specifically so 1.4.2 When the Administration allows any fitting, material,appliance, item of equipment,or type thereof,or provision,procedure,or apparatus, it thereafter, or arrangement, novel designor applicationto be substituted thereof,together should communicateto the Organizationthe particulars with a report on the evidence submitted,so that the Organizationmay B
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Chaoter 1 - Ceneral circulatethe same to other ContractingGovernments the 1974 SOLAS to Convention and Partiesto MARPOL 73/78 for the informationof their officers.
1.5
f .5.1 Surveyprocedure 1.5.1.1 The survey of ships, so far as regards the enforcement of the provisions the regulations of and grantingof exemptions therefrom,should be carried out by officersof the Administration. The Administration may, however,entrustthe surveys either to surveyors nominatedfor the purpose or to organizations recognizedby it. 1.5.1.2 The Administration nominatingsurveyorsor recognizingorganizat i o n s t o c o n d u c ts u r v e y s h o u l d ,a s a m i n i m u m ,e m p o w e ra n y n o m i n a t e d s surveyoror recognized organization to: .l .2 requirerepairs a ship;and to carry out surveys if requested by the port State authority' concerned.
The Administrationshould notify the Organization of the specific responsibilities and conditions of the authority delegated to nominated surveyorsor recognizedorganizations for circulationto the Contracting Governments. 1.5.1.3 When a nominatedsurveyoror recognizedorganization determines t h a t t h e c o n d i t i o n o f t h e s h i p o r i t s e q u i p m e n td o e s n o t c o r r e s p o n d substantially the particulars the certificate is suchthat the shipis not with of or fit to proceedto seawithout dangerto the ship or to persons board,such on surveyor organization or shouldimmediately ensurethat corrective action is t a k e na n d s h o u l di n d u e c o u r s en o t i f yt h e A d m i n i s t r a t i o nf.s u c hc o r r e c t i v e l action is not taken the relevantcertificateshould be withdrawn and the Administration shouldbe notifiedimmediately; and, if the ship is in a port of anotherContracting Government, port Stateauthorityconcerned the should also be notifiedimmediately. 1.5.1.4 everycase,the Administration In shouldguarantee completeness the and efficiencyof the survey,and should undertaketo ensurethe necessary arrangements satisfy to this obligation. 1.5.2 Surveyrequirements 1.5.2.1 The structure, equipment,fittings,arrangements and material(other than items in respectof which a Cargo Ship SafetyConstruction Certificate, Cargo Ship Safety Equipment Certificateand Cargo Ship Safety Radio Certificate Cargo Ship SafetyRadiotelegraphy or Certificate Cargo Ship or SafetyRadiotelephony Certificate issued) a chemicaltankershouldbe are of subjectedto the followingsurveys:
' Port State authority has the meaning as presented in chapter l, regulation 19, of the 19ZB Protocol to the 1974 SOLAS Convention.
IBC Code
.l
rtl$
An initial survey before the ship is put in serviceor before the for certificateof Fitness the carriageof Dangerous lnternational f i c h e m i c a l sn B u l ki s i s s u e do r t h e f i r s tt i m e ,w h i c h s h o u l di n c l u d e a complete examinationof its structure, equipment, fittings, and arrangemenrs materialin so far as the ship is coveredby the Code.This surveyshouldbe such as to ensurethat the structure, and materialfully comply with arrangements equipment,fittings, provisions the Code' of the applicable
specifiedby the Administration, .2 A periodicalsurveyat intervals which shouldbe suchas to ensurethat 5 but not exceeding years, the structure,equipment, fittings, arrangementsand material p s c o m p l yw i t h t h e a p p l i c a b l e r o v i s i o n o f t h e C o d e '
.3 A minimum of one intermediatesurvey during the period of for of Certificate Fitness the Carriage validityof the International w i C o f D a n g e r o u s h e m i c a l sn B u l k .l n c a s e s h e r e o n l y o n e s u c h validity surveyis carriedout in any one certificate intermediate period,itshouldbeheldnotbefore6monthspriorto,norlater periodof date of the certificate's than 6 monthsafter,the half-way validity.Intermediatesurveysshou|dbesuchastoenSurethatt pump safetyequipment,and other equipment,and associated andpipingSystemscomp|ywiththeapp|icab|eprovisionsofthe Code and are in good working order' Such surveysshould be il endorsed on the Internationalcertificate of Fitnessfor the I i C o C a r r i a g e f D a n g e r o u s h e m i c a l sn B u l k ' 'j .{ A mandatory annual survey within 3 months before or after the for of Certificate Fitness the date of the International anniversary a C s c a r r i a g eo f D a n g e r o u s h e m i c a l i n B u l kw h i c h s h o u l di n c l u d e general examinationto ensure that the structure,equipment' a f i t t i n g s , a r r a n g e m e n t s n d m a t e r i a l sr e m a i n i n a l l r e s p e c t s foithe servicefor which the ship is intended.Sucha satisfactory certificate of survey should be endorsed on the International in Chemicals Bulk' of Carriage Dangerous for Fitness the
'sAnadditiona|survey,eithergeneralorpartia|accordingtothe circumstances,shouldbemadewhenrequiredafteran prescribedin 1.5.3'3,or whenever any important investigation repairsor renewalsare made' Such a surveyshould ensurethat thenecessaryrepairsorrenewa|shavebeeneffective|ymad are or of and workmanship suchrepairs renewals that the material and that the ship is fit to proceed to sea without satisfactorv, dangerto the ship or personson board' of 1.5.3 Maintenance conditions aftersurvey to t o T 1 . 5 . 3 . 1 h e c o n d i t i o n f t h e s h i pa n d i t s e q u i p m e n s h o u l db e m a i n t a i n e d that the shipwill remainfit of conformwith the provisions the Code to ensure to oroceedto sea without dangerto the ship or personson board.
10
Chapter 1 - Ceneral 1.5.3.2 After any survey of the ship under 'l .5.2 has been cdmpleted,no changeshould be made in the structure, equipment,fittings,arrangements and materialcoveredby the survey, without the sanction the Administraof tion, except by direct replacement. 1.5.3.3 whenever an accident occurs to a ship or a defect is discovered, eitherof which affects safety the shipor the efficiency completeness the of or of its life-saving appliances other equipment,the masteror owner of the or ship should report at the earliestopportunity to the Administration, the nominatedsurveyoror recognizedorganization responsible issuingthe for relevant certificate,who should cause investigations be initiated to to d e t e r m i n e h e t h e ra s u r v e ya s r e q u i r e d r y 1 . 5 . 2 . 1 . 5s n e c e s s a r yf.t h e s h i p w , t i, l is in a port of anotherContracting covernment,the masteror owner should also report immediatelyto the port State authority concerned and the nominatedsurveyor recognized or organization shouldascertain that sucha report has been made. 1.5.4 lssueof lnternationalCertificate Fitness of 1.5.4.1 certificatecalled an InternationalCertificateof Fitnessfor the A Carriage Dangerous of Chemicals Bulk,the model form of which is serout in in the appendix,should be issuedafter an initialor a periodicar surveyro a chemicaltanker engagedin international voyageswhich complieswith the relevantrequirements the Code. of 1.5.4.2 The certificateissued under provisionsof this section should be available board for inspection all times. on at 1.5.5 lssueor endorsementof InternationalCertificate Fitness of by anotherCovernment f .5.5.f A Partyto the 1974SOLASConvention and ro MARPOL 73178may, at the request anotherParty, of causea shipentitledto fly the flagof the other state to be surveyedand, if satisfied that the requirements the cocre are of compliedwith, issueor authorizethe issueof the certificate the ship,and, to where appropriate, endorseor authorizethe endorsement the certificate of on board the ship in accordancewith the Code. Any certificateso issued shouldcontaina statement the effectthat it has been issued the reouest to at of the Covernmentof the Statewhose flag the ship is entitledto fly. 1'5'6 Duration and validity of the lnternationalCertificate Fitness of 1.5'6.1 lnternational An Certificate Fitness the Carriage Dangerous of for of C h e m i c a l si n B u l k s h o u l d b e i s s u e d f o r a p e r i o d s p e c i f i e d b y t h e Administration which should not exceed5 yearsfrom the date of the initial surveyor the periodicalsurvey. 1.5.6.2No extension of the 5-year period of the certificate shourd be permitted. 1.5.0.3 The certificateshould ceaseto be valid: .l if the surveysare not carriedout within the period specifiedby 1.5.2;
11
IBC Code
.2 upon transfer of the ship to the flag of another State. A new certificateshould only be issuedwhen the Covernmentissuing the new certificate fully satisfied is that the ship is in compliance w i t h t h e r e q u i r e m e n to f 1 . 5 . 3 . 1 n d 1 . 5 . 3 . 2 W h e r e a t r a n s f e r s a . the Governmentof occurs between ContractingCovernments, the Statewhoseflag the shipwas formerlyentitledto fly should,if 'l requested within 2 monthsafterthe transferhas taken place,as soon as possibletransmit to the Administration copies of the certificates carriedby the ship beforethe transfer and, if available, copiesof the relevantsurveyreports.
^ l
,
,lilt Hll
12
ffi
lilr
iFi iii
2.1
General
2'l'l ships subjectto the Code shouldsurvivethe normaleffectsof flooding followingassumedhull damagecausedby some externalforce. In addition, to safeguard the ship and the environment, the cargo tanks of certain typeqof ships should be protectedfrom penetrationin the case of minor damageto the ship resulting, example,from contactwith a ietty or tug, for and given a measureof protectionfrom damage in the case of collisron or stranding, locatingthem at specified by minimumdistances inboardfrom the ship'sshellplating.Both the damageto be assumed and the proximityof the cargo tanks to the ship's shell should be dependent upon the degree of hazardpresented the productsto be carried. by 2.1.2 Shipssubjectto the Code shouldbe designed one of the following to standards: .1 A type 1 ship is a chemicaltanker intendedto transportchaprer 17 productswith very severeenvironmental and safetyhazards w h i c h r e q u i r e m a x i m u m p r e v e n t i v e e a s u r e s o p r e c l u o ea n m t escapeof such cargo. .2 A type 2 ship is a chemicaltanker intendedto transportchapter 17 productswith appreciablysevereenvironmental and safety hazardswhich require significantpreventivemeasuresto preclude an escapeof such cargo. .3 A type 3 ship is a chemicaltanker intendedto transportchapter 17 products with sufficientlysevere environmentaland safety hazardswhich require a moderate degree of containmentto increase survival capabilityin a damagedcondition. Thus a type 1 ship is a chemicaltanker intendedfor the transportation of productsconsidered presentthe greatest to overall hazardand type 2 and type 3 for productsof progressively lesser hazards. Accordingly, type 1 ship a shouldsurvive most severe the standard damageand itscargotanksshould of be located at the maximum prescribeddistance inboard from the shell plating.
* Referenceis made to the Cuidelines for the uniform application of the survivalrequirements of the Bulk Chemical Code and the Cas Carrier Code (see page 201).
13
IBC Code 2.1.3 The ship type requiredfor individualproducts is indicatedin column e i n t h e t a b l eo f c h a p t e r1 7 . 2.1.4 lf a ship is intendedto carry more than one product listedin chapter 17, the standardof damageshould correspondto that product havingthe for The requirements the locationof most stringentship type requirement. individualcargo tanks, however, are those for ship types related to the productsintendedto be carried. respective
2.2
the minimum freeboard 2.2.1 Shipssubjectto the Code may be assigned on Convention Load Linesin force. However, permittedby the International should not be Sreaterthan the the draughtaqociated with the assignment maximumdraughtotherwisepermittedby this Code. 2.2.2 The stabilityof the ship in all seagoingconditionsshould be to a to which is acceptable the Administration. standard liquidsfor of th" 2.2.1 When calculaiing effectof free surfaces consumable that,for each type of liquid,at least it loadingconditions shouldbe assumed pair or a singlecentretank has a free surfaceand the tank or one transverse o c o m b i n a t i o n f t a n k st o b e t a k e n i n t o a c c o u n ts h o u l db e t h o s ew h e r e t h e The free surfaceeffect in undamaged is effect of free surfaces the greatest. compartments should be calculated by a method acceptable to the Administration. in spaces shouldnot normallvbe used in double-bottom 2.2.4 Solidballast the o{ the cargo area.Where, however,because stabilityconsiderations, fitthen its disposition becomesunavoidable, ting of solid ballastin suchspaces should be governedby the need to ensurethat the impact loads resulting structure. to from bottom damageare not directlytransmitted the cargo-tank 2.2.5 The masterof the ship shouldbe suppliedwith a loadingand stability and of booklet.Thisbookletshouldcontaindetails typicalservice information of provisions evaluating other conditions loadingand a for conditions, ballast In summaryof the ship'ssurvivalcapabilities. addition,the booklet should informationto enablethe masterto load and operatethe containsufficient ship in a safeand seaworthymanner.
2.3
led 2.3.1 The provisionand control of valvesfitted to discharges through deck or from within the superthe shell from spacesbelow the freeboard on and deck-houses the freeboarddeck fitted with weathertight structures of of doors shouldcomply with the requirements the relevantregulation the 14
.2 where the verticaldistance from the summerload waterline the to inboardend of the discharge pipe exceeds 0.01[, two automatic nonreturnvalveswithout positivemeansof closing, providedthat the inboardvalve is alwaysaccessible examination for under ser_ vice conditions.
2.3.2 For the purposeof this chapter,,,summerload line,,and ,,freeboard deck" havethe meanings definedin the International as Convention Load on Linesin force. 2.3.3 The automatic nonreturnvalves referred to in 2.3.1 and 2.3.1 .1 .2 shouldbe fully effective preventing in admission water into the ship,taking of into accountthe sinkage, trim and heel in survivalrequirements 2.9, and in shouldcomply wi$ recognized standards.
2.4
Conditions loading of
Damage survivalcapabilityshould be investigated the basisof roading on informationsubmittedto the Administration all anticipated for conditionsof loading and variationsin draught and trim. Ballastconditionswhere the chemicaltankeris not carryingproductscoveredby the Code, or is carrying only residues such products,need not be considered. of
2.5
Damage assumptions
.l.l Longitudinal extent: ,1,2Transverse extent: ( m e a s u r e dn b o a r d i f r o m t h e s h i p ' ss i d e at right anglesto the centreline the at levelof the summer loadline) .1.3Verticalextent: ( f r o mt h e m o u l d e dl i n e of the bottom shell platingat centreline)
upwardswithout limit
15
IBC Code .2 Bottom damage: For 0.3L from the forward perpendicular of the ship Any other part of the ship
extentthan the maximumdamagespecified 2.5.2 lf any damageof a lesser in 2.5.1 would result in a more severecondition,such damage should be considered.
2.6
2.6.2 Except for type 1 ships, suction wells installed in cargo tanks may .2.3 protrude into the vertical extent of bottom damage specifiedin 2.5.1 below and the protrusion providedthat suchwellsare as smallas practicable the inner bottom platingdoes not exceed 25"/. of the depth of the double Where there is no double bottom, the bottom or 350 mm, whicheveris less. tanksbelow the upper limit of protrusion the suctionwell of independent of bottom damage should not exceed 350 mm. Suction wells installedin accordancewith this paragraphmay be ignored in determiningthe compartments affectedby damage. 16
Chapter2 - Shipsurvival
,:
2.1.1 The requirements 2.9 should be confirmedby calculations of which take into consideration the designcharacteristics the ship; the arrange of ments, configurationand contents of the damaged compartments; the distribution, relativedensities and the free surfaceeffectsof iiquids;and the draughtand trim for all conditionsof loading. 2.1'2 The permeabilities spacesassumedto be damagedshould of be as follows: Spaces Appropriated stores to Occupied by accommodation Occupied by machinery 'voids Intendedfor consumable liquids Intendedfor other liquids Permeabilities 0.60 0.95
0.8s
0.95 0 to 0.95. 0 to 0.95*
2'1.3 wherever damage penetrates tank containingriquidsit shourd a be assumedthat the contentsare completelylost from that compartment and replacedby salt water up to the leverof the finarplane of "qriribriur. 2Jl Every watertight division within the maximum extent of damage definedin 2.5.1and considered havesustained to damagein positions given in 2.8'1 should be assumed be penetrated. to where dimage ressthan the maximum is being consideredin accordancewith 2.5.2, onry watertight divisions combinations watertightdivisions or of within the "nu"iopu of such lesser damageshould be assumed be penetrated. to 2'7'5 The ship shouldbe so designed to keep unsymmetrical as floodingto the minimum consistent with efficientarrangements. 2'1.6 Equalization arrangements requiringmechanical aids such as valves or crossJevelling pipes,if fined, shouldnot be considered the purpose for of reducingan angleof heel or attaining minimumrangeof residual the stability to meet the requirements 2.9 and sufficientresidualstabirity of shourdbe maintainedduring all stageswhere equalization used. spaceswhicn is are linked by ducts of large cross-sectional area may be consideredto be common. 2'7'7 lf pipes, ducts, trunks or tunnels are situatedwithin the assumed extent of damage penetration, defined in 2.5, arrangements as should be suchthat progressive floodingcannottherebyextendto c-ompartments other than those assumed be flooded for each caseof damage. to :-The permeabiliry of partially filled compartments should be consistent with the amount of Iquto carneo In tne compartment.
17
IBC Code
directlyabove the side damage 2.1.8 The buoyancyof any superstructure beyond the The unfloodedparts of superstructures should be disregarded. providedthat: extentof damage,however,may be taken into consideration .1 they are separated from the damaged space by watertight o( and the requirements 2.9.3 in respectof theseintact divisions are compliedwith; and spaces .2 openings in such divisions are capable of being closed by remotely operated sliding watertight doors and unprotected w a o p e n i n g s r e n o t i m m e r s e d i t h i nt h e m i n i m u mr a n g eo f r e s i d u a l stabilityrequired in 2.9; however, the immersionof any other may be permitted' capableof beingclosedweathertight openings
2.8
Standardof damage
the shouldbe capableof surviving damageindicatedin 2.5 with 2.8.1 Ships t b n t h e f l o o d i n ga s s u m p t i o nis 2 . 7 t o t h e e x t e n td e t e r m i n e d y t h e s h i p ' s y p e standards: t a c c o r d i n go t h e f o l l o w i n g .l damageanywherein to A type 1 ship shouldbe assumed sustain itslength;
'l to .2 A type 2 shipof more than 50 m in lengthshouldbe assumed damageanywherein its length; sustain 'l to .3 A type 2 ship of 50 m in length or less should be assumed damageanywherein its lengthexcept involvingeither of sustain spacelocatedaft; boundinga machinery the bulkheads to .4 A type 3 shipof more than 225 m in lengthshouldbe assumed damageanywherein its length; sustain .5 A type 3 shipof 125 m in lengthor more but not exceeding225m in length should be assumedto sustaindamageanywherein its length except involving either of the bulkheads bounding a machineryspace located aft; to .6 A type 3 ship below 125 m in lengthshouldbe assumed sustain damage anywherein its length except involvingdamage to the spacewhen locatedaft. However,the abilityto survive machinery by spaceshouldbe considered the the floodingof the machinery Administration. 2.8.2 ln the caseof smalltype 2 and type 3 shipswhich do not comply in all . r s w r e s p e c t s i t h t h e a p p r o p r i a t e e q u i r e m e n to l 2 . 8 . 1 . 3a n d 2 . 8 - 16 , s p e c i a l provided that may only be consideredby the Administration dispensation can measures be takenwhich maintainthe samedegreeof safety. alternative shouldbe approvedand clearlystated measures The natureof the alternative shouldbe Any to and be available the port Administration. suchdispensation referredto in 1.5.4. of Certificate Fitness duly noted on the International -18
2.9
Suruival requirements
2..s'1 shipssubjectto the Code shourdbe capabre surviving of the assumed damage specifiedin 2.5 to the standardprovided in 2.g in a"condition of stableequilibriumand shouldsatisfy the followingcriteria. 2.5.2 ln any stage of flooding: .l the waterline, taking into account sinkage, heel and trim, should be below the lower.edge of any opening through which pro_ gressive floodingor.downflooding may take place.Suchopenings shouldincludeair. pipesand openings which are closedb1irn""n, of weathertightdoors or hatch covers and may excruie those openings closed by means of watertight manhole covers and watertightfrushscuttres, smalrwatertighicargo-tank hatcrrcovers which maintainrhe high integrityof the deck] remotely operated watertight slidingdoors,and sidescuttles the non_opening of type;
.2 the maximumangleof heel due to unsymmetrical floodingshould not exceed25', exceptthat this anglemay be increased Io 30" if no deck immersionoccurs; .3 the residual stabirity duringintermediate stages froodingshourd of be to the satisfaction the Administration. of However, ii shourd never be significantly than that requiredbv 2.9.3less 2.9.3 At final equilibriumafter flooding; .l the righting-lever curve should have a minimum range of 20. b e y o n dt h e p o s i t i o n f e q u i l i b r i u mn a s s o c i a t i ow i t h a m a x i m u m o i n residualrightinglever of at least0.j m within the 20. range; the area under the curve within this range should not be ress than O . O 1 7 S r a d . U n p r o t e c t e d p e n i n g s h o u l dn o t b e i m m e r s e d m o s within this range unress the space concernedis assumedto be flooded.Within this range,the immersionof any of the openings l i s t e d i n 2 . 9 . 2 . 1a n d o t h e r o p e n i n g sc a p a b l e ' o f b e i n g ' c l o s e d weathertight may be permitted;and
19
Chapter3
Shiparrangements
3.1
Cargo segregation
3.1.1 Unless expresslyprovided otherwise, tanks containing cargo or residues of cargo subject to the Code should be segregated from accommodation,service and machineryspacesand from drinking water and storesfor human consumptionby meansof a cofferdam,void space, cargo pump-room/pump-room,empty tank, oil fuel tank or other similar space. of 3.1.2 Cargoes,residues cargoesor mixturescontainingcargoeswhich should: or residues mixtures, mannerwith other carSoes, reactin a hazardous from suchother cargoesby meansof a cofferdam, .1 be segregated space,carSopump-room,pump-room,empty tank, or tank void a containing mutuallycompatiblecargo; which shouldnot pass pumpingand pipingsystems .2 haveseparate through other cargo tanks containing such cargoes, unless i e n c a s e dn a t u n n e l ;a n d .3 tank ventingsystems. have separate
or service 3.1.3 Cargopipingshouldnot passthroughany accommodation, or machineryspaceother than cargo pump-rooms piump-rooms. 3.1.4 Cargoessubjectto the Code shouldnot be carriedin eitherthe fore or aft peak tank.
3.2
or 3.2.1 No accommodation servicespacesor control stationsshould be located within the cargo area except over a cargo pumproom recessor ll2l56 of the 1983 SOLAS pump-roomrecess that complieswith regulation and no cargo or slop tank shouldbe aft of the forward end of amendments any accommodation. 3.2.2 In order to guard againstthe danger of hazardousvapours, due into and openings shouldbe givento the locationof air intakes consideration accommodation,service and machinery spaces and control stations in relationto cargo piping and carSovent systems. 20
3.3
CargopumFrooms
.l .2 passage all times from any ladder platform and unrestricted at from the floor; and unrestricted access all valvesnecessary cargo handling a to for for personwearingthe requiredpersonnel protectiveequipment.
3.3.2 Permanentarrangements should be made for hoistingan injured personwith a rescueline while avoidingany projectingobstacles. 3.3.3 Cuard railings shouldbe installed all laddersand platforms. on 3.3.4 Normal access ladders should not be fitted vertical and should platformsat suitableintervals.* incorporate 3.3.5 Means should be provided to deal with drainageand any possible leakage from cargo pumps and valves in cargo pump-rooms.The bilge systemservingthe cargo pump-roomshould be operablefrom outsidethe cargo pump-room. One or more slop tanksfor storage contaminated of bilge water or tank washingsshould be provided. A shore connectionwith a standard coupling or other facilitiesshould be provided for transferring contaminated liquidsto onshorereceptionfacilities. 3.3.6 Pump dischargepressuregaugessnould be provided outside the carSopump-room.
' Reference is made to the Recommendation on safe access to and working in large tanks (resolutionA.272(Vlll), annex l) as amended by resolution A.330(lX).
21
IBC Code
passing is througha bulkheador 3.3.7 Where machinery drivenby shafting with efficientlubrication other meansof ensuring or the deck, gastight seals permanence the gassealshouldbe fitted in way of the bulkheador deck. of
3.4
3.4.1 Accessto cofferdams,ballasttanks, cargo tanks and other spacesin the cargo area should be direct from the open deck and such as to ensure Access double-bottom to spaces may be througha theircompleteinspection. cargo pump-room, pump-room, deep cofferdam, pipe tunnel or similar subjectto consideration ventilation of aspects. compartments, the 3.4.2 For accessthrough horizontalopenings,hatchesor manholes, should be sufficient allow a personwearing a self-contained to dimensions apparatus and protectiveequipmentto ascendor descendany air-breathing ladder without obstructionand also to providea clear openingto facilitate The minimum of the hoisting an injuredpersonfrom the bottom of the space. c l e a ro p e n i n gs h o u l db e n o t l e s st h a n 6 0 0 m m b y 6 0 0 m m . providingpassage throughverticalopenings, manholes or 3.4.3 For access t h r o u g ht h e l e n g t ha n d b r e a d t ho f t h e s p a c e ,t h e m i n i m u mc l e a r o p e n i n g should be not lessthan 600 mm by 800 mm at a height of not more than gratings other footholdsare or 600 mm from the bottom shellplatingunless provided. may be approvedby the Administration special in 3.4.4 Smaller dimensions suchopenings to removean injured or circumstances,the abilityto traverse if personcan be proved to the satisfaction the Administration. of
3.5
l v s 3 . 5 . 1 P u m p s , a l l a s t i n e s , e n t l i n e sa n d o t h e r s i m i l a re q u i p m e n t e r v i n g b permanentballast tanksshouldbe independent similarequipmentserving of for Dischargearrangements cargo tanks and of cargo tanks themselves. permanent adjacentto cargotanksshouldbe ballast tankssitedimmediately Fillingarrangements outsidemachinery spaces and accommodation spaces. may be in the machineryspacesprovided that such arrangements ensure fillingfrom tank deck leveland nonreturnvalvesare fitted. 3.5.2 Fillingof ballastin cargo tanks may be arrangedfrom deck level by pumps servingpermanentballasttanks,providedthat the filling line has no permanent are connection cargotanksor pipingand that nonreturnvalves to fitted. for 3.5.3 Bilge pumping arrangements cargo pump-rooms,pump-rooms, void spaces, slop tanks,double-bottom tanks and similarspacesshould be double-bottom situated entirelywithin the cargoareaexceptfor void spaces, tanks and ballast tanks where such spaces are separatedfrom tanks of containingcargo or residues cargo by a double bulkhead.
22
3.6
Pumpand pipelineidentification
Provisions should be made for the distinctive markingof pumps,varves and pipelines identifythe serviceand tankswhich they"serve. to
3.1
3.7-1 piping may be fitted to permit bow or stern loading and ..Cargo unloading. Portablearrangements shouldnot be permitted. 3'l'2 Bow or sternroadingand unroading rinesshourdnot be usedfor the transferof products requiredto be carriel in type 1 ships. Bow ano stern loadingand unloadingrinesshourdnot be used'for the iransferof cargoes emitting toxic vapoursrequiredto compry with 15.12.1, unress specifiiaily approvedby the Administration. 3.7.3 In additionto 5.1, the followingprovisions apply: .l rhe pipingoutsidethe cargoareashouldbe fittedat least 76o mm inboard on the open deck. Such piping should be clearly identifiedand fitted with a shutoffvarveatlts connection to the cargo piping system within the cargo area. At this location, it should also be capable of being separated by means of a removablespool_piece blank flangeswhen not in and use.
.2 The shoreconnectionshourdbe fitted with a shutoff varveand a blank flange. .3 The piping sho.uldbe fuil-penetration butt-werded,and fuily radiographed. Flangeconnectionsin the piping stroulJ onty be permittedwithin the cargo area and at the shoie connection. '4 spray shields shourdbe providedat the connections specified in .1 as well as coilectingtraysof sufficient capacity, with meansfor the disposal drainage. of
.5 The piping should be self_draining the cargo to area and preferably into a cargotank.Alternative arrangem"rit, draining fo,. the piping may be acceptedby the Administiation. .6 Arrangements shouldbe made to allow suchpipingto be purged afteruse and maintained gas-safe when not in'rre. ih" vent pipes connectedwith the purge shourdbe rocatedin the cargo area. The relevant connections the pipingshouldbe providei with a to shutoffvalve and blank flange. 3'7.4 Entrances, inlets and openingsto accommodation, air serviceand machineryspacesand contror stationsshourd not ru." inu'.urgotrhor* connection location of. bow. or stern roading and unroading arrariglments.
houseat a distance at least4'h of the rengthof the ship burnoiress of than 3 m from the end of the house facing the cargo shore-connection rocation of the bow or stern loading and unroadingarrangements. This distance.
23
IBC Code facing the shoreconnection however, need not exceed 5 m. Sidescuttles within the or location and on the sides of the superstructure deck-house type. ln distancementioned above should be of the fixed (non-opening) addition, during the use of the bow or stern loading and unloading all arrangements, doors, ports and other openingson the corresponding superstructure deck-house or side shouldbe kept closed.Where, in the case w i th o f s m a l ls h i p s c o m p l i a n c e i t h 3 . 2 . 3a n d t h i sp a r a g r a p hs n o t p o s s i b l e , e , may approve relaxations from the above requirements. Administration 3.7.5 Air pipes and other openingsto enclosedspacesnot listed in 3.7.4 should be shieldedfrom any spraywhich may come from a burst hose or connection. 3.7.6 Escape routesshouldnot terminatewithin the coamingsrequiredby o 3 . 7 . 7o r w i t h i n a d i s t a n c e f 3 m b e y o n dt h e c o a m i n g s . coamings suitableheightshouldbe fitted to keep any of 3.7.7 Continuous and serviceareas. spillson deck and away from the accommodation 3.7.8 Electrical equipmentwithin the coamingsrequiredby 3.7.7 or within with the a distanceof 3 m beyond the coamingsshould be in accordance r e q u i r e m e n to f c h a p t e r1 0 . s for 3.7.9 Fire-fighting arrangements the bow or sternloadingand unloading w 1 a r e a ss h o u l db e i n a c c o r d a n c e i t h 1 1 . 3 . .6 . betweenthe cargo control stationand the 3.7.10 Meansof communication location should be provided and certifiedsafe, if cargo shore-connection Provisionshould be made for the remote shutdown of cargo necessary. pumps from the cargo shore-connection location.
24
Chapter4 Cargocontainment
4.1 Definitions
4.1.1 Independenttank meansa cargGcontainment envelopewhich is not contiguouswith, or part of, the hull structure. independent An tank is built and installedso as to eliminate whenever possible(or in any event to minimize)its stressing a resultof stressing motion of the adjacenthull as or structure. independent An tank is not essential the structural to completeness of the ship's ull. h 4.1.2 lntegral tank means a cargo-containment envelope which forms part o f t h e s h i p ' sh u l l a n d w h i c h m a y b e s t r e s s e id t h e s a m em a n n e ra n d b y t h e n same loadswhich stress contiguoushull structure the and which is normally essential the structural to completeness the ship'shull. of 4.f.3 Cravitytank meansa tank havinga designpressure not greaterthan O.7 bar gaugeat the top of the tank. A gravitytank may be independent or integral.A gravity tank should be constructedand tested according to recognizedstandards, taking account of the temperatureof carriageand relativedensityof the cargo. 4.1.4 Pressure tank means a tank having a design pressuregreater than 0.7 bar gauge.A pressure tank should be an independent tank and should be of a configurationpermittingthe applicationof pressure-vessel design criteriaaccordingto recognizedstandards.
4.2
Requirements both installation for and design of tank types for individual productsare shown in column f in the table of chapter 'l Z.
25
Chapter5 Cargotransfer
5.t Pipingscantlings*
5.1.1 Subjectto the conditionsstated in 5.1.4, the wall thickness(t) of, pipes shouldnot be lessthan: . to+b+c (mm) 1::-:-:jj 1 _ _ 100 where: to : theoreticalthickness t": with P: (bar)referredto in 5.1.2 designpressure PDIQOKe+ P) (mm)
pipes and for longe : efficiencyfactor equal to 1.0 for seamless itudinallyor spirally welded pipes,deliveredby approved manufacturers welded pipes,which are considered of to equivalent pipeswhen non-destructive seamless testingon welds is carriedout in accordance with recognizedstandards. other cases, In an . factor of lessthan 1.0, in accordance efficiency with recognized may be requireddependingon the manufacturing standards, process. for b : allowance bending(mm).The valueof b shouldbe chosenso that the stress the bend, due to internalpressure in calculated only, does not Where suchjustification not given,b exceedthe allowablestress. is shouldbe not lessthan: . b: with r : mean radiusof the bend (mm).
" Reference is afso made to the published Ru/esof the Members and As.sociate Members of the I nternational Association of ClassificationSocieties /IACS).
Dt.. 2-rr(mm)
26
a:
p 5'l'2 The designpressure in the formurafor t. in 5.1.1 is the maximum gaugepressure which the systemmay be subjected to in service, takinginto accountthe highestset pressure any reliefvilve on the on ,yrt".. 5'l:3. Piping and piping-system components which are not protected by a relief valve, or which may be isolatedfrom thei'erief vaive,ir,orro nu designedfor at least the greatestof: .l for pipingsystems components or which may containsome liquid, the saturated vapour pressure 45"C; at the pressure settingof the associated pump discharge rerief varve; the maximum possibretotar pressure head at the outret of the associatedpumps when a pump dischargerelief valve is not installed.
'2 '3
5'l'4 The designpressure shourdnot be ressthan 10 bar gaugeexceptfor open-ended lines,where it shouldbe not lessthan S Uu. S;;gJ 5'l'5 For pipes,the allowabre stress to be considered the formurafor to K in in 5.1.1 is the lower of the followingvalues:
&or&
A where:
Rm: specified minimumtensire strengthat ambienttemperature (N/mm2) Re: specified minimumyield stress ambienttemperature at (N/mm2).rf the stress-strain curvedoes not show a definedyield stress, o.z% proor ihe stress applies. A a n d B s h o u l d h a v e v a l u e sa t fl e a s A : 2 . 7 o t and g:,|.g.
5.1.6.1 he minimum wail thicknessshourd be in T accordance with recognizedstandards. 5'1.6.2Where necessaryfor mechanicar strength to prevent damage, collapse,excessive sag or buckringof pipes duJ to *"i?r,1 oi-pipu, "na content and to superimposed roadsfrom supports, ship dJfrection other lr causes, wall thickness the shouldbe increased over rhat requi.J bt i. r . t or, if this is impracticable wourd causeexcessive or rocarstresses, t#se roaas shouldbe reduced, protectedagainst eriminated other a"rign or by ;"thoar. 5.1.6.3 Flanges,valves and other fittings should be in accordance with recognized standards, takinginto "c.ornt the designpressure definedunder 5.1.2.
27
IBC Code 5.1.6.4For flanges not complyingwith a standard, dimensions flanges the for and associated bolts shouldbe to the satisfaction the Administration. of
6.2
5.2.1 The requirements thissectionapplyto pipinginsideand outsidethe of cargotanks.However,relaxations from theserequirements may be accepted in accordancewith recognizedstandards for open-endedpiping and for piping insidecargo tanksexceptfor cargo piping servingother cargo tanks. 5.2.2 Cargo piping shouldbe joined by welding except: joints; .1 for approvedconnections shutoffvalvesand expansion to and .2 for other exceptional casesspecificallyapproved by the Administration. 5.2.3 The followingdirectconnections pipe lengths of without flanges may be considered: .1 joints with completepenetration the root may be Butt-welded at u s e di n a l l a p p l i c a t i o n s . Slip-onwelded joints with sleevesand related welding having dimensions accordance in with recognized standards shouldonly be usedfor pipeswith an external diameterof 50 mm or less. This type of joint should not be used when crevice corrosion is expected to occur.
.2
.3 Screwedconnections, accordance in with recognizedstandards, shouldonly be usedfor accessory linesand instrumentation lines with externaldiameters 25 mm or ress. of 5.2.4 Expansion piping should normallybe allowedfor by the provision of of expansion loops or bendsin the pipingsystem. .1 Bellows, in accordance with recognized standards,may be speciallconsidered. y
.2 Slipjoints shouldnot be used. 5.2.5 Welding,post-weld heattreatmentand non-destructive testingshould be performedin accordance with Recognized Standards.
5.3
Flangeconnections
5.3.1 Flanges should be of the welded-neck,slipon or socket-welded type. However, socket-welded+ype flangesshould not be used in nominal size a b o v e5 0 m m . 5.3.2 Flangesshould comply with recognized standardsas to their type, manufacture and test. 28
5.5
Piping arrangements
clearances requiredfor damageprotection(see2.6)are maintained; such but distancesmay be reduced where damage to the pipe would not cause release cargoprovidedthat the clearance of requiredfor inspection purposes is maintained.
5.5.1 Cargo piping should be instal/ed not under deckbetween outthe boardside thecargo-containment andtheskin theshipun/ess of spaces of
5.5.2 Cargo piping locatedbelow the main deck may run from the tank it " ,/ serves and penetrate tank bulkheads boundaries or common to longitudinally or transversally adjacent cargotanks,ballast tanks,empty tanks,purp-roors or cargo pump-rooms providedthat insidethe tank it serves is fitted with a it stop valveoperablefrom the weatherdeck and providedcargocompatibility is assured the event of pipingfailure. an exception, in As where a cargo tank is adjacentto a cargo pump-room, stop valveoperablefrom the weather the deck may be situatedon the tank bulkheadon the cargo pump-roomside, provided an additionalvalve is fitted between the bulkheadvalve and the cargo pump. A totallyenclosedhydraulically operatedvalve locatedoutside the cargo tank may, however,be accepted,providedthat the valve is: : .f designed precludethe risk of leakage; to
.2 fitted on the bulkheadof the cargo tank which it serves; .3 suitablyprotectedagainstmechanical damage; '4 fitted at a distancefrom the sheil as requiredfor damage protection;and
.5 operablefrom the weatherdeck. 5.5.3 In any cargo pump-room where a pump serves more than one tank,a stop valve shouldbe fitted in the line to each tank.
29
IBC Code
5.5.4 Cargo piping installedin pipe tunnelsshould also comply with the o r e o u i r e m e n t s f 5 . 5 . 1 a n d 5 . 5 . 2 . P i p e t u n n e l s s h o u l d s a t i s f ya l l t a n k hazard and electrical locationand ventilation for requirements construction, in shouldbe assured the event of a piping Cargocompatibility requirements. exceptto the weather The tunnelshouldnot haveany other openings failure. deck and cargo pump-roomor pump-room. as shouldbe so arranged to throughbulkheads 5.5.5 Cargo piping passing at precludeexcessive stresses the bulkheadand should not utilize flanges b o l t e dt h r o u g ht h e b u l k h e a d .
5.6
Cargo-transfercontrolsystems
5.6.1 For the purpose of adequatelycontrollingthe cargo, cargotransfer should be providedwith: systems .l one stop valve capableof being manuallyoperatedon each tank if line, locatednear the tank penetration; an fillingand discharge the contentsof a individualdeepwellpump is used to discharge line of cargo tank, a stop valve is not requiredon the discharge that tank;
connection; .2 one stop valve at each cargo-hose .3 remote shutdown devices for all cargo pumps and similar equipment.
5.6.2 The controls necessaryduring transfer or transport of cargoes covered by the Code other than in cargo pump-roomswhich have been in dealt with elsewhere the Code should not be locatedbelow the weather deck. control requirements 5.6.3 For certain products,additionalcargo-transfer a r e s h o w ni n c o l u m no i n t h e t a b l eo f c h a p t e r1 7 .
5.7
Ship'scargo hoses
shouldbe compatible 5.7.1 Liquidand vapourhosesusedfor cargotransfer with the cargo and suitablefor the carSotemperature. pressure pumps of or 5.7.2 Hosessubiectto tank pressure the discharge designed for a bursting pressurenot less than 5 times the should be to the maximum pressure hose will be subjected during cargo transfer. 5.7.3 Each new type of cargo hose, complete with end fittings, should be maximum not prototype-tested a pressure lessthan five timesits specified to duringthis prototypetest shouldbe The working pressure. hosetemperature Hosesusedfor prototypetesting temperature. the intendedextremeservice before being placed in should not be used for cargo service.Thereafter, service, each new lengthof cargo hose producedshould be hydrostatically tested at ambient temperatureto a pressurenot less than 1.5 times its specifiedmaximum working pressurebut not more than two-fifthsof its w m d p T b u r s t i n g r e s s u r e .h e h o s es h o u l db e s t e n c i l l e o r o t h e r w i s e a r k e d i t h i t s 30
31
6 . 1 . 1 S t r u c t u r a lm a t e r i a l su s e d f o r t a n k c o n s t r u c t i o n ,t o g e t h e r w i t h piping,pumps,valves,vents and their jointing materials, associated should be suitableat the temperatureand pressure the cargo to be carriedin for accordance with recognizedstandards. Steel is assumedto be the normal materialof construction. 6.1.2 Where applicable,the following should be taken into account in selecting the materialof construction: .l notch ductilityat the operatingtemperature;
.2 corrosiveeffect of the cargo; .3 possibilityof hazardousreactionsbetween the cargo and the materialof construction; and
. 4 s u i t a b i l i to f l i n i n g s . y
6.2
Specialrequirementsfor materials
6.2.1 For certain products, special requirementsapply in respect of materials indicatedby symbolsin column m in the table of chapter 17, as s t i p u l a t e dn 6 . 2 . 2 , 6 . 2 . 3a n d 6 . 2 . 4 . i 6.2.2 The followingmaterials construction of shouldnot be usedfor tanks, pipelines, valves, fittingsand other equipmentwhich may come into contact .-/ with the productsor theirvapourwhere referredto in column m in the table o f c h a p t e r1 7 : N1 Aluminium, copper/ copper alloys, zinc, galvanizedsteel and mercury N2 Copper,copper alloys,zinc and galvanized steel N3 Aluminium,magnesium, zinc,galvanized steeland lithium N4 Copper and copper-bearing alloys N5 Aluminium,copper and alloysof either N6 Copper,silver,mercury,magnesium and other acetylide.forming metalsand their allovs
32
33
7.1
General
7.1.1 When provided, any cargo heating or cooling systemsshould be constructed,fitted and tested to the satisfaction the Administration. of Materials of used in the construction temperature-control systems shouldbe suitablefor use with the product intendedto be carried. 7.1.2 Heatingor cooling media shouldbe of a type approvedfor use with shouldbe givento the surface the specific cargo.Consideration temperature of heating coils or ducts to avoid dangerous reactionsfrom localized o v e r h e a t i n o r o v e r c o o l i n g f c a r g o .( S e ea l s o 1 5 . 1 3 . 6 . ) g o 7.1.3 Heatingor coolingsystems shouldbe providedwith valvesto isolate the systemfor each tank and to allow manualregulation flow. of 7.1.4 In any heatingor coolingsystem, meansshouldbe providedto ensure that, when in any condition other than empty, a higher pressurecan be maintained within the system headthat could be than the maximumpressure exertedby the cargo-tank contentson the system. \ 7.1.5 Means shouldbe providedfor measuring cargo temperature. the .l The means for measuringthe cargo temperatureshould be of restrictedor closed type, respectively, when a restrictedor closed gaugingdeviceis requiredfor individualsubstances, shown in as c o l u m ni i n t h e t a b l eo f c h a p t e r1 7 .
.2 A restricted temperature-measuring device is subject to the definition for a restrictedgauging device in 13.1.'1 e.g. a .2, portable thermometer lowered inside a gauge tube of the restrictedtype. .3 A closedtemperature-measuring deviceis subjectto the definition , f o r a c l o s e dg a u g i n gd e v i c e i n 1 3 . 1 . 1 . 3 e . g . a r e m o t e - r e a d i n g in thermometer which the sensoris installed the tank. of .4 When overheatingor overcoolingcould result in a dangerous which monitorsthe cargotemperature condition, alarmsystem an shouldbe provided.(Seealso operational requirements 16.6.) in 7 . 1 . 6 W h e n p r o d u c t sf o r w h i c h 1 5 . 1 2 , 1 5 . 1 2 . 1o r 1 5 . 1 2 . 3a r e l i s t e di n column o in the table of chapter17 are being heatedor cooled,the heating o r c o o l i n gm e d i u ms h o u l do p e r a t ei n a c i r c u i t : 34
.2 which is externalto the tank carrying toxic products; or .3 where the medium is sampledto checkfor the presence cargo of
before it is recirculated other services the ship or into the to of machineryspace.The samplingequipment should be located within the cargoareaand be capableof detectingthe presence of any toxic cargo being heated or cooled. Where this method is used,the coil returnshouldbe testednot only at the commencement of heatingor coolingof a toxic product,but alsoon the first occasion the coil is used subsequent to having carried an unheatedor uncooledtoxic cargo.
7.2 Additionalrequirements
For certain products,additionalrequirements containedin chapter 15 are s h o w ni n c o l u m no i n t h e t a b l eo f c h a o t e r1 7 .
35
Chapter 8
Cargo-tankventing and gas-freeing
arrangements
8.1 Application
8.1.1 This chapterappliesto shipsconstructed or after 'l lanuary1994. on 8.1.2 Ships constructedbefore 1 January1994 should comply with the requirements chapter8 of this Code which were in force prior to the said of date. 8.1.3 For the purposeof this regulation, the term "ship constructed"is as 'l definedin regulation 11.3.1 the 974 SOLASConvention amended. ll-1 of as 8.1.4 Shipsconstructed orafter 1 July 1986 butbefore 1)anuary'1994 on which fully comply with the requirements the Code applicable that time of at may be regarded complyingwith the requirements regulation as of ll2/59 of soLAS 74. 8.1.5 For shipsto which the Code applies, requirements this chapter the of s h o u l da p p l y i n l i e u o f r e g u l a t i o nl - 2 1 5 9 . 1 n d 5 9 . 2 o f t h e 1 9 7 4 S O L A S l a Convention, amended. as
8.2
Cargo-tankventing
8.2.1 All cargo tanks should be provided with a venting systemappropriate to the cargo being carriedand thesesystems should be independent the of air pipes and venting systems all other compartments the ship.Tank of of ventingsystems shouldbe designed as to minimizethe possibility cargo so of vapouraccumulating about the decks,enteringaccommodation, service and machinery spaces and controlstations and,in the caseof flammable vapours, enteringor collectingin spaces areascontaining or sources ignition. of Tank venting systems should be arrangedto prevententranceof water into the cargo tanks and, at the same time, vent outlets should direct the vapour discharge upwardsin the form of unimpededjets. 8.2.2 The ventingsystems should be connectedto the top of each cargo tank and as far as practicable cargovent linesshouldbe self-draining the back to the cargo tanks under all normal operationalconditionsof list and trim. Where it is necessary drain venting systemsabove the level of any to pressure/vacuum valve,cappedor pluggeddrain cocks shouldbe provided. 8.2.3 Provision should be made to ensurethat the liquid head in any tank does not exceed the design head of the tank. SuitablehighJevelalarms, overflowcontrolsystems spillvalves, or togetherwith gaugingand tank filling 36
ank venting and gas-freeingarrangements procedures, may be acceptedfor this purpose. where the meansof limiting cargo-tankoverpressure includes an automatic closing valve. the valve should comply with the appropriate provisions 15..1 of 9. 8'2'4 Tank venting systemsshourd be designedand operated so as to ensurethat neitherpressure nor vacuum createdin the cargo tanksduring loadingor unloading exceeds tank designparameters. main factorsto be The considered the sizingof a tank ventingsystemare as follows: in .l '2 designloadingand unloadingrate; gas evolutionduring roading: this shourdbe taken accountof by multiplying maximumloadingrate by a factor of at least.|.25; the density of the cargo vapour mixture; pressure lossin vent piping and acrossvalvesand fittings; pressure/vacuum settings reliefdevices. of
.3 .4 .5
8'2.5 Tank vent piping connected to cargo tanks of corrosion_resistant material, to tankswhich are rinedor coated to handrespeciar or cargoesas requiredby the code, shouldbe similarly lined or coated or conJucted of corrosion-resistant material. 8.2.0 The master shourd be provided with the maximum permissible loadingand unloadingratesfor each tank or group of tanks coniistentwith the designof the ventingsysrems.
37
IBC Code
.l at a height of not lessthan 6 m above the weather deck or above a raisedwalkway if fitted within 4 m of the raisedwalkway;
.2 at a distance at least10 m measured of horizontally from the nearest air intakeor openingto accommodation, serviceand machinery spaces and ignitionsources. 8.3.4 The vent outlet heightreferredto in 8.3.3.1may be reducedto 3 m above the deck or a raised walkway, as applicable,provided that highvelocityventingvalvesof an approvedtype, directingthe vapour/airmixture upwards in an unimpededjet with an exit velocityof at least 30 m/s, are fitred. 8.3.5 Controlled tank venting systems fitted to tanks to be used for cargoes havinga flashpoint exceeding not 60'C (closed-cup test)shouldbe provided with devices preventthe passage flameinto the cargotanks. to of The design, testingand locatingof the devicesshould comply with the requirements of the Administration, which shouldcontainat leastthe standards adopted by the Organization.8.3.6 In designing ventingsystems and in the selection devices prevent of to the passage flame for incorporationinto the tank venting system,due of attentionshould be paid to the possibility the blockageof thesesystems of and fittingsby, for example,the freezingof cargo vapour,polymerbuild-up, atmospheric dust or icing up in adverse weatherconditions. this contextit ln shouldbe noted that flame arresters and flame screens more susceotible are to blockage. Provisions shouldbe made suchthat the system and fittingsmay be inspected, operationally checked,cleanedor renewedas applicable. 8.3.7 Reference 8.3.1and 8.3.2to the useof shutoffvalvesin the venting in lines should be interpretedto extend to all other means of stoppage, includingspectacle blanksand blank flanges.
8.4
Venting requirements individualproductsare shown in column g, and for additionalrequirements column o in the table of chapter12. in
8.5
Cargotank gasfreeingt
8.5.1 The arrangements gas-freeing for cargo tanks usedfor cargoesother than thosefor which open ventingis permittedshouldbe suchas to minimize the hazards due to the dispersalof flammable or toxic vapours in the
Referenceis made to the Revisedstandardsfor the design,testing and locating of devicesto prevent the passageofflame into cargo tanks in tankers (MSC/-irc.323/Re;.1) (see page 2O71. I Reference is made to the Revised factors to be taken into consideration when designing cargo tank venting and gasfreeing arrangements(MSC/Circ. 450/Rev.l) (see page zzzj and to the Revisedstandardsfor the design,testing and locating ofdevices to preventlhe passage of flame into cargo tanks in tankers (MSC/Circ. 323/Rev.l) (see page 207). "
38
'wl Chapter 8 - Cargo-tankventing and gas_freeing arrangernents atmosphereand to flammabreor toxic vapour mixturesin a cargo tank. Accordingly, gas-freeing operations shourdbe carriedout suchthat ripour is inirially discharged: throughthe vent outletsspecified g.3.3 and g.3.4; in or ,2 throughoutletsat least2 m abovethe cargo_tank deck levelwith a verticareffruxverocityof at reast30 m/i maintain"J Jriing ,nu gas-freeing operation;or '3 i' .: " ,' throughoutrets reast m abovethe cargo-tank at 2 deck rever with a vertical efflux velocity of at least 20 m7s wtrich ur" frot".t"a ny suitabledevicesto preventthe passage flame. of .l
When the flammabre vapour concentration the outretshas been at reduced to 3oohof the lower flammabre rimit and, in the caseof a toxic product, the vapourconcentration doesnot present significant a hearth hazari, s"r_fr"",ns may thereafterbe continued at cargo_tanlideck level. 8'5.2 The outlets referredto in g.5.1.2 and g.5. r .3 may be fixed or portabre pipes. 8'5'3 ln designing gas-freeing a system contormitywith g.5.1, particurarry in , 'als.r'.:, in order to achievethe requiredexit verocities of a.s.r.2 and ou" consideration shouldbe given to the following: .l ' .2 .3 .4 materials construction system; of of time to gas-free; flow characteristics fans to be used; of the pressurelossescreated by ducting, piping, cargo_tank inlets and outlets;
.5 the pressure achievable the fan drivingmedium (e.g.water in or compressed air); .0 the densitiesof th.e cargo vapour/air mixtures for the range of cargoesto be carried.
39
Chapter9
Environmental control
9.1
General
9.1.1 Vapour spaceswithin cargo tanks and, in some cases/spacessurroundingcargo tanksmay requireto have specially controlledatmospneres. 9.1.2 Thereare four differenttypesof control for cargo tanks,as follows: .1 lnerting- by fillingthe cargo tank and associated piping systems a n d , w h e r e s p e c i f i e dn c h a p t e r1 5 , t h e s p a c e s u r r o u n d i n gh e i s t cargo tanks, with a gas or vapour which will not suppor{ c o m b u s t i o na n d w h i c h w i l l n o t r e a c t w i t h t h e c a r g o , a n d m a i n t a i n i nt h a t c o n d i t i o n . g .2 Padding- by fillingthe cargo tank and associated pipingsystems with a liquid,gas or vapour which separates cargo from the the a i r ,a n d m a i n t a i n i n t h a t c o n d i t i o n . g .3 Drying - by filling the cargo tank and associated piping systems with moisture-free or vapour with a dewpoint of -40"C or gas b e l o w a t a t m o s p h e r ip r e s s u r e ,n d m a i n t a i n i n t h a t c o n d i t i o n . c a g .4 Ventilation- forced or natural.
9.1.3 Where inertingor paddingof cargo tanksis required: .1 An adequatesupplyof inert gasfor use in fillingand discharging the cargo tanksshouldbe carriedor shouldbe manufactureo on board unlessa shore supply is available.In addition, sufficient inert gas shouldbe available n the ship to compensateor o f normal losses during transportation. .2 The inertgassystem board the ship shouldbe able to maintain on a pressureof at least 0.07 bar gauge within the containment systemat all times. In addition,the inert gas systemshould not raisethe cargotank pressure more than the tank,srelielvarve to setting. .3 Where padding is used, similararrangements supply of the for p a d d i n gm e d i u ms h o u l db e m a d e a s r e q u i r e d o r i n e r t g a s i n . 1 f and.2. .4 Means should be providedfor monitoringullagespaces containing a gas blanketto ensurethat the correct atmosphere being is maintained. 40
Chapter 9 - Environmental control 5 Inerting or padding arrangements both, where used with or flammable cargoes, shouldbe suchas to minimizethe creationof s t a t i ce l e c t r i c i t d u r i n gt h e a d m i s s i o n f t h e i n e r t i n g e d i u m . y o m
9.1.4 Where dryingis usedand dry nitrogenis usedas the medium,similar arrangements for supply of the drying agent should be made to those r e q u i r e d n 9 . 1 . 3 . h e r ed r y i n ga g e n t s r e u s e da s t h e d r y i n gm e d i u mo n a l l i W a air inletsto the tank,sufficient medium shouldbe carriedfor the durationof the voyage,takinginto consideration diurnaltemperature the rangeand the expectedhumidity.
9.2
41
10.1.1 The provisions thischapterare applicable shipscarrying of to cargoes which are inherently,or due to their reaction with other substances, flammableor corrosive the electrical to equipment, and shouldbe appliedin c o n j u n c t i o n i t h a p p l i c a b l e l e c t r i c arle q u i r e m e n to f p a r t D o f c h a p t e rl l - 1 w s of the 1983SOLAS mendments. a 10.1.2.1 installations Electrical should be such as to minimizethe risk of fire and explosionfrom flammableproducts.Electrical installations complying with this chapter should not be considereda source of ignition for the purposes 8.2.2.3,havingregardto 10.1 of .4. 10.1.2.2 Where the specificcargo is liableto damagethe materials normally used in electricalapparatus,due considerationshould be given to the particularcharacteristics the materials of chosenfor conductors, insulation, metal parts,etc. As far as necessary, thesecomponents shouldbe protected to preventcontactwith gasesor vapoursliableto be encountered. 10.1.3The Administration shouldtakeappropriate stepsto ensureuniformity s i n t h e i m p l e m e n t a t i oa n d t h e a p p l i c a t i o o f t h e p r o v i s i o no f t h i sc h a p t e r n n n i respectof electrical installations.* 10.1.4 Electricalequipment and wiring should not be installed in the hazardouslocations referred to in 10.2 unless essentialfor operational purposes, when the exceptions listedin 1O.2.3are permitted. 10.1.5 Where electricalequipment is installedin hazardouslocations,as permittedin thischapter,it shouldbe to the satisfaction the Administration of and certifiedby the relevent authorities recognized the Administration by for operationin the flammableatmosphere concerned, indicatedin column i as i n t h e t a b l eo f c h a o t e r1 7 . 10.1.6 Absenceof information temperature group in on classand apparatus column i in the table of chapter 1 7 means that data are not currently (NF) available,and this should not be confusedwith the non-flammable notationdescribing some substances. guidance, For indicationis given if the flashpoint a substance in excess 60'C (closed-cup of is of test).In the caseof heated cargo, carriageconditions might need to be established and the r e q u i r e m e n to f 1 0 . 2 . 2a p p l i e d . s
. Referenceis made to the recommendations published by the InternationalElectrotechnical Commission and in particularto Publication92-502, Electrical lnstallations Ships- Part 5O2: in Specialfeatures - Tankers.
42
' i "'
10.2.1The restrictions this sectiondo not precludethe use of intrinsically in s a f es y s t e m s n d c i r c u i t sn a l l h a z a r d o u so c a t i o n sn c l u d i n g a r g op i p i n g .l t a i l i c is particularly recommendedthat intrinsically safe systems and circuitsare used for measurement, monitoring,control and communication purposes. 19.2.2 Cargoes with a flashpoint exceeding 60'C (closed-cup test): .1 Cargotanksand cargopipingare the only hazardous locations for suchcargoes which haveno qualification column o in the table in of chapter17. Submerged cargo-pump motorsand their associated cablesmay, in exceptional circumstances a specificcargo for or for a clearlydefined range of cargoes,be permitted by the Administration, due consideration havingbeen given to the chemical and physical characteristics the products. of Arrangements shouldbe made to preventthe energizing motorsand cablesin of . flammablegas-air mixturesand to de-energize the motors and c a b l e s n t h e e v e n to f l o w l i q u i dl e v e l . u c ha s h u t d o w n h o u l db e i S s indicatedby an alarm at the cargo control station. .2 Where electrical equipmentis locatedin a cargopump-room, due consideration should be given to the use of types of apparatus which ensurethe absenceof arcs or sparksand hot spotsduring normal operation,or which are of a certifiedsafetype. .3 Where the cargo is heatedto within 15'C of its flashpoint value, the cargo pump-roomshouldbe considered a hazardous as area as well as areaswithin 3 m of openingsfrom tanks where the cargo is so heated,and within 3 m of the entranceor ventilation openings to cargo pump-rooms.Electrical equipment installed within theselocationsshouldbe of a certifiedsafetype. .4 Where the cargo is heatedabove its flashpoint value,the requirem e n t so f 1 0 . 2 . 3a r e a p p l i c a b l e . 10.2.3 For cargoeswith a flashpointnot exceeding60"C (closed-cup test) w i t h o u t q u a l i f i c a t i oin c o l u m no i n t h e t a b l eo f c h a p t e r1 7 , t h e h a z a r d o u s n locations givenbelow.In additionto intrinsically systems are safe and circuits, permitted in hazardouslocationsare the the only electricalinstallations following: .l Cargo tanksand cargo piping: No additionalelectrical equipmentis permitted. .2 Void spaces adjacentto, above or below integraltanks: .2.1 Through runs of cables.Such cables should be installedin joints.Expansion heavygaugesteelpipeswith gastight bends should not be fitted in such spaces.
43
IBC Code
.2.2 Electrical depth-sounding log devicesand impressed-current or c a t h o d i c p r o t e c t i o ns y s t e m a n o d e s o r e l e c t r o d e s T h e s e . devicesshould be housedin gastightenclosures; associated s a t c a b l e s h o u l db e o r o t e c t e d s r e f e r r e do i n 1 0 . 2 . 3 . 2 . 1 . Hold spaces containing independent cargo tanks: Throughrunsof cable without any additionalprotection. Lightingfittingswith pressurized enclosureor of the flame proof type.The lightingsystemshouldbe dividedbetweenat leasttwo branchcircuits. switches All and protectivedevices shouldinterruptall polesor phases and shouldbe locatedin a location. non-hazardous Electrical or and impressed-current depth-sounding log devices . c a t h o d i c p r o t e c t i o ns y s t e m a n o d e s o r e l e c t r o d e s T h e s e enclosures. devices shouldbe housedin gastight
.3 .3.1 .3.2
.3.3
.4 Cargo pump-rooms in and pump-rooms the cargo area: .4.1 Lightingfittingswith pressurized enclosures of the flameor proof type.The lightingsystemshouldbe dividedbetweenat least two branch circuits.All switches and all Drotective devicesshould interruptall poles or phasesand should be locatedin a non-hazardous location. Electrical motorsfor drivingcargo pumps and any associated auxiliary pumps. These should be separatedfrom these couplings, or spaces a gastightbulkheador deck. Flexible by alignment, shouldbe fitted to the other meansof maintaining shaftsbetween the driven equipmentand its motors,and in addition, glands should be provided in accordance with recognized standardswhere the shafts pass through the motorsshouldbe locatedin bulkheador deck.Suchelectrical ventilation. a compartmenthavingpositive-pressure generalalarm audibleindicator. Flameproof
.4.2
.4.3
.5 Zones on open deck, or semi-enclosed spaceson open deck, within 3 m of any cargo-tank outlet, gas or vapour outlet,cargopipe flange,cargo valve or entranceand ventilationopening to cargo pump-rooms; cargoareaon open deck over all cargotanks and cargo-tank holds, includingall ballasttanks and cofferdams within the cargo-tank block,to the full width of the ship,plus 3 m fore and aft and up to a heightof 2.4 m above the deck:
.5.1 .5.2
Equipmentof a certified safe type, adequate for open deck u5e; Throughruns of cables.
44
.6.2 .7
spaceshaving a direct opening into Enclosed semi-enclosed or locationreferredto above should have electrical any hazardous for complying with the requirements the space or installations z o n e i n t o w h i c h t h e o p e n i n gl e a d s .
10.3 Bonding
lndependentcargo tanks should be electricallybonded to the hull. All gasketedcargo-pipejoints and hose connectionsshould be electrically bonded.
45
11.1.1 The requirements for tankers in chapter ll-2 of the 1983 SOLAS amendmentsshould apply to ships covered by the Code, irrespective of tonnage,includingshipsof lessthan 500 tons grosstonnage,exceptthat: .f .2 .3 regulations 61, 62 and 63 should not apply; 60, regulation56.2, i.e. the requirements for location of the main cargo control station,need not apply; regulation as applicable cargoships, 4, to and regulation should 7 apply as they would apply to tankers 2,000 tons grosstonnage of and over;
s . 4 t h e p r o v i s i o no f 1 1 . 3 s h o u l da p p l yi n l i e u o f r e g u l a t i o n 1 ; a n d 6 s . 5 t h e p r o v i s i o no f | 1 . 2 s h o u l da p p l yi n l i e u o f r e g u l a t i o n 3 . 6 11.1.2 Notwithstanding provisions 1 1.'l.1, shipsengagedsolelyin the the of (entry NF in column i of the carriageof productswhich are non-flammable tableof minimumrequirements) need not comply with part D of chapterll-2 of the 1983 SOLASamendments, providedthat they comply with part C of that chapter,exceptthat regulation need not apply to suchshipsand 1 1.2 53 a n d 1 . 13 h e r e u n d e n e e d n o t a p p l y . . r 11.1.3 For shipsengagedsolely in the carriageof productswith flashpoint above 60'C (entry"yes" in column i of the table of minimum requirements), the requirements chapterll-2 of the 1983 SOLASamendments of may apply as specified regulation in ll-2/55.4in lieu of the provisions this chapter. of
ll.2
Cargo pump-rooms
11.2.1The cargo pumproom of any ship should be provided with a fixed g systemas follows: fire-extinguishin .1 a carbon dioxidesystemas specified regulation in ll2l5.1 and .2 o f t h e 1 9 8 3 S O L A S m e n d m e n t s . n o t i c es h o u l db e e x h i b i t e d t a A a the controls statingthat the systemis only to be used for fire. extinguishing and not for inertingpurposes, due to the electrostatic ignition hazard.The alarms referredto in regulationll2/ 'l 5 . 1 . 6o f t h e 9 8 3 S O L A S m e n d m e n ts h o u l db e s a f ef o r u s ei n a a flammable cargo vapour-air mixture. For the purpose of this requirement, extinguishing an systemshould be providedwhich 46
Chapter 11 - Fire protection and fire extinction would be suitable machinery for spaces. However,the amountof gas carriedshould be sufficient providea quantityof free gas to equal to 45"h of the grossvolume of the cargo pump-roomin all cases; or .2 a halogenatedhydrocarbonsystem as specified in regulation l l - 2 / 5 . 1a n d . 3 o f t h e 1 9 8 3 S O L A S m e n d m e n r s . n o t i c es h o u l d a A be exhibitedat the controlsstatingthat the systemis only to be used for fire-extinguishing not for inertingpurposes, and due to the electrostaticignition hazard. The alarms referred to in r e g u l a t i o nl - 2 / 5 . 1 . 6 f t h e 1 9 8 3 S O L A S m e n d m e n t s h o u l db e l o a safe for use in a flammablecargo vapour-air mixture. For the purposeof this requirement, extinguishing an systemshould be provided which would be suitable for machineryspaces but u t i l i z i n g h e f o l l o w i n gm i n i m u md e s i g nq u a n t i t i e sb a s e do n t h e t , grossvolume of the cargo pump-room:
h a l o n1 3 0 1 h a l o n1 2 1 1 halon 24O2
7"/"
J.J10
0.3 kglm3
11.2.2 Cargo pump-rooms shipswhich are dedicatedto the carriage a of of restrictednumber of cargoesshould be protected by an appropriatefireextinguishing systemapprovedby the Administration. I t.2.3 A fire-extinguishing systemconsisting eithera fixed pressure of waterspraysystemor a high-expansion foam systemcould be providedfor a cargo pump-roomif cargoes will be carriedwhich are not suitedto extinguishment by carbon dioxide or equivalentmedia. The lnternationalCertificateof Fitness the Carriageof DangerousChemicals Bulk should reflectthis for in c o n d i t i o n arl e q u i r e m e n t .
47
IBC Code for 11.3.3The arrangements providingfoam shouldbe capableof delivering the foam to the entire cargo tanksdeck area as well as into any cargo tank, t o f w h i c h i s a s s u m e do b e r u p t u r e d ' deck 11.3.4The deck foam system should be capable of simple and rapid located The main controlstationfor the systemshouldbe suitably operation. and readily spaces to adjacent the accommodation outsideof the cargoarea, in and op-erable the event of fires in the areasprotected. accessible the 11.3.5The rate of supply of foam solution should be not less than greatest the following: of where .1 2 llmin per square metre of the cargo tanks deck.are-a'. of the ship caigo tanks deck areameans the maximum breadth extentof the cargo tank spaces; timls the total longitudinal area of the .2 20 llmin per squaremetre of the horizontalsectional singletank havingthe largestsuch area; .3 10 //min per squaremetre of the area protectedby the.largest monitor,such aiea being entirelyforward of the monitor,but not less than 1,25O Umin. For ships of less than 4,000 tonnes deadweight,theminimumcapacityofthemonitorshouldbeto of the satisfaction the Administration' should be suppliedto ensureat least30 foam concentrate 11.3.6 Sufficient foam generationwhen using the highestof the solution rates minutes of 2 , n s t i p u l a t eid 1 1 . 3 . 5 . 11 1 . 3 - 5 . a n d 1 1 . 3 . 5 ' 3 ' 11.3.7 Foam from the fixed foam systemshould be suppliedby meansof in At monitorsand foam applicators. least 5o"/"of the foam rate required o . f s 1 1 . 3 . 5 . 2 h o u l db e d e l i v e r e dr o m e a c hm o n i t o r T h e c a p a c i t y f o 1 1. 3 . 5 . 1 r of any monitorshouldbe at least1o llmin of foam solutionper squaremetre being entirelyforwardof the detk areaprotectedby that monitor,sucharea of less monitor.Suchcapacityshouldbe not lessthan 1,25O llmin. For ships the tonnesdeadweight, minimumcapacityof the monitorshould than 4,000 of be to the satisfaction the Administration' 11.3.8The distance from the monitor to the farthest extremity of the protected area forward of that monitor should be not more than 75o/"ol the monitor throw in stillair conditions. 11.3.g A monitor and hose connectionfor a foam applicatorshould be spaces at both port and starboard the poop front or accommodation situated facingthe cargo area. Applicatorsshould be provided for flexibilityof action during fire 11.3.10 The capafrom the monitors. and to coverareasscreened fightingoperations .iiy ofiny applicatorshould be not lessthan 4oo llmin and the applicator shouldbe not lessthan 15 m. The numberof foam throw in siillair conditions provided should be not less than four. The number and disafpti."to* positionof ioam main outletsshould be such that foam from at leasttwo can be directedto any part of the cargo tanksdeck area' applicators
11.4 Specialrequirements
Fireextinguishing media determined to be effectivefor certain products are l i s t e di n c o l u m n/ i n t h e t a b l eo f c h a p t e r1 7 .
49
l2.l
which containcarSo12.1.1Cargo pumprooms and other enclosedspaces o i s p a c e sn w h i c h w o r k i s p e r f o r m e d n t h e a e handling quipment nd similar capableof being systems, ventilation with mechanical l"rgo ,toul'a be fitted controlledfrom outsidesuch spaces' should be made to ventilatesuch spacesprior to entering 12.1.2Provision and operatingthe equipmentand a warningnoticerequirifre compartment should be placedoutsidethe compartment' ing the use of suchventilation arranged to 12.1.3Mechanical ventilation inlets and outlets should be throughthe spaceto avoid the accumulation air ensuresufficient movement their vapour of toxic or flammablevapours or both (taking into account providea safeworking environoxygento and to ensuresufficient densities)
ment,butinnocaseshou|dtheventilationsystemhaveacapacityof|es tn"n:ochangesofairperhour,baseduponthetota|vo|umeofthespace ventilationratesfor carSopump-roomsare For certainproducts,increased i p r e s c r i b e dn 1 5 . 1 7 12'1.4Venti|ationsystemsshou|dbepermanentandshou|dnorma||y from aboveand below the floor platesshould type. Extraction the extraction pumps,the ventilation In be possible. rooms housingmotors driving carSo type' shouldbe of the positive-pressure area should 12.1.5 Ventilationexhaustducts from spaceswithin the carSo directionfrom at upwardsin locations least10 m in the horizontal discharge serviceand machinery intakesand openingsto accommodation, ventilation outsidethe cargo area' other spaces and and control stations spaces the 12.1.6 Ventilation intakes should be so arranged as to minimize from any ventilationdischarge porriritity of recyclinghazardousvapours opening.
Chapter 12 - Mechanical ventilation in the cargo area 12.1.7 Ventilation ducts shouldnot be led throughaccommodation, service and machineryspaces other similarspaces. or 12.1.8 Electric motors drivingfans should be placed outsidethe ventilation ducts if the carriageof flammableproductsis intended. Ventilation fans and fan ducts,in way of fansonly, for hazardous locations referredto in chaoter 1 0 s h o u l db e o f n o n - s p a r k i nc o n s t r u c t i o n ,e f i n e da s : g d .l impellersor housing of nonmetallicconstruction,due regard being paid to the elimination staticelectricity; of
.2 impellers and housingof nonferrous materials; .3 impellers and housingof austenitic stainless steel;and .4 ferrousimpellers and housingwith not lessthan 13 mm designtip ctearance. Any combination of an aluminium or magnesiumalloy fixed or rotating component and a ferrous fixed or rotating component, regardless tip of clearance, considered sparkinghazardand should not be used in these is a places. l2.l.g Sufficient sparepartsshouldbe carriedfor each type of fan on board requiredby this chapter. 1 2 . 1 . 1P r o t e c t i o n c r e e n s f n o t m o r e t h a n ' l 3 m m s q u a r e e s hs h o u l db e 0 s o m fitted in outsideopeningsof ventilation ducts.
s1
Chapter13 lnstrumentation
13.1 Gauging
one of the following types ot 13.1.1 Cargo tanks should be fitted with gaugingdevices: in:le^.:1*: and .1 Open device which makesuse of an.goenine vapour' An exampleof may exposethe gaugerto the cargo or its t h i si s t h e u l l a g eo P e n i n g ' tank and which' when in .2 Restricteddevice- which penetratesthe quantity of.cargo vapour "'.j'0"]1..::^b,: use, permits u itutt in use' the devtce ts expoied to the atmosphere'When not that no dangerous .otptut"tv .ioi"a' The designshould ensure can take placein opening "i.ub" of iunt-.ont"nts (liquidor spray) the device. .3 ' but which is part of a closed device- which penetratesthe tank, keeps tank contents from being released' closed syste; "; electronicprobe' magnetic are Examples the float-typesystems' an tight-gl"st'Alternatively' indirectdevice probe and pt.i"t*a p"""t*ie tlie tank shelland which is independent which does ""i of cargo' pipe are of the tank t"v n" used' Examples weighing flow meter.
of the equipmentrequired 13.1.2 Cauging devicesshould be independent l u n d e r1 5 . '9 . gaugingshouldbe allowedonly where: 13.1.3 Open gaugingand restricted .l open ventingis allowed by the Code; or
beforethe gaugeis tank pressure .2 meansare providedfor relieving oPeratecl. productsare shown in columni in the for 13.1.4Typesof gauging individual 1 t a b l eo f c h a P t e r 7 .
13.2 VaPourdetection
products or both should be 13.2.1 Ships carrying toxic or flammable for for and calibrated testing equippedwith at t"urt t*o in'trumentsdesigned are not capableof testing vapoursin lulstion' lf such.instruments the specific forbothtoxicconcentrationsandflammab|econcentrations,thentw shouldbe provided' setsof instruments *d;;
52
Chaoter13 - Instrumentation
instrumentsmay be portable or fixed. lf a fixed 13.2.2 Vapour-detection i t i a s y s t e m s i n s t a l l e d , t l e a s to n e p o r t a b l e n s t r u m e ns h o u l db e p r o v i d e d . equipment is not availablefor some 13.2.3When toxic-vapour-detection i p r o d u c t s h i c h r e q u i r e u c hd e t e c t i o na s i n d i c a t e dn c o l u m nk i n t h e t a b l e , w s may exemptthe shipfrom the requirement, of chapter17, the Administration Certificateof provided an appropriateentry is made on the International s n W o s F i t n e sfs r t h e C a r r i a g e f D a n g e r o u C h e m i c a l is B u l k . h e n g r a n t i n g u c h o s a n e x e m p t i o n ,t h e A d m i n i s t r a t i o n h o u l d r e c o g n i z et h e n e c e s s i t yf o r additional breathing-airsupply and an entry should be made on the of Chemicals for of lnternational Certificate Fitness the Carriage Dangerous of in Bulk drawingattentionto the provisions 14.2.4 and 16.4.2.2. for requirements individualproductsare shown in 13.2.4 Vapour-detection k i n t h e t a b l eo f c h a p t e r1 7 . column
53
14.l ProtectiveequiPment
who are engagedin loadingand r4.t.r For rhe protectionof crew members protective tf* in'p should have.on board suitable operations, discharging special gloves with long sleeves' "of equipment consistingof large aprons' material,and tight-fitting chemical-resistani suitablefootwear, .ou"ruli, clothing and equipment or. iu." ,ni"ta' or both' The protective ;;; is unprotected' body shouldcover all skin sotfrat no part of ihe should be kept in easily t4.1.2 Work clothes and protective equipment
with the exception *iinin "..otmodation spaces/ a h a sn o t b e e nu s e ds i n c eu n d e r g o i n g t h o r o u g h t m e n t a n d e q u i p m e nw h i c h storagerooms may' however'approve The Administration li"uning process. segregated spacesif adequately within accommodation for such equipment dining rooms' bathrooms' passageways' from living spacessuch as cabins, etc. equipment should be 14.1.3 Protective entaildangerto Personnel' used in any operationwhich may
14.2 SafetYequiPment
in 15'12;1ot l5'].? ? is.listed for carryingcargoes which 15'1.2' 14.2.1Ships but not 17 shoutdhave on board sufficient in the table JZnup,", ;;t"nl;; personnel eachpermitting than threecomprei" i"t, of safetyequipment, ress therefor at least20 min' unj p"'fott work ."tp"tit""t to entera gas-filled l b r e g u l a t i o nl - 2 1 1 7 t s h o u l db e i n a d d i t i o n o t h a t r e q u i r e d y S u c he q u i p m e n t a of the 1983SOLAS mendments' should consistof: 14.2.2 Onecomplete set of safetyequipment apparatus (not using stored air-breathinS .l one self-contained oxYgen); .2 goggles; protective clothing, boots, gloves and tight-fitting
54
'
.2 an equivalentquantity of spare bottled air in lieu of the lowpressure line. air f 4.2.5 At leastone set of safetyequipmentas requiredby 14.2.2shouldbe kept in a suitable clearlymarkedlockerin a readilyaccessible placenearthe cargo pump-room. The other setsof safetyequipmentshouldalsobe kept in suitable, places. clearlymarked,easilyaccessible 14.2.6The breathing apparatus shouldbe inspected leastonce a month by at a responsible officer,and the inspection recordedin the ship'slog-book. The equipmentshouldbe inspected and testedby an expertat leastonce a year. 14.2.7A stretcher which is suitablefor hoistingan injured personup from spaces suchas the cargopump-roomshouldbe placedin a readilyaccessible location. 14.2.8 Shipsintendedfor the carriage certaincargoes of shouldbe provided with suitablerespiratory and eye protectionsufficientfor every person on board for emergency escapepurposes, subjectto the following: .l filter-type protectionis unacceptable; respiratory
I
55
.1;1.ii':l.l,l
IBC Code apparatus shouldhavenormallyat leasta .2 self-contained breathing o o duration f service f 15 min; protectionshould not be used for .3 emergency escaperespiratory purposes and shouldbe markedto fire-fighting cargo-handling or lhal effect. Individualcargoes to which the provisionsof this paragraphapply are i n d i c a t e dn c o l u m nn i n t h e t a b l eo f c h a p t e r1 7 . i equipment, including 14.2.9The ship shouldhaveon board medicalfirst-aid equipmentand antidotes cargoescarried.* for oxygenresuscitation 1 4 . 2 . 1S u i t a b l y a r k e d e c o n t a m i n a t i o n o w e r s n d a n e y e w a s h h o u l db e 0 m d sh a s locations. The showers and eyewashshould available deck in convenient on i b e o o e r a b l e n a l l a m b i e n tc o n d i t i o n s .
Reference is made Io the Medical Fist Aid Cuide for lJse in Accidens lnvolving Dangerous Coods (MFAC),which includesthe MFAC numbers of products covered by the Code and the emergency procedures to be applied in the event of an incident. MFAC numbers related to .18 p r o d u c t sl i s t e d i n c h a p t e r s1 7 a n d of the IBC Code are given in the Indexof Dangerous ( s e ep a g e 1 5 7 ) . C h e m i c a l s a r r i e di n B u l k C
56
l5.l
Acetonecyanohydrin and lactonitrile solution(80% or less)shouldbe stabilized with an inorganic acid to prevent decomposition.A certificateof stabilization should be provided by the manufacturer, and kept on boaro, specifying: .t n a m ea n d a m o u n to f s t a b i l i z ea d d e d ; r
.2 date stabilizer was added and durationof effectiveness; .3 any temperaturelimitationsqualifyingthe stabilizer's effective lifetime; .4 the action to be taken should the length of voyage exceed the effectivelifetimeof the stabilizer.
57
IBC Code 140'C. High-temperature alarms 145'C and 150'C and a low-temperature at W a l a r m a t 1 2 5 ' C s h o u l db e p r o v i d e d . h e r e t h e t e m p e r a t u r e f t h e h e a t o e x c h a n g i n gm e d i u m e x c e e d s 1 6 0 ' C , a n a l a r m s h o u l d a l s o b e g i v e n . Temperature alarmsand controlsshouldbe locatedon the navigating bridge. 15.2.5 lf the bulk mean cargo temperature reaches145"C, a cargo sample should be diluted with ten oarts of distilledor demineralized water to one part of cargo by weight and the pH should be determinedby meansof a narrow-range indicatorpaperor stick.Acidity measurements shouldthen be takenevery24 hours.lf the pH is found to be below 4.2, ammoniagasshould be injectedinto the cargo until the pH of 5.0 is reached. 15.2.6 A fixed installation shouldbe providedto injectammoniagasinto the bridge. cargo.Controlsfor this systemshould be locatedon the navigation p , F o rt h i sp u r p o s e3 0 0 k g o f a m m o n i a e r 1 , 0 0 0t o n n e so f a m m o n i u mn i t r a t e s o l u t i o n h o u l db e a v a i l a b l e n b o a r d . s o 15.2.7 Cargo pumps should be of the centrifugaldeepwell type or of the centrifugal type with water-flushed seals. 15.2.8 Vent pipingshouldbe fitted with approvedweatherhoods prevent to clogging. Such weatherhoodsshould be accessiblefor inspection and cleaning. 15.2.9 Hot work on tanks,pipingand equipmentwhich havebeen in contact with ammonium nitrate solution should only be done after all traces of ammonium nitratehave been removed,insideas well as outside.
59
IBC Code 15.5.4 Cargotanksshouldbe separated cofferdams from oil fuel tanksor by a n y o t h e r s p a c ec o n t a i n i n gl a m m a b l e r c o m b u s t i b l e a t e r i a l s . f o m 15.5.5Tanksintendedfor the carriageof hydrogenperoxideshouldnot be used for seawater ballast. 15.5.6 Temperature sensors shouldbe installed the top and bottom of the at t a n k . R e m o t et e m p e r a t u r e e a d o u t s n d c o n t i n u o u s o n i t o r i n g h o u l db e r m a s locatedon the navigating bridge.lf the temperature the tanksrisesabove in 3 5 ' C , v i s i b l ea n d a u d i b l ea l a r m ss h o u l d b e a c t i v a t e do n t h e n a v i g a t i n g bridge. Fixedoxygenmonitors(or gas-sampling lines)should be providedin void spacesadjacentto tanks to detect leakageof the cargo into these spaces.Remote readouts,continuousmonitoring(if gas-sampling lines are u s e d ,i n t e r m i t t e ns a m p l i n g s s a t i s f a c t o r y )n d v i s i b l ea n d a u d i b l ea l a r m s t i a similarto those for the temperaturesensors should also be locatedon the navigating bridge.The visibleand audiblealarmsshould be activatedif the oxygen concentration these void spacesexceeds3O"/"by volume. Two in portableoxygenmonitorsshouldalso be available back-upsystems. as 15.5.8 As a safeguard againstuncontrolled decomposition, cargo-jettisona ing systemshouldbe installed discharge cargo overboard. to the The cargo shouldbe jettisoned the temperature of the cargoexceeds rateof 2'C if rise a per hour over a 5-hourperiod or when the temperature the tank exceeds in 40'c. 1 5 . 5 . 9C a r g o t a n k v e n t i n g s y s t e m ss h o u l d h a v e p r e s s u r e / v a c u u m - r e l i e f valvesfor normal controlledventing,and rupture discsor a similardevice for emergencyventing, should tank pressurerise rapidly as a result of uncontrolleddecomposition. Rupturediscsshould be sized on the basisof tank designpressure/ tank size and anticipated decomposition rate. 15.5.10 fixed water-spraysystem should be provided for diluting and A washingaway any concentrated hydrogenperoxidesolutionspilledon deck. The areas covered by the water-spray should include the manifold/hose connectionsand the tank tops of those tanks designatedfor carrying hydrogenperoxide solutions. The minimum applicationrate should satisfy the followingcriteria: The product shouldbe dilutedfrom the originalconcentration to 35% by weight within 5 minutesof the spill. i .2 The rate and estimatedsize of the spill should be based upon m a x i m u m a n t i c i p a t e dl o a d i n g a n d d i s c h a r g er a t e s , t h e t i m e requiredto stop flow of cargo in the event of tank overfillor a piping/hose failure, and the time necessary beginapplication to of ' dilutionwater with actuationat the careo control locationor on the navigating bridge. .l p 1 5 . 5 . 1H y d r o g e n e r o x i d e o l u t i o n s h o u l db e s t a b i l i z e do p r e v e n t e c o m 1 s t d position.A certificateof stabilization should be provided by the manufacturer, and kept on board,specifying: '|5.5.7
60
.2 date stabilizer was added and durationof effectiveness; .3 any temperaturelimitationsqualifyingthe stabilizer's effective
lifetime; .4 the action to be taken should the length of voyage exceedthe effectivelifetimeof the stabilizer.
1 5 . 5 . 1O n l y t h o s e h y d r o g e np e r o x i d es o l u t i o n s h i c h h a v e a m a x i m u m 2 w rate of 1"h per year at 25'C should be carried.Certification decomposition from the shipperthat the productmeetsthisstandard shouldbe presented to representative the manufacturer the masterand kept on board.A technical of should be on board to monitor the transfer ooerations and have the to of capability test the stability the hydrogenperoxide.He shouldcertifyto the masterthat the cargo has been loaded in a stablecondition. 15.5.13 Protectiveclothing that is resistant hydrogenperoxide solutions to should be provided for each crew member involved in cargo-transfer P o p e r a t i o n s . r o t e c t i v ec l o t h i n g s h o u l d i n c l u d e n o n f l a m m a b l e o v e r a l l s , c suitablegloves,boots and eye protection. but Hydrogen peroxide solutionsover Bo/o not over 60o/"by weight 1 5 . 5 . 1T h e s h i p ' s s h e l l p l a t i n gs h o u l d n o t f o r m a n y b o u n d a r i e s f t a n k s 4 o c o n t a i n i n gh i sp r o d u c t . t 1 5 . 5 . 1H y d r o g e n p e r o x i d e s h o u l d b e c a r r i e d i n t a n k s t h o r o u g h l ya n d 5 effectivelycleaned of all traces of previouscargoesand their vapours or passivation Procedures inspection, for cleaning, and loadingof tanks ballast. with MSC/Circ.394 (see page 225). A certificate should be in accordance i s h o u l db e o n b o a r dt h e v e s s eiln d i c a t i n gh a t t h e p r o c e d u r e sn t h e c i r c u l a r t have been followed. The passivation requirementmay be waived by an Administration domesticshipmentsof short duration.Particular for care in this respectis essential ensurethe safecarriageof hydrogenperoxide: to .t When hydrogenperoxideis carried no other cargoesshould be carried imultaneouslv. s
.2 Tankswhich have contained hydrogen peroxide may be used for other cargoesafter cleaningin accordance with the procedures o u t l i n e di n M S C / C i r c 3 9 4 . . . 3 C o n s i d e r a t i o in d e s i g ns h o u l d p r o v i d em i n i m u m i n t e r n a lt a n k n s t r u c t u r e ,f r e e d r a i n i n g , n o e n t r a p m e n ta n d e a s e o f v i s u a l inspection. 1 5 . 5 . 1C a r g o t a n k s a n d a s s o c i a t e de q u i p m e n t s h o u l d b e e i t h e r p u r e 6 aluminium (99.5%) or solid stainless steel of types suitablefor use with ( p A h y d r o g e n e r o x i d e e . 9 . O 4 ,3 0 4 L ,3 1 6 ,3 1 6 L , 3 1 T i ) . l u m i n i u m h o u l dn o t 3 6 s m s b e u s e df o r p i p i n go n d e c k .A l l n o n m e t a l l i c a t e r i a l o f c o n s t r u c t i o f o r t h e n
61
IBC Code containmentsystemshould neitherbe attackedby hydrogenperoxidenor contributeto its decomposition. \ 15.5.17 Cargotanksshouldbe separated a cofferdam by from fuel oil tanksor any other spacecontainingmaterials incompatible with hydrogenperoxide. 15.5.18 Temperature sensors shouldbe installed the top and bottom of the at tank. Remotetemperaturereadoutsand continuousmonitoringshould be locatedon the navigating bridge.lf the temperature the tank risesabove in 3 5 ' C , v i s i b l e n d a u d i b l ea l a r m s h o u l da c t i v a t e n t h e n a v i g a t i n b r i d g e . a g s o 15.5.19 Fixedoxygenmonitors(or gas-sampling lines)shouldbe providedin void spacesadjacent to tanks to detect leakageof the cargo into these s p a c e sT h e e n h a n c e m e no f f l a m m a b i l i t b y o x y g e ne n r i c h m e ns h o u l db e . t y t ( r e c o g n i z e dR e m o t er e a d o u t sc o n t i n u o u s o n i t o r i n g i f g a s - s a m p l i n ig e s . , m l n are used,intermittent is sampling satisfactory) visibleand audiblealarms and similarto those for the temDerature sensors should also be locatedon the navigatingbridge. The visible and audible alarms should activate if the oxygen concentration these void spacesexceeds3O"hby volume. Two in portableoxygenmonitorsshouldalso be available back-upsystems. as 15.5.20 a safeguard As againstuncontrolled decomposition, cargo-jettisona ing systemshould be installed discharge to the cargo overboard. The cargo if shouldbe jettisoned the temperature of the cargoexceeds rateof 2'C rise a p e r h o u r o v e r a S - h o u r e r i o do r w h e n t h e t e m p e r a t u r en t h e t a n k e x c e e d s p i 40"c. 15.5.21 Cargo-tankventing systemswith filtration should have pressure/ vacuum-reliefvalves for normal controlled venting, and a device for emergency venting, should tank pressurerise rapidly as a result of an u n c o n t r o l l e d e c o m p o s i t i o na t e , a s s t i p u l a t e d n 1 5 . 5 . 2 0 . h e s ev e n t i n g d r i T s y s t e m s h o u l db e d e s i g n e dn s u c ha m a n n e r h a t t h e r ei s n o i n t r o d u c t i o n f i t o seawaterinto the cargo tank even under heavy sea conditions.Emergency v e n t i n gs h o u l db e s i z e do n t h e b a s i s f t a n k d e s i g np r e s s u r e n d t a n k s i z e . o a 15.5.22 fixed water-spraysystem should be provided for diluting and A washingaway any concentrated solutionspilledon deck.The areascovered by the water-spray should include the manifold/hose connectionsand the tank tops of those tanks designated the carriageof hydrogenperoxide for s o l u t i o n s . h e m i n i m u ma p p l i c a t i o na t es h o u l ds a t i s f yh e f o l l o w i n g r i t e r i a : T r t c .1 The product shouldbe dilutedfrom the originalconcentration to 3 5 % b y w e i g h tw i t h i n 5 m i n u t e s f t h e s p i l l . o .2 The rate and estimatedsize of the spill should be based upon maximum anticipated loading and discharge rates, the time requiredto stop flow of the cargoin the eventof tank overfillor a piping/hose failure, and the time necessary beginapplication to of dilutionwater with actuationat the cargo control locationor on the navigatinbridge. g
62
Chapter15 - Specialrequirements
A to 15.5.23 Hydrogenperoxideshouldbe stabilized preventdecomposition. and of shouldbe providedbv the manufacturer, kept certificate stabilization on board,specifying: .1 added; name and amount of stabilizer
was added and durationof effectiveness; .2 date stabilizer effective .3 any temperaturelimitationsqualifyingthe stabilizer's lifetime; .4 the action to be taken should the product become unstable d u r i n gt h e v o y a g e . 15.5.24 Only those hydrogen peroxide solutionswhich have a maximum . d e c o m p o s i t i o r a t e o f l " h p e r y e a r a t 2 5 ' C s h o u l db e c a r r i e d C e r t i f i c a t i o n n shouldbe presented to from the shipperthat the productmeetsthisstandard representative the manufacturer of the masterand kept on board.A technical should be on board to monitor the transfer operations and have the to of capability test the stability the hydrogenperoxide.He shouldcertifyto the masterthat the cargo has been loaded in a stablecondition. to clothingthat is resistant hydrogenperoxideshould be 15.5.25 Protective provided for each crew member involved in cargo{ransferoperations. that are nonflammable, suitable Protectirre clothingshouldincludecoveralls gloves,boots and eye protection. 15.5.26 During transfer of hydrogen peroxide the related piping system of from all other systems. Cargohosesusedfor transfer shouldbe separated hydrogen peroxide should be marked "FOR HYDROCEN PEROXIDE T R A N S F EO N L Y " . R
63
IBC Code
water and testedto a minimumequivalent 15.7.2Tanksshouldbe designed h e a d o f 2 . 4 m a b o v e t n e t o p " o f t h e t a n k , u n d e r d e s i g n e d | o a d i n g cand d i t i o n on. of loading account tne aebtn, relativedensityand method ;";;;;".t of discharge the PhosPhorus'
15'7.3Tanksshou|dbesodesignedastominimizetheinterfacia|ar and its water pad' b"i*""n the liquid phosphorus abovethe water 15.7.4 A minimumullagespaceof 1% shouldbe maintained by ventilated naturally pad.The ullagespace,fioria be filledwith inert 8asor but at least6 m above heights at terminating different i*o .o*l"d siandpipes top' the deck and at least2 m above the pump-house snouldbe at the top of cargotanks'and fittingsand ioints 15.7.5 All openings pentoxide' to resistant phosphorus attachedthereto shouldbe of materiais 60'C' not exceeding shouldbe loaded at a temperature 15.7.6 Phosphorus l5.T.TTankheatingarrangementsshou|dbeexterna|totanksandha of temperature the methodof temperiturecontrolto ensurethat the suitable alarm should be phosphorusoo", not !"ceed 60"C' A high-temperature fitted. should be Administration 15.7.8 A water drench systemacceptableto the the surrounding tanks.The systemshouldoperate in installed all void ,p"."i phosphorus' in automatically the event of an escapeof
be providedwith effective 15.7.9 Void spacesreferredto in 15'7'8 should meansofmechanicaluentitationwhichshouIdbecapab|eofbeingseale quickly in an emergencY' governed by a "*hi.h,'ln Loading and dischargeof phosphorusshould be 15.7.10 to incorporatinghigh-level addition i""ii"f ,vrt",i on tne snip is possibleand that such alarms,should "nrurJ ai,;i "; overflow of tanks from eithershipor shore' quicklyin an emergency can be stopped operations to be connected a a Duringcargotransfer, water hoseo.ndeck should 15.7.1,| so that any spillage *ui", ,rppty""na ["ptJto*ing throughoutth/operation may be washeddown with water immediately' of phospl'rorus
15.8 Propyleneoxide and mixturesof ethylene oxide with an ethyleneoxide oxide/propylene content of not more than 30% by weight
of under the provisions this sectionshould be t5.8.1 Productstransported acetylene-free. 15.8.2 Unlesscargo tanks are properlycleaned,these productsshould not be carried in tanks which have contained as one of the three previous polymerization, such as: cargoesany productsknown to catalyse .t n , m i n e r a a c i d s( e . 9 .s u l p h u r i ch y d r o c h l o r i c ,i t r i c ) ; l
(e.g.formic, acetic); .2 carboxylic acidsand anhydrides acids(e.g.chloracetic); .3 halogenated carboxylic a . 4 s u l p h o n i c c i d s( e . 9 .b e n z e n e s u l p h o n i c ) ; hydroxide); .5 causticalkalis(e.g.sodium hydroxide,potassium .6 ammoniaand ammoniasolutions; a . 7 a m i n e s n d a m i n es o l u t i o n s ; .8 oxidizing ubstances. s ,|5.8.3 Beforeloading, to and effectively cleaned, tanksshouldbe thoroughly pipework, remove all tracesof previouscargoesfrom tanksand associated except where the immediatelyprior cargo has been propylene oxide or Particular care shouldbe taken in oxide mixtures. ethyleneoxide/propylene steel. the caseof ammoniain tanksmade of steelother than stainless of 15.8.4 In all cases,the effectiveness cleaningproceduresfor tanks and to pipeworkshouldbe checkedby suitabletestingor inspection, associated ascertainthat no traces of acidic or alkalinematerialsremain that might of situationin the presence theseproducts. createa hazardous prior to each initialloadingof 15.8.5 Tanksshouldbe enteredand inspected heavy rust deposits these productsto ensurefreedom from contamination, service for When cargotanksare in continuous defects. and visiblestructural should be performedat intervalsof not these products,such inspections more than two vears. of 15.8.6Tanksfor the carriage theseproductsshouldbe of steelor stainless steelconstruction. 15.8.7Tanks for the carriage of these products may be used for other pipeworksystems by of afterthoroughcleaning tanksand associated cargoes dq, washing r purging. o equipmentshould be of a fittingsand accessory 15.8.8 All valves,flanges, of for type suitable usewith the productsand shouldbe constructed steelor Discsor disc faces, with recognizedstandards. steelin accordance stainless
65
IBC Code steel of stainless seatsand other wearing parts of valvesshould be made n c o n t a i n i n g o t l e s st h a n 1 1 % c h r o m i u m ' which do not reactwith, of shouldbe constructed materials 15.g.g Gaskets temperatureof these products and dissolvein, or |ower the autoignition mechanicalbehaviour'The aclequate and possess which are fire-resistant (PTFE), or to the cargo should.bepolytetrafluoroethylene ;;;i;;";;"r;nted wound Spirally inertness. givinga similardeireu of safetyby their materials polymer, may be or ,tuint"r, ,i""t,"*ltn a filler of PTFE similarfluorinated accePted. which doesnot if and packing, used,shouldbe of a material Insulation 15.8.10 temperatureof these react with, dissolve in, or lower the autoignition products. for found unsatisfactory gaskets, are The 15.g.11 followingmaterials generally uses in containmentsystemsfor these products and packing and similar iuoutai"quite testingbefore being approvedby the Administration: .lNeopreneornatura|rubber,ifitcomesintocontactwiththe products. or .2 Asbestos' bindersusedwith asbestos' .3Materia|scontainingoxidesofmagnesium,Suchasminera|wool
15's.l2ThreadedjointsshouldnotbepermittedinthecargoIiquidan v a p o u rl i n e s .
15.8'l3Fi|linganddischargepipingshou|dextendtowithinl00mmofth b o t t o m o f t h e t a n k o r a n Ys u m PP i t ' theseproductsshould for system a tank containing The 15.8.14.1 containment connection' have a valvedvapour-return ,|5.8.t4.2 productsshould be loaded and discharged such a manner in The does not occur' lf vapour return to ventingof the tanksto atmosphere that systemconnectedto a shore is usld during tank loading,the vapour-return product should be independentof all other containmentsystem for the c o n t a i n m e ns y s t e m s ' t in the operations, pressure the cargotank must be Duringdischarge 15.8.14.3 above 0.07 bar gauge' maintained only by deepwellpump:' hydraulically The 15.8.15 cargo may be discharged cargo pump displacement'.Each pumps, or inert-gas oj"t"t"a subm"erged' if not heat significantly to'ensurethat the product does should be arranged or otherwiseblocked' in" Jit.f'utg" lirie from the pump is shut off
of Tanks carryingthese products should be vented independently 15.8.16 tankscarryingotherproducts.FacilitiesshouldbeprovidedforsampIing tank contenti without openingthe tank to atmosphere' marked Cargo hosesused for transferof these productsshould be 15.8.17 " F O R A L K Y L E NO X I D ET R A N S F EO N L Y " . R E
Chapter I5 - Specialrequirements
Cargo tanks,void spacesand other enclosedspacesadjacentto an 15.8.18 integralgravitycargo tank carryingpropyleneoxide shouldeither containa compatible cargo (those cargoes specified in 15.8.2 are examples of or incompatible) be inertedby injectionof a suitable considered subsiances inert gas. Any hold space in which an independentcargo tank is located should be inerted.Such inerted spacesand tanks should be monitoredfor these productsand oxygen.The oxygencontent of these spacesshould be equipmentis satisfactory. Portablesampling maintainedbelow 2"/o. n 1 5 . 8 . 1I9 n o c a s es h o u l da i r b e a l l o w e dt o e n t e rt h e c a r g op u m p o r p i p i n g systemwhile theseproductsare containedwithin the system. in the shore-lines, pressure liquid and vapour Prior to disconnecting 15.8.20 a l i n e s s h o u l d b e r e l i e v e dt h r o u g h s u i t a b l ev a l v e si n s t a l l e d t t h e l o a d i n g from these lines should not be dischargedto header. Liquid and vapour atmosphere. tanksor in independent oxide may be carriedin pressure Propylene 15.8.21 shouldbe oxide mixtures oxide/propylene or integralgravitytanks.Ethylene t i n i n d e p e n d e n g r a v i t yt a n k s o r p r e s s u r e a n k s .T a n k ss h o u l d b e t carriei designedfor the maximum pressureexpected to be encounteredduring cargo. loading,conveyingand discharging less oxidewith a designpressure of for 15.8.22.1Tanks the carriage propylene than 0.6 bar gauge and tanks for the carriageof ethyleneoxide/propylene lessthan 1.2 bar gaugeshouldhavea with a designpressure oxide mixtures temperature.' cargo below the reference cooling systemto maintainthe less for requirement tankswith a designpressure refrigeration 15.8.22.2The for the Administration shipsoperating than 0.6 bar gaugemay be waived by duration,and accountmay be of areasor on voyages restricted in restricted of of taken in such cases any insulation the tanks.The areaand timesof year for which such carriagewould be permitted should be included in the conditions of carriage of the InternationalCertificateof Fitnessfor the i C o C a r r i a g e f D a n g e r o u s h e m i c a l sn B u l k . Any 15.8.23.1 cooling systemshould maintainthe liquid temperaturebelow pressure. leasttwo complete At at the boilingtemperature the containment within the tanks,should by regulated variations plants,automatically cooling be provided. Each cooling plant should be complete with the necessary shouldalsobe capableof The controlsystem for auxiliaries properoperation. should be provided to indicate b e i n g m a n u a l l y o p e r a t e d .A n a l a r m of malfunctioning the temperaturecontrols.The capacityof each cooling of to systemshoulJ be sufficient maintainthe temperature the liquid cargo of temperature* the system. below the reference any of may consist three coolingplants, arrangement An 15.8.23.2 alternative below to two of which should be sufficient maintainthe liquid temperature t t h e r e f e r e n c ee m P e r a t u r e . from the productsby a single 15.8.23.3 Cooling media which are separated with the products. wall only shouldbe nonreactive
' See15.14.7.2
67
IBC Code
not of requiringcompression the productsshould Coolingsystems 15.8.23.4 be used. gauge settingsshould not be less than 0'2 bar Pressure-relief-valve 15.8.24 gauge for the carriageof and for pressuretanks not g'"ui"' than-7'0,bar 5'3 bar gauge for the carriageof oropylene oxide and noi gi"ut"' than oxide mixtures' propyleneoxide/ethylene
with theseproductsshould for The 15.8.25.1 pipingsystem tanksto be loaded for piping systems all other tanks' (as be separated aetineJ in 1'3'24)from i n t t a n k st o b e l o a d e di s n o t f li e i n c l u d i n g m p t yt a n K s . , n " o ' p l " d s y s t e m o t shouldbe pipingsepara.tion (as independent definedi" f ':'f 5)] the required and or valves' otherpipe.section of spool-pieces' by accomplished the removal requiredseparation The ilangesat these locations. of in" inriuttution blant< vapour vent linesand any piping' liquid liquid unJ uupo"u' "ppfilt i. all .and supplylines' sucftas common inert-gas connections, oih",. possible with cargoonly in accordance productsmay be transported 15.8.25.2These Each inU""n approved by the Administration' handling plans that f"ruu" cargo-handling a separate on tended loadingurrung"t"nt shouii be shown cargo piping systemano pf".. i"ig. nJndlingplansshould show the entire brank frangesneeded to meet the above of the rocationsfor instairation approved cargo-handling piping separationreqri,"t"n"' A copy oi each certificateof nl"intuin"l on board the ship.The International plan shouldb" in Bulkshouldbe endorsed Chemicals of for Fitness the Carriage Dangerous toinc|udereferencetotheapprovedcargo-handlingplans, and before every Before each initial loading of these products 15.g.25.3 verifyingthat the required return to iuln ,"rui.", certification subsequent obtainedfrom a responsible has piping separation U""n "tf i*"d shouldbe and carriedon board the ship' *o personacceptable in" p"tt Administration a pipelineflange should be Each connectionbetween a blank flange and fittedwithawireandsea|bytheresponsib|epersontoensuretha "a-t"u"", removalof the blank flangeis impossible' at liquid-full the reference No 15.8.26.1 cargotanksshouldbe more than 98% temperature.*
15'8'26'2ThemaximumvolumetowhichacarSotankshou|dbeloadedis P-! Vt : O.\TV Pt where Vt : V : maximumvolume to which the tank may be loaded volume of the tank
cargo at the referencetemperature' P n : relativedensity of and cargo at the loadingtemperature P t : relativedensityof oressure.
.2 See15.14.7
15.10Sulphur(molten)
15.,|0.1 Cargo-tank ventilation shouldbe providedto maintainthe concentrat i o n o f h y d r o g e n u l p h i d e e l o wo n e h a l fo f i t s l o w e re x p l o s i v ei m i tt h r o u g n s b l out the cargo-tank vapour space for all conditionsof carriage,i.e. below 1 . 8 5 " hb v v o l u m e .
69
IBC Code low are used for maintaining ventilationsystems Where mechanical 15.10.2 systemshould be provided to In gas concentrations caigo tank' an alarm tatts' give warningif the sYstem designed and arranged as to Ventilation systems should be so 15.10.3 system' of precludedepositing sulphurwithin the be so to adiacent. cargo tanks should Openings to void spaces. 15.10.4 or cargovapour' sulphur fiited as to preventthe entrv of water' ;;;;;";:;; of and analysing shouldbe providedto permit sampling Connections 15.10.5 v a p o u ri n v o i d s p a c e s ' be provided to ensurethat the Cargo temperaturecontrolsshould 15.10.6 of the sulphurdoes not exceed1ss'c' ;;;;;;
l5.ll Acids
not form any boundariesof tanks l5.ll.1 The ship's shell plating should m l containing ineraacids' related piping systemswith Proposalsfor lining steel.tanks and 15.11.2 The by n" considered the Administration. ,"v n.''ui"riui, corrosion_res,r,un, boundary not'be lessthan that of the supporting of elasticity the lining;;; jit-..i^^,ocicrrnr m:rcrials or fitted materials c wholly of co.rrosion-resistant q{!}jJnless cons.tructed shouldtake into accountthe ttnlng,the platingthickness with an approvecl oi corrosivitv the cargo' shouldbe manifoldconnections of l5.t 1.4Flanges the loadingand.discharge the danger of b",otuJ'qrg' to guard against ;;;h;"; provided with shields, shouidalso be provided ;;;;;iiio.n' drip tralvs the cargo tr"ing,p'"i";'";;i deck' it grlt"J"e"ini leakageon to the of hydrogen when these Because of the danger of evolution 15.11.5 should comply are being carried,the electricalarrangements substances and 10'2'3'7'The .l 1 , O ' 2 ' 3 ' 41 0 ' 2 ' 3 ' 6 ' w i t h o . 2 . 3 . 1 , 1 0 . 2 . 3 . 2 ,1 o ' 2 ' 3 ' 3 , for use in hydrogen-air safe type equipment should be. suitable certified shouldnot be permittedin such spaces' otf,er sourJJr'"iig"r,r." mixtures. sectionshould be of to sub.iected the.requirements this Substances 15.11.6 in requirements to the segregation from oil fu"l1unrc,in addition segregated 3.1.1. of to apparatus detect leakage shouldbe made for suitable Gtt.Drouision adjacentspaces' tff,lnto and drainagearrangements The cargo pumProom bilge pumping 15.1,l.8 materials' should be of corrosion-resistant
Chapter 15 - Specialrequirements
15.12 Toxicproducts
15.12.1 Exhaust openingsof tank vent systems should be located: .1 at a heightof Bl3 or 6 m, whicheveris greater, abovethe weather deck or, in the caseof a deck tank, the access gangway; .2 .3 .4 not lessthan 6 m above the fore-and-aft gangway,if fitted within 6 m of the gangway;and .l 5 m from any openingor air intaketo any accommodation and servicespaces; the vent height may be reduced to 3 m above the deck or foregangway, applicable, providedhigh-velocity and-aft as vent valves of an approvedtype, directing the vapour-air mixtureupwardsin an unimpededjet with an exit velocity of at least 30 m/s, are fiffed.
15.12.2 Tank venting systemsshould be provided with a connectionfor a vapour-return to the shore installation. line 1 5 . 1 2 .P r o d u c t s h o u l d : 3 . .1 .2 .3 not be stowed adjacentto oil fuel tanks; piping systems; have separate and have tank vent systems separate from tankscontainingnontoxic products.
15.13Cargoesprotected by additives
15.13.1 Certaincargoeswith a reference column o in the table of chapter in 17,by the natureof theirchemicalmake-up, tend,undercertainconditions of temperature, exposureto air or contact with a catalyst, undergo polyto merization, decomposition, oxidationor other chemicalchanges. Mitigation of this tendency is carried out by introducingsmall amounts of chemical additives into the liquid cargo or controllingthe cargo-tank environment. 15.13.2 Shipscarryingthese cargoesshould be so designedas to eliminate from the cargotanksand cargo-handling systemany materialof construction or contaminants which could act as a catalyst destroythe inhibitor. or 15.13.3 Care should be taken to ensure that these cargoesare sufficiently protected to prevent deleteriouschemicalchange at all times during the voyage.Shipscarryingsuch cargoesshouldbe providedwith a certificate of protectionfrom the manufacturer, and kept during the voyage,specifying:
71
IBC Code p . 1 t h e n a m ea n d a m o u n to f a d d i t i v e r e s e n | .2 whetherthe additiveis oxygen-dependent; .3 dateadditivewas put in the productand durationof effectiveness; .4 any temperature limitationsqualifying the additives' effective lifetime;and .5 the action to be taken should the length of voyage exceedthe effectivelifetimeof the additives. g 1 5 . 1 3 .S h i p s s i n g h e e x c l u s i o n f a i r a s t h e m e t h o do f p r e v e n t i n o x i d a t i o n 4 t o u o f t h e c a r g os h o u l dc o m p l yw i t h 9 . 1 . 3 . additive should be t5.13.5 product containing an oxygen-dependent A carriedwithout inertion(in tanksof a size not greaterthan 3,000 mr). Such cargoesshould not be carried in a tank requiring inertion under the req u i r e m e n t s f S O L A S h a p t e rl l - 2 . o c 15.13.6 Ventingsystems shouldbe of a designthat eliminates blockagefrom p o l y m e r b u i l d - u p . e n t i n g e q u i p m e n ts h o u l d b e o f a t y p e t h a t c a n b e V for checkedperiodically adequacyof operation. 15.13.7 or of Crystallization solidification cargoes normally carried in the molten statecan lead to depletionof inhibitorin partsof the tank'scontents. r o l S u b s e q u e n te m e l t i n g a n t h u sy i e l d p o c k e t s f u n i n h i b i t e di q u i d ,w i t h t h e c polymerization. preventthis,careshould To accompanying of dangerous risk be taken to ensurethat at no time are suchcargoesallowedto crystallize or in solidify, eitherwholly or partially, any part of the tank.Any requiredheating a r r a n g e m e n ts h o u l db e s u c ha s t o e n s u r e h a t i n n o p a r t o f t h e t a n k d o e s s t cargo become overheatedto such an extent that any dangerouspolymerization can be initiated.lf the temperaturefrom steam coils would induce overheating, indirectlowtemperatureheatingsystemshould be used. an
Chapter15 - Specialrequirements
suchagreement, listinggeographic arearestrictions timesof the year,or and v o y a g ed u r a t i o n i m i t a t i o n s ,h o u l db e i n c l u d e d n t h e c o n d i t i o n s f c a r r i a g e l i s o for the Carriageof Dangerous on the International Certificateof Fitness i C h e m i c a l sn B u l k . gases shore 15.14.4 Connections shouldbe providedfor returning expelled to d u r i n gl o a d i n g . gaugewhich indicates 15.14.5 Eachtank shouldbe providedwith a pressure in the pressure the vapour spaceabove the cargo. '|5.14.6 Where the cargo needs to be cooled, thermometersshould be providedat the top and bottom of each tank. 15.14.7.1 cargotanksshouldbe more than 98% liquid-full the reference No at (R). temperature 15.14.7 The maximumvolume (V1) cargoto be loadedin a tank shouldbe: .2 of
PR Pt
VL:0.98 V
where
V pR : pr : R :
- volume of the tank (R) relativedensityof cargo at the reference temperature relativedensityof cargo at the loadingtemperature reference temperature, the temperature which the i.e. at vapour pressure the cargocorresponds the set pressure of to valve. of the oressure-relief
15.14.7.3 maximumallowable The tank fillinglimitsfor eachcargotank should b e i n d i c a t e do r e a c hl o a d i n g e m p e r a t u r w h i c h m a y b e a p p l i e da n d f o r t h e f t e , applicable maximum referencetemperature,on a list approved by the Administration. copy of the list should be permanently A kept on board by the master.
15.16Cargocontamination
1 5 . 1 6 .W h e r e c o l u m n o i n t h e t a b l e o f c h a p t e r 1 7 r e f e r st o t h i s s e c t i o n , 1 a l k a l i n e r a c i d i cm a t e r i a l s ,u c ha s c a u s t i c o d ao r s u l p h u r i c c i d ,s h o u l dn o t o s s a be allowedto contaminate the cargo. 1 5 . 1 6 .W h e r ec o l u m no i n t h e t a b l eo f c h a p t e r 7 r e f e r so t h i ss e c t i o nw a t e r 2 1 t , should not be allowed to contaminate this cargo. In addition,the following p r o v i s i o na p p l y : s
73
IBC Code the valvesof tankscontaining . 1 Air inletsto pressure/vacuum-relief cargo should be situatedat least2 m above the weatherdeck. mediain a .2 Water or steamshouldnot be usedas the heat-transfer control systemrequiredby chapter7. cargo temperature
.3 The cargo should not be carriedin cargo tanks adjacentto perthe or manentballast water tanksunless tanksare erfiptyand dry.
ventilationrequirements 15.17Increased
For certain products,the ventilationsystemas describedin 12.1.3should of have a minimumcapacityof at least45 changes air per hour, basedupon the total volume of space. The ventilationsystem exhaustducts should spaces, discharge least 10 m away from openingsinto accommodation at systems, and at and intakes ventilation to work areasor other similarspaces, least4 m above the tank deck.
15.19Overflow control
where specificreference of 15.19.t The provisions this sectionare applicable is made in column o in the table of chapter 17, and are in additionto the for requirements gaugingdevices. for safe 15.19.2 the event of a power failure on any system essential In loading,an alarm shouldbe given to the operatorsconcerned. shouldbe terminatedat once in the event of any 15.19.3 Loadingoperations for systemessential safeloadingbecominginoperative. 15.19.4 Levelalarmsshouldbe capableof being testedprior to loading. 1 5 . 1 9 .T h e h i g h J e v e la l a r m s y s t e m r e q u i r e d u n d e r 1 5 . 1 9 . 6 s h o u l d b e 5 9.7 and should systemrequiredby 15.1 independent the overflow-control of r b t b e i n d e p e n d e no f t h e e q u i p m e n t e q u i r e d y 1 3 . 1 . alarm 15.19.6 Cargotanksshouldbe fittedwith a visualand audiblehigh-level s a w t w h i c hc o m p l i e s i t h 1 5 . 1 9 . 1 o 1 5 . 1 9 . 5 n d w h i c hi n d i c a t ew h e n t h e l i q u i d the level in the cargo tank approaches normalfull condition. 74
.2 .3 .
tR:
where
U = ullagevolume (m3)at operatingsignallevel; t = time(s)neededfrom the initiating signalto fully stoppingthe cargo flow into the tank, being the sum of times neededfor each step in sequential operations such as operator's responses signals, to stoppingpumps and closingvalves;
15.21Temperaturesensors
Temperature sensors should be used to monitor the cargo-pumptemperature to detect overheating due to pump failures.
75
Chapter 16
O pe r atio nal req uirem en ts*
16.1 Maximum allowablequantity of cargo per tank
16.1.1The quantityof a cargo requiredto be carriedin a type 1 ship should n o t e x c e e d1 , 2 5 0m ' i n a n y o n e t a n k . 16.1.2The quantityof cargo requiredto be carriedin a type 2 ship should n o t e x c e e d3 , 0 0 0 m ' i n a n y o n e t a n k . should be so loaded 16.1.3Tankscarryingliquidsat ambienttemperatures l a s t o a v o i d t h e t a n k b e c o m i n gl i q u i d - f u ld u r i n g t h e v o y a g e ,h a v i n gd u e which the cargo may reach. regardto the highesttemperature . :: .
.2 action to be taken in the event of spillsor leaks; personal contac! againstaccidental .3 countermeasures procedures media; and fire-fighting .4 fire-fighting
. Attention is afso drawn to the operation guidelinescontained in the ICS Tanker SafetyCuide (Chenicals).
76
Chapter16 - Operationalrequirements
.5 proceduresfor cargo transfer,tank cleaning, gas-freeing and ballasting; .6 for those cargoes required to be stabilized or inhibited in a c c o r d a n cw i t h . l 5 . 1 , 1 5 . 5 . 1 1 r 1 5 . 1 3 . 3t,h e c a r g os h o u l db e e o refused if the certificaterequired by these paragraphsis not supplied. 16.2.4 lf sufficientinformationnecessarv the safe transportation the for of cargo is not available, cargo shouldbe refused. the 16.2.5 Cargoes which evolvehighlytoxic imperceptible vapoursshould not be transported unlessperceptible additives are introducedinto the cargo. 16.2.6 Where column o in the table of chapter 17 refersto this paragraph, t h e c a r g o ' s i s c o s i t y t 2 0 ' C s h o u l db e s p e c i f i e d n a s h i p p i n g o c u m e n t , v a o d and if the cargo'sviscosityexceeds25 mPa.sat 20"C, the temperatureat which the cargo has a viscosityof 25 mPa.sshould be specifiedin the shipping ocument. d 16.2.7 Where column o in the table of chapter 17 refersto this paragraph, t h e c a r g o ' s i s c o s i t y t 2 0 ' C s h o u l db e s p e c i f i e d n a s h i p p i n g o c u m e n t , v a o d and if the cargo'sviscosity exceeds60 mPa.sat 2O"C,the temperatureat which the cargo has a viscosityof 60 mPa.sshould be specifiedin the shipping ocument. d 1 6 . 2 . 8W h e r e c o l u m n o i n t h e t a b l e o f c h a p t e r1 7 r e f e r so t h i s p a r a g r a p h t and the possibility existsthat it will be unloadedwithin a specialarea,*the cargo'sviscosity 20"C shouldbe specified a shippingdocument,and if at on the cargo'sviscosity exceeds mPa.s 25 at20'C, the temperature which the at cargo has a viscosityof 25 mPa.s should be specified in the shipping document. f6.2.9 Where column o in the table of chapter 17 refersto this paragraph, the cargo'smeltingpoint shouldbe indicatedin the shippingdocument.
16.3 Personneltrainingf
16.3.1 All personnelshould be adequately trained in the use of protective equipment and have basic trainingin the proceduresappropriateto their dutiesnecessary under emergencyconditions. 16.3.2 Personnel involvedin cargo operations shouldbe adequately trained p in handling rocedures,
* Specia/ areasare defined in regulation 1(7) of Annex ll to MARPOL 73178. i Referenceis made to the provisionsof the InternationalConvention on Standards Training of Certificationand Watchkeeping for Seafarers,'1978, amended in 1995, and in particularto as "Mandatory minimum requirementsfor the the training and qualificationof masters,officers a n d r a t i n g s o n t a n k e r s " - r e g u l a t i o n Vo l t h e a n n e x t o t h a t C o n v e n t i o n - a n d t o s e c t i o n A - V / 1 /f ofthe STCWCode (paragraphs 5 to 21). 1
77
IBC Code 16.3.3 Officers should be trained in emergency procedures to deal with conditionsof leakage,spillageor fire involvingthe cargo, and a sufficient first aid for number of them should be instructedand trained in essential cargoescarried.
when the only hazardis of a 16.4.3 Personnel shouldnot enter such spaces of purelyflammable nature,exceptunderthe closesupervision a responsible officer.
fully resistant the differentliquidsintendedto to .2 made of material be stowed;and arrangements. .3 equippedwith adequateventilation 16.5.3 Sampleswhich react with each other dangerouslyshould not be stowed close to each other. ,|6.5.4 should not be retainedon board longerthan necessary. Samples
Chapter16 - Operationalrequirements
from other products whose temperature is sufficiently high to initiate a reactionof such cargo (see7.1.5.4). 16.6.2 Heatingcoils in tankscarryingthis product should be blankedoff or securedby equivalent means.
productsshouldnot be carriedin deck tankswhich are 16.6.3 Heat-sensitive not insulated. 16.0.4 In order to avoid elevatedtemperatures, this cargo should not be carriedin deck tanks.
3.1.1 3.1.2.'l 3.1.2.2 3.1.4 3.5.2 3.7.4 7."1.2 7."t.6.3 9.1.4 9.2 11.3.2 1"t.4 12.1.2 12.2 "t3.2.1 13.2.2 13.2.3 13.2.4 ch.14 15.1 15.3.1 15.3.7
15.3.8 15.4.6 15.5 15.6.1 15.6.3 15.6.4 15 . 7 " 1 . 15.7.6 'l5.7 .11 15.8.1 15.8.2 15.8.3 15.8.4 15.8.s 15.8.7 't5.8.14.2 15.8.14.3 15.8.16 15.8.17 15.8.18 15.8.19 15.8.20
15.8.23.3 15.8.23.4 15.8.2s.1 "15.8.25.2 15.8.25.3 15.8.26.1 15.8.26.2 15.8.26.3 15.8.27 15.8.28 15.8.29 15.9 15.10.1 't5.11.4 1s.1 .6 1 '15.'t2.3.1 15.13 15.14.7.1 15.14.7.2 1 5 . 1 . 7. 3 4 1s.16 15.19.8
79
16A.2Conditions of carriage
l6A.2.lThe conditions of carriageof products listed in the Internationat for Certificate Fitness the Carriage Dangerous of of Chemicals Bulkshould in r e f l e c t h e r e q u i r e m e n to f r e g u l a t i o n , Ao f A n n e x l l o f M A R P O L7 3 1 7 8 . s 5 16A.2.2 categoryB substance A with a meltingpoint equal to or greaterthan 15 ' C s h o u l dn o t b e c a r r i e d n a c a r g ot a n ka n y b o u n d a r y f w h i c h i s f o r m e d i o b y t h e s h i p ' ss h e l lp l a t i n ga n d s h o u l do n l y b e c a r r i e di n a c a r g ot a n k f i t t e d with a cargo heatingsystem.*
'
'16A.2.2 When is referred to in column o in the table of chapter 17 for a product but the melting point of the cargo is lessthan 15'C, the requirementsof 16A.2.2 need not apply. The melting point of the cargo should be specified in the shipping document.
80
NOTES EXPLANATORY Product name ( c o l u m na ) UN number ( c o l u m nb ) The product names are not identicalwith the i o n a m e sg i v e ni n p r e v i o u ss s u e s f t h e C o d e ,o r n t h e B C H C o d e ( f o r e x p l a n a t i o s e ep a g e1 5 5 ) . t T h e n u m b e rr e l a t i n g o e a c h p r o d u c ts h o w ni n proposedby the United the recommendations on NationsCommitteeof Experts the Transport o f D a n g e r o u sC o o d s . U N n u m b e r s ,w h e r e only. are available, givenfor information The letter A, B, C or D means the pollution to assigned eachproductuhderAnnex category " 1 1 1m e a n st h e p r o d u c t " l l o f M A R P O L7 3 1 7 8 . was evaluatedand found to fall outside the A, categories B, C or D. that Pollutioncategoryin bracketsindicates categorizedand the product is provisionally to that furtherdata are necessary completethe evaluationof its pollution hazards.Until the hazard evaluationis completed,the pollution is categoryassigned used. "S" meansthat the product is includedin the of Code because its safetyhazards; "P" meansthat the product is includedin the and of Code because its pollutionhazards; "S/P" meansthat the productis includedin the Code becauseof both its safetyand pollution hazards.
Pollution category ( c o l u m nc )
Hazards (column d)
81
IBC Code S h i pt y p e ( c o l u m ne ) Tanktype ( c o lumn0, , ' 2 1 : 2 : 3 : 1 : : . f, : .P s h i pt y p e 1 ( 2 . 1 . 2 ) s h i pt y p e 2 ( 2 . 1 . 2 ) s h i pt y p e 3 ( 2 . 1 . 2 ) independent tank (4.1.1) i n te g ra l tank (4.1.2) g r a v i t y a n k( 4 . 1 . 3 ) t pressure .4) tank (4.1
Open: open venting Cont.: controlledventing SR: safetyreliefvalve Inert: Pad: Dry: Vent: .2.1) inerting(9.1 l i q u i do r g a sp a d d i n g( 9 . 1 2 . 2 ) . d r y i n g( 9 . 1 . 2 . 3 ) .2.4) naturalor forced ventilation(9.1
T1 to T6: temperatureclassesl s l l A , l l B o r l l C : a p p a r a t ug r o u p s i n o n f l a m m a b lp r o d u c t e NF: ( 1 . 1. 6 ) 0 flashpoint exceeding 60"C Yes: (closed-cup test)(10.1.6) No: flashpoint not 6 exceeding 0'C (closed-cup test)0 0.1.6) ( opengauging 13.1.1.1) g ( restricted auging13.1.1.2) ( g c l o s e d a u g i n g1 3 . 1 . 1 . 3 ) ( i n d i r e cg a u g i n g1 3 . 1 . 1 . 3 ) t
Cauging (column1) ,
O: R: C: l:
l:;:1", foam; encompasses foamsthat ar a r e n o t o f a n a l c o h o l - r e s i s t a ntty p e , including uoro-protein fl and aqueous-filmformingfoam (AFFF) C: water-spray D: drv chemicall No: no specialrequirements under this Code
' "No" indicates nil requirements. t Temperature classes and apparatus groups as defined in International Electrotechnical Commission Publication79 (part 1, appendix D, parts 4, 8 and 12). A blank indicatesthat data are currently not available. r Dry chemical powder systems,when used, may require an additional water system for boundary cooling. This is normally provided in sufficient quantities by the standard firemain system required by regulation ll2l4 of the 1974 SOLAS Convention as amended.
82
Chapter 17 - Summary of minimum requirements Materials of construction ( c o l u m nm ) N: see6.2.2 Z: s e e6 . 2 . 3 Y: s e e6 . 2 . 4 A blank indicates specialguidancegivenfor no materials construction of .l E: see 4.2.8 No: no specialrequirements under this Code
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T3
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No Yes
2820
Y1
No
15 . 1 . 2t o 1 5 . 1 1 . 4 , 1 15 . 1 . 6t o 15 . 1 . 8 1 1 15.19.6
2 G Open
No
Yes
No
A,B
NO
bo
Product name
s -b
r Q : E ' Y ^H = c
'I' |i"
d | 6 l f f
NF
Electrical equipment
o o
4.9
:. s F
F C
z
Calciumhypochlorite s o l u t i o n( 1 5 % o r l e s s ) Calciumhypochlorite s o l u t i o n( m o r e t h a n 1 5 % ) C a l c i u m l o n g - c h a i na l k y l ( salicylate C13*) C a m p h o ro i l C a r b o l i co i l Carbon disulphide Carbon tetrachloride C a s h e w n u t s h e l lo i l (untreated) Cetyl/Eicosyl methacrylate mtxture C h l o r i n a t e dp a r a f f i n s (Cro-Cr:)
N a I
nI S l s u !
'G
ho
: ! :i ^\
U R R
No
a * :?o
S/P
q/P
3 3 3 2 2 2 3 3 3
I
2C 2C
Cont.
No
No
N5 N5
No
l5.tb.l
Cont.
NO
NF
No
No
No
15.16.1,15.19.6 16.2.7,16.2.8
15.19.6 1 5 . 1 21 5 . 1 9
C
R
P S/P s,/P
Open 2 C Cont.
IL
No
NO
Yes
IIA No Yes
o
K
No F
A,B A,B
No No No
Cont Cont.
No Pad+ lnert No No
F.T
E T
1131
1846
B B D
ill
S/P
q/P
IU
T6
ilc
NF
No
C No
E Z E
No
1 5 . 3 1 5 . 1 21 5 . 1 9 , , 1 5 . 1 21 5 . 1 7 , 1 5 . " t 9 . 6 ,
c
Yes
T
T
A,B A,D
No
Yes
No
No
No
Yes
No
No
h Elec'trical equtpment
bo
Product name
c
u
c
r 9 ! n
q)
i'lt'l i"'
I
< c t c a:
G N G T
z
C h l o r o a c e t i ca c i d (80% or less) Chlorobenzene
s
2
.t
. a F F C
a| 3l*n! I |5tSF
NF
T1
t :
v . :
t :
*.e
ho (J
U
O
::n
s*
No No
d d
Y5
No
S/P
2C 2C 2C 2C
Cont.
No
o
A)
S/P
Cont.
No No No
ilA NF ilA
No
R
R
F-T A , B
No
Chloroform
C h l o r o h y d r i n s( c r u d e )
B (D)
slP 3
S
Cont. Cont.
T
F-T
No
No
E
No
1 5 . 1 21 5 . 1 9 . 6 ,
I
\
1(a)'
| t '
2 3
No
15.12, 5.19 1
(c)
1578 B
2 C Open
No
NF
o
Yes
No
N1
No
io) t v^ l l n
l \ .
q/p
zv
Cont.
No
A,B,
n
No
ir.
t x x
2- or 3-Chloropropionic cid a
2 5 1 1 ( n )(c)
s/P
q/P
2 C Open
No
Yes
No
Y1
No
C h l o r o s u l p h o n i ca c i d m-Chlorotoluene o-Chlorotoluene
2C 2C 2C
No No
NO
NF No No
C R R
T
E T
No
1 5 . 1 . 2t o 1 5 . 1 . 8 , 1 1 15.'12,15.16.2.15.19
q/P
q/P
3 3
A,B A,B
No No
r5.19.6
15.19.6
E T
o
bo o
o o
z f,
p-Chlorotoluene
Chlorotoluenes (mixedisomers) Coal tar Coal tar naphthasolvent Coal tar pitch (molten) Cobalt naphthenate i n s o l v e n tn a p h t h a Coconut oil fatty acid C r e o s o t e( c o a l t a r ) Creosote (wood) C r e s o l s( a l l i s o m e r s ) C r e s y l i ca c i d , dephenolized C r e s y l i ca c i d , s o d i u m s a l t solution Crotonaldehyde 1 14 3
: c
'b
o b
F
:
B
V '> F :l
i"I
l *
f"
bo
: F
: .
N q 'r
+l +e
F:E No No
NO
i | *P
No No
u
R
R R R R R
N O
>-c
E T
2238 2238
2 2 2
3
2 C Cont.
Cont.
No
NO
15.19.6,16.2.9
E T
15.19.6
15.19.6
2C 2C
l ( r
T2 T3 T2
Yes No
No
E T
No No No
NO
s/P
S
No No No No No
NO
1s.19.6
1 5 . .9 . 6 1 15 . 1 9 . 6 1 6 . 2 . 7I o 1 6 . 2 . 9 I5.19.6
3 2 3 2 2 2 2 2 2
Yes
No
No
E T
s/P (_
P S/P S/P
Yes T2
ilA ltA ilA
o o
No No No No No
No
NO
r2
T1
2076
s/P
S/P
No No
o o
o o
R
No No No
s/P
q/P
No
No
N8
No
No
t-J
ilB
No
F.T
Etectricat equipment
a O
Product name
r Q > n
. = A
z
1,5,9-Cyclododecatriene C y c l o h e p t a n e( b b ) C y c l o h e x a n e( b b ) Cyclohexanone CyclohexanoneCyclohexanol , mixtu re Cyclohexyl acetate Cyclohexylamine '1,3-Cyclopentadiene dimer (molten) C y c l o p e n t a n e( b b ) Cyclopentene p-Cymene(bb) Decanoicacid w Decene 1't46
N
>
i q
e-
a I
s
1
* E : o F:E
;l;l5;
ho
: A
9 . :
;:
-.4
: f
< U : n
G ( l
>-o
> U d d
N2
No No No N5 N5 No No
I
S/P
No No No No No No No No No No
NO
Yes No No
T
F
1 5 . 1 3 ,1 5 . 1 9 ,1 6 . 6 . 1 16.6.2
2241
1145
(c)
C
P P S S P S/P
3 3 3
-t
R R
R R
F F-T
\ (')
I
1915
D D
T2
ilA
No
Yes
No
2243 2357
(B)
3 3
R R
R
No N1 No No No
15."t9.6
1 5 . 9.6 1 1 5 . 19 . 6 , ' t6 . 2 . 6 ,16 . 2 . 9 , 164.2.2 15.'19.6 .t .5..1 9.6
r
T3
ilA
No No No No No Yes No
F-T A , C
F
(c)
(B)
C C
P
P P
D
3
J
2C 2C
Cont. Cont.
R
K
2246 2046
F F No
No No No
NO
3 3 3
2 G Cont. 2 C Open 2C
Cont.
No No
o
R
n E : A
bD
r Q -o o
Product
name
o
n
c
6
El"r'triral equipment
!U FY .
a f a { t
o o
o
z
Decyl acetate Decyl acrylate Decyl alcohol (all isomers) D ecyloxytetra hyd roth i o ph e n e dioxide Dibromomethane Dibutylamine
c o-
-tr
. N X F C
SI S| #F
Yes
I t : , ^| + l + e
s
No No No
I
? O
E d
d d
No
l l
(B)
P S/P
3
z
zu
Open
No No No No No
NO
o o o
R R
19.6
2 C Open 2 C Open 2C
ZL
T3
ilA
A,C, N2 D
No No
P S/P
3 2 2 3
Cont,
A No A,C, D
No
S/P S/P
Cont.
Cont.
N3
N4
No No
r2
ilA
NO
F-T
No No
P P
2 C Open 2
IL
NO
Yes Yes T1
ilA
o o
R
No No
15.19.6,16.2.6 15 . 1 9 . 6
15.19.6, 6.2.6(x), 1 1 16.2.9(v), 6A.2.2(z\ 15 . 12 . 3 , 15 . ' t7 , 15 . 19 . 6 15.19.6
Open
No No No No No
B B 2362 D B
q/P
2 C Cont. 2C 2C 2
Cont. Cont.
Yes
No
A,B, N5 D
No
q/P
E E
No
S
c/p
T2 I2
ilA ilA
NO
2 C Cont.
No
15.19.6
c
!
n Electrical equrpment
m
n
bo
Product name
q)
-d N .F
\ n 't; : H
i'li"l
l
r"
-
z
I ,6-Dichlorohexane
. G F F C
slslsF
oo a U
t :
r.a
c 'n o
:s
v . =
: ^
C U
5 ;
:lo
>-c
I
S/P
2
z
No No No
No
R R
R
A,B A,C, D
No N1
No
15.19.6 "t5.12 1 5 . 1 71 5 . 1 9
2,2'-Dichloroisopropyl ether
Dichloromethane
s/P
5
q /D
Yes T1
ilA
T
T
N5
No No No
3 2 3
Yes Yes
\
15 . 1 9 . 6
15.19.6
2,4-Dichlorophenol
2,4-Dichlorophenoxyacetic a c i d , d i e t h a n o l a m i n es a l t solution 2,4-Dichlorophenoxyacetic a c i d , d i m e t h y l a m i n es a l t solution(70% or less) 2,4-Dichlorophenoxyacetic acid,triisopropanolamine s a l ts o l u t i o n 1, 1 - D i c h l o r o p r o p a n e 1,2-Dichloropropane | ,3-Dichloropropane
Cont.
Dry
No
(')
5 Fo
q/P
2 C Open
NF
o o o
No
No
No
N1
No
q/p
2 C Open
No
NF
No
No
N1
No
15.19.6
q/P
3 2 2 2
2 C Open 2C
Cont. Cont
No
NF
No
No
NI
No
(_
1279
s/P
No No No
R R
R
Z Z
No No
NO
c s/P
D
S
T.l T1
ilA
ilA
No No
2C
Cont.
Electrical equil)ment
^\n Y F
a)
-l
3
o
-d a N a .T.
i'lt'l
t
q |
/"i
a
b c
!
t ^ ld
f , l
>s
-.4
h n
c
v . :
: .
o' o
z
J
* E
No No
o l 0 l trX
T2
ilA No No
l S ^
s
f
s*
E T
? o
l ^ -
2047
B B D D
s/P
s,/p
2 2 3 3 3 3 3 3 3 2
2C
Cont. Cont.
(_
A,B A,B, D
A
E E Y5 N2
N1 N.l No No
F-T
R No No
S S
q/P
q/P
2C
Cont.
Dry
No No No No No No Inert No No No
Yes T.l
ilA ilA ilA Yes No No Yes No
2 C Open 2C 2C
Cont. Cont.
o
R
1154 2686
r2
T2
E E
No No
s/P
2049 2079 11 5 5 D
ill P S S S/P P
2 C Open 2C
Cont.
o
R
B,C, No N4 D
F No
2 C Open
Cont.
T2 T4
ilA ilB
Yes No Yes
o
C
N2 N7 N2
No
F-T
N o A,D No
E
No No
1 5 . 4 1 5 . 1 41 5 . 1 9 , ,
c
C
2 C Open
a
o o
C
2 C Open
Cont.
Yes Yes
(B) s/P
N3
No
l 5.l9.6
a O
Product name
3
'b
^c "b Y F
, ' 1 , "" 1:
o | - l f f
Electrical equrpment
*
.g
b
,G
z
D i g l y c i d y le t h e r o f b i s p h e n o lA D i g l y c i d y le t h e r o f b i s p h e n o lF Di-n-hexyladipate Diisobutylamine Diisobutylene D i i s o b u t y lp h t h a l a t e D i i s o pr o p a n o l a mi n e D iisopropylamine D i i s o pr o p y l b e n z e n e (allisomers) N,N-D i methylacetamide s o l u t i o n( 4 0 % o r l e s s ) Dimethyladipate D i m e t h y l a m i n es o l u t i o n (45% or less) 11 6 0
N G T
i:E
NO
*| s l " i :
c
f a
-.e
> . <F v
'n
: -
() \ " *
No No No
. \ i I L
? o ddr
B B B 2361 2050
3 3 3
z
Yes
o o
No No No N1 No No No
15.19.6,16.2.6
No No No
NO
Yes
Yes
NO
"1s.19.6,16.2.6
h
o
R R
1s.19.6 1 5 . 1 2 . 3 ,s . 1 . 6 1 9
(c)
B B
F-T
F No No
r-l
\ (/) :
I
3 3 3
z
No Yes
No No
NO
g)
c
1 ' l5 8
T2
ilA ilA
Yes
No
o
C
N2 N2
No
r2
E
No
2
l
No
Yes
Yes
o
R
No
| 5.19.6 "t I s . 1 2 .. 5 . 1 7 1
1 5 . 1 9 . 6 ,1 6 . 2 . 9
D B
C
S P
q/P
No No No
N4
No No
o o o
+
3 3
Yes
o
R
No
r2
ilA
NO
F-T
A,C, U
N1
No
1 5 . 1 21 5 . 1 9 . 6 ,
Electrical equrpment
oo
n o
Product name
3
E
'n
-o
N 6 -F
z
D i m e t h y l a m i n es o l u t i o n ( g r e a t e rt h a n 4 5 o l o u t n o t b greater than 557") D i m e t h y l a m i n es o l u t i o n ( g r e a t e rt h a n 5 5 7 o b u t n o t Sreater than 657o) N ,N - D i m e t h y l c y c l o h x y l a m n e e i Dimethyleth nolamine a D i m e t h y l f o r ma m i d e Dimethyl glutarate Dimethyl hydrogenphosphite D i m e t h y l o c t a n o i ca c i d Dimethylphthalate Dimethylsuccinate D i n i t r o t o lu e n e ( m o l t e n ) 1,4-Dioxane
c)
r Q : n -v > c H b I .o ts.J F
i:E
No
;l;l$;
oo
v . =
: -U
d a
-.4
(-)
C
bD q
U o
h E
s
F.T
.5Y lr:o-
& d
E 1 5 . 1 2 ,5 . 1 7 , 1 5 . 1 9 1
I 160
s/P
2 C Cont.
No
11 6 0
c/p
2 2 3
2 C Cont. 2 C Cont.
Cont. Cont.
No
No
F-T R R
R
E
No No No No
| 5 . 1 2 ,1 5 . 1 4 , 5 . 1 7 1 ,
r 5.'l 9
q/p
NO
No
| 5 , 12 , 1 5 . 1 7 15 . 1 9 . 6 ,
)
S P
No No No No No No
NO
T3 T2
IIA ilA
No No
N2
15.19.6
15.19.6
3 3 3 3 3 2 2
2 C Open
It.t
Yes
Yes
o
R
(B) S / P
Cont,
A,D
NO
15 . 1 2 . 1
16.2.8,16.2.9
(c)
C
P P P
2 C Open 2 C Open
Zlt
Yes Yes
Yes
o o o
C C
No No No No
A
Open
16.2.9
't | 5 . ' t2 , 5 . 1 7 1 5 . 1 9 , , 15 . 2 1
1600
11 6 5
q/P
2C (o) C o n t 2C
Cont.
No No
Yes T2
ilB No
T
E T
No
r5.1 , l -5.19 2
Product name
3
'b G
N
t.
3
c
.>! -F
:\n
:-
Electrical equtpment
t :
: F
< a o n,i . ! La o_
n' n 6 . U O Q
z f
Dipentene
: s
I C P P
# E 3 2C
Cont. No No
a ( l
o o >-b
a { :to d d No 1 5 . 19 . 6
2052
F No
Diphenyl
D i p h e n y l a m i n e ,r e a c t i o n product with 2,2,4-Trimethylpentene D i p h e n y l a m i n e sa l k y l a t e d , D i p h e n y l / D i p h e n y le t h e r mixtures D i p h e n y le t h e r Diphenylether/Diphenyl phenyl ether mixture Diphenylmethane diisocyanate Diphenylolpropanee p i c h l o r o h y d r i nr e s i n s D i-n-propylam e in Dodecene (allisomers)
o o
o o
No
15 . 1 9 .l 5.19 15.19.6
15 . 1 9 15.19.6 15.19.6
FJ 6
(A)
s/P
P P P P
No
Yes
No
No
No
Yes Yes
No
No
\ I (/)
3
No
No No
No No No
No No No
o o c
o
lu
Open
2489
(B)
q/P
2C
Cont.
Dry
No
:l 3
B 238.t (B)
P S/P P
3 3
5
No No
NO
No
E T
No
N2
No No
3 \
r
Yes
No
i Electrical equipment
o o
Product name
tr
3
c
-o
N N -f'
z
Dodecyl alcohol Dodecylamine/ Tetradecylamine ixture m Dodecyldimethylamine/ Tetradecyldimethylamine mixture Dodecyl diphenylether d i s u l p h o n a t es o l u t i o n Dodecyl methacrylate Dodecyl/Pentadecyl m e t h a c r y l a t em i x t u r e Dodecylphenol
ill
.=
ts
F C
S
3 2
t s q
sl s l s ;
a ( i
i'li"l r" I t E
: v . :
: r :
>'b
f h
A
'i on 9 d d
No "l 15 . 19 . 6 , 16 . 2 . 6 , 6 . 2 . 9 , 164.2.2 15.19.6
2 C Open 2C
Cont.
NO
Yes Yes
o
R
No
S/P
No
A,D
N2
No
S/P
Open
No
Yes
o
r)
No
B,C, N4 D
No
No
1s.19.6
't 5.19.6 15.13
15.13,16.6, 16.6.2 .
s/P
S S P
2 3
No
NO NO
No No
No No No
NO
o o o
ill
N o A,D No No No
Open
Z\J
No No No No No
15.19
15.19.6 "t 15 . 1 2 , 5 . 1 7 1 5 . 1 9 ,
3 2 3
J
Open
Cont.
Yes IB
No Yes No
o
o
R
No
s/P
S P
E F-T
r
Z\J
Open Cont.
r2
ilA
N2
No No 15.19.6
IL
Electrical equtpment
h
Product name
g
-b
: n < !
z
Ethyl acrylate Ethylamine Ethylamine olutions s (72"/" or less) E t h y la m y l k e t o n e Ethylbenzene N-Ethylbutylamine Ethyl butyrate ( E t h y l c y c l o h e x a n eb b ) N-Ethylcyclohexylamine Ethylene hlorohydrin c Ethylene yanohydrin c Ethylenediamine E t h y l e n ed i b r o m i d e 1604
I I JJ
.]q/P
N 6
s
2 2 2 3 3 3 3 3 3 2 3 2 IC
Cont. Cont.
No No No No No No No No No No No No No
r2 r2
;t;t$;
s
h s
: E
: ^ }U
o O ? A J
-.4
'd a-
a t l
s : = \
F-T F-T C,D
d b
E N2
NI
ilB ilA
No
NO
15 . 1 , 15 .19 . 6 ,1 6 . 6 . 1 3 16.6.2
A)
(c)
S/P
E
F
1 5 . 1 2 ,1 5 . 1 4 , 1 5 . 1 9 . 6
(c) s/P
P
2 C Cont.
Cont.
No No No No No
No
F-T A,C
F F
\
I
R R R
R
No No N1 No No No N1 No
(c) s/P
11 8 0
C P P S S/P S
q/p
F-T
F F
15 . 1 2 . 3 , 1 5 . 1 9 . 6
1 5 . .9 . 6 1 -t 5.19.6 .t 5.19.6 't5.12,15.17,15.19
3 3 AJ
(c)
D
C
R
R
L
2 C Cont.
Z\J
No
F.T
ET
Cont.
r2 r2
No
A,D
E
No
3
o o
(D)
C
2 C Open 2C 2C
Cont.
Yes
No
o
R
C
No
N2 T
No
No
I 605
s/P 2
Cont.
h Electrical equtpment
o o
o
Product name
g
c
-ll a N a T
q)
r P Y S
I
/li"l
r"
@
: ^
6 O : 5 E ^ *
z
Ethylene dichloride
.s
2
J
t.
e
2C
Cont. Open
F:E No No No No
slsls;
{ t
m a
<-+
1't84
q/P
r2
ltA
No Yes
F-T A,B No No No
N4
No No No No
15.19
(c)
C C D
P
P
3 3 3
2C Open 2 C Open 2C
Cont.
Yes
Yes
o o
R
No
No
No
1 s . . t. 6 9
15.8,15.12,1s.14, 15.19
2983
S/P
1 G Cont.
lnert
T2
IB
No
E T
A,C
No
c
B 2276 B B
3 3
2C
Cont.
No No No No
No
No No
No No
r 5..t 9.6
15 , 1 3 1 5 . 1 9 . 6 ,6 . 6 . 1 1 , 16.6.2
1 5 . 1 2 ,1 5 . 1 9 . 6
slP
2C Open 2C 2C
Cont Cont.
T3
ilB
Yes No No
o
R R
s/P 2 s/P 3
F-T
E T
N2 A,D
N4
No No
1s,12.115.16.1 , 15.19.6
Electrical equtpment
m
Product name
3
E
'a
6
z
Ethylmethacrylate o-Ethylphenol 2-Ethyl-3-propylacrolein Ethyltoluene
F e r r i cc h l o r i d e s o l u t i o n s F e r r i cn i t r a t e / n i t r i ca c i d solution Fluorosilicic cid (20-30%) in a water solution F o r m a l d e h y d es o l u t i o n s (45% or less)
'r
G N
s
s
2C
> n < \
c
F:E
;l;l$;
bo bo
h A >: < U : n a q
: -
::
( l
il
^-
d b
No
No
NO
2277
(D)
-t
Cont.
No No No No No No
T2 T1
No Yes
NO NO
F-T A,D
No
E T
15 , ^3 , 15 . 1 . 6 ,16 . 6 . 1 t 9 16.6.2
A)
(A) SIP 3
(A) S I P 3
2 C Open 2C 2C
z\f
o
R
R
15.19.6 .t 5.19.6
15.19.6
(B) 2582
\
I
P
q/p
F
NO
No No
NO
NF NF
o
R R
No
No
3
J
s/P 1778
2 3
2C
T T F-T
E E E (e) Y2,Y3
q/p
1 C Cont. 2C
Cont.
No
NF
No
o
r
1l e8(d), C 2209 D
S/P
No
T2
ilB
l 5 . 1 . 1 ,15 . 1 . 6 , ' 6 . 2 . 9 6 9 t
"l5.11 | 5 . 11. 2 t o .4, 1 5 . 1 . 6t o 1 5 . . 1 . 8 , 1 1 15.19.6
F o r m i ca c i d
1779
2C
Cont
No
T1
ilA
No
T(v)
F u m a r i ca d d u c t o f r o s i n , water dispersion
qJ
B 1199
C
2 C Open
Cont
No No
Yes
o
R
NO
E T
NO
No No
1 s . 1 9 . 61 6 . 2 . 6 ,
SIP 3 T2
ilB No I 5 . 1 6 . 11 5 . 1 9 . 6 ,
Furfural
Product name
F
x !
-d N N .T
Etecltricat equipment
o o
o
: A
bo c oo
z
F u r f u r y la l c o h o l C l u t a r a l d e h y d es o l u t i o n s (50% or less) C l y c i d y l e s t e ro f C 1 e trialkylacetic cid a H e p t a n e ( a l l i s o m e r s )( b b ) H e p t a n o l ( a l l i s o m e r s )( q ) H e p t e n e ( a l l i s o m e r s )( b b ) Heptyl acetate in Hexamethylenediam e solution H e x a m e t h y l e n e i mn e i H e x a n e ( a l l i s o m e r s )( b b ) H e x e n e ( a l l i s o m e r s )( b b ) Hexyl acetate H y d r o c h l o r i ca c i d
.s
3 3
b
c i . c F F C
: n | 3 l s { 3() s * d | 6 | f;f o
No No No
: E a :
2874
C D B
P
C
No No
NO
o
Yes No No No Yes Yes No No No No
No
1 s . '6 . 1 l 15.19.6
15.1 .6 9 15."19.6
No No No No No No No No No No No NF
o
R R R
No F F F No
I
No No No No No
1206
(c)
C C
P P P P
2C 2C
Cont.
Cont. Cont.
3 3 3
2C
15.19.6
15.19.6 15.19.6,16.2.9
2C O p e n 2C 2C 2C Cont,
Cont. Cont.
o
R R R R R R
(- s/P
C
N2 A,C
N1
No No No No No
SIP 2
P P P S
E T
rs . 1 . 6 9
15.19.6 15.1 .6 9
15.19.6 15.1 1
(c)
3
l
J
F F F
(c)
1233
1789
2 C Cont. 2C
Cont.
B D
1 C Cont.
No
(f)
m
h
99 Product name
c
3
'b a N a T
I 6
.!F
U : F G O C
r 9 : n
'l'"1:"
s sIgl$Hs *
U
G
Electrical equipment
: >: o o s!9
t :
-.e
h n
d :
v . :
z
H y d r o g e n p e r o x i d es o l u t i o n s (over 8% but not over 6070) H y d r o g e n p e r o x i d es o l u t i o n s (over 607o but not over 707") 2-Hydroxyethyl acrylate 2-Hyd roxy-4-( methylth io)butanoicacid lcosa(oxypropane-2,3-diyl)s l s o p h o r o n e d a mi n e i l s o p h o r o n ed i i s o c y a n a t e
s
2C 2 2 3 3 3 2
t
.q
< 9
na) d d No
( . s/P
C S/P
q/p
Cont
No
NF
No
No
| 5 . 5 . 1 4o 1 5 . 5 . 2 6 , t | 5.1 ,1s.19.6 8
1 5 . 5 . 1o 1 5 . 5 . 1 3 , t 1 5 . .9 . 6 1
f,-
2C
Cont
No
NF
No
No
No
No
Yes
T
No No
No
\ (^ 5 x
P P S
q/P
No No No
Yes Yes
o
o
R
C
No No
Yes
Yes
T T
r
N2 A,B, D
D
No
NO
:
15 , 1 2 , 15 . 1 6 . 2 15 . 1 7, , 15.19.6
f, 5 5
Dry
No No No No
I J
N5
rsoprene
l s op r o p a n o l a m i n e lsopropylamine
9l
SIP
S/P
Cont.
No Yes No No
No
15 , 1 , 15 . 1 , 15 . -9 . 6 , 3 4 t 1 6 . 6 .,1 6 . 6 . 2 1 16.2.8,16.2.9
o o
2 C Open 2 2 2C
Zlt
T2
N2 N2
N.l
No
1221
s/P (_
S/P
Cont. Cont.
r2
E E
1 5 . 1 2 ,1 5 . 1 4 , 5 . 1 9 1
l s o p r o p y l a m i n e( 7 0 % o r l e s s ) solution
FT CD
1 5 . 1 21 5 . " 1 9 ,
Product name
z
( l s o p r o p y l c y c l o h e x a n eb b ) l s o p r o p y le t h e r
E c
-c
N a T
^\n . S :
rtecltricat equpment
=
o
h s
v . :
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>:
bo ho
.=
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F:
nI S l r u E s * o | 0 |f F
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I 159
2 C Cont.
Cont.
No lnert
R R
F
F
No No
1s . 19 . 6 ,16 . 2 . 7 16 . 2 . 8 , 15.4.6,15."13.3, 15.19.6 t t 1 5 . 1 , 1 5 . 1 2 , 1 5 . 'o 7 1s . 1 9 ,16 . 2 . 616 . 6 . . t o , 1 16.6.3 15.19.6,16.2.6,16.2.9, 16A.2.2 20.5.1 15.12,15.19.6, 16.2.7,16.2.8 15 . 1 . 6 .16 . 2 . 7 16 . 2 . 8 9 . 15 . 1 . 6 ,16 . 2 . 7 16 . 2 . 8 9 , 't6.2.7,16.2.8
)
S/P
1 C Cont.
No
Yes
c o
C
Y1
P
qiP
3 2
-t
2 C Open 2C
Cont.
No No No
Yes No
No
E T
No
E
C C
2 C Open 2C 2C
Cont.
Yes
No
o
R R
No
A,B
No
3
-t
No
No
c c
2215 D
Cont.
No
NO
No
.J
2 C Open 2 C Cont.
No
Yes
Yes
o
R
No
A,B
\(g) C
NO
NO
No
No
Product name
g
c
I V : E
a N .la
Y S
> -
''l''|:"'
Etectrical equipment
a.6 ts F C
z
Mercaptobenzoth iazol, sodium saltsolution M e s i t y lo x i d e Metam sodium solution M e t h a c r y l i ca c i d M e t h a c r y l i cr e s i n i n e t h y l e n e dichloride Methacrylon itrile N - ( 2 - M e t h o x y -- m e t h y l e t h y l ) 1 2-ethyl-6-methylc h l o r o a c e t a nl i d e i Methyl acrylate M e t h y l a m i n es o l u t i o n s (42"h or less\
sI s| $ F
NF T2
ilB NF Yes
tz
, ^| + l + e
t s
h s
v . :
: >P o o ? o
oo
= E
: E
G I f
= :
No
T-l
da'
N1 No No
B 1229 D
S/P
S
q,/p
t
No No No No No
o
No
NO
15.19.6, 16.2.9
f,-
15.19.6
2
J
o
R R
C
No
No
N.l
No No No
15.19.6
15.13,16.6.1 15.19,16.2.6
\
I
253"1
D B
S
q/P
T A,B
F-T
Y1 N4
N4,Z
2 2
2 C Cont. 2 C Cont.
ilA
No
3079
No
No
B "t919
2C Open
2 2 2 C Cont. 2 C Cont. 2 C Cont.
Z\J
No
Yes
,o
R C R
R
No
No
s/p
No
T1
ilB
No
E F.T
F F
No No No
No No No
A,C D
N1
E
No No
15 . 1 9 . 6
15.19.6
Cont.
o m
O
Elec'trical equtpment
: qJ i
Product
name
qJ
3
3 a N a -F
0) b
O
! F > i
e.
.+
z
Methyl butyrate ( Methylcyclohexane bb) d Methylcyclopentadiene imer i M e t h y l d i e t h a n o l a mn e 2-Methyl-6-ethylaniline 2-Methyl-5-ethylpyridine Methyl formate Methyl heptyl ketone tyne 2-Methyl-2-hydroxy-3-bu
s
2C
Cont.
, 6 F F C
slels*
U No No No Yes Yes ilA Yes No No
h ' l
:
lrl
> :
-.4
!Id
o
: E
+ "
:?i :!o
NO
\" -:
1237 2296
(c) (c)
(B) D
P P P S S/P
q/P
No No No No
NO
R R R
F F
NO
15.19.6 15.19.6
3 3
2 C Cont, 2C
Cont,
No No
15.19.6
2 C Open 3 3
z
o o
N2 A,D A,D
N4
(_
2300 1243 (B) D B
ill
No No
E T
No No No No
o
R R R R R
C
S P S
E
No
3 3
z
F
E T
ilA
No
A,B, N6 D
No
15.19.6
1 5 . 13 , 15 . 1 9 . 6 ,16 . 6 . ^ l 16.6.2
1247
S
q/p
No No No No No
r2
ltA
No
F.T
No F
r
No
2 2 2 2
2 C Cont. 2C
Cont. Cont.
Yes
No No No
A,D
N4
No No No No
1s.19.6
1 5 . 1 2 . 31 5 . 1 9 . 6 ,
s s
c s/P
D
c
C
A"C
N4
15.12.3,15."19 1 5 . 1 2 . 3 ,5 . 1 9 1 6 . 2 . 9 1 ,
2C
Cont,
F-T
N4
#
Ptoduct name
flectical equpment
bo
0) c f
3
'tr
N i
t v : n
! s
g
G F
,"|:" l.s
c c O iid
> 'F v :
: E
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Methyl salicylate
$l"eE (-) 6 l * f
q
G O
&a^
No No
!a q)
P S/P
2 C Open
Z\J
No No No
Yes Tl T2 T4 T1
ilB ilA No No
o
R R C R
No
a/pha-Methylstyrene Morpholine
Motor fuel anti-knock compounds (containing leadalkyls)
Cont,
Cont.
F-T A,DF
5A)
S
q/P
zu
N2,Z
No
1 C Cont. 2 2 3 2 2 2 2
2l)
No
ilA
No
F-T A,C
No No No T No No No
E
No No No
(molten) Naphthalene
N a p h t h e n i ca c i d s N e o d e c a n o i ca c i d N i t r a t i n ga c i d ( m i x t u r eo f s u l p h u r i ca n d n i t r i c a c i d s ) N i t r i c a c i d ( l e s st h a n 7 0 % ) Nitric acid (70% and over)
2304
c/P
No No No No No No
ilA
Yes
A,D
P
C P
Yes Yes
NF NF NF
o
C R C
(c) q / P
C
q/P
E E E
No
T T
q/P
2 C Cont.
Cont.
3
6
Nitrobenzene
q/P
No
T1
ilA
Yes
A,D
1 5 . 1 2 ,1 5 . 1 7t o 1 5 . 1 9 , 16.2.9
t
b
c
Electtical equtpment
o o
o
I fr
3 &r I I
I
Product name
o c c
3
-t)
f,
z
Nitroethane N i t r o e t h a n e( 8 0 % ) / N i t r o p r o p a n e( 2 0 o l o ) o - N i t r o p h e n o l( m o l t e n )
a N a -F
.g
S
3 3 2
.>! F b
,G ts
! :
9 E
i'li"l
l l
i"'
*
: F
:-
. 6 F F C
s | 5| s F
ilB No ilB
NO
I t : uI ilsd!
s no
e { l
'n a o
O -
ti5
*a ^ :
No
(D)
Cont
NO
R R
F I
A(u) N 4
N4
S
q/p
Cont.
No
FT A(u)
No
NO
1663 2608
B D D
Zl)
Cont.
No No No
Yes
A,D
1-or 2-Nitropropane
Nitropropane(60%)/ N i t r o e t h a n e( 4 0 % ) m i x t ur e o- or p-Nitrotoluenes N o n a n e ( a l l i s o m e r s )( b b ) Nonene (all isomers) Nonyl acetate Nonyl alcohol (allisomers)
S S
2 C Cont. 3 2
l
ZL
r2
ilB
No
No
R
R
E T
No
NO
Cont.
F-T A ( u ) N 4 T
F
f
"t664 1920
S/P
D
NO
ilB
Yes
NO NO
c
R R
A,B B,C
No
(c)
B
No
NO
No
No No No No No
P P P P
(c)
3 3 2 3
No No No No
No
NO
'l
5.19.6
Nonylphenol
N o n y l p h e n o lp o l y ( 4 + ) ethoxylates
o o o
No No
15.19.6
Open
15 . 1 . 6 ,16 . 2 . 6 16 . 2 . 9 , 9 , 16A.2.2(aa)
Electrical equipment
h
di Product name
o
I
-o a N a T
r P : n o g
t,
u s tr E
z
N o x i o u sl i q u i d ,N . F . ,( 1 ) n . o . s . ( t r a d e n a m e . . . ,c o n t a i n s. . . ) .1, S.T. Cat.A. N o x i o u s l i q u i d , F . ,( 2 ) n . o . s . ( t r a d e n a m e . . . ,c o n t a i n s. . . ) S . T .1 , C a t . A * N o x i o u s l i q u i d , N . F . ,( 3 ) n . o . s ( t r a d e n a m e . . . ,c o n t a i n s. . . ) S.T.2, Cat. A* N o x i o u s l i q u i d , F . ,( 4 ) n . o . s . ( t r a d e n a m e . . . ,c o n t a i n s. . . ) S.T.2, Cat. A* N o x i o u s l i q u i d , N . F . ,( 5 ) n . o . s . ( t r a d e n a m e . . . ,c o n t a i n s. . . ) S . T .2 , C a t . B "
s
I
;l;tF;
oo
} F
< U h E
E 0
. U o o
-.4
OD
.=:
? o ddr
G ( l
s*
No
2 C Open
No
Yes
No
|5.19
o
B o
!o
2 C Cont
No
No
No
15.19
\ (') 3
I
2 C op:n
No
Yes
o
R
No
No
15.19.6
z.
2 C Cont.
No
No
No
15.19.6
2 C Open
No
Yes
No
No
3 3
* In case of a specific n.o.s. cargo assessedas falling within this n.o.s. group that is carried on a ship, this entry, including the cargo's trade name and one or two principal c o m p o n e n t s , s h o u l d b e p r o v i d e d i n t h e s h i p p i n g d o c u m e n t . A b b r e v i a t i o n su s e d m e a n : N.F.: F.: n.o.s.: Flashpoint exceeding 60'C (closed-cup test) Flashpoint not exceeding 60'C (closed-cup test) N o t o t h e r w i s es p e c i f i e d S.T.: Cat.: m.p.: Ship type Pollution category Melting point
b
bo
Elec'rrical equipment
Product name
a)
o o
o
I
'b
o
6
.Y F S H
i ' l i " l t t
I a
z
N o x i o u s l i q u i d , N . F . ,( 6 ) n . o . s ( t r a d e n a m e . . . ,c o n t a i n s. . , ) S . T .2 , C a t . B , m . p . 1 5 ' C + * N o x i o u s l i q u i d , F . ,( 7 ) n . o . s . ( t r a d e n a m e . . . ,c o n t a i n s. . . ) S.T.2, Cat. B* N o x i o u s l i q u i d , F . ,( 8 ) n . o . s . ( t r a d e n a m e . . . ,c o n t a i n s. . . ) S . T .2 , C a t . B , m . p . 1 5 ' C + * N o x i o u s l i q u i d , N . F . ,( 9 ) n . o . s . ( t r a d e n a m e . . . ,c o n t a i n s. . . ) S . T .3 , C a t . A "
'r
o N
t
.6
c
F C
o | 0lf;f
I t s I I Jlr*E
I X r ,
i " -
h 6
- E c
c 6 ( l
v . :
:?i : s >-c
A O
EI
:to d d
2 C Open
No
Yes
o
R
No
No
( 1 s . 1 9 . 6 ,1 6 . 2 . 6 ) 1 , 16.2.9,16A..2.2
15.19.6(16.2.6, , Cont.16.2.9)f
2C
Cont.
No
No
No
2 C Cont.
No
No
No
't5.19.616.2.6)L (, 16.2.9,164.2.2
2 C Open
No
Yes
o
R
No
No
15.19.6
2 C Cont.
No
No
No
I 5.19.6
ln case of a specific n.o.s. cargo assessedas falling within this n.o.s. group that is carried on a ship, this entry, including the cargo's trade name and one or two principal components, should be provided in the shipping document. Abbreviations used mean: N.F.: F.: n.o.s.: t F l a s h p o i n t x c e e d i n g6 0 ' C ( c l o s e d - c u p e s t ) e Flashpoint not exceeding 60'C (closed-cup test) Not otherwise specified S.T.: Cat.: m.p.: Ship type Pollution category Melting point
i Electrical equipment
m
X
s
Product name
c
I
'o a N 6 .F
a)
V F
q,
I !
V E
rli"l
l
i"'
>
>
.G F
z
N o x i o u ls q u i dN . F .(,11 ) n . o . s . i , (trade name...,contains ...) S.T. Cat.B* 3,
N o x i o u s l i q u i d , N . F . .( 1 2 ) n . o . s ( t r a d e n a m e . . . ,c o n t a i n s. . . ) S . T .3 , C a t . B , m . p . 1 5 " C + * N o x i o u sl i q u i d ,F . ,( 1 3 ) n . o . s ( t r a d e n a m e . . . ,c o n t a i n s. . . ) S . T .3 , C a t . B * N o x i o u s l i q u i d , F . ,( ' 1 4 )n . o . s . ( t r a d e n a m e . . . ,c o n t a i n s. . . ) S . T .3 , C a t . B , m . p . 1 5 " C + * ( N o x i o u sl i q u i d ,N . F . , 1 5 ) n . o . s ( t r a d e n a m e . . . ,c o n t a i n s. . . ) S . T .3 , C a t . C .
.Y
X E
. N F F C
o |6|f x
Yes
nI S l r u E
q ( l
t :
> F
oo oo
: : }U o o
F
: s >-o
G O
c O
:d
da^
No
:!
qr
2 C Open
No
o o
R
No
>
AJ
o
D
zlt
Open
No
Yes
No
No
(, t s . 1 e . 61 6 . 2 . 6 ) I 16.2.9,16A..2.2
15 . 19. 6 ,( 16 . 2 6 , . t6.2.e)I
\
r
2C
Cont.
No
No
No
A)
2C
Cont.
No
No
No
1 1 s . - r 9 .(6 ,6 . 2 . 6 ) L 16.2.9,164.2.2
(16.2.7 to't6.2.9)t
-t
2 C Open
No
Yes
No
No
* In case of a specific n.o.s. cargo assessedas falling within this n.o.s. group that is carried on a ship, this entry, including the cargo's trade name and one or two principal components, should be provided in the shipping document. Abbreviations used mean: N.F.: F.: n.o.s.: Flashpoint exceeding 60"C (closed-cup test) Flashpoint not exceeding 60'C (closed-cup test) Not otherwise soecified
o o
k Electrical equtpment
n E -
(.) o -
o Product name
c
I
'b q N .F
r 9 : n
i"I
l *
t"
< Q : 5
: ^
g
6
z
N o x i o u s l i q u i d , F . ,( 1 6 ) n . o . s . ( t r a d e n a m e . . . ,c o n t a i n s. . . ) S . T .3 , C a t . C . O c t a n e ( a l l i s o m e r s )( b b ) Octanol (all isomers) Octene (allisomers) n-Octyl acetate Octyl aldehydes O l e f i n m i x t u r e s( C s - C r ) ( b b ) 11 9 1
s
3 3 3 3 2C Cont.
F:E
0 l f f
+ |l t+ e c s 'o 6
G { l
:x
? O
S5
.FS > U
dd^
No
No
No
R R
1262
(c)
L
P
P
No No No No No No No No
No Yes No
F No F No F
r
A
No No No No No No No No
o
R
B
L
P P P
D
15 . 1 9 . 6
Yes
No No No No
o
R R R R
(B)
L
3 3 3
5
2 C Cont. 2 C Cont. 2C 2C
Cont. Cont.
15.19.6,16.2.9
"15.19.6
(Cu-C.'u) Olefinmixtures
( a / p h a - O l e f i n sC o - C r a ) mixtures
B B
P P
F
r
1s.19.6
15 . 1 . 6 .16 . 2 . 6 16 . 2 . 9 . 9
* In case of a specific n.o.s. cargo assessedas falling within this n.o.s. group that is carried on a ship, this entry, including the cargo's trade name and one or two principal components, should be provided in the shipping document. Abbreviations used mean: N.F.: F.: n.o.s.: Flashpoint exceeding 60"C (closed-cup test) F l a s h p o i n tn o t e x c e e d i n g 6 0 ' C ( c l o s e d - c u p e s t ) t Not otherwise specified S.T.: Cat: m.p.: Ship type P o l l u t i o nc a t e g o r y Melting point
c b
h Electrical equipment
l
Product name
: n
v a N a T
z
Oleum
=
C
s
s
2C 2C
! s
9 *
Cont.
!--
,'li"l i"' I t E
: A
h .F 9 :
N E
No
n| 3 l " R E > - o u | 0 |f f
G { l G O
.s bo
bD
: E
: i \
< U
& b
E
No
? O
| 8 31
s/P
NF
C
Yes Yes
T T
No F
No
.l 1 5 . ' l1 . 2t o 1 5 . .1 . 8 , 15 . 1 2 .,1 5 . 1 6 . 2 ,5 . 1 7 1 1 , 1s.19,16.2.7,16.2.8 15.19.6 16.2.7 16.2.9 to I s.19.6, 16.2.9 "t5.'t9.6 l 5.12. I 5.17. 15 . 1 3 , 5 . 1 . 6 ,16 . 6 . . t o 1 9 1 16.6.3
15.14,"t5."t9.6
f,h
Oleylamine
Palmkernel acid oil Paraldehyde Pentachloroethane 1,3-Pentadiene P e n t a n e( a l l i s o m e r s )( b b ) -1265 1264
slP 2
P
3
Cont.
No No No No No No No No No NF
2 C Open 2C
Cont.
o
R R
A,B
NO NO
\
I
C
D
slP
s/P
3 2 3 3 3 3 3
T3
ilB NF
No
1669
2 C Cont. 2C
Zl'
T
r-l
No
No No No No
s/P
P P P
q/D
Cont.
No
NO
R R R
No
A,B
(c)
L
Cont
No
15.14,"t5."t9.6
NoCont.15.19.6
C 1897 2312 B C
L
R T T
No
F No No
R
Yes C
1 5 . " t 2 ,. 1 5 . 1 2 . 2 , 15 . 1 9 . 6 1 5 . 1 21 5 . 1 9 , 1 6 . 2 . 7 , , 16.2.8,16.2.9
Phenol
ql
q/P
No No
TI
IIA
No No
2tt
Yes .
A,B
o o
o
Product name
a)
I
a N G 't-
z
P h o s p h o r i ca c i d
s .s
3
V F
S H
b
G ts
d F : C
$lsl$H
6 l f
t E
> F
v . :
: :
>-B
il
^-
d b
No I 5 . 11. 1 t o 1 5 . 1 1 4 , . 'I 1 5 . 11 . 6t o 1 5 . 1 . 8
!a
qJ
1805
F\
2 C Open
No
NF
o
No (k)
No
No
P h o s p h o r u sy e l l o w o r w h i t e ,
q/P
I U
No
15.7, 5.19 1
P h t h a l i ca n h y d r i d e ( m o l t e n ) a/pha-Pinene beta-Pinene P i n eo i l P o l y a l k y l( C t u - C r r ) a c r y l a t e in xylene Polyalkylene xide polyol o Poly(2+)cyclic romatics a p Polyethylene olyamines
2214 2368
q/P
2C 3 3 3
Cont.
No No No No No No No No No
T1
ltA
Yes No No
R R R
No F
f
A,D
No No No No No No No
16.2.7 16.2.9 to
15.19.6
2 C Cont. 2C
2li
B 1272
P P P P P
Cont. Open
c
C
Yes
No Yes Yes Yes NF
o
R
No F No N o A,D No No No
2C 3 2 3 3 2
Cont.
2 C Open 2C Cont.
o
R
2 C Open 2 C Open 2C
Cont
o o
N2
No
NO
Dry
Yes (b)
c r(b)
N5
No
15 - 12 , 15 . 16 . 2 , 15 . 19 . 6
Electrical equipment
bo
Product name
a U -c s
a)
s
c
\ n 'vs cH
OJ
z
P o l y o l e f i n a m i n en i alkyl(C2 Ca)benzenes P o l y o l e f i n a m i n en a r o m a t i c i solvent l P o l y o l e fn p h o s p h o r o s up h i d e , i b a r i u m d e r i v a t i v e( C 2 6 - C 2 5 6 ) Potassium hloridesolution c ( 10 7 o o r m o r e )
N G T
s
3 3 3 2C 2C Cont.
Cont.
. a F F E
(c)
(c)
C
;t;tF;
s
q
h F
< U h E
-*.
>i
r.a
bo
U o
(J
s
F F
n, X
:i
^\
+ o
? q ,
dd'
No
NO
No
R R
No
No
No
I\J
Open
No
Yes
o o o
NO
A,B
No
No
No
NF
No
No
1814
C C C
n
S/P P
q/P
No No No No No
No No
No
N8
No No
"t6.2.9
15.19.6
o o
R R
3
2 3
N o A,D
N2
No No
16.2.9
s
S/P
Yes
No
T F-T
1275
P r o p i o n i ca c i d
1848
2C
No
T1
ilA
No
Y1
h
Etectrical equipment
o o o
o
Product name
o
! q N a I
^ \ i
i'li"l
I I
i"'
:
> F
v . :
: A
z
J
s
l
>U d d
s
2 2
,c
. c F F C
D| 0 l fx
T2 T1
ilA ilB ilA No No No No No
| ^| F, nI Jlt*X
Yes
< U : r
(,
6
SE
LiE
Y1
P r o p i o n i ca n h y d r i d e Propionitrile n-Propylamine P r o p y l b e n z e n e( a l l i s o m e r s ) n-Propyl chloride P r o p y l e n ed i m e r ( b b ) Propylene oxide Propylene tetramer Propylene trimer Pyridine
C C
q/P q/P
2 C Cont. 1 C Cont.
z\f
No No lnert No No No lnert No No No No
R C
T
F-T A,D
No
E N2 E
No
1 5 . 1 2 , 1 5 . 1o 1 5 . 1 9 t7 15-12.15.19
15.19.6
S/P
0
Cont
r2
c
R R R
C
F-T A,D r
F F
2 C Cont. 3
.5
1278
S P
q/P
2 C Cont. 2 C Cont. 2C 2C 2C
Cont.
A,B
No No
(c)
1280 2850 2057 1282 C B B D B B B
15.19.6 .l 5.19.6
"t5.8,15.12.1,15.14, 15.19
2 3
J
T2
ltB
No No No
F.T A,C
F
r
No No No
P P S P
Cont.
Cont. Cont.
R R R
15. 9.6 t
15.19.6
T1
ltA
No
F
NO
N4
No No
Rosin
R o s i ns o a p ( d i s p r o p o r t i o n a t e ds o l u t i o n ) S o d i u ma l k y l( C t o - C r z ) 6 sulphonates 0 - 65% solution
3
5
Yes Yes
NF
o o o
No
No
No
1s.19.6
16.2.6
No
No
No
No
Electrical equpment
e
: F
Product name tr
3
! N G t
^ \ 5
S
S
Y F
eG F
z
Sodium aluminate solution
Sodium borohydride (15'h or less)/Sodium h y d r o x i d es o l u t i o n 1819
. a F F C
D
C
3 3
2 C Open 2 C Open
No
;t;t$;
-.4
G O
h 6
>E
d d
No
bo
: a
: E
n, X
r:
^L
NF
o
o
No
No
N1
q/P
No
NF
No
NO
N1
No
16.2.7
2428
ill
s
q/P
3 2
2t.)
Open
No
NF
o
C
No N o
No No
No
1 s . 9 , 1 5 . 1,6 .s . 1 9 . 6 11 15.12.3,15."t9
2 C Open
No
NF
N2
No
A)
hydrogen Sodium sulphide (6%or less)/Sodium (3% carbonate or less) solution hydrogen sulphite Sodium (45%or less) solution Sodium hydrosulphide (45%or less) solution 2693
Open
No
NT
o o
R
No
NO
NO
1s.19.6
s
s/P
2 C Open
No
NF
No
No
No
2949
tt
2C
Cont.
5 r x
NF
No
No
q/P
lll
Cont.
No
F-T
N1
i Electrical equipment
o o
oo
Product name
3
tr
-tl a N a T
o g
^\n V F b
.G ts O
i'li"l
t t
i"'
*
U.Y
bo
h d
'n
O
z
Sodiumhydroxidesolution S o d i u m h y p o c h l o r i t es o l u t i o n ( 15 % o r l e s s ) S o d i u m n i t r i t es o l u t i o n Sodium petroleum sulphonate S o d i u m s i l i c a t es o l u t i o n S o d i u m s u l p h i d es o l u t i o n ( 15 % o r l e s s ) S o d i u m s u l p h i t es o l u t i o n (25%or less) Sodiumtartrates/sodium succinates olution s S o d i u m t h i o c y a n a t es o l u t i o n (56% or less)
. q F F C
u | 6 |Sf
NF NF
r I J l s * X (,
q
I l s | ^ | e,.
o p
9 ',i 0 b >-o
&a'
N8
N5 No No
t f . t o . l
o { ? U
1824 1791
S S/P
q/P
2 C Open 2C
Cont.
No No
o
R
No No
No No
B B
2 C Open 2 C Open
2lt
No No No No
NF Yes NF NF
o o
o
No No No
No
No No
15.12.3.1,15.12.3.2, 15.16.1,15.19
15.19.6,16.2.6
S/P P
)
J
Open
No No N5
No No
q/P
3 3
2C
Cont.
c o
Yes
T
No
No
NF
No
No
D (B) 2055 B
s
P
No
o o
K I
No
AvB
Y5
No
No
Yes
No
No
No
15. I Y.t)
Styrene monomer
c/P
2C
Cont.
No
T1
ilA
No
A,B N4,Z
No
Elecltrical equipment
bo
Product name
0)
3
'b G
N
i'li"l i"'
z
S u l p h oh y d r o c a r b o n l o n g - c h a i n( C 1 s * )a l k y l a m i n e mixture
.s
5
g
6 c ts .a
s E
No
c ; :
I ^| F , , E| 5|*F
u I ils*X
Yes
t :
-.4
bo a ( l a o >-b
c o 0 n , ! ii ^-
}v . F :
: E
i 6
>E
9 0
> U
d d
No
Zli
Open
No
A,B
"t5.19.6, 16.2.6
g) h
(molten) Sulphur
2448
ill
l(r
Open
o T3
Yes
(t)
NF
NF
F-T N o
No
15 . 1 0
\
I
Sulphuric cid a
1 8 3 0/ 't832
C
C
q/P
2 C Open 2 C Open
o
.l
No
No
No
5 A)
S u l p h u r i ca c i d , s p e n t
SIP
P q/p
No
No
No
No
Talloil (crudeand distilled) Tall oil fattv acid, barium salt Tall oil fatty acid ( r e s i na c i d s l e s st h a n 2 0 % ) Tall oil soap ( d i s p r o p o r t i o n a t e ds o l u t i o n )
N,
B B
3 3 3
No No No
Yes Yes
No No No
No No No
o
o
3 3
(c)
B 1702 B
Yes Yes
NF
P
q/p
J
NO
o
R
No
No No
NO
T e t r a c h o r o e t ha n e l
Cont.
No
h Electrical equtpment
o o
o
Product name
q)
3
c -b a N a .F
r 9 \ i Y F
,'l''l:"
: :
= F
*
.g
b .a
. 6 F F C
z
Tetraethylenepentamine Tetrahydrofuran
Tetrahydronaphthalen(bb) e Tetram eth yl ben ze ne (allisomers) Toluene(bb) Toluenediamine 1294
, I sl"ix u |6|f f
bo ho q Q
.
N
c o
O
U
:i ^L
: E
2320 2056
D D C
S S
D
3
7
No No No No No No
Yes
o
R
No
N1
No
NO
T3
ilB
No
F.T
No No F
15.19.6
3 3 3 2
Yes
Yes No
No No No
o
R
C
16.2.9,164.2.2 15.19.6
't 5 . 1 2 ,1 5 . 1 7 1 5 . 1 9 , , 16.2.7,16.2.9
c
C
P S/P
1709
2 C Cont.
Yes
A,D
Nl
2078 1708
SIP 2 2 3 2
J
2C 2C
Cont.
Cont.
Dry
No No No No
NO
T1
ilA
Yes Yes
Yes Yes Yes
C C
E T
c(c), D
N4
E
No No
1 5 . 1 2 , 1 5 . 1 6 .1 5 . 7 , 2, 1 15.19, 6.2.9 1 15. 12, 15. 17, 15. " 9 15.19.6 15.19.6, 16.2.9, 16A..2.2
c slP
B
P
q/P
T
No
2C O p e n 2 C Cont. 2 C Open
t\)
o
R
2321 2831
B
L-
T
No
A,B
No
NO
o
R
SIP 3
Cont.
NF
No
No
r1
Electrical equipment
h
Product name
3
-b
qJ
h ! . 5 h > * F
9 G
r
a
'"
z )
T r i c hl o r o e t h y l e n e
'r C
a N
t
G ts
F:E
d I ib r\ | *9
ilA
*le"
Yes
| :"'
v . :
> i >:
bo
.
G
o
O O
h n
1710
S/P
)
2
2C 2C
Cont. Cont.
No
T2
T T
No
c slP
P
NO
Yes
NF
c o
A,B, D
No
No
15."12,15.17,15."t9
2 C Open
No
No
\
I
phosphate Tricresyl (containing than 17" less ortho-isomer) phosphate Tricresyl (containing or more l7o ortho-isomer)
T r i d e c a n o i ca c i d Triethanolamine Triethylamine Triethylbenzene
l\)
2 C Open
No
Yes
o
(_
No No 15.19.6
x
.<
2s74(J)
s/P
B D
2 G Cont.
No
T2
ilA
Yes
No
A,B
No15.12.3,15.19
I 5 . 19 . 6 , 16 . 2 . 6 ,16 . 2 . 9 , 16^'.2.2
3
f,
P S S/P P
2 C Open 2 C Open
2\)
No No No
NO
Yes
ilA Yes No Yes
o
o
K
:
J
No No F-T A , C No No N1
No No
3 2 2
o 1 5 . 1 21 5 . 1 9 . 6 , 15.19.6
1296
Cont.
T2
ilA
N2
E
No
2 C Open 2 C Open
(,
Triethylenetetram e in
2259
No
r2
ilA
Yes
o o
N1
NO
oo
Product name
r 9 \ n
!
v s
,'1,:" 1"
I t :
o | 6 |*f
No Yes Yes No
Elecvical equipment
o o
o
: A
v . :
z
T r i e t h y lp h o s p h i t e p Triisopropylated henyl phosphates Trimethylacetic cid a T r i m e t h y l a m i n es o l u t i o n (30% or less) Trimethylbenzene (allisomers) Tri methylhexamethylened i a m i n e ( 2 , 2 , 4 -a n d 2,4,4- isomers) Trimethylhexamethylene ( d i i s o c y a n a t e 2 , 2 , 4 -a n d 2,4,4- isomers) 2,2,4-f rim ethyl-1,3-pentanediol-1 isobutyrate
E a N a T
t.
bo dD q
o
{"<
}U
d O
s
2 2
J
* E
No No No No
nI S l r u E
U
o .!! rL
o-
: n
&aNo No
2323
c/p P
F.T A,B
No No
15.12.1.15.19.6
| 5. | 9.tt
o
R C R
D 't297
Y1 N1
No
1 5 . 1 . 2t o 1 5 . 1 . 8 1 1
( _ s/P
P
F-T A,C
F
E
No
15 . 1 2 , 5 . 1 , 15 . 1 9 , 1 4 16.2.9 15.19.6
No
No
2327
2 C Open
No
Yes
o
C
No
A,C
N1
No
15.19.6
2328
S/P
2C
Cont.
Dry
Yes
c(c)
A
No
1s . 1 2 ,1 5 . 1 6 . 2 , 5 . 1 7 1 , 1 5 . '9 . 6 l
2 C Open 2C
Cont. Cont.
No
Yes
o
R R
No
No
2329 D
s
S
5
No
No No
No No
1 s . 1 2 .,1 5 . 1 6 . 2 , 1 15.19.6
1 5 . .9 . 6 1
2C
No
Product name E
3
o
-tr 'r
N N
I
.g
e.
\ n Y F > l-1
:.N
'l'" I
I I
} F
v . =
: sg
o oo a ( t o >-a
G O := l-
z
1,3,5-Trioxane T r i x y l y lp h o s p h a t e Turpentine U n d e c a n o i ca c i d 1- U n d e c e n e Undecyl alcohol Urea/Ammonium nitrate s o l u t i o n ( c o n t a i n i n ga q u a ammonra) ( Valeraldehyde all isomers) Vinyl acetate
s
2C
F:E No No No No No No
stsl
a | 9 lS s
No Yes No
h n e :
S P
Cont.
F No F No No No
A,D
No No No No No No
15 . 1 9 . 6
15.19 1 5 . '9 . 6 l
A)
o
R
1299
B B B B
P P P P
o o o
R
\ (,)
a x
2 C Open
164.2.2(rl
c
2058 1301 't302 C C
C
S/P
q/p
3
2(t
Cont.
NO
NF
T
E T
N4 No
5
Cont. I n e r t
Cont No
T3
T2 T3
ilB IIA
NO
R R
C
No No
q/P
-)
2 2
2C
No
S/P
1 C Cont, 2 C Cont.
lnert
ilB
No
F-T
N6
E E
x N)
V i n y l i d e n ec h l o r i d e
1303
lnert
r2
ilA
No
F-T
N5
1 5 . 1 3 ,15 . 1 4 , 1 5 . 1 9 . 6 , 1 6 . 6 . 11 6 . 6 . 2 ,
k
Electrical equtpment
o o
oo Product name
r 9
3
E
c
: I
-a c
G 'r
z
Vinyl neodecanoate
t.
a.
a.
s
3 3 2 3
F:E No
-lul$u
c bo q { l
.:S
v . : : !
: -
>-c
:f
^L
:to q o
q/P
2 C Open 2C 2C 2C Cont.
Cont. Cont.
Yes
o
R R R
No
A,B A,B
N1
No
15 . f3 , 15 . 1 6 . 1 ,5 . 1 9 . 6 , 1 1 6 . 6 .,11 6 . 6 . 2 1 5 . 1 3 ,5 . 1 9 . 1 6 . 6 . 1 1 6, 16.6.2 | 5.19.6 1 s . 1 9 . 6 ,6 . 2 . 9 ( w l 1 15.19.6, 16.2.9, 16A*2.2 16.2.7, 16.2.8 15."t9.6, 16.2.6
Vinyltoluene
S/P
No
ilA
No
No
P P
No No No ilA
No No Yes
F F No
No No
s/P 3
P
o o
o
No
(c)
B
3 3
No
Yes
No
No
No
Yes
No
No
127
IBC Code
p q (Deleted). of some on having flashpoint 60'C c.c.,or less; a Requirements based thoseisomers are greater the based isomers havea flashpoint than60'C c.c.,and therefore requirements would not applyto suchisomers. on flammability (all Heptanol isomers) r 16A.2.2 applies 1-undecyl to alcoholonly. Reference Undecylalcohol s Applies ndecyl alcoholonly. to Decylalcohol(all isomers) t to UN No. 1114applies benzene. Benzene having107"benzene more or and mixtures u media. Dry chemical shouldnot be usedas fireextinguishing (40%)mixture (60%)/Nitroethane Nitropropane v Confinedspaces shouldbe testedfor both formic acid vapoursand carbon monoxide product. gas,a decomposition Formic acid w Applies pxyleneonly. to Xylenes x pisomerthe viscosity whichis 23 mPas containing of Applies pisomerand mixtures to ar 20'c. (all Dichlorobenzene isomers) pr-isomer meltingpoint of which is 0'C Appliesto pisomer and mixtures containing the and above. (all Dichlorobenzene isomers) z . aa pisomerthe melting pointof whichis 15'C Applies pisomerandmixtures to containing and above. (all Dichlorobenzene isomers) Applies only to products with the meltingpoint of 15'C and above. poly(4+)ethoxylates Nonylphenol bb identified accordance the provisions the unified in with of Applies oil-like to substances by interpretations regulation of Annexll of MARPOL73178agreed the MEPC. of 14
128
Chapter1B
Listof chemicalsto which the Code
ooesnot appry
I The following are chemicalswhich have been reviewed for their safetyand pollutionhazards and determinednot to presenthazardsto such an extentas to warrantapplication the Code.Thismay be usedas a guide of in considering bulk carriageof chemicals whose hazardshave not yet been evaluated. 2 Althoughthe chemicals listedin this chapterfall outsidethe scopeof the Code, the attention of Administrations drawn to the fact that some is safetyprecautions may be neededfor their safetransportation. Accordingly, Administrations should prescribe appropriate safetyrequirements. 3 Some chemicalsare identifiedas falling into pollution category D and, therefore,subject to certain operationalrequirements Annex ll of of M A R P O L7 3 1 7 8 . 4 Liquid mixtureswhich are provisionally assessed under regulation 3(a) of Annex ll of MARPOL 73/78 as fallinginto pollutioncategoryD, and which do not presentsafetyhazards,may be carried under the entry for "noxious liquid, not otherwise specified" in this chapter. Similarly,those provisonally mixtures assessed fallingoutsidepollutioncategory B, C or as A, D, and which do not presentsafetyhazards, may be carriedunder the entry for "non-noxious liquid,not otherwisespecified"in this chapter.
UN number (column b)
Pollution category ( c o l u m nc )
129
IBC Code A, outsidethe categories B, C or D. Pollution indicates that the product categoryin brackets categorizedand that further is provisionally to dataare necessary completethe evaluation of its pollution hazards. Until the hazard evaluationis completed,the pollution category assigned used. is
a Product name
Acetone
1090
III D
3065
ill
( Alcohols Clr+) (Cr n-Alkanes o*) A l k e n y l ( C r* ) a m i d e 1 Alkenyl(C rz) acid Alkyl(Ce*)amine, estermixture Alkyl(Cg*)benzenes (C6 Afkyldithiothiadiazole -Cz+) s Aluminium ulphateolution s A m noethyld iethan ol am inel s Am noethylethanolamine olution 2-Amino-2-hydroxym ethyl- 1,3-pro paned iol solution(a0% or less) p s A m m o n i u mh y d r o g e n h o s p h a t e o l u t i o n
s Ammonium lignosulphonate olutions
III D
ill
D D 11 0 5 11 0 5 11 0 5 D D
ill
130
Chapter 18 - List of chemicals to which the Code does not apply a Product name
c Pollution category
p Amylalcohol, rimary Animal and fish acid oils and distillates, n . o . s .i,n c l u d i n g : A n i m a la c i d o i l Fishacid oil Lardacid oil Mixed acid oil Mixed generalacid oil Mixed hard acid oil Mixed soft acid oil A n i m a la n d f i s ho i l s ,n . o . s .i,n c l u d i n g : C o d l i v e ro i l Lanolin Neatsfootoil Pilchard il o S p e r mo i l A p p l ej u i c e (C1 Aryl polyolefins 1-C56) Benzenetricarboxylic trioctylester acid, Brakefluid basemix: (C2-C3)glycols/ (Poly(2-8)alkylene C P o l y a l k y l e n(e r - C ro ) g l y c o l s m o n o a l k y( C r - C + )e t h e r s n d t h e i r l a borateesters)t n-Butylalcohol sec-Butvl alcohol tert-Butvl alcohol Butyleneglycol Butyl stearate gamma-Bulyrolactone Calciumcarbonateslurry Calciumhydroxideslurry
ill
D
ill
1120
1120
1120
D
ilt D ill D
Use
131
IBC Code
a Product name
to C a l c i u ml i g n o s u l p h o n a se l u t i o n s alkarylsulphonate Calciumlong-chain ( C rr - C s o ) alkyl phenate Calciumlong-chain ( sulphideCu-Coo) alkyl phenolic Calciumlong-chain a m i n e( C s - C a 6 ) nitrate/ Calciumnitrate/Magnesium s P o t a s s i u mh l o r i d e o l u t i o n c (molten or aqueous e psilon-Caprolactam solutions) C a r a m es o l u t i o n s l (Ct Chlorinatedparaffins q-Cr z) (wirh 52'h chlorine) s C h o l i n ec h l o r i d e o l u t i o n s Citric acid (70% or less)
ilt
D D ill ill D ill ill D D ill ltl D D 11 7 4
Clayslurry
Coal slurry Coconut oil fatty acid methyl ester Cyclohexanol Decahydronaphthalene Dextrosesolution Diacetonealcohol Dialkyl(Cr-Cr :) phthalates glycol Diethylene glycol dibutyl ether Diethylene glycol diethylether Diethylene Diethyleneglycol phthalate acid, Diethylenetriaminepentaacetic pentasodium saltsolution 11 8 4
(D)
ill
D
D D
D
ill D ilt
132
Chapter 18 - List of chemicals to which the Code does not apply a Product name
Di-(2-ethylhexyl) pate adi Diheptylphthalate Dihexylphthalate 1,4-Dihydro-9, ihydroxyanth 10-d racene, d i s o d i u m a l ts o l u t i o n s Diisobutylketone Diisononyl adipate Diisooctylphthalate (bb) Diisopropylnaphthalene 2,2-Dimethylpropane-1,3-diol Dimethylpolysiloxane D i n o n y lp h t h a l a t e Dioctyl phthalate Dipropyleneglycol Ditridecyladipate Ditridecylphthalate Diundecylphthalate Dodecane(all isomers) Dodecenylsuccinic acid, dipotassium salt solution Dodecylbenzene Dodecylxylene D r i l l i n g r i n e s i,n c l u d i n g : b C a l c i u mb r o m i d es o l u t i o n C a l c i u mc h l o r i d e o l u t i o n s S o d i u mc h l o r i d e o l u t i o n s 2-Ethr ',ethanol Ethylacetate Ethylacetoacetate
1 1 4 1
D ilt
ill ill "t157
D D
ill D (D)
ilt D
ilt ill ill
D D
ill
(D)
ilt ill
lll
D
D (D)
1173
133
IBC Code
a
Product name
E t h y la l c o h o l Ethylene carbonate acid, inetetraacetic Ethylenediam salt solution tetrasodium glycol Ethylene glycol acetate Ethylene glycol methyl butyl ether Ethylene glycol phenylether Ethylene glycol phenylether/Diethylene Ethylene glycol phenylether mixture Ethylene-Vinyl acetatecopolymer (emulsion) 2-Ethylhexanoic acid roxymethyl propane-1,32-Ethyl-2-(hyd ) e d i o l ,C 6 - C 1 6 s t e r Ethylpropionate C13*) Fattyacid (saturated ineFerrichydroxyethylethylenediam triaceticacid, trisodiumsalt solution Fishsolubles' Formamide C l u c o s es o l u t i o n Clycerine Dioxanedimethanol G lycerine(B3o/"), (177o)mixture Clycerolmonooleate C lycerolpolyalkoxylate Glvcervl triacetate
D
D (D)
n
D
D ill
D
D I195 D ill D
ill
ilt
ill D
D
ill
(ilr)
'Water-based
134
Product name
s C l y c i n e , o d i u ms a l ts o l u t i o n Clyoxalsolution(40% or less) acid n-Heptanoic adipate Hexamethylenediamine (50% in water) glycol Hexamethylene solutions Hexamethylenetetramine Hexanoicacid Hexanol Hexyleneglycol N-(Hydroxyethyl)ethylenediaminetriacetic s a c i d ,t r i s o d i u m a l ts o l u t i o n lsoamylalcohol lsobutylalcohol lsobutvlformate (Cro-Crr ) lso-and cyclo-alkanes (C12*) lso. and cyclo-alkanes lsophorone lsopropyl acetate lsopropylalcohol Kaolinslurry Lacticacid Lard "h Latex,amnronia(1 or lessfinhibited Latex: Carboxylatedstyrene-Butadiene copolymer Styrene-Butadienerubber acid, sodiumsalt solution Ligninsulphonic 11 0 5 1212
D D
ill
D D 2282
D
ill
D D
ill D
2393
D
ill D
1220
1219
D
ill D ill ill ill
135
c Pollution category
L o n g - c h a ia l k a r y s u l p h o n i c c i d ( C 1 6 n a l Cuo) L o n g - c h a ia l k y l p h e n a t e / P h e n o ll p h i d e n su mixture Magnesium hloride olution c s Magnesium ydroxide lurry h s Magnesiumlong-chain alkarylsulphonate ( C rr - C s o ) 3-Methoxy-1-butanol acetate 3-Methoxybutyl Methyl acetate Methyl acetoacetate M e t h y la l c o h o l M e t h y la m y l k e t o n e Methylbutenol Methyl tert-butyl ether Methyl butyl ketone Methylbutynol Methvl ethvl ketone N-Methylglucamine solution(7O"/" less) or Methvl isobutvlketone 3-Methvl-3-methoxvbutanol 3-Methyl-3-methoxybutyl acetate Methyl propyl ketone N-Methyl-2-pyrrolidone Molasses Myrcene ^t249 1245 11 9 3 1231
D
ill ill ilt D ill D ill
D 't230
1110
D D
(D)
2398
D D
ill
136
c Pollution category
N a p h t h a l e n e s u l p h o n ic i d ac Formaldehyde copolymer,sodium salt solution Nitrilotriacetic acid,trisodiumsalt solution N o n a n o i c c i d ( a l li s o m e r s ) a monomer Nonyl methacrylate . N o x i o u sl i q u i d ,n . o . s ( 1 7 ) ( t r a d en a m e. . . ,c o n t a i n s . . )C a t .D . i . N o n - n o x i o uls q u i d ,n . o . s ( 18 ) ( t r a d en a m e . . . ,c o n t a i n s. . )A p p e n d i xl l l " . Octanoicacid ( a l lisomers) Octyl decyl adipate
D
D D (D)
D
ill D ill
D
ill D
D D
ill D
(ilr)
D D ill
'
as In case of a specificn.o.s.(not otherwise specified)cargo assessed falling within this n.o.s. group that is carried on a ship, this entry, including the cargo's trade name and one or two principal components, should be provided in the shipping document.
137
IBC Code
a
c Polluilon category
Product name
Polybutene P o l y b u t e n y lu c c i n i m i d e s (molecular weight 2000+) Polyether glycol Polyethylene glycoldimethylether Polyethylene sodiumsalt solution Polyglycerin, (containing than 3% sodiumhydroxide) less Polyglycerol Poly(4+)isobutylene (molecular weight 300+) Polyolefin e P o l y o l e f i n m i d ea l k e n e a m i n( C 2 s * ) a borate Polyolefin amide alkeneamine (Cza-Czso) Polyolefin amide alkeneamine/ mixture molybdenumoxysulphide polyol Polyolefin amide alkeneamine Polvolefin anhvdride Polyolefin ester(C2s-C256)
P o l y o l e f i np h e n o l i c a m i n e ( C 2 6 - C 2 5 6 )
ilt D
D ill ilt ill ill ill ill
D
D
ill
D D D
D ill ill D ill 1276 1274 D ill ill ilt D
Poly(20)oxyethylene sorbitanmonooleate Poly(5+)propylene glycol Polypropylene Polysiloxane n-Propylacetate n-Propyl alcohol PropyleneButylene copolymer glycol Propylene glycol methyl ether acetate Propylene
138
glycol monoalkylether Propylene Sodiumacetatesolutions tl S o d i u ma l u m i n o s i l i c a seu r r v Sodiumbenzoate s S o d i u mc a r b o n a t e o l u t i o n solutions Sodiumpoly(4+)acrylate Sodiumsulphatesolutions Sorbitolsolution (n S u l p h o h y d r o c a r b oC : - C a a ) Sulpholane Tallow Tallow fatty acid glycol Tetraethylene Tridecane Tridecylacetate Triethylphosphate glycol Triethylene Triisopropanolamine polyethoxylate Trimethylolpropane 1,3-pentanediol 2,2,4-Trimelhyldiisobutyrate glycol Tripropylene Urea/Ammoniummono- and di-hydrogen phosphate/Potassium chloridesolution n s Urea/Ammonium itrate olution solution Urea/Ammoniumphosphate resinsolution Urea formaldehyde U r e as o l u t i o n
(D)
ill ill ill D ill ill D ill ill (D) n D ill ill
139
c Pollution category
n V e g e t a b l e c i d o i l sa n d d i s t i l l a t e s ,. o . s . , a including: corn acid oil, cotton seedacid oil, dark t m i x e da c i do i l ,g r o u n d n ua c i do i l ,m i x e d acid oil, mixed generalacid oil, mixed hard acid oil, mixed soft acid oil, acid oil, soya rapeseed acid oil, safflower acid oil. sunflowerseedacid oil o V e g e t a b l e i l s ,n . o . s .i,n c l u d i n g : oil, babassu beech nut oil, castoroil, cocoa butter,coconut oil, corn oil, cotton seedoil, groundnutoil, hazelnut o , o i l ,l i n s e e d i l ,n u t m e gb u t t e r o i t i c i c a i l , o o l i v eo i l , p a l m n u t o i l , p a l m o i l , p e e l o i l ( o r a n g e s n d l e m o n s )p e r i l l a i l , p o p p y o a , seedoil, rapeseedoil, rice bran oil, raisin oil, oil, safflower saladoil, sesame oil, soya bean oil, sunfloweroil, tucum oil, t u n g o i l , w a l n u to i l Vegetableproteinsolution(hydrolysed) Water Waxes Z i n c a l k e n yc a r b o x a m i d e l
140
lg.l
General
19.1.1 Chapters 1 to 16 apply to incineratorships, as relevant,and as or of supplemented modified by the provisions this chapter. lg.l.2 Information the compositionand the hazardsof the waste to be on o i n c i n e r a t e ds h o u l d b e m a d e a v a i l a b l et o t h e A d m i n i s t r a t i o n r p o r t Administration, both, as appropriate,which may prohibit carriageof or to those wastesdeemed to be too hazardous be carriedin bulk.. apply: 19.1.3 The followingadditionaldefinitions .1 Incineratorspace is a gastight space containing solely the incinerator and its associated auxiliaries. the blowerswhich Incinerator blower spaceis a spacecontaining burners. supplycombustionair to the incinerator London Convention 1972 means the Convention on the Prevena b t i o n o f M a r i n eP o l l u t i o n y D u m p i n go f W a s t e s n d O t h e r M a t t e r at Sea,1972.
.2
.3
.4 Cargo area is that part of the ship defined in 1.3.5, excluding incinerators and chemicalwaste piping leadingto the incinerators. s t 9 . 1 . 4 D u r i n g t h e p e r i o d i c a la n d i n t e r m e d i a t e u r v e y sr e q u i r e d u n d e r a 1 . 5 . 2 . 1 . 2 n d . 3 , a l l c a r g o t a n k s a n d t h e c a r g o p i p i n g s y s t e ms h o u l d b e of inspectedfor corrosionand the remainingthickness materialshould be inspections Where severely wasteshavebeen carried, corrosive determined. of cargo tanks and the cargo piping systemfor corrosionshould be held d d t o a a n n u a l l y n d t h e r e m a i n i n gh i c k n e s s f m a t e r i a l s e t e r m i n e d u r i n gt h o s e inspections.
The environmentalaspectsof incinerationand dumping of wastes are regulated by rhe 1972 London Convention.The SixteenthConsultativeMeeting of Contracting Partiesto the London Convention in November 1993 adopted amendments to the Convention (resolution 1C.50(16)) which entered into force for all Contracting Parties on 21 February 1994, and which provide that incinerationat sea of industrialwastes is prohibited. '
"t 41
SCANNED BY KIVAN ( MKP ) 2004
IBC Code
and of for Convention the controlof incineration wastes Thestandards out by the London set other matterat seashouldalsobe observed.
143
IBC Code ,|9.5.2Arrangements the cargo piping and controlsshould be such as to of preclude the dischargeoverboard of wastes intended to be incinerated op d u r i n gn o r m a lc a r g o - h a n d l i n g e r a t i o n s . may be connectedin front of the 1g.5.3 Oil fuel and cargo piping systems and the oil fuel pipesare cocksare installed providedthat three-way burners, space. insidethe incinerator nonreturnvalves fitted with two screw-down 13.5.4 Remoteshutdowndevicesto cut off the supplyof wasteand fuel for incinerationshould be fitted at the control station and on the navigating bridge. Shutoffvalvesshould be located in the cargo area.Where shutoff valvesare remotelycontrolled,provisionfor local manualoperationshould manuallyoperatedvalve should be fitted' be made,or a separate shouldbe providedwith of 1S.5.5Flanges the loadingmanifoldconnections which may be portable,to guard againstthe danger of the cargo shields, Drip traysshouldalso be provided. being sprayed.
l9.6 Materials of construction - is by for requirementsmaterials replaced the 6.2 13.6.1 Section - special
following: .l Aluminium, copper, copper alloys, zinc, galvanizedsteel or valves, mercury should not be used for cargo tanks,pipelines, fittingsand other equipmentwhich may come into contactwith o t h e l i q u i dw a s t e s r t h e i rv a p o u r . g25"C, Materialsof constructionhaving a melting point below used for external e.g. aluminium and its alloys,should not be operationson ships intended piping involved in cargo-handling the carriageof wasteswith a flashpointnot exceeding60'C for (closed-cup test). Short lengthsof externalpipes connectedto if cargo tanks may be permittedby the Administration they are insulation. providedwith fire-resistant the corrosivity of the scantlings the cargo system, In determining of the waste should be taken into account.
.2
.3
19.9 Electricalinstallation
19.9.1 In incinerator spaces, incinerator blower spaces, and adjacentspaces having direct accessthereto, the lighting systems,telephone and public addresssystems and generalalarm systems should be of the certifiedsafe type. 19.9.2 All other electrical installations which are fitted in the spaces referred to in 19.9.1 should be of the certified safe type unless the following conditionsare comoliedwith: .1 lt is assuredthat the spacesare adequatelyventilatedprior to activatinginstallations not of a certified safe type. Interlocks should be provided between fans and the switchgearof such installations ensurecompliancewith this requirement. to lnstallations of a certifiedsafe type should be automatically not s w i t c h e d f f i n c a s eo f l o s so f t h e p r e s s u r ee q u i r e d y 1 9 . 1 1 . 2 . 1 o r b a n d 1 9 . 1 . 3 . 1 . r e a s o n a b lte m e d e l a ym a y b e p e r m i t t e d y t h e 1 A i b Administration before these installations switchedoff. are Installations not of a certified safe type should comply as a m i n i m u mw i t h l P 5 5 . o r e q u i v a l e np r o t e c t i o n . t
.2 .
.3
145
SCANNED BY KIVAN ( MKP ) 2004
IBC Code
spaceshouldbe permanent, systemof the incinerator The 19.11.2 ventilation of and independent all other air supply type normallyof the positive-pressure systems. .l within shouldalwaysbe positiveto the pressure The air pressure the furnace(seealso 19.9.2.2).
.2 A minimum capacityof 45 changesof air per hour should be space' provided,basedupon the total volume of the incinerator during maintenance should be givento ventingrequirements Consideration of burners. The ventilationsystem of the incineratorblower space should be 19.11.3 of type permanent, normallyof the positive-pressure and independent other systems. air supply within shouldalwaysbe positiveto the pressure .1 The air pressure t h e f u r n a c e( s e ea l s o 1 9 . 9 . 2 . 2 ) . .2 A minimum capacityof 20 changesof air per hour should be blower provided,basedupon the total volume of the incinerator space.
19.t3 Personnelprotection
'14.2, and includingrespiratory The safetyequipment describedin 19.13.1 eye protectionfor every person on board describedin 14.2.8,should be provided.
146
Chapter20
Transportof liquid chemical wastes
. f l c
2g.1 Preamble
20.1.1 Maritimetransport liquidchemical of wastes could present threatto a human healthand to the environment. 20.1.2 Liquid chemicalwastes should,therefore,be transportedin accordancewith relevant international conventions and recommendations and,in particular, where it concernsmaritimetransportin bulk, with the requirementsof this Code.
20.2 Definitions
For the purposeof this chapter: 20.2.1 Liquidchemical wastesare substances, sotutions mixtures, or offered for shipment,containingor contaminated with one or more constituents which are subjectto the requirements this Code and for which no direct of use is envisaged but which are carriedfor dumping,incineration other or methodsof disposal other than at sea. 20.2.2 Transboundary movement means maritime transportof wastesfrom jurisdiction one countryto or throughan area an areaunderthe national of jurisdiction anothercountry,or to or throughan area under the national of not under the nationaljurisdiction any country,provided at least two of countries are concerned the movement. by
20.3 Applicability
20.3.1The requirements thischapterare appticable the transboundary of to movement liquidchemical of wastes bulk by seagoing in shipsand shouldbe considered conjunction in with all other requirements this Code. of 20.3.2 The requirements this chapterdo not apply to: of .f wastesderivedfrom shipboardoperations which are coveredby the requirements MARPOL73/78; of
.2 liquid chemicalwastescarriedby shipsengagedin the incineration of suchwastesat seawhich are coveredby chapter19 of this ' Code; and .3 substances/ solutionsor mixturescontainingor contaminated with radioactive materials which are subjectto the applicable requirements radioactive for materials. 'l47
IBC Code
20.4 Permittedshipments
20.5 Documentation
in specified 16.2 of thisCode,ships 20.5.f In additionto the documentation wastes shouldcarry movementof liquidchemical in engaged transboundary authority of by documentissued the competent on boarda wastemovement the countryof origin.
of .2 any additional requirements this Code applicableto the presenting the or, substance in caseof a mixture,its constituent predominanthazard.
148
Appendix Model form of lnternational Certificate of Fitness the Carriage for of Dangerous Chemicals Bulk* in
INTERNATIONAL CERTIFICATE FITNESS THE CARRIAGE OF FOR O F D A N C E R O U S E M I C A LN B U L K CH IS
(Official seal)
(full official designation of the competent person or organization recognizedby the Administration) Distinctive numDer r o
| trfftrrc
Name of ship
Port of registry
Cross tonnage
The Certificate shouldbe drawn up in the officiallanguage the issuing of country.lf the language usedis neither English French, text shouldinclude translitioninto one of nor the a theselanguages.
'
'149
SCANNED BY KIVAN ( MKP ) 2004
IBC Code
Date on which keel was laid or on which the ship was at a similarstageof to or construction (in the caseof a convertedship)date on which conversion chemicaltankerwas commenced:
The ship is exempted from compliance with the following provisionsof the Code:
THIS ISTO CERTIFY: .l That the ship has been surveved in accordance with the p r o v i s i o n o f s e c t i o n1 . 5 o f t h e C o d e ; s
.2 that the survey showed that the construction and equipment of of the ship compliedwith the relevantprovisions the Code; '.3 that the ship is an incineratorship complying also with the of and modified requirements chapter 19; supplementary
with That the ship has been providedwith a manual in accordance as the standardsfor proceduresand arrangements called for by 5, regulations 5A and 8 of Annex ll of MARPOL73l78, and that the and equipmentof the ship prescribedin the manual arrangements are in all respects satisfactory and comply with the applicable of requirements the said Standards;
' Delete as appropriate.
150
SCANNED BY KIVAN ( MKP ) 2004
Appendix
That the ship is suitablefor the carriagein bulk of the following products, provided that all relevant operationalprovisionsof the Code are observed:
3,4
Products
* Continuedon attachment1, additionalsignedand dated sheets * Tank numbersreferredto in this list are identified attachment on 2. signedand dated tank plan.
'1.4 That, in accordancewith rnd'2.8.2, the provisionsof the Code are modified in respectof the ship in the {ollowingmanner:
That the ship must be loaded: '.1 in accordance with the loading conditions provided in the approved loading manual,stamped and dated officerof the Administration, of an and signedby a responsible or organization recognizedby the Administration; *.2 in accordance with the loading limitations appended to this Certificate. Where it is requiredto load the ship other than in accordance with the above instruction, then the necessarycalculationsto justify the proposedloadingconditions shouldbe communicated the certifying to Administrationwho may authorize in writing the adoption of the proposedloadingcondition.f
' '
Delete as appropriate. Instead of being incorporated in the Certificate, this text may be appended to the Certificate if duly signed and stamped.
151
SCANNED BY KIVAN ( MKP ) 2004
IBC Code
s T h i sC e r t i f i c a t ie v a l i du n t i 1 . . . . . . . . . . . . with 1.5 of the Code. in subjectto surveys accordance
Notes on completion of Certificate: 1 2 can be issuedonly to shipsentitledto fly the flagsof The Certificate to which are Parties both SOLAS74 and MARPOL73178. States Ship type: Any entry under this column must relate to all relevant "type 2" should mean type 2 in all e.g. recommendations, an entry prescribed the Code. by respects productslistedin chapter17 of the Code,or which havebeen Products: with 1.1.3of the Code, in by evaluated the Administration accordance "new" products,any special should be listed.In respectof the latter s y r e q u i r e m e n tp r o v i s i o n a l lp r e s c r i b e d h o u l db e n o t e d . l t s h o u l db e s waste" is to be entered ships"liquid chemical noted that for incinerator l i n l i e u o f t h e i n d i v i d u ap r o d u c tn a m e s . to The listof productsthe shipis suitable carryshouldinclude Products: of the noxiousliquid substances categoryD which are not coveredby D a " c h a p t e r1 8 c a t e g o r y " . t h e C o d e a n d s h o u l db e i d e n t i f i e d s of on The limitations the carriage categoryB or of Conditions carriage: under 16A.2 of the Code should also be category C substances indicated.
152
Appendix
ENDORSEMENT FOR ANNUAT AND INTERMEDIATE SURVEYS THlsls ro CERTIFY at a survey that required 1.5of thelnrernational by Code for the Construction Equipment ships and of Carrying -provisions Dangerous Chemicals in Bulk,the shipwasfoundto complywith the rerevant of the
Code.
Annualsurvev:
(sealor stampof the Authority, as appropriate) Annual"/lntermediate* survev: Signed: (signatureof duly authorized officiat) Place:.............. Date:............... (sealor stampof the Authority, as appropriate) Annual survey: Signed: (signatureof duly authorized officiat) Place:.............. Date:.............. (sealor stampof the Authority, as appropriate)
. Deleteas appropriate.
153
IBCCode
. :A'
154
Appendix
155
SCANNED BY KIVAN ( MKP ) 2004
.l
listedin these chapters well as abbreviations Chemicals as are Alternative namesare shown in lower case shown in capitals. l e t t e r s i t h a n i n i t i a c a p i t a lI.f t h e c h e m i c ailn c o l u m n1 i s l i s t e d n w l i r c h a p t e r1 7 o r c h a p t e r1 B t h e r e l e v a n t e f e r e n c es i n d i c a t e d n i i to column 2. Where no reference an appropriate chapteris given in column 2, the name of the basicchemicalis given and the chapterreferences and conditions carriage that chemical of for A a r ea p p l i c a b l e . n a s t e r i s ( * ) a l o n g s i d a c h e m i c an a m es i g n i f i e s k e l with the system nomenclature the of that the name conforms of ( I n t e r n a t i o n a l n i o n o f P u r ea n d A p p l i e dC h e m i s t r yI U P A C ) . U Prefixesforming an integral part of the name are shown in ordinary(roman) type and are takeninto accountin determining Theseincludesuch prefixes the alphabetical order of entries. as:
Mono Di Tri
.2
Tetra
Penta lso
Bis
Neo
Ortho
.3
for Prefixes that are disregarded purposesof alphabetical order a r e i n i t a l i c s n d i n c l u d et h e f o l l o w i n g : a nsectertomp' N. (normal-) (secondary-) (tertiary-) (ortho-) (meta-) (para-)
dtc,st rans(E)-
(z)-
oSYMUNS-
alphabetagammaepsilon-
(u)
(p) (v)
(e)
whereit the UN numberof the chemical, 2 Column3 of the indexgives tablenumberin the MedicalFirst the appropriate is avaifable. Column4 gives InvolvingDangerous Coods (MFAC number). Aid Cuide for Use in Accidents of to Column5 refers the year of revision the entry.Where no year is given, before 1993 the entry appeared
157
IBC Code
Name Acetaldehyde cyanohydrin *AcETlc ACID * A C ET t c A N HvD RID E ACetic ester Acetic ether Acetic oxide ACetoacetic ester ACETOCHLOR * AC E T o N E ACEToNECYANOHYDRIN *ACEToNTTRTLE Acetylene tetrachloride Acetyl oxide Acroleic acid * A C R Y L AM T DE (s0 S OL UT T ON % OR LESS) *ACRYLIc ACID Acrylic acid, 2-hydroxyethyl ester A c r y l i c a m i d e so l u ti o n , 5 0 % o r less Acrylic resin monomer AC R Y L o N IT RIL E AC R Y L O N IT RIL E -S T Y R E NE OLYMER COP D I SP E R S ION P OL Y E T HEP OLYOL IN R *ADrPoNrrRrLE " (9 AL AC H L O R E CH NIC A L o % o R MORE) T Alcohol Al c o h o l , C 7 Alcohol, Cs Al c o h o l , C e Al c o h o l , C 1 s Alcohol, C11 Al c o h o l , C 1 2 A L C o H o L r c B E V E RA C E S , .s. N.o A L C o H o L (cr2 -crs) p o l y(1 -6 )ETHOXYLATES A L C O H O L ( C 1 2 - C r P)O L Y ( 7 - 1 9 ) - i - . s ETHOXYLATES p o l y(2 o +)A L C o H o L (c1 2 -c1 s) ETHOXYLATES A L C o H o L S (c1 3 *) A L C O H O L (C 6 -C rr) (S E C OND A RY) POLY(3-6)ETHOXYLATES A L C O H O L (c6 -c1 r) (S E C OND A RY) POLY( 12 )ETHOXYLATES 7Aldehyde collidine Aldehydine ( A L KA N E SC u -C s) (C n - AL KA N E S to *) (Ce-C2o) ALKARYL POLYETHERS ALKENYL(C1'*)AMIDE A L Kv LA C R yL A T E -vtNyL p yR tDtNE C O P O L YME R T OL UE N E IN (C AL KY L ( C B*)A MIN E ,K E NY L rz*) AL ACID ESTER MIXTURE A L Kv L B E N Z E N A L K vL IN DA N E , E, (E A L KY L T N DE N E X T U RE A C HC12- C1) MT A L KY L ( C 3 -C 4 )B E N Z E N E S A L KY L ( C s -CB )B E NZ E NE S A L KY L ( C e +)B E NZ E NE S A L KY L BE NZ E NE S U L P HON CID A IC A L Kv L B E N Z E N E S UL e H ONIC A CID, S O D I U M SA L TS OL UT ION ALKyLDfrHrorHrADrAZoLE(Cu-Cz+) ALKYL(Cr-Cg) NTTRATES ALKyL(cz-cr 1)pHENoLpoly(4- 12)ETHOXYLATE
See UN No. MFAG LACTONITRILE SOLUTION '{'; (Bo% oR LESS) Chapter 1 7 7OO Chapter 1 7 1715 7O O ETHYLACETATE ETHYLACETATE ACETIC ANHYDRTDE ETHYLACETOACETATE ChapterlT Chapter 1 B 1090 300 Cha pter 17 1541 2'l5 '1648 ChapterlT 215 TETRACHLOROETHANE ACETICANHYDRIDE ACRYLIcACID Chapter 17 2074 323 Chapter 1 7 2218 7O O 2-HYDROXYETHYL ACRYLATE ACRYLAM IDE SOLUTION (s0% oR LESS) METHYLMETHACRYLATE Chapter 1 Z 1 093 21 5 Chapter 18 Chapter 17 Chapter 1 7 ETHYL ALCoHoL HEPTANoL( ALLtsoM ERs) ocrANoL (ALL tsoMERS) NoNyL ALCoHoL ( ALLtsoM ERS) DECvLALCoHoL ( ALLtsoMERS) UNDECYL ALCOHoL DODECYL ALCOHOL Chapter 18 Chapter 1 Z ChapterlZ Chapter 17 Chapter 18 Chapter 1 7 Chapter 17 2-METHYL-5-ETHYLPYRIDINE 2-METHYL-5-ETHYLPYRIDINE Chapter 1 7 Chapter 18 Chapter 17 Chapterl8 Chapter 17 Chapter 1B Chapter 17 . 22OS 215
Rev.
1997
1993
1993
3065
305 1993
1993 19 9 3 19 9 3 19 9 3 1993
Chapter 17 C h a p t e r1 7 Chapter18
Chapter 1 Z Chapter 1 7 Chapter 1B
700 700
Chapter 17
Chapter 1 7
1gg7
158
Name *A L L Y L A L C o Ho L *A L L v L C HL o R T D E *A L U M TN |UM (3 CH L ORT DE 0 % OR LESS) / H YD ROC HL OR TA C|D (2 O %OR LESS) C SO L UT ION *AL U M TN T U M S UL e H A T E L UTtoN so Aminoacetic acid, sodium salt solution Aminobenzene l - A m i n o b u ta n e 2 - A m i n o b u ta n e Aminocyclohexane Aminoethane Aminoethane solutions, 72o/oor less * 2-Aminoethanol *z - 1 2 - n vrNo E T Ho xy)E T H A NoL " 2-(2-Aminoethylamino)ethanol A M I N OE T H Y L DIF T H A NOL AM INE/ AM INOETHYLETHANOLAM E IN SOLUTION AMINOETHYLETHANOLAMINT N - A M I N OE T H Y L P IP E RA Z TNE 1-(2-Aminoethyl)piperazine * z-AMtNo-2-HyDRoxyMETHyL1 , 3 - PR OP AE DIOLS OL UTION N (40% OR LESS) 2 - Am i n o i so b u ta n e A m i n o me th a n e so l u ti o n s, 42"/" or less 1-Amino-2-methylbenzene 2 - A m i n o l -me th yl b e n ze n e *2-AMINo-2-METHvL-1-pRopANoL (eo% oR LESS) Aminophen 1 - A m i n o p ro p a n e 2 - Am i n o p ro p a n e 2-Aminopropane (7O% or less) solution
Chapter 18 CLYCINE, SODIUM SALT SOLUTION ANILINE BUTLAM|NE ( ALLISOMERS) BUTLAM |NE ( ALLISOM ERS) CYCLOHEXYLAMINE ETHYLAMINE ETHYLAMINE SOLUTIONS ( 72% OR LESS) cTHANOLAMINE Chapter 17 AMtNoETHvLETHANoLAMINE Chapter 18
3055
320
2815
320 325 1I
BUTLAM|NE ( ALLISOM ERS) METHYLAM INE SOLUTIONS (42% OR LESS) o-TOLUIDINE o- TOLUIDINE Chapter 1 7 ANILINE n-PROPYLAMINE ISOPROPYLAMINE (7o"/,OR LESS) ISOPROPYLAMINE
lt
* 1-Aminopropan -2-ot
* 1 - Am i n o 2 -p ro p a n o l * 3 - Am i n o p ro p a n -1 -o l 2 - Am i n o to l u e n e o - Am i n o to l u e n e *AMMONTA A Q U E O U S( 2 8 % O R L E S S ) Am m o ni a w a te r, 2 8 % o r l ess AM M O N IUM B IS UL P H ITS O LUTION( 70% E o R LE S S ) A M M O NIU M HY D ROC E NP HOSPHATE SO L U T ION *A m m o ni u m h yd ro g e n su l p hite
,,3?k3I'IJ"LAMTNE
tsopRopANoLAMlNE n- PROPANOLAM INE I- TOLUIDINE o- TOLUIDINE chapter 1Z AM M ONIA AQUEOUS ( 2 8 %O R L E S S ) Chapter 1 7 Chapter 1B AMM oNtuM BtSuLPHtTE lt
. .: i, ,
2672
725
, , . , :1!
Jit'liil8,lJb3R
(28% OR LESS) Chapter 1B Chapter 17 Chapter 1B Chapter 1B Chapter 17 Chapter 17
LESS)
1997 235
2683
225
159
IBC Code
Name * AM M o N t u M See Chapter 17 UN No. MFAG : 1993 1104 330
T Hto su L p H A T Eso LUTr oN (60% oR LESS) n-Amyl acetate sec-Amyl acetate (A A M Y L A C E T A T E L LIS OME RS ) Amyl acetate, commercial Amylacetic ester Amyl alcohol n - A M Y LAL C OHOL sec-AMyL ALCOHOL t e r t - A M Y L L COH OL A AM Y L A L COHOL ,P R IMA R Y Amyl aldehyde Amyl carbinol alpha-n-Amylene Amylene hydrate tert-Amylenes Amyl ethyl ketone Amyl hydrate Amyl hydride Anaesthetic ether *ANILINE Aniline oil A n i m a I a c id o i | A N T M AL AND F rsHA C ID o rL S A ND Dt} TILLATES N.O.S. A N I M A L AND F IS HOIL S ,N .O.S . Anthracene oil (coal tar fraction) Ant oil, artificial APPLE UrcE J Aqua fortis (C1,' ARYLPOLYOLEFINS -Cuo) (cB eARAFFINS AVTATToN ALKvLATES A N D |S O-P A R A F F TB .P T 9 s-120' C) NS . * Azepane Azotic acid ,
(ALLTSOMERS) AMYL ACETATE ACETATE ISOMERS) (ALL ISOMERS) AMYL ACETATE Chapter 17 (ALLtsoMERs) AMYL ACETATE (ALL ISOMERS) AMYL ACETATE n-AMYL ALCOHOL Chapter 1 B Chapter 1 8 Chapter 18 Chapter 18 (ALL VALERALDEHYDE ISOMERS) HEXANoL (ALLISOMERS) PENTENE tert-AMYL ALCOHOL (ALLISOMERS) PENTENE ETHvLAMvL KEToNE n-AMYL ALCOHOL (ALLISOMERS) PENTANE DIETHYL ETHER Chapter 17 ANILINE ANIM AL AND FISHACID oILS AND DISTILLATES, N.O.S. Chapter 1B Chapter 18 coAL TAR FURFURAL Chapter 18 NITRICACID (7O"/" AND OVER) Chapter 1 B Chapter 1 Z HEXAMETHYLENEIMINE NlTRtc AC|D (7Oo/" AND OVER)
1547
335
Babassu oil vECETABLE otLS, N.o.s. Ba n a n a o i l (ALL ISOMERS) AMYL ACETATE Ba t t e r y a c i d SULPHURIC ACID Beech nut oi| VECETABLE OILS,N.O.S. Beechwood creosote CREOSOTE Behenyl alcohol ALcoHoLS (cr3*) BCNZenam ine 2-METHYL-6-ETHYLANILINE * B E N Z EN E A N D Mtxru R E SH A V T NG10% Chapter 1 7 , BENZENE R MORE O * B E N Z . EN E S UL e H o NvL cHL o R tDE Chapter 17 B E N Z EN E T RIC A RB OX Y L IC A CID,TRIOCTYL Chapter 1B ESTER, Benzol BENZENE AND MtxruRES HAVI N C 1 O %B E N Z E N E R M O R E O Benzole BENZENE AND MIXTURES HAV. I N C 1 O %B E N Z E N E R M O R E O B e n z o p h e no l PHENOL (2-Benzothiazolylthio) sodium solution MERCAPTOBENZOTHIAZOL, SODIUM SALTSOLUTION 'l * BENZYLACETATE Chapter 7 * BENZYL ALCoHoL Chapter 1 7 Benzyl butyl phthalate BUryL BENzyL eHTHALATE "17 * B E N Z v Lc HL o Rf D E , Chapter Betu|a oi| METHYLSALICYLATE * Biphenyl otpHENyL * Bis(2-aminoethyl)amine DIETHYLENETRIAMINE Bis(chloroethyl) ether DICHLOROETHYL ETHER * Bis(2-chloroethyl) ether DICHLOROETHYL ETHER *Bis(2-chloro-1-methylethyl) ether 22lDtclloRorsopRopyl ETHER
'11'14 2225
312 7O O
19 9 3 305 '1738 7 40
160
SCANNED BY KIVAN ( MKP ) 2004
.B:Eloic acid
o,t1lltLrLHEXyL) ADrpArE DI-(2-ETHYLHEXvL)pHoSpHoRtC ACID DtocTyL PHTHALATE DTETHANOLAMTNE DtocryL eHTHALATE Chapter18 FURFURAL chapter l z 1BB7 (ALL BUTvRALDEHvDE rsoMERs) (ALL BUTRALDEHvDE rsoMERS) (ALL BUTYRALDEHYDE TSOMERS) BUryLENE clycol BUTYLENE CLYcoL BUryLENE clycol BUWLENE CLYCOL BUryLENE CLYCOL BUryLENE cLyCoL
'lgg
34s
:|,U#:i..?3"o,_
:B:[tl::i
n-Butanorr
i;:v,]if'^:?B:'", ;Tii,li't[35'"'
sec-BUTYL ALCOHOL tert-BUTYLALCOHOL (ALL tsoMERS) BUryL ACETATE (ALL rsoMERS) BUTYLACETATE gamma-BUTYROLACTONE . 1anna-BUTYROLACTONE METHYLETHYL KETONE METHYLETHYL KETONE CROTONALDEHYDE cRoToNALDEHvDE ( OCTENE ALLTSOMERS) MALETC ANHYDRTDE '17 Ch apter n-BUTYLETHER ETHvLENE clycol MoNoALKyL ETHERS ETHYLENE r1Jl-ry clycol MoNoALr, CLYCOL MONOALKYL ; 'lgg. 1gg. - :
sec-Butanol tert-Butanol Bultanol acetate 2-Butanol acetate 1 , 4 - B u ta n o l i d e * Butan-4-olide *2.Butanone " BUtAn-2-one * 2-Butena| . (E)-But-2-enal anhydride BUTENE oLtcoMER " l-Butoxybutane "2-Butoxyethanol B u t e n e d i me r "crs-Butenedioic
199: '1993
*2-tert-Butoxyethanot * 2-(2-Butoxyethoxy)ethanot
*2-(2-Butoxyethoxy)ethyl acetate
pilff::,ALKyLENE GLycoL
MONOALKYL(Cl -C6) ETHER roLv(2-B)ALKvLENE clycol MONOALKYL (Cl-C6) ETHER ACETATE ETHYLENE CLYCOL BUTYLETHER ACETATE (ALLtsoMERS) BUryL ACETATE chapter 1 Z (ALL rsoMERs) BUryL ACETATE (ALLrsoMERS) BUTvL ACETATE (ALLtsoMERS) BUTvLACETATE (ALLTSOMERS) BUryL ACRYLATE Chapter 1 Z n-BUWL ALCOHOL Chapter 1B Chapter 1 B Chapter 18 (ALL |SOMERS) BUTYRALDEHYDE .
1ss.
,lgg3
*2-Butoxyethyl
acetate
* Butyl acetate * (ALLTSOMERS) BUryL ACETATE n-Butyl acetate *sec-Butyl acetate *tert-Butyl acetate n-Butyl acrylate * (ALLISOMERS) BUwL ACRvLATE * Butyl alcohol n - BU T YL L C OHOL A *sec-BUTYL ALCOHOL *tert-BUTYL ALCOHOL n-Butyl aldehyde
330
161
SCANNED BY KIVAN ( MKP ) 2004
IBC Code
Name * BUTYLAMTNE lsoMERS) (ALL n-Butylamine *sec-Butylamine * tert-Butylamine * tert-Butylbenzene * BUryLBENZENE tsoMERs) (ALL BENZYL PHTHALATE BUTYL * Butyl butanoate *n-Butylbutyrate * BUryLBUTYRATE tsoMERs) (ALL n-Butylcarbinol Butyl "carbitol" Butyl "carbitol" acetate Butyl "cetlosotve" Butyl "cellosolve" acetate BUTYL/D ECYL/C EICOSYL ETYL/ MIXTURE METHACRYLATE * Butyl/decyl/hexade cosyl cyl/i mixture methacrylate Butyl diglycol acetate UN No. MFAC Rev. See 320 Chapter 1 7 19 9 3 ( BUTYLAMr NEALLTSOMERS) (ALr-TSOMERS) BUTYLAMTNE BUTLAM |NE ( ALLTSOMERS) (ALL BUTYLBENZENE ISOMERS) 2709 310 1993 Chapter 17 330 Chapter 1 7 (ALL ISOMERS) 19 9 3 BUTYLBUTYRATE (ALLISOMERS) 19 9 3 BUTYLBUTYRATE 3 3 0 19 9 3 Chapter 1 7 . n-AMYL ALCOHOL -B)ALKYLEN CLYCOL 19 9 3 E POLY(2 MONOALKYL(Cr-Cu) ETHER -B)ALKYLEN CLYCOL 19 9 3 E POLY(2 MONOALKYL(Cr-Co) ETHER ACETATE 19 9 3 ETHYLENE CLYCOL MONOALKYL ETHERS 19 9 3 CLYCOL BUTYLETHER ETHYLENE ACETATE 330 Chapter 17
ICOSYL BUWL/D ECYL/CFTYL/E MIXTURE METHACRYLATE -B)ALKYLENE GLYCOL POLY(2 MONOALKYL (Cr-Co) ETHER ACETATE Chapter 1B GLYCOL BUTYLENE BUWLENECLYCOL Chapter 1 7 BUWL ACETATE {ALL ISOMERS) (ALL ISOMERS) BUTYLACETATE n-BUWL ETHER Chapter 17 ocrANorc AcrD (ALLrsoMERS) N-ETHYLBUTYLAMINE N-ETHYLBUTYLAMINE (ALLTSOMERS) HEXENE (ALL TSOMERS) BUrYL ACETATE Chapter 1 7 ETHYLENE CLYCOL METHYL BUTYLETHER METHYLtert-BUWL ETHER \ BUTYL STEARATE DIBUryL PHTHALATE Chapter 1 7 Chapter 1B (ALLISOMERS) BUryRALDEHYDE Chapter 1 7 Chapter 1 7 BUryRIC ACID n-BUWL ALCOHOL BUryRALDEHYDE(ALL lsoMERs) Chapter 1B
1993
BUryLENE CLYCOL glycol alpha-Butylene glycol beta-Butylene OXIDE 1,2-BUWLENE Butyl ester * Butyl ethanoate Butyl ether n-BUWL ETHER acid Butylethylacetic * Butyl(ethyl)amine N-Butylethylamine Butylethylene Butylicether * BUryLMETHACRYLATE * Butyl 2-methoxyethyl ether *tert-Butyl methyl ether * Butyl octadecanoate :. :
308
3022
365
1149
330
1993 330
B u t y lp h t h a l a t e . ,.:...i. PROPIONATE n-BUWL * BUryLSTEARATE n-Butyraldehyde (ALL BUWRALDEHYDE TSOMERS) * BUryRIC ACID n-Butyric acid Butyricalcohol Butyricaldehyde * gamma-BUTYROLACTONE
1993
330
DIPENTENE Cajeputene SULPHIDE/ Chapter 1 7 ALKYL(Cg)PHENOL CALCIUM LPHIDE POLYOLEFI N PHOSPHOROSU MIXTURE CALCIUM LONG-CHAINALKYL Calciumalkyl salicylate
* Calciu bis(O-alkylsalicylate) m
(C13*) SAL|CYLATE CALCIUM LONC-CHAINALKYL (Cr:*) SAL|CYIATE * Calciumbromide ( CONTAININC BRTNES /zinc bromide solution DRTLLTNG ZINC SALTS) " cALcruMCARBONATE Chapter 1B SLURRY
162
A C A L C IUML ON C-CH A IN L KYLPHENATE Chapter 1B s u L PHID E(Cs-C4 o ) A L C A L C TU M ON G-C HA IN L KYLPHENOLIC Chapter 18 (Cu -Co o ) A M T NE CALCIUM LONC-CHAINALKYLSALICYLATEChapter 1 7 (Crr*) *cnLCruM NITRATE/ chapter 1B NITRATE/MACNESIUM S P O T AS S IUM L ORID E OLUTION CH cAMPHoR oll C a m p ho r, l i q u i d chapter 1 7 C AM P HOROrL DECANoIc ACID C a p r i c a ci d ocrANotc ACID (ALL lsoMERS) alpiha-Caproicacid (MOLepsilon-CAPROLACTAM Caprolactam TEN OR AQUEOUSSOLU . TroNs) * (MOLTENOR Chapter 1B epsilon-CAPROLACTAM A Q U E OUSS OL UT IONS ) ' ocrANoL (ALLlsoMERS) Capryl alcohol ocrANolc ACID (ALL lsoMERS) Caprylic acid n-OCWL ACETATE Caprylyl acetate Chapter 1 B S C AR A ME L OL UT IONS METHYLALCOHOL Carbinol "Carbitol" CLYCoi POLY(2-B)ALKYLENE acetate M ONOALKYL( Cl- C6) ETH ER ACETATE "C a r b i to l " so l ve n t GLYC OL POLY( 2- B) ALKYLENE M ONOALKYL( Cl- C6) ETH ER PHENoL C a r b o li c a ci d Chapter 17 O CARBOLIC IL CARBONDISULPHIDE C a r b o n b i su l p h i d e *c A R s o N Chapter l T Dtsu L P H tDE *c A R B o N Chapter 1 7 T E T RA C HL o R IDE Chapter 17 o C A S H E WN UT S H E L L l l (U NTREATED) vECETABLE olls, N.O.s. Castor oil HYDROXIDE POTASSIUM Caustic potash solution SOLUTION SOLU T ION SODIUM HYDROXIDE C Au St i CS Od A ,,Ce|Iosolve,, ACCIAIC ACETATE 2-ETHOXYETHYL "C e l t o so l ve " so l ve n t CLYCOLMONOA LKYL ETHYLENE ETHERS MIXTURE Chapter 17 METHACRYLATE CETYL/EICOSYL ALCoHoLS (c**) Cetyl/stearyl alcohol (Cr Chapter 1 7 P C H L O R INA T E D A R A F F INS o- Cr :) (Cr Chapter 18 P C H L O R INA T E D A R A F F INS +- Cr z) (wrrH s2% CHLORINE) *CHLOROACETTC AC|D (Bo"/" OR LESS) Chapter 17 I,3-DICHLOROPROPENE alpha-Chloroallyl chloride ALLYL CHLORIDE C h l o r oa l l yl e n e *CHLoRoBENZENE Chapter 17 CHLOROBENZENE f h l o r o b e n zo l BROMOCHLOROMETHAN E C h l o r o b ro mo me th a n e * EPICHLOROHYDRIN 1 - C h l oro -2 ,3 -e p o xyp ro p a ne CHLOROHYDR IN ETHYLENE C h l o r o e th a n o l -2 * -ethylacet-o ACETOCHLOR 2-Chloro-N-ethoxymethyl-6 toluidide ACETocHLoR 2-Chloro-N-ethoxymethyl-N-(2-ethyl: 6-methylphenyl)acetamide " TTHYLENE cHLORoHYDRIN 2-Chloroethanol *2 - C h l oro e th vl ETHYLENE cHLoRoHYDRIN a l co h o l
1! 1!
331
1!
1! 1t
1t
71O
1846
340 71A
1t 330 1!
'a75O
7OO
1134
34O 11
1{ , 11
163
IBC Code
Name beta-Chloroethyl alcohol * CH L o R o F o RM (C CH L O R O H YD RIN S RU DE ) m-Chloromethylbenzene o-Chloromethylbenzene p-Chloromethylbenzene Chloromethylethylene oxide (2-Chloro-1-methylethyl) ether " C h l o r o m e t hyl o xi ra n e +CHLORO-2-METHYLPHENOXYACETIC ACID, DIMETHYLAMINE SALTSOLUTION o { H L O R O N IT R OB E NZ E NE * 1-Chloro-2-nitrobenzene * 2- or 3-Chloropropanoic acid * 3-Chloropropene 2- or 3-CHLOROPROPIONIC ACID alpha- or beta-Chloropropionic acid 3-Chloropropylene alpha-Chloropropylene C h l o r o p r o p yl e n e o xi d e C H L O R O S UL P H ONT C A C|D * Ch l o r o s u l p hu ri c a ci d * ulpha-Chlorotoluene * m- C H L O R O TOL UE N E * o{HLOROTOLUENE See UN No. MFAG ETHvLENE CHLoRoHyDRtN Chapter 17 1888 34O Chapter 12 740 n-CHLOROTOLUENE o-CHLOROTOLUENE p-CHLOROTOLU ENE EPICHLOROHYDRTN 2,2'-DtcHloRolsopRonrl ETHER EPICHLOROHYDRTN Chapter 17 Chapter 1 7 I-CHLORONITROBENZENE 2-or 3-CHLOROPROPIONIC ACID ALLYLCHLORIDE Chapter 1 7 2- or 3-cHloRopRoptoNtc ActD ALLYLCHLORIDE ALLYLCHLORTDE EPTCHLOROHYDRTN chapter 17 cHloRosulpHoNtc ActD BENZYL CHLORTDE Chapter 17 Chapter 1 7 1578 335 Rev
199.
7OO
" ,754
7OO
'
2238 2238
340 34O
.:'lit
tri18 i13
8l:il::13
wHfTE SPtRtl LOW (1s-2oo/") AROMATIC Chapter 18 Chapter 1 7 CoAL TAR NAPHTHA soLVENT Chapter 1 7 Chapter 1 7 Chapter 1 7 31 1 310 199:
Cleaning solvents
C O A L S L U RR Y coAL TAR CoaI tar distiltate COAL TAR NAPHTHA SOLVENT CoAL TAR PITCH(MOLTEN) COBALTNAPHTHENATE SOLVENT lN NAPHTHA Cocoa butter VECETABLE OILS,N.O.S. Coconut oi| VECETABLE OILS,N.o.S. COCONUT orl FATTY AC|D Chapter 17 cocoNUT orl FATry AC|D METHYLESTER chapter 1B Cod liver oil ANTMALAND FtsH otLS, N.o.s. Colamine ETHANOLAMINE Cologne spirits ETHvLALCOHOL Columbian spirits METHvLALCOHOL corn acid oil VECETABLE ACID OILS AND DrsrtLLATEs, N.o.s. Corn oil VEcETABLE otls, N.o.s. Corn sugar solution DEXTROSE SOLUTTON Cotton seed acid oil vEcETABLE ACID otls AND DISTILLATES, N.O.S Cotton seed oil vEGETABLE otLS, N.o.s. (COAL TAR) CREOSOTE chapter 1 7 (WooD) CREOSOTE Chapte 17 Chabt"r r f Z Creosote salts (MOLTEN) NAeHTHALENE " c RE S o L S ( AL Ltso ME R S ) chapter 1 z C R ES Y L IACID , DE P H E NOL T Z E D C Chapter 17 (ALLISOMERS) Cresylic acids CRESOLS CRESYL|C ACID, SODIUM SALTSOLUTION Chapter 17 (ALLISOMERS) Cresylols CRESOLS * CR O T O N AL DE HY D E chapter 1Z Crotonic aldehyde CROTONALDEHYDE
'
164
See UN No. MFAG Rev. (ALL PROPYLBENZENE ISOMERS) 1993 ACRYLONITRILE ACETONE CyANoHyDRtN Chapter 1Z ChapterlT Chapter17 NApHTHENtc ActDS Chapter 1B ChapterlT ' Chapter17 :
2241 1145
1993 1993
1915
1993
ENZENE MIXTURES AND HAVoR MoR' affi,Jro'irtt*zENE ,ro, Chapter17 2357 N,N-DIMETHYLCYCLOHEXYLt-ffi')LycLoHEXyLAMrNE CYCLOHEXANONE Chapter'17 Chapter17 Chapter17 Ch apter 17 p-CYMENE
330 320
1993
1993 1993
2,2-DtcHLoRopRoproNrc ACID VEGETABLE OILS ACID AND DISTILLATES, N.O.S. DICHLOROPROPENE/DICHLOROPROPANE MIXTURES DTMETHYLETHANoLAMTNE Chapter 1B 1147 (Cro*) n-ALKANES C h a p t e r1 2 (ALL DECvL ALCOHoL rsoMERS) C h a p t e r1 7 ACID DECANotc Chapter 17 Chapter 17 (ALL DECvL ALCoHOL rsoMERS) chapter 17 ALKYL(Ce*)BENZENES
DECANotc ACID OCTYL DECYLADIPATE Chapter lZ Iv-METHYLGLUCAMTNE soLUTr oN ( 70% oR LESS ) ALKYL(Ce*)BENZENES Chapter 18 ETHYLACETOACETATE DIACETONE ALCOHOL Chapter 1 B Chapter 18 ETHYLENEDIAMINE H:*AMETHYLENEDIAMINE SOLUTION TOLUENEDIAMINE ISOPHORONEDIAMINE ETHYLENE DIBROMIDE Chapter 1 7 Chapter 17 NoNyL ALCoHoL ( ALLisou r ns ) n-BUWL ETHER
310 1993
19 9 3
305
^.^^^.^
1993 1993
1 148
305
:.
2664
345 32O
'1997
165
IBC Code
Name n-Dibutylether
D I BU r y L H Y D ROC E NP H OS P HONATE * D I BU T YL P HT HA L A T E * 1,2-Dtchloroben zene " * m-Dichlorobenzene o - D i c h l o r o b e n ze n e
340
2362
340
sym-Dichloroethane Dichloroether * 1 -Dichloroethylene ,1 DICHLOROETHYL ETHER sym-Dichloroethyl ether Dichloroethyl oxide * 1,6-DtcHLoROHEXANE
' 2 , 2 ' - D I C H L OROIS OP R OPE T H ER YL * D T c H L o R oME T HA N E ' * 2,+-DT:HLoROPHENOL ACID, 2,4-DaCHLOROPHENOXYACETIC DIETHANOLAMINE SALTSOLUTION 2,4-DICHLOROPHENOXYACETIC ACID, DIMETHYLAMINE SALTSOLUTION (70% OR LESS) 2,+DICHLOROPHENOXYACETIC ACID, TRII S O P R O P A NOL A MINE L TS OLUTION SA
340
..
2490 1593 2021
C h a p t e r1 7 Chapter'17
Chapter 17 Chapter 1 7
1993
1993
Chapter 1 7
Chapter 17 C h a p t e r1 7 Chapter17
DICHLOROPROPENE/DICHLOROMIXTURES PROPANE
1279
1993
Dichloropropane/dichloropropene mixtures
1 , 3 - D T C H Lo Ro P R o P E NE Chapter 17 DICHLOROPROPENE/DICHLOROPROPANE Chapter 1 7 MIXTURES * 2,2-DtctloRopRoptoNtc ACID Chapter 1 7 D i c h fo r o p r o p yl e n e I,3- DICHLOROPROPENE '1,4-Dicyanobutane ADIPONITRILE Dicyclopentadiene 1,3-CYCLOPENTADIENE DIMER (MoLrEN) * Didecyl phthalate (Cr-C,l3) PHTHALATES DTALKYL * Didodecylphthalate DfALKYL(Cz-Cr3) PHTHALATES DIETHANOLAMINE Chapter 17 * DTETHYLAMTNE Chapter 17 * 2-Diethylaminoethanol DIETHYLAMINOFIHANOL DIETHYLAMINOFIHANOL Chapter 17 * 2,6-DTETHYLANILTNE Chapter 1 7 DIETHYLBENZENE Chapter 17 "carbitol" Diethyl DIETHYLENE CLYCOL DIETHYL ETHER 1,4-Diethylene dioxide 1,+ DIOXANE 1,+ DIOXANE Diethyleneether DIETHYLENE CLYCOL Chapter 1B Diethylene glycol butyl ether POLY(2-B)ALKYIENE CLYCOL MONOALKYL( Cr - Cu)ETHER Diethyfene glycol butyl ether acetate POLY(2-8)ALKYLENE CLYCOL MONOALKYL( Cl - C6) ETHER ACETATE D I ET H YL ENE Y C OLDIB U T Y L THER E CL Chapter 18 DTETHvLENE DTETHvL ETHER clycol Chapter 1B
330
.'166
SCANNED BY KIVAN ( MKP ) 2004
POLY(2-B)ALKYLENE CLYCOL
1ss3
1993
'lgg3
p#?)-"#iJitLi;ElttJ3i(Cr-Cu) ErHER Lou[oALKYL POLY(2-B)ALKYLENE CLYCOL MONOALKYL (Cr-C6) ETHER L POLY(2-s)ALKYLENE GLYCO MONOALKYL (Cr-Co) ETHER
1993 1gg3
tit:'iliJ,tor*rrr*E cLYcoL
( M O N O A L K Y L C l - C 6 )E T H E R CLYC O L POLY( 2- B) ALKYLENE MONOALKYL( Cr- Co) ETH ER ACETATE Chapter 1 B I,4- DIOXANE / chapter 17 a Chapter 1B
1ss3
1993
CLYCOL PHTHALATE DIETHYLENE D i e t h yl e n e o xi d e D | E T HY L E NE T RT A MT NE ACID, DIETHYLENETRIAMINEPENTAACETIC SALTSOLUTION PENTASODIUM DIETHYLAMINOFI-HANOL Diethvlethanolamine DIETHYLAMINOETHANOL N,N-Diethylethanolamine * Chapter 1 Z D T ET H YE T H E R L ADIPATE Chapter 1 B DI-(2-ETHYLHEXYL) ACID Chapter 1 Z DI-(2-ETHYLHEXYL)PHOSPHORIC DloCrYL PHTHALATE Di-(2-ethylhexyl) phthalate DIETHYL ETHER Diethyl oxide *D I ET HY L Chapter 17 P HT HA L A T E , "DTETHvL Chapter 17 suLpHATr A Chapter 1 7 E OF D I C L Y CID Y L T HE R B IS PHENOL r Chapter 17 E OF D I G L YC IDY L T HE R B IS PHENOL DIETHYLENE cLYCoL Diglycol . 2-(2-AMINOETHOXY)ETHANOL Digf ycolamine *D l H Ep ryL Chapter 18 e HT HA L A T E Chapter 17 A D I - n - H E X Y LD IP A T E *D I H EX Y L Chapter 18 P HT HA L A T E 1,4-DIHYDRO-9,10-DIHYDROXYANTHRA- Chapter 1B DIS OD IUM S A L TS O LUTION C E NE , BUTYLENE GLYCOL 2,3-Dthydroxybutane DIETHANOLAMINE 2,2'-Dihydroxydiethylamine DIETHANOLAMINE Di-(2-hydroxyethyl)amine DIETHYLENE GLYCOL Dihydroxyethyl ether PROPYLENE CLYCOL 1,2-Dihydroxypropane * Chapter 1 Z DlrsoeurylAMrNE NoNYL ALCoHoL ( ALLlso M ER s ) D i i s o bu tyl ca rb i n o l Chapter 1 Z D I I S OB UT Y L E NE DIISOBUryLENE alpha-Ditsobutylene DIISOBUryLENE beta-Diisobutylene * Chapter 1 B D n s o s u ryL K E T o N E *D r s o BU ryL Chapter 17 e HT HA L A T E TOLUENEDIISOCYANATE 2,4-Diisocyanatotoluene DIALKYL(Cz-Cr:) PHTHALATES Diisodecyl phthalate Chapter 18 A D I I S ONON Y L D IP A T E , (Cz-C13) DIALKYL PHTHALATES Diisononyl phthalate 'l Chapter B DIISOOCryL PHTHALATE -l Chapter Z DIISOPROPANOLAMINE *DrfsopRopyr-AMtNE ChapterlT
1 1 55 1902
330 700
, 1594 315
, 1993
2361 2050
320 310
1157
300 330
167
SCANNED BY KIVAN ( MKP ) 2004
IBC Code
Name See UN No. MFAG * (A Dn s o p R o p yL B E NzE N E L Ltso MERs) Chapter 1 7 310 * Diisopropyl ether ISOPROPYL ETHER D I I SO P R O P Y L N A P HT HA L E N E Chapter 18 D i i s o p r o p y l o xi d e ISOPROPYL ETHER * N N - D T M ET HvL A C E T A MIDE so L UTtoN Chapter 17 (4o%oR LESS) * DTMETHYL ADTPATE Chapter 1 Z * DT M ET H YL A MT NE (4 S OL U T T ON s% OR LESS) chapter 17 1 160 320 * DI M E T H v L AMT NE 1160 so L UT to N (cREATER Chapter 1Z 320 THAN 45% BUT NOT CREATER THAN ss%) * DT M ET H YL A M|N E (CR EATER 1 160 S OL UT T ON Chapter 17 320 THAN 55% BUT NOT CREATER THAN 65%) Dimethylaminoethanol DTMETHYLETHANoLAMTNE * 2 - D i m e t h y l a mi n o e th a n o l DTM ETHvLETHANOLAMTNE D i m e t h y l b en ze n e s XYLENES * 1,3-Dimethylbutyl acetate METHYLAMYL ACETATE D i m e t h y l c a rb i n o l tsopRoPyl ALCoHoL N , N - D I M E T H Y L CY C L OHE X Y L AM INE Chapter 17 2264 320 DT M ET H v L E T H A No L A MT N E Chapter 17 2051 32O 1, 1 - D i m e t h yl e th a n o l ter t- BUW LALCOHOL 1, 1 - D i m e t h yl e th yl a l co h o l ter t- BUWLALCOHOL Dimethyl ethyl carbinol tert-AMYLALCOHOL BUTYLENE sym-Dimethylethylene glycol cLYCoL "DTMETHvLFoRMAMTDE Chapter 17 2265 321 * DTMETHYL cLUTARATE Chapter 1 7 * 2,6-Dimethyl-4-heptanone DIISOBUryL KETONE * 2,6-Dimethylheptan-4-one DIISOBUTYL KETONE * DT M E T H v L HyD Ro cE N p H o sP HtTE Chapter 17 Di m e t h y l h yd ro xyb e n ze n e s XYLENOL * 1 , 1 ' - D i m e r h yl -2 ,2 '-i mi n o d i e th a nol DltsopRoPANoLAM tNE * Dimethyl ketone ACETONE DI M E T H YL O C T A N OICC ID A Chapter 1Z 700 * Dimethylphenols XYLENOL * DTMETHYL PHTHALATE Chapter 1 Z D r M ET H y L po L ystL o xA NE Chapter 18 * 2 , 2 - D I M ET HY L P ROP A N E -1 ,3 -DIOL Chapter 1B * 2,2-Dimethylpropionic acid TRIMETHYLACETTC ACID * D T M ET H YLu cctNA T E s Chapter 1 7 D l N l r R o r o L UE N E (MOL T E N) Chapter 1 7 1600 335 * DlNoNvL PHTHALATE Chapter 1 8 * Dioctyl adipate DI-(2-ETHYLHEXYL) ADIPATE * Dioctyl hydrogen phosphate DI-(2-ETHYLHEXYL)PHOSPHORIC Rer
'199
"'iil?-tlHExyl)pHospHoRrc
ACID Chapter 1B I,4- DIOXANE Chapter 1Z ETHYLENE CARBONATE ETHYLENE CARBONATE 1,4-DIOXANE Chapter 1Z Chapter 17 Chapter 12 Chapter 12 Chapter 17 DIPHENYL/DIPHENYL ETHER MIXTURES DODECYLDIPHENYL ETHER DISULPHONATE SOLUTION DODECYLDIPHENYL ETHER DISULPHONATE SOLUTION Chapter 1Z 1993 1165 330
2052
330
168
1993 1993
diyldioxide
*DrrRrDEcyL ADTeATE *D l r R l D EC yL e HT HA L A T E * D T U N D EC vL HA L A T E rHT * -o l D o c o s a n-l * -Docosanol 1 * D o D E C A N E( A L L lsoMERS) *D o d e c a n o i c a ci d * D o d e c a n-1 -o l * l - D o d e c an o l n-Dodecanol * D o D E C E N E( A L L rsoMERS) D O D E C E NY L S U CC INIC A CID ,
310
1gg3
solu'oN ""3$SlttitZHAT
chapter 12
30s
1993 1993 1993 7O O
n-Dodecyl alcohol ooDECyL ALcoHoL *D O D E C Y L A MT N E /T E T RA D E CYLAM TNE Chapter 17 M I XT UR E "D o D E C v LD T ME T H vL A MIN E 1TETRADECvLChapter 17 MIX D I M E T HY L A MINE T UR E DODECYLBENZENE Chapterl8 D O D E C Y LD IP HE N Y L T H E R E Chapter 1 7 , D I S U L P H ONA TS OL U T ION E D o d e c y l d i p h e n yl o xi d e d i sulphonate DODECYLDIPHENYL ETHER S O l u t i on DISULPHONATE SOLUTION ( D o d e c y l en e DODECENEALLISOM ERS) *D o D E C v L ME T HA C RvL A T E Chapter 1 7 Dodecyl 2-methyl-2-propenoate DODECYLMETHACRYLATE Dodecyl 2-methylprop-2-enoate DODECYLMETHACRYLATE "D O D EC Y L /P E N T A D E CY L ME T HACRYLATE chapter 17 M I X T URE DODECYLPHENOL ChapterlT D O D EC Y L X Y L E NE Chapter 18 D R I L L I N C R I N EC A L C I U MB R O M I D E B : Chapter 1B S O L U TION D R I L L I N C R I N EC A L C I U MC H L O R I D E B : Chapter 1B S O L U TION D r i l l i n g bri n e : p o ta ssi u m ch l or ide POTASSIUM CHLORIDE s o l u t - i on SOLUTION( 10% OR MORE) (CON T A IN INC D R I L L I NC R INE S B ZINC Chapter 1 7 SALTS) D R I L L I N C R I N ES O D I U M C H L O R I D E B : Chapter 1B S O L U TION D u t c h l i qu i d ETHYLENE DTcHLoRTDE Dutch oiI ETHYLENE DICHLORIDE En a n t h i c a ci d E n a n t h y l a l co h o l n- HEPTANOTC ACID HEeTANoL( ALLtsoMERS)
330
330 710
t :
1993
'
169
IBC Code
Name Engravers' acid E P I C H L o Ro H Y DR IN * 1,2-Epoxybutane *'1,2-Epoxypropane * E t h a n a m i n e so l u ti o n s, 7 2 % o r less * 1,2-Ethanediol * Ethanoic acid Ethanoic anhydride * Ethanol ETHANOLAMINE Et h e r Ethinyl trichloride * 2 - ET H O XY E T HA N OL * 2-(2-Ethoxyethoxy)ethanol " 2-(2-Ethoxyethoxy)ethyl acetate See NITRICACID (70%AND OVER) Chapter 12 OXIDE 1,2-BUryLENE OXIDE PROPYLENE SOLUTIONS ETHYLAMINE (72% OR LESS) cLYCoL ETHYLENE l ACID ACETIC ANHYDRIDE ACETIC ALCOHoL ETHYL Chapter 17 ETHER DIETHYL TRICHLoROETHYLENE Chapter 1 B CLYCOL POLY(2-8)ALKYLENE MONOALKYL(C, -Co) ETHER CLYCOL POLY(2-s)ALKYLENE MONOALKYL (Cr-Cu) ETHER UN No. MFAG 2023 740 Re
249'1
32O
117'1
3 30 19 19
* 2-ErHoxyErHyL ACETATE
* l-Ethoxypropan -2-ol
.f"tJlitit
CLYCOL MONOPROPYLENE
1't72
330
19
* ErHyL ACETATE
" ETHYLACETOACETATE " ETHYLACRYLATE * ET H YL L COH OL A * ETHYLAMINE * ETHvLAMTNE soLUTtoNS (22% oR LEss) Ethylam inocyclohexane A ET H YL M Y L K E T o NE * ETHYLBENZENE Ethyl benzol . Ethyf butanoate * N-ETHYLBUTLAMINE *E T H YL B U ryRA T E Ethyl cyanide * ETHYLCYCLoHEXANE *N-ETHYLCYCLOHEXYLAMINE Ethyl(cyclohexyl)amine Ethyldimethylmethane Ethylene alcohol Ethylenebisiminodiacetic acid tetrasodium salt solution . E t h y l e n e b ro mi d e *ETHvLENE cARBoNATE Ethylenecarboxylic acid Et h y l e n e c h l o ri d e ET H YL ENC HL OR OHY D RIN E ET H YL ENC Y A NOH Y DR IN E * Ethylene diacetate * ET H v L EN E DIA MINE
.fi|lj,T5't*
Chapter 1 B Chapter 12 Chapter 18 Chapter 1 7 Chapter 1 7 N-ETHYLCYCLOHEXYLAMINE Chapter 17 ChaPter 17 ETHYLBENZENE ErHYL BUTYRATE Chapter 1 7 Chapter 17 PROPIONITRILE Chapter 1 7 Chapter 12 N-ETHYLCYCLOHEXYLAMINE (ALLISOMERS) PENTANE cLYCoL ETHYLENE ETHYLENEDIAMINETETRAACffiC SALT ACID, TETRASODIUM SOLUTION DIBROMIDE ETHYLENE chapter 18 AcRYLlc ACID DICHLORIDE ETHYLENE Chapter 17 , Chapter 17 ETHYLENE GLYCOL DIACETATE Chapter 17 Chapter 18
1173 330
1917 1170 1036 2270 2271 1175 330 330 305 32O 320 227 310 19
1 180
19
lio
:: i
1 135
1604
ACID, ETHYLENEDIAMINETETRAACETIC SALTSOLUTION TETRASODIUM * ETHvLENE DtBRoMtDE " E T H YL EN E D T C HL OR IDE 2,2'-Ethylenedi-iminodi(ethylamine) Ethylenedinitrilotetraacetic acid tetrasodium salt solution * 2,2'-Ethylenedioxydiethanol * ETHYLENE GLYCoL ETHYLENE CLYCOLACETATE Ethylene glycol acrylate Ethylene glycol butyl ether
-.
1 605 Chapter 1 7 '1184 Chapter 17 TRIETHYLENETETRAMINE ETHYLENEDIAMINETETRAACETIC SALT ACID, TETRASODIUM SOLUTION cLYcoL TRIETHYLENE Chapter 1 B Chapter 1B ACRYLATE 2-HYDROXYETHYL GLYCOLMONOALKYL ETHYLENE ETHERS
308
1I
170
330 1993
1993
'.l[".T"g|yco|monomethyletherET$''i:il3''J^.'?LMETHYL,.
Ethylene glycol monophenyl ethe r E T H YL ENCL Y C OLP H E NY L E ETHER ETHYLENE ETHER/ CLYCOL PHENYL DIETHYLENE CLYCOL PHENYL ETHER M]XTURE ETHYLENE OXIDE/PROPYLENE OXIDE MIXTURES WITH AN ETHYLENE OXIDE CONTENTOF NOT MORE THAN 30% I N W EICH T Ethylene trichloride * ETHvLENE-vINvL AcETATE CopoLyMER ( E M UL S T ON) * Ethyl ethanoate Ethyl ether ETHYL 3-ETHOXYPROPTONATE Et h y l f l u i d ETHYLENE CLYCOL PHENYL ETHER Chapter 18 Chapter 1B
330
Chapter 1 7
2983
365
TRICHLOROETHYLENE Chapter 18 ETHYLACETATE DTETHYL ETHER Chapter 1 7 MOTOR FUEL ANTI-KNOCK coMpouNDS ( coNr Ar Nr N c
1993
1993 1993
gtycot Ethyt
rrirtir?,fflttit]"t MoNoALKyL
1ss3
ETHERS 2-Ethylhexatdehyde oCwL ALDEHYDES *2-Ethylhexanal ocrYl ALDEHYDES *2-ETHYLHEXANoIc ACID Chapter 18 2-Ethylhexanol ocrANoL (ALL tsoMERS) 2-Ethyf hexenaf 2-ETHyL-3-pRopyLACRoLEtN *2-Ethyf hex-2-enal z-ETHyL-3-pRopyLACRoLEtN 2-Ethylhexoic acid ocrANorc ACID(ALL tsoMERS) *2-ETHvLHEXvL ACRvLATE Chapter 17 *2-Ethylhexyl alcohol ocrANoL (ALL tsoMERs) *2-ETHYLHEXYLAMTNE Chapter 17 2276 2-ETHYL-2-(HYDROXYMETHYL)PROPANE-1,3Chapter 18 DloL,ce-cro ESTER "S-Ethylidenebicyclo(2,2,1)hept-2-ene ETHYLIDENENORBORNENE Ethyf idenechloride 1,I-DICHLOROETHANE " Ethylidene dichloride I,I-DICHLOROETHANE ETHYLIDENENORBORNENE C h a p t e r1 7 * ETHvL METHACRvLATE Chapter 17 2277 " 2-Ethyl-6-methylaniline 2-METHvL-6-ETHvLANTLTNE * Ethylmethyl ketone METHYL ETHYL KETONE . s-fihyl-2-methytpyridine 2-METHyL-s-ETHyLpyRtDtNE Ethyloxide DIETHYL ETHER
310 330
171
IBC Code
Name o - E T H YL PH E NOL * 2 - E t h y p h en o l f Ethyl phthalate 5-Ethyl-2-picoline . Ethyl propenoate * ET H YL R o P to NA T E P 2 - E T H YL - 3-P R OP Y L A CR OL E IN E t h y l s u l p ha te E T H YL T OL U E NE * 6-Ethyl-o-toluidine * E t h v l v i n v l e th e r
t r *."'r.*--
See Chapter 17 o- r r uYlPHENOL PHTHALATE DIETHYL DI N 2-METHYL-s-ETHYLPYRI E ETHYLACRYLATE Chapter 1 B Chapter 17 SULPHATE DIETHYL Chapter 17 2-METHYL-6-ETHYLANILINE ETHER VINYL ETHYL '
1 1 95
330 300
chapter 18 DODECYLALCOHOL (chapter 17) and ALCOHOLS( Cr s*) ( Chapter 18) ALCOHOL ETHYL Fermentation alcohol : Chapter 17 F ER R I C HL OR IDE OL U T ION S S C Chapter 18 F ER R I C YD ROX Y E T HY L E T HYLENEDIAMINEH SALT T R I AC E T IC CID , T R IS ODIU M A S O L U T I ON ACID SOLUTION Chapter 1 7 FERRIC NITRATE/NITRIC ANIMAL AND FISHACID OILS Fish acid oi|
2582
700 :
FtsH soLUBLEs
r F L U O R O S IL IC |C |D (2 O-3 O%) N W ATER AC S O L U T I ON * F o R M AL D EHvD E so L U T to N S (4s% oR LESS) Formalin F O R M AM ID E F o r m d i m eth yl a mi d e "FoRMrc ACID F o r m i c a l de h yd e WATERDl} F U M AR I C DD UC T OF R OS IN, A P E R S I ON FuTaI * 2 - F u r a l d e h yd e * F u r a n - 2 , 5 -d i o n e * 2 , S- F u r a nd i o n e FURFURAL 2-Furfuraldehyde , * F U R F U R vL L Co H o L A Furylcarbinol Caultheria oil Glacial acetic acid *Clucitol s ol u ti o n * cL U C o s E s o L UT to N CLUTARALDEHYDE SOLUTIONS (so% oR LESS) G L YC E R I NE CLYCERIN (83%),DIOXANEDIMETHANOL E ( 1 7 %) M r xru R E * Clycerol C L YC E R OL MONOOL E A T E Clycerol oleate POLYALKOXYLATE CLYCEROL *Glycerol triacetate CLYCERYL TRIACETATE E OF C L YC I D Y L S T E R C l o T R IA L KYLACETIC ACID G L YC I N ESODIU M S A L TS OL UTION , Glycol Glycol carbonate
N'o's' af,i?"TlsrrllArEs'
Chapter 17 Chapter 17
1778
7OO 300
FORM ALDEHYDE SOLUTIONS (4s% oR LESS) Chapter 18 DIMETHYLFORM AMIDE Chapter 17 FORM ALDEHYDE SOLUTIONS ( 4s% oR LESS) Chapter 1Z FURFURAL FURFURAL ANHYDRIDE MALEIC MALEIC ANHYDRIDE ChapterlT FURFURAL Chapter 1 7 FURFURYL URFURY ALCOHOL METHYLsALIcYLATE ACETIcACID SOLUTION SORBITOL Chapter 18 Chapter 1 7 Chapter 18 Chapter 1 B CLYCERINE Chapter 18 MONOOLEATE CLYCEROL Chapter 18 TRIACETATE CLYCERYL Chapter 1B Chapter 17 Chapter 18 ETHYLENE GLYCOL ETHYLENE CARBONATE
1199 2874
300 305
300
172
19 9 3 1993
1206
310
305
1993
311
1993
Chapter 1 7 HEXAM ETHYLENEDIAMIN E SOLUTION HEXAMETHYLENE CLYCOL Chapter 1B HEXAMETHYLENEIMINE Chapter 17 * HEXAMETHYLENETETRAMINE SOLUTIONS C h a p t e r 1 8 Hexanaphthene CYCLOHEXANE n-Hexane (ALLISOMERS) HEXANE * HEXANE tsoMERs) (ALL Chapter 1 7 * Hexane-1,6-diamine solutions HEXAMETHYLENEDIAMINE SOLUTION * 1,6-Hexanediamine solutions HEXAM ETHYLENEDIAMIN E SOLUTION * 1,6-Hexanediol HEXAMETHYLENE CLYCOL * Hexane-1,6-diol HEXAMETHYLENE CLYCOL * HEXANOTC ACtD Chapter 1B HEXANOL Chapter 1 B " Hexan-l-ol HEXANOL * Hexan-6-olide ep siIo n-CAPROLACTAM(MO LTE N oR AQUEOUSSOLUTIO N S) * 2-Hexanone METHYLBUTYLKETONE * Hexan-2-one METHYLBUryL KETONE * 1-Hexene ( HEXENEALLISOMERS)
1783
320
.
2493 320
1208
310
1993
1993
1993
2282 3 0 5
1993
173
IBC Code
UN No. MFAG See Name (ALLISOMERS) HEXENE Hexene.'l *Hex-1-ene ( HEXENEALLISOM ERS) *2-Hexene ( HEXENEALLISOM ERS) 'l * ( chapter z H E X E N EAL LT S OME RS ) KETONE METHYLISOBUTYL HCxoNe * H EX v L ', '----1233 330 Chapter 17 AC E T A T E ACETATE METHYLAMYL sec-Hexyl acetate * HEXANOL H e x y l a l c o ho l (ALLlsoMERs) HEXENE Hexylene 308 Chapter 18 HE X Y L ENCL Y C OL E * 1789 7OO Chapter 1 7 H y D R o c H L o Rtc A C ID FoRM lc ACID Hy d r o g e n ca rb o xyl i c a ci d * ACID HYDROCHLORIC H y d r o g e n ch l o ri d e , a q u e o u s *HyDRocEN pERoxlDE 735 2014, Chapter 17 soLUTroNS 2984 (ovER B% BUT NOT OVER 60%) *HYDRocEN pERoxlDE 2015 735 Chapter 17 soLUTtoNS (ovER 60% BUT NOT OVER 7o%) ACID SULPHURIC H y d r o g e n s u l p h a te PHENOL H y d r o x y b e n ze n e ganna-BUTYROLACTONE 4-Hydroxybutanoic acid lactone gamma-BtJryROLACTONE 4-Hydroxybutyric acid lactone gamma-BUTYROLACTONE gamma-Hydroxybutyric acid lactone XYLENOL H y d r o x y d i me th yl b e n ze n e s *2-Hydroxyethvl CLYCOL ACETATE ETHYLENE acetate "2-HyDRoxyETHyL 330 Chapter 1 7 ACRvLATE ETHANOLAMINE 2-Hydroxyethylamine N-(HYDROXYETHYL)ETHYLENEDIAMINE-Chapter 1B TRIACET]C ACID, TRISODIUMSALT SOLUTION AMINOETHYLETHANOLAMINE N-beta-Hydroxyethylethylenediamine ETHYLENE CLYCOL PHENYL beta-Hydroxyethyl phenyl ether ETHER ACEToNE cYANoHYDRIN alpha-Hydroxyisobutyronitrile DIACETONEALCOHOL 4-Hydroxy-2-keto-4-methylpentane ALCOHOL DIACETONE 4-Hydroxy-4-methylpentanone-2 " ALCOHOL DIACETONE 4-Hydroxy-4-methylpentan-2-one ISOBUryL ALCOHOL 2-(Hydroxymethyl)propane * ACEToNEcYANoHYDRIN 2-Hydroxy-2-methylpropiononitrile * 2 - H y D R o x y-+(ME T HvL T HT o )B UTANotc Chapter 17 AC I D oNITROPHENOL(MOLTEN) 2-Hydroxynitrobenzene (molten) CLYCOL PHENYL ETHYLENE 1-Hydroxy-2-phenoxyethane ETHER LACTIc ACID alpha-Hydroxypropionic acid LACTONITRILE soLUTloN alpha-Hydroxypropionitrile (BO"/" OR LESS) ETHYLENE cYANOHYDRIN beta-Hydroxypropionitrile * ETHYLENE CYANOHYDRIN 3-Hydroxypropiononitrile ISOPROPANOLAMINE , 2 - H y d r o x y p ro p yl a mi n e n-PROPANOLAMINE 3-Hydroxypropylamine ALCOHOL BENZYL * 2,2,4-TRIMETHYL-I 3-Hydroxy-2,2,4-trimethylpentyl ,3-PENTANEDIOL-I-ISOBUWRATE isobutyrate * chap ter 17 lcosnloxypRoPANE-2,3-DrYl)s " TETRAETHYLENEPENTAMINE 2,2'-[lminobis(ethyleneimino)]diethyl: amine * DIETHANOLAMINE 2,2'-lminodiethanol * DIETHYLENETRIAMINE 2 , 2 ' - l m i n o d i (e th yl a mi n e ) * ' - l m i n o di p ro p a n -2 -o l DIISOPROPANOLAMINE 1, 1 * FERRIC SOLUTIONS CHLORIDE lr o n ( l l l ) c h l o ri d e so l u ti o n s * NITRATE/NITRIC ACID FERRIC lron(lll) nitrate/nitric acid solution SOLUTION (ALLISOMERS) AMYL ACETATE lsoamyl acetate 1 105 305 Chapter 1 8 I SO A M Y L L COH OL A ( ALL BUTYRALDEHYDE ISOM ERS) ls o b u t a l d e hyd e ( ALLTSOM ERS) BUr yRALDEHYDE ls o b u t a n a l lsoBUr yL ALCoHoL ls o b u t a n o l Rev.
1993 1993
1993
1993
1gg7
174
1 'l
1 1
.[3;[$*i[?^''ro',X*oRLESS)li :R:3[i
SOLUTION fsopropenylbenzene * 2-lsopropoxyethanol *2-lsopropoxypropane * rsopRopyl ACETATE lsopropylacetone * r s o p Ro p yl A L C o Ho L *l s o p R o p yL A MtNE *rsopRopyLAMrNE (7oo/" oR LESs) SOLUTION lsopropylbenzene lsopropyl carbinol * tsopRopyLCYCLoHEXANE I S O P R O P YE T H E R L lsopropylideneacetone 4-lsopropyltoluene 4-lsopropyltoluol fsovaleral * Isovaleraldehyde lsovaleric aldehyde lsovalerone Kaolin clay slurry K A O L I NS L U R R Y Ketohexamethytene Ketone propane Ketopropane * LACTTc ACID a[pha-METHYLSTYRENE ETHYLENE CLYCOL MONOALKYL ETHERS ETHER ISOPROPYL Chapter 1 B . KETONE METHYLISOBUTYL Chapter 1 B Chapter 1 7 Chapter 1 7 (ALL PROPYLBENZENE |SOMERS) ISOBUTYL ALCOHoL chapter 1 7 Chapter 1Z MESIryLOXIDE p-CYMENE pCYMENE (ALLrsoMERS) vALERALDEHyDE (ALL ISOMERS) VALERALDEHYDE (ALL VALERALDEHYDE ISOMERS) DIISOBUTYL KETONE KAOLINSLURRY Chapter 18 ctiionrxANoNE ACETONE ACETONE Chapter 1 B
320
320 1997 1gg3
1 1
1159
330
1 1993 1
7OO
175
,.,-*t*il..
IBC Code
tVame (80% OR LESS) LACTONITR| SOLUTTON LE Lanolin L AR D
^xffi'#"-,x?:i:sl3f'"
725 725
L A T EXA M MON T A (1 % , OR L E S S ) - INHIBITED Chapter 1B LATEX: CARBOXYLATED SryRENE-BUTAChapter 18 D I EN EC O P OL Y ME R L A T EXS T YRE N E -B U T A D T E N E : RU BBER chapter 18 *LAURtc ACID Chapter 17 Lauryl alcohol DoDECvL ALCoHoL Lauryl methacrylate DODECYL METHACRYLATE Lead alkyls, n.o.s. MOTOR FUELANT|-KNOCK coMPouNDS ( CONTAINtNC LEAD ALKYLS) Lead tetraethyl MoroR FUELANTt-KNocK coMPouNDS ( CONTAINtNC
Lead tetramethyt
L I C N I N SU L P HON ICCID , S ODIUM SALT A SOLUTION Limonene Linseed oi| L I Q U I D C H E MIC A L WA S T E S LONC-CHAINALKARYL POLYETHER ( C rr - C z o ) L O N G - C H AIN L K A R Y L UL P H ONIC A S ACID (CreCeo) LONC-CHAINALKYLPHENATE/PHENOL S U L PH I D E MIX T U RE LONC-CHAINPOLYETHERAMINE lN AL KY L ( C2 -C 4 )B E N Z E N E S L O N G - C H A IN OL Y E T HE R A MT lN P NE AROMATICSOLVENT Lye, potash
M5#-1tiJ,-'?*r'*NocK
coMPouNDS ( CONTA|NtNC LEADALKYLS) Chapter . 1B DIPENTENE VEGETABLE OILS,N.o.S. Chapter 17 Chapter 1 7 Chapter 1B Chapter 1B Chapter 1 7 Chapter 17 eOTASSIUMHyDRoxtDE '
1ss
1gS 195
Lye, soda
* MA C N E S T uM cH L o RtD E so L UT toN * MA C N E S I u M H yDR o xtDE sL U RRy MACNESIUM LONC-CHAINALKARYL (C s u L PH O N A T E l r -C so ) M AC N E S I U ML ONC -C HA IN L K YL A (Cl1*) SAL|CYLATE " M AL El c AN HvD RID E * dlp-Mentha-l ,B-diene MERCAPTOBENZOTHTAZOL, SODIUM SALT SO L U T I ON MESIryL xlDE o Metaformaldehyde M ET AM SO DIU M S OL UT ION * M F f H A C R y Ltc A C |D alpha-Methacrylic acid Methacrylic acid, dodecyl ester Methacrylic acid, lauryl ester M E T H AC R Y L IC E S INN E T H Y L E NE R l D I C H L O RID E METHACRYLONITRILE * Methanal M e t h a n a m i de , Methanecarboxylic acid " M e t h a n o i c a ci d * Methanol *3-METHOxv-1-BUTANOL
ri3'f',Jil"RoxrDE soLUroN
Chapter 18 Chapter 18 '18 Chapter Chapter 17 chapter 12 DIPENTENE DlPENTENE Chapter 17 Chapter 17 1,3,5-TR|OXANE Chapter 17 Chapter 12 METHACRvLIC ACID DODECYLMETHACRYLATE DODECYLMETHACRYLATE Chapter 12 Chapter 17 FORMALDEHYDE soLUTIoNs ( 4s% oR LESS) FORM AMTDE ACETTC ACID FoRM tC ACID METHyLALCOHOL Chapter 18 221s ' '1229 7oo 375 300 1 gg3 253'1 7OO 'l g9
176 . L \
*2\2-Methoxvethoxv)ethvr t?l5i,iltffi1il:$t'?3:acetate
. *2-Methoxyethyl acetate
1se3
*w-12-rrrFrHoxy-1-MErHyLErHyL)-2-ErHyL6af"?ltitit
LOROACETAN ILI DE METHYLCH * 1-Methoxyprop an-2-ol
* 1-(2-Methoxypropoxy)propan-2-ol
\\.,'PRoPYLENE I \-\-'L MoNocLYcoL 'YI\-,'I ALKYL ETHER
1ss7
PoLY(2-B)ALKYLENE cLYCoL -Cu) ETHER MONOALKYL (C,| .3-[3-(3-Methoxypropoxy)propoxy]eoLY(2-s)ALKvLENE cLYCoL p r o pa n -1 -o l M ONOALKYL( c' - cu) ET H ER POLY(2-B)ALKYLENE GLYCOL Methoxytriglycol MONOALKYL (Cl -C6) ETHER PROPIONALDEHYDE Methylacetaldehyde *METHvL ACETATE Chapter 1 B PRoPtoNtc AclD Methylacetic acid *METHYL ACEToACETATE Chapter 18 CROTONALDEHYDE beta-Methylacrolein * METHYLACRYLATE Chapter 1 7 *2-Methylacrylic METHACRYLTC ACID acid DODECYLMETHACRYLATE 2-Methylacrylic acid, dodecyl ester DODECYLMETHACRYLATE 2-Methylacrylic acid, lauryl ester * METHvLALcoHoL Chapter 1 B *M ET H vL A MINE so L U T l o NS (42% oR LESS) Chapter 17 o-TOLUIDINE 1-Methyl-2-aminobenzene o-ToLUIDINE 2-Methyl-1 -aminobenzene Chapter 17 METHYLAMYL ACETATE METHYLAMYL ALCOHOL Chapter 17 A Chapter 18 M ET HY L MY L K E T ONE * o- TOLUIDINE 2 - M e t h yl a n i l i n e o-TOLUIDINE o-Methylaniline o- TOLUIDINE 2 - M e t hyl b e n ze n a mi n e I- TOLUIDINE o - M e t hyl b e n ze n a mi n e TOLUENE Methylbenzene TOLUENEDIAMINE M e t h y l b e n ze n e d i a mi n e ToLUENE M e t h y l b e n zo l
1231
330
1919
330
'1230 1235
306 320
i.
1233 2053 1 1 10
1993 1 993
* 2-Methyl-1,3-butadiene
3-Methyl-1,3-butadiene *2-Methylbutane * 2-Methylbutan-2-ol * 2-Methyl-2-butanol 2-Methyl-4-butanot * 3-Methyl-1-butanol * 3-Methylbutan-1-ol 3-Methylbutan-3-ol *3-Methylbut-1-ene Methylbutenes METHYLBUTENOL * 1-Methylbutyl acetate alcohol 2-Methyl-2-butyl 2-Methyl-4-butyl alcohol alcohol 3-Methyl-1-butyl alcohol 3-Methyl-3-butyl ETHER METHYL tert-BUWL
ISOPRENE ISOPRENE (ALL PENTANE ISOMERS) ALCOHOL tert-AMYL ALCOHOL tert-AMYL tsoAMYL ALCoHoL tsoAMYL ALCoHoL lsoAMYL ALCoHoL ALCOHOL tert-AMYL (ALL PENTENE ISOMERS) (ALL PENTENE ISOMERS) Chapter 1B (ALL AMYL ACETATE ISOMERS) ALCOHOL tert-AMYL ALCoHoL lsoAMYL lsoAMYL ALCoHoL ALCOHOL tert-AMYL Chapter 18
177
IBC Code
See UN No. MFAG Rev. Chapter 1 B METHYLBUTYNOL METHYLBUTYNOL METHYLBUryNOL Chapter 1B * 3-Methyl (ALL 1993 VALERALDEHYDE ISOMERS) butyraldehyde * METHYL 1237 330 Chapter 1 7 BUTYRATE -B)ALKYLENE 19 9 3 POLY(2 CLYCOL 2-beta-Methyl " carbitol" MONOALKYL( Cr- Co) ETHER 't993 -B)ALKYLEN C LYCOL POLY(2 E Methyl "carbitol" acetate - Co) ETHER MONOALKYL( Cr ACETATE "cetlosotve" ETHYLENE CLYCOL MONOALKYL 19 9 3 Methyl ETHERS '1993 "cellosolve"acetate ETHYLFNE Methyl GLYCOLMETHYL ACETATE ETHER LO E 1,1, 1-TRICH ROETHAN Methylchloroform * Methyl cyanide ACETONITRILE * METHYLCYCLOHEXANE 2296 310 Chapter 1 7 M ETHYLCYCLOPENTAD E IEN Methyl-1,3-cyclopentadiene dimer DIMER DIMER METHYLCYCLOPENTADIENE Chapter 1 7 '1993 METHYLDIETHANOLAMINE Chapter 1 7 isocyanate) DIPHENYLMETHANE Methylenebis(phenylene DIISOCYANATE Methylenebis(phenyl isocya nate) DIPHENYLMETHANE DIISOCYANATE DIBROM OMETHANE 1997 Methylenebromide DICHLOROMETHANE Methylene chloride * Methylene DICHLOROMETHANE dichloride * Methylenedi-p-phenylene diisocyanate DIPHENYLMETHANE DIISOCYANATE DIPHENYLMETHAN ate E 4,4' -Methylened iphenyl isocyan DIISOCYANATE 335 2-M ETHYL-6-ETHYLANI LI E N Chapter 1 Z Methylethylcarbinol sec-BUWLALCOHOL glycol PROPYLENE CLYCOL Methylethylene "l193 300 METHYL ETHYL KETONE Chapter 1B 2300 325 ETHYL-s-ETHYLPYRI DINE Chapter 1 7 2-M * METHYL 1 2 4 3 33 0 Chapter 1 7 FORMATE "1997 (70%OR C h a p t e r 1 B N-METHYLCLUCAMTNE SOLUTTON
LESS) Methyl glycol " 5-Methyl-3-heptano ne * 5-Methyl eptan-3-one h METHYL HEPTYL KETONE * 5-Methylhexan-2-one Methylhexylcarbinol 2-M ETHYL-2-HYD ROXY-3-B E UryN Methyl isoamylketone Methyl isobutenyl ketone Methylisobutylcarbi nol acetate Methylisobutylcarbinol METHYL ISOBUWL KETONE * 2-Methyl lacton Ie itri * METHYL METHACRYLATE * Methyl methanoate ETH ETH UTAN L O 3-M YL-3-M OXYB 3-METHYL-3-M ETHOXYB UTYLACETATE METHYLNAPHTHALEN E (MOLTEN) (o- and p-)Methylnitroben zene * B-Methylnonan-1-ol Methylolpropane * 2-Methylpentane * 2-Methylpentane2, 4-diol * 2-Methyl-2,4-penta edio I n Methylpentan-2-ol 4-Methylpentanol-2
PROPYLENE CLYCOL AMYL KETONE ETHYL ETHYL AMYL KETONE Chapter 1 7 METHYLAMYL KETONE ocr ANoL ( ALLTSOMERS) Chapter 1 7 METHYLAMYL KETONE MESITYL OXIDE ALCOHOL METHYLAMYL METHYLAMYL ACETATE Chapter 1B ACETONE CYANOHYDRIN Chapter 1 7 METHYLFORMATE Chapter 1 B Chapter 1 B Chapter 1 7 (o- and p-)NrnoroluENE DECYLALCOHOL (ALL TSOMERS) ALCOHOL n-BUTYL ( HEXANE ALLTSOMERS) HEXYLENE CLYCOL HEXYLENE CLYCOL METHYLAMYL ALCOHOL METHYLAMYL ALCOHOL
19 9 3
310
1993
1993
178
1!
'
BUTRALDEHvDE( ALLr soMER S) tsoBUTyL ALCOHOL tsoBUr yL ALCoHoL ' tert-BUTYL ALCOHOL tert-BUWL ALCOHOL METHACRvLTC ACID (ALL ISOMERS) BUTYLACRYLATE tsoBUTyL ALCoHoL tert-BUTYLALCOHOL p-CYMENE sec-AMYLALCOHOL ( HEXENEALLISOM ERS) Chaprer 1 B Chapter 1 7 Chapter 17 Chapter 1 Z alpha-Methylpyridine 2-METHYLPYRIDINE N-Methylpyrrolidinone N-METHYL-2-PYRROLIDONE * 1-Methylpyrrolidin-2-one N-METHYL-2-PYRROLIDONE N-METHYL-2-PYRROLIDONE Chapter 18 * 1-Methyl-2-pyrrolidone N-METHYL-2-PYRROLIDONE *M ET H YL sA L tcY L A T E Chapter 1Z Methylstyrene VINYLTOLUENE " aIpha-UETHYLSTYRENE Chapter 17 Middle oil cARBoLtc otl MiIK acid LACTICACID Mineral jelly PETROLATUM Mineral wax PETROLATUM Mixed acid oil footnote Mixed general acid oil footnote Mixed hard acid oil footnote Mixed soft acid oil footnote MOLASSES Chapterl8 ,:. M o n o ch l o ro b e n ze n e CHLOROBENZENE M o n o ch l o ro b e n zo l CHLOROBENZENE M o n o e th a n o l a mi n e ETHANOLAM INE M o n o e th yl a mi n e ETHYLAM INE Monoethylamine solutions, 72"/" or less ETHYLAMINE SOLUTIONS ( 72% OR LESS) Monoisopropanolamine ISOPROPANOLAMINE M o n o i so p ro p yl a mi n e ISOPROPYLAM INE M o n o m e th yl a mi n e so l u ti o ns, 42o/oor M ETHYLAM INESOLUTIO N S ( 42% OR LESS) less M o n o pro p yl a mi n e n- PROPYLAMINE *MoRPHoLTNE Chapter 17 MOTOR FUEL NTI-KNOCK OMPOUNDS Chapter 1Z A C (coNTArNrNC LEADALKYLS) M u r i a t i c a ci d HYDRoCHLoRtc ACID MYRCENE Chapter 1 B
1l , .i
1!
1g 'l S
325
2303
31 0
2054 "1649
322 111
19
ffiN|MALANDF|SHAC|DotLSANDDlST|LLATES,N.o.S.orVEcETABLEAC|D( A N D D I S T I L L A T E S ,. O . S . s h o u l d b e u s e d f o r t h i s s u b s t a n c e , e p e n d i n g o n i t s o r i g i n . N d
179
IBC Code
Name See Naphtha, coal tar COAL TAR NAPHTHA SOLVENT * (MoLTEN) NAPHTHALENE Chapter 1 7 N A P H T H AL E N E S UL P H ONIC A CID- FORM-Chapter 1B A L D EH Y DE COP OL Y ME R, OD IUM SALT S SOLUTION WH|TE SPlRlT, rOW (5-20"/"1 Naphtha safety solvent AROMAT]C N A P H T H EN IC CID S Chapter 1 7 A ANTMALAND FlsH olLS, N.o.s. Neatsfoot oil NEODECANOICCID A Chapter 17 VINYL NEODECANOATE Neodecanoic acid vinyl ester v*v' Neopentanoic acid TRIMETHYLACFI-IC ACID N I T R AT I N G ACID (MIX T U RE S ULPHURIC Chapter 1 7 OF A N D N I T R IC CID S ) A *Nitric ACID ( 70% AND OVER) NITRIC a c i d , fu mi n g "NrrRrc A C I D ( 7 o %A N D o v E R ) Chapter 17 UN No. MFAG 2304 3' 14 Rev
7OO
1796
7OO
2031,
610/
2032 NITRIC NrrRrc ACID AcrD (70%AND ovER) OVER) Nitric acid, red fuming * N|TRTC AC|D(LESS THAN70%) chapter 17 NITRILOTRIACETIC TRISODIUM ACID, SALT Chapter1B SOLUTION * 2,2',2"-Nitrilotriethanol TRTETHANOLAMTNE *1 TRllsopRopANoLAMtNE ri-2-propanol ,1','1"-Nitrilot * 1',1i,1 "-Nitrilotripropan -2-ol TRilsopRopANoLAMtNE * NITRoBENZENE C h a p t e r17 2031
700 700
1662
335
(2O%\ NTTROPROPANE * o N I T R O PH E NOL (MOL T E N ) Chapter 17 * 2 - N i t r o p h e n o l (mo l te n ) (M o- NITROPHENOL OLTEN) 'l * 1 - o r 2 - N I T R OP ROP A N E Chapter 7 N I T R O PR O P A N(6 0 %)/NIT ROE THANE E Chapter 1Z (4o%) MTXTURE *oChapter 1 7 o r p - N I T ROT OL UE N E S *NoNANE (ALL rsoMERS) Chapter 17 n-Nonane NONANE ( ALLISOMERS) * NO N AN O I C A C|D (A L LT S OME R S) chapter 1 B * NONYL ALCOHOL ( ALLISOMERS) No n a n o l s * METHYLHEPryL KETONE Nonan-2-one * No N E N E ( A L Lrso ME RS ) Chapter 1 Z N O N - N O X I OUS l QUl D, N .o .S . (1 8) ( TRADE Chapter 1B L ll N A M E . . . , O N T A T N S . .A)P P E N D I X l C . * NONYL ACETATE Chapter 1 7 ' 17 *NoNyL Chapter A L Co Ho L (A L Lrso ME R S ) DECvLALCoHoL ( ALLtsoM ERS) N o n y l c a r b i no l NONENE( ALLISOMERS) Nonylene Nonyl hydride NONANE ( ALLISOMERS) * NoNyL METHACRvLATE MONoMER Chapter 1 B NONYLPHENOL Chapter 12 NONYLPHENOL POLY(4+)ETHOXYLATES Chapter 17 N A M E . . . ,C O N T A | N S . . .S . T .1 , C A T .A , ) N O X I O U SL lQU tD, F .,(2 ) N .O.S .(TRADE N A M E . . . , O N T A I N S . . .S . T .1 , C A T .A C ) N O X I O U SL lQU l D , N.F .,(3 ) N.O.S .(TRADE N AM E . . . ,CON T A |N S ...) .T .2 , C AT.A S N O X I O U SL lQU l D , F .,(4 ) N .O.S .(TRADE N A M E . . . , O N T A I N S . . .S . T . , C A T .A C ) 2 N O X I O U SL lQU l D , N.F .,(5 ) N.O.S .( TRADE N A M E . . . ,CON T A IN S ...) .T .2 , CNf. B S (6 N O X I O U SL | QU l D , N.F ., ) N.O.S .( TRADE N A M E . . . ,CON T A |N S ...) .T .2 , CNf. B, S M . P .1 5 " C + NOXIOUS LlQUlD, F., (7) N.O.S.(TRADE N A M E . . . , O N T A | N S . . .S . T . , C A T .B C ) 2
1664 1920
19 9 3 305 199
710 199
Chapter 1 7
180
Chapter 17 Chapter 17
* l - O c t a d eca n o t ALCOHOLS( cr 3*) *O c t a d e c an -1 -o l ALCOHOLS( cr 3*) '' *c r s - 9 - O c ta d e ce n o i c a ci d olEtc ACID . 1993 . (Z)-octadec-9-enoic acid olEtc ACID 1 993 * Octanal oCryL ALDEHYDES * o C T A N E ( A L L | S o M E R S ) C h a p t e r 1 7 . | 2 6 2 3 1 0 1 9 9 3 *o c r A N o t c ,l gg3 A CfD (A L LIS OME RS) chapter 18 *Octan-1-ol ocrANoL (ALLtsoMERS) * ocrANoL (ALL tsoMERS) Chapter 1 Z 305 1993 *o c r E N E (A L Ltso ME RS ) Chapter 1Z 1 993 octoic acid ocrANotc ActD (ALLtsoMERs) * Octyl acetate n-OCTyL ACETATE nOCTYL ACETATE Chapter 1 7 *Octyl acrylate 2-ETHYLHEXYL ACRYLATE *Octyl alcohol ocrANoL (ALLtsoMERs) *o c r y L A L DE H yDE S Chapter 1 z 1191 300 1gg3 Octylcarbinol NoNYL ALCoHoL (ALLISoMERS) OCryL DECYLADIPATE Chapter 18 octyl decyl phthalate D|ALKYL(Cz-Cl:) PHTHALATES Octylic acid ocTANOtC ACtD (ALL TSOMERS) *Octyl nitrate ALKYL(cz-Ce) N|TRATES 1993 *o c t y l n i t r a te s (a l l i so me rs) ALKvL( cr - cs) NITRATES 1993 Octyl phthalate (Cz-C,,) PHTHALATES DIALKYL O i l o f m i rb a n e NTTROBENZENE O i l o f v i t ri o l suLpHURtc ACID Oiticica oil vEGETABLE otLS, N.o.s. OLEFIN-ALKYL ESTER COPOLYMER Chapter 18 (MOLECULAR WETCHT 2000+) (Cs-Cr) OLEFINMIXTURES Chapter 1 7 O L E F I N I X T U R E( C s - C l s ) M S Chapter 1Z 'lgg3 (Cr:*, A L L IS OME R S ) O L EF I N S Chapter 18 (Co-C,s)MIXTURES alpha-OLEFINS Chapter 17 *oLEfC ACID Chapter 18 1gg3
oLEUM
cnubi"rrT
183 1
7oo
1gg3
chapterlT VEGETABLE oILS, N.o.S. pHospHoRtc ACID M ORPHOLINE tSOpROpyLETHER DTETHvLENE cLyCoL DtpRopyLENE CLycoL
181
IBC Code
Name Oxymethylene See SOLUTIONS FORMALDEHYDE ( 4s% oR LESS) UN No. MFAC Rev.
ACID OIL PALM KERNEL Pa I m n u t o i l PaIm oil Palm oil fatty acid ACID METHYLESTER PALM OIL FATTY PaIm oil methV| CStCr PALM STEARIN ParaffiN n-Paraffins (Cro-Cro) Paraffin scale PARAFFIN X WA e AR A L D EH vDE PCANUT OiI Pear oil P e e l o i l ( o ra n g e s a n d l e mo n s) P e l a r g o n i c a ci d P e l a r g o n i c a l co h o l * P EN T AC H L OROE T HA N E Pentadecanol * 1 - Pe n t a d e c e n e * P e n t a d e c - 1-e n e * Penta-1,3-diene * 1,3-PENTADTENE Pentaethylene glycol P E N T AE T HY L E NE H E X A MIN E Pentalin Pentamethylene " Pentanal * Pentane n-Pentane * e EN T AN E A L LT S OME RS ) ( * Pentanedial solutions, 50% or less * PE N T AN o t c A CID n-Pentanol * Pentan-l-ol * l-Pentanol * Pentan-2-ol * 2 - Pe n t a n o l * Pentan-3-ol * 3-Pentanol sec-Pentanol
ChaPter 1 7 VECETABLE OILS,N.O.S. VECETABLE OILS,N.O.S. ACID oll PALM KERNEL Chapter 1B ACID MFTHYL PALM OIL FATTY ESTER Chapter 1B WAX PARAFFIN (Cro*) n-ALKANES WAX PARAFFIN ChaPter 18 1264 Chapter 1 Z OILS,N.O.S. VECETABLE (ALLISOMERS) AMYL ACETATE olLS, N.o.s. VECETABLE NONANOIC ACID ( ALLISOMERS) NONYL ALCOHOL( ALLISOM ERS) 1669 Chapter 17 ALCoHoLS ( c13*) ( OLEFINSCr :*, ALL ISOM ERS) ( OLEFINSCr r *, ALL ISOM ERS) 1,3- PENTADIENE C h a p t e r 17 PoLYETHYLENE cLYCoL Chapter 18 PENTACHLOROETHANE CYCLOPENTANE ( ALL vALERALDEHYDE ISOMERS) (ALLISOMERS) PENTANE ( PENTANEALLISOM ERS) 'l 1265 Chapter 7 SOLUTIONS CLUTARALDEHYDE (so% oR LESS) Chapter 18 n-AMYL ALCOHOL n-AMYL ALCOHOL n-AMYLALCOHOL sec-AMYL ALCOHOL ALCOHOL SCC-AMYL sec-AMYLALCOHOL sec-AMYLALCOHOL sec-AMYL ALCOHOL
19 9 3
19 9 3
300 1993
1993
310
" 1993
1 993 19 9 3 1 993 19 9 3
i:"'J;::lioicetate
n-Pentene * Pentenes * P EN T EN EA L L ( rso ME R S ) * Pent-1-ene * Pentyl acetate sec-Pentyl acetate * Pentyl alcohol sec-Pentyl alcohol * tert-Pentyl alcohol n-PENTYLPROPIONATE * e E R C H L O ROF T HY L E N E * Perchloromethane * P e r h y d r o a ze p i n e Pe r i I I ao i l P ET R O L A T U M Pe t r o l e u m j e l l y Ph e n e
ffi?T:'#f,ill,',,oMERS)
(ALLISOMERS) PENTENE ( ALLISOMERS) PENTENE Chapter 17 ( ALLISOMERS) PENTENE (ALLISOMERS) AMYL ACETATE (ALLISOMERS) AMYL ACETATE n-AMYL ALCOHOL sec-AMYL ALCOHOL tert-AMYL ALCOHOL ChapterlT Chapter 17 CARBON TETRACHLORIDE HEXAM ETHYLENEIMINE OILS,N.O.S. VECETABLE Chapter 18 PETROLATUM HAVAND MTXTURES BENZENE O I N C 1 O %B E N Z E N E R M O R E
1ee3
1993
1993 1993
182
1 993 1993
1993 1993
1993
1993
1997 1993
1993
183
IBC Code
See Name * POLYETHYLENE POLYAM INES P o l y ( i m i n o eth yl e n e )s * POLY(4+)ISOBUTYLENE Polyisobutylene Chapter 18 PO L Y( 4 + ) I SOB UT Y L E NE Chapter 17 PO L YM E T HY L E NE -P OL Y P HE NYL ISOCYANATE ( Czu*) Chapter 18 PO L YO L EF INMIDE A L K E NE A MINE A BORATE Chapter 1 B PO L YO L EF INMID EA L K E N E A MINE A UN No. MFAG Rev. '1993 370
1ee3
1993 1gg3 1993 1gg3 1993 1993 1993 1993 19 9 3 1993
'
1993
320
Propenenitrite
Pr o p e n e o xi d e * P r o p e n o i c a ci d 1 - Pr o p e n o l-3 * Prop-)-en-1-ol .2-Piopen-1-ol Propenyl alcohol beIa-PROPIOLACTONE * pRopIoNALDEHyDE *pRoproNrc ACID Pr o p i o n i c al d e h yd e *pRoproNrc ANHvDRIDE PR O P I O N I T R IL E beta-Propionolactone
^Jll'fuRTtHli' :
PROPYLENE OXIDE ACID ACRYLIC ALCoHOL ALLYL ALLYLALCoHOL ALLYL ALCoHoL ALLYLALCOHOL ChapterlT Chapter 1Z Chapter 17 PROPIONALDEHYDE Chapter 17 Chapter 1 7 beIa-PROPIOLACTONE
184
' 1276
330
1277
1278
34O
308 L Y C o ] - _ j 'lgg3
t-t?|i?$l[i,:t'it#?)t?.tlHi,:tfErHER .il3i::ib*tt
Chapter 1B PROPYLENE CLYCOL
1ee3
1ss3
"1993
.ffi[:tt*t'ErHER Chapter 12
Chapter 1 7 ( ALLISOM ERS) PENTENE DI-n-PROPYLAMINE BUryLENEclycol TRIM ETHYLBENZENE :
)3?3 3?3
2057 31 0
*PYRIDTNT
Py r o l y s i s g a so l i n e , co n ta i n i ng looh or m o r e b e n ze n e Pyrolysis gasoline (steam-cracked naphtha)
c$il:??Yt-t'
BENZENE AND M IXTURES VHA ING 10% BENZENE M OR E OR BENZENE AND MtxruRES HAVI N C 1 0 % B E N Z E N ER M o R E o
1282 32s
Raisin seed oil R a p e s e e d a ci d o i l Rape seed oil R i c e b r an o i l R O SI N R o s i n , f u ma ri c a d d u ct i n w ater d i s p e r si o n R O S I NS OA P (DIS P R OP ORTIONATED) SOLUTION R u b b i n g a l co h o l Safety solvent Safflower acid oil Safflower oil Salad oil Saturated fatty acid (C13 and above)
VEGETABLE OILS,N.O.S. vEcETABLE ACID otLS AND DISTILLATES, N.O.S vEcETABLE otLS, N.o.s. VECETABLE otLS, N.o.s. Chapter 1 7 FUM ARIC ADDUCT OF ROSIN, WATERDISPERSION Chapter 17 tsopRopi' L ALCoHoL WHITE SPlRlT, LOW (15-20%) AROMATIC vECETABLE ACID otLS AND DISTILLATES, N.O.S vECETABLE otLS, N.o.s. vECETABLE olLS, N.o.s. FATry ACID (SATURATED Cr3*)
185
IBC Code
UN No. MFAG See vECETABLE olLS, N.o.s. suLPHURlc ACID, sPENT Chapter 1B i ALKYLBENZENESULPHONIC , AC ID SODIUM SALTSOLUTION S O D I U M AL K Y L(C ro -Crr)S U L P HONATES Chapter 17 60-65"/uSOLUTION 705 1819 Chapter 17 S S O D I U M AL U MIN A T E OL UT IO N SL Chapter 1B S O D I U MA L U M I N O S I L I C A T E U R R Y *soDtuM Chapter 18 BENZOATE * MERCAPTOBENZOTHIAZOL Sodium 1,3-benzothiazole-2-thiolate , SODIUM SALTSOLUTION Solution MERCAPTOBENZOTHIAZOL, S o d i u m 1 ,3 -b e n zo th i a zo l -2 -ylsulphide SODIUM SALTSOLUTION solution SODIUM DICHROM ATE S o d i u m b i ch ro ma te soLUTr oN ( 70% oR LESS) 705 (1 OR LESS) / Chapter 17 S O D I U M B OROH Y DR IDE s.,/" S S O D I U M HY D ROX ID E OL U T ION *soDruM Chapter 18 s cARBoNATE oLUTtoN *SODIUM 2428 745 Chapter 17 S CHL OR A T E OL UT |ON( s0% OR L ES S ) ACID, SODIUM SALT RESYLIC Sodium cresylate SOLUTION "soDtuM 155 Chapter 1z so DT cHR o MA T E L UT l oN ( 7 O %O R L E S S ) " 1,+DIHYDRO-9,10-DI-HYDROXYdiSodium 1,4-dihydroanthracene-9,10DISODIUM SA LT ANTHRACENE, d i y l d i o xi d e SOLUTION "Sodium CLYCINE, SODIUM SALT g lyci n a te so l u ti o n SOLUTION SOLUTI O N SODIUM HYDROXIDE So d i u m h y d ra te ( C h a p t e r 17 S S O D I U M H Y D R O C E N U L P H I D E6 % O R (3% L E S S ) / S OD T U M R B ONA T E OR LESS) CA S O L U T I ON "soDtuM 635 2693 HyD Ro cE N su l p H trE soLUTtoN Chapter 17 (4s% oR LESS) *soDruM 225 2949 Chapter 17 H v D R o S U L P H I Ds o L U T t o N E (4s% oR LESS) SODIUMHYDROSULPHIDE/AMMONIUM Chapter 17 S SULPHIDE OLUTION * 705 1 824 Chapter 1 7 soDlu M HyDRoxlDE soLUTtoN *soDruM 1791 741 Chapter 17 H yp o c.HL o R rrEso L UTloN (15% OR LESS) AC LIGNINSULPHONIC ID, Sodium lignosulphonate SODIUM SALTSOLUTION *So d i u m me th yl d i th i o ca rb a ma te solution METAM SODIUM SOLUTION *soDtuM 235 Chapter 17 s NrrRrrE oLUTtoN Chapter 17 S S O D I U M PE T ROL E U M UL P H O NATE SOLUTIONS Chapter 1B SODIUM POLY(4+)ACRYLATE *s o D t u r v r Chapter 17 stL tcA T E L U T to N so *s o D r u M so Chapter 1B SUL e H A T E L U T to N S *soDruM 225 Chapter 17 s suLpHrDE oLUTtoN (1s%oR LESS) *s o D l u M Chapter 17 so S U L P HIT E l tfrrn S l ( 25% oR Name Sesame oil S l u d g e a c id *soDtuM AC E T A T E L U T to N S so S o d i u m a l kyl b e n ze n e su l p h o n ate .i Rev.
1993 1993
1993
1993
19 9 3
1993
tol5ilL sulphydrate
Sodium tartrates and mono-/di-succinate SODIUM TARTRATES/SODIUM SUCCINATES SOLUTION solution *s o D r u M succtNATES Chapter 17 T A RT RA T E S /so DIu M SOLUTION *S o d i u m ( t etra h yd ro b o ra te (1 5 %" or !ess) / soDluM BOROHYDRIDE1s% HYDROX ID E OR LESS) /SODIUM s o d i u m h yd ro xi d e so l u ti o n SOLUTION * Chapter 1 7 soDtuM THtocyANATE soLUTtoN (s6%oR LESS)
., : ;
186
rt
1993
SO R B T TOLOL U T ION S So y a a ci d o i l Soya bean oil Sp e r m oi l Spirits of wine Stoddard solvent *STYRENE MONOMER Suberane (C S U L PH OH Y DR OCA R B ON a -Css) S U L PH OH Y DR OCA R B ON ONC- CHAIN L ( c r a *) AL K Y L A MT NMIX T U RE E SULPHOLANE *suLpHURrc ACrD "Sulphuric acid, fuming *s u L p H U RrC A C ID, sP E NT S u l p h u r i c ch l o ro h yd ri n S u l p h u r i c e th e r *s u L p H U R (MOL T E N ) Sunflower oil S u n f l o we r se e d a ci d o i l Sweet-birch oiJ Tatleol TALLOf L (CRUDEAND DISTILLED) TALLOIL FATTY ACID, BARIUM SALT T AL LO I L F A T ry A CID (RE S IN ACIDSLESS THAN 2O%) T AL LO I L S OA P (D IS P ROP ORTIONATED) S O L U TION Tallot T AL L O W TALLOW FATTY ACID Tar acids Tar camphor * 3,6,9,1 2-Tetraazatetradecane 1 , 14 d i a m i n e *"l , 3 , 5 , 7 Je tra a za tri cycl o [3 .3 .1.13' 7]TETRACHLOROETHANE "T e t r a c h lo ro e th yl e n e *T e t r a c h l o ro me th a n e *Tetradecan-1-ol * - T e t r a d e ca n o l 1 Tetradecene T e t r a d e c yl b e n ze n e TETRAETHYLENE CLYCOL . TETRAETHYLENEPENTAMINE "Tetraethvllead
2055
310
1830 1832
2448
6351
700 19
J:J,:l'?)'
PERCHLOROETHYLENE TETRACHLORIDE CARBON TETRACHLORIDE ALCOHOLS(cr:*) ALCOHOLS( cr :*) ( ALL ISOM ERS) OLEFINSC13*, ALKYL( Ce+) BENZENES Chapter 18 Chapter 1 7 MoroR FUEL ANTI-KNOCK coMPouNDS ( CONTATNT N C LEAD ALKYLS) chapter 17 DICYCLOPENTADIENE ChapterlT TETRAHYDRONAPHTHALENE MORPHOLINE MORPHOLINE SULPHOLANE SULPHOLANE TETRAHYDRONAPHTHALENE
1702340
'19 19 19 19 2320 320
'
'a9
*TTTRAHYDROFURAN * ydro-4,7-methanoindene 3a,4,7,7a-Tetrah TETRAHYDRONAPHTHALENT * 1,2,3,4+etrahydronapthalene Tetrahyd ro-1,4-oxazine T e t r a h y dro th i o p h e n e l -d i o xide *T e t r a h y d ro th i o p h e n e 1,1 -d i oxide I . TetTAIin
2056
330 310
.ii .. :
187
IBC Code
Name 1 , 2 , 3 , s - T e tra me th yl b e n ze n e
Tetramethylene cyanide * Tetramethylene ide dicyan glycol Tetramethylene Tetramethylene oxide Tetramethylene sulphone * Tetramethyllead
Tetrapropylbenzene Thiophan ulphone s *TOLUENE TOLUENEDIAMINE TOLUENE DIISOCYANATE * 2-Toluidine * o-TOLUIDINE Toluol
o-Tolylamine (.-, o- and p-)Tolyl chlorides
UN No. MFAG Rev. See 1993 TETRAMETHYLBENZENE ( ALLTSOM ERS) Chapter 17 ADlPONITRILE ADIPONITRILE BUr yLENE CLYCOL TETRAHYDROFURAN SULPHOLANE 1993 ANTI- KNOCK M OTOR FUEL coM PouNDS ( CONTATNtNC LEAD ALKYLS) 1gg3 ALKYL( Cs*) BENZENES SULPHOLANE 1294 310 Chapter 1Z 1709 335 Chapter 1 7 2078 370 Chapter 17 19 9 3 o- TOLUIDINE 1708 335 Chapter 1 7 TOLUENE o- TOLUIDINE (m-,o- and p-)CHLOROTOLUENES DIISOCYANATE TOLUENE A MALEIC NHYDRIDE CLYOXALSOLUTION (4o% oR LESS) EPENTAMTN E TETRAETHYLEN Chapter1Z Chapter 17 Chapter 17 Chapter 17 1,1,2-TRICHLOROETHANE LOROETHYLENE TRICH Chapter17 2321 2831 330 340 340 340
1710
CHLOROFORM Chapter 1 7 * -1,2,2:fRTFLUOROETHANE Chapter 1 Z 1,1,2-TRlcHLoRo (CON T A ININCLESS Chapter 1Z T R I C R ES Y L P HOS P H A T E THAN 1o/o ortho-ISOMER) (C T R I C R ES Y L OS P HA T E ONT AININC1% Chapter 17 PH
2574
355
ortho-ISOMER) OR MORE *tRToECANE *TRrDECANoIc ACrD Tridecanol Tridecene Tridecoicacid *TRIDECYL ACETATE
*Tridecyl alcohol * T r i d e c y l b e nze n e
Chapter 1 B Chapter 1 7 ALCOHOLS( Cl3*) ( OLEFINSCI:*, ALL ISOMERS) ACID TRIDECANOIC Chapter 1B ALCoHoLS (c13*)
Triethylene glycol monobutyl ether Triethylene glycol ethyl ether Triethylene glycol methyl ether
TRIETHYLENETETRAMINE *TRIETHYL PHOSPHATE *TRIETHYL PHOSPHITE Triformol Tri(2-hyd roxyethyl mine )a Trihydroxypropane
2259
320
'1993 19 9 3
2323 330
lBB
SCANNED BY KIVAN ( MKP ) 2004
1297
'1993
BUTLAMINE ( ALLISOM ERS) TRIM ETHYLBENZENE ( ALLTSOM ERS) *T R I M E T HvL B E N Z E N EL L (A rso M ERS) : Chapter 1 7 TRIMETHYLBENZENE uns-Trimethylben zene ( ALLTSOM ERS) Trimethylcarbinol tert-BUWL ALCOHOL * ISOPHORONE 3,5,5-Trimethylcyclohex-2-en-1-one "T r i m e t h yl e n e 1,3- DICHLOROPROPANE ch l o ri d e T r i m e t h yl e n e d i ch l o ri d e 1,3- DICHLOROPROPANE "3 , 3 ' - T r i me th yl e n e d i o xyd i p ropan- 1ol TRTPROPYLENECLYCOL *T R I M E T HvL H E X A ME T HvL ENEDTAMTNE 2327 Chapter 1 7 (2,2,+ and 2,4,+ISOMERS) *TRIMETHvLHEXAMETHvLENE DnsocyAN2328 Chapter 1 7 ATE(2,2,4and 2,4,4-ISOMERS) TRIMETHYLOLPROPANE POLYETHOXYLATEChapter 1B 2,2,4-TRIMETHYL-1,3-PENTANEDIOLChapter 17 1-ISOBUTYRATE 2,2,4-TRIMETHYL-1,3-PENTANEDIOL Chapter 1 B DIISOBUryRATE DIISOBUTYLENE 2,4,4-Trimethylpentene'1 * DIISOBUr yLENE 2 , 4 , 4 - Tri me th yl p e n t-1 -e n e DIISOBUTYLENE 2,4,4lrimethyf pentene-2 * 2,4,4-[rimethylpent-2-ene DIISOBUryLENE *TRTMETHyI priospHrrE 2329 Chapter 1 7 * 2 , 4 , 6 - Tri me th yl -1 ,3 ,5 -tri o xane PARALDEHYDE * 1 , 3 , 5 - TRl o xA NE Chapter 1 7 1,3,5-TRIOXANE sym-Trioxane 1,3,5- TRIOXANE Trioxin -,\ Tripropylene PROPYLENE TRIMER T R I PR OP Y L E N E Y COL Chapter 18 CL POLY(2-B)ALKYLENE Tripropylene glycol methyl ether CLYCOL M ONOALKYL( C,- Cu) ETH ER TRIXYLYL Tris(dimethylphenyl) phosphate PHOSPHATE Tris(hydroxymethyl)aminomethane 2-AMINO-2-HYDROXYMETHYL-1,-
320 370
,-i,fi:i3[iLrris(2-hydroxypropyr)amine
;[[371"ilil,'l
::''"so]-urroN
( CONTAININC1% OR MOR E ortho-ISOMER) TRICRESYL PHOSPHATE (CONTAININC LESS THAN 1% PHOSPHATE TRIXYLYL Chapter 17 vE VECETABLE OILS,N.O.S. vEGETABLE otLS, N.o.s. Ch apter 17 TURPENTINE TURPENTINE (Cto*) n-ALKANES Chapter 17 Chapter 1 7 Chapter 1 Z ALKYL( Ce*) BENZENES UNDECANoIc ACID
1993
1993
189
IBCCode
:' Na m e Urea, ammonia liquor .:'"* See NITRATE LJREA/AM M ONIUM l soLUTloN ( coNTAlNlNG AQUA AM M ONTA) UREA/AMM ONIUMNITRATE soLUTr oN ( coNTA|NlNc AQUA AM M ONTA) Chapter 1B U N N o. M F AG R ev .
Ur e a , a m m o n i u m ca rb a ma te solutions
U R E AA M M O N I U M M O N O - A N D D l UM HYDROCEN PHOSPHATE/POTASSI C H L O R I DE OL UT ION S *uRrnTnMMoNtuM NITRATE soLUTtoN S UR E A / A M MONIU MN IT R A T E OL UTION ( c o N T Ar NrNC A QU A A MMONIA) *uRrnTnMMoNtuM pHospHATE S O L U T I ON S UR E AF O R M A L D E HY DR E S IN OLUTION E U r e a r e s i n s o l u ti o n *uREA soLUTroN
Chapter 1B RESIN UREAFORMALDEHYDE SOLUTION Chapter 18 (ALLtsoMERS) vALERALDEHYDE Chapter 1 7 ( ALL VALERALDEHYDE ISOMERS) ACID PENTANOIC ACID PENTANOIC (ALL VALERALDEHYDE ISOMERS) HITESPlRlT, LOW ( 15- 20%) 1 993 1993 1993
Valeral (A V AL ER A L DE HY D E L LIS OME RS ) n - V a l e r a l d e h yd e . *Valeric acid n-Valeric acid Valeric aldehyde Varnoline
2058
300
1993
1301
330 1993
t .
Walnut oiI WATER Water-based fish meal extract W AX E S Whale oil Wh i t e c a u sti c W H I T ES P l R l T , O W ( 1 s - 2 0 % )A R O M A T I C L Wi n e Wintergreen oil Wo o d a l c o h o l Wood tar creosote * x Y L EN r s *xYLENoL Xy l o l s Z I N C AL KA RY L DIT HIOP H OS P HATE (Cz-Cro) Z I N C AL KE NY L R B OX A MID E CA *ztNC AL Ky LDrrH ro p H o sp HA T E(cr - cr a) Zinc bromide drilling brine .
1307 2261
,:190
INTRODUCTION
for chemicals 1.1 The criteriaaie intendedfor use when considering i n c l u s i o nn c h a p t e r l " a n d f o r a s s i g n i n a p p r o p r i a t e p e c i a r e q u i r e m e n t s . g s l i V fo e o T h e y s h o u l da l s o b e u s e d b y A d m i n i s t r a t i o n s r p r e l i m i n a r y v a l u a t i o n f p r o d u c t s h i c ha r e n o t i n c l u d e d n t h e C o d e ,p e n d i n g h e i rc o n s i d e r a t i ob y i t n w t h e S u b - C o m m i t t eo n B u l kC h e m i c a l s . e 1.2 Although the criteria have been developedto identify chemicals which appearto requirespecialprecautions, they should not be used as must alwaysbe taken into account.A certain absolutes. Human experience i a m o u n t o f f l e x i b i l i t y s a l l o w a b l ei n d e a l i n gw i t h p r o d u c t sw h i c h h u m a n hazards showsmay presentgreateror lesser than the evaluation experience systemsuggests. numerical valueswilt need 1.3 For a number of productsthe suggested adjustmentto account for such physicalpropertiesas vapour pressure, in hazard, For example, estimating inhalation the the sofubifity and density. LCsowill providea relativeidea of the vapour toxicitybut the chemical's for volatility also and odour characteristics need to be considered a realistic Products which are volatileand offer littlewarningthat hazardassessment. benzene)are more dangerous than their vapoursare harmful(chloroform, a s t h o s eh a v i n ga l o w v a p o u rp r e s s u r e t a m b i e n tt e m p e r a t u r ea n d a d i s t i n c t w o d o u r ( p r o p i o n i c c i d , e t h a n o l a m i n e P.r o d u c t s i t h a h i g h e rL C s os h o u l d a ) if also be considered, they are lessdensethan water and of low solubility, s i n c et h e y w i l l f l o a t i f s p i l l e df r o m a d a m a g e dt a n k a n d p r e s e n ta m u c h greater inhalationhazard than those which are more dense and sink. f t, S i m i l a r l y h e L D s o( o r a l )c a n n o tb e u s e da s t h e s o l ec r i t e r i o no r j u d g i n gt h e products which are solublein water and do not have hazardfrom ingestion; in tasteor odour are more likelyto be ingested largerdoses. a pronounced products with a somewhat lower LDsobut which havea very Forthis reason, . , w l o w s o l u b i l i t i n w a t e r ,o r a d i s t i n ct a s t e s h o u l dn o t b e i n c l u d e dF i n a l l y , i t h y regardto dermaltoxicity,some productsare absorbedrapidlythroughthe Products skin or absorbedwith very little or no irritation(phenol,aniline).
* The criteria were approved before the IBC Code was adopted. Therefore the reference to chapter Vl should be taken as a referenceto chapter 1 7.
191
IBC Code with thesecharacteristics a somewhathigher LDso(dermal)shouldbe but included 1.4 The followingcriteriaare intendedfor guidanceonly, and a certain flexibility approachmust be allowed for productswhich in realitymay of presentgreateror lesserhazardsthan the evaluation systemsuggests. For this reason, experience and good judgementare necessary. :
PARTAISAFETYHAZARDS
2 MINIMUM HAZARDCRITERIA
2.1 which fall into one or more of the followingcategories Chemicals shouldbe considered hazardous, and be includedin chapterVl. .l Significantly toxic by inhalation LCso(1 hour, rats)lessthan or equal to 2000 ppm, takingvolatility into account. ,
.2 Significantty toxic by oral ingestion LDsolessthan or equal to 1000 melk1 (oral,rat).Factors suchas solubility and tasteshould be taken into account. \ .3 Significantty toxic by skinabsorption LDsolessthan or equalto 12OOme/ke (dermal,rabbit).Products with a somewhathigher LDso but which are absorbedwith very little or no irritation s h o u l db e i n c l u d e d . .4 Inhalation vapours is known to cause attergicsensitization, of leadingto seriousor long-termeffects .5 tntermittent exposure vapours periodof time to over an extended is known to causemoderateto severeinjury. .6 Liquids that are corrosive the skin,i.e.,liquids to that causevisible necrosis the skin tissueat the site of contactwhen testedon of the intactskin of an animalfor a period of up to 4 hours. .l Liquidsthat are skin sensitizers, leadingto seriousor long-term ffects. Liquids that are sufficiently reactive with water to causea h azard, due to the productionof gas,aerosols largeamountsof heat. or
"
.8
192
SCANNED BY KIVAN ( MKP ) 2004
Re/eva decisionsof the MSC and MEPC nt .l 1 Flashpoint below 23"C (closed cup) and differencebetween (expressed a percentage upperand lower limitsof flammability as 2O%. by volume in air) exceeds : . .12 Severety corrosive the materials normal ship construction to of (principally steel)such as to endanger the integrity the ship. of 2.2 P r o d u c t sh a t m e e to n e o r m o r eo f t h e c r i t e r i ai s t e d n 2 . 1 . 1t o 2 . 1. 1 2 t l i inclusive to be furtherevaluated determinethe requiredstandard are to of containment, lt shouldbe understood etc. that only if a substance brought is within the scopeof the Code by satisfying of the minimumrequirements one above is it then appropriate apply the further criteriaas set out in 3 to to the requiredstandard containment, determine of etc.
products whereotherwise Except stated, that meetone or more of the criteria under each requirementwill be consideredfor the assignment that of requirement.
3.1 Shiptype
3.f.f '' Type .l
;'
with particularly Substances severetoxicity risks.(Products with toxicity riskstoo severefor type 2 ships and determinedon a for case-by-case basisto be appropriate type 1 ships.Substances determined be too toxic for type 1 shipsshouldbe prohibited to i n b u l ks h i p m e n t . ) Extremely reactive with water, producingtargequantities toxic of gasor aerosols (e.9.chlorosulphonic or corrosive acid).
.2
.3 Very severeflammability characteristics, i.e.: .3.1 .3.2 autoignition temperature below 65"C (ASTM D215t5-66; D I N s 1 7 9 a ) ;o r differencebetween the limits of flammability(expressed a as percentage volume in air) exceeds5O"/". by
3.1.2 Type2 .l .f .l .1,2 .1.3 Moderatelyto highlytoxic products(meetsone or more of the followingcriteria): LDso(oral,rats)equal to or lessthan 300 mslkg; LDso(dermal, rabbits) equalto or lessthan 600 mglke; g L C s o( 1 h o u r , r a t s )e q u a l t o o r l e s s t h a n 1 0 0 0 p p m , takin volatility into account; 193
IBC Code \ .2 Highly ieactivewith water, producingtoxic or corrosivegas or ( - a e r o s o l se . g .o l e u m ) . characteristics, i e.: .3 Severe flammability .3.1 .3.2 3.f.3 _
autoignitiontemperaturebelow 200'C (ASTM D2155-66; D I N s 1 7 9 4 ) ;o r s exceed 40"/o. difference betweenthe limitsof flammability
3.2
Tank type
: . .
.1 Extremely i.e. LCso(1 hour, rats) less than toxic by inhalation, s o 2 O Ap p m , w i t h a d j u s t m e n tu p w a r do r d o w n w a r dd e p e n d i n g n volatility. .2 Severely toxic by skin absorption LDso (dermal,rabbits)less than 2O0 mslke .3 Autoignitiontemperaturebelow 65"C (ASTM D2155-66; DrN sl 794). betweenthe limitsof flammability 4O%. .4 Difference exceeds
reactive with water producinglargequantities toxic .6 Extremely of gasor aerosols. or corrosive 3.2.2 lntegralgravity 2C
A l l o t h e rb u l k l i q u i d s .
3.3
3.3. I
Venting device
Controlled .l toxic by inhalation LCso(1 hour, rats)lessthan or Significantly into account. equalto 2000 ppm, takingvolatility
periodof time to over an extended .2 Intermittent exposure vapours is known to causemoderateto severeinjury. .3 Inhalation vapoursis known to causeallergic of sensitization. . 4 C a r g or e q u i r i n gn e r t i o n . i . 5 F l a s h p o i n tq u a lt o o r l e s st h a n 6 0 ' C ( c l o s e d u p ) . e c .6 Corrosive vapours. 194
Re/eva decisionsof the MSC and MEPC nt 3.3.2 Open All other bulk products.
3.4
Cauging device
,2 Intermittent periodof tim exposure vapours to over an extended is known to causesevereinjury. .3 Inhalationof vapours is known to cause allergicsensitizatior leadingto seriousor long-term effects.
r | | - . . ' l l .
[fiJI) i:,;il:',"y;'iliiJ
5 S e v e r e l yc o r r o s i v e v a p o u r s .
3.4.2 Restricted 1 Significantly moderatelytoxic by inhalation(acute) LCso to (1 hour, rats)lessthan or equal to 2000 ppm, but not lessthan 1 0 0 0 p p m , t a k i n gv o l a t i l i t yn t o a c c o u n t . i
'
3.5
3.5. 1
Tank environmentcontrol
lnert .l
::
.2 Autoignition te.mperature elow 200"C (ASTM Dt2155-66; b DrN s1 7e4). .3 Differencebetween the limits of flammability(expressed a as percentage volume in air) exceeds40"/", by
195
IBC Code 3.5.2 Dry situation. to with water vapour,leading a dangeroUs Productis reactive
3.6
)
(1 toxic by inhalation LCso hour,rats)lessthan or ec 3.6.1 Significantly ppm, takingvolatility into account. to 2000 : leac sensitization, 3.6.2 Inhatation vapoursis known to causealtergic of to seriousor long-termeffects 3.6.3 Intermittent exposureto vapoursover an extendedperiod of tim known to causemoderateto severeinjury.
3.7
3.7.1
Cargo-tankoverflow protection
HighJevelalarm anda tank overflow control system (free from manual intervention) .l Highly to severelytoxic products (meets one or more of the followingcriteria): LDso(oral,rats)lessthan 300 mglkg; LDso(dermal,rabbits)lessthan 600 melk1; LCso(1 hour, rats)lessthan 1000 ppm, taking volatilityinto account.
.2 Inhalationof vapours is known to cause allergicsensitization, leadingto seriousor long-termeffects. o t l . 3 H i g h l yc o r r o s i v ei q u i d s i,. e .l i q u i d s h a t c a u s ev i s i b l en e c r o s i s f the skintissueat the siteof contactwhen testedon the intactskin
:l,il"ritffil,i"i.,i.
.4 Autoignition temperaturebelow 200"C (ASTM D2155-66; DIN s1 7e4). as .5 Differencebetween the limits of flammability(expressed a percentage volume in air) exceeds 4O%. by 3.7.2 HighJevelalarms only .l toxic products(meetsone or more of the fotlowing Significantly criteria): LCso(1 hour, rats) less than or equal to 2000 ppm, taking into account; volatility
.1.1
Re/eva decisions of the MSC and MEPC nt .1.3 LDso(dermal, rabbits) Iessthan or equal to 12OOmelke
.2 Inhalation vapoursis known to causeallergic of sensitization. .3 Corrosive liquids, liquids i.e. that causevisible necrosis the skin of tissueat the site of contactwhen testedon the intactskin of an animalfor a periodof between3 and 60 minutes.
'
. 4 F t a s h p o i n tq u a lt o o r l e s st h a n 6 0 " C ( c l o s e d u p ) . e c
3.8
3.8.f
Toxic products
Exhaust openings tank ventsystems oi .1 LCuo(1 hour, rats) less than 1000 ppm, taking volatitityinto rccou nt.
.2 Intermittent periodof time exposure vapours to over an extended is known to causemoderateto severeinjury. , .3 Inhalation vapoursis known to causeallergic of sensitization. 3.8.2 Stowage,piping and venting .l (1 LCso hour,rats)lessthanor equalto 2000 ppm, takingvolatility into account.
.2 LDso(oral,rats)lessthan or equal to 300 mglk1. .3 LDso(dermat, rabbits) lessthan or equal to 600 me/ke.
3.9
3.9.f
Pump-rooms
pump-room ventilation lncreased .1 Highlyto severely toxic by inhalation, LCso(1 hour, rats)less i.e. into account. r than or equal to 1000 ppm, takingvolatility periodof time .2 Intermittent exposure vapours to over an extended is known to causemoderateto severeinjury. .3 Inhalation vapoursis known to causeallergic of sensitization. .4 Corrosiveor severely irritating vapours.
197
IBC Code
the Substances, marinepollution hazardsof which have been evaluatedby h c C E S A M P a n df o u n dt o m e e to n e o r m o r eo f t h e f o l l o w i n g a t e g o r i e s , o u l d * and be includedin chapter 17 of the IBC Code hazardous be considered ( c h a p t e V l o f t h e B u l kC h e m i c aC o d e ) : r l with attendantrisk to aquatic life or human .1 bioaccumutated "T" in ( t t t o h e a l t h r l i a b l e o c a u s e a i n t i n go t h e s e a f o o d " * " , t t Z " o r column A of the CESAMPhazardprofile); "4" t l . 2 t o x i ct o a q u a t i c i f e- 9 6 h T L - l e s s h a n 1 0 0 m g l l ( " 2 " , t t 3 "o r i n c o l u m nB ) ; life to non-toxic aquatic - 96h TL- lessthan 1000 mgll .3 practically s t ( t t 1 "i n c o l u m nB ) w h e n t h e s u b s t a n cp r e s e n t h a z a r d so h u m a n e mammal)Iessthan 500 melkg ("2" in LDso(laboratory health o o e c o l u m n C ) a n d i s m o d e r a t e l y b j e c t i o n a b l b e c a u s e f s m e l lo r ("XX" in column E). poisonous irritantcharacteristics or i: ..
of from the evaluation its highercriteria has Unless substance beenassigned a undereach that substances meet one or more of the criteria safetyhazards, o f r e q u i r e m e nw i l l b e c o n s i d e r e do r t h e a s s i g n m e n tf t h a t r e q u i r e m e n t . t
CESAMP is the IMO/FAO/UNESCO-IOCIWMOIWHO/IAEAIUN/UNEP Joint Group of The rationalefor the hazard evaluationis Aspectsof Marine Pollution. on Experts the Scientific c o n t a i n e di n C E S A M P R e p o r t sa n d S t u d i e sN o . 1 7 ( 1 9 8 2 ) .
198
5.1
5.f.f
Ship type
T y p eI .l which are bioaccumulated a significant Substances to extentand are known to produce a hazardto aquaticlife or human health ("+" in column A of the CESAM?hazardprofile)and which are (tt4" in column B); or highlytoxic to livingresources
.2 Substances which are bioaccumulated a significant to extentand are known to produce a hazardto aquaticlife or human health ("+" in column A) and which causeseverereductionof amenities ( " X X X "i n c o l u m n E ) ;o r . .3 Substances which are liableto causetaintingof seafood(ttT" in olumn A) and which are Qghly toxic to livingresources 4" in (" c o l u m nB ) . 5.1.2 Type 2 rl Substances which are bioaccumulated a significant to extentand are known to producea hazardto aquaticlife or human health' ("+" in column A) exceptthosein type 1 above;or
.2 Substances which are bioaccumulatedwith attendant risk to aquaticorganisms humanhealth, or howeverwith shortretention of the order of one week or less("2" in columnA) and which are highly or moderatelytoxic to living resources ("4" or tt3" in .r :::::l';hich are bioaccumurated with a*endanr risk to aquaticorganisms human health,but with short retentionof or t h e o r d e ro f o n e w e e k o r l e s s( " Z " i n c o l u m nA ) a n d w h i c h c a u s e ("XXX" in column E). severereductionof amenities
.4 Substances which are liableto causetaintingof seafood("T" in olumn A)* exceptthose in type 1 above;or .5 Substances which are highly toxic to living resources 4" in (tt c o l u m nB ) ;o r .6 Substances which are moderatefy ("3" in toxic to livingresources
ff:ff]liowhichcauseSeVerereductionofamenities(,,xxx
5.f .3 Type 3
All substances which do not fall underthe criteria shiptypes1 and 2 above for but which have been allocatedwith pollution categories B and C in A, accordance with appendixI to Annex ll of MARPOL73/78.
* See footnote to the table in the note (page 200).
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IBC Code
5.2
5.2.1
Cargo-tankoverflow protection
alarm anda tank overflow control system HighJevel for as identified appropriate type 1 ships. .1 Substances
5.2,2
Shiptype
B i o a c c u m ul a t i o n and tainting A
Damageto l i v i n gr e s o u r c e s B 4
+ + T* + Z Z Z T*
XXX
o o
3
XXX
c a A I I o t h e rs u b s t a n c efs l l i n gu n d e rp o l l u t i o n a t e g o r i e s A, B andC.
with strong tainting properties as identified by the Sub-Committeeon Bulk Chemicals at its T*: Substances These are as follows: thirteenth and later sessions. Camphor oil :' Ethyl acrylate Creosote (wood tar) Naphthalene (mi xe d i so me rs) Cre so l s a/pha-Methylnaphthalene Carbolic oil Naphthenic acids Di ch l o ro e th yle th e r
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Guidelines the uniformapplication for of the survival requirements the Bulk of ChemicalCode and the Gas carrier Code
(Approvedby theMSCat its forty-secondsessionr, l9B0*) Preamble The followingshouldbe considered guidelines the purposeof uniform as for a p p l i c a t i o n f t h e s u r v i v a r e q u i r e m e n to f t h e B u l k C h e m i c a l o d e I B C H o l s C Code] and the Cas CarrierCode. Alternativemethods to the suggested programme calculations ptesgntation specific of and which demonstrate, to the Administration's satisfaction, compliancewith the applicablesurvival criteria may be accepted
l.l T h e p a r c e l t a n k e rw i l l r e q u i r ea c o m p l e t ea n a l y s i s f t h e f i m i t i n g o survivaf characteristics the full rangeo f i n t e n d e d o a d i n g o n d i t i o n sa s over l ( c detailedn 2). i 1.2 The dedicatedservicetanker will require approvalof calculations b a s e d n s e r v i c e o n d i t i o n s r o p o s e d y t h e b u i l d e r r o w n e r ,i n w h i c hc a s e o p c b o the certificate fitnessshould be endorsedin respectof the conditions of accepted. 1.3 The inherentty safe ship is one that will meet survival requirements w i t h t h e s h i p a s s u m e dt o b e a t a m a x i m u m d r a u g h t a n d t r i m , w i t h a l l compartments within the extentof damageassumed be empty and with to maximumverticalcentreof gravity(adjusted free liquids) for
Minimum requiredmetacentric height (GM) or maximum allowableheight of the centre of gravity (KC) as a function of the draught of the parcel tanker
2.1 , A systematic investigation damage-survival of characteristics should b e u n d e r t a k e n y m a k i n gc a l c u l a t i o nts o b t a i nt h e m i n i m u mr e q u i r e d M b o C o r m a x i m u ma l l o w a b l eK C a t a s u f f i c i e n n u m b e r o f d r a u g h t s i t h i n t h e t w o p e r a t i n g a n g et o p e r m i tt h e c o n s t r u c t i o o f a s e r i e s f c u r v e s f " r e q u i r e d r n o o C M " o r " a l l o w a b l e C " i n r e l a t i o no d r a u g h t n d c a r g o - t a nc o n t e n ti n w a y K t a k o f t h e d a m a g e . T h ec u r v e sm u s t b e s u f f i c i e n t l c o m p r e h e n s i v t o c o v e r y e o p e r a t i o n atlr i m r e q u i r e m e n t s .
* These guidelines were originallyissuedas annex 2 of STABXXIV/I 2 and later part of MSC/ Circ.406/Rev.1.
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IBC Code Each of the curves thus constructedrelatesto one position of 2.2 should be repeatedfor each assumeddamage only and the calculations at extentof damageto be assumed any part of the ship. damageand lesser that the effect of certain Where it can be determinedby inspection 2.3 f t o w d a s s u m e d a m a g e i l l b e l e s s n e r o u s h a no t h e ra s s u m e d a m a g e o r w h i c h of then the investigation such are calculations providedand curvesprepared, w be dispensed ith. m d a m a g ec a s e s a y 2.4 shouldtake accountof: The damagecalculations .l damagefilled with liquid at incretanks in way of the assumed betweenempty and the maximumweightof mentsof about 25"/o r i l i q u i d ,o r l i q u i d s , n t e n d e dt o b e c a r r i e di n t h e p a r t i c u l a t a n k s un d e r c o n s i d e r a t i o n ;
\ which tanks)concerned in of .2 the distribution liquids the adjacent trim; intoaccount taking result, will givethe mostsevere
. 3 a n u m b e r o f d r a u g h t so v e r t h e o p e r a t i n gr a n g e , u p t o a n d includingthe Tropical FreeboardMark. The fresh water freeboardsneed not be considered; spaceand adjacent the .4 the effectof damageinvolving machinery a o l t a n k sc o n t a i n i n gi q u i d s v e r a n u m b e ro f d r a u g h t s s i n 2 . 4 . 3 ; whichever condition, or .5 the shipin eitherthe departure the arrival will give the most severeresult; : number of trims covering .6 the ship without trim and a sufficient i r t h e o p e r a t i n g a n g e , n o r d e r t o p e r m i ti n t e r p o l a t i o n .
concerningsurvivalcapabilitycalculations Particulars
t a sh T h e c a l c u t a t i o n s o u l db e b a s e do n m o u t d e dt i n e s n d i n c t u d e a r g e 3.f skegsand bow thrusters. such as shaftbosses, appendages heights(CM), stabilitylevers(CZ) and centre of The metacentric 3.2 gravity positions(KC) for judging the final survivalconditionsshould be (lost-buoyancy) method. by calculated the constant-displacement 3.3 T h e c a l c u l a t i o ns h o u t db e d o n e f o r t h e s h i pf r e e l yt r i m m i n g . s
should to acceptable the Administration Only computercalculations 3.4 be used. the damagecauses shipto trim by the stern,the Where the assumed 3.5 allowable to ship in the intactconditionshouldbe assumed havethe largest requirements. with operational trim by the stern,consistent the damagecauses ship to trim by the bow, the Where the assumed 3.6 allowable to ship in the intactconditionshouldbe assumed havethe largest requirements. with operational trim by the bow, consistent 2A2
Re/eva decisions of the hlSC a'iid MEPC nt 3.7 Lesser extent of damageshould be taken into accountonly where i n d i c a t e d y t h e p r e s e n c e f s u b d i v i s i oe x t e n d i n gn t o t h e m a x i m u m x t e n t o n b i e of dam?ge, e.g.double-bottom tanks, sideballast tanks, sidecargotanks, fuel tanksand void spaces. However,the followingshouldbe givenattention: .l lesser extent means the reduction of any'one of the three maximum dimensions damagesingfyor in combinationand of afso the assessment the effect of damage affecting any of w c o m b i n a t i o no f c o m p a r t m e n t s i t hi n t h e m a x i m u m e x t e n t o f damage.
.2 Where any damage involvesthe releaseof very heavy cargo liquid,then heel to the intactside of the ship may take place.In such casesthe effect of lesserverticalextent of damage above the level of the tank top may resultin the largerangle of heel, sinceotherwisethe effectof cargo loss may be compensated by flood water enteringthe double-bottom tanks on the damaged side. 3.8 The numl:er of calculations required to show compliance with survivalrequirements should be that necessary obtain sufficient to data for t h e l o a d i n gm a n L r a l n d s h o u l db e s u c ht h a t a l l l o a d i n g o n d i t i o n sn d i c a t e d a i c in paragraph1 can be covered,i.e. no additionalcalculations should be necessary once the series calculations been executed. of has 3.9 to trim and the vertical Calculations determinethe displacement, positionof the centreof gravityshouldbe performedfor each operational loadingcondition.The verticalpositionof the centre of gravityshould be graphs correctedfor free surface effects. One r1ethodwould be to construct moments the\iterion anglefor all filtingtevels showingthe free surface of at a specificgravityof one. The free surfacemomentsfor all tankscan then be gravity. takenfrom the graphsand be multiplied the cargo specific by 3.10 In calculating effectof free surface consumable the of liquidsit is to pair or a that, for each type of liquid,at leastone transverse be assumed single centrelinetank has maximurn free surface,and the tank or combinationof tanks to be taken into account is to be that where the is in effectof free surfaces the greatest; each tank the centreof gravityof the contentsis to be taken at the centreof volume of the tank.The remaining filled,and tanksare to be assumed eithercompletely empty or completely liquidsamongthesetanksis to be suchas to of the distribution consumable possible height above the keel for the centre of gravity. obtain the greatest within cargo compart3.lf To take accountof the presence structure of ments,a permeability 0.95 should be assumed statedin the Codes. of as Where, in particularcases,such as the cargo tanks of gas carriers, this in volume,it is would leadto a significant discrepancy cargo-tank assumption preferableto calculatethe permeability taking into account actual tank shouldthen be calculated separately structure; volumeof tank insulation the p y a n d a n a p p r o p r i a t e e r m e a b i l i ta p p l i e d .
243
IBC Code flooding of 3.12 Attentionshould be paid to the possibility progressive pipesif these ventilation throughdeck cargo pipesand common cargo-tank o a r e i m m e r s e da t l a r g e a n g l e so f h e e l a f t e r d a m a g e . T h e p o s s i b i l i t y f t p r o g r e s s i v f l o o d i n gt h r o u g h b a l l a s tp i p i n g p a s s i n g h r o u g h t h e a s s u m e d e valvesare not fitted to the ballast extent of dam dge,where positive-action system at the open ends of the pipes in the tanks served,should be are fitted to ballastvalvesand Where remote control systems considered. extentof damd1e then the effectof passthroughthe assumed thesecontrols , would that the valves to shouldbe considered ensure damageto the system r e m a i nc l o s e di n t h a t e v e n t . bottom 3.13 Where the ship is required to be capable of sustaining damageanywherein its length (t), the following method should be used f t w h e n d a m a g ei s a s s u m e d o o c c u r i n t h e v i c i n i t yo f t h e 0 . 3 1 p o s i t i o n r o m t h e f o r w a r dp e r p e n d i c u l a r : I W h e n a p p l y i n g t h e l o n g i t u d i n a le x t e n t o f b o t t o m d a m a g e applicableto the foremost part of the ship, no part of the damage should be assumedto extend abaft the 0.3t position from the forward perpendicular.
Re/eva decisions of the MSC and MEPC nt 3.18 Where dry cargoes carried the sametime as bulk liquidcargoes are at w h i c h r e q u i r ec o m p l i a n c e i t h t h e r e q u i r e m e n t o f t h e C o d e s t h e n t h e w s permeability the spacecarryingthe d ry cargois to be ascertained of 3 . 1 9 T h e h a r m o n i z e de g u l a t i o ns p e c i f y h a t n o a c c o u n ts h o u l db e t a k e n r s t of cross-flooding arrangements attainstipulated to limitsof heel in the final stateof equilibrium afterdamage. However,compartments the opposite on sideof a ship could be regarded singlecompartments as from the aspectof floodingif they were to be linkedby openings ducts of sufficiently or large area.In suchcases consideration shouldbe givento the adequacy tank air of flow and to the effect of free surface.
4.1 With regardto loadingconditions be submittedto the Administo e t r a t i o n( e x c l u s i vo f t h e l o a d i n g o n d i t i o n o n t a i n e dn l o a d i n g n d s t a b i l i t y c i c a manual), principal the objective, the stageof designevaluation, that the at is presented cover all Administration satisfy can itselfthat the calculations will c o n d i t i o n o f f u l l a n d p a r t i a l o a d i n gi,n c l u d i n g a r i a t i o no f d r a u g h t n d t r i m . s v s a To achievethis objectivethe Administration may either:
I
.1 requirea compteteanalysis survival requirements of over the full r a n g eo f p r o b a b l e o a d i n gc o n d i t i o n so r l ; proposed .2 undertake approvalon the basisof serviceconditions by the builderor owner, in which casethe Certificate Fitness of for shouldbe endorsed the conditions accepted. 4.2 Particutar attention shoutd be paid to the provisionof adequate stability data to enablethe masterto take into accountaccurately effect the of liquid heeling moments of the contents of undamagedtanks.These heeling moments vary with the specific gravity of the liquid and the percentage fillingof the tanks and may changesignificantly magnitude in from conditionto condition.Adequateinformationwould include curves showingthe variationof liquid heelingmoment with the contentsof each i n d i v i d u atla n k . / 4.3 in{information required under intact ln addition to the usuat toad stabilityrequirements,h e m a s t e rs h o u l d b e s u p p l i e dw i t h t h e f o l l o w i n g t pertaining damagestability: , information to .l data relativeto loading and distributionof cargo and ballast necessary ensure compliancewith damage-survival to requirem ents;
.2 data relative the ship'ssurvivat to capabilities; .3 a damage-control drawing showing the position of important fittingsand listinginstructions their control; for .4 data relating to the effect of free surface or liquid heeting momentsof cargotanksat all stages filling; of
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IBC Code .5 example calculationsand standard blank forms to facilitate l c a l c ua t i o n s , 4.4 of The followingshoutdbe statedon the Certificate Fitness: .1 the deepest draught or least freeboard for those loading which requiregreaterfreeboardthan the International conditions Load Line Certificate(1966); . .2 the range of specificgravitiesof cargoeswhich may be carried; this relatesto all cargoes; .3 the particularcargo tanks in which certain ranges of specific gravitiesof cargoesmay be carried,if relevant; ." : for valvesetc., the control of which is essential .4 detailsof fittings, survival, together with instructionsfor control, operation and loggingand ; of .5 identification requiredloadingand stabilitymanual.
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for testing standards the desigtr, "Revised to and locatingof devices preventthe passage flame into cargotanks in tankers of
(adoptedby theMSCat its ion, 1g84, forty-ninth sess and 1988") amended at its fifty-fifthsession,
f C o T h e 1 9 8 1 a n d t h e 1 9 8 3a m e n d m e n tts t h e I n t e r n a t i o n a l o n v e n t i o no r t h e for Safetyof Lifeat Sea,1974 (SOLAS74),includerevisedrequirements fire safety measuresfor tankers. RegulationU-2159of these amendments gas-freeing ventilation. purging, and provisions ventinB, concerning contains ll-2159.1 states: .5 Regulation "The ventingsystem with devices prevent the to shallbe provided passage flame into the cargo tanks.The design,testingand of locatingof these devicesshall comply with the requirements
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IBC Code 1.2.4 Devices shall be tested and located in accordancewith these ndards. Sta 1.2.5 Devices are installed protect: to .l o p e n i n g sd e s i g n e dt o r e l i e v ep r e s s u r e r v a c u u m c a u s e d b y o s l 2 t h e r m a lv a r i a t i o n ( r e g u l a t i o nl - 2 1 5 9 ..1 . 1 ) ;
. 2 o p e n i n g s e s i g n e d o r e l i e v ep r e s s u r e r v a c u u m d u r i n g c a r g o d t o r o l o a d i n gb a l l a s t i no r d u r i n gd i s c h a r g i n(g e g u l a t in 1 1 2 1 5 9..2 . 2 ) ; , g 1 .3 outlets designedfor gas-freeing describedin the proposed as (a r e g u l a t i o nl - 2 1 5 9 . 2 . 2 . 3 p p e n d i x ) . l 1 1.2.6 Devicesshall not be capableof being bypassed blocked open or u n l e s s t h e y a r e t e s t e d i n t h e b y p a s s e do r b l o c k e d - o p e np o s i t i o n i n with section3. accordance 1.2.7 TheseStandards not includeconsideration sources ignition do of of since insufficient informationis availableto such as lighting discharges f o r m u l a t ee q u i p m e n tr e c o m m e n d a t i o n s .l l c a r g o - h a n d l i n ga n k - c l e a n i n g A t, b d a n d b a l l a s t i no p e r a t i o n s h a l l e s u s p e n d e o n t h e a p p r o a c h f a n e l e c t r i c a l g o storm 1.2.8 TheseStandards not intendedto deal with the possibility the are of passage flame from one cargo tank to anotheron tankers with common of ventingsystems.
g
1.2.9 When outlet openingsof gas-freeing systems tankersnot fitted on with inert gas systems requiredto be protectedwith devices, are they shall comply with these Standards except that the tests specifiedin 3.2.3 and 3.3.3.2 renot required. a 1.2.10Certainof the testsprescribed section3 of these Standards in are potentially hazardous, no attemptis made in this circularto specifysafety but requirements thesetests. for
1.3
Definitions
For the purposeof theseStandards, followingdefinitions applicable. the are ' | .3. I Flame arrester a device to prevent the passageof flame in is accordancewith a specified performancestandard. lts flame-arresting e l e m e n ti s b a s e do n t h e p r i n c i p l e f q u e n c h i n g . o ' 1.3.2 Flame wire meshto preventthe passage screenis a deviceutilizing of performance flames,in accordance with a specified unconfined standard. 1.3.3 Flamespeed the speedat which a flamepropagates is alonga pipe or other system f .3.4 208 is Flashback the transmission a hrre througha device. of
Re/eva decisions of the MSC and MEPC nt ,. , 1.3.5 High-velocityvent is a device to prevent the passageo v a t c o n s i s t i no f a m e c h a n i c a la l v ew h i c h a d j u s t sh e o p e n i n g v a i l a b l e g w a i n a c c o r d a n c e i t h t h e p r e s s u r e t t h e i n l e to f t h e v a l v ei n s u c ha ' r the effluxvelocitycannotbe lessthan 30 mls. valve*is a devicedesigned maintainpresl to 1.3.6 Pressure/vacuum v a c u u mi n a c l o s e dc o n t a i n e w i t h i n p r e s e tl i m i t s . r
4;
,-
2 2.1
STANDARDS
l - v r l l l - t \ t
Principles
2.1.1 Dependingon their serviceand location,devicesare req protectagainst the propagation of: .l ; m o v i n gf l a m e s a n d / o r
gases; flamesfrom pre-mixed .2 stationary from any cause. after ignitionof gasesresulting , 2 . 1 . 2 W h e n f l a m m a b l eg a s e sf r o m o u t l e t s i g n i t e , t h e f o l l o w i n g f o u may occur: situations .l At low gasvelocities, flame may: the .1 .2 flashback;or lize itsetfas if the outlet were a burner. stabi
.2 At high velocities, flame mav: the .1 .2 burn at a distanceabove the outlet; or be blown out.
of 2.1.3 In order to preventthe passage flame into a cargo tank, device one or more of the followingfunctions: must be capableof performing .l / permittingthe gas to passthrough passages without flashbacl on sidewhen thr and without ignitionof the gases the protected period; to deviceis subjected heatingfor a specified
of .2 maintaining efftuxvelocityin excess the flamespeedfor thr an goS, of irrespective the geometric of configuration the deviceanr without the ignition of gaseson the protectedside when the device is subjectedto heatingfor a specifiedperiod;and of .3 preventing influxof flame when conditions vacuum occu an within the cargo tanks.
* Pressure/Vacuumvalves are devices to prevent the passageof flame when designed and tested in accordancewith these Standards.
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IBC Code
2.2
Mechanicaldesignstandards
as resistance the pipe to which th, heat resistance corrosion and strength, are attached. . and remo\ shallallow for easeof inspection 2.2.2 The designof devices or cleaning repair. for of internalelements replacement, true and shallprovir 2.2.3 All flat joints of the hosingshallbe machined metal-to-metal contact. for a joint havingan adequate : 2.2.4 Flame-arrester elementsshallfit in the housingin such a way th f l a m ec a n n o tp a s sb e t w e e nt h e e l e m e n ta n d t h e h o u s i n g . shallbe at least1.5 timestl 2.2.5 The clearareathroughflame arresters area cross-sectional of the vent line. o s m 2 . 2 . 6 R e s i l i e n te a t s a y b e i n s t a l t e d n l y i f t h e i rd e s i g ni s s u c ht h a t ,i f t ' sealsare partiallyor completelydamaged or burned, the device is s preventing passage flame. of the capableof effectively 2.2.7 Devices shall allow for efficient drainage of moisture witho of to impairing their efficiency preventthe passage flame. shall be capable 2.2.8 The casingand element and gasketmaterials e a t w i t h s t a n d i ntg e h i g h e s p r e s s u r e n d t e m p e r a t u r t o w h i c h t h e d e v i c em h fire be exposedunder both normaland specified test conditions. devices shatl be so constructedas to direct the effl 2.2.g End-of-tine vertically upwards. ' , o to 2 . 2 . 1 0 F a s t e n i n g ss s e n t i a t t h e o p e r a t i o n f t h e d e v i c e( i . e . s c r e w s t e loosening. shallbe protectedagainst 2.2.11 Meansshallbe providedto check that any vatvelifts easilywithc r e m a i n i n gn t h e o p e n p o s i t i t i o n . i effect is achievedby the val 2.2.12 Devicesin which the flame-arresting (e elements functionand which are not equippedwith the flame-arrester valves) must havea width of the contactareaof the valvese high-velocity of at least5 mm w i s 2 . 2 . 1 3 D e v i c e s h a l tb e r e s i s t a ntto c o r r o s i o nn a c c o r d a n c e i t h 3 . 5 . 1 . gasketsand sealsshall be of materialresistant bc to 2.2.14 Elements, carried eawaterand the cargoes 2.2.15The casing or housing shall be capable of passinga hydrosta p r e s s u r ee s t ,a s r e q u i r e d n 3 . 5 . 2 . i t 2.2.16 In-line devices shall be able to withstand,without damage permanentdeformation,the internal pressureresultingfrom detonati, with section3.4. when testedin accordance 210
Re/eva decisions the MSC and MEPC nt of 2 . 2 . 1 7A f l a m e - a r r e s t e lre m e n ts h a l lb e d e s i g n e do e n s u r eq u a l i t yc o n t r o l t of of manufactureto meet the characteristics the prototype tested, in with theseStandards. accordance
2.3
Performancestandards
with 3.5 and thereafter shown 2.3.1 Devices shallbe testedin accordance s t o m e e t t h e t e s t r e q u i r e m e n to f 3 . 2 t o 3 . 4 , a s a p p r o p r i a t e . such as flow ratesunder both positive 2.3.2 Performance characteristics, flow resistance operatingsensitivity, and velocity, and negativepressure, tests. shallbe demonstrated appropriate by to 2.3.3 Devices shallbe designed and constructed mi,{irize the effectof In f o u l i n gu n d e rn o r m a lo p e r a t i n g o n d i t i o n s . s t r u c t i o n sn h o w t o d e t e r m i n e c o f w h e n c l e a n i n gs r e q u i r e d n d t h e m e t h o do f c l e a n i n g h a l lb e p r o v i d e d o r i a s m s e a c h d e v i c ei n t h e m a n u f a c t u r e r i' n s t r u c t i o n a n u a l . 2.3.4 Devicesshatlbe capableof operatingin freezingconditions and, if so any device is provided with heating arrangements that its surface o t e m p e r a t u r e x c e e d s 5 " C , t h e n i t s h a l lb e t e s t e da t t h e h i g h e s t p e r a t i n g 8 t e m p e r a tr e . u v g s l b u 2 . 3 . 5 D e v i c e s a s e d p o n m a i n t a i n i na m i n i m u m e l o c i t y h a t b e c a p a b l e i o f o p e n i n gi n s u c ha w a y t h a t a v e l o c i t yo f 3 0 m l s i s i m m e d i a t e l yn i t i a t e d , m a i n t a i n i n a n e f f l u xv e l o c i t y f a t l e a s t3 0 m l s a t a l l f l o w r a t e sa n d ,w h e n g o , t h e g a s f l o w i s i n t e r r u p t e db e c a p a b l eo f c l o s i n gi n s u c h a w a y t h a t t h i s m i n i m u mv e l o c i t yi s m a i n t a i n e d n t i l t h e v a l v ei s f u l l y c l o s e d u 2.4 Flamescreens
f s .2 s e c u r e l yi t t e di n o p e n i n g s o t h a t f l a m e sc a n n o tc i r c u m v e ntth e s c r e e na n d ; s e .3 a b l et o m e e tt h e r e q u i r e m e n to f t h e s eS t a n d a r d s ,x c e p t h a tt h e i t e s ts p e c i f i e dn 3 . 2 . 3n e e d n o t b e c o m p l i e dw i t h .
2.5
.2 g a se v o l u t i o n ;
SCANNED BY KIVAN ( MKP ) 2004
211
IBC Code .3 pressure loss acrossdevices, taking into accountthe resistance coefficient;
.5 pressure which the vent opensif a high-velocity at valveis used; and .6 densityof the saturated vapourf airmixture. 2.5.2 Devicesshallbe locatedat the outletsto atmosphere unlesstested and approvedfor in-lineinstallation. Devicesfor in-lineinstallation may not be fitted at the outletsto atmosphere unless they havealsobeen testedand approvedfor that position. 2.5.3 Except may be permittedin 1.2.2,flame screens as referred in 2.4 to shallbe fittedonly at vacuuminlets throughwhich vapours cannotbe vented t o a t m o s p h e r e .F l a m e s c r e e n ss h a l l b e p r o t e c t e d a g a i n s t m e c h a n i c a l damage. 2.5.4 Where end-of-line are fitted with cowls,weatherhoods and devices deflectors, etc., theseattachments shallbe fitted for the testsdescribed in 3.2. rrestersare installed, in-linedevices as ventingto atmosphere, they shouldbe locatedat a sufficient from distance y t h e o p e n e n d o f t h e p i p e l i n e o a s t o p r e c l u d e h e p o s s i b i l i to f a s t a t i o n a r y s t flame resting the arrester. on 2.5.6 When ventingto atmosphere not performed is throughan end-of-line d e v i c ea c c o r d i n go 2 . 5 . 4 ,o r a d e t o n a t i o nl a m ea r r e s t ea c c o r d i n go 2 . 5 . 5 , f t r t t h e i n - l i n e e v i c eh a st o b e s p e c i f i c a l lty s t e dw i t h t h e i n c l u s i o n f a l l p i p e s , d e o tees, bends,cowls, weather hoods, etc., which may be fitted between the d e v i c ea n d a t m o s p h e r e .h e t e s t i n g h a l l o n s i so f t h e f l a s h b a c t e s to f 3 . 2 . 2 T s c t k and, if for the giveninstallation is possible a stationary it for flameto reston t h e d e v i c e t h e t e s t i n g h a l la l s oi n c l u d e h e e n d u r a n c e u r n i n g e s to f 3 . 2 . 3 . , s t b t 2.5.7 Means shall be provided to enable personnelto reach devices situatedmore than 2 m above deck to facilitatemaintenance, repair and inspection.
3 . 1 . 1 T e s t s s h a l l b e c o n d u c t e d b y a l a b o r a t o r y a c c e p t a b l et o t h e Administration. 3.1.2 Onty one device shallbe submittedfor each type test programme. Such a deviceshallhave the same dimensions nd most unfavourable a clearances expectedin the productionmodel. 212
Re/eva decisions the MSC and MEPC nt of 3.1.3 Testsdescribed this sectionusinggasoline in vapours(a non-leaded p e t r o l e u m d i s t i l l a t e o n s i s t i n g s s e n t i a l l y f a l p h a t i ch y d r o c a r b o nc o m c e o p o u n d sw i t h a b o i l i n gr a n g ea p p r o x i m a t i n 6 5 " C 1 7 5 " C )t,e c h n i c a h e x a n e g l propane, appropriate, referred in thissection, vapours, technical or as and to a r e s u i t a b l e f o r a l l d e v i c e s p r o t e c t i n g t a n k s c o n t a i n i n ga f l a m m a b l e atmosphere the cargoesreferredto in 1.2.1 This does not precludethe of . vapoursor technical use of gasoline hexanevapoursfor all testsreferred to i n t h i ss e c t i o n .
3.2
p 3 . 2 . 1 T h e t e s t r i g s h a l l c o n s i s to f a n a p p a r a t u s r o d u c i n ga n e x p l o s i v e mixture,a small tank with a diaphragm, flangedprototypeof the flame a ( a r r e s t e ra p l a s t i c u g * a n d a f i r i n gs o u r c ei n t h r e e p o s i t i o n s s e ea p p e n d i x , b 2)J Other testrigsmay be used,providedthe testsreferred in thissection to areachievedtothesatisfactionoftheAdministration. 3.2.2 A flashback test shatlbe carriedout as follows .l The tank,flame arrester assembly and the plasticbag enveloping the prototypeflame arrestershall be filled so that this volume
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testingof the gas composition the plasticbag.Where devices in alongthe axisof the bag,one closeto the flamearrester, another as far away as possible therefroffi, and the third at the midpoint b e t w e e n t h e s e t w o . T h e s e t h r e e s o u r c e ss h a l l b e f i r e d i n succession, duringeach of the three tests. one .2 lf a flashback occurs,the tank diaphragm will burst and this will b e a u d i b l e n dv i s i b l e o t h e o p e r a t o r y t h e e m i s s i o n f a f l a m e . a t b o Flame, heatand pressure sensors may be usedas an alternative to d a bursting iaphragm
3.2.3 An enduranceburningtest shall be carriedout, in additionto the flashback test,for flamearresters outletswhere flows of explosive at vapour are foreseeable: .f The testrig as referred in 3.2.1may be used, to withoutthe plastic bag. The flame arrestershall be so installedthat the mixture i . e m i s s i o ns v e r t i c a l I n t h i s p o s i t i o n h e m i x t u r es h a l lb e i g n i t e d . t
. The dimensionsof the plasticbag are dependent on those of the flame arrester, but for the ffame arresters normally used on tankers,the plasticbag may have a circumferenceof 2 m, a l e n g t ho f 2 . 5 m a n d a w a l l t h i c k n e s s f 0 . 0 5 m . o t In order to prevent remnants of the plastic bag from falling back on to the device being tested after ignition of the fuellair mixture, it may be useful to mount a coarse wire frame acrossthe devicewithin the plasticbag.Thq frame should be so constructedas not to interfere with the test result. \ I Refer to IEC Publication79-1
213
IBC Code
Where devicesreferredto in 2.5.6 are tested,the flame arrester as shallbe so installed to reflectits final orientation. .2 Endurance burning shall be achievedby using the rnost easily ignitablegasolinevapourfair mixture or the most easilyignitable vapourfairmixturewith the aid of a pilot flameor hexane technical a spark igniter at the outlet. By varying the proportionsof the shallbe heated flammablemixtureand the flow rate,the arrester on temperature the cargotankside of until the highestobtainable may be temperature obtainable The is the arrester reached. highest considered to have been reached when the rate of rise of does not exceed0.5oCper minuteover a 10 minute temperature for period.This temperature shallbe maintained a period of 10 afterwhich the flow shallbe stoppedand the conditions minutes, the thermal stability, observed.If difficultyarisesin establishing has reached followingcriteriashallapply.When the temperature . the apparent maximum, using the most severe conditionsof at and flow rate,but increases a rate in excess flammablemixtures burning of 0.5"C per minuteover a 10 minuteperiod,endurance
Flashback shall observed. flow shallbe stoppedand the conditions not occur duringthis test.
3.3
3.3.1 The test rig shallbe capableof producingthe requiredvolume flow test rigsare shown.Other of 3 rat.ln appendices and 4, drawings suitable of test rigs may be used,providedthe testsare achievedto the satisfaction the Administration. vents 3.3.2 A flow condition test shall be carried out with high-velocity air using compressed or gas at agreed flow rates.The following shall be recorded: .l The flow rate.Where air or a gas other than vapours of cargoes with which the vent is to be usedis employedin the test,the flow ratesachievedshallbe correctedto reflectthe vapour densityof s u c hc a r g o e s . The pressure before the vent opens.The pressurein the test tank on which the deviceis locatedshallnot riseat a rate greaterthan 0.01 N/m mt lmtn. !
.2
214
nt Re/eva decisionsof the MSC and MEPC 3.3.3 The followingfire safetytestsshallbe conductedusinga mixtureof g a s o l i n e a p o u ra n d a i r o r t e c h n i c ah e x a n e a p o u ra n d a i r w h i c h p r o d u c e s l v v . s i m a t h e m o s te a s i l yg n i t a b l e i x t u r e t t h e p o i n to f i g n i t i o nT h i sm i x t u r e h a l lb e t a i g n i t e d i t h t h e a i d o f a p e r m a n e np i l o tf l a m eo r a s p a r ki g n i t e r t t h e o u t l e t : w .1 of in Flashback tests, which propanemay be usedinstead gasoline o r h e x a n e ,s h a l l b e c a r r i e do u t w i t h t h e v e n t i n t h e u p r i g h t p o s i t i o n n d t h e n i n c l i n e d t 1 0 ' f r o m t h e v e r t i c a lF o rs o m ev e n t . a a
w v s o f c o m b i n e d a l v e s h a l lb e t e s t e di n a c c o r d a n c e i t h 3 . 2 . 2w i t h t h e v a c u u m v a l v e m a i n t a i n e di n t h e o p e n p o s i t i o n f o r t h e
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the order test erriciencv device to orthe tJ,|;::.''
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.
in cJescribed 3 .2.3,shallbe carried .2 An end uranceburningtest,as d t o u t . F o l l o w i n gh i st e s t ,t h e m a i nf l a m es h a l lb e e x t i n g u i s h ea n d : d o t h e n ,w i t h t h e p i l o tf l a m eb u r n i n g r t h e s p a r ki g n i t e r i s c h a r g i n g , 'small q u a n t i t i e s f t h e m o s t e a s i l yi g n i t a b l e i x t u r es h a l l b e m o , f a l l o w e dt o e s c a p e o r a p e r i o do f 1 0 m i n u t e sd u r i n gw h i c h t i m e of flashback shallnot occur. For the purposes this test the soft sealsor seatsshallbe removed
3.4
for Test rig and test procedures detonation located in-line i flame arresters
' at shall be installed one end of a pipe of suitable 3.4.1 A flame arrester On lengthand of the samediameteras the flangeof the flame arrester. the The pipe shallbe filledwith exposedflange,a plasticbag. shallbe affixed. m t h e m o s t e a s i l yi g n i t a b l e i x t u r eo f p r o p a n ea n d a i r ,w h i c h s h a l lt h e n b e shallbe measured ignited. The velocityof the flame near the flame arrester and shallhave a value of that for stabledetonations. shall 3.4.2 Three detonationtests shall be conductedand no flashback shallbe damaged occur throughthe deviceand no part of the flamearrester j deformation or show permanent 3.4.3 Other test rigs may be used provided the testsare achievedto the A of satisfaction the Administration. drawing of the test rig is shown in 5 appendix .
3.5
Operationaltest procedures
tbst shallbe carriedout. ln this test i completedevice, 3.5.1 A corrosion to of including section the pipe to which it is fitted,shallbe exposed a 2A"/" a of chloridesolutionsprayat a temperature 25"C for a periodof 24O sodiunr An test hoursand allowedto dry for 48 hours. equivalent may be usedto the
Th" dl*""ti,rns shallbe at lpast4 m circumference,4 m length and a materialwall thickness of 0.05 mm. /
215
IBC Code Followingthis test, all movable parts shall satisfaction the Addrinistration. of which cannot be operateproperlyand there shallbe no corrosiondeposits washed off. p o o 3 . 5 . 2 A h y d r a u l i c r e s s u r ee s ts h a l lb e c a r r i e d u t i n t h e c a s i n g r h o u s i n g t w . i o f a s i m p l ed e v i c e , n a c c o r d a n c e i t h 2 . 2 . 1
4 4.1
fixed tag marked or have a permanently Eachdevice shallbe permanently , material, indicate: to made of stainless steelor other corrosion-resistant name or trade mark; .1 manufacturer's for designation the .2 styte,type, model or other manufacturer's device; .3 sizeof the outlet for which the device is approved;
i, . 4 a p p r o v e dl o c a t i o nf o r i n s t a l l a t i o n n c l u d i n gm a x i m u mo r m i n imum lengthof pipe, if any,betweenthe deviceand the atmosphere; .5 directionof flow throughthe device; of and report number;and .6 indication the test laboratory w s . 7 c o m p l i a n c e i t h t h e r e q u i r e m e n to f M S C / C i r c .3 7 3 / R e v . 1 .
4.2
Laboratoryreport
. L
.2 types of testsconducted.Where in-tinedevicesare tested,this p s t i n f o r m a t i o n h o u l di n c l u d e h e m a x i m u m r e s s u r ea n d v e l o c i t i e s s in observed the tesU .3 specific adviceon approvedattachments; .4 types of cargo for which the device is approved; : of .5 drawings the test rig; at vent, the pressures which the .6 in the case of a high-velocity deviceopensand closesin the effluxvelocity;and \ markedon the devicein 4.1. .7 all the information
I
216
4.3
Manufacturer's instructionmanual
4 . 3 . 1 T h e m a n u f a c t u r es h a l l s u p p l y a c o p y o f t h e i n s t r u c t i o n a n u a l , r m w h i c h s h a l lk e p t o n b o a r dt h e t a n k e ra n d w h i c h s h a l li n c l u d e : .l n i n s t a l l a t i oin s t r u c t i o n s ; :
. 2 o p e r a t i n gn s t r u c t i o n s ; i .3maintenancerequirements,inc|udingc|eaning(see2.3.3); .4 copy of the laboratoryreport referredto in 4.2; and , .5 flow test data,including flow ratesunder both positive and negflow resistance velocity. ativepressures, operating sensitivity, and
Appendix 1
Proposed amendments regulation to ll-2159 [seeNote belowl 2 Cargo tank purging andf gas-freeing* or
Arrangements purging andf gas-freeing for or shatlbe suchas to minimizethe hazards of vapoursin the atmosphere due to the dispersal flammable and to flammable mixtures a cargotank.Accordingly: in : .1 When the ship is providedwith an inert gas system, the cargo tanks shallfirst be purged in accordance with the provisions of
.2 When the shipis not provided with an inertgassystem, operathe t i o n s h a l l e s u c ht h a tt h e f l a m m a b l e a p o u ri s d i s c h a r g eid i t i a l l y : b v n .2.1 .2.2
When the flammable vapourconcentration the outlet has been reducedto at 30% of the lower flammable limit,gas-freeing thereafter continued may be at cargotank deck level.
* Refer to the Revisedstandardsfor the design, testing and locating of devices to prevent the passage flame into cargo tanks in tankers(MSClCirc.373lRev. 1) and to Revised of factorsto be taken into consideration when designingcargo tank venting and gas-freeing arrangements ( M S C / C u c . 4 5 O l R e v .1 ) . N o t e ; T h i s a m e n d e d t e x t w a s a d o p t e d b y r e s o l u t i o nM S C . 1 3 ( 5 7 )o n l l A p r i l 1 9 8 9 .
217
IBC Code
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IBC Code
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Appendix 5
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rate:the venting system should be .1 Maximum loading/discharge n t d e s i g n e d o t a k e i n t o c o n s i d e r a t i o t h e m a x i m u mp e r m i s s i b l e rate loadingldischarge for each cargo tank and in the caseof a Theseloading ffi, combinedventingsyste for each group of tanks. of ratesshouldalsobe usedfor the design the inert and discharge , g a ss y s t e mr e g u l a t i o nl - 2 1 6 2 . 3 . 1 . l , requires least25% to be at ll-2159.1.9.5 regulation .2 Casevolution.' addedto the maximumloadingrate to accountfor the increased volume dure to gas evolution from the cargo. A higher gas for evolutionfactor may be considered highlyvolatilecargoes. .3 lossacross data relatingto pressure devices: /oss Pressure across of , devices preventthe passage flame,approvedin accordance to ll-2159.1 are .5, to with MSC/Circ.373 and referred in regulation o . i t o b e c o n s i d e r e dn t h e d e s i g no f t h e v e n t i n gs y s t e m F o u l i n g f shouldbe taken into account. devices pressure of loss calculations /oss Pressure in the venting systemi includingpipes,valves,bends,fittings,etc., should be systems insidethe cargotanksdoes not made to ensurethat the pressure to taking thesetanksare designed withstand, exceedthe pressure w I an i n t oc o n s i d e r a t i o n . 2 d . 3 a b o v e . n t h e c a s e h e r ea c o m b i n e d with loadingof cargotanks ventingsystemis used in association generthe simultaneously, combined effect of vapour pressure s a t e d i n t h e t a n k sa n d v e n t i n gs y s t e m h o u l db e c o n s i d e r e d . of Pressure which the ventsopen:the initialopening pressure at i t s t h e v e n t v a l v e s h o u l db e c o n s i d e r e dn s e l e c t i n gh e a p p r o p r i a t e valvesfor the ventingsystem. Densityof the gaseousmixture:the maximum density of the gaseousmixtureslikely to be encounteredin the cargo tanks,
.4
.5
.6
222
of nt Re/eva decisions the MSC and MEPC havingregardto the types of cargo intendedto be carriedand is their temperature, to be considered. .'l Designto prevent liquid overfill:where overflow control systems is are fitted, consideration to be givento the dynamiccondition d u r i n gl o a d i n g . of Locationof vent outlets:horizontaland vertical distances the ll-2159. i with regulation vent outletsare to be in accordance Types of venting systems:due regard is to be given to cargo when consideringa venting system or inert gas segregation commonto more thanone tank.Where the inertgasmain system is designedfor venting of cargo tanks, additionalmeans for llwith regulation ventingof thesetanksare to be in accordance 2 1 6 21 1. 3 . .
.8 .9
'
f t; . 1 0 V e n t d r a i n i n g a r r a n g e m e n t s h e d r a i n i n g a r r a n g e m e n t so r with regulation in are ventingsystems to be designed accordance 4 l l - 2 1 5 9 ..1 . systemin conformitywith a in .11 Cas-freeing: designing gas-freeing ( p r o p o s e dr e g u l a t i o n l - 2 1 5 9 . 2 . 2 .a n d 5 9 . 2 . 2 . 3 s e e a n n e x * )i n l 2 the exit velocities, followingshould the required order to achieve be considered: .l of the flow characteristics the fansto be used;
.3
for of .4 the densities the cargovapourlairmixtures the rangeof to cargoes be carried. and renewalof the ventingsystemshould conform to the Repairs 3 are in Factors the above paragraphs to be taken originaldesignparameters. are when modifications carriedout to the ventingsystem. into consideration information The masteris to be providedwith a manualcontaining 4 ratesfor eachtank or group relating the maximumloadingand unloading to ds during the designof the ventingsystem, per paraof tanks established graph 1 above. l 3 4.3 ofMSC/Circ. 73lRev. shouldbe to Data referred in paragraph 5 when renewingdevicesreferredto in the above into consideration taken l c i r c ua r .
nre annex has not been included. lts text is identicalwith appendix 1 of MSC lCirc.373l Rev. 1 (see page 217).
223
"
Note: For the purpose of this illustration, a single tank encompassesthe entire beam of the ship)
: 9 m , 9 m x ' 1 4 . 5m _ 1 3 0 . 5 m 2
"l4.5 m
I I
"
This is bur"J on MSC/C| rc. 3'14.Paragraphnumbers have been altered from those of the BCH Code (for which the circularwas developed)to refer to appropriateparagraphs the of IBC Code.
224
Re/eva decisions of the MSC and MEPC nt Calculations I 11 . 3 . 5 11.3.5.1 D e t e r m i n a t i o o f f o a m s u p p l yr a t e : n t T h e l a r g e so f : the foam supplyrate basedupon the entirecargodeck area 2 tlm2lmin x 812 mu : 1,624 llmin 11.3.5.2 the foam supplyrate basedupon the horizontal sectional area of the singlelargest tank 2 0 t / m 2 l m i nx 1 3 0 . 5m ' : 2 , 6 1 At / m i n 11.3.5.3 the foam supply rate based upon the area protectedby the largest monitor x 1 0 t l m ' 1 m i n 1 3 0 . 5m ' : * 1 , 3 0 5 l l m i n (.Shall not be lessthan 1,250 llmin) 2,610llmin,which is the largest the three of Thefoam supplyrateis therefore rates. abovecalculated 2 Determination the requiredquantityof foam concentrate: of 2,610 llmin is the foam supplyratefrom regulation 3.14.5. This flow ratefor thirtyminutes will require min x 2,610 llmin = 30 lf 78,300litresof foam-watersolution. a 5"/"foam concentrate is used,then 5"h of the 78,300litresmustbe foam concentrate, o r 0 . 0 5x 7 8 , 3 0 0 : 3 , 9 1 5l i t r e s
11.3.6
3Determinationoftheminimummonitorcapacity: 11.3.7 Eachmonitormustsupplyat least: (a) 50% of the requiredfoam rate;or z (b) 10 tlm'l^in for the areait protects; or (c) 1,2s0 lf min, whichever greater is
5 s } % o f t h e f o a m s u p p l yr a t e: 2 , 6 1 0 l / - i n x 0 . 5 : 1 , 3 0 l l m i n 1Ollm'l^in timesthe areathe monitorprotects : 1 3 0 . 5m ' x l O l l m 2 l m i n : 1 , 3 0 5l l m i n is The minimummonitorcapacity therefore1,305 llmin. monitorspacing 15 metresbetweenmonitors. to wishesto increase Designer I requiredfoam supply: Recalculate '1 s a m ea s b e f o r e- , 6 2 4 l l m i n 11 . 3 . 5 . 1 1 1.3 .5.2 1 1.3.5.3 sameas before- 2,610 llmin largerareacoveredby monitoris 15mx14.5m:217.5m' m 1 Ot l m ' 1 m i n x 2 1 7 . 5 ' : 2 , 1 7 5 t l m i n remains 2,610 titresper minute. foam rate therefore The required
225
IBC Code
2 Recalculate requiredfoam concentrate supply:
1136
3 11.3.7
]Hi,l?Jl'#,::il.::::'J,..:?:",f:,,i1?:r'.Ll;j"o'th
50% of foam supplyrate 2 , 6 1 0 l l m i nx 0 . 5 : 1 , 3 0 5l l m t n
R e c a l c u l a tm i n i m u mm o n i t o rc a p a c i t y : e
10 llm'1min of areaprotectedby monitor :: 1o tlmtl^in x 217.5m' = 2,175llmin The new minimurnmonitorcapacity therefore is 2,175 tlmin.
226
passivation Procedures inspectiotr, for cleaning, and loadingof tanksfor the carriage of peroxide hydrogen solutions 60"/", which have Bcontained other cargos, for the carriage or of other cargoes after the carriage . of hydrogenperoxide*
I Tanks having contained cargoes other than hydrogen peroxide shouldbe inspected, cleanedand passivated beforere-use the transport for peroxide of hydrogen The solutions. procedures inspection for and cleaning, s a s g i v e ni n p a r a g r a p h 1 . 1 t o 1 . 7 b e l o w , a p p l y t o b o t h s t a i n l e ss t e e la n d p u r e a l u m i n i u mt a n k s ( s e e p a r a g r a p h . 2 0 . 1 6 o f t h e B C H C o d e a n d 4 p a r a g r a p h 5 . 5 . 1 5 f t h e I B C C o d e ) .P r o c e d u r efs r p a s s i v a t i oa r e g i v e ni n n 1 o o p a r a g r a p h . 8 f o r s t a i n l e s s t e e la n d 1 . 9 f o r a l u m i n i u m U n l e s so t h e r w i s e 1 . specified, stepsapplyto the tanksand to all associated all equipment having been in contactwith the other cargo. 1.1 After unloading previous the cargothe tank shouldbe rendered safe for and inspected any residues, scaleand rust. 1.2 Tanks and associated equipment should be washed with clean filteredwater. The water to be used should at least have the quality of potablewater with a low chlorinecontent. 1.3 Traceresidues vapours the previous and of cargoshouldbe removed by steaming f tankand equipment. o 1.4 Tank and equipmentare washedagainwith cleanwater (qualityas above)and dried,usingfiltered, oil-free air. 1.5 The atmosphere the tank shouldbe sampledand investigated in for the presence organicvapoursand oxygenconcentration. of 1.6 l n T h e t a n ks h o u l db e c h e c k e d g a i nb y v i s u a i n s p e c t i o f o r r e s i d u e o f a s the previouscargo,scaleand rust as well as for any smellof the previous car8o. 1,7 lf inspection measurements indicatethe presence residues or of of the previous cargo or its vapours, steps1.2 to 1.4 shouldbe repeated. 1.8 T a n ka n d e q u i p m e n m a d ef r o m s t a i n l e ss t e e lw h i c h h a v ec o n t a i n e d t s other cargoesthan hydrogenperoxideor which have been under repair regardless any previouspassivation, of should be cleanedand passivated, according the followingprocedure: to
* These procedureswere originallypubfishedas the annex to MSClCrrc.394.
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IBC Code
.l
N e w w e l d s a n d o t h e r r e p a i r e dp a r t s s h o u l d b e c l e a n e da n d or chisel, sandpaper buff. steelwire brush, finished usingstainless . R o u g hs u r f a c e s h o u l db e g i v e na s m o o t hf i n i s h A f i n a lp o l i s h i n g is necessary. , , appropriateorganic solventsor detergentsolutionsin water. s ng T h e u s eo f c h l o r i n e - c o n t a i n ic o m p o u n d s h o u l db e a v o i d e da s with passivation interfere they can seriously
a .3 T h e r e s i d u e so f t h e d e g r e a s i n g g e n t s h o u t d b e r e m o v e d , followedby a washingwith water. .4 In the next step, scale and rust should be removed by the acids), of application acid (e.g.a mixtureof nitricand hydrofluoric followedagainby a washingwith cleanwater.
.5 A l l t h e m e t a l s u r f a c e sw h i c h c a n c o m e i n t o c o n t a c t w i t h of by hydrogenperoxideshould be passivated the application between 10 and 35% by weight. nitri. acid of a concentration other oxidizing The nitric acid must be free from heavy metals, processshould agents or hydrogen fluoride. The passivation n u d f c o n t i n u e o r B t o 2 4 h o u r s , e p e n d i n g p o n t h e c o n c e n t r a t i oo f . e a c i d ,t h e a m b i e n t e m p e r a t u r a n d o t h e rf a c t o r sD u r i n gt h i st i m e and to contactbetweenthe surfaces be passivated a continuous h t h e n i t r i ca c i ds h o u l db e e n s u r e dI.n t h e c a s eo f l a r g es u r f a c ets i s g h b m a y b e a c h i e v e d y r e c i r c u l a t i ntg e a c i d . H y d r o g e n a sm a y b e process, of leadingto the presence an evolvedin the passivation e x p l o s i v e a t m o s p h e r e i n t h e t a n k s . T h e r e f o r e ,a p p r o p r i a t e o o m m e a s u r e s u s t b e t a k e nt o a v o i d t h e b u i l d - u p r t h e i g n i t i o n f s u c ha n a t m o s p h e r e . washedwith shoutdbe thoroushly the .6 After passivation surfaces clean filteredwater. The washingprocessshould be repeated w u n t i l t h e e f f l u e n t a t e r h a s t h e s a m e p H v a l u ea s t h e i n c o m i n g water. to . 7 Surfaces treatedaccording the above stepsmay causesome d e c o m p o s i t i o nw h e n c o m i n g i n t o c o n t a c t w i t h h y d r o g e n will peroxidefor the first time. This decomposition ceaseafter a short time (usuallywithin two or three days). Thereforean peroxide a periodof at least for with hydrogen flushing additional two daysis recommended. agentsand acid cleaningagentswhich have .8 Only degreasing o f b e e n r e c o m m e n d e do r t h i s p u r p o s eb y t h e m a n u f a c t u r e rf t h e . hydrogenperoxideshouldbe used in the process. l.g T a n k s a n d e q u i p m e n t m a d e f r o m a l u m i n i u ma n d w h i c h h a v e contained cargoesother than hydrogen peroxide,or which have been The and passivated. followingis an example , u n d e rr e p a i r s h o u l db e c l e a n e d p of a recommended rocedure: 228
nt Re/eva decisions of the MSC and MEPC .l T h e t a n k s h o u l d b e w a s h e dw i t h a s o l u t i o no f a s u l p h o n a t e d in detergent hot water,followedby a washingwith water. of of solutionof sodiumhydroxide a concentration 7"/"by weight solution or treatedfor a longer period with a lessconcentrated T ( e . g . f o r1 2 h o u r sw i t h 0 . 4 t o 0 . 5 %s o d i u mh y d r o x i d e ) .o p r e v e n t with at excessive corrosion the bottom of the tank when treating water should of solutions sodiumhydroxide, more concentrated s b e a d d e d c o n t i n u o u s l t o d i l u t e t h e s o d i u mh y d r o x i d e o l u t i o n y which collects there. washedwith clean,filteredwater. .3 The tank shouldbe thoroughly As soon as possible after washing, the surface should be passivated the application nitric acid of a concentration of by process should between30 and 35% by weight.The passivation c D f c o n t i n u e o r 1 6 t o 2 4 h o u r s . u r i n gt h i st i m e a c o n t i n o u s o n t a c t and to betweenthe surfaces be passivated the nitricacid should be ensured. washedwith shouldbe thorouShly the .4 After passivation surfaces clean,filteredwater. The washingprocessshould be repeated w u n t i l t h e e f f l u e n t a t e r h a s t h e s a m e p H v a l u ea s t h e i n c o m i n g water. s . 5 A v i s u a li n s p e c t i o n h o u l db e m a d e t o e n s u r et h a t a l l s u r f a c e s flushing that an additional have been treated.lt is recommended i s c a r r i e do u t f o r a m i n i m u mo f 2 4 h o u r sw i t h d i l u t e h y d r o g e n peroxide solution of a concentraction approximately3% by weight. peroxide to solution of and I.10 The concentraction stability the hydrogen *i b e l o a d e ds h o u l db e d e t e r m i n e d . t 1 . 1 1 T h e h y d r o g e np e r o x i d ei s l o a d e d u n d e r i n t e r m i t t e nv i s u a ls u p e r o o v i s i o no f t h e i n t e r i o r f t h e t a n k f r o m a n a p p r o p r i a t e p e n i n g . r w b 1 . 1 2 l f s u b s t a n t i a lu b b l i n gi s o b s e r v e d h i c h d o e s n o t d i s a p p e aw i t h i n o , o 1 5 m i n u t e s f t e rt h e c o m p l e t i o n f l o a d i n g t h e c o n t e n t s f t h e t a n k s h o u l d a . la o a b e u n l o a d e d n d d i s p o s e d f i n a n e n v i r o n m e t a l sy f em a n n e rT h et a n ka n d above. as equipmentshou[dthen be repassivated described o a 1 . 1 3 T h e c o n c e n t r a t i o n n d s t a b i l i t y f t h e h y d r o g e np e r o x i d es o l u t i o n w l a a s h o u l db e d e t e r m i n e d g a i n . f t h e s a m ev a l u e s r e o b t a i n e d i t h i nt h e l i m i t s d t o f e r r o ra s i n s t e p 1 . 9 ,t h e t a n k i s c o n s i d e r e do b e p r o p e r l yp a s s i v a t ea n d the cargo readyfor shipment. / l} n o 1 . 1 4 S t e p s1 . 1 t o 1 . 7 s h o u l db e c a r r i e d u t u n d e rt h e s u p e r v i s i oo f t h e o 1 . m a s t e r r s h i p p e rS t e p s . 8 t o 1 . 1 2s h o u l db e c a r r i e d u t u n d e rt h e o n - s i t e o of of and supervision responsibility a respresentative the hydrogenperoxide y a m a n u f a c t u r eo r u n d e r s u p e r v i s i o n n d r e s p o n s i b i l i to f a n o t h e r p e r s o n r properties hydrogenperoxide. of with the safety-relevant familiar
229
IBC Code The following procedure should be applied when tanks having 2 containedhydrogenperoxidesolutionare to be used for other products all (unless specified, stepsapplyto the tanksand to all associated otherwise p h e q u i p m e n t a v i n gb e e n i n c o n t a c tw i t h h y d r o g e n e r o x i d e ) : .l Hydrogen peroxidecargo residueshould be drained as comf p l e t e l ya s p o s s i b l er o m t a n k sa n d e q u i p m e n t
.2 Tanks and equipmentshould be rinsedwith clean water, and washedwith cleanwater. thorouShly subsequently for .3 The interiorof the tank should be dried and inspected any residues. n or of out underthe supervision the master 2.1 to 2.3 shouldbe carried Steps with the safetyfamilier out by a person Step2.3 shouldbe carried the shipper. properties of the chemical to be transportedand of hydrogen relevant. peroxide. may enrich the CAUTIONS: 1 Hydrogenperoxidedecomposition SPECIAL with oxygen and appropriateprecauatmosphere tionsshouldbe observed. 2 Hydrogen gas may be evolved in the passivation 1.8.5,1.9.2and in processes described paragraphs 1.9.4, leading to the presenceof 1an explosive orp, appropriate atmospherein the tank. Theref " measures must be taken to avoid (he build-upor
the ignition of such an atmosphere.
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CODE FORTHECONSTRUCTION INTERNATIONAL C T AN D EQU IPM ENOF SH IPS AR R YIN G IN D AN GER OUC H EM IC ALS BU IK S ( r BCC OD E)
| 998 Edition
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ln the last sentence of the existingparagraph 8.3.2, replace the 3 "8.3.5" by referenceto "8.3.6". referenceto Add the followingnew paragraph8.3.3 after the existingparagraph 4 8.3.2: "8.3.3 On ships constructed on or after 1 July 2002, controlled tank venting systemsshould consistof a primary and a secondary means of allowingfull flow reliefof vapour to preventover-pressure i o r u n d e r - p r e s s u r en t h e e v e n t o f f a i l u r e o f o n e m e a n s . sensors Alternatively, secondarymeansmay consistof pressure the
' These amt'ndments were adopted by the Marine Environment Protection Committee by 'l o r t ' s o l u l i o nM E P C . 7 9 ( 4 3 ) n 1 J u l y 9 9 9 a n d w i l l b e c o m e e f f e c t i v eo n 1 J u l y 2 0 0 2 .
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fitted in each tank with a monitoring system in the ship's cargo control room or positionfrom which cargo operationsare normally c a r r i e d o u t . S u c h m o n i t o r i n ge q u i p m e n ts h o u l d a l s o p r o v i d e a n or alarm facility which is activated by detection of over-pressure under-pressure conditionswithin a tank." Renumber the existing paragraphs8.3.3 to 8.3.7 as paragraphs 5 8 . 3 . 4t o 8 . 3 . 8 . 6 In the last sentenceof renumbered paragraph8.3.5, replace the r e f e r e n c eo " 8 . 3 . 3 . 1 " b v r e f e r e n c e o " 8 . 3 . 4 . 1 " . t I Chapter 16 - Operational requirements (paragraph16.7), 7 f o the list of additionaloperationalrequirements " a d d " 8 . 3 . 6 " u n d e r n e a t h 7 . 1. 6 . 3 " . Amendments to chapters 5, 14, 15 and 16" : Chapter 5 - Cargo transfer 5J 1 Ships' cargo hoses Rep/aceexistingparagraph5.7.3 by the following: "5J.3 For cargo hoses installedon board ships on or after 1 July 2OO2, each new type of cargo hose, complete with end-fittings, at should be prototype-tested a normal ambient temperaturewith 2OO pressure cycles from zero to at least twice the specified After this cycle pressure test has been maximum working pressure. carried out, the prototype test should demonstrate a bursting pressure at least5 times its specified maximum working pressure of at the extreme service temperature. Hoses used for prototype testing should not be used for cargo service.Thereafter,before being placed in service,each new length of cargo hose produced should be hydrostaticallytested at ambient temperature to a p r e s s u r en o t l e s st h a n 1 . 5 t i m e s i t s s p e c i f i e dm a x i m u m w o r k i n g The pressurebut not more than two-fifthsof its burstingpressure. hose should be stencilledor otherwise marked with the date of testing, its specified maximum working pressureand, if used in its services other than the ambient temperatureservices, maximum and minimum service temperature,as applicable.The specified maximum working pressureshouldnot be lessthan 10 bar gauge." protection Chapter 14 - Personnel 2 Reptace existingparagraph 14.2.9by the following: "14.2.9 The ship should have on board medical first-aidequipf n o m e n t , i n c l u d i n g x y g e n r e s u s c i t a t i oe q u i p m e n ta n d a n t i d o t e s o r cargoes to be carried,based on the guidelinesdeveloped by the Organization." Chapter 15 - Specia/ requirements 3 .l Replacethe existing text of section 5.3 by the following: "15.3 Carbon disulphide m e C a r b o nd i s u l p h i d e a y b e c a r r i e d i t h e ru n d e r w a t e r p a d o r u n d e r suitableinert gas pad as specifiedin the following paragraphs.
These amendments were adopted by the Marine Environment Protection Committee by M o r e s o l u t i o n E P C . 9 0 ( 4 5 ) n 5 O c t o b e r 2 0 0 0 a n d w i l l b e c o m e e f f e c t i v eo n 1 l u l v 2 0 0 2 .
Carriage under water pad 15.3.1 Provisionshould be made to maintain a water oad in the c a r g o t a n k d u r i n g l o a d i n g ,u n l o a d i n ga n d t r a n s i t .I n a d d i t i o n ,a suitable inert gas pad should be maintained in the ullage space d u r i n gt r a n s i t . 15.3.2 All openings should be in the top of the tank, above the deck. 15.3.3 Loadinglinesshould terminatenear the bottom of the tank. 15.3.4 A standard ullage opening should be provided for emergencysounding. 1 5 . 3 . 5 C a r g o p i p i n g a n d v e n t l i n e s s h o u l d b e i n d e p e n d e n to f piping and vent lines used for other cargo. 15.3.6 Pumps may be used for discharging cargo, provided they types.The driven submersible are of the deepwell or hydraulically m e a n so f d r i v i n ga d e e p w e l lp u m p s h o u l dn o t p r e s e n t s o u r c eo f a i g n i t i o nf o r c a r b o n d i s u l p h i d e n d s h o u l d n o t e m p l o y e q u i p m e n t a that may exceed a temperatureof 80"C. 15.3.7 lf a cargo dischargepump is used, it should be inserted through a cylindricalwell extendingfrom the tank top to a point near the tank bottom. A water pad should be formed in this well before attemptingpump removalunlessthe tank has been certified as gas-free. 15.3.8Water or inert gas displacement may be used for dischargingcargo, provided the cargo system is designedfor the expected pressureand temperature. steelconstruction. 15.3.9 Safetyreliefvalvesshould be of stainless 15.3.10 ecause of its low ignition temperature and close B requiredto arrestits flame propagation, only intrinsically clearances safe systemsand circuits should be permitted in the hazardous locationsdescribedin 1O.2.3. Carriage under suitable inert gas pad l 5 . 3 . t l C a r b o n d i s u l p h i d e h o u l d b e c a r r i e di n i n d e p e n d e nt a n k s s with a design pressureof not lessthan 0.6 bar gauge. All 15.3.12 openings should be located on the top of the tank, above the deck. 15.3.13 Caskets used in the containment system should be of a material which does not react with. or dissolve in. carbon disulohide.
15.3.14 Threaded joints should not be permitted in the cargo s c o n t a i n m e n t y s t e m i,n c l u d i n gt h e v a p o u r l i n e s . 15.3.15 Prior to loading,the tank(s)should be inerted with suitable inert gas until the oxygen level is 2% by volume or lower. Means maintaina positivepressure in should be providedto automatically the tank using suitable inert gas during loading, transport and discharge.The system should be able to maintain this positive pressurebetween 0.1 and O.2 bar gauge,and should be remotely alarms. monitored and fitted with over-/under-pressure
1
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H 1 5 . 3 . 1 6 o l d s p a c e ss u r r o u n d i n ga n i n d e p e n d e n tt a n k c a r r y i n g i s c a r b o nd i s u l p h i d e h o u l db r ei n e r t e db y a s u i t a b l e n e r tg a su n t i lt h e oxygen level is 2"h or less.Means should be provided to monitor and maintainthis condition throughout the voyage. Means should also be provided to sample these spacesfor carbon disulphide vaoour. 1 5 . 3 . 1 7 a r b o n d i s u l p h i d e s h o u l d b e l o a d e d , t r a n s p o r t e da n d C dischargedin such a manner that ventingto the atmospheredoes v n o t o c c u r . l f c a r b o nd i s u l p h i d e a p o u r i s r e t u r n e dt o s h o r ed u r i n g the vapour return system loading or to the ship during discharge, should be independentof all other containmentsystems. 1 5 . 3 . 1 8 a r b o n d i s u l p h i d es h o u l d b e d i s c h a r g e do n l y b y s u b C merged deepwell pumps or by a suitableinert gas displacement. The submergeddeepwell pumps should be operated in a way that p r e v e n t sh e a t b u i l d - u pi n t h e p u m p . T h e p u m p s h o u l d a l s o b e e q u i p p e d w i t h a t e m p e r a t u r es e n s o ri n t h e p u m p h o u s i n gw i t h remote readout and alarm in the cargo control room. The alarm should be set at B0'C. The pump should also be fitted with an automatic shut-down device, if the tank pressure falls below during the discharge. atmosphericpressure 15.3.19 should not be allowed to enter the cargo tank, cargo Air p u m p o r l i n e sw h i l e c a r b o n d i s u l p h i d e s c o n t a i n e di n t h e s y s t e m . i 1 5 . 3 . 2 0 o o t h e r c a r g o h a n d l i n g ,t a n k c l e a n i n g o r d e b a l l a s t i n g N should take place concurrentwith loadingor dischargeof carbon disulohide. 15.3.21 water spray system of sufficient capacity should be A provided to blanket effectivelythe area surrounding the loading manifold, the exposed deck piping associated with product h a n d l i n g a n d t h e t a n k d o m e s . T h e a r r a n g e m e n to f p i p i n g a n d nozzles should be such as to give a uniform distributionrate of 1O llm2 lmin Remote manual operation should be arrangedsuch that remote startingof pumps supplyingthe water-spraysystem and remote operationof any normally closed valves in the system can be carried out from a suitablelocationoutside the cargo area and adjacentto the accommodationspacesand readily accessible operablein the event of fire in the areasprotected.The water-spray
system should be capable of both local and remote manual operation, and the arrangement should ensure that any spilled to cargo is washed away. Additionally,a water hose with pressure the nozzle when atmospheric temperature permits, should be connected ready for immediate use during loading and unloading ooerations. at No 15.3.22 cargo tanks should be more than 98% liquid-full the referencetemperature(R). 15.3.23 The maximum volume (VL)of cargo to be loaded in a tank s h o u l db e :
Chapter 16 - Operational requirements .16.3.3 Replace existingparagraph by the following: 4 "16.3.3 Officers should be trained in emergency procedures to or deal with conditionsof leakage,spillage fire involvingthe cargo, based on the guidelinesdeveloped by the Organization,and a sufficient number of them should be instructed and trained in essential first aid for cargoescarried."
Vt: O.98Vff
where: V : pn : pr : R : volume of the tank relativedensityof cargo at the reference ( temperature R) relativedensity of cargo at the loading temperature referencetemperature,i.e.,the temperatureat which the vapour pressureof the cargo correspondsto the valve. set pressureof the pressure-relief
The maximum allowable tank filling limits for each cargo 15,3.24 tank should be indicatedfor each loading temperaturewhich may be applied, and for the applicable maximum referencetemperaA ture, on a list approved by the Administration. copy of the list should be permanentlykept on board by the master. spaces on open 15.3.25 Zones on open deck, or semi-enclosed deck within three metres of a tank outlet, gas or vapour outlet, cargo pipe flange or cargo valve of a tank certifiedto carry carbon l d i s u l p h i d e s h o u l d c o m p l y w i t h t h e e l e c t r i c a e q u i p m e n tr e q u i r e ' , "i", chapter 17. ments specifiedfor carbon disulphidein column Also, within the specifiedzone, no other heat sources,like steam piping with surface temperaturesin excess of B0'C should be allowed. 15.3.26 Means should be provided to ullageand samplethe cargo without opening the tank or disturbingthe positive suitable inert gas blanket. only in accordancewith The product should be transported 15.3.27 a cargo handling plan that has been approved by the Administrat i o n . C a r g o h a n d l i n gp l a n s s h o u l d s h o w t h e e n t i r e c a r g o p i p i n g system.A copy of the approved cargo handling plan should be availableon board. The Certificateof Fitnessfor the Carriageof D a n g e r o u s C h e m i c a l si n B u l k s h o u l d b e e n d o r s e d t o i n c l u d e referenceto the approved cargo handling plan."